Multiple mantle metasomatism beneath the Leizhou Peninsula,South China: evidence from elemental and Sr-Nd-Pb-Hf isotope geochemistry of the late Cenozoic volcanic rocks

ABSTRACT

We analysed whole-rock major and trace elements and Sr-Nd-Pb-Hf isotopes of the late Cenozoic volcanic rocks in the Leizhou Peninsula, South China to investigate their mantle source characteristics. These volcanic rocks, collected from Jiujiang, Tianyang and Huoju areas of the Leizhou Peninsula, are characterized by incompatible element enrichment but variable isotopic depletion. The volcanic rocks from Jiujiang and Tianyang show prominent primitive-mantle-normalized positive Nb, Ta and Sr anomalies and depleted Sr-Nd-Pb-Hf isotope compositions, whereas those from Huoju show slight positive to negative Nb and Ta anomalies, a prominent positive Pb anomaly, and more enriched Sr-Nd-Pb-Hf isotope compositions. Two types of mantle metasomatism are required to explain the geochemical characteristics of these rocks. The Jiujiang and Tianyang samples were largely derived from a mantle source metasomatized recently by a low-F melt. Such low-F melt is generated within the asthenospheric mantle, which is enriched in volatiles and incompatible elements with positive Sr anomaly and depleted Sr-Nd-Pb-Hf isotope compositions. The Huoju samples were largely derived from a mantle source metasomatized by recycled upper continental crust material. These two types of mantle metasomatism beneath the Leizhou Peninsula are consistent with trace element characteristics of mantle mineralogy (e.g. clinopyroxene vs. amphibole), which reflects source evolution in space and time (e.g. tectonic setting change).     

Trace Element Geochemistry and Petrogenesis of Finnish Greenstone Belts

Archean metavolcanic rocks from three greenstone belts (Suomussalmi,Kuhmo and Tipasjärvi) of eastern Finland have been subjectto a detailed geochemical study which leads to a discussionof their petrogenesis and the problem of compositional heterogeneityin the Archean mantle. Lithostratigraphically, the greenstonebelts are roughly divided into a lower and an upper volcanicsequence. Rocks of komatiitic and tholeiitic compositions arerestricted to the lower sequence, while andesitic tuffs, dacite-rhyodacitelavas and minor basalts of alkaline affinity occur in the uppersequence. All rocks from the greenstone belts have been subjectto regional metamorphism of the upper greenschist facies tothe lower garnet amphibolite facies. Consequently, the geochemicaldistinction of original magma types and the discussion of petrogenesishave relied heavily on the abundances of less mobile elements,such as TiO₂, rare earth elements (REE), and some transitionmetals (e.g. Ni and Cr). Using all the possible discriminants of major element compositions,we have concluded that two general magmatic series that existin the lower volcanic sequence might be distinguished by theparameter of TiO₂ content: the komatiitic series is characterizedby having TiO₂ 1.0 per cent and the tholeiitic series by 1.0per cent. The general series do not imply that a cogenetic relationshiplinked only by fractional crystallization exists in each series. Several magmatic types could be distinguished by their characteristicREE distribution patterns. In general, the komatiitic rocksshow flat HREE (heavy REE) and flat or depleted LREE (lightREE) patterns; the tholeiitic rocks show fractionated patternswith some degree of LREE enrichment, whilst the acidic rocksdemonstrate highly fractionated patterns with significant HREEdepletion. Model calculations indicate that: (1) the komatiiticand the tholeiitic series have no clear genetic relationship;(2) some basaltic komatiites (MgO < 12 per cent) could havebeen derived by crystal fractionation from a melt of peridotitickomatiite composition (MgO 30 per cent), but others requirevarious degrees of partial melting from the same or differentsource regions to account for their trace element abundances;(3) both partial melting and fractional crystallization haveinterplayed for the production of various rocks within the tholeiiticseries; (4) three different types of source materials are proposedfor all magmas from the lower volcanic sequence. All three typeshave the same initial HREE (about 2x chondrites) but differentLREE (from very depleted to 2x, flat) abundances; (5) volcanicrocks of the upper volcanic sequence must have originated atgreat depths where garnet remains in the residue after partialmelting and melt segregation. The recognition of the strongly LREE-depleted mantle sources,deduced from the REE patterns of peridotitic komatiites fromFinland, Canada and Rhodesia, may suggest that this depletionis a worldwide phenomenon, and that the Archean upper mantleis as heterogeneous in composition as the modern upper mantle.The causal effect of the depletion might be related to the generationof some contemporaneous LREE-enriched tholeiitic rocks, or morelikely, to contemporaneous or previous continental crust formingevents.     

