Differential Late Paleozoic active margin evolution in South-Central Chile (37°S–40°S) – the Lanalhue Fault Zone

The N–S oriented Coastal Cordillera of South Central Chile shows marked lithological contrasts along strike at 38°S. Here, the sinistral NW–SE-striking Lanalhue Fault Zone (nomen novum) juxtaposes Permo-Carboniferous magmatic arc granitoids and associated, frontally accreted metasediments (Eastern Series) in the northeast with a Late Carboniferous to Triassic basal-accretionary forearc wedge complex (Western Series) in the southwest. The fault is interpreted as an initially ductile deformation zone with divergent character, located in the eastern flank of the basally growing, upwarping, and exhuming Western Series. It was later transformed and reactivated as a semiductile to brittle sinistral transform fault. Rb–Sr data and fluid inclusion studies of late-stage fault-related mineralizations revealed Early Permian ages between 280 and 270 Ma for fault activity, with subsequent minor erosion. Regionally, crystallization of arc intrusives and related metamorphism occurred between 306 and 286 Ma, preceded by early increments of convergence-related deformation. Basal Western Series accretion started at >290 Ma and lasted to 250 Ma. North of the Lanalhue fault, Late Paleozoic magmatic arc granitoids are nearly 100 km closer to the present day Andean trench than further south. We hypothesize that this marked difference in paleo-forearc width is due to an Early Permian period of subduction erosion north of 38°S, contrasting with ongoing accretion further south, which kinematically triggered the evolution of the Lanalhue Fault Zone. Permo-Triassic margin segmentation was due to differential forearc accretion and denudation characteristics, and is now expressed in contrasting lithologies and metamorphic signatures in todays Andean forearc region north and south of the Lanalhue Fault Zone.     

Geochemical prospecting for stratabound mineralization in late Precambrian sediments of East Greenland (72–74°N)

A geochemical investigation was carried out mainly in a 14-km thick sedimentary sequence of late Precambrian age. The project included analysis of rock samples and drainage samples for Cu, Co, and Zn. The drainage samples were heavy-mineral concentrates and stream sediment samples.The results for the drainage sediments distinguish three well defined cupriferous horizons in the sedimentary column. Lithogeochemical studies of quartzites, pelites, and carbonates confirm that the anomalous values obtained in the drainage sediments arise from several Cu-mineralized horizons.The study has shown that geochemical prospecting appears to be well suited to Cu prospecting in Central East Greenland under arctic climate conditions even with a low sampling density of one sample per 5–10 km² for the drainage samples, and one sample per 10–100 m of the sedimentary stratigraphic column for the rock samples.     

Late Quaternary vegetation and climate history of a perennial river canyon in the Río Salado basin (22°S) of Northern Chile

Plant macrofossils from 33 rodent middens sampled at three sites between 2910 and 3150 m elevation in the main canyon of the Río Salado, northern Chile, yield a unique record of vegetation and climate over the past 22,000 cal yr BP. Presence of low-elevation Prepuna taxa throughout the record suggests that mean annual temperature never cooled by more than 5°C and may have been near-modern at 16,270 cal yr BP. Displacements in the lower limits of Andean steppe and Puna taxa indicate that mean annual rainfall was twice modern at 17,520–16,270 cal yr BP. This pluvial event coincides with infilling of paleolake Tauca on the Bolivian Altiplano, increased ENSO activity inferred from a marine core near Lima, abrupt deglaciation in southern Chile, and Heinrich Event 1. Moderate to large increases in precipitation also occurred at 11,770–9550 (Central Atacama Pluvial Event), 7330–6720, 3490–2320 and at 800 cal yr BP. Desiccation occurred at 14,180, 8910–8640, and 4865 cal yr BP. Compared to other midden sites in the region, early Holocene desiccation seems to have happened progressively earlier farther south. Emerging trends from the cumulative midden record in the central Atacama agree at millennial timescales with improved paleolake chronologies for the Bolivian Altiplano, implying common forcing through changes in equatorial Pacific sea-surface temperature gradients.     

