新疆且末县米特河地区1:5万水系沉积物地球化学特征及找矿意义

根据1:5万水系沉积物地球化学测量工作成果,对采集的3138件样品中Cu,Pb,Zn,Au,Ag,W,Sn,Mo,Bi,As,Sb,Cr,Co,Ni共14种元素进行分析测试。研究结果表明,Au,Ag,Cu,Ni是区内最有找矿潜力的成矿指标元素;聚类分析所划分的4类元素簇群,主要与中低温成矿元素、阿尔金南缘断裂、蛇绿混杂岩相关,通过因子分析得到Ni-Cr-As-Sb-Cu-Bi,W-Bi-As-Cu,Bi-W,As,Ag-Zn-Pb,Cu-Bi-As共6类元素组合。其中Cr,Ni,Sb,Cu,As,Bi组合反映出与低温热液活动和断裂构造活动有关;Cr,Ni元素的富集主要与研究区内叶桑岗蛇绿混杂岩带关系密切;Ag,Pb,Zn组合则与地层低温热液元素局部富集和断裂构造活动密切相关。在综合异常分析和查证的基础上,结合区域成矿地质条件、区内矿产地质特征,圈定、划分出2个找矿远景区,并指出了研究区内以金、铜、银、镍为主要优势矿种,铅、锌为潜力矿种。     

Geochemical features of sulfides from the Deyin-1 hydrothermal field at the southern Mid-Atlantic Ridge near 15°S

In this study, geochemical compositions of elements in sulfide samples collected from the Deyin-1 hydrothermal field near the 15°S southern Mid-Atlantic Ridge (SMAR) were analyzed by the X-ray fluorescence spectrometry (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) to examine the enrichment regulations of ore-forming elements and hydrothermal mineralization. These sulfide precipitates can be classified macroscopically into three types: Fe-rich sulfide, Fe-Cu-rich sulfide and Fe-Zn-rich sulfide, and are characterized by the enrichment of base metal elements along with a sequence of Fe>Zn>Cu. Compared with sulfides from other hydrothermal fields on MAR, Zn concentrations of sulfides in the research area are significantly high, while Cu concentrations are relatively low. For all major, trace or rare-earth elements (REE), their concentrations and related characteristic parameters exhibit significant variations (up to one or two orders of magnitude), which indicates the sulfides from different hydrothermal vents or even a same station were formed at different stages of hydrothermal mineralization, and suggests the variations of chemical compositions of the hydrothermal fluid with respect to time. The hydrothermal temperatures of sulfides precipitation decreased gradually from station TVG10 (st.TVG10) to st.TVG12, and to st.TVG11, indicating that the precipitation of hydrothermal sulfides is subjected to conditions changed from high temperature to low temperature, and that the hydrothermal activity of study area was at the late stage of a general trend of evolution from strong to weak. The abnormally low concentrations of REE in sulfides and their similar chondrite-normalized REE patterns show that REEs in all sulfides were derived from a same source, but underwent different processes of migration or enrichment, or sulfides were formed at different stages of hydrothermal mineralization. The sulfides collected from the active hydrothermal vent were mainly attributed to precipitating directly from the hydrothermal fluid, while those collected from the extinct hydrothermal chimney might have already been altered by the seawater. Generally, ore-forming elements in the sulfides can be divided into three groups: Fe-based element group, Cu-based element group and Zn-based element group. The first group includes Fe, Mn, Cr, Mo, Sn, Rb and bio-enriching elements, such as P and Si, reflecting the similar characteristics to Fe in the study area. And the second group contains Cu, W, Co, Se, Te and Bi, suggesting the similar behavior with Cu. Moreover, the third group includes Zn, Hf, Hg, Cd, Ta, Ga, Pb, As, Ag, Ni and Sb, which indicates the geochemical characteristics of most dispersed trace elements controlled by Zn-bearing minerals to some extent.     

