Diagenesis and reservoir quality of sandstones with ancient “deep” incursion of meteoric freshwater——An example in the Nanpu Sag,Bohai Bay Basin,East China

An example of diagenesis and reservoir quality of buried sandstones with ancient incursion of meteoric freshwater is presented in this study. The interpretation is based on information including porosity and permeability, petrography, stable isotopic composition of authigenic minerals, homogenization temperatures (T_h) of aqueous fluid inclusions (AFIs), and pore water chemistry. These sandstones, closely beneath or far from the regional unconformity formed during the late Paleogene period, are located in the thick Shahejie Formation in the Gaoliu area of Nanpu Sag, Bohai Bay Basin, East China. Early-diagenetic calcite cements were leached to form intergranular secondary pores without precipitation of late-diagenetic calcite cements in most sandstones. Feldspars were leached to form abundant intragranular secondary pores, but with small amounts of concomitant secondary minerals including authigenic quartz and kaolinite. The mass imbalance between the amount of leached minerals and associated secondary minerals suggests that mineral leaching reactions occurred most likely in an open geochemical system, and diagenetic petrography textures suggest that advective flow dominated the transfer of solutes from leached feldspars and calcites. Low salinity and ion concentrations of present pore waters, and extensive water rock interactions suggest significant incursion of meteoric freshwater flux in the sandstones. Distances of the sandstones to the regional unconformity can reach up to 1800 m, while with significant uplift in the Gaoliu area, the burial depth of such sandstones (below sea level) can be less than 800–1000 m during the uplift and initial reburial stage. Significant uplift during the Oligocene period provided substantial hydraulic drive and widely developed faults served as favorable conduits for downward penetration of meteoric freshwater from the earth's surface (unconformity) to these sandstone beds. Extensive feldspar leaching has been occurring since the uplift period. Coupled high T_h (95∼115 °C) of AFI and low δ¹⁸O_(SMOW) values (+17∼+20‰) within the quartz overgrowths show that quartz cementation occurred in the presence of diagenetic modified meteoric freshwater with δ¹⁸O_(SMOW) values of −7∼−2‰, indicating that authigenic quartz only have been formed during the late reburial stage when meteoric fresh water penetration slowed down. Secondary pores in thin sections and tested porosity suggest that meteoric freshwater leaching of feldspars and calcite minerals generated approximately 7–10% enhanced secondary porosity in these sandstones. Meteoric freshwater leaching reactions cannot be ignored in similar sandstones that located deep beneath the unconformity, with great uplift moving these sandstones above or close to sea level and with faults connecting the earth's surface with the sandstone beds.     

Provenance of gravity-flow sandstones from the Upper Jurassic–Lower Cretaceous Farsund Formation,Danish Central Graben,North Sea

Through the Upper Jurassic and Lower Cretaceous gravity-flow sandstones were deposited in the Danish Central Graben. These gravity-flow sandstones were deposited within mudstones of the Farsund Formation which is the main source rock in the area, and they are thus potential oil and gas reservoirs. The petrography and geochemistry of the sandstones show good intra well relations and several local geographical relations, which may indicate that they were derived from multiple locally sourced flows and not merely by one basin-axial flow system. The gravity-flow sandstones deposited in the eastern part of the basin are less mature and richer in, especially, carbonates and albite compared to previously deposited Jurassic sandstones and simultaneously deposited sandstones in the western part of the Danish area. This may indicate a division of the basin in an eastern and a western provenance province. This study addresses the provenance of the gravity-flow sandstones by petrographical and geochemical analyses in order to derive possible shared detrital sources as a means of understanding the transport system(s) of the gravity flows.     

