Delineating volcanic aquifer recharge areas using geochemical and isotopic tools

Relative recharge areas are evaluated using geochemical and isotopic tools, and inverse modeling. Geochemistry and water quality in springs discharging from a volcanic aquifer system in Guatemala are related to relative recharge area elevations and land use. Plagioclase feldspar and olivine react with volcanically derived CO₂ to produce Ca-montmorillonite, chalcedony and goethite in the groundwater. Alkalinity, Mg, Ca, Na, and SiO_2(aq) are produced, along with minor increases in Cl and SO₄ concentrations. Variations in groundwater δD and δ¹⁸O values are attributed to recharge elevation and used in concert with geochemical evolution to distinguish local, intermediate, and regional flow systems. Springs with geochemically inferred short flow paths provided useful proxies to estimate an isotopic gradient for precipitation (??.67 δ¹⁸O/100?m). No correlation between spring discharge and relative flow-path length or interpreted recharge elevation was observed. The conceptual model was consistent with evidence of anthropogenic impacts (sewage and manure) in springs recharged in the lower watershed where livestock and humans reside. Spring sampling is a low-budget approach that can be used to develop a useful conceptual model of the relative scale of groundwater flow (and appropriate watershed protection areas), particularly in volcanic terrain where wells and boreholes are scarce.     

Geochemical and flow modelling as tools in monitoring managed aquifer recharge

Due to a growing world population and the effects of anthropogenic climate change, access to clean water is a growing global concern. Managed aquifer recharge (MAR) is a method that can help society's response to this increasing demand for pure water. In MAR, the groundwater resources are replenished and the quality of the recharged surface water is improved through effects such as the removal of organic matter. This removal occurs through mechanisms such as microbial decomposition, which can be monitored by studying the isotopic composition of dissolved inorganic carbon (DIC). Nevertheless, the monitoring can be difficult when there are other factors, like dissolving calcite, affecting the isotopic composition of DIC.The aims of this study were to establish a method for monitoring the decomposition of organic matter (dissolved organic carbon – DOC) in cases where calcite dissolution adds another component to the DIC pool, and to use this method to monitor the beginning and amount of DOC decomposition on a MAR site at Virttaankangas, southwestern Finland. To achieve this, we calculated the mean residence times of infiltrated water in the aquifer and the fractions of this water reaching observation wells. We conducted geochemical modelling, using PHREEQC, to estimate the amount of DOC decomposition and the mineral reactions affecting the quality of the water.     

A thirty-year artificial recharge experiment in a coastal aquifer in an arid zone: The Teboulba aquifer system (Tunisian Sahel)

With the increased demand for groundwater resulting from fast demographic growth, accelerated urbanization, economic and agricultural activity diversification, and the increase of per capita consumption, ground water resources, in particular in coastal regions, remain relatively low, compared to demand. The groundwater quality and piezometric variations result mainly from intensive exploitation, agricultural activities and the intrusion of seawater. This phenomenon is observed mostly in semi-arid areas, such as the oriental Sahel of Tunisia, where an apparent reduction in rainfall in recent years can be seen. Groundwater becomes overexploited especially as its natural recharge by rainwater does not succeed in maintaining the hydrologic balance. The imbalance between water demand and resources induces the degradation of the water quality. In such a case, the artificial recharge of water-table aquifers by water from dams is a credible alternative to improve the hydrodynamic and physicochemical conditions of the groundwater. Like most coastal aquifers, the Teboulba water-table aquifer is threatened by overexploitation for at least three decades. This threat appears by a considerable piezometric level drop and by water salinisation, due to seawater intrusion. Given this alarming situation, since 1971, artificial recharge through wells with surface water from a dam was tested in order to restore the water levels and to improve water quality. The piezometric and chemical surveys of the Teboulba aquifer permitted one to describe the temporal and spatial piezometric and geochemical conditions of the aquifer and to show the effect of the artificial recharge. Indeed, the artificial recharge undertaken since 1971 made the geochemical and piezometric conditions of the Teboulba aquifer improve. This example is a rare, well-documented case-study of the benefits of artificial recharge in a coastal aquifer, over the long term.     

