Observation of the Comet Kohoutek (1973f) in the resonance light (A2Σ+−X2 ∏) of the OH radical

Two monochromatic pictures of the Comet Kohoutek (1973f) were taken on January 15, 1974 in the resonance light (A²Σ ? X² ∏) of the radical OH with a photographic telescope placed on board the NASA 990 Convair airplane. From an intensity profile we derive the production rate of OH radicals Q_OH = 4 xsx 10²⁸ moleculesec ^?1sr^?1 at 0.6 AU and the lifetime of the OH radical which is τ_OH = 4.5 × 10⁴ sec at 0.6 AU. This short lifetime (very similar to the lifetime of H₂O) combined with the high total production rate of gas in comets can explain the observed velocity of 8km sec^?1 for the H-atoms: The H-atoms produced by photodissociation of H₂O are thermalized at short distancesfrom the nucleus; the H-atoms produced by photodissociation of OH have a velocity of ?8km sec^?1 and can reach the outer part of the hydrogen envelope.     

Flowing afterglow studies of temperature dependencies for electron dissociative recombination of HCNH, CH3CNH and CH3CH2CNH and their symmetrical proton-bound dimers

A study has been made using a variable temperature flowing afterglow Langmuir probe technique (VT-FALP) to determine the equilibrium temperature dependencies of the dissociative electron-ion recombination of the protonated cyanide ions (RCNH⁺, where R=H, CH₃ and C₂H₅) and their symmetrical proton-bound dimers (RCNH⁺NCR). The power law temperature dependencies of the recombination coefficients, α_e, over the temperature range 180 to 600 K for the protonated ions are α_e(T)(cm³ s⁻¹)=3.5±0.5×10⁻⁷ (300/T)^1.38 for HCNH⁺, α_e(T)=3.4±0.5×10⁻⁷ (300/T)^1.03 for CH₃CNH⁺, and α_e(T)=4.6±0.7×10⁻⁷ (300/T)^0.81 for CH₃CH₂CNH⁺. The equivalent values for the proton-bound dimers are α_e(T)(cm³ s⁻¹)=2.4±0.4×10⁻⁶(300/T)^0.5 for (HCN)₂H⁺ to α_e(T)=2.8±0.4×10⁻⁶(300/T)^0.5 for (CH₃CN)₂H⁺, and α_e(T)=2.3±0.3×10⁻⁶(300/T)^0.5 for (CH₃CH₂CN)₂H⁺. The relevance of these data to molecular synthesis in the interstellar medium and the Titan ionosphere are discussed.     

The DH ratio in the atmosphere of Uranus: Detection of the R5(1) line of HD

Observations of Uranus during the 1975, 1976, and 1978 apparitions reveal a weak absorption at the wavelength of the R₅(1) line of HD with equivalent width $\text{1.0 ± 0.4}\text{m}\text{A}\text{?}$. The $\text{D}\text{H}$ ratio in Uranus' atmosphere implied by this line and other published spectra is (4.8 ± 1.5) × 10^?5, and may not be significantly different from that in the atmospheres of Jupiter and Saturn. In addition, the spectra exhibit two weak absorption at $\text{6044.76 ± 0.02}\text{and}\text{6045.54 ± 0.02}\text{A}\text{?}$ which we were unable to identify. No trace of absorption is visible near these wavelengths or near the HD wavelength in a laboratory spectrum of 4.92 km-am CH₄ which we obtained in an attempt to identify these absorption features and to verify that the HD feature does not arise from CH₄.     

On the C/H and D/H ratios in the atmospheres of Jupiter and Saturn

Using a method defined in a previous paper [M. Combes and T. Encrenaz, Icarus39 1–27 (1979)], we reestimated the C/H ratio in the atmospheres of Jupiter and Saturn by the measurements of the weak visible CH₄ bands, the CH₄ 3ν₃ band, and the (3-0) and (4-0) quadrupole bands of H₂. In the case of Jupiter we conclude that the C/H ratio is enriched by a factor ranging from 1.7 to 3.6 relative to the solar value. In the case of Saturn, our derived C/H value ranges from 1.2 to 3.2 times the solar value. The Jovian D/H ratio derived from this study is 1.2 × 10^?5 < D/H < 3.1 × 10^?5. The value derived for the D/H ratio on Saturn is not precise enough to be conclusive.     

