Oxygen isotope geochemistry of hydrothermally-altered synmetamorphic granitic rocks from South-Central Maine,USA

Hydrothermally-altered mesozonal synmetamorphic granitic rocks from Maine have whole-rock ¹⁸O (SMOW) values 10.7 to 13.8. Constituent quartz, feldspar, and muscovite have ¹⁸O in the range 12.4 to 15.2, 10.0 to 13.2, and 11.1 to 12.0, respectively. Mean values of _Q–F ( ¹⁸O_quartz– ¹⁸O_feldspar)=2.4 and _Q–M ( ¹⁸O_quartz– ¹⁸O_muscovite)=3.3 are remarkably uniform (standard deviations of both are 0.2). Measured _Q–F and _Q–M values demonstrate that the isotopic compositions of the minerals are altered from primary magmatic ¹⁸O values but that the minerals closely approached oxygen isotope exchange equilibrium at subsolidus temperatures. Analyzed muscovites have D (SMOW) values in the range –65 to –82.Feldspars in the granitic rocks are mineralogically altered to either (a) muscovite+calcite, (b) muscovite+calcite+epidote, (c) muscovite+epidote, or (d) muscovite only. A consistent relation exists between the assemblage of secondary minerals and the oxygen isotope composition of whole rocks, quartz, and feldspar. Rocks with assemblage (a) have whole-rock ¹⁸O>12.1 and contain quartz and feldspar with ¹⁸O>13.8 and >11.4, respectively. Rocks with assemblages (b), (c), and (d) have whole-rock ¹⁸O<11.4 and contain quartz and feldspar with ¹⁸O< 13.1 and <11.0, respectively. The correlation suggests that the mineralogical alteration of the rocks was closely coupled to their isotopic alteration.Three mineral thermometers in altered granite suggest that the hydrothermal event occurred in the temperature range 400°–150° C, 100°–150° C below the peak metamorphic temperature inferred for country rocks immediately adjacent to the plutons. Calculations of mineral-fluid equilibria indicate that samples with assemblage (a) coexisted during the event with CO₂-H₂O fluids of and ¹⁸O=10.8 to 12.2 while samples with assemblages (b), (c), or (d) coexisted with fluids of and ¹⁸O=9.4 to 10.1. Compositional variations of the hydrothermal fluids were highly correlated: fluids enriched in CO₂ were also enriched in ¹⁸O. Because CO₂ was added to the granites during hydrothermal alteration and because fluids enriched in CO₂ were enriched in ¹⁸O, some or all of the variation in ¹⁸O of altered granites may have been caused by addition of ¹⁸O to the rocks during the hydrothermal event. The source of both the CO₂ and ¹⁸O could have been high-¹⁸O metasedimentary country rocks. The inferred change in isotopic composition of the granites is consistent with depletion of the metacarbonate rocks in ¹⁸O close to the plutons and with large volumes of fluid that were inferred from petrologic data to have infiltrated the metacarbonate rocks during metamorphism.A close approach of minerals to oxygen isotope exchange equilibrium in altered mesozonal rocks from Maine is in marked contrast to hydrothermally-altered epizonal granites whose mineral commonly show large departures from oxygen isotope exchange equilibrium. The difference in oxygen isotope systematics between altered epizonal granites and altered mesozonal granites closely parallels a differences between their mineralogical systematics. Both differences demonstrate the important control that depth exerts on the products of hydrothermal alteration. Deeper hydrothermal events occur at higher temperature and are longer-lived. Minerals and fluid have sufficient time to closely approach both isotope exchange and heterogeneous chemical equilibrium. Shallower hydrothermal events occur at lower temperatures and are shorter-lived. Generally there is insufficient time for fluid to closely approach equilibrium with all minerals.     

Oxygen isotope map of the giant metamorphic-hydrothermal system around the northern part of the Idaho batholith, U.S.A.

Determinations of δ¹⁸O values from 100 outcrops of Belt Supergroup (Wallace Fm.) metasedimentary rocks in the Idaho panhandle reveal a regular regional pattern that was produced by pervasive fluid infiltration and isotopic exchange. Low grade argillites at large distances (60 km) from the Idaho batholith have high δ¹⁸O values +15, compatible with their probable primary values. Pelitic rocks with anomalously low δ¹⁸O values of + 8.7 to + 12.7‰ occur in the following zones: (1) in a 5000 km² zone of schist and gneiss peripheral to the Idaho batholith, generally coincident with high-grade (sillimanite-bearing) assemblages; (2) in high-grade metasedimentary roof pendants within the Idaho batholith; (3) peripheral to small Cretaceous stocks; and (4) within and near the scapolite-bearing zone south-west of St. Regis. On δ¹⁸O−δ¹⁸O plots, data from coexisting minerals define trends with unit slopes, indicating that the reductions in ¹⁸O occurred under high-grade metamorphic conditions. This metamorphism culminated in the emplacement of the Idaho batholith, probably as a consequence of profound crustal thickening associated with the Cretaceous accretion of the Wallowa-Seven Devils arc terranes with North America. The huge low-¹⁸O region is bounded by a “steep” δ¹⁸O gradient (0.1–0.5‰/km) that occurs in low-grade rocks along and near the Lewis and Clark Line, well below the biotite isograd. This boundary zone may be analogous to, but is not nearly as sharp as, those of meteoric-hydrothermal systems in many regions. The important ore deposits of the Coeur d'Alene district are located in this peripheral zone, suggesting that the metamorphic-hydrothermal system may have been intimately involved in their formation. In addition, the metamorphic-hydrotermal system in Idaho is larger, deeper and higher in temperature than typical meteoric-hydrothermal systems, and it involved fluids with much higher δ¹⁸O values that were probably dominantly derived from formation waters. Accordingly, this system produced rocks with δ¹⁸O values similar to those of the Idaho batholith, and mineral assemblages that approach isotopic equilibrium under high temperature conditions.     

Precambrian tillite rocks of U.S.S.R.