Principles to coordinate managed aquifer recharge with natural resource management policies in Australia

Managed aquifer recharge (MAR) is a tool available to water-resources managers that assists agencies to secure water supplies and protect aquifers and groundwater-dependent ecosystems in the face of climate change and growing water demand. Yet few natural-resources managers have access to a coordinated set of policies that enable the potential benefits of MAR to be fully realised in urban and rural areas. This paper reviews contemporary Australian water-resource policies and systematically applies a refined set of ‘robust separation of rights’ principles based on secure entitlements, annual allocations and end-use obligations to guide the coordination of policies specific to each of the four operational processes central to MAR schemes: source water harvesting, aquifer recharge, recovery of stored water and end use. Particular attention is given to the formulation of policies relating to the recovery of water, including the feasibility for market exchange of permanent and temporary rights to recover recharged water, as these have the potential to greatly expand the role of MAR. Aquifer characteristics, existing groundwater extractions and potential third party effects need to be taken into account in determining both recovery entitlements and annual allocations. A transitional pathway to implement novel MAR policies is suggested.     

Use of treated wastewater for managed aquifer recharge in highly populated urban centers: a case study in Addis Ababa,Ethiopia

Fast population growth and rapid industrialization, on one hand, and lack of sewerage network and poor living condition, on the other, have led to the deterioration of surface and ground water quality in the city of Addis Ababa. The urban wastewater is discharged largely into streams that drain the city. Only less than 3% join the wastewater treatment facilities. Due to sporadic rainfall that causes shortage in groundwater recharge, managed aquifer recharge (MAR) experiment was tested on soil column collected from Akaki Well Field which is located in the southern part of the city using water from the Big Akaki River that crosses the same well field and effluent from Kaliti Wastewater Treatment Plant. Water quality analysis for 17 different parameters was done for both the inflow and outflow water samples and soils were tested for electrical conductivity and cation exchange capacity. The results indicate improved water quality as a result of higher attenuation/filtration capacity of the vadose zone in the well field due to the presence of vertisols. The main geochemical processes that have acted in the soil column could be cation exchange, dissolution, precipitation, oxidation, nitrification, die off etc. that are responsible for the effectiveness of vadose zone for MAR.     

Interactions of diffuse and focused allogenic recharge in an eogenetic karst aquifer (Florida, USA)

The karstic upper Floridan aquifer in north-central Florida (USA) is recharged by both diffuse and allogenic recharge. To understand how recharged water moves within the aquifer, water levels and specific conductivities were monitored and slug tests were conducted in wells installed in the aquifer surrounding the Santa Fe River Sink and Rise. Results indicate that diffuse recharge does not mix rapidly within the aquifer but instead flows horizontally. Stratification may be aided by the high matrix porosity of the eogenetic karst aquifer. Purging wells for sample collection perturbed conductivity for several days, reflecting mixing of the stratified water and rendering collection of representative samples difficult. Interpretive numerical simulations suggest that diffuse recharge impacts the intrusion of allogenic water from the conduit by increasing hydraulic head in the surrounding aquifer and thereby reducing influx to the aquifer from the conduit. In turn, the increase of head within the conduits affects flow paths of diffuse recharge by moving newly recharged water vertically as the water table rises and falls. This movement may result in a broad vertical zone of dissolution at the water table above the conduit system, with thinner and more focused water-table dissolution at greater distance from the conduit.     

The effect of typical geological heterogeneities on the performance of managed aquifer recharge: physical experiments and numerical simulations