华北地块北缘金、多金属成矿地质背景

华北地块北缘是我国重要的金、多金属成矿带。根据区域地质建造特点、构造性质将研究区划分为５种成矿地质背景。不同的区域成矿地质背景有不同的成矿特点：变质基底区,主要形成沉积变质改造型ＣｕＦｅＡｕＰｂＺｎ成矿系列;盖层区,主要在中晚元古代沉降区形成ＰｂＺｎ（Ａｇ）沉积成矿系列、ＰｂＺｎ（ＡｇＡｕ）沉积改造成矿系列;地槽区,主要形成中酸性岩浆热液多金属成矿系列,火山－次火山热液金、多金属成矿系列,基性－超基性岩浆ＣｕＮｉ成矿系列;中生代火山断陷盆地,主要形成中酸性火山－次火山金、多金属成矿系列;构造岩浆活动带则广泛形成中酸性岩浆热液金、多金属成矿系列。     

应用聚类和因子分析讨论猫岭金矿元素组合特征

猫岭金矿是一低品位、大型热液型金矿床。金矿体主要以脉状、似层状、透镜状产于下元古界辽河群盖县组二段的千枚岩中,受北北东向片理化带及低序次构造裂隙所控制。矿床原生晕样品的 R 型聚类分析和因子分析的结果表明,与金矿化关系最密切的元素为 Pb、Ag,其次为 As。即 Au、Pb、Ag 代表了主成矿阶段矿化元素组合特征,而 As 和 Co、Ni 元素组合分别反映了与 Au 矿化具成因联系的毒砂和磁黄铁矿化特点。(Au、Pb、Ag)因子与(As、Ag)因子紧密相关,与宏观上所见矿化阶段生成的矿物(自然金、方铅矿等)沿毒砂裂隙分布的特点相吻合,从而说明这两个因子的元素组合代表了最佳成矿地段的元素组合特征。     

滨州海岸带土壤和海底沉积物重金属空间分布特征

通过对滨州近海海域海底沉积物测试数据及海岸带陆域土壤地球化学分析,对滨州海岸带陆域土壤和海底沉积物中7种重金属(Hg,Cd,Pb,Cu,Zn,Cr,Ni)的空间分布特征进行了研究,并绘制了各指标含量陆海联合分区图。分析结果表明,滨州市海岸带重金属元素含量基本上均低于国标规定的海洋一类沉积物的最高标准,仅有个别元素含量超过一级标准值,表明局部存在一定的重金属污染。从滨州海岸带重金属含量空间分布上来看,除Hg元素外,其余重金属元素含量呈现一定的规律,基本上陆域含量高于海域含量,且大部分元素都呈现出陆域城镇值高,郊区值低的态势。区内化工企业较发达,Ni,Cr属于中度变异区,Cd,Hg,Pb属于高度变异,受人为影响因素较大,考虑区内土壤及海底沉积物重金属富集主要来源于工业"三废"。     

The Mineral Composition and Sources of the Fine-Grained Sediments from the 49.6°E Hydrothermal Field at the SWIR

We used the X-ray diffraction method to determine systematically the mineral phases in bulk sediment samples and acid undissolved residuals of the fine-grained fraction of the surface sediments from the 49.6°E hydrothermal field at the Southwest Indian Ridge(SWIR)and discussed the mineral sources of the surface sediments.The results showed that the surface sediments in this region were composed of calcareous ooze,and calcite was the dominant mineral.The sediments also contained quartz,feldspar,clay minerals,pyroxene,sphalerite,barite,serpentine,and magnetite.The quartz,feldspar,and clay minerals were exogenous minerals that mainly originated from the Namib and Kalahari deserts in southern Africa.The pyroxene,serpentine,magnetite,sphalerite,calcite,and barite were endogenous minerals from weathering of seafloor basement rocks and seafloor hydrothermal activities.The sulfide particles in the sediments were mainly deposited from upwelling plumes.     