Detailed regional studies and the author' personal observations on tillite-like rocks in Siberia and Ural suggest that pseudo-tillites, only too common in subaqueous landslide formations, were often mistaken for tillites or tillite-like rocks, because of their resemblance to fossil moraines. --V. P. Sokoloff.     

Oxygen isotope study of a Precambrian banded iron-formation,Hamersley Range,Western Australia

Oxygen isotope ratios were determined for quartz, magnetite, ankerite, siderite, riebeckite, hematite and talc in samples of banded iron-formation from the Dales Gorge Member of the Brockman Iron Formation and for quartz, dolomite and calcite in samples of the Wittenoom Dolomite and Duck Creek Dolomite Formations, all from the Hamersley Range area of Western Australia. Additionally, in order to interpret the measured isotope ratios, isotopic fractionations for oxygen between quartz, siderite and magnetite and between these minerals and water as a function of temperature were calculated, using a combination of spectroscopic and thermodynamic data and constraints set by experimental determinations of the fractionations.The Dales Gorge Member was found to have undergone isotopic exchange between minerals at a temperature estimated on the basis of the isotopic fractionations to be above 270°C and probably less than 310°C, during burial metamorphism. At these temperatures quartz and the carbonates were almost completely equilibrated with one another, while hematite apparently underwent negligible exchange. Magnetite may have undergone exchange in some samples but not others, as a result of permeability variations, or it may have been as resistant to exchange as hematite. Riebeckite, and probably talc as well, were also subject to exchange, but to a lesser degree or on a smaller scale than quartz and the carbonates. Hematite formed at temperatures of 140°C or below. Magnetite appears to have formed at temperatures above 140°C, and possibly over a range of temperatures between about 180 and 300°C.The Wittenoom Dolomite and Duck Creek Dolomite samples show apparent lack of equilibrium, due to incomplete exchange or to retrograde effects. A chert from the Wittenoom Dolomite, along with two samples from the Marra Mamba Iron Formation, with δ¹⁸O values of + 24%. can be considered to set a lower limit of about ?11%. on the δ¹⁸O value of the ocean 2.2 × 10⁹ yr ago. Internal fractionations in the Wittenoom Dolomite chert sample may be interpreted as yielding an upper limit on this oceanic δ¹⁸O value of ? 3.5%.     

Rb-Sr ages of the Archean rocks from the Vermilion district,northeastern Minnesota

The Vermilion district of northerneastern Minnesota is a classic example of a lower Precambrian greenstone-granite terrane. It is a complex volcanic-sedimentary pile, characterized by repeated periods of volcanism and the presence of intercalated pyroclastic, volcanoclastic and epiclastic rocks. The volcanic-sedimentary pile is surrounded and intruded by contemporaneous granitic batholiths. Several rock units from the district have been dated by the whole-rock Rb-Sr method. The isochron ages and the corresponding initial Sr⁸⁷/Sr⁸⁶ ratios (= I) are:

     

7.

Geochemistry of granitic rocks from the Hercynian Sardinia-Corsica batholith: Implication for magma genesis   总被引：5，自引：0，他引：5  

Giampiero Poli  Claudio Ghezzo  Sandro Conticelli 《Lithos》1989,23(4):247-266

The Sardinia-Corsica batholith was structured in the late stage of the Hercynian orogenesis. The granitoids intrude mainly metamorphic complexes grading from zeolite up to amphibolite facies. The batholith is heterogeneous consisting of complexes with different affinity, chemical composition, age and degree of deformation. The present paper reports major-and trace-element data for selected samples coming only from Sardinian outcrops.

The rocks range from gabbro-diorite to tonalite, monzogranite and leucogranite. The two latter lithologies are the most abundant, gabbrodiorites and tonalites occurring in minor amounts and mainly in northern-central Sardinia. Over 75% of the granitoids contain microgranular enclaves of magmatic origin. The age of the rocks falls in the interval between 307 and 281 Ma. Sr isotope initial ratios are high, ranging between 0.7083 and 0.7107.

REE, Rb, Sr, Ba, Zr, Th, Ta, Hf, Co and Sc abundances were determined on selected samples. All elements follow three types of trends vs. CaO, which is used as differentiation index. Two trends show positive and negative correlations while the third one shows a bell-shaped pattern. LREE have different degrees of enrichment (La = 20−120× ch) and HREE show variable fractionation with prevailing (Tb/Yb)_n<1. The two peraluminous samples have very different geochemical characteristics.

From the geochemical point of view all the rocks coming from the Sardinian segment of the batholith display a typical calc-alkaline chemical character showing the imprint of both “normal and mature” continental arc geodynamic environments.

Geochemical trends suggest some petrogenetic constraints. The complete sequence of differentiation can be neither the product of crystal/liquid fractionation processes starting from a single basic parent magma nor the product of an AFC process. On the contrary, a two-stage model can be proposed. In the first stage a mafic melt of subcrustal origin interacted with monzogranitic magmas derived from 25–35% degree of melting of a crustal biotite amphibolitic source. Such a mixing process acted together with a crystal/liquid fractionation process to give tonalites and granodiorites. In the second stage lesser degrees of melting of the same crustal source could give the late-stage leucogranitic masses.

A possible scenario, able to take into account field and geochemical data, can be suggested for the genesis of this suite and we propose it as a working model for future investigations.     

8.