Understanding the role of geological heterogeneity on the performance of managed aquifer recharge (MAR) in terms of effective groundwater storage is crucial to design MAR systems. Natural aquifers are affected by a variety of geologic strata and structures at different scales, which are responsible for wide ranging hydraulic properties. This study combines physical experiments and numerical modeling to investigate the effect of geologic structures commonly encountered in sedimentary environments, on MAR-induced groundwater flow patterns using injection wells. Models were conceptualized and parametrized based on the hydrogeological conditions of Tailan River basin in arid NW China, which hosts a typical, structurally complex, alluvial-fan aquifer system affected by sediment layering, clay lenses and anticline barriers, and is extensively studied for the strategic potential of MAR in addressing water shortages in the region. Results showed that, compared to a homogeneous scenario, high-permeability aquifer layers shortened groundwater ages, decreased the thickness of the artificially recharged water lenses (ARWLs), and shifted the stagnation points downstream. Clay lenses increased groundwater residence times but had little effect on spatial flow patterns due to their elongation parallel-to-flow direction. Overall groundwater ages, as well as the thickness of ARWLs created through injection on the upstream side of an anticline, increased, and this to a larger extent than through injection on the downstream side, which did not increase significantly compared to the homogeneous scenario. Results provide insights for MAR optimization in naturally heterogeneous aquifer systems, along with a benchmark tool for application to a wide range of typical geological conditions.

     

A comparison of the geochemical response to different managed aquifer recharge operations for injection of urban stormwater in a carbonate aquifer

Managed aquifer recharge (MAR) is increasingly being considered as a means of reusing urban stormwater and wastewater to supplement the available water resources. Subsurface storage is advantageous as it does not impact on the area available for urban development, while the aquifer also provides natural treatment. However, subsurface storage can also have deleterious effects on the recovered water quality through water–rock interactions which can also impact on the integrity of the aquifer matrix. A recent investigation into the potential for stormwater recycling via Aquifer Storage Transfer and Recovery (ASTR) in a carbonate aquifer is used to determine the important hydrogeochemical processes that impact on the recovered water quality. An extensive period of aquifer flushing allows observation of water quality changes under two operating scenarios: (1) separate wells for injection and recovery, representing ASTR; and (2) a single well for injection and recovery, representing Aquifer Storage and Recovery (ASR).     

屋面雨水回灌裂隙岩溶水工程风险评价

济南城市雨洪水回灌岩溶含水层是维护自然水循环,增加地下水补给量,维持济南泉群喷涌以及城市防洪的有效途径。但由于裂隙岩溶含水层具有渗透系数大、水流速度快,地下水一旦污染很难短时间恢复等特点,需要对回灌工程开展风险评价。本文以济南大学西校区的屋面雨水深井回灌裂隙岩溶水工程为例,利用澳大利亚MAR指南对工程进行风险评价。主要由初级风险评估、试运行调查、试运行风险评价及风险控制与管理4部分组成。初级风险评估结果显示屋面雨水回灌裂隙岩溶含水层工程的总体难度水平较低,项目可行。试运行调查期间监测的屋面雨水和回灌前后地下水水质可知屋面雨水经初期弃流、沉淀和过滤后,除浊度外基本达到地下水Ⅲ类标准,且处理后达标的雨水可迅速补充地下水。试运行风险评价结果显示屋面雨水中浊度经预处理后仍较高,使其成为该系统的最大风险项和关键控制点,故本项目的风险控制措施为改进预处理设施,降低雨水中的浊度。为保证工程能够高效持续运行,加强后期管理也尤为重要。      

Percolation pond as a method of managed aquifer recharge in a coastal saline aquifer: A case study on the criteria for site selection and its impacts

Percolation ponds have become very popular methods of managed aquifer recharge due to their low cost, ease of construction and the participation and assistance of community. The objective of this study is to assess the feasibility of a percolation pond in a saline aquifer, north of Chennai, Tamil Nadu, India, to improve the storage and quality of groundwater. Electrical resistivity and ground penetrating radar methods were used to understand the subsurface conditions of the area. From these investigations, a suitable location was chosen and a percolation pond was constructed. The quality and quantity of groundwater of the nearby area has improved due to the recharge from the pond. This study indicated that a simple excavation without providing support for the slope and paving of the bunds helped to improve the groundwater quality. This method can be easily adoptable by farmers who can have a small pond within their farm to collect and store the rainwater. The cost of water recharged from this pond works out to be about 0.225 Re/l. Cleaning the pond by scrapping the accumulated sediments needs to be done once a year. Due to the small dimension and high saline groundwater, considerable improvement in quality at greater depths could not be achieved. However, ponds of larger size with recharge shafts can directly recharge the aquifer and help to improve the quality of water at greater depths.     

