美国西尔斯盐湖钙华研究综述

钙华具有重要的科研价值.美国加利福尼亚州西尔斯湖内北部、中部和西南部广泛发育钙华丘,丘状体的高度从几厘米至45 m不等,通常高度为5～12 m.钙华丘内存在4种沉积相,分别为多孔海绵状钙华沉积相、结壳状钙华沉积相、柱状钙华沉积相和薄层结壳状钙华沉积相.从时空分布来讲,钙华呈两种沉积层序,分别为多孔海绵状钙华沉积相-结壳...     

Origin and evolution of tufa mounds related to artesian karstic springs in Isona area (Pyrenees,NE Spain)

This work analyses a suite of relict tufa mounds generated by artesian karstic springs in Isona area (Spanish Pyrenees). Geological and geophysical data (seismics and vertical electrical resistivity soundings) indicate that the location of the discharge area in which the spring mounds formed was controlled by (1) a bulge in the axial zone of the anticline that affects the Areny-Montsec aquifer, with the consequent thinning of the overlying confining unit and (2) N-S and E-W trending extensional faults. These uncommon meteogene mounds occur in two stepped morphostratigraphic units that constitute the caprock of a mesa 9 km2 in area. The upper tufa complex is 47 m thick and has yielded several U/Th dates of >350 ka. The obtained U/Th ages for the mounds of lower tufa complex, 10 m thick, range from >350 to 214 ± 11 ka. The sedimentological analysis of the scarce exposures and electrical resistivity profiles show the same morphological and depositional components as those described in geothermal springs: (1) Cylindrical vents; (2) Pools fed by the vents and dammed by annular tufa barriers; (3) Tufa barriers (rimstones) constructed by overflowing waters through vertical accretion and progradation. These rimstones may have overhanging upflow sides. (4) Slope tufa facies with terracettes and microgours.     

Petrographic and trace element analysis of uranium-rich tufa calcite, middle Miocene Barstow Formation, California, USA

An integrated petrographic and spectroscopic (X‐ray diffraction, phosphor imaging and synchrotron X‐ray absorption spectroscopy) study of tufas from the Miocene Barstow Formation, California, relates sample morphology, mineralogy and geochemical composition. The tufas, composed mainly of calcite that formed at the interface between an ancient alkaline lake and ground or spring waters, have textures similar to those of microbially mediated terrestrial stromatolites and travertines. The tufas have elevated concentrations of a number of trace elements including Mn, Fe, Sr and U. Synchrotron X‐ray fluorescence analyses show that U concentrations can exceed 500 p.p.m. X‐ray absorption spectroscopy indicates that the U in these samples is incorporated as U(IV). It is suggested here that alkaline lake waters had a high U/Ca ratio and tufa calcite formed where groundwater or (possibly epithermal) springs brought in Ca and trace elements such as Sr. The rapid, and possibly microbially mediated, precipitation of calcite allowed for incorporation of high concentrations of trace metals as either structural substitutes or extremely fine‐scale inclusions.     

Petrography and textural development of inorganic and biogenic lithotypes in a relict barite tufa deposit at Flybye Springs, NT, Canada

A relict mound of Holocene barite (BaSO₄) tufa underlies the Flybye Springs, a small, barium‐rich, cold sulphur spring system in the Northwest Territories of Canada. The tufa is composed of relatively pure barite with ≤0·34 wt% Ca²⁺ and ≤0·77 wt% Sr²⁺. The mound is made up of coated bubble, raft, undulatory sheet, stromatolitic, coated grain and detrital conglomerate barite tufa. Although previously unreported in barite, these lithotypes are akin to facies found in many carbonate spring deposits. Raft and ooid‐coated grain tufa was formed via ‘inorganic’ barite precipitation in spring water ponds and tributaries where rapid oxidation of sulphide to sulphate established barite supersaturation. Undulatory sheet tufa may have formed by the reaction of dissolved barium with sulphate derived from the oxidation of extracellular polysaccharide‐rich colloidal sulphur films floating in oxygenated, barite‐saturated spring water ponds. Coated bubble, oncoid‐coated grain and stromatolitic tufa with filamentous microfossils was formed in close association with sulphur‐tolerant microbes inhabiting dysoxic and oxygenated spring water tributaries and ponds. Adsorption of dissolved barium to microbial extracellular polysaccharide probably facilitated the development of these ‘biogenic’ lithotypes. Detrital conglomerate tufa was formed by barite cementation of microdetrital tufa, allochthonous lithoclasts and organic detritus, including caribou hair. Biogenic textures, organic artefacts and microfossils in the Flybye barite tufa have survived diagenetic aggradational recrystallization and precipitation of secondary cements, indicating the potential for palaeoecological information to be preserved in barite in the geological record. Similarities between the Flybye barite tufa and carbonate spring deposits demonstrate that analogous textures can develop in chemical sedimentary systems with distinct mineralogy, biology and physiochemistry.     

