Magmatic evolution and rare earth element enrichment of Saima alkaline complex,Liaoning, ChinaSCIEI北大核心CSCD

赛马碱性杂岩体位于我国辽东半岛,是一个典型的铀-铌和稀土多金属矿化杂岩体,富含重稀土,其复杂的演化过程和稀土元素富集机制仍没有得到有效约束。本文对该碱性杂岩体中角闪辉石正长岩、正长岩、黑云正长岩、云霓霞石正长岩和异霞正长岩5类岩石及锆石的元素地球化学特征进行了系统研究,并开展了特征矿物包裹体的显微岩相学研究,旨在限定杂岩体母岩浆的演化路径,揭示稀土元素的富集机制。研究结果显示,赛马碱性杂岩体的母岩浆经历了由钾质碱性(角闪辉石正长岩、正长岩和黑云正长岩),到钾质过碱性(云霓霞石正长岩),向钠质过碱性(异霞正长岩)的充分演化。在演化过程中赛马碱性杂岩体母岩浆的体系状态发生了明显变化,碱性岩浆演化受流体不饱和的纯岩浆体系的控制,而过碱性岩浆岩则形成于流体过饱和的岩浆体系,且异霞正长岩母岩浆流体的饱和程度明显高于云霓霞石正长岩的母岩浆。研究还显示,钾质碱性岩浆稀土元素的地球化学行为主要受控于磷灰石等矿物的分离结晶,而成矿的钠质过碱性岩浆稀土、锆和铌等元素的富集成矿则主要受富CO_(2)的高盐度岩浆热液的控制。     

Study on frost heaving characteristics of sandstone under different freezing conditions北大核心CSCD

At present,artificial freezing method has become one of the effective methods for coal mine shaft to pass through water-rich soft rock strata,which can stop the movement of groundwater and limit the deformation of surrounding rock. In order to study the frost heaving characteristics of sandstone under different freezing conditions,frost heaving tests of saturated and dry Cretaceous red sandstone samples under different freezing rates （10 ℃·h-1,5 ℃·h-1,2 ℃·h-1,1 ℃·h-1）and different confining pressures（5 MPa,10 MPa,15 MPa,20 MPa,25 MPa）were carried out by using GCTS（Geotechnical Consulting & Testing Systems）servo-controlled low temperature and high pressure triaxial rock testing system. In this paper,based on the existing theory of physical and mechanical properties of frozen soil,we studied the frost heaving law of sandstone under different freezing conditions and explored the frost heaving mechanism. The result shows that in the process of cooling,the dry rock sample always produce cold shrinkage deformation,while the saturated rock sample first produce cold shrinkage deformation,then produce frost deformation,and finally the deformation tends to be stable. The deformation of saturated rock samples is much larger than that of dry rock samples. The larger the stress level of rock samples at the same temperature is,the smaller the frost deformation is,which shows a linear negative correlation,mainly because the high confining pressure limits the volume expansion of the water phase in the pore inside the rock samples when it becomes ice. The frost deformation of rock samples is mainly affected by confining pressure and water content,while the frost heaving rate is mainly affected by cooling rate. Under this test condition,the higher the cooling rate of sandstone is,the higher the frost heaving rate is,and the relationship between them is approximately linear. For saturated rock samples,the confining pressure reduces the rock frost heaving by limiting the expansion during the phase transformation of ice water,and the temperature affects the rock frost heaving by affecting the freezing rate of pore water and the thermal expansion and cold contraction of rock skeleton. For dry rock samples,the deformation is mainly due to the volume contraction of rock mineral particles caused by thermal expansion and cold contraction effect,and the greater the temperature change,the greater the deformation. Based on the experimental results and theoretical analysis method,a calculation formula of rock frost heaving considering the influence of confining pressure was established. By calculating the frost heave of sandstone samples under different confining pressures,it is found that the calculated values are in good agreement with the experimental results. Moreover,according to the calculation formula of frost heaving,the influence factors of rock frost heaving during freezing can be divided into two categories：internal cause and external cause. The internal cause includes porosity,saturation,volume modulus of ice and rock skeleton,and the external cause includes temperature and confining pressure. For saturated rock,the frost heaving is mainly affected by factors such as confining pressure,temperature and porosity. When the saturation,porosity and freezing rate are low,the rock may only produce shrinkage deformation,because these indicators determine whether the rock produces frost heave or freeze shrinkage. The mechanism of rock frost heaving is very complicated due to the interaction and restriction between the internal and external factors and the dynamic changes of rock micro-structure and mechanical properties during the process of frost heaving. The research results can provide theoretical reference for freezing construction scheme design of deep coal seam mine construction,and also provide a theoretical basis for the study of physical and mechanical properties and engineering application of soft rock in frozen soil area. © 2022 Science Press (China).     

