Seasonal variations in the cycling of aluminium,cadmium and manganese in a Scottish sea loch: biogeochemical processes involving suspended particles

Concentrations of Al, Cd and Mn were determined in water and particles collected from water bottles over one year during 19 surveys of a silled fjord. Nutrient and hydrographic data were also collected. Particle fluxes were determined at one site using a sediment trap array. Concentrations of dissolved Al showed the strongest (negative) relationship to salinity (r=0.91). This correlation decreased with the onset of the diatom bloom and was insignificant immediately post bloom. Removal of dissolved Al was coincident with an increase in particulate Al concentrations. The degree of removal could be predicted from previously reported Al/Si uptake ratios. Concentrations of leachable P in particulate material from the sediment traps increase at the onset of the bloom and decrease coincident with rapid regeneration as the bloom crashed. Particulate leachable Cd showed a lag in apparent uptake and regeneration relative to particulate leachable P. A substantial amount (ca. 53%) of the annual particle flux of Mn to the deepest trap is material recycled at the sediment surface and is not accumulated in the bottom sediment. Dissolved and particulate Mn levels in the loch have a strong seasonal pattern with low values prior to the spring phytoplankton bloom and increased values after the bloom crash. Maximum concentrations were observed in late autumn. Levels decreased to near pre-bloom values early the following year. This suggests bacterial decay of deposited organic carbon associated with the spring bloom-maintained suboxic conditions at or near the seawater-sediment interface throughout the majority of the year. After exhaustion of this organic matter pool recycling ceased for a brief (2–3 months) winter period.     

Reflection of an internal wave at an interface representing a rapid increase in viscosity

Abstract

Internal waves at high altitudes are greatly damped by the drastic increase in molecular viscosity and thermal diffusivity, resulting in important heating and other effects at those altitudes. Here we consider the case where this increase in viscosity is very rapid, idealized as an interface with inviscid flow in the lower layer and constant viscosity in the upper layer. The results show that waves are partially reflected by this interface, with a reflection coefficient that increases monotonically with an increase in the viscosity of the upper layer. This mechanism would have a significant impact on the vertical distribution of thermal energy at high altitudes.     

Theory of internal gravity wave saturation

Gravity wave saturation is an important process affecting the transport and deposition of momentum, heat, and constituents in the earth's atmosphere. This paper informally discusses several saturation mechanisms and their effects, including convection, Kelvin-Helmholtz instability, vortical mode instability, parametric subharmonic instability, and mean flow interaction. Convective saturation is emphasized. The parameterization of convective adjustment is discussed and a few remarks are made concerning the effects of turbulence localization on the convective saturation process. Several outstanding problems in saturation theory are identified that could be addressed with observational, numerical, and laboratory studies.     

High-frequency bottom-pressure and acoustic variations in a sea strait: internal wave turbulence

During a period of 3?days, an accurate bottom-pressure sensor and a four-beam acoustic Doppler current profiler (ADCP) were mounted in a bottom frame at 23?m in a narrow sea strait with dominant near-rectilinear tidal currents exceeding 1?m?s^?1 in magnitude. The pressure record distinguishes small and short surface waves, wind- and ferry-induced near-surface turbulence and waves, large turbulent overturns and high-frequency internal waves. Typical low-frequency turbulent motions have amplitudes of 50?N?m^?2 and periods of about 50?s. Such amplitudes are also found in independent estimates of non-hydrostatic pressure using ADCP data, but phase relationships between these data sets are ambiguous probably due to the averaging over the spread of the slanted acoustic beams. ADCP's echo amplitudes that are observed in individual beams show much better phase correspondence with near-bottom pressure, whether they are generated near the surface (mainly air bubbles) or near the bottom (mainly suspended sediment). These 50-s motions are a mix of turbulence and internal waves, but they are not due to surface wave interactions, and they are not directly related to the main tidal flow. Internal waves are supported by stratification varying between extremely strong thin layer and very weak near-homogeneous stratification. They are driven by the main flow over 2-m amplitude sand-wave topography, with typical wavelengths of 150?m.     

Dissolved and particulate trace metals in a Scottish sea loch: an example of a pristine environment?

