Maintenance of equatorial superrotation in the atmospheres of Venus and Titan

This paper extends Leovy's theory on Venus’ equatorial superrotation by analytically examining additional terms in the mean zonal momentum equation that stably balances the momentum source of pumping by thermal tides. The general analytical solution is applied to the atmospheres of both Venus and Saturn's moon Titan. The main results are: (i) Venus’ equatorial superrotation of 118 m s⁻¹ results primarily from a balance between the momentum source of pumping by thermal tides and the momentum sink of meridional advection of wind shear by horizontal branches of the Hadley circulation; (ii) no solution is found for Titan's stratospheric equatorial superrotation centered at the 1-hPa level; (iii) however, if the main solar radiation absorption layer in Titan's stratosphere is lifted from 1 hPa (∼185 km) to 0.1 hPa (∼288 km), an equatorial superrotation of ∼110 m s⁻¹ centered at 0.1-hPa could be maintained. Titan's equatorial superrotation results mainly from a balance between the momentum source of tidal pumping and the momentum sink of frictional drag.     

Ion flow and momentum transfer in the Venus plasma environment

An analysis of ion data from 390 Venus Express, VEX, orbits demonstrates that the flow of solar wind- and ionospheric ions near Venus is characterized by a marked asymmetry. The flow asymmetry of solar wind H⁺ and ionospheric O⁺ points steadily in the opposite direction to the planet’s orbital motion, and is most pronounced near the Pole and in the tail/nightside region. The flow asymmetry is consistent with aberration forcing, here defined as lateral forcing induced by the planet’s orbital motion. In addition to solar wind forcing by the radial solar wind expansion, Venus is also subject a lateral/aberration forcing induced by the planet’s orbital motion transverse to the solar wind flow.The ionospheric response to lateral solar wind forcing is analyzed from altitude profiles of the ion density, ion velocity and ion mass-flux. The close connection between decreasing solar wind H⁺ mass-flux and increasing ionospheric O⁺ mass-flux, is suggestive of a direct/local solar wind energy and momentum transfer to ionospheric plasma. The bulk O⁺ ion flow is accelerated to velocities less than 10 km/s inside the dayside/flank Ionopause, and up to 6000 km in the tail. Consequently, the bulk O⁺ outflow does not escape, but remains near Venus as a fast (km/s) O⁺ zonal wind in the Venus polar and nightside upper ionosphere. Furthermore, the total O⁺ mass-flux in the Venus induced magnetosphere, increases steadily downward to a maximum of 2 × 10⁻¹⁴ kg/(m² s) at ≈400 km altitude, suggesting a downward transport of energy and momentum. The O⁺, and total mass-flux, decay rapidly below 400 km. With no other plasma mass-flux as replacement, we argue that the reduction of ion mass-flux is caused by ion-neutral drag, a transfer of ion energy and momentum to neutrals, implying that the O⁺ plasma wind is converted to a neutral (thermosphere) wind at Venus. Incidentally, such a neutral wind would go in the same direction as the Venus atmosphere superrotation.     

Observable effects of convection and gravity waves on the Venus condensational cloud

We present results of a simple two-dimensional model investigating the observable effects that convective motions and gravity waves can have on the condensational Venus cloud. Gravity waves have been observed in the Venus atmosphere in the form of temperature scintillations in the Magellan and Pioneer Venus occultation data. Multiple in situ probes and long-duration remote observations indicate the presence of convective motions in the Venus clouds. Dynamical studies by others have suggested that gravity waves can exist in the stable regions of the Venus atmosphere above the middle clouds and beneath the middle clouds, and likely are triggered by flow past sub-cloud plumes caused by convective overshooting. We find that a simplified treatment of convective kinematics generates variation in the Venus condensational cloud consistent with the observed variability of optical depth and brightness temperature. Specifically, we find that the downdraft regions in our simulated convective cell exhibit a decrease in cloud optical depth of around Δτ∼10. The brightness temperature ranges from about 460 K in the downdraft regions of the simulated convective cells, to about 400 K in the simulated updrafts. We also find that gravity waves launched by obstacles (such as overshooting convective plumes) near the cloud base exhibit horizontal wavelengths comparable to the separation between convective cells, and generate variations in brightness temperature that should be observable by instruments such as VIRTIS on Venus Express. However, a more robust treatment of the atmospheric dynamics is needed to address adequately these interactions between the clouds and the mesoscale dynamics.     