A study on the geochemical characteristics of natural gas and gas sources in the Bozhong sag

Natural gas is composed largely of hydrocarbon gas, especially wet gas in the Bozhong sag. The carbon isotopic composition shows that the gas is of organic origin. The carbon isotopic values of ethane indicate that the natural gas is dominated by mixed gas with minor coal-generated gas and oil-type gas. A gas-source correlation study showed that the source rocks of natural gas are those of the Lower Dongying Formation, the Shahejie Formation and the pre-Tertiary. The natural gas is characterized by multi-source and continuous generation in the study area, indicating that gas exploration potential is good in the Bozhong sag.     

A review on the advances in surge-type glacier study北大核心CSCD

冰川跃动是多种冰川灾害的主要致灾因子,近年来与冰川跃动相关的冰崩、冰川垮塌、冰川泥石流等灾害的发生频率不断增加,使其成为国际国内冰川学研究的热点。依据对现有文献的统计发现,全球总计约有1 850条跃动冰川,主要分布于环北极地区和亚洲高山区,其中我国西部约有跃动冰川146条。跃动冰川可通过其特殊的表面形态标志,跃动前后冰川末端位置、表面高程和运动速度的变化,以及跃动产生的地貌学和沉积学特征来进行鉴别。跃动冰川的特殊运动模式主要由其内部和底床特性决定,包括冰内/冰下的热力学、水力学与形变等参数及变化过程等。现有大多数跃动冰川研究是基于各类遥感技术,主要着眼于跃动冰川表面变化,并据其对冰川跃动的可能机制进行分析。由于遥感方法精度有限且受天气、地形条件等的制约,同时无法获取冰内/冰下关键参数,因此野外现场观测在这些参数获取方面仍具有不可替代的作用。受限于冰内/冰下参数野外观测数据的缺乏,目前对冰川跃动机理的认识仍局限于早期提出的水力学和热力学两种机制,无法解释同一区域具备不同跃动机制的冰川共存,以及部分冰川跃动从冰川下部发起等问题。同时,在气候变化对跃动冰川的影响研究以及冰川跃动的模拟和预测等方面还有较大欠缺,需要在未来研究中重点关注。     

Long-term thermal stability study of the typical embankment along the Qinghai-Tibet Railway in warm permafrost regions北大核心CSCD

Using the long-term ground temperature monitoring data of the permafrost zone along the Qinghai-Tibet Railway from 2006 to 2020,three types of typical roadbed structures were analyzed. Traditional embankment（TE）,U-shaped crushed rock embankment（UCRE）and crushed rock revetment embankment（CRRE）were included the three types of typical roadbed,which were selected to the long-term monitoring sections within the warm permafrost zones. The evolution of ground temperature field,mean annual ground temperature （MAGT）and annual maximum ground temperature（AMGT）in the depth range of 20 m under the embankment were analyzed and studied since 15 years of operation. The monitoring and analysis results show that：the growth rate of MAGT under the left and right shoulders of the TE is always higher than that of the same depth in the natural site. The MAGT under the UCRE is always lower than the natural site and always maintains a certain difference,whereas,the difference in ground temperature under the left and right shoulders is also not negligible. The MAGT of the left shoulder in the CRRE is not much different from that of the natural hole,while the MAGT of the right shoulder is always lower than that of the natural hole,and the differ in ground temperature between the left and right shoulders is smaller than that of the UCRE. The artificial permafrost table（APT）under the TE is always lower than that of in the natural site. Both the UCRE and CRRE,the APT in the left and right shoulders of them has been elevated into the embankment,and the differ of APT between the left and right shoulders is about 1. 0~1. 5 m. the differ of APT between the left and right shoulders in the CRRE is slightly lower than that of UCRE. Overall,because of the influence of thermal disturbance about engineering and climate warming,the TE in the warm permafrost zones cannot keep the thermal stability of permafrost under the embankment. Some active-cooling and reinforcement measures need to be taken. Both of the UCRE and CRRE,have a certain active-cooling effect on the permafrost under embankment,but the differ in ground temperature between the left and right shoulders still needs to be taken seriously. © 2022 Science Press (China).     