Spatial and temporal patterns of iceberg rafting (IRD) along the East Greenland margin,ca. 68°N,over the last 14 cal.ka

Twelve 1–2 m, 10-cm-diameter gravity cores collected in 1988 and 1991, from the continental shelf and fjords of East Greenland near Kangerlussuaq Fjord/Trough (ca. 68°N, 32°W), have distinct changes in lithofacies and in the quantity of iceberg rafted (IRD) sediments. These changes are readily observed in X-radiographs of the split cores. We quantify the IRD contribution through grain-size analyses and counting the number of clasts >2 mm from the X-radiographs. Chronological control is provided by acclerated mass spectroscopy ¹⁴C dates on foraminifera. During deglaciation, after 14 cal.ka there was one interval of IRD accumulation ca. 12–13 cal.ka, followed by a brief return to IRD conditions centred at 9 cal.ka. Thereafter, a prominent feature of most cores on the shelf is an increase in IRD accumulation that started ca. 5–6 cal.ka, and which has increased toward the present. Indicators of iceberg rafting, such as the net sand flux and numbers of clasts >2 mm ka⁻¹, follow a power law distribution when graphed against distance from the present East Greenland coast, a measure of the position of the glacier margins. The form of the relationship indicates that there is a dramatic decrease in the supply of sediment from the fjords to the shelf. These relationships are used to estimate changes in the location of the ice margin during the late Quaternary based on a site on the East Greenland slope, Denmark Strait, and to discuss factors that can negate such a simple transfer function. © 1997 by John Wiley & Sons Ltd.     

Interaction between the Nazca and South American plates and formation of the Altiplano–Puna plateau: Review of a flexural analysis along the Andean margin (15°–34°S)

The results of a two-dimensional flexural analysis applied to the Andean margin, which is based on the correlation between topography and Bouguer anomaly, are here reviewed in order to characterize rigidity variations across and along the forearc–arc transition of the Central Andes and to understand the role of the forearc in the formation of the Altiplano Plateau. The forearc has maximum rigidities between 15° and 23°S. Forearc rigidity decreases gradually southward and sharply toward the plateau. The main orogen (elevations higher than 3000 m) is very weak along the entire Central Andes. A semi-quantitative interpretation of these trends, based on the relationship between flexural rigidity and the thermo-mechanically- and compositionally-controlled strength of the lithosphere, allows the following conclusions to be made: (1) across-strike rigidity variations are dominated by the thermal structure derived from the subduction process; (2) the forearc constitutes a strong, cold and rigid geotectonic element; (3) southward weakening of the forearc is directly related to the decreasing thermal age of the subducted slab; (4) very low rigidities along the main orogen are caused by the existence of a thick, quartz-rich crust with a low strain rate-to-heat flow ratio; (5) the strength of the plateau lithosphere is localized in an upper-crustal layer whose base at 15 km could be correlated with a P-to-S seismic wave converter (TRAC1 of Yuan et al., 2000 [Yuan, X., Sobolev, S., Kind, R., Oncken, O. et al. 2000. Subduction and collision processes in the Central Andes constrained by converted seismic phases. Nature, V 408, 21/28 Diciembre, p. 958–961]); (6) the forearc–plateau rigidity boundary corresponds to a zone of changing thermal conditions, eastward-increasing crustal thickness and felsic component in the crust, and low strain-rate deformation, which correlates with a west-verging structural system at the surface. These conclusions suggest that the rigid forearc acts as a pseudo-indenter against the weak plateau and allows the accumulation of ductile crustal material that moves westward from the eastern foreland. This pseudo-indenter is geometrically represented by a crustal-scale triangular zone rooted at TRAC1. This model allows the integration of existing contradictory ideas on the dynamics of forearc–plateau interaction that are related to the relative importance of upper-crustal compressive structures and lower crustal accumulation below the forearc.     

Late Holocene sedimentary changes in floodplain and shelf environments of the Tagus River (Portugal)

Sedimentary changes during the last ∼2500 years have been reconstructed from cored sedimentary records from the deltaic floodplain of the Lower Tagus Valley and the Tagus mudbelt on the continental shelf offshore Lisbon. We used a multi-proxy approach consisting of sedimentology, grainsize, pollen data and magnetic susceptibility. In the floodplain grainsize coarsened and sedimentation rate and magnetic susceptibility increased during the late Holocene due to an increased flooding frequency and/or intensity. On the Tagus shelf the mudbelt grainsize fined, together with a higher sedimentation rate and increased magnetic susceptibility. The fining grainsize is explained by an increased suspended sediment flux towards the shelf and subdued winnowing. Floodplain and shelf records were correlated by radiocarbon dating and changes in sediment characteristics. We identified four depositional phases (∼2300/∼1600/∼1100/∼670 cal BP) on the floodplain and the shelf. These are tentatively explained by land-use changes in the Tagus catchment.     