A direct comparison of 14C and 230Th ages at Searles Lake,California

Thorium-230 dating on saline of the Lower Salt unit in pluvial Searles Lake, California, shows that this unit was formed between 24,500 and 32,000 years ago. The initial apparent ¹⁴C age of the lake is estimated to be about 900 years. After correcting for nonradiogenic ²³⁰Th and for the initial ¹⁴C age, excellent agreement between ²³⁰Th and ¹⁴C ages is obtained. The reliability of ²³⁰Th dating on salt deposit opens a new way for continuation of absolute chronology below the Lower Salt in Searles Lake.     

Sediment characteristics and mineralogy of salt mounds linked to underground spring activity in the Lop Nor playa,Western China

Salt mounds are commonly distributed along playa margins and typically comprise alternating layers of loose fine sand and slightly hard halite-rich sediments as a result of long-term underground spring activity. A model of salt mound development was constructed for this study. It suggests that wind-blown sand supply and upward recharge of underground springs are two important factors in salt mound construction. Furthermore, it proposes that salt mound height is mainly controlled by the vertical transport range of underground springs and the thickness of the capillary fringe. A 1.5 m representative profile dug from the center of salt mound LP1 in the Lop Nor playa revealed a fairly complicated mineral assemblage including halite, gypsum, anhydrite, glauberite, epsomite, anhydrite, calcite, bischofite, polyhalite, schoenite, kieserite and carnallite. This matches closely with the assemblage predicted by the EQL/EVP model. The groundwater in the area is highly concentrated brine rich in Cl⁻ and Na⁺ and poor in Ca²⁺, displaying low alkalinity, and containing considerable amounts of SO₄²⁻, Mg²⁺ and K⁺. Chemical analysis of groundwater revealed considerable variation in the salinity and chemical composition of groundwater over time. The Cs-137 technique was used to measure the accumulated ages of the salt mounds. This method may prove useful in the research of relatively young playa environments where carbon dating techniques are unworkable because of an absence of carbon-rich materials in recent saline sediments.     

Confirmation of an interglacial age for the Condat tufa (Dordogne,France) from biostratigraphic and isotopic data

The Condat tufa is a localised deposit, reaching 8.2m in thickness, composed of freshwater carbonates deposited in a complex series of environments which include marsh, spring and stream facies. Five radiocarbon determinations had previously been obtained from different stratigraphic levels within the tufa and had given a consistent series, ranging from 12320 ± 175 BP to 31050 ± 1500BP. Although the youngest two dates, from near the surface of the tufa, had been rejected as being anomalously young, the older dates were regarded as indicating tufa formation during the last cold stage. Biostratigraphic analyses of the molluscan and ostracod faunas, presented here, demonstrate that the tufa formed under fully temperate conditions throughout. The occurrence of certain snails that are either locally extinct (e.g. Belgrandia marginata) or unknown living in western France (e.g. Daudebardia brevipes), together with the geomorphological setting, suggest that the tufa is of interglacial age. New radiocarbon determinations of the Condat tufa all proved to be >33 Ka BP and support this conclusion.     

The Composite Nature of the Provo Level of Lake Bonneville, Great Basin, Western North America

Deposits of a transgressive-phase Lake Bonneville stillstand or oscillation are found just below the elevation of the regressive-phase Provo shoreline at numerous exposures throughout the Bonneville basin. Existence of these subProvo shoreline deposits provides a new explanation for the massive size of Provo depositional and erosional landforms, which can no longer be explained by a long stillstand at the Provo shoreline. Provo coastal landforms are large because they are superimposed on subProvo landforms. Results also help to clarify divergent interpretations regarding the relative age of the Provo shoreline and the number of times it was occupied by the water plane. Occupation of approximately the same level during both the transgressive and the regressive phase of Lake Bonneville may be coincidental, or it may indicate that a bedrock sill controlled outflow at subProvo as well as Provo time. Rise to the Bonneville level could have occurred after massive slope failure plugged the outlet pass.     