Zircon U-Pb gcochronology and geochemical characteristics of the reshui monzogranite in the eastern kunlun and their tectonic significances北大核心CSCD

In order to probe the genesis and tectonic significance of the granite in the Reshui area, geoehronologicai and geochemical studies of the Reshui monzogranite have been carried out in this paper. The results show that the Reshui monzogranite has LA-1CP-MS zircon U-Pb age of 231 ±1 Ma, indicating that it was formed in late Triassic. It has high contents of Si()2(68. 74%-7l.69%) , Al,(),( 14. 78%-15. 18%). and k,()( 3. 78%-4. 32% ) , with k,()/Na,() ratios ranging from 1. 05 to 1. 32 ,r Rttmann indexes ranging from 1. 87 to 2. 21 . and A/CNk values varying from 1. 03 to 1. 07, respectively. Thus, the Reshui monzogranite belongs to the high k calc-Alkaline weak peraluminous granite. In addition, it has total REE contents(ΣREE) of I 18. 28x 10-6 - 148. 1 x 10-6, with right declined REE distribution patterns showing strong enrichment of LREE and relative depletion of HREE. Its large ion lithophile elements( L1LE) , including Rb. Ra, Th, and l.REE are enriched, while its high field strength elements( HESE) , including Nh, Ta, P. and Ti, are relatively depleted. It has characteristics of the 1-Type granite. It could be mainly sourced from the partial melting of the subducted slab or basic rocks of the lower crust, mixed partly with mantle materials. Combining with regional geological background, it is believed that the Reshui monzogranite was formed by the interaction of the crust and mantle under the tectonic environment of collision-post collision.     

Comparative analysis of the cold surge characteristics over China before and after 2000北大核心CSCD

Based on the daily minimum temperature data in China from 1961 to 2018, using n-order polynomial fitting, sliding t-test, empirical Orthogonal Function analysis, Morlet wavelet transform and other methods, this paper reveals the temporal and spatial distribution characteristics of the number of cold surge (CS) day, CS frequency and CS intensity by time and region. The results are as follows. On a national level, the number of CS day, CS frequency, and CS intensity decreased from 1962 to 2000. Specifically, the trend of every element of CS has changed from a previous decrease trend to an increase trend, and the inflection point was around 2000. The CS activity occurred more frequently, became more strengthen, and last for longer time after 2000. There are obvious spatial differences in the number of CS days, CS frequency, CS intensity and their changing trends in China. The number of CS days and CS frequency reach the maximum value in northeast China and northern Inner Mongolia. Meanwhile, the CS intensity value is low in the southeast China and high in the northwest China, with the exception of southern Xinjiang. The changes in the number of CS day and the CS frequency are mainly manifested as the “Northeast, Southwest Reverse Pattern”, the CS intensity is mainly manifested as the “Uniform Change Pattern”. The number of CS day, CS frequency, and CS intensity did not change significantly after, but a significant transition point was detected in 1980. On a regional scale, from 1962 to 2018, the number of CS day, frequency and intensity of cold surge in all regions showed a decreasing trend, while they increased after 2000. In the northern and northeastern of China, mean of three elements of cold surge increased after 2000. The transition year was different in different regions. The transition year of three elements of cold surge in Northeast China were the earliest. Mean value of the number of CS day, CS frequency, and CS intensity have an oscillation period of 3~5 years in total China and all regions. In addition, the periodic oscillations of the number of CS day and CS frequency in all regions are basically the consistent. © 2022 Science Press (China).     

