Comparison of copper speciation in the Zhujiang River Estuary between summer and winter:implication for upwelling current

The contents of total copper, total dissolved copper, particulate copper, and free ion copper in the Zhujiang River Estuary were investigated in July 2002 and January 2003 respectively, and the spatial distribution trend of these species of copper were compared in two cruises. It was found that, in summer, the total copper content in the Zhujiang River Estuary increased with salinity, while the content office ion copper decreased with salinity. However, in winter, the contents of total copper and free ion copper both decreased with salinity. So, it could be concluded that, copper content and speciation in the Zhujiang River Estuary were regulated by other factors than runoffdiffusion such as upwelling current. In order to prove the spatial trend of rice ion copper content in the Zhujiang River Estuary, the cultivation of Dunaliella tertiolecta in waters obtained from sampling stations with different salinities was carried out, and the copper uptake by algae cells was measured then. It was found that, the cells＇ uptake of copper increased with rice ion copper, not the content of total copper.     

Distributional characteristics of grain sizes of surface sediments in the Zhujiang River Estuary

Distributions of the parameters of sedimentary grain sizes and their correlations were studied to trace the sources of silts and their movement trends in the Zhujiang River Estuary based on the analyses of grain sizes from more than 1080 sedimentary samples. The distributions of the median diameter, public value, quartile deviation, and skewness of sediments were complex in the Zhuiiang River Estuary mainly because of the impact of the matter source regions, distances from the source regions, and hydrodynamic conditions, such as waves, tidal currents, and coastal currents. Analyses of the parameters of the grain sizes for the various types of sediments showed that the distributions of the surface sediments in the Zhujiang River Estuary were controlled by many factors. Their matter sources were mainly the sediments discharged from the runoffs and ebb tidal currents, and from the open sea. The sediments mainly moved by suspension movement. The silts formed a large area of sediments with suspended fine silts in the Zhujiang River Estuary by internal adjustment transportation in the area, and moved toward the western coast of the Zhujiang River Estuary under the effect of Coriolis forces and coastal currents.     

FLOCCULATION OF DISSOLVED Fe, Al, Mn, Si, Cu, Pb AND Zn DURING ESTUARINE MIXING

This is the first study of the flocculation of dissolved Fe, Al, Mn, Si, Cu, Pb and Zn during mixing in Zhujiang Estuary, based on the experiment on a series of solutions of salinities ranging from 0 to 24 by mixing the Zhujiang water near Zhongshan University and the seawater in Wan-shan Archipelago area. The mechanism of flocculation of the 7 elements is explored, and the effects of time, acidity and temperature on flocculation are discussed. The results show that the flocculation rates of Fe and Pb in the Zhujiang water are almost a hundred per cent, while that forCu reaches 76%; for Mn, 51%; for Al, 48%; for Zn, 28%; and for Si, 1.2%, indicating that Si is conservative.     

Preliminary study of the retention mechanism of planktonic copepods in the Jiulong Estuary in China

The horizontal and vertical distribution patterns of five planktonic copepods,Calanus sinicus, Acartia pacifica, Tortanus derjugini, Acartiella sinensis and Pseudodiaptomus poplesia, predominant in the Jiulong Estuary, were investigated from May 2003 to April 2004. The results showed that the distribution of these copepods was related to the tidal period but that each species had its own specific pattern. C. sinicus showed no tidal vertical migration behavior and was thought to be a non-resident species in this estuary. Among Acartia pacifica,T. derjugini,Acartiella sinensis, more individuals occurred in the surface than in the bottom waters during flood tide, and the pattern was reversed during ebb tide. The epibenthic copepod P. poplesia usually remained in the bottom waters in the upstream part of the estuary, but it displayed strong tidally-oriented vertical migration in the middle reaches of the estuary.Taking into account the hydrographic characteristics of the Jiulong Estuary,it was hypothesized that the planktonic copepods in this estuary had more or less adopted the mechanism of vertically migrating to the surface waters during flood tide in order to make use of the inflowing tide, and then sinking to the bottom during ebb tide to avoid being carried out of the estuary by net outflow.     

