Diffuse interstellar bands (DIB): co-planar doubly excited He and metal atoms embedded in Rydberg Matter

The interpretation of the more than 300 diffuse interstellar bands (DIBs) is one of the most long-standing problems in interstellar spectra since the two first bands were reported in 1921. We now predict the frequencies of 260 diffuse interstellar bands (DIBs) using the Rydberg Matter model we have developed previously. These transitions involve mainly He atoms, but other two-electron atoms like Ca and other metals can take part in the absorption processes. Approximately 70% of the total intensity of the DIBs is due to absorption in doubly excited states and 30% in singly excited He atoms. The doubly excited states are in inverted states while the He atoms are thermal. The possibilities to observe DIBs in the UV and NIR ranges are discussed and band positions are predicted.     

Blueshifted diffuse interstellar bands in the spectrum of HD 34078

In this paper, we report the very first observation of diffuse interstellar bands (DIBs) that, in the spectrum of HD 34078 (AE Aur), are blueshifted with respect to the normal position that they have in other objects, where the rest-wavelength velocity frame is determined using very sharp interstellar atomic lines or molecular features. Only reasonably narrow DIBs seemingly show this effect, which is absent in broader ones. The result is confirmed independently using three different spectrographs attached to two different telescopes.     

On the identification of the C60+ interstellar features

The identity of the carriers of the diffuse interstellar bands (DIBs) is one of the most fascinating puzzles of modern spectroscopy. Over the last few years the number of known DIBs has grown substantially. In this paper we discuss the two recently discovered near-infrared weak interstellar features which have already been proposed as fingerprints of the buckminsterfullerene We present and discuss measurements of the two related DIBs within a larger sample of reddened targets, observed with different spectrometers, telescopes and site conditions. We provide additional arguments in favour of the interstellar origin of the two bands. We find evidence around the 9577-Å DIB of far-wing structures, which may affect broad-band measurements. We estimate corrections and errors for telluric and stellar blends, and show that the cores of the two DIBs are well correlated with a ratio near unity within 20 per cent. Finally, we discuss their relation to the laboratory spectra of and the search for two expected weaker transitions.     

Correlation patterns between 11 diffuse interstellar bands and ultraviolet extinction

We relate the equivalent widths of 11 diffuse interstellar bands, measured in the spectra of 49 stars, to different colour excesses in the ultraviolet. We find that most of the observed bands correlate positively with the extinction in the neighbourhood of the 2175-Å  bump. Correlation with colour excesses in other parts of the extinction curve is more variable from one diffuse interstellar band to another; we find that some diffuse bands (5797, 5850 and 6376 Å) correlate positively with the overall slope of the extinction curve, while others (5780 and 6284 Å) exhibit negative correlation. We discuss the implications of these results on the links between the diffuse interstellar band carriers and the properties of the interstellar grains.     

Profiles of blue and infrared diffuse interstellar bands

The paper presents a survey of profiles of reasonably strong diffuse interstellar bands (DIBs) based on the extensive set of high-resolution spectra acquired with the aid of echelle spectrographs installed at the 2-m Terskol, 2-m Pic du Midi and 1-m SAO telescopes. The surveyed diffuse interstellar bands cover the spectral ranges of blue and near-infrared, i.e the DIBs not surveyed by Krełowski & Schmidt . The possible modifications caused by stellar and telluric lines are discussed. The very broad features such as 4430 are not discussed because the shapes of their profiles, extracted from echelle spectra, are very uncertain. The signal-to-noise (S/N) ratios of the spectra are not high enough to enable discussion of the profiles of numerous weak interstellar features discovered recently.     

Very high resolution profiles of four diffuse interstellar bands

Ultra-high-resolution  ( R ∼ 300 000)  profiles of four diffuse interstellar bands (DIBs) are presented. The λλ 5797-, 5850-, 6196- and 6379- Å DIBs were observed towards the reddened supergiant HD 24398, a line of sight free of Doppler splitting; thus the observed profiles can be considered as intrinsic to the DIB carriers. Three of the profiles show substructure which supports the hypothesis of a molecular origin for these DIBs.     

The identification of diffuse bands

Our present knowledge of the diffuse interstellar bands (two of which were first noted by Wilson in 1958) is briefly summarized. Other broad and very broad interstellar features (the 220nm extinction bump, the very broad structure in the extinction curve, the extended red emission in reflection and other nebulae, and the unidentified-sometimes called the “overidentified”-infrared bands) are also briefly described. The origins of all these features remain unknown, in spite of intensive study. Possible relations between these various features and families is briefly discussed. Recent observations are shown to support the hypothesis that the carriers of the diffuse bands are free-flying molecules, whereas the alternative hypothesis of dust grains now seems to be untenable. Candidate types of molecular carriers are mentioned, and the possible source of such molecules in the diffuse interstellar medium is briefly discussed.     

Diffuse interstellar band formation in dense clouds

Measurements of the strengths of the diffuse interstellar bands at 4430, 5780 and 5797 Å show that the bands tend to be week with respect to extinction in dense interstellar clouds. Data on 10 stars in the ? Ophiuchi cloud complex show further that the diffuse band-producing efficiency of the grains decreases systematically with increasing grain size. It is concluded that the diffuse bands are not formed in the mantles which accrete on the grains in interstellar clouds, but that they could be produced in the cores of grains or in some molecular species.     