The evolution of an impact-generated atmosphere

Shock wave and thermodynamic data for rock-forming and volatile-bearing minerals are used to determine minimum impact velocities (v_cr) and minimum impact pressures (p_cr) required to form a primary H₂O atmosphere during planetary accretion from chondritelike planetesimals. The escape of initially released water from an accreting planet is controlled by the dehydration efficiency. Since different planetary surface porosities will result from formation of a regolith, v_cr and p_cr can vary from 1.5 to 5.8 km/sec and from 90 to 600 kbar, respectively, for target porosities between 0 and ～45%. On the basis of experimental data, hydration rates for forsterite and enstatite are derived. For a global regolith layer on the Earth's surface, the maximum hydration rate equals 6 × 10¹⁰ g H₂O sec^?1 during accretion of the Earth. Attenuation of impact-induced shock pressure is modeled to the extent that the amount of released water as a function of projectile radius, impact velocity, weight fraction of water in the target, target porosity, and dehydration efficiency can be estimated. The two primary processes considered are the impact release of water bound in hydrous minerals (e.g., serpentine) and the subsequent reincorporation of free water by hydration of forsterite and enstatite. These processes are described in terms of model calculations for the accretion of the Earth. Parameters which lead to a primary atmosphere/hydrosphere are: an accretion time of ? 1.6 × 10⁸years, the use of an accretion model defined by Weidenschilling (1974, 1976), a mean planetesimal radius of 0.5 km, a hydration rate of 6 × 10¹⁰ g H₂O sec^?1 inferred from a mean porosity of ～ 10% for the upper 1 km of the accreting Earth, and values for the dehydration efficiency, DE, of 0.55 and 0.07 for the maximum and minimum pressure decay model, respectively. Conditions which prohibit the formation of a primary atmosphere include an accretion time much longer than 1.6 × 10⁸ years, a hydration rate for forsterite and enstatite well in excess of 6 × 10¹⁰ g H₂O sec^?1, and a dehydration efficiency DE < 0.07. We conclude that the concept of dehydration efficiency is of dominant importance in determining the degree to which an accreting planet acquires an atmosphere during its formation.     

Postperihelion interference filter photometry of the “annual” comet P/Encke

Interference filter photometry was taken of Comet Encke on June 14, 1974 (1.07 AU heliocentric distance, postperihelion) at the CTIO (Cerro Tololo Interamerican Observatory) 150-cm reflector. Production rates were calculated of 4.1 × 10²³ mol sec^?1 of CN, 5.3 × 10²³ mol sec^?1 of C₃, and 4.3 × 10²⁴ mol sec^?1 of C₂. These are about three times smaller than at comparable heliocentric distance preperihelion, assuming a value of 100 for the ratio H₂O/ (C₂ + C₃ + CN). An upper limit was placed on the production of nonvolatiles at about one-third that of volatiles in mass by assuming a bulk density of 1 g cm^?3, a particle geometric albedo of 0.1, and a phase function of 0.2.     