Geochronology and paleoenvironment of pluvial Harper Lake,Mojave Desert,California, USA

Accurate reconstruction of the paleo-Mojave River and pluvial lake (Harper, Manix, Cronese, and Mojave) system of southern California is critical to understanding paleoclimate and the North American polar jet stream position over the last 500 ka. Previous studies inferred a polar jet stream south of 35°N at 18 ka and at ~ 40°N at 17–14 ka. Highstand sediments of Harper Lake, the upstream-most pluvial lake along the Mojave River, have yielded uncalibrated radiocarbon ages ranging from 24,000 to > 30,000 ¹⁴C yr BP. Based on geologic mapping, radiocarbon and optically stimulated luminescence dating, we infer a ~ 45–40 ka age for the Harper Lake highstand sediments. Combining the Harper Lake highstand with other Great Basin pluvial lake/spring and marine climate records, we infer that the North American polar jet stream was south of 35°N about 45–40 ka, but shifted to 40°N by ~ 35 ka. Ostracodes (Limnocythere ceriotuberosa) from Harper Lake highstand sediments are consistent with an alkaline lake environment that received seasonal inflow from the Mojave River, thus confirming the lake was fed by the Mojave River. The ~ 45–40 ka highstand at Harper Lake coincides with a shallowing interval at downstream Lake Manix.     

Molluscan successions from the Holocene tufa of St Germain‐le‐Vasson,Normandy (France) and their biogeographical significance

A detailed molluscan succession from a 10 m thick deposit of Holocene tufa at St Germain‐le‐Vasson, Normandy, provides the most complete record from northern France and has shed new light on the historical biogeography of several species of land snail. The succession has been reconstructed from four profiles and a chronology provided by accelerator mass spectrometry radiocarbon dating of charcoal, wood and shell. The onset of tufa formation occurred after 9700±90 yr BP and persisted until 4213±77 yr BP. The tufa appears to have accumulated at a remarkably constant rate (14.4–16.5 cm 100 yr^?1), except for the upper levels, where the rate increases fourfold. The succession has been divided into six local molluscan zones. An early assemblage consisting of ecologically tolerant species and those indicative of marshy grassland is replaced by a sequence of shade‐demanding taxa, reflecting the encroachment of woodland. Shaded conditions persist until the end of the sequence but the most hygrophilous elements decline after 5422±60 yr BP (zone 5), a change also reflected in the tufa lithology by the development of silty grey horizons. Notable species recovered from the tufa include Acicula fusca, Vertigo substriata, V. alpestris, V. moulinsiana (all rare or unknown living in northern France). Hygromia limbata, a twentieth century introduction to Britain, was previously thought to be a relatively recent arrival in northern France, but its record at St Germain shows that it has been present in Normandy since 6500 yr BP. Azeca goodalli, another shade‐demanding species, appeared at St Germain much later, just after 4420±65 yr BP. Several other species present in the tufa, such as Pomatias elegans, no longer live on the site, adding to the evidence for a distributional decline in Normandy and elsewhere. Perhaps the most noteworthy record is that of Leiostyla anglica, between about 8500 yr BP and 5000 yr BP, because this constitutes its only Holocene occurrence from mainland Europe. Following this discovery it seems likely that further Holocene sites with L. anglica may be found along the western seaboard of Europe connecting populations in Iberia with those of the British Isles. Copyright © 2004 John Wiley & Sons, Ltd.     