Distribution and source of main contaminants in surface sediments of tidal flats in the Northern Shandong Province

Twenty-nine samples of surface sediments from tidal flats in the Northern Shandong Province were collected for grain size, heavy metal(Hg, Cu, Pb, Zn, Cd, and Cr), and oil pollution analyses. The geoaccumulation index(Igeo) and factor analysis were introduced to evaluate sediment quality and source of contaminants. The mean concentrations of Hg, Cu, Pb, Zn, Cd, Cr, and oil in the surface sediments in the study area are 0.033, 17.756, 19.121, 55.700, 0.291, 59.563, and 14.213 μg g-1, respectively. The heavy metal contamination in the old delta lobe is slightly higher than that in the abandoned delta lobe; however, the opposite was observed for oil pollution. The Igeo results revealed that the overall quality of the surface sediments in the study area is in good condition. The heavy metal pollution levels show a descending order: Cd Hg Cr Cu Zn Pb, Cd being the main pollutant. The contamination level for in the study area is relatively lower than those for China's other tidal flats. Heavy metals are mainly derived from natural sources of rock weathering and erosion, partly influenced by industrial and agricultural discharge. However, oil pollution is mainly from runoff input, motorized fishing boat sewage, and oil exploitation.     

胶东乳山金矿区原生晕地球化学特征及深部成矿预测

英格庄金矿以相对富As、Co、Ni而三甲和铜锡山金矿则以相对富Cu、Pb、Zn、Ag为特征.聚类分析显示,英格庄金矿具Bi+Hg、As+Sb+Co与Pb+Zn组合,三甲金矿具Bi+Hg+As+Sb+Co、Pb+Zn与Ag+Cu+Au组合,而铜锡山金矿则显示Bi+Hg+Sb+Pb+Ag、Cu+Au+Zn+As及Mo+Ni组合.结合Ni、Co、Mo与Ag、Hg、As、Sb等的相关特征,认为上述三个金矿均有成矿头尾晕叠加现象.Au、Ag、Cu、Pb、Zn、As、Sb、Bi、Hg、Mo等元素垂向变化规律显示,英格庄金矿在-200m标高以下、三甲金矿在-500m标高以下尚有成矿富集段存在.其中,所确定的英格庄金矿的靶位在16勘探线附近,三甲金矿的靶位则在16～20勘探线间.     

Mitochondrial phylogenomics reveal the origin and adaptive evolution of the deep-sea caridean shrimps(Decapoda:Caridea)

The deep-sea is considered as the most extensive ecosystem on the Earth.It is meaningful for elucidating the life origins by exploring the origin and adaptive genetic mechanisms of the large deepsea organisms.Caridean shrimps have colonized and successfully adapted to deep-sea environments.They provide an ideal model to analyze the origin and adaptive evolution of modern deep-sea fauna.Here,we conducted the phylogenetic analyses of mitocho ndrial genomes(mitogenomes) from carideans,including 11 newly sequences reported in this investigation to explore the habitat origins,divergence times,and adaptive evolution of deep-sea(seamounts and hydrothermal vents) caridean shrimps.The results showed that the species of deep-sea Caridea formed a monophyletic group.Phylogenetic analysis supported that the deepsea caridean shrimps may originated from shallow sea.The hydrothermal vents alvinocaridid shrimps and Lebbeus shinkaiae from Thoridae underwent a second range expansion from seamounts to vent ecosystems.Estimates of divergence time showed that the caridean shrimps invaded into deep-sea at 147.75 Ma.The divergence of most of the modern seamount and hydrothermal vent species are in the late Cretaceous/early Tertiary.This may associate with the geological events of the Western Pacific,the climate change,and the global deep-water anoxic/dysoxic events during this period.Twenty-two potentially important adaptive residues were detected in the deep-sea shrimp lineage,which were located in atp6,atp8,cox1,cox3,cytb,nad2,nad4 l,and nad5.This investigation adds our understanding of the evolutionary history of deep-sea caridean shrimps,and provides insights into the mitochondrial genetic basis of deep-sea adaptation in this group.     

基于便携式X射线荧光光谱(PXRF)分析的西南印度洋脊龙角区沉积物地球化学找矿研究

洋中脊热液活动伴生的多金属硫化物是未来重要的接替资源,但目前其勘查技术手段相对匮乏。便携式X射线荧光光谱(PXRF)是针对野外原位快速分析而发展起来的一项新技术,常被应用于岩石露头地球化学研究和土壤重金属污染评价。采用PXRF对西南印度洋脊龙角区的沉积物开展了化学组成分析,并通过元素的空间分布特征确定热液区可能产出的位置。结果表明,研究区的沉积物可能由钙质沉积物、基岩碎屑、热液组分等组成,部分沉积物具有较高的热液成矿元素含量,明显受到了热液活动的影响。通过面浓度-个数分形方法,确定Cu、Zn、Fe、Mn、As等主要成矿元素的异常下限。根据上述元素的空间分布特征,在研究区识别出了6处异常区,其中3处异常区与已知热液区相吻合,另外3处异常区可能代表了未发现的热液活动。上述工作为洋中脊多金属硫化物的勘查提供了新的思路。      