Origin of diffuse interstellar bands: spectroscopic studies of their possible carriers

The results of astrophysical observations that provide evidence for the molecular origin of the diffuse interstellar bands (DIBs) are reviewed. It is established that molecular systems with a linear, planar or spherical carbon skeleton are good candidates as DIB carriers, and laboratory spectroscopic data concerning such systems are discussed. The characteristic features of the electronic spectra of fullerenes, polycyclic aromatic hydrocarbons, and of linear carbon chains and their ions are found to be consistent with the principal spectroscopic features of DIBs. Analysis of the astrophysical electronic spectra of several simple molecules that have so far been assigned indicates that polar molecules should be easier to detect in this way than those without a permanent electric dipole moment.     

Rotational contours of CH2X chain species compared with several diffuse interstellar bands

We have calculated synthetic spectra of perpendicular and parallel rovibronic bands of cumulene carbene molecules of the form C _n H₂. The perpendicular bands are consistent with a regularly spaced group of diffuse interstellar bands (DIBs) near 6850 Å. Parallel bands calculated for these molecular structures are consistent with the intrinsic profile of the associated 6614-Å DIB. Both types of bands are expected for an electronic transition that these species should have at those energies. We could not determine if the molecule was charged or if an atom other than carbon terminated the chain-end. Constraints due to molecular geometry and temperature place the chain length at 7–15 carbons to fit the 6850-Å group and 9–13 carbons to fit the 6614-Å DIB.     

Absorption bands and extinction in small interstellar particles

The production of discrete line and broad-band extinction by small interstellar oxide and silicate particles is discussed quantitatively. Restrictions on particle size and refractive index that are required to produce ‘pure’ absorption features are reviewed. The relationship between optical depth in interstellar extinction and absorption coefficients for bulk materials is used to reach some general conclusions concerning the diffuse interstellar features, VUV extinction and the composition of interstellar dust. It is noted that charge transfer bands of ions such as Fe³⁺ may be detectable in the VUV spectrum of dust. Several effects that lead to the enhancement of oscillator strength by 10³–10⁴ in small particles are discussed.     

Detailed optical spectroscopy of the B[e] Star MWC17

Based on the material of multiple high-resolution R = 60 000 observations conducted on the 6-m telescope (BTA) of the Special Astrophysical Observatory in combination with the Nasmyth Echelle Spectrograph (NES), we closely studied the features of the optical spectrum of the star MWC17 with the B[e] phenomenon. In the wavelength interval of 4050–6750 Å, we identified numerous permitted and forbidden emissions, interstellar Na I lines, and diffuse interstellar bands (DIBs). Radial velocities were estimated from lines of different origin. As the systemic velocity, V_sys, the velocity of the forbidden emissions can be accepted: ?47 kms^?1 (relative to the local standard V_lsr = ?42 kms^?1). Comparison of the obtained data with the earlier measurements allows us to conclude on the absence of considerable variability of spectral details.     

Optical spectrum of the infrared source IRAS 23304+6147

Based on CCD spectra obtained with the PFES echelle spectrometer of the 6-m telescope, we have determined for the first time the effective temperature T _eff=5900 K, surface gravity logg=0.0, and detailed chemical composition of the faint star identified with the infrared source IRAS 23304+6147 by the model-atmosphere method. Its metallicity indicates that the object belongs to the old Galactic disk (the mean abundance of the iron-group elements V, Cr, and Fe for IRAS 23304+6147 is [X/H]=?0.61 dex). The stellar atmosphere exhibits an enhancement of carbon and nitrogen, [C/Fe]=+0.98, [N/Fe]=+1.36, and C/O>1. Significant overabundances of lanthanides were detected: the mean [X/Fe]=+1.04 for La, Ce, Pr, Nd, and Eu. The elemental abundances suggest that the atmospheric chemical composition of IRAS 23304+6147 was modified mainly by nucleosynthesis followed by mixing. By modeling the object's spectrum, we revealed absorption features at the positions of well-known absorption diffuse interstellar bands (DIBs). An analysis of radial-velocity and intensity measurements for these DIBs leads us to conclude that, for IRAS 23304+6147, the DIBs originate mostly in its circumstellar dust envelope expanding at a velocity of about 20 km s^?1. Molecular C₂ Swan emission bands were detected in the object's spectrum, which also originate in the circumstellar envelope. There is a close match between the object's atmospheric effective temperatures determined independently by the model-atmosphere method and by modeling its optical and infrared energy distribution, within the accuracy of the methods.     

Unusual extinction profiles by RAYLEIGH scattering

The extinction efficiencies for small smooth metallic particles (granules) have been calculated using rigorous MIE theory of scattering. Strong size dependent resonances for spheres composed of sodium, potassium, and calcium have been found. The results seem to have relevance to the problems of interstellar grains especially with reference to structures in the observed extinction curve, diffuse bands and anomaly of cosmic abundances of elements.     