Transtensional deformation in the Lake Tahoe region, California and Nevada, USA

Dextral transtensional deformation is occurring along the Sierra Nevada–Great Basin boundary zone (SNGBBZ) at the eastern edge of the Sierra Nevada microplate. In the Lake Tahoe region of the SNGBBZ, transtension is partitioned spatially and temporally into domains of north–south striking normal faults and transitional domains with conjugate strike-slip faults. The normal fault domains, which have had large Holocene earthquakes but account only for background seismicity in the historic period, primarily accommodate east–west extension, while the transitional domains, which have had moderate Holocene and historic earthquakes and are currently seismically active, primarily record north–south shortening. Through partitioned slip, the upper crust in this region undergoes overall constrictional strain.Major fault zones within the Lake Tahoe basin include two normal fault zones: the northwest-trending Tahoe–Sierra frontal fault zone (TSFFZ) and the north-trending West Tahoe–Dollar Point fault zone. Most faults in these zones show eastside down displacements. Both of these fault zones show evidence of Holocene earthquakes but are relatively quiet seismically through the historic record. The northeast-trending North Tahoe–Incline Village fault zone is a major normal to sinistral-oblique fault zone. This fault zone shows evidence for large Holocene earthquakes and based on the historic record is seismically active at the microearthquake level. The zone forms the boundary between the Lake Tahoe normal fault domain to the south and the Truckee transition zone to the north.Several lines of evidence, including both geology and historic seismicity, indicate that the seismically active Truckee and Gardnerville transition zones, north and southeast of Lake Tahoe basin, respectively, are undergoing north–south shortening. In addition, the central Carson Range, a major north-trending range block between two large normal fault zones, shows internal fault patterns that suggest the range is undergoing north–south shortening in addition to east–west extension.A model capable of explaining the spatial and temporal partitioning of slip suggests that seismic behavior in the region alternates between two modes, one mode characterized by an east–west minimum principal stress and a north–south maximum principal stress as at present. In this mode, seismicity and small-scale faulting reflecting north–south shortening concentrate in mechanically weak transition zones with primarily strike-slip faulting in relatively small-magnitude events, and domains with major normal faults are relatively quiet. A second mode occurs after sufficient north–south shortening reduces the north–south S_hmax in magnitude until it is less than S_v, at which point S_v becomes the maximum principal stress. This second mode is then characterized by large earthquakes on major normal faults in the large normal fault domains, which dominate the overall moment release in the region, producing significant east–west extension.     

Freshwater control of ice-rafted debris in the last glacial period at Mono Lake, California, USA

The type section silts of the late Pleistocene Wilson Creek Formation at Mono Lake contain outsized clasts, dominantly well-rounded pebbles and cobbles of Sierran lithologies. Lithic grains > 425 μm show a similar pattern of variability as the > 10 mm clasts visible in the type section, with decreasing absolute abundance in southern and eastern outcrops. The largest concentrations of ice-rafted debris (IRD) occur at 67–57 ka and 46–32 ka, with strong millennial-scale variability, while little IRD is found during the last glacial maximum and deglaciation.Stratigraphic evidence for high lake level during high IRD intervals, and a lack of geomorphic evidence for coincidence of lake and glaciers, strongly suggests that rafting was by shore ice rather than icebergs. Correspondence of carbonate flux and IRD implies that both were mainly controlled by freshwater input, rather than disparate non-climatic controls. Conversely, the lack of IRD during the last glacial maximum and deglacial highstands may relate to secondary controls such as perennial ice cover or sediment supply. High IRD at Mono Lake corresponds to low glacial flour flux in Owens Lake, both correlative to high warm-season insolation. High-resolution, extra-basinal correlation of the millennial peaks awaits greatly improved age models for both records.     

Shoreline tufa and tufaglomerate from Pleistocene Lake Bonneville,Utah, USA: stable isotopic and mineralogical records of lake conditions,processes, and climate