Environmental monitoring of the Zhujiang Estuary and its coastal waters

The Zhujiang (Pearl River) Estuary is a complex water system whose catchments basincovers a very large part of southern China. The large quantity of fresh water carried by the river system flows into the northern coast of the South China Sea through its eight inlets. The Zhujiang River Delta has experienced the fastest economic growth in China during the past two decades. Rapid population expansion and increased industrial development coupled with insufficient waste management turned the Zhujiang Estuary into waste disposal channels just before entering the coastal waters. The water quality of the estuaries and the coastal oceans has become polluted. During the past two years, an intensive study and monitoring efforts of the pollutions of these waters have been made. A systematic and integrated monitoring task including shore-based measurements, shipboard in-situ measurements, and satellite and radar remote sensing surveys has been completed. Comprehensive collection of physical, chemical and biological     

Three-dimensional structure of a low salinity tongue in the southern Taiwan Strait observed in the summer of 2005

Cruise observations with CTD (conductivity-temperature-depth) profiler were carried out in the southern Taiwan Strait in the summer of 2005. Using the cruise data, two-dimensional maps of salinity and temperature distributions at depths of 5, 10, 15, 20, and 30 m were generated. The maps show a low salinity tongue sandwiched by low temperature and high salinity waters on the shallow water side and high temperature and high salinity waters on the deep water side. The further analysis indicates that the low salinity water has a nature of river-diluted water. A possible source of the diluted water is the Zhujiang (Pearl) Estuary. Meanwhile, the summer monsoon is judged as a possible driving force for this northeastward jet-like current. The coastal upwelling and the South China Sea Warm Current confine the low salinity water to flow along the central line of the strait. Previous investigations and a numerical model are used to verify that the upstream of the low salinity current is the Zhujiang Estuary. Thus, the low salinity tongue is produced by four major elements:Zhujinag Estuary diluted water, monsoon wind driving, coastal upwelling and South China Sea Warm Current modifications.     

Study of radioactive status in the Zhujiang Estuary and adjacent sea area in South China Sea (SCS)

Through the investigation on radioactive activities of water, sediment and some marine organismsin the Zhujiang Estuary, adjacent sea area and the distributary mouths of the Zhujiang River, activities of total α. radioactivity, total β radioactivity, artificial radioactive 90Srand 157Cs, and factors inflencing the distribution and the content of U in seawater are studied.The mainly radioactive pollution substances and their sources in the sea area are studied by γ spectra obtained from sediment in the sea area. The results show that the main radioactivity substances are natural radioactivity U,Th series and 40K. which were produced by the modern industry and transported into the sea through the main current of the Zhujiang River.     

Tidal Bore Dynamics Around the Similar Right-Angle Shoreline in the Qiantang Estuary,China

Tidal bores are a unique hydrodynamic phenomenon during flood tide in the Qiantang Estuary. The tidal bore propagation around the similar right-angle shoreline is rarely documented in tidal estuaries. To investigate tidal bores around this shoreline, a hydrodynamic model combined with a theoretical method is employed to reveal the characteristics of the bore propagation. The theoretical solution of the tidal bore intensity is deduced to illustrate the relationship of the incident tidal bores and...     

Investigation of saltwater intrusion and salinity stratification in winter of 2007/2008 in the Zhujiang River Estuary in China

Saltwater intrusion is a serious environmental problem in the Zhujiang River Estuary(ZRE),which threatens the water supply of fifteen million people.The hydrological observations as well as meteorological and tidal forcing in the winter of 2007/2008 were analyzed to examine the saltwater intrusion in the ZRE.The observational results suggest that the maximum vertical difference of salinity can reach 10 in the Humen Channel during neap tide,but is very small in the Hengmen Channel.The vertically averaged salinity from time series stations during spring tide is higher than that during neap tide.A three-dimensional finite difference model was developed based on the environmental fluid dynamic code(EFDC) to study the mechanism of saltwater intrusion and salinity stratification in the ZRE.By analyzing the salt transport and the temporal variation of saltwater intrusion,the authors found that the net salt transport due to the estuarine circulation during neap tide was more than that during spring tide.This caused salt to advance more into the estuary during neap tide.However,saltwater intrusion was stronger during spring tide than that during neap tide because the spring-neap variation in salt transport was small relative to the total length of the saltwater intrusion.The physical mechanism causing this saltwater intrusion was investigated by a series of sensitivity experiments,in order to examine saltwater intrusion in response to river discharge and winds.The freshwater source was a dominant influencing factor to the saltwater intrusion and controlled salinity structure,vertical stratification and length of the saltwater intrusion.The prevailing northeast monsoon during winter could increase the saltwater intrusion in the ZRE.Though the southwest wind was unfavorable to saltwater intrusion during spring tide,it could increase stratification and saltwater intrusion during neap tide.     