Solar radiation scattered in the Venus atmosphere: The Venera 11,12 data

Results of the scattered solar radiation spectrum measurements made deep in the Venus atmosphere by the Venera 11 and 12 descent probes are presented. The instrument had two channels: spectrometric (to measure downward radiation in the range 0.45 < γ < 1.17 μm) and photometric (four filters and circular angle scanning in an almost vertical plane). Spectra and angular scans were made in the height range from 63 km above the planet surface. The integral flux of solar radiation is 90 ± 12 W m^?2 measured on the surface at the subsolar point. The mean value of surface absorbed radiation flux per planetary unit area is 17.5 ± 2.3 W m^?2. For Venera 11 and 12 landing sites the atmospheric absorbed radiation flux is ～15 W m^?2 for H >; 43 km and ～45 W m^?2 for H < 48 km in the range 0.45 to 1.55 μm. At the landing sites of the two probes the investigated portion of the cloud layer has almost the same structure: it consists of three parts with boundaries between them at about 51 and 57 km. The base of clouds is near 48 km above the surface. The optical depth of the cloud layer (below 63 km) in the range 0.5 to 1 μm does not depend on the wavelength and is ～29 and ～38 for the Venera 11 and 12 landing sites, respectively. The single-scattering albedo, ω₀, in the clouds is very close to 1 outside the absorption bands. Below 58 km the parameter (1 ? ω₀) is <10^?3 for 0.49 and 0.7 μm. The parameter (1 ? ω₀) obviously increases above 60 km. Below 48 km some aerosol is present. The optical depth here is a strong function of wavelength. It varies from 1.5 to 3 at λ = 0.49 μm and from 0.13 to 0.4 at 1.0 μm. The mean size of particles below the cloud deck is about 0.1 μm. Below 35 km true absorption was found at λ < 0.55 μm with the (1 ? ω₀) maximum at H ≈ 15 km. The wavelength and height dependence of the absorption coefficient are compatible with the assumption that sulfur with a mixing ratio ～2 × 10^?8 normalized to S₂ molecules is the absorber. The upper limits of the mixing ratio for Cl₂, Br₂, and NO₂ are 4 × 10^?8, 2 × 10^?11, and 4 × 10^?10, respectively. The CO₂ and H₂O bands are confidently identified in the observed spectra. The mean value of the H₂O mixing ratio is 3 × 10^?5 < F_H2O < 10^?4 in the undercloud atmosphere. The H₂O mixing ratio evidently varies with height. The most probable profile is characterized by a gradual increase from F_H2O = 2 × 10^?5 near the surface to a 10 to 20 times higher value in the clouds.     

A study of the 3ν3CH4 region in a high-resolution spectrum of Jupiter recorded by Fourier transform spectroscopy

A spectrum of Jupiter between 6000 and 12 000 cm^? at high resolution (0.05 cm^?) was recorded with a Michelson interferometer at Palomar Mountain in October 1974. An analysis of the R branch of the 3ν₃CH₄ band with the reflecting-layer model, taking into account the H₂ absorption which occurs in the same spectral range, leads to a Lorentzian half-width of 0.09 ± 0.02 cm^?1, a rotational temperature of 175 ± 10° K, and a CH₄ abundance of order 52m atm. Five lines of the ¹³CH₄3ν₃ band have been identified; a comparison with new laboratory spectra indicates that the ¹³CH₄/¹²CH₄ ratio in the Jupiter atmosphere is close to the terrestrial ratio.     

An estimate of the PH3, CH3D,and GeH4 Abundances on Jupiter from the Voyager IRIS data at 4.5 μm

The abundances of PH₃, CH₃D, and GeH₄ are derived from the 2100- to 2250-cm^?1 region of the Voyager 1 IRIS spectra. No evidence is seen for large-scale variations of the phosphine abundance over Jovian latitudes between ?30 and +30°. In the atmospheric regions corresponding to 170–200°K, the derived PH₃/H₂ value is (4.5 ± 1.5) × 10^?7 or 0.75 ± 0.25 times the solar value. This result, compared with other PH₃ determinations at 10 μm, suggests than the PH₃/H₂ ratio on Jupiter decreases with atmospheric pressure. In the 200–250°K region, we derive, within a factor of 2, CH₃D/H₂ and GeH₄/H₂ ratios of 2.0 × 10^?7 and 1.0 × 10^?9, respectively. Assuming a C/H value of 1.0 × 10^?3, as derived from Voyager, our CH₃D/H₂ ratio implies a D/H ratio of 1.8 × 10^?5, in reasonable agreement with the interstellar medium value.     

Phosphine photochemistry in the atmosphere of Saturn

A model is presented for the photochemistry of PH₃ in the upper troposphere and lower stratosphere of Saturn that includes the effects of coupling with NH₃ and hydrocarbon photochemistry, specifically the C₂H₂ catalyzed photodissociation of CH₄. PH₃ is rapidly depleted with altitude (scale height ～35 km) in the upper troposphere when K～10⁴cm²sec^?1; an upper limit for K at the tropopause is estimated at ～10⁵cm²sec^?1. If there is no gas phase P₂H₄ because of sublimation, P₂ and P₄ formation is unlikely unless the rate of the spin-forbidden recombination reaction PH + H₂ + M → PH₃ + M is exceedingly slow. An upper limit P₄ column density of ～2×10¹⁵cm^?2 is estimated in the limit of no recombination. If sublimation does not remove all gas phase P₂H₄, P₂ and P₄ may be produced in potentially larger quantities, although they would be restricted almost entirely to the lowest levels of our model, where T?100°K. Potentially observable amounts of the organophosphorus compounds CH₃P₂H₂ and HCP are predicted, with column densities of >10¹⁷ cm^?2 and production rates of ～2×10⁸cm^?2sec^?1. The possible importance of electronically excited states of PH_x and additional PH₃/hydrocarbon photochemical coupling paths are also considered.     