Shoreline carbonate deposits of Pleistocene Lake Bonneville record the conditions and processes within the lake, including the evaporative balance as well as vertical and lateral chemical and isotopic gradients. Tufas (swash‐zone) and tufaglomerates (cemented, subaqueous colluvium or beachrock) on multiple, well‐developed shorelines near the Silver Island Range, Utah, also present an opportunity to examine physicochemical lake processes through time. Three shorelines are represented by carbonate deposits, including the 23–20 ka Stansbury stage, 15–14.5 ka Bonneville stage, and 14.5–14 ka Provo stage. Mean δ¹⁸O_VSMOW values of all three shorelines are statistically indistinguishable ( ～ 27 ± 1‰), when a few Bonneville samples of unusual composition are neglected. However, differences in primary carbonate mineralogy indicate that the correspondence is an artefact of the different fractionation factors between calcite or aragonite and water. Second, in order to sustain a much smaller, shallower lake during the colder Stansbury stage, the climate must have also been relatively dry. Third, δ¹⁸O values in tufa are higher than tufaglomerate by ～ 0.5‰, consistent with greater evaporative enrichment of lake water in the swash zone. Fourth, mean δ¹³C values for the Provo, Stansbury and Bonneville shorelines (4.4, 5.0 and 5.2‰, respectively) show that carbon species were dominated by atmospheric exchange, with the variations produced by differences in the oxidation of organic matter. Comparisons of shoreline carbonates with deep‐lake marls of the same approximate age indicate that shoreline carbonate was much higher in δ¹³C and δ¹⁸O values (both ～ 2.5‰) during Bonneville time, whereas isotopic differences were minor (both ～ 1‰) in Stansbury time. In particular, the Bonneville stage may have sustained large vertical or lateral isotopic gradients due to evaporative enrichment effects on δ¹⁸O values. In contrast, the lake during the much shallower Stansbury stage may have been well mixed. Differences in the primary mineralogy (Stansbury and Bonneville, aragonite > calcite; Provo, calcite > aragonite) reflect profound differences in lake chemistry in terms of open versus closed‐basin lakes. The establishment of a continuous outlet during Provo time probably reduced the Mg²⁺/Ca²⁺ ratio of lake water. Curiously, regardless of primary mineralogy, tufaglomerate cements are enriched in Na⁺ and Cl^? and depleted in Mg²⁺ relative to capping tufa of the same age. This probably reflects vital or kinetic effects in the swash zone (tufa). We suspect that ‘abiotic’ effects may have been important in the dark pore space of developing tufaglomerate, where the absence of light suppressed photosynthesis. Copyright © 2005 John Wiley & Sons, Ltd.     

Evidence for 17th-century tsunamis generated on the Kuril–Kamchatka subduction zone, Lake Tokotan, Hokkaido, Japan

In the seventeenth century, two tsunamis that were generated by earthquakes on the Kuril–Kamchatka subduction zone inundated the eastern coast of Hokkaido, northern Japan. Stratigraphic evidence for these two tsunamis and related land-level change in coastal Hokkaido consists of two landward-thinning sand layers in the sediments of Lake Tokotan, a coastal lagoon on the Hokkaido coast. The marine origin of these sand layers is indicated by the presence of brackish–marine diatoms. The rarity and high degree of fragmentation of diatom valves suggests that the sands were transported in a short time over a considerable distance. Tsunamis at this site were probably generated by great earthquakes along the Kuril–Kamchatka Trench. Volcanic ash deposits lying just above the sands suggest that tsunamis occurred in the late 17th century. Tsunamis during the historic period are not recorded in Lake Tokotan, which suggests that the sand layers were deposited by tsunamis substantially larger than historic tsunamis.     

Petrology of Lower Cretaceous carbonate mud mounds (Albian, N. Spain): insights into organomineralic deposits of the geological record

The process of organomineralization is increasingly well understood with respect to modern carbonate sediments accumulating adjacent to tropical reef atolls and reef caves. Mineralization related to non-living organic substrates results in autochthonous micrite production (‘automicrites’). ‘Automicrites’ are the main constructive element of Lower Cretaceous (Albian) carbonate mud mounds in northern Spain. These slope mud mounds occur within transgressive and early highstand system tracts encompassing several macrobenthic ecological zones. They are clearly separated from the biocalcifying carbonate factory (Urgonian carbonate platforms), in both space and time. Within these build-ups, most ‘automicrites’ were initially indurated and accreted to form a medium-relief growth framework. ‘Automicrites’ have a uniform, presumably high-Mg-calcite precursor mineralogy. They show an inorganic stable-isotope signature (?¹³C around +3·3‰) within the range of early marine cements, and skeletal compounds lacking major vital effects. Epifluorescence microscopy shows that they have facies-specific fluorescence, which is similar to skeletal compounds of Acanthochaetetes, but clearly different from allomicritic sediment and cements, which are mostly non-fluorescent. The EDTA-soluble intracrystalline organic fraction (SIOF) of Albian automicrites shows an amino acid spectrum that is similar to shallow subsurface samples from their modern counterparts. Gel electrophoresis of the SIOF demonstrates an exclusively acidic character, and a mean molecular size range between 20 and 30 kDa. Experiments in vitro (inhibition tests) indicate that the SIOF has a significant Ca²⁺-binding capacity. Fluorescence and chemical characteristics of SIOF point to a main substance class, such as humic and fulvic acids, compounds that form from pristine organic matter during early diagenesis. Biomarker analyses provide evidence for the crucial role of biodegradation by heterotrophic microorganisms, but no biomarker for cyanobacteria has been found. Primary sources of organic material should have been manifold, including major contributions by metazoans such as sponges. It is concluded that many carbonate mud mounds are essentially organomineralic in origin and that the resulting fabric of polygenetic muds (‘polymuds’) may represent ancestral metazoan reef ecosystems, which possibly originated during the Neoproterozoic.     

