Effect of rock mass disturbance on the stability of rock slopes using the Hoek–Brown failure criterion

The process of creating man made or “cut” slopes in rock invariably leads to stress relief within the rock mass which in turn induces a certain degree of fracturing and disturbance. The level of disturbance can be particularly significant when the slope is formed using blasting techniques. However, the effects of this disturbance on the overall rock slope stability have not been investigated thoroughly in the current literature. In order to account for rock mass disturbance during construction, a disturbance factor has been included in the Hoek–Brown failure criterion [1]. This paper uses finite element upper and lower bound limit analyses to estimate rock slope stability based on the Hoek–Brown failure criterion whilst including the effect of rock mass disturbance. A rigorous set of analyses have been performed where the level of disturbance is considered as constant or linearly varying throughout the slope. The results are then compared to a number of reported case histories for verification purposes. From the results of this study, the disturbance factor was found to have significant influence on the rock slope stability assessment, especially for poorer quality rock masses. Hence, cautious engineering judgement must be exercised when estimating the level of disturbance. In addition, utilising stability charts to estimate the stability of cut rock slopes without considering the rock mass disturbance may lead to significant overestimations.     

Contrasting rock permeability in the aureole of the Ballachulish igneous complex, Scottish Highlands: the influence of surface energy?

The Ballachulish igneous complex in the Scottish Highlands, part of a widespread group of late Caledonian calcalkaline intrusions, was emplaced at a depth of 10 km into Dalradian metasediments resulting in melting of the country rocks near the intrusive contact. The greatest extent of melting occurred in the Leven schist in the 400 m wide so-called Chaotic Zone which experienced infiltration of aqueous fluids from the pluton. In contrast, adjacent to the Chaotic Zone, the feldspar-bearing Appin quartzite underwent significant melting only within a few metres of the intrusion, despite both being in contact with the same fluid source as the Leven schist and having a similar (wet) melting point. The permeability of the Appin quartzite and quartz horizons in the Leven schist to pervasive grain-edge infiltration of aqueous fluids was determined by measuring the equilibrium quartz-H₂O dihedral angle for the P-T conditions of contact metamorphism. Addition of powdered samples of both rock types to the pure quartz-H₂O system results in a linear decrease of the quartz-H₂O dihedral angle with increasing temperature. The rate of this decrease for the Leven schist is greater than that for the Appin quartzite, and the angle decreases below 60° some 30 °C below the wet solidus (670 °C at 0.3 GPa). Charges bearing Appin quartzite had dihedral angles greater than 60° at all temperatures below the wet solidus (690 °C at 0.3 GPa). These results demonstrate that quartz-rich horizons in the Leven schist would have been permeable to infiltration of aqueous fluids close to the solidus, permitting extensive H₂O-fluxed melting to occur. The Appin quartzite would have remained impermeable to grain-edge flow, consistent with the observed differences in the extent of partial melting of the two lithologies. Received: 25 November 1996 / Accepted: 29 October 1997     

Dynamic stability analysis of rock slope considering the strength vibration degradation of through-type rock discontinuitiesEI北大核心

考虑结构面抗剪强度震动退化效应对分析与评价岩质边坡动力稳定性具有重要意义。基于岩石动力试验获取了多因素影响的结构面强度震动退化系数方程,结合极限平衡理论和动态矢量法原理,以UDEC程序作为计算引擎,采用其内置Fish语言编程实时刷新结构面强度特性参数和捕获任意地震历时时刻边坡地震惯性力,并以最小平均安全系数法求解边坡最终动力稳定性评价指标值,从而提出了一种考虑结构面强度震动退化的边坡动力稳定性系数动态算法。研究表明:结构面强度震动退化系数是取决于岩块间循环剪切次数、循环剪切幅度及相对运动速度响应值的动态变量;将该算法应用于含贯通型平直状结构面边坡动力稳定性算例中,其分析结果表明,动力作用时程内考虑结构面强度震动退化的边坡动力稳定性系数较未考虑该效应时的系数衰减更为明显,即前者计算结果更符合一般性自然规律,亦即验证了该算法的可行性;结构面最小强度震动退化系数随动力激励时程变化近似呈负指数函数形式逐渐衰减,且当结构面初始黏聚力(内摩擦角)越大、而坡角(层面倾角)或动荷载幅值(频率)越小时,地震历时过程中边坡最小动力稳定性系数越大,此时边坡最终动力稳定性相对越强。     