Organic geochemical identification of reservoir oil–gas–water layers in the Junggar Basin,NW China

The identification of reservoir oil–gas–water layers is a fundamental task in petroleum exploration and exploitation, but is difficult, especially in cases of complex hydrocarbon migration and accumulation. In such cases, hydrocarbon remigration and dysmigration take place very commonly, leading to the presence of residual or paleo-oil accumulations and layers, which cannot be easily identified or misinterpreted as oil layers by conventional logging and geophysical data. In this paper, based on a case study in the Luxi area of the central Junggar Basin, NW China, we seek to characterize such layers in terms of organic geochemistry. We suggest specific indicator parameters of organic geochemistry such as the chloroform bitumen content of reservoir extracts, which is usually >1.0% in oil layers. We explore the application of grains containing oil inclusions (GOI) (the ratio of mineral grains containing oil inclusions to the total number of mineral grains) for the identification of oil–gas–water layers in the Junggar Basin for the first time; this method has been used elsewhere. The maximum GOI values for the oil layers, oil–water layers, water layers and dry layers are >11%, 7%–11%, 6%–7% and <6%, respectively. In addition, gas layers and heavy-oil layers that are difficult to identify by conventional organic geochemical parameters were identified using biomarkers. The typical characteristics of the soluble reservoir bitumen in the gas layers include a much greater abundance of tricyclic terpanes (two times in general) relative to pentacyclic terpanes and a tricyclic terpane distribution of C₂₀ > C₂₁ > C₂₃. In contrast, the typical characteristic of the heavy-oil layers is the presence of 25-norhopanes in reservoir bitumen extracts. These specific indicators can be applied in the Junggar Basin and in similar settings elsewhere.     

Diagenesis and reservoir properties of Middle Jurassic sandstones,Traill Ø, East Greenland: The influence of magmatism and faulting

The c. 500 m thick Middle Jurassic sandstones of the fluvial Bristol Elv and marine Pelion Formations of the East Greenland Basin are evaluated here in order to improve the understanding of the processes that influenced the diagenetic evolution. The study may help to predict the reservoir properties of sandstones affected by magmatism and faulting, both in general and specifically in undrilled areas on- and offshore East Greenland and, in the Vøring Basin on the Mid-Norwegian shelf. The study shows a variety of authigenic mineral phases dominated by quartz cement, carbonate cement, illite and iron-oxide. One of the clear differences between the two formations is the presence of early carbonate-cemented horizons in the marine sandstones; these horizons are inferred to reflect a primary concentration of biogenic clasts and fossil shells. Intense quartz cementation occurs primarily in the fluvial sandstones but the marine sandstones are also highly quartz-cemented. Two episodes of burial and uplift are recorded in the diagenetic sequence and widespread grain-crushing in coarse-grained intervals is believed to result from overpressure and subsequent compaction due to sudden pressure release along major faults. Maximum burial depths may only have been around 2000–2500 m. Cathodoluminescence analyses show that grain crushing was followed by intense quartz cementation. The quartz cement is to a great deal believed to have formed due to increased surface area from crushing of detrital quartz grains, creating fresh nucleation sites for the quartz. Cathodoluminescence investigations also show that only minor pressure dissolution has taken place between detrital quartz grains and that the ubiquitous quartz cementation displays several growth zones, and was thus in part the result of the introduction of silica-rich extra-formational fluids related to the flow of hot fluids along reactivated faults and increased heat flow and temperature due to magmatism. This interpretation is supported by fluid inclusion homogenization temperatures between 117 and 158 °C in quartz cements. In one of the two study areas, the development of macroscopic stylolites has significantly enhanced quartz cementation, probably in connection with thermal convection flow. As a result of the magmatic and fault-related quartz cementation and illitization, the reservoir quality of the sandstone formations deteriorated and changed drastically.     

Coalbed methane reservoirs’ pore-structure characterization of different macrolithotypes in the southern Junggar Basin of Northwest China