西藏冈底斯带石炭纪陆缘裂陷作用：火山岩和地层学证据

冈底斯作为重要的中、新生代岛弧岩浆岩带,历来是青藏高原最热门的地质研究领域,但是对晚古生代火山岩的性质及其形成的构造背景仍缺乏研究。本文在区域地质调查资料的基础上,对冈底斯带石炭纪火山-沉积岩系进行了系统的地层学和岩石地球化学研究,测量了重点剖面,对火山岩进行了常量、微量元素和Sr、Nd、Pb同位素地球化学测试。研究表明,石炭系与下伏泥盆系或前寒武系之间普遍存在不整合或岩性、沉积相的突变面,代表重要的构造转换面。石炭纪的沉积环境大致有两次滨海-深海或深水斜坡-滨海沉积演化旋回,深海-深水斜坡沉积或冰海相含砾板岩与两次火山活动伴生。石炭纪火山岩主要为安山玄武岩和英安岩、流纹岩类,略具双峰式火山岩特点。安山玄武岩类的成分与典型MORB和岛弧玄武岩相比,具有MgO含量低,TiO2、Al2O3、P2O5含量高等特点,稀土和微量元素为LREE和LILE富集型分配模式,与大陆拉斑玄武岩相似。石炭纪酸性火山岩的稀土和微量元素地球化学特征与陆内流纹岩相似。岩石地球化学示踪和地层学研究表明,冈底斯带石炭纪为伸展背景下的冈瓦纳陆缘裂陷环境。火山岩的源区地幔具有典型的Dupal异常,发生过复杂的混合作用,涉及到原始地幔、富集地幔EMII和地壳成分等,说明发生过冈瓦纳古陆壳俯冲、再循环进入古老地幔等过程。玄武岩类成分的某些特殊性,可能与源区混合作用有关。     

Chemical geodynamics of Western Anatolia

We report major and trace element concentrations and Nd–Sr–Pb isotopic data of 10 post-collisional volcanic domains in Western Anatolia, a seismically active part of the Alpine–Himalayan belt in the Aegean extensional province. Our objective is to provide geochemical constraints for tectono-magmatic processes shaping the late Cenozoic geodynamic evolution of Western Anatolia.

Calc-alkaline volcanic rocks occurring to the north of the Izmir–Ankara–Erzincan suture zone show arc-like trace elements and isotopes and were formed by the melting of the metasomatized Neotethyan mantle-wedge; this process was facilitated by asthenospheric upwelling resulting from slab delamination. Calc-alkaline and alkaline volcanic rocks from within the Izmir–Ankara–Erzincan suture zone also show the imprint of subduction fluids in their major and trace elements, but their isotopic compositions indicate derivation from a metasomatized lithospheric mantle followed by assimilation of ancient crust. Volcanics along the N–S-oriented Kirka–Afyon–Isparta trend were derived from the lithospheric mantle that was metasomatized by fluids from the older subduction of the African plate. Golcuk–Isparta volcanic rocks show an asthenospheric imprint; the latter was a consequence of upwelling following a tear in the subducting African lithosphere. Shoshonitic Kula volcanic rocks show very high trace element concentrations, OIB mantle-like trace elements, and Nd–Sr–Pb isotopic signatures, and were formed by partial melting of the upwelling asthenospheric mantle; this event was synchronous with the Aegean extension and possibly also with slab window formation due to ruptures in the African plate.

Inherent in the above chemical geodynamic models are the high ?_Nd(0) values (+6.4) of the end-member volcanic rocks, implying the presence of an asthenospheric source beneath Western Anatolia that is responsible for the currently observed high heat flow, low Pn wave velocities, high seismicity, and tectonic activity.     