Snow avalanches striking water basins: behaviour of the avalanche’s centre of mass and front

Gutenberg and Richter developed an empirical relation, \(\log_{10} N(M) = a - bM\), to quantify the seismicity rate of various magnitudes in a given region and time period. They found the equation fit observed data well both globally and for particular regions. In conventional G–R relation, N(M) represents an arithmetic mean. As a result, the arithmetic standard deviation cannot be explicitly incorporated in the log-linear G–R relation. Moreover, this representation is susceptible to influence of spuriously large numbers of aftershocks of major earthquake sequences. To overcome these shortcomings, we propose an alternative representation of the G–R relation in terms of the logarithmic mean annual seismicity rate and its standard deviation. We select the crustal earthquake data from 1973 to 2011, as listed in the National Earthquake Information Center (NEIC) global catalog and the Central Weather Bureau (CWB) Taiwan regional catalog, to illustrate our methodology. We first show that by using the logarithmic annual seismicity rates we can significantly suppress the influences of spuriously large numbers of aftershocks following major earthquake sequences contained in the Taiwan regional catalog. More significantly, both the logarithmic mean annual seismicity rate and its standard deviation can be explicitly represented in the Gutenberg–Richter relation as follows:

$${\text{For}}\,{\text{global}}\,{\text{crustal}}\,{\text{seismicity}}{:}\;\log_{10} N = 8.14 - 1.03M \pm (0.04M - 0.13);$$

$${\text{For}}\,{\text{Taiwan}}\;{\text{crustal}}\,{\text{seismicity}}{:}\;\log_{10} N = 5.62 - 0.90M \pm (0.02M + 0.17)$$

where log₁₀ N represents the logarithmic annual seismicity rate. Above analytical equations are very well constrained by observed global seismicity data with \(5.0 \le M \le 7.0\) and by Taiwan seismicity data with \(3.0 \le M \le 5.0\). Both equations can be extrapolated with confidence to simultaneously estimate not only the median annual seismicity rates but also their uncertainties for large earthquakes for the first time since inception of the G–R relation. These equations can be used to improve the conventional probabilistic seismic hazard assessment by including the dispersion of the annual seismicity rate. Finally, the corresponding numerical median annual seismicity rate with its upper and lower bounds obtained from above equations for \(5.0 \le M \le 9.0\) is listed in Table 1.

Table 1 Observed and estimated median annual seismicity rate and return period with their dispersions for Taiwan and global crustal earthquakes

Magnitude	Catalog
	Taiwan catalog (CWB)	Taiwan catalog (CWB)	Global catalog (NEIC)	Global catalog (NEIC)
	Annual rate (event/year)	Return period (year)	Annual rate (event/year)	Return period (year)
M ≥ 5.0	24.55 13.18 7.08	0.041 0.076 0.14	1148.16 977.24 831.76	0.0009 0.001 0.0012
M ≥ 5.5	8.91 4.68 2.45	0.11 0.21 0.41	367.28 298.54 242.66	0.0027 0.0033 0.0041
M ≥ 6.0	3.24 1.66 0.85	0.31 0.60 1.18	117.49 91.20 70.79	0.0085 0.011 0.014
M ≥ 6.5	1.17 0.59 0.30	0.85 1.69 3.33	37.58 27.86 20.65	0.027 0.036 0.048
M ≥ 7.0	0.43 0.21 0.10	2.33 4.76 10.0	12.02 8.51 6.03	0.083 0.12 0.17
M ≥ 7.5	0.15 0.074 0.036	6.67 13.51 27.78	3.85 2.60 1.76	0.26 0.38 0.57
M ≥ 8.0	0.056 0.026 0.012	17.86 38.46 83.33	1.23 0.79 0.51	0.81 1.27 1.96
M ≥ 8.5	0.020 0.009 0.004	50.00 111.11 250.0	0.39 0.24 0.15	2.56 4.17 6.67
M ≥ 9.0	0.0074 0.0033 0.0015	135.14 303.03 666.67	0.13 0.074 0.04	7.69 13.51 25.00