Coalbed methane (CBM) development in the southern Junggar Basin of Northwest China has aroused extensive attention owing to its significant resource potential. The accurate characterization of coal pore structure is important for CBM exploration and production. In order to explore the relationship between coal pore structure and macrolithotype, which has rarely been studied in the southern Junggar Basin, a series of laboratory experiments were performed on eight samples of different macrolithotypes. The results show that the porosity exhibits regularity with macrolithotype in the order bright < semibright < semidull < dull, and also shows an increase with the rise of the inertinite content. The pore-size distribution results show that the dominating pores of bright and semibright coals are usually greater than that of dull and semidull coals in size. The pore-type analysis indicates that the bottleneck pores (Type B) are well developed in dull and semidull coals, while bright and semibright coals mainly host two sides (Type A), namely opened pores and one-side-closed pores (Type C). The pore-type and -size distribution strongly affect pore connectivity refers to the facts that: 1) the proportion of effective porosity increases with an increasing proportion of pores greater than 100 nm in size; and 2) that the mercury withdrawal efficiency is always lower when the pores are mostly of Type B. So the pore connectivity of semibright and bright coals is higher than that of semidull and dull coals. Furthermore, pores are developed mainly in the inertinite, with pore-type being dominated by Type B and C, secondly in the vitrinite, with pore-type being dominated by Type A and C, and less developed in the liptinite with pore-type of B and C. The pore connectivity of each maceral is in the order vitrinite > inertinite > liptinite. Finally, according to the research results, the reservoir fracturing improvement should be more arranged on the dull or semi-dull coals, and the producing layers should be bright or semi-bright coals as much as possible on the premise that the gas contents of coal layers are not much different from each other.     

Prediction of diagenetic facies using well logs – A case study from the upper Triassic Yanchang Formation,Ordos Basin,China

Understanding diagenetic heterogeneity in tight sandstone reservoirs is vital for hydrocarbon exploration. As a typical tight sandstone reservoir, the seventh unit of the Upper Triassic Yanchang Formation in the Ordos Basin (Chang 7 unit), central China, is an important oil-producing interval. Results of helium porosity and permeability and petrographic assessment from thin sections, X-ray diffraction, scanning electron microscopy and cathodoluminescence analysis demonstrate that the sandstones have encountered various diagenetic processes encompassing mechanical and chemical compaction, cementation by carbonate, quartz, clay minerals, and dissolution of feldspar and lithic fragments. The sandstones comprise silt-to medium-grained lithic arkoses to feldspathic litharenites and litharenites, which have low porosity (0.5%–13.6%, with an average of 6.8%) and low permeability (0.009 × 10⁻³ μm² to 1.818 × 10⁻³ μm², with an average of 0.106 × 10⁻³ μm²).This study suggests that diagenetic facies identified from petrographic observations can be up-scaled by correlation with wire-line log responses, which can facilitate prediction of reservoir quality at a field-scale. Four diagenetic facies are determined based on petrographic features including intensity of compaction, cement types and amounts, and degree of dissolution. Unstable and labile components of sandstones can be identified by low bulk density and low gamma ray log values, and those sandstones show the highest reservoir quality. Tightly compacted sandstones/siltstones, which tend to have high gamma ray readings and relatively high bulk density values, show the poorest reservoir quality. A model based on principal component analysis (PCA) is built and show better prediction of diagenetic facies than biplots of well logs. The model is validated by blind testing log-predicted diagenetic facies against petrographic features from core samples of the Upper Triassic Yanchang Formation in the Ordos Basin, which indicates it is a helpful predictive model.     

Controls on regional variability in marine pore-water diagenesis below the seafloor in Upper Jurassic–Lower Cretaceous prodeltaic sandstone and shales,Scotian Basin,Eastern Canada