A sedimentary facies model for glacial-age sediments in Baldwin Lake, Southern California

A combined sedimentological and high-resolution petrographic analysis was conducted on a glacial-age (20,000–65,000 cal yr BP) sediment core from Baldwin Lake, Southern California. The results of this research represent the most complete glacial-age, terrestrial climate record from Southern California to date. These results are used to characterize the different sediment types and to investigate the difference in depositional processes and environments between the core's three predominant sediment types: massive, semi-laminated, and laminated sediments. Massive sediments are commonly associated with a blocky texture and/or desiccation cracks, are organic-poor, have high magnetic susceptibility values, and are coarser-grained. Thin-sections from massive sediments reveal a homogenous sediment fabric. Sub-centimeter-scale laminated and centimeter-scale semi-laminated sediments are generally organic-rich, have low magnetic susceptibility values, and are finer grained. Thin-sections from laminated and semi-laminated sediments reveal diffuse sub-millimeter- to millimeter-scale laminae. This combination of sedimentological and high-resolution petrographic data enabled us to characterize four sediment facies, each related to specific depositional processes and environments: (1) a playa lake; (2) a perennial shallow lake; (3) an intermediate lake with variable lake level; and, (4) a perennial deep lake. At centennial-to millennial-timescales, lower lake levels are represented by deposition of massive to semi-laminated sediments in a playa to a perennial shallow lake environment. At similar timescales, higher lake levels are recorded by semi-laminated to laminated sediments deposited in an intermediate lake to a perennial deep lake environment. These results provide an additional sedimentological study for comparison to similar arid environment basins, and for comparison to existing regional paleoclimatic reconstructions.     

Vertical Distribution of Bacteria in Doroninskoe Lake(Zabaikalie,Russia):Paradigm of Dominance

正1 Introduction Prokaryotes are key organisms in aquatic ecosystems as they play animportant role in the biogeochemical cycling of elements.Investigations on the relationships betweenthe diversity of microbial community and environmentalfactors offer useful information that bothleads to understanding of the process of element     

Formation of the Campbell-Red Lake gold deposit by H2O-poor, CO2-dominated fluids