In the near pristine environment of a silled fjord on the west coast of Scotland samples were taken for the determination of dissolved and particulate trace metals (Fe, Mn, Cu, Ni, Cd, Zn and Pb), together with nutrient and hydrographic data, during 19 surveys carried out over a year. An indication of the pristine nature of the environment are the low concentrations of dissolved silicon, phosphate and nitrate which are considerably lower than those of coastal waters which are subject to larger anthropogenic burdens. Distributions of dissolved Cu, Ni and Cd were found to broadly reflect conservative mixing of freshwater and seawater with both end members having similar concentrations. The concentration of dissolved Cu and Ni in seawater entering upper Loch Linnhe (Cu 0.28 μg l⁻¹; Ni 0.26 μg l⁻¹) was consistent with the 1:1 conservative mix of Irish Sea water and North Atlantic surface water predicted from radio-caesium tracer experiments (Mackay & Baxter, 1985). Atmospheric input of trace metals to upper Loch Linnhe appeared to be a relatively minor term in the mass balance relative to fluvial inputs. Values of distribution coefficients Kd were similar to those previously reported for the coastal environment. Iron showed the strongest affinity for the suspended sediments; with particulate percentages of the total load usually greater than 80%. Lead and Mn showed a similar strong affinity to the particle phase. For Cu, Ni and Zn the mass of the element in the dissolved phase was generally greater than that in the particulate fraction. Cadmium, was least associated with the particles, with typically greater than 90% existing in the dissolved phase.     

Observations of semidiurnal internal tidal currents off central Chile (36.6°S)

Observations of semidiurnal internal tidal currents from three moorings deployed on the continental shelf off central Chile during summer and winter of 2005 are reported. The spectra of the baroclinic currents showed large peaks at the semidiurnal band with a dominant counterclockwise rotation, which was consistent with internal wave activity. The amplitude of the barotropic tidal currents varied according to the spring–neap cycle following the sea level fluctuations. In contrast, the amplitudes of the internal tide showed high spatial-temporal variability not directly related to the spring–neap modulation. Near the middle of the continental shelf and near the coast (San Vicente Bay) the variance of the semidiurnal baroclinic current is larger than the variance of its barotropic counterpart. The vertical structure of the baroclinic tidal current fluctuations was similar to the structure of the first baroclinic internal wave mode. In general, in the three study sites the variance of the baroclinic current was larger near the surface and bottom and tended to show a minimum value at mid depths. Kinetic energy related to semidiurnal internal waves was larger in winter when stratification of the water column was stronger. During summer, upwelling and the decrease of freshwater input from nearby rivers reduced the vertical density stratification. The amplitude of the semidiurnal internal tide showed a tendency to be enhanced with increasing stratification as observed in other upwelling areas. The continental shelf break and submarine canyons, which limit the continental shelf in the alongshore direction, represent near-critical slopes for the semidiurnal period and are suggested to be the main internal tide generation sites in the study region.     

Trapped internal waves over undular topography in a partially mixed estuary

The flow of a stratified fluid over small-scale topographic features in an estuary may generate significant internal wave activity. Lee waves and upstream influence generated at isolated topographic features have received considerable attention during the past few decades. Field surveys of a partially mixed estuary, the Rotterdam Waterway, in 1987, also showed a plethora of internal wave activity generated by isolated topography, banks and groynes. Additionally it revealed a spectacular series of resonant internal waves trapped above low-amplitude bed waves. The internal waves reached amplitudes of 3–4 m in an estuary with a mean depth of 16 m. The waves were observed during the decreasing flood tide and are thought to make a significant contribution to turbulence production and mixing. However, while stationary linear and finite amplitude theories can be used to explain the presence of these waves, it is important to further investigate their time-dependent and non-linear behaviour. With the development of advanced non-hydrostatic models it now becomes possible to further investigate these waves through numerical experimentation. This is the focus of the work presented here. The non-hydrostatic finite element numerical model FINEL3D developed by Labeur was used in the experiments presented here. The model has been shown to work well in a number of stratified flow investigations. Here, we first show that the model reproduces the field data and for idealised stationary flow scenarios that the results are in agreement with the resonant response predicted by linear theory. Then we explore the effects of non-linearity and time dependence and consider the importance of resonant internal waves for turbulence production in stratified coastal environments.Responsible Editior: Hans Burchard     

A note on the amount of wave energy transmitted over nearshore sand bars

The wave energy loss as waves break on nearshore bars is an important geomorphological process as it controls the stability of the adjacent beaches and dunes. The effect is particularly important during storms as it serves to guard against severe shoreline erosion. Field measurements from Florida and Ireland of waves crossing both single and multiple bar bedforms, indicate that where bar-breaking occurs, between 78 and 99 per cent of wave energy may be dissipated from individual waves. However, a further 20 per cent energy may reach the shore if wave frequencies increase during the reformation process. This latter effect was not noted at the multiple bar site where spilling mode breakers dominate. The level of energy dissipation is related to the time taken to cross that section of the submerged bar below the critical depth, d < 1.28H. In the field this may be approximated by the ratio of wave speed to the width of the bar breaker zone.     