Oxygen isotope study of metamorphic and granitic rocks of the Yanai district in the Ryoke belt,Japan     

Hiroji Honma  Hitoshi Sakai 《Contributions to Mineralogy and Petrology》1975,52(2):107-120

¹⁸O/¹⁶O ratios have been obtained for 134 whole-rocks and minerals from metamorphic and granitic rocks of the Yanai district in the Ryoke belt, Southwest Japan. The ¹⁸O/¹⁶O ratios of pelitic rocks of the marginal metamorphic zone decrease progressively with increasing metamorphic grade. In the gneiss-granite complex (zone of migmatite [1]), the most characteristic feature of the rocks is that oxygen isotopic homogenization proceeds on both local and regional scales in parallel with “granitization” or chemical homogenization. Granitic rocks of various origin are fairly uniform in isotopic composition with δ ¹⁸O of quartz of 12 to 14‰ (SMOW) and δ ¹⁸O of biotite of 7 to 9‰ and are about 3 to 4‰ enriched in ¹⁸O compared to other Cretaceous granites of non-metamorphic terranes in Japan. The high ¹⁸O/¹⁶O ratios of granitic rocks of this district were discussed in relation to the ¹⁸O-depletion in metasediments. Oxygen isotopic fractionations among coexisting minerals from various rock-types of the gneiss-granite complex indicate that these minerals were formed under near isotopic equilibrium at a temperature of about 600 to 700° C. Some abnormal fractionations of quartz-biotite pairs also were obtained for rocks which had undergone a progressive ¹⁸O-depletion or ¹⁸O-enrichment. This is due to high resistivity of quartz and contrastive susceptibility of biotite to isotopic exchange during metamorphism and “granitization”.     

9.

Oxygen isotope fractionation and disequilibrium displayed by some granulite facies rocks from the Fraser Range,Western Australia     

Allan F. Wilson  Ajoy K. Baksi 《Geochimica et cosmochimica acta》1984,48(3):423-432

The granulites of the Fraser Range are assumed to have formed in a carbon-rich fluid, and are generally devoid of hornblende, and lack obvious hydrous retrograde features. In these granulites, pyroxene, garnet, plagioclase and quartz are the minerals most likely to retain the oxygen isotope ratios fixed at an early stage of initial granulite metamorphism. Temperature estimates using these minerals commonly suggest that oxygen isotopic exchange ceased in the range 600 to 680°C. The peak metamorphic temperature was probably ～ 850°C as based on the stability fields of the coexisting minerals and some cation temperatures from coexisting pyroxenes in these rocks. Ilmenite may be slightly out of isotopic equilibrium with the other minerals. Thus, grains of quartz, feldspar, pyroxene and ilmenite have suffered considerable oxygen isotopic exchange during the retrogressive phase of the metamorphism, in spite of the fact that very little water was present in these granulites. The observed deviation from the peak metamorphic temperatures can be explained by essentially closed system solid-state diffusion (on at least a scale of centimetres) during slow cooling of the rocks from ~850 to 650°C, followed by more rapid cooling down to ～ 300°C. Such an explanation is not at variance with the radiometric data available for rocks from the area, which suggest that the latter phase could have involved uplift rates of ?0.5 mm/yr for a period of about 40 Ma. Wholerock δ¹⁸O values on non-quartzose mafic granulites, about 7.2%., fall within the range of basalts affected by seafloor weathering.     

10.

华北地台前寒武花岗岩类、陆壳演化与克拉通形成   总被引：18，自引：12，他引：18  

② 《岩石学报》1999,15(2):1

通过华北前寒武纪花岗岩类的研究,提出英云闪长岩和奥长花岗岩（Ｔ１Ｔ２）代表不成熟陆壳组成,Ｔ１Ｔ２Ｇ１Ｇ２代表半成熟陆壳组成,花岗闪长岩和花岗岩（Ｇ１Ｇ２）代表成熟陆壳组成。讨论了大陆根的形成与性质。识别出华北地台内１０个太古陆核。讨论了中太古代初始陆核、新太古代陆核;新太古代末两个微大陆尺度的陆核的形成;早元古代两个成熟陆核的构造拼合并形成华北克拉通     

11.

Composition of the Precambrian Llano Uplift,central Texas,U.S.A.     

Linda A. Johnson  John J.W. Rogers  Richard M. Nagy 《Geochimica et cosmochimica acta》1976,40(11):1419-1420

The Llano uplift exposes rocks of approximately 1000 m.y. age. The weighted average composition of the exposed crust is: 70.7% SiO₂; 0.35% TiO₂; 13.6% A1₂O₃; 3.4% total Fe as Fe₂O₃; 1.1% MgO; 2.6% CaO; 3.3% Na₂O; and 4.4% K₂O. This composition is similar to, but more potassic, than equivalent estimates for the Canadian shield.     

12.

Oxygen isotope studies of potassic volcanic rocks of the Roman Province,Central Italy   总被引：2，自引：0，他引：2  

Bruno Turi  Hugh P. Taylor Jr. 《Contributions to Mineralogy and Petrology》1976,55(1):1-31

The ¹⁸O/¹⁶O ratios of rocks and coexisting minerals were measured for 93 samples of leucite-bearing lavas, pyroclastics, and related volcanic rocks from the Quaternary Roman Co-Magmatic Province, Italy. The ¹⁸O values were found to generally increase northward in the sequence: Ischia (5.8 to 7.0); Somma-Vesuvius and Phlegrean Fields (7.3 to 8.3); Alban Hills (7.3 to 8.7); M. Sabatini (7.3 to 9.7); Vico Volcano (7.4 to 10.2); and M. Vulsini (8.1 to 11.7). The northward increase in ¹⁸O parallels a similar increase in ⁸⁷Sr/⁸⁶Sr, and these data indicate that the Roman magmas have interacted strongly with high-¹⁸O continental crust. A marked increase in ¹⁸O occurs just north of Rome where the Roman Province begins to overlap the calc-alkaline, oversaturated Tuscan Magmatic Province. Therefore, some of the observed ¹⁸O/¹⁶O and ⁸⁷Sr/⁸⁶Sr enrichments in the Roman magmas may have been facilitated by direct mixing with the high-¹⁸O Tuscan magmas or because the high-¹⁸O country rocks underwent widespread heating during a couple of million years of Tuscan igneous activity. Although many of the Roman magmas underwent fractional crystallization without appreciable change in ¹⁸O, contamination has produced a correlation between ¹⁸O and SiO₂ content at several of the volcanic centers; thus the trachytes are typically higher in ¹⁸O than the undersaturated rocks. The major features of the oxygen isotope data can be explained in terms of a simple two-component mixing model in which one end-member was a primary, strongly undersaturated magma derived from the upper mantle, with ¹⁸O+6, ⁸⁷Sr/⁸⁶Sr0.704 to 0.705, and SiO₂<44wt.%. However, none of the analyzed samples have these values, as they have all been contaminated to some extent. The closest approach is found in some of the leucitepyroxenite ejecta from the Alban Hills. The second end-member, derived from the continental crust, had a variable composition with ¹⁸O+12 to +20, ⁸⁷Sr/⁸⁶Sr0.712 to 0.720, and SiO₂65wt.%, and it mixed in much greater proportions in the volcanoes north of Rome than in those of the Alban Hills or the Naples area. The widespread interactions between the Roman magmas and the continental crust are probably due to (1) the fact that such low-SiO₂ magmas always have a very strong tendency to interact with quartz-bearing rocks of the continental crust, and (2) in Italy, these magmas were emplaced into a tectonically very active area containing poorly consolidated sedimentary rocks, and in the northern part of the belt there had been a prior history of extensive calc-alkaline igneous activity.Publication of the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, Contribution Number 2501.     