黄骅盆地中新生代火山岩岩相及岩石化学特征

通过对渤海地区黄骅盆地中新生代火山岩进行典型的岩芯取样、岩相及全岩分析,并结合KAr法测年、微量元素和同位素地球化学分析,得出以下结论:主要岩石类型有新生代老第三纪玄武岩、中生代晚白垩世玄武粗安岩、中生代晚白垩世粗面英安岩和流纹岩和中生代早三叠世英安岩。晚中生代火山岩岩石的主量元素丰度呈双峰分布,从老到新,火山岩主元素中SiO2减少,Fe2O3、FeO、CaO、MgO、TiO2、P2O5、MnO有所增加。新生代玄武岩可能源自亏损的软流圈地幔,晚白垩世玄武粗安岩源自玄武质组分亏损和受到富集改造的岩石圈地幔,     

Melting of enriched Archean subcontinental lithospheric mantle: Evidence from the ca. 1760 Ma volcanic rocks of the Xiong’er Group,southern margin of the North China Craton

The Xiong’er Group is an important geologic unit in the southern margin of the North China Craton. It is dominated by the volcanic rocks, dated at 1763 ± 15 Ma, that have SiO₂ contents ranging from 52.10 wt% to 73.51 wt%. These volcanic rocks are sub-alkaline and can be classified into three subgroups: basaltic andesites, andesites and rhyolites. They unexceptionally show enrichment of light rare earth elements (LREE) and share similar trace element patterns. Depletions in Nb, Ta, Sr, P and Ti relative to the adjacent elements are evident for all the samples. The volcanic rocks are evolved with low MgO contents (0.29–5.88 wt%) and accordingly low Mg^# values of 11–53. The Nd isotopes are enriched and show a weak variation with ?_Nd(t) = −7.12 to −9.63. Zircon Hf isotopes are also enriched with ?_Hf(t) = −12.02 ± 0.45. The volcanic rocks of the Xiong’er Group are interpreted to represent fractional crystallization of a common mantle source. The volcanic rocks might have been generated by high-degree partial melting of a lithospheric mantle that was originally modified by the oceanic subduction in the Late Archean. This brings a correlation with the subduction-modified lithospheric mantle in an extensional setting during breakup of the Columbia supercontinent in the late Paleoproterozoic, rather than in an arc setting. The elevated SiO₂ contents and evolved radiogenic isotope features indicate the possible incorporation into their source of lower crustal materials that have similar Nd isotopic characteristics to the subcontinental lithospheric mantle. The existence of extensive Xiong’er volcanic rocks (60,000 km²) indicates an early large-scale subduction-related metasomatism in the area and probably suggest a flat subduction model for the plate-margin magmatism in the Late Archean.     

Petrogenesis of the Neogene volcanic units in the NE–SW-trending basins in western Anatolia,Turkey

The western Anatolian volcanic province formed during Eocene to Recent times is one of the major volcanic belts in the Aegean–western Anatolian region. We present new chemical (whole-rock major and trace elements, and Sr, Nd, Pb and O isotopes) and new Ar/Ar age data from the Miocene volcanic rocks in the NE–SW-trending Neogene basins that formed on the northern part of the Menderes Massif during its exhumation as a core complex. The early-middle Miocene volcanic rocks are classified as high-K calc-alkaline (HKVR), shoshonitic (SHVR) and ultrapotassic (UKVR), with the Late Miocene basalts being transitional between the early-middle Miocene volcanics and the Na-alkaline Quaternary Kula volcanics (QKV). The early-middle Miocene volcanic rocks are strongly enriched in large ion lithophile elements (LILE), have high ⁸⁷Sr/⁸⁶Sr_(i) (0.70631–0.71001), low ¹⁴³Nd/¹⁴⁴Nd_(i) (0.512145–0.512488) and high Pb isotope ratios (²⁰⁶Pb/²⁰⁴Pb = 18.838–19.148; ²⁰⁷Pb/²⁰⁴Pb = 15.672–15.725; ²⁰⁸Pb/²⁰⁴Pb = 38.904–39.172). The high field strength element (HFSE) ratios of the most primitive early-middle Miocene volcanic rocks indicate that they were derived from a mantle source with a primitive mantle (PM)-like composition. The HFSE ratios of the late Miocene basalts and QKV, on the other hand, indicate an OIB-like mantle origin—a hypothesis that is supported by their trace element patterns and isotopic compositions. The HFSE ratios of the early-middle Miocene volcanic rocks also indicate that their mantle source was distinct from those of the Eocene volcanic rocks located further north, and of the other volcanic provinces in the region. The mantle source of the SHVR and UKVR was influenced by (1) trace element and isotopic enrichment by subduction-related metasomatic events and (2) trace element enrichment by “multi-stage melting and melt percolation” processes in the lithospheric mantle. The contemporaneous SHVR and UKVR show little effect of upper crustal contamination. Trace element ratios of the HKVR indicate that they were derived mainly from lower continental crustal melts which then mixed with mantle-derived lavas (~20–40%). The HKVR then underwent differentiation from andesites to rhyolites via nearly pure fractional crystallization processes in the upper crust, such that have undergone a two-stage petrogenetic evolution.     