Observed value is shown in bold number, estimated value in regular number \(\log_{10} N = 5.62 - 0.90M \pm (0.02M + 0.17)\) for Taiwan crustal earthquakes \(\log_{10} N = 8.14 - 1.03M \pm (0.04M - 0.13)\) for global crustal earthquakes

     

Metacarbonatite or marble? — the case of the carbonate,pyroxenite, calcite–apatite rock complex at Borra,Eastern Ghats,India

Carbonatites are often of economic importance, which raises the problem of distinguishing carbonatites from limestones when either are metamorphosed to high-grade marbles. They can be of similar appearance, particularly those from the Proterozoic and Archaean of the Indian Subcontinent. This study also contributes to solving the problem of determining the frequency of alkaline and carbonatitic magmatism during the early history of the Earth.The mineral assemblage of apatite–magnetite–phlogopite–calcite is common to marbles of both carbonatite and limestone origin. If pyrochlore is present that identifies the rock as carbonatite; if anorthite, fassaite, scapolite or spinel then it was formerly a limestone. If these minerals are absent, then trace element analysis can supply the critical Sr and REE data, which are both normally high in carbonatitic rocks and low in former limestones. These distinguishing factors are applied to the metamorphic carbonate, pyroxenite, calcite–apatite rock complex at Borra, Eastern Ghats, India, which has been variously interpreted as formerly a carbonatite and as a limestone. The evidence shows that the Borra rocks are meta-sedimentary.     

Fluid–rock interaction during subsolidus microtextural development of alkali granite as exemplified by the Saertielieke pluton,Ulungur of the northern Xinjiang,China

Three lithological Groups I (medium-grained, with magmatogenic arfvedsonite), II (medium-grained, with secondary arfvedsonite) and III (fine-grained, with magmatogenic arfvedsonite) are identified in the Saertielieke alkali granite pluton, Ulungur of the northern Xinjiang, China. A weak negative correlation between the δ¹⁸O values of alkali feldspar and quartz separates from each group, and the distinctly lower δ¹⁸O values of alkali feldspar separates from Groups I and II than those from Group III are interpreted in terms of superimposed closed-system and open-system isotope exchange. A small amount of locally exsolved magmatic fluid is involved in the development of the perthitic texture in alkali feldspar at ∼400 °C that results in a volume increase and, hence, causes quartz deformation. The microtextural changes promote the closed-system oxygen isotope exchange between quartz and alkali feldspar that causes a dispersion in the quartz δ¹⁸O values. However, the distinctly lower δ¹⁸O values of alkali feldspar and secondary arfvedsonite coupled with their microtextural characteristics indicate that meteoric-derived water plays an important role in the further development of alkali feldspar exsolution texture at T<400 °C and directly causes secondary arfvedsonite formation. The estimated relative exchange rates k_Quartz/k_Feldspar/k_Arfvedsonite of ∼10/100/1 for Groups I and III, and ∼10/100/100 for Group II suggest that alkali feldspar, quartz, and secondary arfvedsonite have exchanged with meteoric-derived water mainly via dissolution–reprecipitation, whereas magmatogenic arfvedsonite has exchanged via diffusion.     

Rock Maker: an MS Excel? spreadsheet for the calculation of rock compositions from proportional whole rock analyses, mineral compositions, and modal abundance