13.

Oxygen and carbon isotope analysis of the Mooreville Chalk and late Santonian-early Campanian sea level and sea surface temperature changes, northeastern Gulf of Mexico, U.S.A.     

Kaiyu Liu   《Cretaceous Research》2009,30(4):980-990

Oxygen and carbon isotope profiles for strata of the Mooreville Chalk (upper Santonian-lower Campanian) of the eastern Gulf Coastal Plain, U.S.A., show correlations with published curves for these isotopes. The δ¹⁸O curve exhibits a strong similarity to the Exmouth Plateau δ¹⁸O curve from ODP drilling sites offshore northwestern Australia, and the δ¹³C curve can be correlated with the δ¹³C curve from the English Chalk Trunch section.A thermal maximum probably occurred in the northeastern Gulf of Mexico during the latest Santonian (83.8 Ma), as evidenced by the minimum δ¹⁸O values in the lower Mooreville beds. A δ¹³C positive excursion occurs at the same stratigraphic level, which has been recognized as the “Santonian/Campanian boundary event” worldwide. After this event, ocean surface water temperature decreased throughout the early Campanian. This carbon isotope excursion is followed by a plateau in δ¹³C values with a peak value occurring in a condensed section (80 Ma), which has been correlated to a downlap or maximum flooding surface on seismic data from offshore Alabama. The section characterized by increasing δ¹³C values corresponds to a marine transgression. The interval characterized by decreasing δ¹³C values corresponds to regression and progradation. The maximum flooding event occurred 0.8 Ma later than the thermal maximum event.The Mooreville chalk/marl cycles are most likely a product of fluctuations in siliciclastic sediment influx into the northeastern Gulf of Mexico modulated by the precession band of the Earth's orbital cycles. Higher carbon isotope values occur in the marl beds indicating that these beds were formed in a more anoxic/dysoxic environment characterized by higher clay, silt input and higher organic carbon accumulation.     

14.

Pollen evidence of vegetational change following early European settlement of Monhegan Island, Maine, northeastern U.S.A.     

MIRJAMI TOLONEN 《Boreas: An International Journal of Quaternary Research》1983,12(3):201-215

Postsettlemcnt vegetation changes beginning in the early 17th century were studied through comparing stratigraphic peat-pollen data with available historical evidence. The isolation of the site and the relatively long historical record were ideal for the study. Human disturbance of the vegetation was readily identified in the pollen diagram with a contemporaneous increase in sediment mineral matter. The effects were much the same as the changes associated with Neolithic forest clearance in Northern Europe. Settlement resulted in the introduction and expansion of several cultural weeds after grazing and cultivation of Zea mays began on the island in the first decades of the 17th century; Rumex acetosa-acetosella, Ranunculus acris type, Plantago major-media and several new Compositae and Umbelliferae species all appeared at that time. The response of the native species to settlement was varied. Because of the limitations of the palynologic method, the area of cultivated land and detailed kind of agriculture can only be estimated. The data suggest that although agriculture was intensive from time to time, it took place on a very limited local scale; fires, grazing, and lumbering were the major factors affecting natural ecosystems.     

15.

Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying Holocene climate change in the Rocky Mountain region, U.S.A.     

Derek J. Sjostrom  Michael T. Hren 《Quaternary Research》2004,61(1):64-71

Oxygen isotopes of goethite from ferricrete deposits were measured from both northern and southern Rocky Mountain localities to assess geographic variability in regional Holocene paleoclimate change. A ∼3.7‰ increase in oxygen isotope values of ¹⁴C-dated goethites in the northern Rocky Mountains suggests a regional-scale relative increase in amounts of isotopically heavy summer precipitation since the early Holocene. In contrast, oxygen isotope values from the southern Rocky Mountains increase abruptly ∼2.1‰ at ∼6200 ¹⁴C yr B.P., then decrease ∼2.4‰ between ∼2000 ¹⁴C yr B.P. and the present. We interpret this period of relatively high δ¹⁸O values as evidence for a middle Holocene warm period combined with a relatively strong summer monsoon. These variable climate records suggest that the Rocky Mountains of the western United States have had a spatially heterogeneous Holocene climate history.     

16.

Geochemistry of Precambrian mafic dikes,central Bighorn Mountains,Wyoming, U.S.A.     

Theodore J. Armbrustmacher 《Precambrian Research》1977,4(1):13-38

Precambrian quartz dolerites and metadolerites of the central Bighorn Mountains form dikes that intrude a Precambrian metamorphic and igneous terrane typical of the Laramide uplifts of the middle Rocky Mountains. They have a restricted range of major- and trace-element compositions and are typical of basalts in the middle stages of tholeiitic fractionation. Fractionation in the direction of iron enrichment occurred by removal of plagioclase. Average element concentrations of the two groups are nearly identical to one another, are comparable to those in Archean metabasalts from numerous shield areas, and are intermediate between those of modern oceanic tholeiites and continental tholeiites. These average concentrations suggest a depth of magma generation and thickness of crust intermediate between those for the oceanic and continental environments.     

17.

Carbon isotope geochemistry of graphite vein deposits from New Hampshire,U.S.A.     