Interstellar and circumstellar medium in the direction to IR source IRAS 01005+7910

Using the high-resolution spectra obtained at the 6-meter telescope of the SAO RAS over 2002–2013, we studied the spectral features of the lines of interstellar medium. The radial velocities of the Na I 5890 Å, Na I 5896 Å, Ca II 3934 Å and Ca II 3968 Å absorption lines were analyzed. Seven diffuse interstellar bands 4964, 5780, 5797, 6196, 6203, 6379 Å were identified in the optical spectrum of IRAS01005+7910. Radial velocities V_r and equivalent widths W_λ of these DIBs were measured, for which the values of the interstellar reddening E_B?V and column density of neutral hydrogen log [N(H)] were calculated.     

New in the optical spectrum and kinematic state of the atmosphere of the variable V1027 Cyg (=IRAS 20004+2955)

Based on our high-spectral-resolution observations performed with the NES echelle spectrograph of the 6-m telescope, we have studied the peculiarities of the spectrum and the velocity field in the atmosphere and envelope of the cool supergiant V1027 Cyg, the optical counterpart of the infrared source IRAS 20004+2955. A splitting of the cores of strong absorptions of metals and their ions (Si II, Ni I, Ti I, Ti II, Sc II, Cr I, Fe I, Fe II, BaII) has been detected in the stellar spectrum for the first time. The broad profile of these lines contains a stable weak emission in the core whose position may be considered as the systematic velocity V _sys = 5.5 km s^?1. Small radial velocity variations with an amplitude of 5–6 km s^?1 due to pulsations have been revealed by symmetric low- and moderate-intensity absorptions. A long-wavelength shift of the Hα profile due to line core distortion is observed in the stellar spectrum. Numerous weak CN molecular lines and the KI 7696 Å line with a P Cyg profile have been identified in the red spectral region. The coincidence of the radial velocities measured from symmetric metal absorptions and CN lines suggests that the CN spectrum is formed in the stellar atmosphere. We have identified numerous diffuse interstellar bands (DIBs) whose positions in the spectrum, V _r (DIBs) = ?12.0 km s^?1, correspond to the velocity of the interstellar medium in the Local Arm of the Galaxy.     

Diffuse Interstellar Band at 862 nm as a Reddening Tracer for GAIA

We investigate the plausibility of using diffuse interstellar band at862 nm for tracing interstellar extinction with the ESA's astrometric space mission GAIA. For this purpose we perform numerical tests to simulate the conditions of real observations, covering a wide range of stellar parameters and different amounts of interstellar extinction. Our simulations indicate that with the present Radial Velocity Spectrometer setup the uncertainty in color excess of σ_E(B-V)≤ 0.05 can be achieved only for the interstellar reddening tracers brighter than V ∼ 13. None of the plausible tracers can provide accurate color excesses (σ _E(B-V) ≤ 0.05) at the distances beyond 2 kpc. We therefore conclude that with the currently planned instrumentation onboard GAIA this method can not be used as a stand-alone approach for probing interstellar extinction on the Galactic distance scales within the framework of the GAIA mission. This revised version was published online in July 2006 with corrections to the Cover Date.     

Interstellar Dust in the Solar System

We deduce the mass distribution and total mass density of interstellar dust streaming into the solar system and compare the results to the conditions of the very local interstellar medium (VLISM). The mass distribution derived from in situ measurements shows a gentler slope and includes larger grains, compared to a model distribution proposed for the wavelength dependence of the interstellar extinction. The mass density of grains in the solar system is consistent with that expected from measurements of the visible interstellar extinction and the abundance constraints of elements in the diffuse interstellar medium (ISM), instead of those in the VLISM. This may imply that interstellar dust grains are not associated with the VLISM and that the conditions of the grains are better represented by the ones expected in the diffuse ISM. If this is the case, then the flatter slope in the mass distribution and the detection of larger interstellar grains in the solar system may even indicate that coagulation growth of dust in the diffuse ISM is more effective than previously inferred. This revised version was published online in July 2006 with corrections to the Cover Date.     

Diffuse interstellar bands in low E (B – V) objects

We analyse spectra of slightly reddened, early-type stars in which the major diffuse interstellar bands at 5870 and 5797 Å are either strong or weak in relation to E(B – V) . It is demonstrated that among the low E(B – V) objects one can find stars obscured by 'sigma' as well as 'zeta' type clouds. The profiles of the diffuse bands seem not to be dependent on the total opacities of the interstellar clouds. We also discuss the physical conditions leading to the formation of the diffuse band carriers in low-opacity interstellar clouds; the carriers are apparently formed in media in which one can observe complex velocity fields.     

On a vibronic origin for the diffuse band spectrum

Duley (1982) has proposed that many of the diffuse interstellar bands in the wavelength interval 677 nm>λ>542 nm arise from vibronic transitions of Cr³⁺ ions in MgO grains. No explanation has been offered for the fact that as many as 85 of the possible 108 transitions of this system have not been observed in the interstellar medium. Moreover, the relative intensities of the diffuse bands which are observed appear to be inconsistent with their assignment. We therefore conclude that this model is not consistent with the observations.