Variation of reactivity of particulate and sedimentary organic matter along the Zhujiang River Estuary

To investigate organic matter source and reactivity in the Zhujiang River (Pearl River)Estuary and its adjacent areas, particulate organic carbon (POC), particulate hydrolysable amino acids (PHAA), and Chl a during two cruises in July 1999 and July 2000 were measured. The highest POC and PHAA concentration was observed in the waters with maximum Chl a. The spectra distribution,relative content (dry weight in milligram per gram), PHAA-C% POC and other indicators such as the ratios of amino acids vs. amino sugars (AA/AS) and glucosamine vs. galactosamine (Glum/Gal) suggested that particulate amino acids in the water column and sediments in the Zhujiang River Estuary were mainly derived from biogenic processes rather than transported from terrestrial erosion. In inner estuary where high turbidity was often observable, organic matter was mainly contributed by re-suspension of bottom sediments with revealed zooplankton, microbial reworked characteristics, which suggest that these organic matters were relatively “old“. In the estuarine brackish region, organic matter in water column is mainly contributed by relatively fresh, easily degradable phytoplankton derived organic matter.During physical - biological processes within the eastuary, organic matter derived from phytoplankton was subjected to alteration by zooplankton grazing and bacterial reworking.     

Impact of the eastern water diversion from the south to the north project on the saltwater intrusion in the Changjiang Estuary in China

The south to the north project(WDP) on the saltwater intrusion in the Changjiang Estuary is studied by the improved three-dimensional(3D) numerical model.The net unit width flux in the Changjiang Estuary as well as the sectional salt flux is calculated in the North Branch(NB),the South Branch(SB),the North Channel(NC),the South Channel(SC),the North Passage(NP) and the South Passage(SP),respectively.The net seaward water flux in the SB is reduced,and the net water flux spilling over from the NB to the SB is enhanced after the eastern WDP.Under the mean river discharge condition in the dry season,the net salt flux spilling over from the NB to the SB is increased by 2.09 t/s and 0.52 t/s during the spring and neap tides,respectively,due to the eastern WDP.The saltwater intrusion in the Changjiang Estuary is enhanced by the eastern WDP.Compared with that during the spring tide,the net water diversion ratio during the neap tide in the NC is smaller,and thus the enhancement of the saltwater intrusion by the eastern WDP is smaller in the NC,and larger in the NP and the SP.The tidally averaged surface salinity at the water intakes of the Dongfengxisha Reservoir,the Chenhang Reservoir and the Qingcaosha Reservoir rises both during the spring and neap tides.     

Atmosphere-ocean interaction and teleconnection in the Northern Pacific during the cold season

On the basis of the idea in our work (Jiang and Wallace, 1991) , the horizontal structure of SST pattern, the atmospheric response to SST change and the atmospheric forcing of the ocean in the Northern Pacific during the cold season are discussed. The results show that PNA pattern is the most prominent normal mode in the atmosphere-ocean interaction in the Northern Pacific during the cold season.     