《Geochimica et cosmochimica acta》1986,50(6):1239-1247

     

18.

Zircon Hf isotope perspective on the origin of granitic rocks from eastern Bavaria, SW Bohemian Massif     

Wolfgang Siebel  Fukun Chen 《International Journal of Earth Sciences》2010,99(5):993-1005

The petrogenetic potential of in situ laser ablation Hf isotope data from melt precipitated zircons was explored through the analyses of about 700 individual crystals derived from about 20 different granitic intrusions covering the Variscan basement segment of eastern Bavaria, SE Germany. In combination with geochemical features, four major suites of granitic rocks can be distinguished: (1) NE Bavarian redwitzites (52–57 wt% SiO₂, intrusion ages around 323 Ma) have chondritic εHf(t) values (+0.8 to –0.4). The redwitzites are hybrid rocks and the Hf data are permissive of mixing of a mantle progenitor and crustal melts. (2) Various intermediate rock types (dioritic dyke, granodiorite, palite, 59–63 wt% SiO₂, 334–320 Ma) from the Bavarian Forest yield negative εHf(t) values between –3.4 and –5.1. These values which apparently contradict a mantle contribution fingerprint an enriched (metasomatized) mantle component that was mixed with crustal material. (3) Voluminous, major crust forming granites sensu stricto (67–75 wt% SiO₂, 328–298 Ma) are characterized by a range in εHf(t) values from –0.5 to –5.6. Different crustal sources and/or modification of crustal melts by various input of juvenile material can explain this variation. (4) Post-plutonic (c. 299 Ma) porphyritic dykes of dacitic composition (64–67 wt% SiO₂) from the southern Bavarian Forest have chondritic εHf(t) values (+0.6 to –1.1) and display large intergrain Hf isotope variation. The dykes form a separate petrogenetic group and the Hf data suggest that the zircons crystallized when a pristine mantle-derived parental melt was modified by infiltration of crustal material. The zircon Hf data form a largely coherent positive array with the whole-rock Nd data and both systems yield similar two-stage depleted mantle model ages (1.1–1.7 Ga).     

19.

Classification and description of dolomitic fabrics of rocks from the Floridan aquifer,U.S.A.     

Anthony F. Randazzo  Louis G. Zachos 《Sedimentary Geology》1984,37(3):151-162

     

20.

The Northeast Kingdom batholith,Vermont: magmatic evolution and geochemical constraints on the origin of Acadian granitic rocks     

Robert A. Ayuso  Joseph G. Arth 《Contributions to Mineralogy and Petrology》1992,111(1):1-23

Five Devonian plutons (West Charleston, Echo Pond, Nulhegan, Derby, and Willoughby) that constitute the Northeast Kingdom batholith in Vermont show wide ranges in elemental abundances and ratios consistent with major crustal contributions during their evolution. The batholith consists of metaluminous quartz gabbro, diorite and quartz monzodiorite, peraluminous granodiorite and granite, and strongly peraluminous leucogranite. Contents of major elements vary systematically with increasingSiO<₂ (48 to 77 wt.%). The batholith has calc-alkaline features, for example a Peacock index of 57, and values for K<₂O/Na₂O (<1), K/Rb (60–350), Zr/Hf (30–50), Nb/Ta (2–22), Hf/Ta (up to 10), and Rb/Zr (<2) in the range of plutonic rocks found in continental magmatic ares. Wide diversity and high values of minor- and trace-element ratios, including Th/Ta (0.5–22), Th/Yb (0–27), Ba/La (0–80), etc., are attributed to intracrustal contributions. Chondrite-normalized REE patterns of metaluminous and relatively mafic intrusives have slightly negative slopes (La/Yb_cn<10) and negative Eu anomalies are small orabsent. The metaluminous to peraluminous inter-mediate plutons are relatively enriched in the light REE (La/Yb_cn>40) and have small negative Eu anomalies. The strongly peraluminous Willoughby leucogranite has unique trace-element abundances and ratios relative to the rest of the batholith, including low contents of Hf, Zr, Sr, and Ba, low values of K/Rb (80–164), Th/Ta (<9), Rb/Cs (7–40), K/Cs (0.1–0.5), Ce/Pb (0.5–4), high values of Rb/Sr (1–18) low to moderate REE contents and light-REE enriched patterns (with small negative Eu anomalies). Flat REE patterns (with large negative Eu anomalies) are found in a small, hydrothermally-altered area characterized by high abundances of Sn (up to 26 ppm), Rb (up to 670 ppm), Li (up to 310 ppm), Ta (up to 13.1 ppm), and U (up to 10 ppm). There is no single mixing trend, fractional crystallization assemblage, or assimilationscheme that accounts for all trace elementvariations from quartz gabbro to granite in the Northeast Kingdom batholith. The plutons originated by mixing mantle-derived components and crustal melts generated at different levels in the heterogeneous lithosphere in a continental collisional environment. Hybrid rocks in the batholith evolved by fractional crystallization and assimilation of country rocks (<50% by mass), and some of the leucogranitic rocks were subsequently disturbed by a mild hydrothermal event that resulted in the deposition of small amounts of sulfide minerals.     

	$\text{t(}\text{in b.y.}\text{) ± 2σ}$	$\text{1 ± 2σ}$
Ely Greenstone	$\text{2.69 ± 0.08}$	$\text{0.70056 ± 0.00026}$
Newton Lake Formation	$\text{2.65 ±0.11}$	$\text{0.70086 ± 0.00024}$
Granitic pebbles	$\text{2.69 ± 0.28}$	$\text{0.70078 ± 0.00058}$

Geochemistry of granitic rocks from the Hercynian Sardinia-Corsica batholith: Implication for magma genesis

The Sardinia-Corsica batholith was structured in the late stage of the Hercynian orogenesis. The granitoids intrude mainly metamorphic complexes grading from zeolite up to amphibolite facies. The batholith is heterogeneous consisting of complexes with different affinity, chemical composition, age and degree of deformation. The present paper reports major-and trace-element data for selected samples coming only from Sardinian outcrops.