Venus astra/novae: Estimates of the absolute time duration of their activity

In order to assess the age relations between astra/novae (features with extensive radial fracture-graben systems) and their surroundings, and to determine the duration of their activity, we undertook a photogeologic analysis of Magellan images of 78 astra, 49 dark-parabola craters and 114 clear-halo craters. For seven of these 78 astra it was found that the astrum-forming faulting started before or close to the time of emplacement of regional plains and extended into the second part of post-regional-plains time. Because the mean age of the regional plains is close to the mean surface age of Venus (which is estimated to be ∼750 m.y), this means that the duration of activity of these seven astra was several hundred millions of years. This is longer than the duration of activity of ongoing mantle plumes on Earth, but shorter than the duration of activity of the plume feeding the martian volcano Olympus Mons. The basic morphologic characteristics of these seven astra, as well as their age relations with other geologic units, are similar to those of the majority of other astra; therefore, such a long duration could also be typical of some other astra. We confirm the two-phase (pre- and post-regional-plains) evolution of astrum-forming faulting suggested in previous studies. For the first phase we show evidence for purely tectonic faulting caused by the diapiric rise of a mantle plume. For the second phase we find evidence supporting the interpretation of other studies that the observed faults resulted from subsurface dike intrusions produced by magmatism associated with the plume. We also found that faulting during the second phase was not instantaneous but distributed over a long period of time.     

EUV spectroscopy of the Venus dayglow with UVIS on Cassini

We analyze EUV spatially-resolved dayglow spectra obtained at 0.37 nm resolution by the UVIS instrument during the Cassini flyby of Venus on 24 June 1999, a period of high solar activity level. Emissions from OI, OII, NI, CI and CII and CO have been identified and their disc average intensity has been determined. They are generally somewhat brighter than those determined from the observations made with the HUT spectrograph at a lower activity level, We present the brightness distribution along the foot track of the UVIS slit of the OII 83.4 nm, OI 98.9 nm, Lyman-ß + OI 102.5 nm and NI 120.0 nm multiplets, and the CO C-X and B-X Hopfield-Birge bands. We make a detailed comparison of the intensities of the 834 nm, 989 nm, 120.0 nm multiplets and CO B-X band measured along the slit foot track on the disc with those predicted by an airglow model previously used to analyze Venus and Mars ultraviolet spectra. This model includes the treatment of multiple scattering for the optically thick OI, OII and NI multiplets. It is found that the observed intensity of the OII emission at 83.4 nm is higher than predicted by the model. An increase of the O⁺ ion density relative to the densities usually measured by Pioneer Venus brings the observations and the modeled values into better agreement. The calculated intensity variation of the CO B-X emission along the track of the UVIS slit is in fair agreement with the observations. The intensity of the OI 98.9 nm emission is well predicted by the model if resonance scattering of solar radiation by O atoms is included as a source. The calculated brightness of the NI 120 nm multiplet is larger than observed by a factor of ∼2-3 if photons from all sources encounter multiple scattering. The discrepancy reduces to 30-80% if the photon electron impact and photodissociation of N₂ sources of N(⁴S) atoms are considered as optically thin. Overall, we find that the O, N₂ and CO densities from the empirical VTS3 model provide satisfactory agreement between the calculated and the observed EUV airglow emissions.     