A study of orthogonal design tests on frost-heaving characteristics of graded crushed rockEI北大核心CSCD

Seasonally frozen soil is distributed widely in the Northeast China. The prevention measures against the frost heave of graded crushed rock, which is used as the filler of surface layer in subgrade, are crucial to high-speed railway constructed in seasonally frozen soil region due to the strict requirements of subgrade deformation. In order to study the frost heave characteristics of graded crushed rock under different conditions, water content, fine content, cooling temperature and compaction are chosen as influential factors of frost heave characteristics. The closed system laboratory frost heave experiments have been performed based on the orthogonal design, showing that different frost heave amounts appear in different combinations of factors and levels. The frost heave ratio of most graded crushed rock samples is small when water content is 5%, and it exceeds 1% when water content is above 7%. The temperature field, frozen depth, frost heave deformation process and water content distribution in sample after freezing are analyzed. It is found that the water content is greater than the initial water content at the cold side, and is lower than initial water content at the warm side. Using the frost heave ratio as a reference sequence and other factors as comparison sequences, the correlation degrees among water content, fine content, compaction, temperature at cold side and frost heave ratio are analyzed with the gray correlation method. The results from this analysis indicate that water content produces the most significant effect on the frost heave ratio of graded crushed rock. The water content of graded crushed rock should be maintained below 5% in order to prevent frost heave development in the cold regions.     

Petrogenesis of Late Ordovician intrusive rocks in the West Kunlun orogenic belt: Constraints on the subduction process of the Proto-Tethys OceanSCIEI北大核心CSCD

西昆仑造山带发育有大量的早古生代岩浆岩,它们的形成与原特提斯洋俯冲-碰撞密切相关,然而,对于这些岩浆岩的岩石成因和形成的构造背景仍然存在较大的争议。本文对西昆仑造山带早古生代阿喀孜二长岩和赛图拉石英闪长岩岩体开展了详细的矿物学、锆石U-Pb年代学、全岩地球化学和Sr-Nd-Hf-O同位素研究,以探讨这些侵入岩的岩浆源区与成因,揭示原特提斯洋在这一时期的构造演化过程。这两个岩体的LA-ICP-MS锆石U-Pb年龄分别为456±2Ma和452±2Ma,指示它们形成于晚奥陶世。阿喀孜二长岩具有富碱(K_(2)O+Na_(2)O=10.5%~11.8%)、富钾(K_(2)O/Na_(2)O=1.20~1.44)特征,相对低MgO(0.89%~0.97%)、TiO_(2)(0.42%~0.45%)含量,富集Rb、Th、U等大离子亲石元素,且具有较高的全岩锆饱和温度(T_(Zr)=814~862℃),属于钾质碱性岩石。该岩体具有较高的(^(87)Sr/^(86)Sr)_(i)值(0.72057~0.72186),负的全岩ε_(Nd)(t)值(-5.1~-4.5)和负的锆石ε_(Hf)(t)值(-7.6~-3.4),以及较高的锆石δ^(18) O值(5.39‰~7.94‰),表明其源区可能为伸展环境下古老基性下地壳部分熔融。赛图拉石英闪长岩SiO_(2)含量为56.8%~58.6%,全碱(Na_(2)O+K_(2)O)含量为5.75%~6.39%,具有较低的铝饱和指数(A/CNK=0.85~0.89),相对高的MgO含量(2.93%~3.41%)以及Mg^(#)值(~45),为高钾钙碱性系列岩石。它们富集大离子亲石元素(Rb、Ba、Th)和亏损高场强元素(Nb、Ta、Ti),且具有微弱的Eu异常(δEu=0.72~0.77),类似于俯冲带岩浆岩地球化学特征。这些石英闪长岩具有相对高的(^(87)Sr/^(86)Sr)_(i)比值(0.71317~0.71322),负的全岩ε_(Nd)(t)值(-5.6~-5.1)和负的锆石ε_(Hf)(t)值(-7.8~-2.9),与同时期来源于富集地幔的基性岩同位素特征相似,表明赛图拉石英闪长岩岩浆可能是由俯冲板片流体交代的富集地幔楔部分熔融形成,并在岩浆演化的过程中经历了橄榄石、辉石、角闪石、磷灰石和Fe-Ti氧化物等矿物的分离结晶作用。结合同位素和数字模拟计算(Rhyolite-MELTS)结果表明,赛图拉石英闪长岩可能由塔里木克拉通南缘玄武质岩浆的分离结晶而成。综合前人研究,本文提出晚奥陶世阿喀孜二长岩和赛图拉石英闪长岩形成于原特提斯洋向北俯冲相关的活动大陆边缘环境,该时期原特提斯洋板片回撤,诱发软流圈地幔的上涌,从而产生了大量的弧岩浆岩。     