Trace element evidence for the origin of ocean island basalts: an example from the Austral Islands (French Polynesia)

The Austral Islands, a volcanic chain in the South-Central Pacific Ocean (French Polynesia) are composed mainly of alkali basalts and basanites with subordinate amounts of olivine tholeiites and strongly undersaturated rocks (phonolite foidites and phonolite tephrites). The basaltic rocks have geochemical features typical of oceanic island suites. The distribution of incompatible trace elements indicate that the lavas were derived from a heterogeneous mantle source. The chondrite-normalized patterns of the incompatible elements in basaltic rocks of the Austral Islands are complementary to those of island arc tholeiites. As supported by isotope data, the observed trace element heterogeneities of the source are probably due to mixing of the upper mantle with subducted oceanic crust from which island arc tholeiitic magma was previously extracted.     

Chemical discontinuities in Archean metavolcanic terrains and the development of Archean crust

Most large Archean greenstone belts ( 2.7 Ga), comprise thick (12–15 km) mafic to felsic metavolcanics sequences which exhibit consistent but discontinuous geochemical patterns resulting from mantle-crust processes. In a typical Archean metavolcanic sequence, thick (5–8 km) uniform tholeiitic basalt is followed by geochemically evolved rock units (4–7 km thick) containing intermediate and felsic calc-alkaline rocks. This major geochemical discontinuity is marked by a change from LIL-element depleted basalts which show unfractionated REE abundance patterns, to overlying andesites with higher LIL-element contents, fractionated REE patterns and relatively depleted HREE. A less well marked discontinuity separates andesitic rocks from still later more felsic dacite-rhyolite extrusive assemblages and their intrusive equivalents, and is identified by a further increase in LIL element content and REE fractionation. The major geochemical discontinuity apparently separates rocks derived by partial melting of mantle (either directly or through shallow fractionation processes) from those which originated either by partial melting of mantle material modified by crustal interactions or by partial melting of crustal material.We suggest that accumulation of a great thickness of mantle derived volcanic rocks can lead to sagging and interaction of the lower parts of the volcanic piles with upper mantle material. The resulting modified mantle acts as a source for some of the geochemically evolved rocks observed in volcanic successions. Subsequent direct melting of the volcanic pile produces the felsic magmas observed in the upper parts of Archean volcanic successions. This process, termed sag-subduction, is the inferred tectonic process operating in the comparatively thin, hot Archean crustal regime. By this process, large masses of ultimately mantle-derived material were added to the crust.     

Trace Element Geochemistry of Cenozoic Volcanic Rocks in Shandong Province

The Cenozoic volcanic rock of Shandong Province are mainly alkalic and strongly alkalic basaltic rocks.The Contents of major and trace elements including transitional,incompatible and rare-earth elements were determined.The chemical characterisitics of major and trace elements indicate that these basaltic rocks were derived from a mantle source and probably represent a primary magma,I,e.,unmodifiecd partical melts of mantle peridotite in terms of Mg values,correlatione between P2O5 and Ce,Sr,Ni and Rb concentrations,mantle xenoliths,etc.The abundances of trace elements vary systematically from west to east.The compatible transition elements such as Co,Ni,and Cr show a remarkable depletion,whereas the incompatible and rare-earth elements are abundant as viewed from the chondrite-nor-malized patterns.The chemical composition and correlation are consistent with the tectonic setting.According to the batch and fractional partial melting theory,the trace element contents of Shandong volcanic rocks can be calculated from the two-component mixing model.     