Tectono‐sedimentary evolution of the northernmost margin of the NE German Basin between uppermost Carboniferous and Late Permian (Rotliegend)

The tectono‐sedimentary evolution of the Rotliegend deposits of the northernmost margin of NE German Basin (NEGB) has been analysed on the basis of detailed sedimentary logs of 300 m of core material together with the re‐evaluation of 600 km of seismic lines. Three distinct phases were recognized. During the initial Phase I, basin geometry was largely controlled by normal faulting related to deep‐seated ductile shearing leading to a strong asymmetric shape, with a steep fault‐controlled eastern margin and a gently, dipping western margin. The results of forward modelling along a cross‐section fit the basin geometry in width and depth and reveal a footwall uplift of c. 1000 m. Adjacent to the steep faults, local sedimentation of Lithofacies Type I was confined to non‐cohesive debris flow‐dominated alluvial fans, whereas the gently dipping western margin was dominated by alluvial‐cone sedimentation. During the post‐extensional period (Phase II), cooling of the lithosphere generated additional accommodation space. The sediments of Lithofacies Type II, comprising mainly clast‐supported conglomerates, are interpreted as braided ephemeral stream flow‐surge deposits. Tectonic quiescence and an increase in flood events resulting from wetter climate led to progradation of this facies over the entire region. At the end of this period, the accommodation space was almost completely filled resulting in a level topography. Phase III was controlled by the thermal‐induced subsidence of the southerly located NEGB in post‐Illawarra times. The formerly isolated region tilted towards the SW, thus forming the northern margin of the NEGB during uppermost Havel and Elbe Subgroup times. The sediments of Lithofacies Type III were divided into a marginal sandstone‐dominated environment and a finer‐grained facies towards the SW. The former consists of poorly‐sorted coarse‐grained sandstones of a proximal and medial ephemeral stream floodplain facies. The latter comprise mud flat fines and fine‐grained distal ephemeral stream deposits. The end of the tectono‐sedimentary evolution is marked by the basinwide Zechstein transgression. Copyright © 2001 John Wiley & Sons, Ltd.     

Geomorphologic evidence for Plio‐Quaternary shortening in the southern Neuquén basin (40°S,Argentina)

A morphostructural analysis of a Pliocene flood basalt formation in the southern Neuquén basin (40°S) shows evidence of contractional deformation less than 3.5 Ma ago. This formation exhibits a general dip towards the south‐east, with relict outcrops located 100 m higher than the main source volcano, which suggests a local tilting of the lava flow. This tilt has been brought about by Plio‐Quaternary reactivation of the eastern border of the Sañico Massif along two thrusts that offset the lava flow. Another long‐wavelength bulge in the southern part of the lava flow unit indicates a possible Pliocene uplift of the North Patagonian Massif. These results provide new evidence of continuing shortening in the Neuquén basin during the Plio‐Quaternary, challenging the hypothesis that an extensional regime has existed since the end of the Miocene in this basin.     

Sedimentary response to Late Quaternary sea-level changes in the Romagna coastal plain (northern Italy)

Data from 17 continuously cored boreholes, 40–170 m deep, reveal the subsurface stratigraphy of the Romagna coastal plain. Sedimentological and microfaunal data allow the distinction of eight facies associations of Late Pleistocene–Holocene age, including 18 lithofacies and 16 faunal associations. Ten ¹⁴C dates provide the basis to establish a sequence stratigraphic framework for the succession corresponding to the upper part 35 ky BP of the last glacio-eustatic cycle. The eight facies associations can be grouped into lowstand, transgressive and highstand systems tracts. The upper part of the lowstand systems tract consists of alluvial plain deposits. These accumulated during the Late Pleistocene when the shoreline was ≈250 km south of its present-day position. A pronounced stratigraphic hiatus (between 25 and 8·8 ky BP) is invariably recorded at the upper boundary (transgressive surface) of these Pleistocene, indurated and locally pedogenized alluvial deposits. The succeeding postglacial history is represented by a well developed transgressive–regressive cycle. Transgressive deposits, interpreted to reflect the rapid landward migration of a barrier–lagoon system, include two wedge-shaped, paralic and marine units. These thicken in opposite directions and are separated by a ravinement surface. Above the transgressive deposits, the maximum flooding surface (MFS) marks the change from a transgressive barrier–lagoon complex to a prograding, wave-dominated delta system (early Po delta). The MFS can be traced landwards, where it constitutes the base of lagoonal deposits. An aggradational to progradational stacking pattern of upper delta plain (marsh), lower delta plain (lagoon/bay), and delta front (beach ridge) deposits reflects the progressive increase in the sediment supply/accommodation ratio during the following highstand. The alluvial deposits capping the sequence accumulated by the 13th century AD, in response to an avulsion event that caused abandonment of the former Po delta lobe and the northward migration of the Po River towards its present position.     