Numerical simulation of a managed aquifer recharge system designed to supply drinking water to the city of Amsterdam,The Netherlands

Managed aquifer recharge (MAR) is increasingly used to secure drinking water supply worldwide. The city of Amsterdam (The Netherlands) depends largely on the MAR in coastal dunes for water supply. A new MAR scheme is proposed for the production of 10 × 10⁶ m³/year, as required in the next decade. The designed MAR system consists of 10 infiltration ponds in an artificially created sandbank, and 25 recovery wells placed beneath the ponds in a productive aquifer. Several criteria were met for the design, such as a minimum residence time of 60 days and maximum drawdown of 5 cm. Steady-state and transient flow models were calibrated. The flow model computed the infiltration capacity of the ponds and drawdowns caused by the MAR. A hypothetical tracer transport model was used to compute the travel times from the ponds to the wells and recovery efficiency of the wells. The results demonstrated that 98% of the infiltrated water was captured by the recovery wells which accounted for 65.3% of the total abstraction. Other sources include recharge from precipitation (6.7%), leakages from surface water (13.1%), and natural groundwater reserve (14.9%). Sensitivity analysis indicated that the pond conductance and hydraulic conductivity of the sand aquifer in between the ponds and wells are important for the infiltration capacity. The temperature simulation showed that the recovered water in the wells has a stable temperature of 9.8–12.5 °C which is beneficial for post-treatment processes. The numerical modelling approach is useful and helps to gain insights for implementation of the MAR.

     

Alleviating drought and water scarcity in the Mediterranean region through managed aquifer recharge

Drought and water scarcity can significantly impair the sustainable development of groundwater resources, a scenario commonly found in aquifers in the Mediterranean region. Water management measures to address these drivers of groundwater depletion are highly relevant, especially considering the increasing severity of droughts under climate change. This study evaluates the potential of managed aquifer recharge (MAR) to offset the adverse effects of drought and water scarcity on groundwater storage. Los Arenales aquifer (central Spain), which was unsustainably exploited for irrigation in the second half of the twentieth century, is employed as a case study. Two neighbouring zones within this aquifer are contrasted, namely, Los Arenales (LA) and Medina del Campo (MC). The primary difference between them in terms of water resources management is the wide-scale implementation of MAR systems in LA since the early 2000s. Several groundwater statistical methods are used. Groundwater-level trend analysis and average piezometric levels show in LA a faster recovery of aquifer storage and less susceptibility to drought compared to MC. On the other hand, standardised precipitation indexes and standardised groundwater level indexes of detrended groundwater-level time series, which do not include the effects of MAR, show that LA can be more negatively affected by drought and groundwater abstraction. The sharper recovery of piezometric levels in LA when considering MAR, and bigger drought impacts observed when the effects of this measure are removed, demonstrate that MAR can effectively alleviate the impacts of water scarcity and drought, providing an adaptation solution to climate change worldwide.

     

Impact of recharge water temperature on bioclogging during managed aquifer recharge: a laboratory study

To investigate the effect of recharge water temperature on bioclogging processes and mechanisms during seasonal managed aquifer recharge (MAR), two groups of laboratory percolation experiments were conducted: a winter test and a summer test. The temperatures were controlled at ~5±2 and ~15±3 °C, and the tests involved bacterial inoculums acquired from well water during March 2014 and August 2015, for the winter and summer tests, respectively. The results indicated that the sand columns clogged ~10 times faster in the summer test due to a 10-fold larger bacterial growth rate. The maximum concentrations of total extracellular polymeric substances (EPS) in the winter test were approximately twice those in the summer test, primarily caused by a ~200 μg/g sand increase of both loosely bound EPS (LB-EPS) and tightly bound EPS (TB-EPS). In the first half of the experimental period, the accumulation of bacteria cells and EPS production induced rapid bioclogging in both the winter and summer tests. Afterward, increasing bacterial growth dominated the bioclogging in the summer test, while the accumulation of LB-EPS led to further bioclogging in the winter test. The biological analysis determined that the dominant bacteria in experiments for both seasons were different and the bacterial community diversity was ~50% higher in the winter test than that for summer. The seasonal inoculums could lead to differences in the bacterial community structure and diversity, while recharge water temperature was considered to be a major factor influencing the bacterial growth rate and metabolism behavior during the seasonal bioclogging process.     