Analysis of water vapor characteristics in snowstorm process on the northern slope of Tianshan Mountains北大核心CSCD

Based on the daily precipitation data of 16 national meteorological observation stations on the north⁃ ern slope of Tianshan Mountains from 2000 to 2020（September to April the following year）,28 blizzard weath⁃ er processes were screened out. Then NCEP/NCAR reanalysis data and HYSPLIT model were used to simulate backward tracking of the water vapor during the snowstorm,analysis of the circulation background of the snow⁃ storm process on the northern slope of the Tianshan Mountains,as well as the main sources and transport of wa⁃ ter vapor and its contribution to the snowstorm. The research showed that the snowstorm area in the northern slope of the Tianshan Mountains was located on the right side of the axis of the southwest jet at 300 hPa high,the southwest airflow in front of the West Siberia trough at 500 hPa,the front convergence of the exit area of the southwest jet at low level at 700 hPa,and the convergence area of water vapor flux divergence and the overlap near the ground cold front area. The water vapor affecting the blizzard on the northern slope of the Tianshan Mountains mainly came from the Mediterranean Sea,the Black Sea and its vicinity,Southwest Asia,Central Asia,the Atlantic Ocean and its coasts,as well as the 850 hPa water vapor in Europe and northern Xinjiang. The water vapor from North America and other places had a relatively small contribution to the blizzard;after each water vapor source reaches the key area with the westerly airflow,under suitable circulation conditions. It mainly entered the blizzard area along the westward（southwest）and the northwest paths. But there were some differences between the layers. Based on the above characteristics,the structure of the source and transport of wa⁃ ter vapor in the snowstorm process on the northern slope of the Tianshan Mountains was established and the char⁃ acteristics of vapor transport at various heights were revealed. © 2023 The Author(s).     

Experimental study on mechanical properties and pore characteristics of the modified lime mortars under freee-thaw cycles北大核心CSCD

石灰土作为路基填料代替宕渣是一种较为经济的方案,但灰土初始强度低、硬化速率慢、碳化时间长,不利于快速施工,需要进行改良研究。利用偏高岭土与石灰发生火山灰反应的原理改良灰土,通过单轴压缩试验和三轴压缩试验,分析改良灰土冻融循环条件下力学参数变化规律,利用图像处理技术提取改良灰土图像表面孔隙,建立孔隙率与强度的关系,并通过研究龄期、石灰含量和含水率变化规律,分析偏高岭土改良灰土的机制。结果表明：偏高岭土能够有效提高灰土材料反应速率,改善灰土力学特性;偏高岭土在一定程度上能够恢复冻融循环导致的灰土力学性能损失,降低冰晶体产生的孔隙;灰土强度达到最优后,其强度随着石灰的增加而降低,而经偏高岭土改良后其强度将继续增加;火山灰反应比灰土碳化过程消耗更多的水分,有效提高了灰土的抗冻性能。     