Rare-earth element distributions in volcanic rocks from Archean greenstone belts

Rare-earth element distributions in Archean volcanic rocks from the South Pass (Wyoming), Yellowknife (NW Canada) and Abitibi (Quebec) greenstone belts and from the Upper Fig Tree Group of the Barberton (S. Africa) greenstone belt reveal two distinct types of Archean volcanism. One type, herein referred to as the arc-type, is characterized by flat (or slightly enriched) REE distributions in tho leiites and enrichment in total and light REE and a variable negative Eu anomaly in more siliceous volcanic members. The second type, herein referred to as the Abitibi-type, is characterized by rather flat REE patterns and negative Eu anomalies in all volcanic rock types.REE distributions in the arc-type volcanic successions can be produced by either progressive shallow fractional crystallization of tholeiitic magma or by decreasing amounts of equilibrium melting of a plagioclase-bearing mantle source. REE distributions in the Abitibi volcanic rocks are most readily explained in terms of progressively decreasing amounts of fractional melting of a source area in which REE are contained chiefly in minor minerals (with low melting temperatures) that are depleted in Eu. The melting models seem to necessitate the existence of one or more pre-greenstone magmatic episodes as well as a continuously replenished mantle source. Replenishment of source material could be accomplished in either of the melting models in subduction zones but the analogy to Phanerozoic plate tectonics should be used with caution. Melting models also imply either (or both) a decreasing geothermal gradient with time or systematic changes in mantle source-area composition.     

Trace-element geochemistry of archean greenstone belts

Progressive alteration, diagenesis, and low-grade metamorphism of Archean greenstone belts often leads to redistribution of alkali and related trace elements. Transition metals and rare earths are relatively resistant to these processes and hence are most useful in evaluating petrologic problems.Depleted Archean tholeiite (DAT) exhibits flat REE distributions and low LIL-element contents while enriched Archean tholeiite (EAT) exhibits slightly enriched REE patterns and moderate LIL-element contents. DAT is grossly similar to modern rise and are tholeiites and EAT to cale-alkaline and oceanic island tholeiites. Archean and esites fall into three categories: depleted Archean andesite (DAA) exhibits flat REE patterns, negative Eu anomalies and low LIL-element contents; low-alkali Archean andesite (LAA) shows minor light REE enrichment and low LIL-element contents; and high-alkali Archean andesite (HAA) shows light REE enrichment and high LIL-element contents. LAA is grossly similar to modern cale-alkaline andesites, but DAA and HAA do not have modern analogues. Archean depleted siliceous volcanics (DSV) exhibit depletion in heavy REE and Y compared to modern siliceous volcanics whereas undepleted varieties (USV) are similar to modern ones. Almost all Archean volcanic rocks, regardless of composition, are enriched in transition metals compared to modern varieties. Archean graywackes are similar in composition to Phanerozoic graywackes. Rock associations in Archean greenstones suggest the existence of two tectonic settings.Magma model studies indicate that partial melting has left the strongest imprint on trace-element distributions in greenstone volcanics. Three magma source rocks are necessary (listed in order of decreasing importance): ultramafic rock, eclogite, and siliceous granulite. Trace-element studies of Archean graywackes indicate a mixed volcanic—granitic provenance with minor ultramafic contributions.Alkali and related trace-element contents of Archean volcanics have been interpreted in terms of both undepleted and depleted upper mantle sources. Preferential enrichment of transition metals in Archean volcanics may have resulted from upward movement of immiscible liquid sulfide droplets with Archean magmas, depleting the source area in these elements. Initial Sr isotope distributions in Archean volcanics indicate the upper mantle during the Archean was heterogeneous in terms of its Rb/Sr ratio.     

鲁西纯橄岩捕虏体中富硅质熔（流）体的交代作用：对中生代岩石圈地幔减薄的意义

鲁西中生代辉长-闪长质岩石中纯橄岩捕虏体的岩石学、矿物化学及微量元素地球化学研究表明,纯橄岩捕虏体代表了古老岩石圈地幔的残留;地幔纯橄岩捕虏体中存在两种类型的交代作用,一是以填隙型金云母为代表的早期富含CO_2和H_2O的不活动流体的交代作用;二是以斜方辉石交代脉和网络状斜方辉石为代表的晚期富硅质熔(流)体的交代作用。后者代表了起源于软流圈的富硅质熔(流)体对古老岩石圈地幔的一种化学侵蚀。这对认识华北地块东部中生代岩石圈地幔的性质以及岩石圈减薄机制具有重要意义。     