Seasonal variations and trophic ecology of microzooplankton in the southeastern Arabian Sea

The seasonal ecological response of microzooplankton in the southeastern Arabian Sea is presented. During the spring intermonsoon period, stratification and depletion of nitrate in the surface waters (nitracline was at 60 m depth) cause low integrated chlorophyll a (av. 19±11.3 mg m⁻²) and primary production (av. 164±91 mgC m⁻² d⁻¹). On the other hand, nutrient enrichment associated with coastal upwelling and river influx during the onset and peak summer monsoon resulted in high integrated chlorophyll a (av. 21±6 mg m⁻² and av. 29±21 mg m⁻², respectively) and primary production (av. 255±94 mgC m⁻² d⁻¹ and av. 335±278 mgC m⁻² d⁻¹, respectively). During all three periods, diazotropic cyanobacterium Trichodesmium erythraeum dominated in the nutrient depleted surface waters. A general increase in abundance of larger diatoms was evident in the surface waters of the inshore region during monsoon periods. The microzooplankton abundance was found to be significantly higher during the spring intermonsoon (av.241±113×10³ ind m⁻²) as compared to onset of summer monsoon (av. 105±89×10³ ind m⁻²) and peak summer monsoon (av.185±175×10³ ind m⁻²). Microzooplankton community during the spring intermonsoon was numerically dominated by ciliates while heterotrophic dinoflagellate was the dominant ones during the monsoon periods. The high abundance of ciliates during the spring intermonsoon could be attributed to the stratified environmental condition prevailed in the study area which favors high abundance of smaller phytoplankton and cyanobacteria, the most preferred food of ciliates. On the other hand, the dominance of heterotrophic dinoflagellates during the monsoon periods could be linked to their ability to graze larger diatoms which were abundant during the monsoon periods. The overall results show low abundance of microzooplankton in the eastern Arabian Sea during the monsoon periods mainly due to a decline in ciliates abundance. This decline during the monsoon periods could be the result of (a) low abundance of smaller phytoplankton and (b) high stock of mesozooplankton predators (av. 245 ml 100 m⁻³).     

Cross-shelf transport into nearshore waters due to shoaling internal tides in San Pedro Bay, CA

In the summer of 2001, a coastal ocean measurement program in the southeastern portion of San Pedro Bay, CA, was designed and carried out. One aim of the program was to determine the strength and effectiveness of local cross-shelf transport processes. A particular objective was to assess the ability of semidiurnal internal tidal currents to move suspended material a net distance across the shelf. Hence, a dense array of moorings was deployed across the shelf to monitor the transport patterns associated with fluctuations in currents, temperature and salinity. An associated hydrographic program periodically monitored synoptic changes in the spatial patterns of temperature, salinity, nutrients and bacteria. This set of measurements show that a series of energetic internal tides can, but do not always, transport subthermocline water, dissolved and suspended material from the middle of the shelf into the surfzone. Effective cross-shelf transport occurs only when (1) internal tides at the shelf break are strong and (2) subtidal currents flow strongly downcoast. The subtidal downcoast flow causes isotherms to tilt upward toward the coast, which allows energetic, nonlinear internal tidal currents to carry subthermocline waters into the surfzone. During these events, which may last for several days, the transported water remains in the surfzone until the internal tidal current pulses and/or the downcoast subtidal currents disappear. This nonlinear internal tide cross-shelf transport process was capable of carrying water and the associated suspended or dissolved material from the mid-shelf into the surfzone, but there were no observation of transport from the shelf break into the surfzone. Dissolved nutrients and suspended particulates (such as phytoplankton) transported from the mid-shelf into the nearshore region by nonlinear internal tides may contribute to nearshore algal blooms, including harmful algal blooms that occur off local beaches.     