The Campbell-Red Lake gold deposit in the Red Lake greenstone belt, with a total of approximately 840 t of gold (past production + reserves) and an average grade of 21 g/t Au, is one of the largest and richest Archean gold deposits in Canada. Gold mineralization is mainly associated with silicification and arsenopyrite that replace carbonate veins, breccias and wallrock selvages. The carbonate veins and breccias, which are composed of ankerite ± quartz and characterized by crustiform–cockade textures, were formed before and/or in the early stage of penetrative ductile deformation, whereas silicification, arsenopyrite replacement and gold mineralization were coeval with deformation. Microthermometry and laser Raman spectroscopy indicate that fluid inclusions in ankerite and associated quartz (Q1) and main ore-stage quartz (Q2) are predominantly carbonic, composed mainly of CO₂, with minor CH₄ and N₂. Aqueous and aqueous–carbonic inclusions are extremely rare in both ankerite and quartz. H₂O was not detected by laser Raman spectroscopic analyses of individual carbonic inclusions and by gas chromatographic analyses of bulk samples of ankerite and main ore-stage quartz (Q2). Fluid inclusions in post-mineralization quartz (Q3) are also mainly carbonic, but proportions of aqueous and aqueous–carbonic inclusions are present. Trace amounts of H₂S were detected by laser Raman spectroscopy in some carbonic inclusions in Q2 and Q3, and by gas chromatographic analyses of bulk samples of ankerite and Q2. ³He/⁴He ratios of bulk fluid inclusions range from 0.008 to 0.016 Ra in samples of arsenopyrite and gold. Homogenization temperatures (T _h–CO₂) of carbonic inclusions are highly variable (from −4.1 to +30.4°C; mostly to liquid, some to vapor), but the spreads within individual fluid inclusion assemblages (FIAs) are relatively small (within 0.5 to 10.3°C). Carbonic inclusions occur both in FIAs with narrow T _h–CO₂ ranges and in those with relatively large T _h–CO₂ variations. The predominance of carbonic fluid inclusions has been previously reported in a few other gold deposits, and its significance for gold metallogeny has been debated. Some authors have proposed that formation of the carbonic fluid inclusions and their predominance is due to post-trapping leakage of water from aqueous–carbonic inclusions (H₂O leakage model), whereas others have proposed that they reflect preferential trapping of the CO₂-dominated vapor in an immiscible aqueous–carbonic mixture (fluid unmixing model), or represent an unusually H₂O-poor, CO₂-dominated fluid (single carbonic fluid model). Based on the FIA analysis reported in this study, we argue that although post-trapping modifications and host mineral deformation may have altered the fluid inclusions in varying degrees, these processes were not solely responsible for the formation of the carbonic inclusions. The single carbonic fluid model best explains the extreme rarity of aqueous inclusions but lacks the support of experimental data that might indicate the viability of significant transport of silica and gold in a carbonic fluid. In contrast, the weakness of the unmixing model is that it lacks unequivocal petrographic evidence of phase separation. If the unmixing model were to be applied, the fluid prior to unmixing would have to be much more enriched in carbonic species and poorer in water than in most orogenic gold deposits in order to explain the predominance of carbonic inclusions. The H₂O-poor, CO₂-dominated fluid may have been the product of high-grade metamorphism or early degassing of magmatic intrusions, or could have resulted from the accumulation of vapor produced by phase separation external to the site of mineralization.Geological Survey of Canada contribution 2004383.     

Calcium and magnesium‐limited dolomite precipitation at Deep Springs Lake,California

Dolomite [Ca,Mg(CO₃)₂] precipitation from supersaturated ionic solutions at Earth surface temperatures is considered kinetically inhibited because of the difficulties experienced in experimentally reproducing such a process. Nevertheless, recent dolomite is observed to form in hypersaline and alkaline environments. Such recent dolomite precipitation is commonly attributed to microbial mediation because dolomite has been demonstrated to form in vitro in microbial cultures. The mechanism of microbially mediated dolomite precipitation is, however, poorly understood and it remains unclear what role microbial mediation plays in natural environments. In the study presented here, simple geochemical methods were used to assess the limitations and controls of dolomite formation in Deep Springs Lake, a highly alkaline playa lake in eastern California showing ongoing dolomite authigenesis. The sediments of Deep Springs Lake consist of unlithified, clay‐fraction dolomite ooze. Based on δ¹⁸O equilibria and textural observations, dolomite precipitates from oxygenated and agitated surface brine. The Na‐SO₄‐dominated brine contains up to 500 mm dissolved inorganic carbon whereas Mg²⁺ and Ca²⁺ concentrations are ca 1 and 0·3 mm , respectively. Precipitation in the subsurface probably is not significant because of the lack of Ca²⁺ (below 0·01 mm ). Under such highly alkaline conditions, the effect of microbial metabolism on supersaturation by pH and alkalinity increase is negligible. A putative microbial effect could, however, support dolomite nucleation or support crystal growth by overcoming a kinetic barrier. An essential limitation on crystal growth rates imposed by the low Ca²⁺ and Mg²⁺ concentrations could favour the thermodynamically more stable carbonate phase (which is dolomite) to precipitate. This mode of unlithified dolomite ooze formation showing δ¹³C values near to equilibrium with atmospheric CO₂ (ca 3‰) contrasts the formation of isotopically light (organically derived), hard‐lithified dolomite layers in the subsurface of some less alkaline environments. Inferred physicochemical controls on dolomite formation under highly alkaline conditions observed in Deep Springs Lake may shed light on conditions that favoured extensive dolomite formation in alkaline Precambrian oceans, as opposed to modern oceans where dolomites only form diagenetically in organic C‐rich sediments.