我国瓯江口和珠江口凤鲚洄游模式和生境利用研究

Habitat use of the tapertail anchovy(Coilia mystus Linnaeus, 1758) from the Oujiang River Estuary and the Zhujiang(Pearl) River Estuary was studied by examining the environmental signatures of Sr and Ca in otoliths using electron probe microanalysis. Individuals from the Oujiang River had higher and varied Sr:Ca ratios(expressed as(Sr:Ca)×1 000, 3.83–13.0 average) in the otolith core regions, suggesting that they were born in brackish or sea waters, and that a freshwater habitat might not be necessary for egg hatching and larval growth.While, individuals from the Zhujiang River had lower Sr:Ca ratios(0.39–2.51 average) in the core regions,suggesting a freshwater origin. After hatching, anchovies from the Zhujiang River migrate downstream to the river estuary close to brackish water. Our results demonstrated varied habitat use for spawning during stages of early life history between the two populations, and suggested that such variations are promoting diversity of life history strategies of this species.     

Impacts of channel dredging on hydrodynamics and sediment dynamics in the main channels of the Jiaojiang River Estuary in China

Channel dredging in estuaries increases water depth and subsequently impacts sediment dynamics and morphology. The Jiaojiang River Estuary is dredged frequently owing to heavy shipping demands. In this study,the effects of different dredging schemes on siltation were assessed through numerical modeling. The sediment model of the Jiaojiang River Estuary utilized an optimized bottom boundary layer model that considered the bed sediment grain size and fluid mud, and this model was calibrated using ...     

Relationship between suspended sediments from the Changjiang Estuary and the evolution of the embayed muddy coast of Zhejiang Province

South of Hangzhou Bay, Zhejiang Province, exhibits an embayed muddy coastline, with the muddy beaches of embayments extending continuously seaward.The source of sediments on this coast presents an interesting problem to marine geologists and geomorphologists .The total annual load of sediments from the rivers of Zhejiang is only 12×106t.These materials affect only the area near the river mouths. The paper showed that the sediment along the coast of Zhejiang mainly comes from the Changjiang Estuary through analysing the time and space variations of suspended sediment, the features of sediment and the sedimentary transport.The Changjiang River is the largest river system in China, its sediment to the sea amounting to 468×106t. The sediment during summer transports mainly eastward, and is affected by the water body with high temperature, salinity and transparency; the winter season is the period with high sediment concentration. The sediment of the Changjiang Estuary transports together with the longshor     

The study on three-dimensional numerical model and fronts of the Jiulong Estuary and the Xiamen Bay

Applying the methods of on-site observation and dynamic model, the research on the fronts at the Jiulong Estuary has been carried out, during which spatial and temporal distribution, dynamic characteristics and formation mechanism of salinity fronts are analyzed and discussed. The research shows that the estuarine fronts mainly lie in the area from the Jiyu Islet to the Haimen Island, outside of Yuweizai to Hulishan cross-section, the near coast of Yuweizai and the south of the Songyu-Gulangyu Channel. The fronts in the former two regions are formed directly by plume, while the one near the coast of Yuweizai is a tidal intrusion front caused by flood current and the one at the south of the Songyu-Gulangyu Channel is the result of current shear transformation. Under normal circumstances, fresh water of the Jiulong River mainly influences the inside of the Xiamen Bay, and when it is in typhoon seasons, plume front can affect the Taiwan Strait and has an effect on the biogeochemical processes in the strait.     

Numerical study on residual current and its impact on mass transport in the Hangzhou Bay and the Changjiang Estuary Ⅰ.A3-D joint model of the Hangzhou Bay and the Changjiang Estuary

A 3-D numerical model is set up in a large domain covering the Hang zhou Bay and the Changjiang Estuary based on the ECOM model in orthogonal curvilinear coordinates.The numerical schemes for baroclinic pressure gradient (BPG) terms and convective terms are improved in the paper according to the characteristics of velocity field and mass transport in the area.The model is validated by the simulations of residual current and salinity transport in the Hangzhou Bay and the Changjiang Estuary.     