The rocks range from gabbro-diorite to tonalite, monzogranite and leucogranite. The two latter lithologies are the most abundant, gabbrodiorites and tonalites occurring in minor amounts and mainly in northern-central Sardinia. Over 75% of the granitoids contain microgranular enclaves of magmatic origin. The age of the rocks falls in the interval between 307 and 281 Ma. Sr isotope initial ratios are high, ranging between 0.7083 and 0.7107.

REE, Rb, Sr, Ba, Zr, Th, Ta, Hf, Co and Sc abundances were determined on selected samples. All elements follow three types of trends vs. CaO, which is used as differentiation index. Two trends show positive and negative correlations while the third one shows a bell-shaped pattern. LREE have different degrees of enrichment (La = 20−120× ch) and HREE show variable fractionation with prevailing (Tb/Yb)_n<1. The two peraluminous samples have very different geochemical characteristics.

From the geochemical point of view all the rocks coming from the Sardinian segment of the batholith display a typical calc-alkaline chemical character showing the imprint of both “normal and mature” continental arc geodynamic environments.

Geochemical trends suggest some petrogenetic constraints. The complete sequence of differentiation can be neither the product of crystal/liquid fractionation processes starting from a single basic parent magma nor the product of an AFC process. On the contrary, a two-stage model can be proposed. In the first stage a mafic melt of subcrustal origin interacted with monzogranitic magmas derived from 25–35% degree of melting of a crustal biotite amphibolitic source. Such a mixing process acted together with a crystal/liquid fractionation process to give tonalites and granodiorites. In the second stage lesser degrees of melting of the same crustal source could give the late-stage leucogranitic masses.

A possible scenario, able to take into account field and geochemical data, can be suggested for the genesis of this suite and we propose it as a working model for future investigations.     

Oxygen isotope study of metamorphic and granitic rocks of the Yanai district in the Ryoke belt,Japan

¹⁸O/¹⁶O ratios have been obtained for 134 whole-rocks and minerals from metamorphic and granitic rocks of the Yanai district in the Ryoke belt, Southwest Japan. The ¹⁸O/¹⁶O ratios of pelitic rocks of the marginal metamorphic zone decrease progressively with increasing metamorphic grade. In the gneiss-granite complex (zone of migmatite [1]), the most characteristic feature of the rocks is that oxygen isotopic homogenization proceeds on both local and regional scales in parallel with “granitization” or chemical homogenization. Granitic rocks of various origin are fairly uniform in isotopic composition with δ ¹⁸O of quartz of 12 to 14‰ (SMOW) and δ ¹⁸O of biotite of 7 to 9‰ and are about 3 to 4‰ enriched in ¹⁸O compared to other Cretaceous granites of non-metamorphic terranes in Japan. The high ¹⁸O/¹⁶O ratios of granitic rocks of this district were discussed in relation to the ¹⁸O-depletion in metasediments. Oxygen isotopic fractionations among coexisting minerals from various rock-types of the gneiss-granite complex indicate that these minerals were formed under near isotopic equilibrium at a temperature of about 600 to 700° C. Some abnormal fractionations of quartz-biotite pairs also were obtained for rocks which had undergone a progressive ¹⁸O-depletion or ¹⁸O-enrichment. This is due to high resistivity of quartz and contrastive susceptibility of biotite to isotopic exchange during metamorphism and “granitization”.     

Oxygen isotope fractionation and disequilibrium displayed by some granulite facies rocks from the Fraser Range,Western Australia

The granulites of the Fraser Range are assumed to have formed in a carbon-rich fluid, and are generally devoid of hornblende, and lack obvious hydrous retrograde features. In these granulites, pyroxene, garnet, plagioclase and quartz are the minerals most likely to retain the oxygen isotope ratios fixed at an early stage of initial granulite metamorphism. Temperature estimates using these minerals commonly suggest that oxygen isotopic exchange ceased in the range 600 to 680°C. The peak metamorphic temperature was probably ～ 850°C as based on the stability fields of the coexisting minerals and some cation temperatures from coexisting pyroxenes in these rocks. Ilmenite may be slightly out of isotopic equilibrium with the other minerals. Thus, grains of quartz, feldspar, pyroxene and ilmenite have suffered considerable oxygen isotopic exchange during the retrogressive phase of the metamorphism, in spite of the fact that very little water was present in these granulites. The observed deviation from the peak metamorphic temperatures can be explained by essentially closed system solid-state diffusion (on at least a scale of centimetres) during slow cooling of the rocks from ~850 to 650°C, followed by more rapid cooling down to ～ 300°C. Such an explanation is not at variance with the radiometric data available for rocks from the area, which suggest that the latter phase could have involved uplift rates of ?0.5 mm/yr for a period of about 40 Ma. Wholerock δ¹⁸O values on non-quartzose mafic granulites, about 7.2%., fall within the range of basalts affected by seafloor weathering.     

华北地台前寒武花岗岩类、陆壳演化与克拉通形成

通过华北前寒武纪花岗岩类的研究,提出英云闪长岩和奥长花岗岩（Ｔ１Ｔ２）代表不成熟陆壳组成,Ｔ１Ｔ２Ｇ１Ｇ２代表半成熟陆壳组成,花岗闪长岩和花岗岩（Ｇ１Ｇ２）代表成熟陆壳组成。讨论了大陆根的形成与性质。识别出华北地台内１０个太古陆核。讨论了中太古代初始陆核、新太古代陆核;新太古代末两个微大陆尺度的陆核的形成;早元古代两个成熟陆核的构造拼合并形成华北克拉通     

Composition of the Precambrian Llano Uplift,central Texas,U.S.A.

The Llano uplift exposes rocks of approximately 1000 m.y. age. The weighted average composition of the exposed crust is: 70.7% SiO₂; 0.35% TiO₂; 13.6% A1₂O₃; 3.4% total Fe as Fe₂O₃; 1.1% MgO; 2.6% CaO; 3.3% Na₂O; and 4.4% K₂O. This composition is similar to, but more potassic, than equivalent estimates for the Canadian shield.     