Carbon isotope and rare earth element composition of Late Quaternary sediment gravity flow deposits on the mid shelf of East China Sea: Implications for provenance and origin of hybrid event beds

The East China Sea Shelf has an unusually wide and low gradient shelf, supplied from sediment‐charged rivers and large river delta systems, with bottom currents sweeping the sea floor and located in the path of strong typhoons. Sediment gravity flow deposits, including four hybrid event beds and a high density turbidite, are identified in a core from the mid‐shelf of the East China Sea. The hybrid event beds typically comprise three or two internal divisions from the base to the top: (i) H1, H3 and H5; or (ii) H3 and H5. Radiocarbon ages of the hybrid event beds were in the range of 3821 to 8526 yr bp . Based on correlation with surrounding cores, the hybrid events may have happened at any time between 1930 yr bp and 3890 yr bp . The δ¹³C values in hybrid event beds together with bathymetry data suggest local erosion on the shelf. The average δ¹³C value for the H1 division is similar to the H3 division in the hybrid event beds, implying that the organic matter in the H1 and H3 divisions may come from the same source area. Cross‐plots of upper continental crust normalized rare earth elements in the five units reveal that the sediment source of the four hybrid event beds and the turbidite was ultimately primarily from Korean rivers. Partial transformation from a moderate‐strength debris flow with the additional role of erosional bulking can explain occurrences of hybrid event beds on the East China Sea Shelf. The data indicate that hybrid sediment gravity flow deposits were sourced from intra‐shelf failures and subsequently transformed and deposited as hybrid event beds. The study shows that hybrid sediment gravity flows and turbidity currents may not necessarily indicate proximity to a major fluvial or deltaic system and that intra‐shelf sedimentation can be a sediment source. It is unlikely that the debris flows and turbidity currents were triggered by a hyperpycnal flow or tsunami, because both can carry continental and/or coastal signals which have not been recognized in the core. Typhoons are the probable triggering mechanism.     

Late Holocene sea-surface temperature and precipitation variability in northern Patagonia, Chile (Jacaf Fjord, 44°S)

A high-resolution multi-proxy study including the elemental and isotopic composition of bulk organic matter, land plant-derived biomarkers, and alkenone-based sea-surface temperature (SST) from a marine sedimentary record obtained from the Jacaf Fjord in northern Chilean Patagonia (44°20′S) provided a detailed reconstruction of continental runoff, precipitation, and summer SST spanning the last 1750 yr. We observed two different regimes of climate variability in our record: a relatively dry/warm period before 900 cal yr BP (lower runoff and average SST 1°C warmer than present day) and a wet/cold period after 750 cal yr BP (higher runoff and average SST 1°C colder than present day). Relatively colder SSTs were found during 750–600 and 450–250 cal yr BP, where the latter period roughly corresponds to the interval defined for the Little Ice Age (LIA). Similar climatic swings have been observed previously in continental and marine archives of the last two millennia from central and southern Chile, suggesting a strong latitudinal sensitivity to changes in the Southern Westerly Winds, the main source of precipitation in southern Chile, and validating the regional nature of the LIA. Our results reveal the importance of the Chilean fjord system for recording climate changes of regional and global significance.     