Estimation of groundwater recharge in a major sand and gravel aquifer in Ireland using multiple approaches

Groundwater recharge was investigated in the most extensive sand and gravel aquifer (area of approximately 200 km²) in the Republic of Ireland as part of a wider study seeking to derive recharge estimates using aquifer vulnerability mapping. The proportion of effective rainfall (total rainfall minus actual evapotranspiration) that leads to recharge is known as the recharge coefficient. The recharge investigation involved a variety of approaches, including soil moisture budgeting, well hydrograph analysis, numerical modelling and a catchment water balance. The adoption of multiple techniques provided insights on recharge and also on aquifer properties. Comparison of two soil moisture budgeting approaches (FAO Penman-Monteith with Penman-Grindley) showed how variations in the effective rainfall values from these methods influence groundwater levels simulated in a numerical groundwater model. The catchment water balance estimated the recharge coefficient to be between 81 and 85%, which is considered a reasonable range for this aquifer, where overland flow is rarely observed. The well hydrograph analysis, using a previous estimate of specific yield (0.13), gave recharge coefficients in the range of 40–80%, considered low for this aquifer: a revised specific yield of 0.19 resulted in a more reasonable range of recharge coefficients of between 70 and 100%.     

In situ infiltration test using a reclaimed abandoned river bed: managed aquifer recharge in Shijiazhuang City,China

Managed aquifer recharge (MAR) is necessary for water resources management in arid and semiarid regions. Infiltration rate is often a decisive limiting factor in site selection for MAR. In order to avoid scale effects in the application of infiltration rate parameters, the largest in situ infiltration test in China was undertaken between August 19 and August 30, 2009 to measure the infiltration rate of the field selected for MAR in Shijiazhuang City, China. The in situ test lasted for 10 days, and about 1.82 × 10⁷ m³ of water was introduced into the infiltration field. Groundwater level variations were monitored during the test. Monitoring showed that the infiltration rate of surface water was 1.5 m/day, which means that about 10–15 × 10⁸ m³/a of water could be injected into the target aquifer. Also, groundwater level variations showed that the northern part of the infiltration field had a higher infiltration rate, as predicted, and the test result supplied a sound foundation for validation of the groundwater numerical simulation, which will be of benefit for future predictions of the response of the groundwater level to artificial recharge engineering. Finally, an artificial recharge plan was proposed based on the infiltration test results and the water source conditions, which would be useful for the development of MAR programs and management of local water resources.     

Contribution of geophysical surveys to groundwater modelling of a porous aquifer in semiarid Niger: An overview

Subsurface geophysical surveys were carried out using a large range of methods in an unconfined sandstone aquifer in semiarid south-western Niger for improving both the conceptual model of water flow through the unsaturated zone and the parameterization of numerical a groundwater model of the aquifer. Methods included: electromagnetic mapping, electrical resistivity tomography (ERT), resistivity logging, time domain electromagnetic sounding (TDEM), and magnetic resonance sounding (MRS). Analyses of electrical conductivities, complemented by geochemical measurements, allowed us to identify preferential pathways for infiltration and drainage beneath gullies and alluvial fans. The mean water content estimated by MRS (13%) was used for computing the regional groundwater recharge from long-term change in the water table. The ranges in permeability and water content obtained with MRS allowed a reduction of the degree of freedom of aquifer parameters used in groundwater modelling.     

Aquifer residence times for recycled water estimated using chemical tracers and the propagation of temperature signals at a managed aquifer recharge site in Australia

A prerequisite for minimizing contamination risk whilst conducting managed aquifer recharge (MAR) with recycled water is estimating the residence time in the zone where pathogen inactivation and biodegradation processes occur. MAR in Western Australia’s coastal aquifers is a potential major water source. As MAR with recycled water becomes increasingly considered in this region, better knowledge of applied and incidental tracer-based options from case studies is needed. Tracer data were collected at a MAR site in Floreat, Western Australia, under a controlled pumping regime over a distance of 50 m. Travel times for bromide-spiked groundwater were compared with two incidental tracers in recycled water: chloride and water temperature. The average travel time using bromide was 87?±?6 days, whereas the estimates were longer based on water temperature (102?±?17 days) and chloride (98?±?60 days). The estimate of average flow velocity based on water temperature data was identical to the estimate based on bromide within a 25-m section of the aquifer (0.57?±?0.04 m day^?1). This case study offers insights into the advantages, challenges and limitations of using incidental tracers in recycled water as a supplement to a controlled tracer test for estimating aquifer residence times.     