Rock Maker is a simple software tool that computes bulk rock compositions resulting from mixing or unmixing of rocks or minerals. The calculations describe the chemical expression of processes such as magma mixing, fractional crystallization, assimilation, residual melt extraction, or formation of solid solutions. Rock Maker can also be used for the elimination of thermodynamically inactive or unwanted chemical components from the whole rock composition, such as cores of porphyroblasts that are considered not to be in equilibrium with the matrix. The calculation of the resulting rock composition is essentially based on modal proportions and compositions of different components in rocks, which may include specific portions of the rock or individual mineral phases. Compositional data, obtained using XRF, ICPMS, EDS, or EPMA, may include major and trace element concentrations. Depending upon the nature of the problem to be solved, the concentrations of oxidic and elemental components can be added to, or subtracted from, each other, producing the calculated normalized whole rock composition after completion of the investigated process (mixing, unmixing, depletion, enrichment, etc.). Furthermore, the software allows the calculation of whole rock compositions from ideal mineral compositions, for which modal proportions can be chosen from pre-defined mineral compositions. The data set includes the most common rock forming minerals and allows the addition of further phases. This section can be used to calculate the approximate whole rock compositions from petrographic modal analysis. This part of Rock Maker is specifically suitable as a teaching tool that illustrates the interrelationship between mineral compositions, modes, and the corresponding whole rock compositions.     

Irreversible water–rock mass transfer accompanying the generation of the neutral,Mg–HCO3 and high-pH,Ca–OH spring waters of the Genova province,Italy

In a recent survey of the spring waters of the Genova province, many neutral Mg–HCO₃ waters and some high-pH, Ca–OH waters were found in association with serpentinites. All the springs are of meteoric origin as indicated by the stable isotopes of water and dissolved N₂ and Ar. Interaction of these meteoric waters with serpentinites determines a progressive evolution in the chemistry of the aqueous phase from an immature Mg-rich, SO₄–Cl facies of low salinity to an intermediate Mg–HCO₃ facies (pH 7.0–8.5, P_CO210^−3.5–10^−2.5 bar, Eh 150–250 mV), and to a mature Ca–OH facies (pH 10–12, P_CO2 10^−9.4−10^−10.6 bar, Eh-390 to-516 mV). The irreversible water–rock mass transfer leading to these chemical changes in the aqueous phase was simulated through reaction path modeling, assuming bulk dissolution of a local serpentinite, and the precipitation of gibbsite, goethite, calcite, hydromagnesite, kaolinite, a montmorillonite solid mixture, a saponite solid mixture, sepiolite, and serpentine. The simulation was carried out in two steps, under open-system and closed-system conditions with respect to CO₂, respectively. The calculated concentrations agree with analytical data, indicating that the computed water-rock mass transfer is a realistic simulation of the natural process. Moreover, the simulation elucidates the role of calcite precipitation during closed-system serpentinite dissolution in depleting the aqueous solution of C species, allowing the concurrent increment in Ca and the acquisition of a Ca–OH composition. Calcium–OH waters, due to their high pH, tend to absorb CO₂, precipitating calcite. Therefore, these waters might be used to sequester anthropogenic CO₂, locally preventing environmental impact to the atmosphere.     

Fe isotope systematics of coexisting amphibole and pyroxene in the alkaline igneous rock suite of the Ilímaussaq Complex,South Greenland