Oxygen isotope studies of potassic volcanic rocks of the Roman Province,Central Italy

The ¹⁸O/¹⁶O ratios of rocks and coexisting minerals were measured for 93 samples of leucite-bearing lavas, pyroclastics, and related volcanic rocks from the Quaternary Roman Co-Magmatic Province, Italy. The ¹⁸O values were found to generally increase northward in the sequence: Ischia (5.8 to 7.0); Somma-Vesuvius and Phlegrean Fields (7.3 to 8.3); Alban Hills (7.3 to 8.7); M. Sabatini (7.3 to 9.7); Vico Volcano (7.4 to 10.2); and M. Vulsini (8.1 to 11.7). The northward increase in ¹⁸O parallels a similar increase in ⁸⁷Sr/⁸⁶Sr, and these data indicate that the Roman magmas have interacted strongly with high-¹⁸O continental crust. A marked increase in ¹⁸O occurs just north of Rome where the Roman Province begins to overlap the calc-alkaline, oversaturated Tuscan Magmatic Province. Therefore, some of the observed ¹⁸O/¹⁶O and ⁸⁷Sr/⁸⁶Sr enrichments in the Roman magmas may have been facilitated by direct mixing with the high-¹⁸O Tuscan magmas or because the high-¹⁸O country rocks underwent widespread heating during a couple of million years of Tuscan igneous activity. Although many of the Roman magmas underwent fractional crystallization without appreciable change in ¹⁸O, contamination has produced a correlation between ¹⁸O and SiO₂ content at several of the volcanic centers; thus the trachytes are typically higher in ¹⁸O than the undersaturated rocks. The major features of the oxygen isotope data can be explained in terms of a simple two-component mixing model in which one end-member was a primary, strongly undersaturated magma derived from the upper mantle, with ¹⁸O+6, ⁸⁷Sr/⁸⁶Sr0.704 to 0.705, and SiO₂<44wt.%. However, none of the analyzed samples have these values, as they have all been contaminated to some extent. The closest approach is found in some of the leucitepyroxenite ejecta from the Alban Hills. The second end-member, derived from the continental crust, had a variable composition with ¹⁸O+12 to +20, ⁸⁷Sr/⁸⁶Sr0.712 to 0.720, and SiO₂65wt.%, and it mixed in much greater proportions in the volcanoes north of Rome than in those of the Alban Hills or the Naples area. The widespread interactions between the Roman magmas and the continental crust are probably due to (1) the fact that such low-SiO₂ magmas always have a very strong tendency to interact with quartz-bearing rocks of the continental crust, and (2) in Italy, these magmas were emplaced into a tectonically very active area containing poorly consolidated sedimentary rocks, and in the northern part of the belt there had been a prior history of extensive calc-alkaline igneous activity.Publication of the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, Contribution Number 2501.     

Oxygen and carbon isotope analysis of the Mooreville Chalk and late Santonian-early Campanian sea level and sea surface temperature changes, northeastern Gulf of Mexico, U.S.A.

Oxygen and carbon isotope profiles for strata of the Mooreville Chalk (upper Santonian-lower Campanian) of the eastern Gulf Coastal Plain, U.S.A., show correlations with published curves for these isotopes. The δ¹⁸O curve exhibits a strong similarity to the Exmouth Plateau δ¹⁸O curve from ODP drilling sites offshore northwestern Australia, and the δ¹³C curve can be correlated with the δ¹³C curve from the English Chalk Trunch section.A thermal maximum probably occurred in the northeastern Gulf of Mexico during the latest Santonian (83.8 Ma), as evidenced by the minimum δ¹⁸O values in the lower Mooreville beds. A δ¹³C positive excursion occurs at the same stratigraphic level, which has been recognized as the “Santonian/Campanian boundary event” worldwide. After this event, ocean surface water temperature decreased throughout the early Campanian. This carbon isotope excursion is followed by a plateau in δ¹³C values with a peak value occurring in a condensed section (80 Ma), which has been correlated to a downlap or maximum flooding surface on seismic data from offshore Alabama. The section characterized by increasing δ¹³C values corresponds to a marine transgression. The interval characterized by decreasing δ¹³C values corresponds to regression and progradation. The maximum flooding event occurred 0.8 Ma later than the thermal maximum event.The Mooreville chalk/marl cycles are most likely a product of fluctuations in siliciclastic sediment influx into the northeastern Gulf of Mexico modulated by the precession band of the Earth's orbital cycles. Higher carbon isotope values occur in the marl beds indicating that these beds were formed in a more anoxic/dysoxic environment characterized by higher clay, silt input and higher organic carbon accumulation.     

Pollen evidence of vegetational change following early European settlement of Monhegan Island, Maine, northeastern U.S.A.

Postsettlemcnt vegetation changes beginning in the early 17th century were studied through comparing stratigraphic peat-pollen data with available historical evidence. The isolation of the site and the relatively long historical record were ideal for the study. Human disturbance of the vegetation was readily identified in the pollen diagram with a contemporaneous increase in sediment mineral matter. The effects were much the same as the changes associated with Neolithic forest clearance in Northern Europe. Settlement resulted in the introduction and expansion of several cultural weeds after grazing and cultivation of Zea mays began on the island in the first decades of the 17th century; Rumex acetosa-acetosella, Ranunculus acris type, Plantago major-media and several new Compositae and Umbelliferae species all appeared at that time. The response of the native species to settlement was varied. Because of the limitations of the palynologic method, the area of cultivated land and detailed kind of agriculture can only be estimated. The data suggest that although agriculture was intensive from time to time, it took place on a very limited local scale; fires, grazing, and lumbering were the major factors affecting natural ecosystems.     

Oxygen isotope records of goethite from ferricrete deposits indicate regionally varying Holocene climate change in the Rocky Mountain region, U.S.A.