Las Matras Block, Central Argentina (37°S-67°W): the Southernmost Cuyania Terrane and its Relationship with the Famatinian Orogeny

The Las Matras Block in Central Argentina constitutes the southernmost part of the Cuyania terrane, which was accreted to the southwestern margin of Gondwana during the Early to Mid Ordovician Famatinian orogeny. The Grenville-aged rocks of the Las Matras Block are represented by the tonalitic to trondhjemitic Las Matras pluton. A new U-Pb conventional zircon age of 1244±42 Ma confirms previous Sm-Nd and Rb-Sr isochron ages of this pluton. Mineral composition data are consistent with the tonalitic-trondhjemitic character of the pluton, and constrain its emplacement level to 1.9 to 2.6 kb. This shallow level of emplacement and the undeformed character of the pluton are distinctive features of this southernmost basement. A regional comparison indicates that the igneous-metamorphic evolution of the Grenville-aged basement rocks of the Cuyania terrane occurred over a period of more than 200 million years, with ages older than 1200 Ma up to those close to 1000 Ma. The shallowest crustal level is found in Las Matras, suggesting a southward shallowing of the exposed level of basement. The deformation and metamorphism associated with the collisional Famatinian orogeny affect both the Cuyania terrane and the adjacent western margin of Gondwana, and the Gondwana margin was also the locus of the related arc magmatism, but the compressive effects of the collision decrease in intensity toward the south. The Famatinian metamorphism and magmatism continue even further south into the Patagonia region, but the southern continuity of the Cuyania terrane into this region remains uncertain.     

Late Quaternary submarine bedforms and ice‐sheet flow in Gerlache Strait and on the adjacent continental shelf,Antarctic Peninsula

Geophysical data from Gerlache Strait, Croker Passage, Bismarck Strait and the adjacent continental shelf reveal streamlined subglacial bedforms that were produced at the bed of the Antarctic Peninsula Ice Sheet (APIS) during the last glaciation. The spatial arrangement and orientation of these bedforms record the former drainage pattern and flow dynamics of an APIS outlet up‐flow, and feeding into, a palaeo‐ice stream in the Western Bransfield Basin. Evidence suggests that together, they represent a single ice‐flow system that drained the APIS during the last glaciation. The ice‐sheet outlet flowed north/northeastwards through Gerlache Strait and Croker Passage and converged with a second, more easterly ice‐flow tributary on the middle shelf to form the main palaeo‐ice stream. The dominance of drumlins with low elongation ratios suggests that ice‐sheet outlet draining through Gerlache Strait was comparatively slower than the main palaeo‐ice stream in the Western Bransfield Basin, although the low elongation ratios may also partly reflect the lack of sediment. Progressive elongation of drumlins further down‐flow indicates that the ice sheet accelerated through Croker Passage and the western tributary trough, and fed into the main zone of streaming flow in the Western Bransfield Basin. Topography would have exerted a strong control on the development of the palaeo‐ice stream system but subglacial geology may also have been significant given the transition from crystalline bedrock to sedimentary strata on the inner–mid‐shelf. In the broader context, the APIS was drained by a number of major fast‐flowing outlets through cross‐shelf troughs to the outer continental shelf during the last glaciation. Copyright © 2004 John Wiley & Sons, Ltd.     

Palaeoenvironmental control on sediment composition and provenance in the late Quaternary deltaic successions: a case study from the Po delta area (Northern Italy)

Accumulation of continental, deltaic and shallow‐marine sediments in the Po River coastal plain preserves a record of the Late Quaternary sea‐level changes and shoreline migrations. The palaeoenvironmental evolution of this area and the changes in composition and provenance of sediments have been investigated through integrated sedimentological, micropalaeontological (mainly foraminifers) and geochemical analyses of core S1, from the southern part of the Po River delta, within a chronological framework supported by radiocarbon dating and correlations with adjacent core sequences. Eleven lithofacies, grouped into five facies associations, and four palaeontological assemblages provide the basis to define the palaeoenvironmental reconstruction of this succession consisting, from the base to the top, of: (i) continental sediments accumulated during the Late Pleistocene; (ii) back‐barrier sediments marking the onset of Holocene sea‐level rise; (iii) transgressive sands deposited during the rapid landward migration of a barrier‐lagoon system; (iv) shallow‐marine and prodelta sediments with faunal associations indicating a gradual approach to the Po River mouth; and (v) sub‐recent delta front sands that form a considerable portion of the present coastal plain. Bulk chemical composition of sediments shows remarkable relationships with palaeoenvironments and locally improves facies characterizations. For example, they reveal carbonate leaching that emphasizes the occurrence of palaeosols in continental deposits or record enrichments in loss on ignition, S and Br, diagnostic of organic‐rich layers in back‐shore sediments. Selected geochemical elements (e.g. Mg and Ni) are particularly effective for the recognition of sediment provenances from the three main source areas observed in the subsurface deposits of the Po River coastal plain (e.g. Apenninic rivers, North Adriatic rivers and Po River). An Apenninic provenance is observed in continental and back‐barrier sediments. A North Adriatic provenance characterizes the transgressive sands and the shallow‐marine deposits; a significant Po River provenance is recorded in sediments related to the onset of the prodelta environment, confirmed by foraminiferal assemblages indicating remarkable increase in fluvial influxes. Copyright © 2006 John Wiley & Sons, Ltd.     