Chemical processes in Triton's atmosphere and surface

Liquid solutions of N₂ containing up to one-third CH₄ can exist on Triton's surface in regions T > 62.5°K. More generally, subsurface oceans of N₂ solution are expected to be stable beneath overlying, thermally insulating, less dense layers of the abundant light hydrocarbon products of radiochemical synthesis: C₂H₆, C₃H₈, and C₄H₁₀. Cosmic rays are the main source of energy, capable of producing synthesis of organic compounds from N₂CH₄ solutions on the surface. For baseline Triton models with R = 2500 km, ϱ = 2.1 g cm⁻³, and T_s = 65 or 55°K, respectively, 4 × 10⁻³ or 7 × 10⁻³ erg cm⁻² sec⁻¹ (49 or 87% of the total incident flux) is deposited within a few meters below the surface. Using yields from laboratory experiments, we estimate the quantities of products produced: over 4.5 billion years, the cosmic ray flux alone produces 2 to 4 m of organic product, about half of which is C₂H₆. For ocean depths <250 m, C₂H₆ will reach its saturation limit and form a surface “slick.” For ocean depths <10 km, all of the other products also oversaturate and exsolve, adding to the surface slick and/or to a denser bottom sediment. Products produced from solid N₂CH₄ mixtures will accumulate as evaporite deposits because of the rapid volatile transport (of N₂ and CH₄) over Triton's surface. The complex, reddish organic solid found in laboratory simulations is probably the source of Triton's reddish color. Estimated yields over 4.5 billion years (for 7 × 10⁻³ erg cm⁻² sec⁻¹) are 190 (C₂H₆), 58 (NH₃), 17 (HCN), 3.5 (HN₃), 2.5 (C₄H₁₀), 0.35 (CH₃CN), and 0.14 (C₂H₅N₃) g cm⁻². More basic laboratory work on the low-temperature, low-pressure solvent properties and phase equilibria of N₂-hydrocarbon systems is clearly needed.     

Comet C/2010X1 (Elenin). Unrealized expectations

We present the analysis of the photometric and spectroscopic data obtained for comet C/2010 X1 (Elenin) when it was at a distance of 2.92 AU from the Sun. The observations were made at the prime focus of the 6-m BTA telescope with the SCORPIO focal reducer. The magnitude of the comet, measured in the R _c -band with an 9?? aperture radius amounted to 16?8 ± 0?1. The computed dust production rate was estimated to be about 6 kg/s. The cometary coma manifested the emissions in the (0?C0) band of the CN molecule violet system, and a number of emission band heads of the C₃ molecule. The gas production rate of the molecules is determined using the Haser model and amounts to 1.41 × 10²⁴ and 4.20 × 10²³ molecules per second for CN and C₃, respectively. The ratio of gas production rates log[Q(C₃)/Q(CN)] is equal to ?0.85, which is close to the mean value, determined for a significant number of comets. A normalized gradient of the cometary dust reflectivity, calculated for the 4430?C6840 ? spectral range amounts to 14.3 ± 1.2%.     

Recombination of electrons with H3+ and H5+ ions

The dissociative recombination coefficients α for capture of electrons by H₃⁺ and H₅⁺ ions have been determined as a function of electron temperature T_e using a microwave afterglow-mass spectrometer apparatus. At ion and neutral temperatures T_u+ = T_n = 240 K, the coefficient α (H₃⁺) is found to vary slowly with T_e at first, decreasing from 1.6 × 10^?7 cm³/s at T_e = 240 K to 1.2 × 10^?7 cm³/s at T_e = 500 K, thereafter falling as T_e^?1 over the range 500 K ? T_e, ? 3000 K. These results, which have a ± 20% uncertainty, agree satisfactorily over the common energy range (0.03–0.36 eV) with the recombination cross sections determined in merged beam measurements by Auerbach et al. At T₊ = T_n = 128 K, the coefficient α(H₅⁺) is found to be (1.8 ± 0.3) × 10^?6 [T_e(K)/300]^?0.69 cm³/s over the range 128 K ? T_e ? 3000 K, with a more rapid decrease, as T_e^?1, between 3000 K and 5500 K. The implications of these results for modelling planetary atmospheres and interstellar clouds are briefly touched on.     