Oxygen isotopes of goethite from ferricrete deposits were measured from both northern and southern Rocky Mountain localities to assess geographic variability in regional Holocene paleoclimate change. A ∼3.7‰ increase in oxygen isotope values of ¹⁴C-dated goethites in the northern Rocky Mountains suggests a regional-scale relative increase in amounts of isotopically heavy summer precipitation since the early Holocene. In contrast, oxygen isotope values from the southern Rocky Mountains increase abruptly ∼2.1‰ at ∼6200 ¹⁴C yr B.P., then decrease ∼2.4‰ between ∼2000 ¹⁴C yr B.P. and the present. We interpret this period of relatively high δ¹⁸O values as evidence for a middle Holocene warm period combined with a relatively strong summer monsoon. These variable climate records suggest that the Rocky Mountains of the western United States have had a spatially heterogeneous Holocene climate history.     

Geochemistry of Precambrian mafic dikes,central Bighorn Mountains,Wyoming, U.S.A.

Precambrian quartz dolerites and metadolerites of the central Bighorn Mountains form dikes that intrude a Precambrian metamorphic and igneous terrane typical of the Laramide uplifts of the middle Rocky Mountains. They have a restricted range of major- and trace-element compositions and are typical of basalts in the middle stages of tholeiitic fractionation. Fractionation in the direction of iron enrichment occurred by removal of plagioclase. Average element concentrations of the two groups are nearly identical to one another, are comparable to those in Archean metabasalts from numerous shield areas, and are intermediate between those of modern oceanic tholeiites and continental tholeiites. These average concentrations suggest a depth of magma generation and thickness of crust intermediate between those for the oceanic and continental environments.     

Zircon Hf isotope perspective on the origin of granitic rocks from eastern Bavaria, SW Bohemian Massif

The petrogenetic potential of in situ laser ablation Hf isotope data from melt precipitated zircons was explored through the analyses of about 700 individual crystals derived from about 20 different granitic intrusions covering the Variscan basement segment of eastern Bavaria, SE Germany. In combination with geochemical features, four major suites of granitic rocks can be distinguished: (1) NE Bavarian redwitzites (52–57 wt% SiO₂, intrusion ages around 323 Ma) have chondritic εHf(t) values (+0.8 to –0.4). The redwitzites are hybrid rocks and the Hf data are permissive of mixing of a mantle progenitor and crustal melts. (2) Various intermediate rock types (dioritic dyke, granodiorite, palite, 59–63 wt% SiO₂, 334–320 Ma) from the Bavarian Forest yield negative εHf(t) values between –3.4 and –5.1. These values which apparently contradict a mantle contribution fingerprint an enriched (metasomatized) mantle component that was mixed with crustal material. (3) Voluminous, major crust forming granites sensu stricto (67–75 wt% SiO₂, 328–298 Ma) are characterized by a range in εHf(t) values from –0.5 to –5.6. Different crustal sources and/or modification of crustal melts by various input of juvenile material can explain this variation. (4) Post-plutonic (c. 299 Ma) porphyritic dykes of dacitic composition (64–67 wt% SiO₂) from the southern Bavarian Forest have chondritic εHf(t) values (+0.6 to –1.1) and display large intergrain Hf isotope variation. The dykes form a separate petrogenetic group and the Hf data suggest that the zircons crystallized when a pristine mantle-derived parental melt was modified by infiltration of crustal material. The zircon Hf data form a largely coherent positive array with the whole-rock Nd data and both systems yield similar two-stage depleted mantle model ages (1.1–1.7 Ga).     

The Northeast Kingdom batholith,Vermont: magmatic evolution and geochemical constraints on the origin of Acadian granitic rocks

Five Devonian plutons (West Charleston, Echo Pond, Nulhegan, Derby, and Willoughby) that constitute the Northeast Kingdom batholith in Vermont show wide ranges in elemental abundances and ratios consistent with major crustal contributions during their evolution. The batholith consists of metaluminous quartz gabbro, diorite and quartz monzodiorite, peraluminous granodiorite and granite, and strongly peraluminous leucogranite. Contents of major elements vary systematically with increasingSiO<₂ (48 to 77 wt.%). The batholith has calc-alkaline features, for example a Peacock index of 57, and values for K<₂O/Na₂O (<1), K/Rb (60–350), Zr/Hf (30–50), Nb/Ta (2–22), Hf/Ta (up to 10), and Rb/Zr (<2) in the range of plutonic rocks found in continental magmatic ares. Wide diversity and high values of minor- and trace-element ratios, including Th/Ta (0.5–22), Th/Yb (0–27), Ba/La (0–80), etc., are attributed to intracrustal contributions. Chondrite-normalized REE patterns of metaluminous and relatively mafic intrusives have slightly negative slopes (La/Yb_cn<10) and negative Eu anomalies are small orabsent. The metaluminous to peraluminous inter-mediate plutons are relatively enriched in the light REE (La/Yb_cn>40) and have small negative Eu anomalies. The strongly peraluminous Willoughby leucogranite has unique trace-element abundances and ratios relative to the rest of the batholith, including low contents of Hf, Zr, Sr, and Ba, low values of K/Rb (80–164), Th/Ta (<9), Rb/Cs (7–40), K/Cs (0.1–0.5), Ce/Pb (0.5–4), high values of Rb/Sr (1–18) low to moderate REE contents and light-REE enriched patterns (with small negative Eu anomalies). Flat REE patterns (with large negative Eu anomalies) are found in a small, hydrothermally-altered area characterized by high abundances of Sn (up to 26 ppm), Rb (up to 670 ppm), Li (up to 310 ppm), Ta (up to 13.1 ppm), and U (up to 10 ppm). There is no single mixing trend, fractional crystallization assemblage, or assimilationscheme that accounts for all trace elementvariations from quartz gabbro to granite in the Northeast Kingdom batholith. The plutons originated by mixing mantle-derived components and crustal melts generated at different levels in the heterogeneous lithosphere in a continental collisional environment. Hybrid rocks in the batholith evolved by fractional crystallization and assimilation of country rocks (<50% by mass), and some of the leucogranitic rocks were subsequently disturbed by a mild hydrothermal event that resulted in the deposition of small amounts of sulfide minerals.