Research progress on methylmercury in the cryosphere北大核心CSCD

The cryosphere is one of the climate system component which plays an important role in the global biogeochemical mercury cycling. Anthropogenic mercury has been transported to remote cold and high regions worldwide through atmospheric circulation,and then transformed into methylmercury in the cryosphere. As one of the highly toxic environmental pollutants,methylmercury can be greatly bioaccumulated and biomagnified through the food web,which potentially poses threats to human and wildlife as well as the global cryospheric en⁃ vironments. In order to gain a full picture of research progress on methylmercury in the cryosphere,our study comprehensively summarized the concentration levels and analytical methods of methylmercury,and biogeo⁃ chemical processes such as the migration,transformation and fate of methylmercury in various cryospheric envi⁃ ronments including glacier,permafrost,snow ice and sea ice. We particularly made the literature review of mi⁃ crobial mercury methylation and evaluated the risk of methylmercury exposure to human and wildlife in the cryo⁃ sphere. Meanwhile,we focus on distribution,behavior,and environmental effects of methylmercury in the cryosphere against the backdrop of climate change,which is essential for assessing the exposure risk of methyl⁃ mercury to humans and wildlife. Perspectives of methylmercury researches in the cryosphere have also been highlighted in this review,though there is existing a knowledge gap of biogeochemical methylmercury cycling in the low temperature environments which merits further study. © 2023 The Author(s).     

Review on snowmelt runoff simulation in mountain regions,Northwest China北大核心CSCD

Snowmelt runoff is a valuable water resource in Northwest China. In the past few decades, progress has been achieved in snowmelt runoff simulation in mountainous areas, including observation and simulation of snow melt process, improvement and development of distributed snow melt runoff model, and ability for application of snow melt runoff model with temporal and spatial distribution driving data. The development of interpolation algorithm, remote sensing and data assimilation technology provides data support for the widespread application of distributed snowmelt runoff model in northwest mountainous regions of China. Climate warming and economic and social development will further aggravate the contradiction between supply and demand of water resources in the arid regions of Northwest China, which requires higher precision and detail spatial and temporal resolution of snowmelt runoff simulation. Based on the progress and challenges on snowmelt runoff simulation in mountainous regions of Northwest China, following studies need more attention：the mechanism of snow accumulation and ablation, snow cover spatial and temporal distribution monitoring and high precision of snow distribution data acquisition, quantitative climate change impact on river basin snowmelt runoff. © 2022 The authors.     

Composition characteristics and significance of spinel in the kinibcrlite from No. 30 Pipe in the wafangdian area. China北大核心CSCD

The spinel coexisting with diamonds is often used as indicator mineral to evaluate the diamond-bearing potentiality of the kimberlite. In order to figure out the characteristics of spinels in the No. 30 kimberlite pipe, this paper has carried out detailed morphological observation and electron probe analysis on the spinels. The results show that spinels are elliptical and sub-Angular grains, with large particle diameter( 5(H)-1000 μm). A small amount of spinels shows erosional embay men t shape. With high contents of Cr2O3( up to 66. 56% ) and MgO ( 8. 88% - 16. 68% ) , and low TiO2, contents (mostly相似文献   

Magmatic control on the contrasting Sn feritility of different granite plutons in the giant Gejiu orefield.SCIEI北大核心CSCD

云南个旧锡矿是全球最大的锡多金属矿床之一,但矿区内同时代花岗岩成锡矿潜力差异显著,其控制因素仍不清楚。本文选取贫矿的龙岔河似斑状花岗岩和成锡矿的老厂-卡房(后文简称老-卡)花岗岩为研究对象,通过全岩地球化学成分和黑云母成分分析,系统研究个旧矿区不同花岗岩成锡矿潜力差异的控制因素。测试结果表明,龙岔河花岗岩和老-卡花岗岩具有相似的、以表壳物质为主的岩浆源区以及较高的初始熔融温度,表明岩浆源区和熔融条件不是控制二者成矿潜力差异的主要原因。黑云母成分显示老-卡花岗岩和龙岔河花岗岩均具有较低的氧逸度,岩浆演化过程中锡为不相容元素,有利于锡在残余熔体中富集,表明氧逸度条件也不是导致成矿潜力差异的关键因素。龙岔河花岗岩发育角闪石、榍石、黑云母,而老-卡花岗岩发育岩浆白云母,指示后者分异程度更高。此外,与龙岔河花岗岩相比,老-卡花岗岩具有富硅,贫钛、铁、镁、钙和稀土元素特征,稀土元素呈现“海鸥式”配分模式,并且具有较低的Nb/Ta、Zr/Hf、K/Rb和较高的Rb/Sr比值,同样指示老-卡花岗岩具有更高的结晶分异程度。并且相比于龙岔河花岗岩为准铝质的特征,老-卡花岗岩的过铝质特征有利于锡分配进入岩浆出溶的流体相中富集成矿。因此,岩浆性质和演化程度是导致个旧地区不同花岗岩成矿潜力差异的主要原因,龙岔河花岗岩形成锡矿化的潜力较小。     