Pre-Cenozoic intra-plate magmatism along the Central Andes (17–34°S): Composition of the mantle at an active margin

Sr–Nd–Pb isotope ratios of alkaline mafic intra-plate magmatism constrain the isotopic compositions of the lithospheric mantle along what is now the eastern foreland or back arc of the Cenozoic Central Andes (17–34°S). Most small-volume basanite volcanic rocks and alkaline intrusive rocks of Cretaceous (and rare Miocene) age were derived from a depleted lithospheric mantle source with rather uniform initial ¹⁴³Nd/¹⁴⁴Nd ( 0.5127–0.5128) and ⁸⁷Sr/⁸⁶Sr ( 0.7032–0.7040). The initial ²⁰⁶Pb/²⁰⁴Pb ratios are variable (18.5–19.7) at uniform ²⁰⁷Pb/²⁰⁴Pb ratios (15.60 ± 0.05). A variety of the Cretaceous depleted mantle source of the magmatic rocks shows elevated Sr isotope ratios up to 0.707 at constant high Nd isotope ratios. The variable Sr and Pb isotope ratios are probably due to radiogenic growth in a metasomatized lithospheric mantle, which represents the former sub-arc mantle beneath the early Palaeozoic active continental margin. Sr–Nd–Pb isotope signatures of a second mantle type reflected in the composition of Cretaceous (one late Palaeozoic age) intra-plate magmatic rocks (¹⁴³Nd/¹⁴⁴Nd  0.5123, ⁸⁷Sr/⁸⁶Sr  0.704, ²⁰⁶Pb/²⁰⁴Pb  17.5–18.5, and ²⁰⁷Pb/²⁰⁴Pb  15.45–15.50) are similar to the isotopic composition of old sub-continental lithospheric mantle of the Brazilian Shield.

Published Nd and Sr isotopic compositions of Mesozoic to Cenozoic arc-related magmatic rocks (18–40°S) represent the composition of the convective sub-arc mantle in the Central Andes and are similar to those of the Cretaceous (and rare Miocene) intra-plate magmatic rocks. The dominant convective and lithospheric mantle type beneath this old continental margin is depleted mantle, which is compositionally different from average MORB-type depleted mantle. The old sub-continental lithospheric mantle did not contribute to Mesozoic to Cenozoic arc magmatism.     

Late Quaternary river development in the southwest Chad Basin: OSL dating of sediment from the Komadugu palaeofloodplain (northeast Nigeria)

The Komadugu river system is the major Nigerian tributary to Lake Chad. Its large alluvial complex represents an important archive of the late Quaternary environmental history of the Chad Basin. Modern floodplains are incised into an older fluvial terrace that extends over 5000 km². Evidence from satellite images suggests that the ancient river system was dammed up by the Bama Beach Ridge during high stands of mega Lake Chad. This caused the formation of extensive wetlands with a chaotic network of relic channels. The first set of luminescence ages presented here fits well into the previously established environmental history of the Chad Basin. Both the early and mid‐Holocene pluvial periods as well as a final relatively humid period during the late Holocene are reflected by point bar to overbank deposits or channel fills. The onset of the Holocene was characterised by erosion of older dune fields as indicated by grain‐size distributions of the alluvium. Satellite images and sedimentological observations show that the floodplain was dominated by meandering channels shifted by frequent avulsion, reflecting a high variability in precipitation and discharge patterns at the beginning and end of Holocene humid periods. Copyright © 2007 John Wiley & Sons, Ltd.