Fission of a weakly nonlinear interfacial solitary wave at a step

The transformation of a weakly nonlinear interfacial solitary wave in an ideal two-layer flow over a step is studied. In the vicinity of the step the wave transformation is described in the framework of the linear theory of long interfacial waves, and the coefficients of wave reflection and transmission are calculated. A strong transformation arises for propagation into shallower water, but a weak transformation for propagation into deeper water. Far from the step, the wave dynamics is described by the Korteweg-de Vries equation which is fully integrable. In the vicinity of the step, the reflected and transmitted waves have soliton-like shapes, but their parameters do not satisfy the steady-state soliton solutions. Using the inverse scattering technique it is shown that the reflected wave evolves into a single soliton and dispersing radiation if the wave propagates from deep to shallow water, and only dispersing radiation if the wave propagates from shallow to deep water. The dynamics of the transmitted wave is more complicated. In particular, if the coefficient of the nonlinear quadratic term in the Korteweg-de Vries equation is not changed in sign in the region after the step, the transmitted wave evolves into a group of solitons and radiation, a process similar to soliton fission for surface gravity waves at a step. But if the coefficient of the nonlinear term changes sign, the soliton is destroyed completely and transforms into radiation. The effects of cubic nonlinearity are studied in the framework of the extended Korteweg-de Vries (Gardner) equation which is also integrable. The higher-order nonlinear effects influence the amplitudes of the generated solitons if the amplitude of the transformed wave is comparable with the thickness of lower layer, but otherwise the process of soliton fission is qualitatively the same as in the framework of the Korteweg-de Vries equation.     

On leakage of energy from turbulence to internal waves in the oceanic mixed layer

In this paper, we address the question of energy leakage from turbulence to internal waves (IWs) in the oceanic mixed layer (OML). If this leakage is substantial, then not only does this have profound implications as far as the dynamics of the OML is concerned, but it also means that the equation for the turbulence kinetic energy (TKE) used in OML models must include an appropriate sink term, and traditional models must be modified accordingly. Through comparison with the experimental data on grid-generated turbulence in a stably stratified fluid, we show that a conventional two-equation turbulence model without any IW sink term can explain these observations quite well, provided that the fluctuating motions that persist long after the decay of grid-generated turbulence are interpreted as being due to IW motions generated by the initial passage of the grid through the stably stratified fluid and not during turbulence decay. We conclude that there is no need to postulate an IW sink term in the TKE equation, and conventional models suffice to model mixing in the OML.     

层结海洋中小振幅内行进波的演变和破碎

采用高精度的拟谱方法,数值模拟了层结海洋中小振幅内行进波的演变和破碎过程.在演变过程中,导致内波破碎的PSI不稳定机制在共振相互作用中逐渐占据主导地位,能量从初级波向低频、高波数运动缓慢传递并形成一次级波包,随即破碎发生.破碎后产生的层化湍流引起的强烈混合以及湍流间歇性可从总能量和涡度峰度随时间的变化趋势看出.我们分析了层化湍流的一些统计特性,包括动能和有效位能沿垂向波数ky的功率谱.结果表明,动能和有效位能谱都存在一个谱段满足k-3y律,且分别可表示为0.1N4k-3y和0.2N4k-3y(N为Brunt-Visl频率),通常称其为浮力子区.另外,我们分析了Cox数(湍流扩散系数与分子扩散系数之比),在层化湍流维持在一定强度时,计算结果和由海洋内区观测(远离内波强生成源和复杂地形)所推测的结论较为吻合.     

Assessment of chemical dispersant effectiveness in a wave tank under regular non-breaking and breaking wave conditions

Current chemical dispersant effectiveness tests for product selection are commonly performed with bench-scale testing apparatus. However, for the assessment of oil dispersant effectiveness under real sea state conditions, test protocols are required to have hydrodynamic conditions closer to the natural environment, including transport and dilution effects. To achieve this goal, Fisheries and Oceans Canada and the US Environmental Protection Agency (EPA) designed and constructed a wave tank system to study chemical dispersant effectiveness under controlled mixing energy conditions (regular non-breaking, spilling breaking, and plunging breaking waves). Quantification of oil dispersant effectiveness was based on observed changes in dispersed oil concentrations and oil-droplet size distribution. The study results quantitatively demonstrated that total dispersed oil concentration and breakup kinetics of oil droplets in the water column were strongly dependent on the presence of chemical dispersants and the influence of breaking waves. These data on the effectiveness of dispersants as a function of sea state will have significant implications in the drafting of future operational guidelines for dispersant use at sea.     

Solitary waves in a compressible fluid

Evolution equations for long nonlinear internal waves in a compressible fluid are derived, with the aim of comparing these equations with their counterparts in an incompressible fluid. Both the Korteweg-de Vries equation, and the deep fluid equation are discussed, for both dry and moist atmospheres. It is shown that the effects of compressibility, or non-Boussinesq terms, are generally small, but measurable, and are manifested mainly in the nonlinear term of the evolution equation. For the case of a moist atmosphere the effect of a gain in energy by latent heat release is compared with the energy lost by radiation damping.     