松辽盆地长岭断陷中基性火山岩的时代与其成因

锆石U-Pb定年结果显示,松辽盆地长岭断陷松南180井中基性火山岩形成于101～116 Ma的早白垩世晚期,属于营城组,非火石岭组火山岩。岩相学观察主要由安山岩和橄榄玄武岩组成,化学成分显示为玄武岩、粗面玄武岩和玄武质粗面安山岩,属碱性系列,镁质量分数较低,镁值较小（Mg^#=0.27~0.53）。稀土元素总量较高（w（∑REE）=（164.98~257.27）×10^-6）,轻重稀土分馏明显（（La/Yb）_N=6.60~10.96）,铕异常微弱（δEu=0.85~1.02）。富集大离子亲石元素和轻稀土元素, Rb,K 相对亏损,相容元素（Cr、Co、Ni）质量分数低,高场强元素Nb、Ta弱富集,整体表现出与 OIB(洋岛玄武岩)一致的稀土图谱和微量元素特征。岩浆源区为软流圈地幔,经历了深部地幔流体的交代富集作用,岩浆未遭受地壳物质的混染。     

Sr and Nd isotopic geochemistry of the early ultramafic–mafic rocks of the Mako bimodal volcanic belt of the Kedougou–Kenieba inlier (Senegal)

The Mako bimodal volcanic belt of the Kédougou–Kéniéba inlier is composed of volcanic basalts and peridotites interbedded by quartzites and limestones intruded by different generations of granitoïds. The early volcanic episode of the belt is constituted of submarine basalts with peridotite similar to those of the oceanic abyssal plains. It is intruded by the Badon Kakadian TTG?granitic batholite dated around 2200 Ma. The second volcanic phase is constituted of basaltic, andesitic, and felsitic flows exhibit structures of aerial volcanic rocks. It is intruded by granites dated between 2160 and 2070 Ma. The general pattern of trace element variation of submarine volcanic rocks is consistent with those of basalts from oceanic plateaus which are the modern equivalent of the Archean greenstones belts. The Nd and Sr isotopic systematics typical of juvenile material indicates that the source of these igneous rocks is derived from a depleted mantle source. These results are consistent with the idea of a major accretion within the West African Craton occurring at about 2.1 Ga and corresponding to an important process of mantle–oceanic lithosphere differentiation.     

Geochemistry of late Paleozoic mafic igneous rocks from the Kuerti area,Xinjiang, northwest China: implications for backarc mantle evolution

The composition of Kuerti mafic rocks in the Altay Mountains in northwest China ranges from highly geochemically depleted, with very low La, Ta and Nb and high ε_Nd(t) values, to slightly enriched, arc lava-like composition. They display flat to light rare earth element (REE)-depleted patterns and have variable depletions in high field-strength elements (HFSE). These mafic rocks were most probably derived from a variably depleted mantle source containing a subduction component beneath an ancient intra-oceanic backarc basin. Together with the slightly older arc volcanic rocks in the Altay region, the Kuerti mafic rocks display generally positive correlations of their key elemental ratios (e.g., Th/Nb, La/Yb and Th/Yb). These indicate that the more mid-ocean ridge basalt (MORB) component was contained in these magmas, the less arc component was present in their mantle source. Therefore, we propose a two-stage melting evolution model to interpret the compositional evolution of the Kuerti mafic rocks and associated arc volcanic rocks. First, arc basaltic melts were extracted from the hydrated arc mantle wedge beneath Kuerti, leaving behind a mantle source that is variably depleted in incompatible trace elements. Then, mafic rocks were erupted during seafloor spreading in the Kuerti backarc basin from the upwelling asthenospheric mantle. The variably depleted mantle source produced mafic rocks with composition ranging from arc lava-like to more geochemically depleted than MORB. The recognition of Kuerti mafic rocks as backarc basin basalts (BABB) is consistent with the proposed tectonic model that an active backarc basin–island arc system along the paleo-Asian ocean margin was formed in the Altay region during Devonian–Early Carboniferous. New data further indicate that the final orogenic event in the Altay Mountains, i.e. the collision of the north and south continental plates in the region, most probably took place in Late Carboniferous and Permian.     

Rare earth element geochemistry of Archean metasedimentary rocks from Kambalda,Western Australia

Archean sedimentary rocks of very limited lateral extent from horizons within basaltic and ultramafic volcanic sequences at Kambalda, Western Australia, are extremely variable in major elements, LIL and ferromagnesian trace element compositions. The REE patterns are uniform and do not have negative Eu anomalies. Two samples have very low total REE abundances and positive Eu anomalies attributed to a very much greater proportion of chemically deposited siliceous material. Apart from these two samples, the Kambalda data are similar to REE abundances and patterns from Archean sedimentary rocks from Kalgoorlie, Western Australia and to average Archean sedimentary rock REE patterns. These show a fundamental distinction from post-Archean sedimentary rock REE patterns which have higher $\text{La}\text{Yb}$ ratios and a distinct negative Eu anomaly.     