A study on the geochemical characteristics of Upper Permian continental marginal arc volcanic rocks in the northern segment of South Lancangjiang Belt

1IntroductionThe northern segment of the South LancangjiangBelt refers to the terrain about200km east of theYunxian-Lingcang granite in the South LancangjiangBelt(Fig.1).During the seventh Five-Year Plan peri-od,Mo Xuanxue et al.(1993)undertook the resear…     

Mobility of rare earth elements in the system soils–plants–groundwaters: a case study of an arid area (Oman)

Groundwater samples from six wells and various species of plants from soils developed on ophiolites were collected from an arid area (AlKhod area, Oman) and analyzed for trace elements including rare earth elements (REEs). The distribution patterns of REEs in plants indicated an enrichment in middle REEs (MREEs?=?Sm to Dy) and heavy REEs (HREEs?=?Ho to Lu), when they are normalized to the REE composition of the Post Archean Australian Shale (PAAS), with a significant negative anomaly in Ce and a positive anomaly in Eu. Compared to Oman ophiolites, the REEs in different species of plants are depleted in Ce and enriched in MREEs and slightly enriched in light REE (LREE?=?from La to Nd). Relative to PAAS, the distribution of REEs in groundwaters revealed similar patterns to the REE distribution in plants. The distribution patterns of REEs in plants relative to those in waters are nearly flat. These patterns suggest that the transfer of REEs from soil solutions to the groundwaters in Oman occurs without any significant fractionation.     

Distribution characteristics and its influencing factors of active layer thickness in Tanggula area on the Qinghai-Tibet Plateau北大核心CSCD

多年冻土区活动层的冻融过程显著影响地-气间的水热交换、地表水文过程、冰缘地貌演变及寒区工程建设。活动层厚度的空间分异规律及其空间分布的准确模拟计算是冻土学研究的基础和核心问题之一。作为青藏高原中部东西走向最大的山脉和青藏高原多年冻土的主要分布区,唐古拉地区是青藏高原南部湿润区与北部干旱区的过渡区,该地区的活动层厚度空间分异规律研究对于揭示青藏高原多年冻土区活动层厚度整体空间分布规律具有重要意义。利用唐古拉地区南、北坡两个区域野外实测活动层厚度分布数据,分析了该区域活动层厚度的空间分异特征及其主要影响因素。结果表明,活动层厚度分布的突出特点是空间分异巨大,最小值仅为1.2 m,最大值达到5.6 m。以不同植被类型区活动层的平均厚度为对比标准,其分布特征为：沼泽草甸<高寒草甸<高寒荒漠<高寒草原,高寒草原的平均活动层厚度最大。对比南、北坡,南坡活动层厚度普遍大于北坡。Stefan方程的计算结果表明,活动层厚度的变化速率随土壤含水率的变化最大,其次为土壤热导率,而随地表融化指数的变化最小。实测土壤含水率、探坑数据及地表融化指数与活动层厚度分布关系表明,影响活动层厚度空间分异的最为敏感的因素为土壤含水率,其次为土壤热导率,地表融化指数的敏感性最小。     

Migration-circulation processes and enrichment-mineralization mechanism of lithium-beryllium elements in the continental crust.SCIEI北大核心CSCD