Internal wave weather heterogeneity in a deep multi-basin subalpine lake resulting from wavelet transform and numerical analysis

The internal wave-field of a Y-shaped lake (Lake Como, North Italy) was investigated over a 3-year long period applying wavelet time–frequency analysis to temperature and wind data time series, recorded at the edge of each of the three arms. The comparison with the results from a modal model allowed to identify the presence of both first and second vertical modes of oscillations. The field data analysis underlined a heterogeneous baroclinic response with the eastern arm decoupled from the remaining part of the lake constituted by the northern and western arms (north–south west transect). This disjoined response is expected to enhance the water exchange between the northern and the western arm, with relevant consequences on the inter-basins water exchanges and on the distribution of chemical and biological species. In the north–south west transect the analysis of the low power signals in winter underlined a residual internal wave activity ascribed to the first vertical free mode of oscillation (V1H1).     

Estimates of Reynolds stress in a highly energetic shelf sea

In recent years the use of Acoustic Doppler Current Profilers (ADCPs) to estimate Reynolds stresses, using the so-called variance method, has become popular; and although there was great effort in studying the uncertainties on this technique, there were no reports in the main literature of its validity using independent measurements. This work reports on the comparison of ADCP and Acoustic Current Velocimeter (ADV) estimates of Reynolds stresses. The comparison of the ADCP and ADV is encouraging during periods when no strong waves were present with both the explained variance of 0.8 and the slope of the regression being 0.97. Nevertheless, when strong waves are present the method breaks down and the comparison between ADCP and ADV is very poor with R² =0.04.     

Tides and mixing in the northwestern East China Sea Part I: Rotating and reversing tidal flows

Bottom-mounted ADV and ADCP instruments in combination with CTD profiling measurements taken along the Chinese coast of the East China Sea were used to study the vertical structure of temperature, salinity, and velocity in reversing tidal currents on a shallow inner shelf and in rotating tidal flows over a deeper sloping bottom of the outer shelf. These two regimes of barotropic tide affect small-scale dynamics in the lower part of the water column differently. The reversing flow was superimposed by seiches of ∼2.3 h period generated in semienclosed Jiaozhou Bay located nearby. As the tidal vector rotates over the sloping bottom, the height of the near-bottom logarithmic layer is subjected to tidal-induced variations. A maximum of horizontal velocity U_max appears at the upper boundary of the log layer during the first half of the current vector rotation from the minor to the major axis of tidal ellipse. In rotating tidal flow, vertical shear generated at the seafloor, propagated slowly to the water interior up to the height of U_max, with a phase speed of ∼5 m/h. The time-shifted shear inside the water column, relative to the shear at the bottom, was associated with periodically changing increases and decreases of the tidal velocity above the log layer toward the sea surface. In reversing flows, the shear generated near the bottom and the shear at the upper levels were almost in phase.     

On the effect of subinertial phenomena on the internal lee waves generation in the Strait of Gibraltar

The generation of internal lee waves (ILW) in the Strait of Gibraltar takes place in the main sill where the tidal flow interacts with a submarine obstacle. The tidal flow is perturbed by subinertial phenomena of different nature summarized in the subinertial currents that can inhibit the ILW generation. The authors present an attempt to randomize the problem by the introduction of a Gaussian noise in the Taylor–Goldstein equation. The random number sets are generated from the statistical distribution of the previously isolated random part of the subinertial currents from experimental data taken in the area during the Gibraltar Experiment 94–96. The effect of the noise is translated into a continuous spreading of the spectrum around the solution of the noise-free problem. A stability analysis is carried out in order to determine the single neutral modes of oscillations and the phase space is divided onto regions of stability and instability as a function of the inflowing subinertial current. The methodology and results could be useful for the design and timing of oceanographic surveys in straits where the ILWs occur.     

Longshore variations in nearshore wave processes at magilligan point,northern ireland

Magilligan Point is a recurved cuspate foreland at the mouth of Lough Foyle. Two wave regimes intersect in the estuary mouth and the manner of their interplay controls shoreline changes. Ocean swell waves from the N and NE are refracted around the recurve, losing both height and energy longshore. Width of the surf zone decreases and waves tend to steepen, although both these changes and wave refraction owe something to nearshore geometry. Angle of wave approach becomes more acute and a westerly flowing longshore current moves sand S and SW along the beach. Estuary waves from the S and SW are wind-driven with high-frequencies and steepnesses. They generate a northeasterly current which returns material N, but dies out as the waves become obliterated by nearshore attenuation and breaking of swell. It is possible to identify a time-averaged null-point where shoreline wave power is balanced, although this tends to shift over short periods causing rapid morphological changes. The existence of two independent, but counteractive cells ensures the long-term maintenance of the foreland, without requiring major or continuous supplies of fresh sediment.