Diagenesis in the uppermost Jurassic to Lower Cretaceous deltaic sandstones and shales of the Scotian Basin is an important control on reservoir quality. Ferruginous zone (sub-oxic) marine pore-water diagenesis controls the initial formation of Fe²⁺-silicates that are the precursors of grain-rimming chlorite that preserves porosity. This study assesses the regional controls on the type of marine pore-water diagenesis by studying the sedimentology, mineralogy, and geochemistry of the retrogradational units and underlying progradational units in parasequences from conventional cores in two wells in different parts of the basin. Coated grains preserve a record of whether marine pore-water diagenesis below the seafloor was dominantly in the ferruginous or sulphidic geochemical zone. Four types of coated grain were distinguished, each with a different mineral paragenesis. Mineralogical and chemical evidence of ferruginous zone diagenesis includes the presence of diagenetic chlorite and siderite, and the correlation of P with Fe or Ti. Pyrite and Fe-calcite are found where the sulphidic zone is more significant than the ferruginous zone. Ferruginous zone diagenesis was common in low-sedimentation rate retrogradational sediments with low organic carbon, and in delta-front turbidites and river-mouth sandstones. Estuarine, tidal flat and prodeltaic facies that are directly supplied by riverine sediments have a lower Fe:Ti ratio than do fully marine shoreface and open shelf facies as a result of input of detrital ilmenite and its alteration products. The relative contribution of colloidal iron (hydr)-oxides appears greater in distal low-sedimentation rate environments. Where large changes in sedimentation rate occurred at ravinement surfaces, the underlying progradational rocks have evidence of ferruginous zone diagenesis, whatever their facies. Rapid upward migration of the pore-water profile resulting from the change in sedimentation rate reduced the time available for mineral products to form in the deeper pore-water zones. This study has shown that the availability of Fe and organic carbon varying in a complex manner in marine deltaic sediments, but that the resulting diagenesis by marine pore-water can be predicted from facies and paleogeographic setting.     

Diagenetic evolution of the upper Cretaceous limestone and sandstone exhumed reservoirs in the western Basque–Cantabrian Basin,North Spain

The Basque–Cantabrian Basin (NE Spain) has been considered one of the most interesting areas for hydrocarbon exploration in the Iberian Peninsula since the 60th to 70th of last century. This basin is characterized by the presence of numerous outcrops of tar sands closely associated with fractures and Triassic diapirs. The aims of this work is to establish the diagenetic evolution of the Upper Cretaceous reservoir rocks with special emphasis in the emplacement of oil and their impact on reservoir quality. The studied rocks are constituted of carbonates and sandstones that contain massive quantities of bitumen filling vugs and fractures.Petrographic results indicate that the carbonate rocks from Maestu outcrops are bioclastic grainstones and wackestones, whereas the tar sandstones from Atauri and Loza outcrops are dominated by quartzarenites and subordinated subarkoses. The paragenetic sequence of the main diagenetic phases and processes include, pyrite, bladed and drusy calcite cement, calcite overgrowths, silicification of bioclasts and microcrystalline rhombic dolomite cement, and first stage of oil emplacement, blocky calcite cement, coarse crystalline calcite cement, calcitized dolomite, calcite veins, saddle dolomite and stylolites filled by the second phase of oil entrance. Together with the above mentioned diagenetic alterations, the arenites are affected by early kaolinitization of feldspars and the scarce formation of clay rim and epimatrix of illite. All sandstones and dolomitized carbonate rocks show high intercrystalline and intergranular porosity which is full by biodegraded hydrocarbons (solid bitumen). The biodegradation affects alkanes, isoprenoids and partially hopanes and steranes saturated hydrocarbons. Aromatics hydrocarbons, like naphthalenes, phenanthrenes, dibenzothiophenes and triaromatics are also affected by biodegradation. Results indicate that the first HC emplacement corresponds to early stage of calcite and dolomite cementation, and the second and more important emplacement is related to fracturation processes resulting in the formation of excellent reservoirs.     

A Report about the Seminar on the Development of Port and Coast in the Mainland and Taiwan of China, Nanjing, China

The Seminar on the Development of Port and Coast in the Mainland and Taiwan was heldfrom October 15th to 20th, 1993 in Hohai University, Nanjing, China, under the sponsorship ofHohai University and National Cheng Kung University, Tainan, and under the co-sponsorshipof Nanjing Hydraulic Research Institute and Jiangsu Society of the Mainland and Taiwan Rela-tionship. The aim of the Seminar is to strength the academic exchanges in the fields of port andcoastal engineering, to promote cooperation in science and technology, to benefit the develop-ment of construction as well as science, technology and education in port and coastal engi-neering in the Mainland and Taiwan of China. The main topics covered are in four aspects:     

Structural development and tectonic evolution of Gunsan Basin (Cretaceous–Tertiary) in the central Yellow Sea