The abundance of acetylene in the atmosphere of Jupiter

The Q and R branches of the C₂H₂ ν₅ fundamental, observed in emission in an aircraft spectrum of Jupiter near 750 cm^?1, have been analyzed with the help of an improved line listing for this band. The line parameters have been certified in the laboratory with the same interferometer used in the Jovian observations. The maximum mixing ratio of C₂H₂ is found to be between 5 × 10^?8 and 6 × 10^?9, depending on the form of its vertical distribution and the temperature structure assumed for the lower stratosphere. Most consistent with observations of both Q and R branches are: (1) distributions of C₂H₂ with a constant mixing ratio in the stratosphere and a cutoff at a total pressure of 100 mbar or less, and (2) the assumption of a temperature at 10^?2 bar which is near 155°K.     

Near-infrared spectra of laboratory H2O-CH4 ice mixtures

We present 1.25-19 μm infrared spectra of pure solid CH₄ and H₂O/CH₄=87, 20, and 3 solid mixtures at temperatures from 15 to 150 K. We compare and contrast the absorptions of CH₄ in solid H₂O with those of pure CH₄. Changes in selected peak positions, profiles, and relative strength with temperature are presented, and absolute strengths for absorptions of CH₄ in solid H₂O are estimated. Using the two largest (ν₃+ν₄) and (ν₁+ν₄) near-IR absorptions of CH₄ at 2.324 and 2.377 μm (4303 and 4207 cm⁻¹), respectively, as examples, we show that peaks of CH₄ in solid H₂O are at slightly shorter wavelength (higher frequency) and broader than those of pure solid CH₄. With increasing temperature, these peaks shift to higher frequency and become increasingly broad, but this trend is reversible on re-cooling, even though the phase transitions of H₂O are irreversible. It is to be hoped that these observations of changes in the positions, profiles, and relative intensities of CH₄ absorptions with concentration and temperature will be of use in understanding spectra of icy outer Solar System bodies.     

Water production and release in Comet 153P/Ikeya-Zhang (C/2002 C1): accurate rotational temperature retrievals from hot-band lines near 2.9-μm

Multiple non-resonance fluorescence lines of water (H₂O) were detected in Comet 153/P Ikeya-Zhang (2002 C1) between UT 2002 March 21.9 (R_h=0.51 AU) and April 13.9 (R_h=0.78 AU), using the Cryogenic Echelle Spectrometer (CSHELL) at the NASA Infrared Telescope Facility. Analysis of 2.9-μm water lines enabled accurate determination of rotational temperatures on three dates. The derived H₂O rotational temperatures were 138⁺⁶₋₅, 141⁺¹⁰₋₉, and 94±3 K on UT 2002 March 22.0, March 23.0, and April 13.8, respectively. Water production rates were retrieved from spectral lines measured in nineteen separate grating settings over seven observing periods. The derived heliocentric dependence of the water production rate was Q=(9.2±1.1)×10²⁸[R_h^{(−3.21±0.26)}] molecules s⁻¹. The spatial distribution of H₂O in the coma was consistent with its release directly from the nucleus (as a native source) on all dates.     