Geological,physical, and chemical characteristics of seafloor hydrothermal vent fields

Seafloor hydrothermal vent fields(SHVFs) are located in the mid-ocean ridge(MOR),backarc basin(BAB),island arc and hot-spot environments and hosted mainly by ultramafic,mafic,felsic rocks,and sediments.The hydrothermal vent fluids of SHVFs have low oxygen,abnormal pH and temperature,numerous toxic compounds,and inorganic energy sources,such as sulfuric compounds,methane,and hydrogen.The geological,physical,and chemical characteristics of SHVFs provide important clues to understanding the formation and evolution of seafloor hydrothermal systems,leading to the determination of metal sources and the reconstruction of the physicochemical conditions of metallogenesis.Over the past two decades,we studied the geological settings,volcanic rocks,and hydrothermal products of SHVFs and drawn new conclusions in these areas,including:1) the hydrothermal plumes in the Okinawa Trough are affected by the Kuroshio current;2) S and Pb in the hydrothermal sulfides from MOR are mainly derived from their host igneous rocks;3) Re and Os of vent fluids are more likely to be incorporated into Fe-and Fe-Cu sulfide mineral facies,and Os is enriched under low-temperature(200℃) hydrothermal conditions in global SHVFs;4) compared with low-temperature hydrothermal sulfides,sulfates,and opal minerals,high-temperature hydrothermal sulfides maintain the helium(He) isotopic composition of the primary vent fluid;5) relatively low temperature(116℃),oxygenated,and acidic environment conditions are favorable for forming a native sulfur chimney,and a "glue pudding" growth model can be used to understand the origin of native sulfur balls in the Kueishantao hydrothermal field;and 6) boron isotope from hydrothermal plumes and fluids can be used to describe their diffusive processes.The monitoring and understanding of the physical structure,chemical composition,geological processes,and diverse organism of subseafloor hydrothermal systems will be a future hot spot and frontier of submarine hydrothermal geology.     

延边地区火山岩型金矿地球化学及成矿作用研究

延边地区北部大面积出露中生界（Ｊ３）火山岩系，为正常的钙碱性系列，由玄武岩－安山岩－石英安山岩组成，以富含ＡＳ、Ａｇ、Ｓｂ、ＡＳ、Ｂｉ为特征。其中的金矿床可分为两类即蚀变岩型高温热液矿床和浅成中低温热液矿床。同位素资料表明，其成矿热液主要来自火山岩浆。     

山东沂南铜井金矿地质地球化学特征及矿床成因探讨

山东沂南铜井金矿位于沂沭断裂带的鄌郚-葛沟断裂西侧,是鲁西典型的矽卡岩型金矿。矿石成分主要有自然金、黄铁矿、黄铜矿、石榴子石、方解石、石英等,矿石结构主要有半自形-他形粒状结构、他形填隙结构、压碎结构等,矿石构造类型有浸染状构造、脉状构造、块状构造。矿石岩性主要有黄铁矿化闪长玢岩、黄铁矿化角岩、黄铁矿化磁铁矿化矽卡岩、黄铁矿化大理岩还有部分石英脉型矿石和磁黄铁矿型矿石。成矿期次划分为矽卡岩期、热液期、表生期。该文利用光谱分析对矿石中Au,Ag,Cu,Pb,Zn,As,Sb,Bi 8种微量元素进行相关性分析和聚类分析。利用电子探针对矿石薄片进行微区分析,对矿石元素地球化学等特征进行研究总结,研究表明:光谱中Au,Cu,Ag,Sb四种元素显示了较好的聚类特征,对找矿有较好的指示作用。电子探针数据分析显示Co与Ni的比值大于1,As元素含量较低,矿床呈现岩浆热液成矿与变质热液成矿叠加的特点。     