This study analyzes the structural development of the Gunsan Basin in the central Yellow Sea, based on multi-channel seismic reflection profiles and exploratory well data. The basin comprises three depressions (the western, central, and eastern subbasins) filled with a thick (ca. 6000 m) Cretaceous to Paleogene nonmarine succession. It was initiated in the early Cretaceous due to intracontinental extension caused by oblique subduction of the Izanagi plate under the Eurasian plate and sinistral movement of the Tan-Lu fault. The basin appears to have undergone transtension in the late Cretaceous–Eocene, caused by dextral movement of the Tan-Lu and its branching faults. The transtension was accommodated by oblique intra-basinal normal faults and strike-slip (or oblique-slip) movement of a NE-trending bounding fault in the northern margin of the central subbasin. The entire basin was deformed (NE–SW contraction) in the Oligocene when tectonic inversion occurred, possibly due to the changes in strike-slip motion, from right- to left-lateral, of the Tan-Lu fault. During the early Miocene, extension resumed by reactivation of the pre-existing normal and transpressional faults. A combination of extension, uplift, and erosion resulted in differential preservation of the early Miocene succession. At the end of the early Miocene, extension ceased with mild contraction and then the basin thermally subsided with ensued rise in sea level.     

Variability of the circulation in the southern Huanghai Sea and East China Sea during the two investigative cruises in June 1999

1IntroductionAlotofworkonthestudyofthecircula-tionintheHuanghai(Yellow)Sea(HS)andEastChinaSea(ECS)hasbeenmadeandreviewedbyscientists,suchasSu(1998),Suetal.(1994),Guan(1985),YuanandSu(1983,2000),Yuanetal.(1997,1988,1994,2001),Tangetal.(2000)andsoon.Inthispapertheseworks willnotbereviewedagainduetolimitationofpages.Thejointinvestigationontheair-seainteractionprocessofcycloneoutbreakoverthesouthernHuanghaiSeaandEastChinaSeawascarriedoutinthecooperativestudybytheChinese(in-clusiveofTaiwa…     

The study of the Kuroshio in the East China Sea and the currents east of the Ryukyu Islands

In this study, the inverse method is used to compute the Kuroshio in the East China Sea and southeast of Kyushu and the currents east of the Ryukyu Islands, on the basis of hydrographic data obtained during September-October, 1987 by R/V Chofu Maru. The results show that: (1)A part of the Taiwan Warm Current has a tendency to converge to the shelf break; (2) the Kuroshio flows across the section C3 (PN) with a reduced current width, and the velocity of the Kuroshio at the section C3 increases and its maximum current speed is about 158 cm/s, and its volume transport here is about 26×106m3/s; (3) the Kuroshio has two current cores at the sections C3 (PN) and B2 (at the Tokara Strait); (4) the currents east of the Ryukyu Islands are found to flow northward over the Ryukyu Trench during September-October, 1987. The velocities of the currents are not strong throughout the depths. At the section C2 east of the Ryukyu Islands, the maximum current speed is at the 699 m levei and its magnitude is 25 cm/s, and i     

The Mesozoic–Cenozoic organic facies in the Lower Tagus sub-basin (Lusitanian Basin,Portugal): Palynofacies and organic geochemistry approaches