Desalination of a sedimentary rock aquifer system invaded by Pleistocene Champlain Sea water and processes controlling groundwater geochemistry

The objective of this study was to identify geochemical processes and Quaternary geological events responsible for the variations in groundwater geochemistry observed in a sedimentary rock aquifer system, including brackish to saline groundwater. Inorganic constituents and environmental isotopes were analyzed for 146 groundwater samples. Dissolution of carbonates dominates in recharge areas, resulting in Ca-, Mg-HCO₃ groundwater. Further along flow paths, under confined conditions, Ca²⁺–Na⁺ ion exchange causes groundwater evolution to Na-HCO₃ type. Na-Cl groundwater is also found and it falls on a seawater mixing line. Using conservative tracers, Cl⁻ and Br⁻, the original Champlain Sea water is shown to have been, in the region, a mixture of about 34% seawater and 66% freshwater, a composition still retained by some groundwater. Na-Cl groundwater thus results from mixing with former Champlain Sea water and also from solute diffusion from overlying marine clay. The system is thus found to be at different stages of desalinization, from the original Champlain Sea water still present in hydraulically stagnant areas of the aquifer to fully flushed conditions in parts, where more flow occurs, especially in recharge zones. The geochemical processes are integrated within the hydrogeological context to produce a conceptual geochemical evolution model for groundwater of the aquifer system.     

Hydrogeologic controls on groundwater recharge and salinization: a geochemical analysis of the northern Hueco Bolson aquifer, Texas, USA

Identification of hydrogeologic controls on groundwater flowpaths, recharge, and salinization is often critical to the management of limited arid groundwater resources. One approach to identifying these mechanisms is a combined analysis of hydrogeologic and hydrochemical data to develop a comprehensive conceptual model of a groundwater basin. To demonstrate this technique, water samples were collected from 33 discrete vertical zone test holes in the Hueco Bolson aquifer, located within the Trans-Pecos Texas region and the primary water resource for El Paso, Texas, USA and Juárez, Mexico. These samples were analyzed for a suite of geochemical tracers and the data evaluated in light of basin hydrogeology. On the basis of δ²H and δ¹⁸O data, two regional recharge sources were recognized, one originating from western mountain-fronts and one from through-flow of the adjacent Tularosa aquifer. Chloride concentrations were strongly correlated with lithologic formations and both Cl/Br and ³⁶Cl ratios suggested the primary chloride source is halite dissolution within a specific lithologic unit. In contrast, sulfur isotopes indicated that most sulfate originates from Tularosa basin Permian gypsum sources. These results yielded a more comprehensive conceptual model of the basin, which suggested that chloride salinization of wells is the result of upconing of waters from the Fort Hancock formation.     

Delineating spring recharge areas in a fractured sandstone aquifer (Luxembourg) based on pesticide mass balance

A simple method to delineate the recharge areas of a series of springs draining a fractured aquifer is presented. Instead of solving the flow and transport equations, the delineation is reformulated as a mass balance problem assigning arable land in proportion to the pesticide mass discharged annually in a spring at minimum total transport cost. The approach was applied to the Luxembourg Sandstone, a fractured-rock aquifer supplying half of the drinking water for Luxembourg, using the herbicide atrazine. Predictions of the recharge areas were most robust in situations of strong competition by neighbouring springs while the catchment boundaries for isolated springs were extremely sensitive to the parameter controlling flow direction. Validation using a different pesticide showed the best agreement with the simplest model used, whereas using historical crop-rotation data and spatially distributed soil-leaching data did not improve predictions. The whole approach presents the advantage of integrating objectively information on land use and pesticide concentration in spring water into the delineation of groundwater recharge zones in a fractured-rock aquifer.