长江口最大浑浊带潮周期内悬浮物中的重金属

In order to discuss the content distributions and fluxes of heavy metals in suspended matters during a tidal cycle in the turbidity maximum around the Changjiang(Yangtze) Estuary,the contents of heavy metals(Zn,Pb,Cd,Co and Ni) have been analyzed.During a tidal cycle,the average contents of heavy metals are in the order of ZnNiPbCo àCd.The average contents in ebb tide are generally higher than that in flood tide.However,at the inshore Sta.11,influenced by the contamination from the nearby waste treatment plant,the average contents of Zn and Ni in flood tide are higher than those in ebb tide and at the offshore Sta.10,the content of Cd in flood tide higher than that in ebb tide due to marine-derived materials.The five heavy metals,mainly terrigenous,are transported towards east-northeast,and settle down with suspended matters in the area between Sta.11 and Sta.10.Influenced by marine-derived materials,the flux value of Cd does not alter significantly with obviously changing in flux direction towards northwest.The source of heavy metals,the salinity of water and the concentration of suspended matters are the main factors controlling the content distributions of heavy metals during a tidal cycle.There is a positive correlation between the contents of heavy metals(Zn,Pb,Co and Ni) and the salinity of water,while the opposite correlation between the contents and the concentrations of suspended matters.Because of marine-derived materials,the content of Cd is not correlated with the concentration of suspended matters and the salinity of water.     

A model study of influence of circulation on the pollutant transport in the Zhujiang River Estuary and adjacent coastal waters

A tracer model with random diffusion coupled to the hydrodynamic model for the Zhujiang River Estuary (Pearl River Estuary, PRE) is to examine the effect of circulations on the transport of completely conservative pollutants. It is focused on answering the following questions: (1) What role does the estuarine plume front in the winter play in affecting the pollutants transport and its distribution in the PRE? (2) What effect do the coastal currents driven by the monsoon have on the pollutants transport? The tracer experiment results show that: (1) the pollutant transport paths strongly depend on the circulation structures and plume frontal dynamics of the PRE and coastal waters; (2) during the summer when a southwesterly monsoon prevails, the pollutants from the four easterly river inlets and those from the bottom layer of offshore stations will greatly influence the water quality in Hong Kong waters, however, the pollutants released from the four westerly river-inlets will seldom affect the water quality of Hong Kong waters due to their transport away from Hong Kong; (3) during the winter when a northeasterly monsoon prevails, all pollutants released from the eight river gates will be laterally transported seaward inside the estuary and transport westward in the coastal waters along the river plume frontal zone. However, pollutants released from the surface layer of offshore stations near or east of the Dangan Channel will be carried into the coastal waters of Hong Kong by the landward component of the westward coastal current driven by the winter northeasterly monsoon. But the pollutants from the bottom layer of the offshore stations will be carried away from the offshore by the bottom flow driven by the northeasterly monsoon. This implies that only surface-released matter from offshore stations will affect the water quality of the coastal waters around Hong Kong during the winter when a northeasterly monsoon prevails.     

商业平板式超滤膜包完整性检验：对海洋胶体生物地球化学研究的启示

The performance and integrity of a cassette cross-flow ultrafilter(Pellicon 2, Millipore) are examined with a suite of macromolecules of different molecular masses. The retention coefficient during the cross-flow ultrafiltration experiments increases with increasing molecular mass and reaches 90% with 10 kDa dextran in both milli-Q water and ultrafiltered seawater media. Based on a 90% retention coefficient, the molecular mass cut-off for the ultrafiltration membrane is defined at 10 kDa, which is ten times(1 kDa) that rated by the manufacturer. To further validate the accuracy of the laboratory calibration, the samples from the lower Zhujiang River and the Jiulong River Estuary are ultrafiltered with the cassette ultrafiltration membrane and the colloidal organic carbon abundances in these samples are quantified with the ultrafiltration permeation model based on time series permeation subsamples. The colloidal organic carbon abundances are 5.8%–21.1% in the Jiulong River Estuary and 5.6%–11.0% in the lower Zhujiang River. These are consistent with the reported values for both estuaries as well as with the colloidal organic carbon abundances in marine environments over the coastal and open oceans with 10 kDa cut-off membranes. Therefore, these field data support the laboratory calibration result and indicate the validity of the experimental and quantification procedure adopted. The discrepancy between the nominal molecular mass cut-off and the actual pore size of the ultrafiltration membrane should be of great concern for research in colloidal and nanoparticle biogeochemistry. Careful examination of the membrane integrity should be taken during ultrafiltration experiments in order to avoid misleading molecular mass cut-off information.