The Ilímaussaq intrusion, South Greenland, provides an exceptional test case for investigating the changes of stable Fe isotope fractionation of solidus phases with changes in the Fe³⁺/∑Fe ratio of an evolving melt. The intrusion comprises a sequence of four melt batches that were fed from the same parental alkali basaltic magma. Differentiation produced cumulate rocks that range from augite syenite (phase I) over peralkaline granite (phase II) to agpaitic syenites (phases IIIa and IIIb). Fe³⁺/∑Fe ratios in amphiboles increase substantially from phase I to phase II and III rocks and mark a major change in the parental magma composition from augite syenites to peralkaline granites and agpaitic syenites. Before this transition, olivine, clinopyroxene, and amphibole in augite syenite, the most primitive rock type in the Ilímaussaq Complex, have a uniform Fe isotope composition that is identical to that of the bulk of igneous crustal rocks and approximated by the average isotopic composition of basalts (δ^56/54Fe_IRMM-014 = 0.072 ± 0.046‰). After the transition, amphiboles in the peralkaline granites and agpaitic syenites yield significantly heavier Fe isotope compositions with δ^56/54Fe_IRMM-014 values ranging from 0.123 to 0.237‰. Contamination of the Ilímaussaq magma by ongoing crustal assimilation as cause for this increase can be excluded on the grounds of Nd isotope data. Large-scale metasomatic overprint with an external fluid can also be dismissed based on amphibole O and Li isotope systematics. Rather, the increase towards heavy Fe isotope compositions most likely reflects the change in chemical compositions of amphiboles (calcic in augite syenite to sodic in the agpaitic syenites) and their Fe³⁺/ΣFe ratios that mirror changes in the chemical composition of the melt and its oxygen fugacity. A sensitive adjustment of equilibrium Fe isotope fractionation factors to amphibole ferric/ferrous ratios is also supported by beta-factors calculated from Mössbauer spetroscopy data. Comparison of the measured isotope fractionation between clinopyroxene and amphibole with that predicted from Mössbauer data reveal Fe isotope systematics close to equilibrium in augite syenites but Fe isotopic disequilibrium between these two phases in phase IIIa agpaitic syenites. These results are in agreement with O and Li isotope systematics. While amphiboles in all Ilímaussaq lithologies crystallized at temperatures between 650 and 850 °C, textural evidence reveals later clinopyroxene crystallization at temperatures as low as 300–400 °C. Therefore, isotopic equilibrium at crystallization conditions between these two phases can not be expected, but importantly, subsolidus reequilibration can also be dismissed.     

Effect of Groundwater Radiolysis on the Wall—rock Alteration of Uranium Ore Deposits

Reported for the first time in this paper are the results of simulating experiments on the γ-irradiation-induced oxidation of Fe^2 under the physicochemical conditions(T=200℃，P=50MPa,Eh=-0.1V,pH=7.2)simial to those under which moderate-low temperature hydrothermal uranium deposits are formed.Evdence shows that the effect of groundwater radiolysis seems to be the major mechanism of wall-rock alteration(hematitizaton)of hydrothermal uranium deposits.Moreover,adiscussion was made of possible effects of radiolysis of the water-rock system on wall-rock alterations including argillization and decoloration of uranium ore deposits on the basis of the experimental results.     

Geochemical modelling of fluid–rock interactions in the context of the Soultz-sous-Forêts geothermal system

The development of the Enhanced Geothermal System (EGS) at Soultz-sous-Forêts (France) has given to scientists an interesting opportunity for the application of geochemical modelling of water–rock interactions, combining theoretical studies with field and experimental data. The main results of four successive and complementary studies are summarized: geochemical modelling of fluid–rock interactions with prediction of dissolution/precipitation of minerals, feed-back effects on the mineralogy and petrography of the rock (major role of silicates in the geological past and of carbonates in the near future of the exploitation), experimental control of the dynamics of silicates under thermal gradient and relation between the evolution of the petrophysics of the rocks and the heat and mass transfers. The thermal cycle of the fluid, between 200 °C and 65 °C in the geothermal loop, may be responsible for dissolution/precipitation of minerals which modify the porosity and permeability of the granite, as it happened in the geological past, in relation with hydrothermal circulations in the Rhine Graben.     

The origin of fluids and nature of fluid–rock interaction in mid-crustal auriferous mylonites of the Renco mine, southern Zimbabwe