新疆东昆仑三岔顶地区水系沉积物地球化学特征及找矿方向研究

通过开展三岔顶一带1:5万水系沉积物测量,分析了研究Au,Ag,Cu,Pb,Zn,W,Sn,Mo,As,Bi,Sb,Cr,Ni,Co,Hg,Cd共16种元素地球化学参数特征及其相关性,认为该区元素的富集与地层、构造、岩浆岩明显相关;Hg,Cr,Ni,W,As,Au,Pb,Zn等元素变异系数较大,易于形成异常;Ag,As,Au,Co,Cr,Cu,Hg,Ni,Sb,Zn等10种元素不同程度富集,成矿可能性大。通过因子分析,提取了6种具有代表性的因子组合类型,讨论了各元素空间分布特征。全区共圈定31处地球化学综合异常,在综合异常查证的基础上,结合区域成矿地质条件、矿产地质特征,圈定出寒凝泉铬钴镍铜、黄沙河东铜银钼铅多金属、月牙湾铜银铅锌多金属3处找矿远景区,为该地区进一步开展找矿工作提供了基础地球化学依据。     

青海省锡铁山铅锌矿成矿元素物质场结构及深部找矿潜力

青海省柴达木盆地北缘锡铁山铅锌矿是我国大型的喷流沉积型(SEDEX)矿床，赋矿围岩主要是大理岩和片岩，浅部主要为大理岩型矿体，深部主要为片岩型矿体。系统描述了不同矿石类型中铅锌矿体与黄铁矿的空间共生关系、矿体空间形态三维变化规律；利用局部奇异性分析方法、相关性分析方法对矿区Pb、Zn、Ag、Au等成矿元素物质场结构特征及变化趋势进行了系统分析，2种分析方法均可表现元素物质场不同的结构特征，即:Pb、Zn、Au元素整体上沿着矿体的侧伏方向仍然有明显的向深部富集的趋势，且不受大理岩的影响，在片岩中物质场所反映的元素富集程度依然很强；Ag元素整体上从浅部到深部在矿化空间内均有明显的不连续富集特征。锡铁山铅锌矿水平方向上元素分带由远至近(由西向东)依次为Mn-Fe-S-Ag-Pb-Zn-S-Au，垂向上元素分带由上到下依次为Mn-S-Ag-Pb-Zn-S-Au，同时系统研究了成矿元素物质场中元素富集结构的变化规律，分析讨论了锡铁山深部找矿潜力。      

Impact of Drain Effluent on Surficial Sediments in the Mediterranean Coastal Wetland: Sedimentological Characteristics and Metal Pollution Status at Lake Manzala,Egypt

Surface sediments were collected from Lake Manzala, the Mediterranean coastal wetland located to the east of the Nile Delta, Egypt, to assess the effect of drain effluent on the spatial variations of sedimentary characteristics and heavy metal pollution. Grain-size compositions, textures, and heavy metal distribution patterns in sediments are presented using GIS technique. Results of the analysis of the sediment showed a clear effect of drain effluent, with an increase in fine fractions and homogeneous suspensions in transportation mode. Lake sediments were dominated by sandy mud textures, and mode of transportation was homogeneous suspension and rolling. Spatial distribution of heavy metals(Fe, Mn, Zn, Cu, Ni, Cr, and Pb) was studied in the lake's surficial sediments, along with their relationship to drain effluent and their contamination status in the ecological system. Heavy metal pollution status was assessed by means of accepted sediment quality guidelines and contamination assessment methods(contamination factor, contamination degree, modified contamination degree, geo-accumulation, and enrichment factor). Among the determined heavy metals, Pb had the most ecological risk. Generally, the heavy metals in the surface sediments indicated pollution risk ranging from moderate to considerable, particularly, in those sites facing drains and inlets that had the highest toxic effluent. The results were interpreted by statistical means. A cluster analysis defined areas facing drain discharge and inlets as separated groups. ANOVA indicated that most of the sedimentation and studied metals directed this clustering.     