锂铍金属是世界关键金属资源,矿床类型多样,成矿作用发生在大陆地壳。但大陆地壳中锂铍元素的迁移-循环规律及不同锂铍矿床间的成因联系尚不清楚。本文系统地总结与梳理了大陆地壳结构与物质循环特征和不同类型锂铍金属矿床间的成因联系,提出大陆地壳锂铍循环-成矿系统的概念与模型,并将大陆地壳锂铍的迁移与循环划分为四个过程:变质过程、深熔过程、花岗岩浆过程、花岗质岩浆岩风化、淋滤与蚀变的浅-表生过程。沉积岩中锂铍元素在变质过程中可富集到一些变质矿物中,一些富锂铍黏土矿物也在变质过程转变成新的富锂铍变质矿物(如绿泥石、云母与堇青石);地壳深熔过程使得锂铍元素从变质矿物中释放出来并聚集在花岗岩浆中,麻粒岩相深熔(如黑云母脱水熔融与堇青石分解熔融)可能是锂铍大规模成矿的主要熔融方式;绝大多数锂铍矿床与花岗岩浆及其岩浆岩有关,是花岗岩浆与花岗质岩浆岩在不同演化阶段与不同方式富集成矿的结果;浅-表生过程对锂铍花岗岩-伟晶岩和流纹岩与流纹质凝灰岩的物理化学改造,可形成盐湖卤水型锂矿床、黏土型锂矿床以及各种次生锂铍矿床。变质过程中锂铍的迁移与富集机制,大型-超大型花岗岩-伟晶岩型锂铍矿床形成条件与关键控制因素等问题,是亟待研究与思考的科学问题。     

Enrichment characteristics and its geological significance of dispersed elements within sulfide minerals from the VI ore belt in the Maoping Pb-Zn deposit,Yunnan Province,ChinaSCIEI北大核心CSCD

作为华南大面积低温成矿域的重要组成部分,川滇黔铅锌矿集区是我国重要的铅锌银等资源基地之一,同时该矿集区也是Ge、Cd、Ga和In等稀散元素的超常富集区域。毛坪矿床是该矿集区内第二大铅锌矿床,累计探明铅锌金属储量超过3Mt(Pb+Zn平均品位≥18%),锗(Ge)保有储量182t。本文以新发现的Ⅵ矿带(铅锌金属已探明储量≥60万t,Pb+Zn平均品位≥20%)为研究对象,利用LA-ICPMS对主要矿石矿物闪锌矿和黄铁矿进行了微区原位微量元素组成和Mapping分析。研究结果显示Ⅵ矿带闪锌矿普遍富集Ge(最高580×10^(-6),均值81.1×10^(-6))、Cd(最高3486×10^(-6),均值1613×10^(-6))和Ga(最高190×10^(-6),均值44.4×10^(-6));黄铁矿普遍富集Mn、As、Pb、Cu、Ag和Sb。与Ⅰ和Ⅱ号矿带闪锌矿相比,Ⅵ号矿带闪锌矿更富集Ge和Ga。闪锌矿中Fe和Pb以类质同象为主,偶见黄铁矿和方铅矿显微包体;Cu、Ge、Ag和As赋存形式主要为类质同象,替代方式为Ge^(4+)+2(Cu+,Ag+,As+)↔3Zn^(2+);Cd以类质同象方式赋存为主,替代机制为Cd^(2+)↔Zn^(2+);Ga和In可能主要以类质同象方式存在。黄铁矿中Pb和Mn主要以方铅矿和碳酸盐矿物显微包体为主;Cu、As和Sb以类质同象形式存在于黄铁矿中;Ag和Zn可能以独立矿物形式赋存;Co和Ni以类质同象方式替代Fe进入黄铁矿晶格中,替代方式为Ni^(2+)+Co^(2+)↔2Fe^(2+)。毛坪矿床新发现Ⅵ矿带硫化物相比典型MVT矿床硫化物具有不同的In和Ge含量以及Cd/Fe比值,结合矿床地质特征和其他证据,表明毛坪矿床成因类型特殊,有别于经典MVT铅锌矿床,属于川滇黔型铅锌矿床。