Geothermometric constraints on auriferous shear zones of the Renco mine in the Northern Marginal Zone of the late-Archaean, granulite-facies Limpopo Belt in southern Zimbabwe indicate that deformation and associated mineralization occurred at temperatures of at least 600 °C up to more likely 700 °C. Mid- to upper-amphibolite facies conditions during mineralization correspond to the regional-scale retrogression of granulite facies wall rocks during the late-Archaean thrusting of high-grade metamorphic rocks of the Northern Marginal Zone onto low- to medium-grade granite-greenstone terrains of the Zimbabwe craton. Mineral assemblages indicate that the ore fluid was moderately oxidized with log f_O2 values between 10⁻¹⁷ and 10⁻¹⁸ bars with high H₂S activities of 0.25–0.75. Elements enriched in the shear zones include Au, S, Fe, Cu, Mo, Bi, Te, Ni, Co, and H₂O, Au and Cu being the most enriched. Geochemically, Au correlates with Cu but not with S, which, together with the fact that gold is only rarely intergrown or in direct contact with sulfides, possibly indicates a transport of gold as a chloride complex. The siting of gold along fractures or within implosion breccias suggests that gold was precipitated due to fluid immiscibility induced by catastrophic fluid pressure drops during seismic slip events. Fluid inclusions are predominantly CO₂ (±CH₄ ± N₂)-rich, but petrographic work indicates that fluid inclusions have undergone extensive post-entrapment modifications due to the pervasive recrystallization of mineral textures in the high-temperature shear zones. The mineralized shear zones are enriched in ¹⁸O compared to wall-rock enderbites, which is interpreted to represent an influx of externally derived fluids of probably metamorphic origin. Based on temporal and spatial relationships between mineralization, late-Archaean overthrusting of the Northern Marginal Zone onto the Zimbabwe craton, and coeval amphibolite-facies hydration of granulites, we suggest that the Renco mineralization formed in a mid-crustal environment from metamorphic fluids that were generated from dehydration of subcreted greenstone terrains of the Zimbabwe craton. Received: 27 October 1998 / Accepted: 13 August 1999     

Modeling of water–rock interactions in an aquitard of sandy clay in the coastal area near Beihai,China

Unconsolidated sand, gravel and clay deposits near Beihai and in the Leizhou Peninsula in southern China form an unconfined aquifer, aquitard and a confined aquifer. Water and soil samples were collected from the two aquifers in the coastal Beihai area for the determination of chemical compositions, minerals and soluble ions. Hydrogeochemical modeling of three flow paths through the aquitard are carried out using PHREEQC to determine water–rock interactions along the flow paths. The results indicate that the dissolution of anorthite, fluorite, halite, rhodochrosite and CO₂, and precipitation of potash feldspar and kaolinite may be occurring when groundwater leaks through the aquitard from the unconfined aquifer to the confined aquifer. Cation exchanges between Na and Ca can also happen along the flow paths.     

Geochronology and geochemistry of a dyke–host rock association and implications for the formation of the Bavarian Pfahl shear zone, Bohemian Massif

To place constraints on the formation and deformation history of the major Variscan shear zone in the Bavarian Forest, Bavarian Pfahl zone, SW Bohemian Massif, granitic dykes and their feldspar-phyric massive host rock (so-called palite), zircons were dated by the U–Pb isotope dilution and Pb-evaporation methods. The dated samples comprise two host rocks and four dykes from a K-rich calc-alkaline complex adjoining the SW part of the Bavarian Pfahl shear zone. The palites, which appear to be the oldest magmatic rocks emplaced in the shear zone, yield ages of 334±3, 334.5±1.1 Ma (average ²⁰⁷Pb/²⁰⁶Pb-evaporation zircon ages) and 327–342 Ma (range of U/Pb zircon ages) suggesting a Lower Carboniferous age for the initiation of the Pfahl zone. Absence of inherited older cores in all investigated zircons indicates that incorporation of crustal zircon material has played virtually no role or that the melting temperature was very high. Determination of the dyke emplacement age is complicated by partial Pb-loss in most of the fractions analysed. This Pb-loss can be ascribed to higher U content of the dyke zircons compared to those from host rock. Upper discordia intercept ages of the different dykes range from 322±5 to 331±9 Ma. The dykes are pre- to synkinematic with respect to penetrative regional mylonitisation along the Pfahl zone, and the upper intercept ages provide a maximum age for this tectonic event.     

Overview of geological and hydrogeological conditions of the Äspö hard rock laboratory site

The site of the underground facility, the Äspö Hard Rock Laboratory, was excavated at a depth of 450 m below the island of Äspö and has been extensively investigated by geological, hydrogeological and hydrochemical methods as part of the geoscientific research for disposal of nuclear waste in Sweden. The geological history of the area dates back to 1.85 Ga and is dominated by granitoids belonging to the Trans-Scandinavian Igneous Belt but also includes basic sheets and xenoliths and dikes of fine-grained granite. Seven tectonic episodes, giving rise to fracture mineralization, are recognised. The major discontinuities and fracture zones were characterised from surface investigations before the tunnel construction work started. These structural features were also identified in the tunnel and are, as predicted, the major water conducting features. Sets of open fractures in the NNW–NW and N–S directions and the brittle fine-grained granite are other important water conductors. Groundwater flow modelling shows that the location of Äspö island has a major impact on the current distribution of groundwater salinity due to varying hydraulic/boundary/conditions in the late and post glacial period.     