Studies of the Mesozoic and Cenozoic sequence crossed by the Barreiro-4 borehole provide an improved understanding of the organic matter deposited in the Lower Tagus sub-basin (Lusitanian Basin, Portugal) and the implications for the potential source rock and depositional environment. This study focused on 43 samples (Middle Jurassic to Neogene) that were subjected to palynofacies and organic geochemistry analyses (Total Organic Carbon, Rock-Eval pyrolysis and molecular biomarker analysis). The palynofacies data indicate that the sequence contains mainly phytoclasts (non-opaque phytoclasts). However, the Middle Jurassic samples are dominated by Amorphous Organic Matter (AOM). Continental and/or marine palynomorphs are present in all the samples. The Cretaceous samples are characterized by small amounts of kerogen that have high contents of solid bitumen. The Total Organic Carbon (TOC) content is generally less than 1 wt.%. The Rock-Eval S1 and S2 parameters vary from 0.01 to 3.50 mgHC/g rock and 0.15 to 34.03 mgHC/g rock, respectively, with the highest values corresponding to the Cretaceous samples. The hydrogen index (HI) and oxygen index (OI) values range from 35 to 552 mgHC/g TOC and 4 to 180 mgHC/g TOC, respectively. The T_max values range from 416 to 437 °C. The biomarker analysis showed that n-alkanes with 15–30 carbon atoms are present and usually have a unimodal distribution with a predominance of low to medium molecular weight compounds. The CPI values range between 0.63 and 3.65, and the pristane/phytane ratios vary between 0.48 and 1.64, indicating alternation of oxic–anoxic conditions along the sequence. The distribution of terpanes shows small amounts of tricyclic and tetracyclic terpanes in most of the samples (except for some Cretaceous samples) and a predominance of pentacyclic terpanes. The amount of 17α (H),22,29,30-trisnorhopane (Tm) usually exceeds the amount of 18α (H),22,29,30-trinorneohopane (Ts). The 20S/(20S + 20R) and αββ/(ααα + αββ) ratios of the C29 steranes generally have values below the range of equilibrium, indicating an immature stage of the OM.     

Formation of methane-related authigenic carbonates in a highly dynamic biogeochemical system in the Krishna–Godavari Basin,Bay of Bengal

We report the abundant occurrence of authigenic Fe-rich carbonate, high Mg-calcite (HMC) and low Mg-calcite from 11 cores recovered from the Krishna–Godavari Basin (K–G Basin), Bay of Bengal. The cores were collected as part of the Indian gas hydrate exploration program on board R/V Marion Dufresne (MD-161: May, 2007) in different environments, including mounds (mud diapirs), mass flows, and hemipelagic sediments over a range of water depths from 647 to 2079 m. Authigenic carbonates range in size from 1 mm to 12 cm and display various morphologies like roundish or platy (micro-) nodules and tube-like forms. From the cores, 173 carbonate samples have been investigated for their depth distribution, mineralogy, geochemical and stable isotopic composition. The stable carbon isotopic composition of 46 out of 88 measured carbonate samples are around −50‰ which allows the differentiation into methane-related carbonates (HMC), especially at Sites 8 and 15, but also in low abundance at Sites 1, 5, 9 and 12. Results indicate that the carbonates at Site 8 and 15 represent paleo methane seepage locations. The Fe-rich carbonates occur abundantly at many sites in the K–G Basin. Their varying carbon isotopic composition indicates that probably not only sulfate reduction through organic matter degradation but also methanogenesis are the responsible processes for their formation.     

Palynology and petroleum potential of the Kazhdumi Formation (Cretaceous: Albian–Cenomanian) in the South Pars field,northern Persian Gulf

The Kazhdumi Formation of the Bangestan Group is a well-known source rock that has produced abundant oil in most petroleum fields in the Zagros Basin, which stretches from northwest to southwest Iran over hundreds of kilometres. The formation reaches a thickness of 230 m at the type section in northwest Zagros but thins out to 40–50 m in wells studied from the South Pars giant petroleum field, where it comprises mainly grey shales with occasional intercalations of marls and sandstones. South Pars, best known as the Iranian part of the world's largest non-associated gas field, contains small quantities of oil above and below the Kazhdumi Formation.     

Changes in physical properties of a reservoir sandstone as a function of burial depth – The Etive Formation,northern North Sea