舟山西蟹峙海洋倾倒区及邻近海域表层沉积物重金属污染及其生态风险评价

根据2011年7月浙江舟山西蟹峙海洋倾倒区及邻近海域表层沉积物重金属的监测结果,采用单因子指数法和Hakanson生态危害指数法分析表层沉积物重金属的污染特征,并评价其潜在生态风险。结果表明:沉积物重金属元素Cu、Zn、Pb、Cd、Cr、Hg、As含量均符合国家海洋沉积物质量一类标准;重金属元素污染程度由高到低依次为Zn、Cr、Pb、Cu、As、Cd、Hg,其中Cu、Pb、Cd、Hg和As 5种重金属元素为低污染水平,Zn和Cr 2种重金属元素为中等污染程度水平;7种重金属元素单个和综合潜在生态危害程度均为低风险水平,由高到低依次为Cd、Hg、As、Pb、Cu、Cr、Zn。     

多元统计在化探数据分析中的应用——以沂源县鲁村镇崮山村地区土壤化探测量为例

地球化学元素的多元统计分析可以推测地球化学元素在复杂的成矿过程中的组合及演化特征,从而为预测找矿提供有用的微观信息。应用多元统计方法,对沂源县鲁村镇崮山村地区土壤、岩石地球化学测量数据进行研究分析,得出:与中国东部岩石丰度对比,研究区岩石背景特征为Au,Ag,Pb,Sb,As,Hg元素富集,Cu,Zn贫化;与山东省土壤背景值对比,研究区土壤背景值中Au,Ag,Cu,Pb,Zn元素都出现了不同程度的富集。区内成矿元素组合特征表现为:Ag,Pb,Zn元素之间相关性较强,其中Ag、Pb元素之间的相关性最强,反应出了组合成矿的可能性;而Au与其他元素几乎不具相关性,Cu元素与Ag,Pb,Zn元素均具有弱相关性。通过因子分析得出成矿元素的富集与矿化过程大致可以划分3个阶段:Ag-Pb-Zn元素组合的富集与矿化;Cu元素的富集与矿化;Au元素的富集与矿化;反映出了该区多期富集或蚀变矿化特点。利用因子得分圈定元素组合异常,通过异常分析,并结合地质背景、地质构造特征,最终圈定找矿有利靶区,为进一步找矿提供了科学依据。     

青城子矿田石英脉-硅质岩与金银成矿关系讨论

辽东裂谷西段辽河群赋存大型铅锌矿床,近年又发现多处大（ 中）型金银矿床。目前的研究表明,该区金银资源潜力仍然很大。一个值得重视的地质现象是所有金、银矿床都伴随有硅质岩、石英脉的出现。硅质岩受层位控制,呈似层状、扁豆状,基本平行上下岩层,本身亦可构成矿体。辽东裂谷中的金、银、铅、锌矿床与石英脉关系密切,石英脉的规模、分布及特征在很大程度上决定矿床规模。因此,硅质岩、石英脉是地质找矿的直接标志,如在青城子地区,找到了硅质岩就可以发现金矿化。硅质岩主要成分是玉髓,矿物学特征和稀土地球化学特征表明硅质岩是浅海火山喷气的产物,形成于辽河群沉积时沿同生断裂发生的火山喷溢时期,而石英脉则为岩浆期后热液成因,后期热液的叠加更有利于成矿。     

黑龙江省草帽山-基座山地区地球化学特征及成矿远景预测

黑龙江省草帽山-基座山地区位于大兴安岭中段华力西、燕山期铁、钨、银、金、钼、铜成矿带的北东端,呼玛县兴隆砂金矿区的南部。区内经历了漫长的沉积地层发育及多期次的强烈岩浆活动,分布有众多砂金矿床及岩金矿点,成矿条件较为优越。文章对区内1∶5万水系沉积物测量采集的样品分析数据进行了统计分析,将11种元素划分成Ag,Cu,Pb,Zn组合类型、W,Mo,Bi组合类型、As,Sb,Hg组合类型、Au组合类型,总结了区内地球化学特征及地质意义,并通过对各元素的平均值、变异系数、相关性及元素空间分布特征进行比较研究,认为Au元素含量高于全省丰度、变异系数为大(5.668),单元素异常强度高、浓度分带明显,为该区最主要的成矿元素,研究区是金成矿的有利地区。