Non-double-couple mechanisms of microearthquakes induced during the 2000 injection experiment at the KTB site, Germany: A result of tensile faulting or anisotropy of a rock?

Moment tensors of microearthquakes induced during the 2000 injection experiment at the KTB deep drilling borehole at a depth level of 5.4 km are studied. A family of 37 most reliable moment tensors contains significant non-double-couple (non-DC) components. The DC is on average 60% and the non-DC is 40%. Fault plane solutions computed from the DC part show preferred strike-slip mechanisms with small normal or reverse components. A predominant azimuth of P and T axes is in the range of N320°–340°E and of N230°–250°E, respectively. The non-DC components contain both the isotropic (ISO) and compensated linear vector dipole (CLVD) components. The mean value of ISO is 1.5%, the mean value of CLVD is − 5.7%. The predominantly negative CLVD components are inconsistent with the concept of the non-DC mechanisms as a result of tensile faulting due to fluid injection into the rock. The main origin of the non-DC components is probably anisotropy in the focal area. The other origins are errors produced by mismodelling of the medium when calculating the Green functions, and numerical errors produced by noise and limitations of input data. Adopting four alternative models of anisotropy obtained by other seismic measurements at the KTB, we have employed the non-DC components for estimating an optimum orientation of anisotropy in the focal area. The optimum orientation of the symmetry plane of anisotropy is nearly vertical with a strike of N335°–340°E. This strike coincides well with the strike of 330° typical for many major lithological units and faults and with the orientation of the transversely isotropic model inferred by other authors. After removing the anisotropy effects from the moment tensors by calculating the source tensors, the distribution of ISO is significantly narrowed. This indicates predominantly shear, but not tensile faulting.     

Mesozoic–Cenozoic sedimentary rock records and applications for provenance of sediments and affiliation of the Simao Terrane,SW China

ABSTRACT

As the north part of Simao Terrane, Lanping Basin is located between the Sanjiang Tethys Orogen (STO) and Yangtze Block, also the junction zone between the Gondwanaland and Cathaysian old land (Pan Huaxia mainland), which includes Yangtze and Cathaysian Blocks. The aim of this study is to decipher the provenance of the sedimentary units in the Lanping Basin and affiliation of Simao Terrane by the U-Pb ages, Hf isotope of detrital zircons and whole-rock geochemistry. The whole-rock geochemistry and the mineral composition indicate that most of the Triassic–Paleocene sedimentary rocks are derived from the upper crust and exhibit recycled orogen features. The detrital zircon U-Pb ages from the North Simao Terrane are consistent with the magmatic events during Early Neoproterozoic and Permian in the Western Yangtze Block. And the detrital zircons ages from North Simao Terrane show same distribution features as the Permian–Triassic magmatic rocks, which are distributed in the Simao Terrane and along major sutures. These comparisons suggest that the clastic sediments in Lanping Basin (North Simao Terrane) are derived from Early Neoproterozoic and Permian magmatic rocks from Western Yangtze Block, Permian–Triassic magmatic rocks from Simao Terrane, along Jinshajiang, Garz-Litang and Ailaoshan Sutures. The comparison of the detrital zircon age distributions shows that Simao Terrane and Yangtze Block exhibited similarity tectonic setting in the evolution history, especially during Paleoproterozoic–Late Paleozoic. This suggests that the Simao Terrane is part of Cathaysian old land, although Simao Terrane was separated from Yangtze Block for short period during Early Paleozoic. Besides, the Hf mapping, stratigraphic succession, paleogeography and paleomagnetism in SW China support that Simao Terrane has a Cathaysian old land-affinity, rather than one involving Gondwanaland.     

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.