Rock physical properties, like velocity and bulk density, change as a response to compaction processes in sedimentary basins. In this study it is shown that the velocity and density in a well defined lithology, the shallow marine Etive Formation from the northern North Sea increase with depth as a function of mechanical compaction and quartz cementation. Physical properties from well logs combined with experimental compaction and petrographic analysis of core samples shows that mechanical compaction is the dominant process at shallow depth while quartz cementation dominates as temperatures are increased during burial. At shallow depths (<2000–2500 m, 70–80 °C) the log derived velocities and densities show good agreement with results from experimental compaction of loose Etive sand indicating that effective stress control compaction at these depths/temperatures. This indicates that results from experimental compaction can be used to predict reservoir properties at burial depths corresponding to mechanical compaction. A break in the velocity/depth gradient from about 2000 m correlates with the onset of incipient quartz cementation observed from petrographic data. The gradient change is caused by a rapid grain framework stiffening due to only small amounts of quartz cement at grain contacts. At temperatures higher than 70–80 °C (2000–2500 m) the velocities show a strong correlation with quartz cement amounts. Porosity reduction continues after the onset of quartz cementation showing that sandstone diagenesis is insensitive to effective stress at temperatures higher than 70–80 °C. The quartz cement is mainly sourced from dissolution at stylolites reflected by the fact that no general decrease in intergranular volume (IGV) is observed with increasing burial depth. The IGV at the end of mechanical compaction will be important for the subsequent diagenetic development. This study demonstrates that mechanical compaction and quartz cementation is fundamentally different and this needs to be taken into consideration when analyzing a potential reservoir sandstone such as the Etive Formation.     

The evolution of rifting on the volcanic margin of the Pelotas Basin and the contextualization of the Paraná–Etendeka LIP in the separation of Gondwana in the South Atlantic

The Pelotas Basin is the classical example of a volcanic passive margin displaying large wedges of seaward-dipping reflectors (SDR). The SDR fill entirely its rifts throughout the basin, characterizing the abundant syn-rift magmatism (133–113 Ma). The Paraná–Etendeka Large Igneous Province (LIP), adjacent to west, constituted the pre-rift magmatism (134–132 Ma). The interpretation of ultra-deep seismic lines showed a very different geology from the adjacent Santos, Campos and Espírito Santo Basins, which constitute examples of magma-poor passive margins. Besides displaying rifts totally filled by volcanic rocks, diverse continental crustal domains were defined in the Pelotas Basin, such as an outer domain, probably constituted by highly stretched and permeated continental igneous crust, and a highly reflective lower crust probably reflecting underplating.The analysis of rifting in this portion of the South Atlantic is based on seismic interpretation and on the distribution of regional linear magnetic anomalies. The lateral accretion of SDR to the east towards the future site of the breakup and the temporal relationship between their rift and sag geometries allows the reconstitution of the evolution of rifting in the basin. Breakup propagated from south to north in three stages (130–127.5; 127.5–125; 125–113 Ma) physically separated by oceanic fracture zones (FZ). The width of the stretched, thinned and heavily intruded continental crust also showed a three-stage increase in the same direction and at the same FZ. Consequently, the Continental-Oceanic Boundary (COB) shows three marked shifts, from west to east, from south to north, resulting into rift to margin segmentation. Rifting also propagated from west to east, in the direction of the final breakup, in each of the three segments defined. The importance of the Paraná–Etendeka LIP upon the overall history of rupturing and breakup of Western Gondwanaland seems to have been restricted in time and in space only to the Pelotas Basin.     

The description of a new kind and three new types of medusae nematocysts in the Xiamen Harbour, China

A new kind of nematocyst, heteromorphore, and three new types of nematocysts, microbasic spino-mastigophore, microbasic undulata-mastigophore, microbasic laevis-mastigophore, are described from medusae of the Xiamen Harbour and discussed by comparison with the results of other research workers.     

Sediment quality assessment in a tropical estuary: The case of Ceará River,Northeastern Brazil

The present study aimed to assess the sediment quality in a tropical estuary located in the northeast of Brazil under semi-arid conditions and multiple sources of contamination, using both toxicity bioassays and metal distribution. The metal distribution followed a concentration gradient decreasing one order of magnitude from the inner station toward the outer estuary, with amounts in the following order: Fe > Al > Zn > Cr > Pb > Cu. The index of geoaccumulation indicated a metal enrichment in the Ceará river sediment, mainly at inner sites, considered from moderately to strongly contaminated by Al, Cu, Cr and Zn. Sediment samples were considered toxic by means of whole sediment tests with copepods (reproduction) and amphipods (survival), and also elutriate fraction and sediment–water interface with sea urchin embryos (development). Acute and chronic toxicity did not exhibit a significant correlation with metals, emphasizing the influence of other contaminants mainly related to the pollution sources installed in the mid-estuary.