Constraints on the Trace Element Composition of the Archean Mantle Root beneath Somerset Island, Arctic Canada

Peridotites that sample Archean mantle roots are frequentlyincompatible trace element enriched despite their refractorymajor element compositions. To constrain the trace element budgetof the lithosphere beneath the Canadian craton, trace elementand rare earth element (REE) abundances were determined fora suite of garnet peridotites and garnet pyroxenites from theNikos kimberlite pipe on Somerset Island, Canadian Arctic, theirconstituent garnet and clinopyroxene, and the host kimberlite.These refractory mantle xenoliths are depleted in fusible majorelements, but enriched in incompatible trace elements, suchas large ion lithophile elements (LILE), Th, U and light rareearth elements (LREE). Mass balance calculations based on modalabundances of clinopyroxene and garnet and their respectiveREE contents yield discrepancies between calculated and analyzedREE contents for the Nikos bulk rocks that amount to LREE deficienciesof 70–99%, suggesting the presence of small amounts ofinterstitial kimberlite liquid (0·4–2 wt %) toaccount for the excess LREE abundances. These results indicatethat the peridotites had in fact depleted or flat LREE patternsbefore contamination by their host kimberlite. LREE and Sr enrichmentin clinopyroxene and low Zr and Sr abundances in garnet in low-temperatureperidotites (800–1100°C) compared with high-temperatureperidotites (1200–1400°C) suggest that the shallowlithosphere is geochemically distinct from the deep lithospherebeneath the northern margin of the Canadian craton. The Somersetmantle root appears to be characterized by a depth zonationthat may date from the time of its stabilization in the Archean. KEY WORDS: Canada; mantle; metasomatism; peridotite; trace elements     

宽甸火山群地质遗迹的地质特征与特殊性

宽甸地处营口-宽甸古隆起东部北缘,在距今0.12~8 Ma间,火山多次喷发留下了特殊的火山群地质遗迹.宽甸火山群的多期喷发,产生多种岩石组成的火山岩,火山岩中含有大量上地幔橄榄岩包体与丰富的巨晶矿物以及特殊的火山群地质地貌具有追溯地质历史的重大科学研究价值和观赏价值.     

Geochemical evidence concerning sources and petrologic evolution of Faial Island,Central Azores

Volcanic rocks that make up Faial Island, Central Azores, consist of four volcano-stratigraphic units, with ages between 730 ka and the present. Lavas range from alkali basalts to trachyandesites and belong to the alkaline-sodic series. The oldest unit is the Ribeirinha Volcanic Complex, generally characterized by low MgO contents. The Cedros Volcanic Complex is composed of basalts to benmoreites with low MgO contents. The Almoxarife Formation represents fissure flows, containing MgO contents similar to to slightly higher than those of the underlying Cedros Volcanic Complex. The youngest unit, the Capelo Formation, consists of mafic rocks with MgO values higher than those of the other units. Bulk-rock major and trace element trends suggest that differentiation of the three earliest units were dominated by fractional crystallization of plagioclase ± clinopyroxene ± olivine ± titanomagnetite. Capelo bulk-rock compositions are the most primitive, and are related to a period when volcanic activity was fed by deep magmatic chambers, and melts ascended more rapidly. Comparison among geochemical patterns of the trace elements suggests a strong similarity between the lavas from Faial and Pico islands. Corvo Island volcanism contrasts with the geochemistry of Faial and Pico lavas, reflecting its strong K and Rb depletion, and Th, U, Ta, Nb, La, and Ce enrichment. Absence of the Daly gap in the Faial volcanics is attributed to early crystallization of Ti-Fe oxides. The probable source of the Faial magma coincides with the MORB-FOZO array, which implies the presence of ancient recycled oceanic crust in the mantle source. Ratios of incompatible trace elements suggest the similarity of Corvo volcanic rocks with magmas derived from HIMU sources, whereas the Faial and Pico volcanic rocks could have been produced from sources very close to EMII-type OIB.