Rocket measurements of oxygen and nitrogen emissions in the aurora

Altitude distributions of electronically excited atoms and molecules of oxygen and nitrogen in the aurora have been obtained by means of rocket-borne wavelength scanning interference filter photometers launched from Fort Churchill, Manitoba (58.4°N, 94.1°W) on January 23, 1974. Atomic oxygen densities derived from mass spectrometer measurements obtained during the flight are used in conjunction with the volume emission rate ratio of the N₂(C³Π_u?B³Π_g) (0-0) second positive and N₂(A³Σ_u⁺, v = 1?X¹Σ_g⁺) Vegard-Kaplan bands to derive a rate constant for quenching of the N₂(A³Σ_u⁺, v = 1) level with O(³P) of 1.7(±0.8) × 10^?11 cm³ s^?1 These data, together with O den derived from the O₂(b¹Σ_g⁺) state nightglow emission observed during the rocket ascent, suggest that quenching of the N₂(A³Σ_u⁺, v = 1) level by O₂ has a significant positive temperature dependence. The processes involved in the production and loss of the N₂(A³Σ_u⁺) state are considered and energy transfer from the N₂(A³Σ_u⁺) state to O(³P) is found to be a significant source of the OI 5577 Å green line in this aurora at altitudes below 130 km. Emission from the NO(A²Σ⁺?X²Π) gamma bands was not detected, an observation which is consistent with the mass spectrometer data obtained during the flight indicating that the NO density was <10⁸ cm³ at 110 km. On the basis of previous rocket and satellite measurements of the NO gamma bands, energy transfer from the N₂(A³Σ_u⁺) state to NO(X²Π) is shown to be an insignificant source of the gamma bands in aurora. Altitude profiles of the N₂(a¹Π_g?X¹Σ_g⁺) Lyman-Birge-Hopfield band system are presented.     

Excitation of oxygen emissions in the night airglow of the terrestrial planets

The excitation, energy transfer and quenching of O₂ (A³ Σ_u⁺, C³ Δ_u, c¹ Σ_u^?) and O(¹S) are discussed, taking into account laboratory measurements and observations on the airglow of the Earth, Venus and Mars. The excitation of O(¹S) occurs by the Barth mechanism with O₂(c) as a precursor: the rate coefficient is 2.5 × 10^?12 cm³ s^?1 for υ > 0 and 2.5 × 10^?12 exp($\text{?1100}\text{T}$) cm₃ s^?1for υ = 0. The O₂(c) can be formed directly by recombination or by O₂(A) and O₂(C) colliding with other molecules; the O₂(c) yield through quenching of these states is about 0.3 in air and about 1.0 in carbon dioxide. The rate coefficients of some processes that control the molecular oxygen bands and the atomic oxygen green line are estimated.     

Tidal dissipation in the solid cores of the major planets

If the orbital resonances in the Jovian and Saturnian satellite systems are the result of orbital evolution due to tidal dissipation then the present rates of energy dissipation ($\text{E}\text{dot}$) are >2 × 10²⁰ ergs sec^?1 (Jupiter) and ?2 × 10¹⁶ ergs sec^?1 (Saturn). These values of $\text{E}\text{dot}$ can be accounted for if the planets have rocky cores with volumes equal to those suggested by current models of the interiors and if the material of these cores is both solid and imperfectly elastic (Q_e ～ 34). The calculated values of Q_e are not strongly dependent on either the rigidity of the core or the densities of the core and the mantle. Thus, these quantities need not be known precisely. It may be significant that approximately the same value of Q_e is needed for all the major planets (Jupiter, Saturn, and Uranus) even though the values of $\text{E}\text{dot}$ for these planets differ by a factor greater than 10⁴.     

Near-infrared laboratory spectra of solid H2O/CO2 and CH3OH/CO2 ice mixtures

We present near-IR spectra of solid CO₂ in H₂O and CH₃OH, and find they are significantly different from that of pure solid CO₂. Peaks not present in either pure H₂O or pure CO₂ spectra become evident when the two are mixed. First, the putative theoretically forbidden CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹), that is absent from our spectrum of pure solid CO₂, is prominent in the spectra of H₂O/CO₂=5 and 25 mixtures. Second, a 2.74-μm (3650 cm⁻¹) dangling OH feature of H₂O (and a potentially related peak at 1.89 μm) appear in the spectra of CO₂-H₂O ice mixtures, but are probably not diagnostic of the presence of CO₂. Other CO₂ peaks display shifts in position and increased width because of intermolecular interactions with H₂O. Warming causes some peak positions and profiles in the spectrum of a H₂O/CO₂=5 mixture to take on the appearance of pure CO₂. Absolute strengths for absorptions of CO₂ in solid H₂O are estimated. Similar results are observed for CO₂ in solid CH₃OH. Since the CO₂ (2ν₃) overtone near 2.134 μm (4685 cm⁻¹) is not present in pure CO₂ but prominent in mixtures, it may be a good observational (spectral) indicator of whether solid CO₂ is a pure material or intimately mixed with other molecules. These observations may be applicable to Mars polar caps as well as outer Solar System bodies.