The post-terminator ionosphere of Venus

We have modeled the near and post-terminator thermosphere/ionosphere of Venus with a view toward understanding the relative importance of EUV solar fluxes and downward fluxes of atomic ions transported from the dayside in producing the mean ionosphere. We have constructed one-dimensional thermosphere/ionosphere models for high solar activity for seven solar zenith angles (SZAs) in the dusk sector: 90°, 95°, 100°, 105°, 110°, 115° and 125°. For the first 4 SZAs, we determine the optical depths for solar fluxes from 3 Å to 1900 Å by integrating the neutral densities numerically along the slant path through the atmosphere. For SZAs of 90°, 95°, and 100°, we first model the ionospheres produced by absorption of the solar fluxes alone; for 95°, 100°, and 105° SZAs, we then model the ion density profiles that result from both the solar source and from imposing downward fluxes of atomic ions, including O⁺, Ar⁺, C⁺, N⁺, H⁺, and He⁺, at the top of the ionospheric model in the ratios determined for the upward fluxes in a previous study of the morphology of the dayside (60° SZA) Venus ionosphere. For SZAs of 110°, 115° and 125°, which are characterized by shadow heights above about 300 km, the models include only downward fluxes of ions. The magnitudes of the downward ion fluxes are constrained by the requirement that the model O⁺ peak density be equal to the average O⁺ peak density for each SZA bin as measured by the Pioneer Venus Orbiter Ion Mass Spectrometer. We find that the 90° and 95° SZA model ionospheres are robust for the solar source alone, but the O⁺ peak density in the “solar-only” 95° SZA model is somewhat smaller than the average value indicated by the data. A small downward flux of ions is therefore required to reproduce the measured average peak density of O⁺. We find that, on the nightside, the major ion density peaks do not occur at the altitudes of peak production, and diffusion plays a substantial role in determining the ion density profiles. The average downward atomic ion flux for the SZA range of 90–125° is determined to be about 1.2 × 10⁸ cm⁻² s⁻¹.     

Microscale simulations of Venus’ convective adjustment and mixing near the surface: Thermal and material transport processes

Heat and material transport processes caused by convective adjustment and mixing are important in modeling of Venus’ atmosphere. In the present study, microscale atmospheric simulations near the venusian surface were conducted using a Weather Research and Forecasting model to elucidate the thermal and material transport processes of convective adjustment and mixing. When convective adjustment occurs, the heat and passive tracer are rapidly mixed into the upper stable layer with convective penetration. The convective adjustment produces large eddy diffusions of heat and passive tracer, which may explain the large eddy diffusions estimated in the radiative-convective equilibrium model.For values of surface heat flux Q greater than a threshold (=0.064 K m s⁻¹ in the present study), the convectively mixed layer with high eddy diffusion coefficients grows with time. In contrast, the mixed layer decays with time for Q values smaller than the threshold. The thermal structure near the surface is controlled not only by extremely long-term radiative processes, but also by microscale dynamics with time scales of several hours. A mixed layer with high eddy diffusion coefficients may be maintained or grow with time if the surface heat flux is high in the volcanic hotspot and adjacent areas.     

UVIS observations of the FUV OI and CO 4P Venus dayglow during the Cassini flyby

We analyze FUV spatially-resolved dayglow spectra obtained at 0.37 nm resolution by the UVIS instrument during the Cassini flyby of Venus. We use a least-squares fit method to determine the brightness of the OI emissions at 130.4 and OI 135.6 nm, and of the bands of the CO fourth positive system which are dominated by fluorescence scattering. We compare the brightness observed along the UVIS foot track of the two OI multiplets with that deduced from a model of the excitation of these emissions by photoelectron impact on O atoms and resonance scattering of the solar 130.4 nm emission. The large optical thickness 130.4 nm emission is accounted for using a radiative transfer model. The airglow intensities are calculated along the foot track and found to agree with the observed 130.4 nm brightness within ∼10%. The modeled OI 135.6 nm brightness is also well reproduced by the model. The oxygen density profile of the VTS3 model is found to be consistent with the observations. We find that self-absorption of the (0, v″) bands of the fourth positive emission of CO is important and we derive a CO vertical column of about 6.4 × 10¹⁵ cm⁻² in close agreement with the value provided by the VTS3 empirical atmospheric model.     

Venus night airglow: Ground-based detection of OH, observations of O2 emissions, and photochemical model

Venus nightglow was observed at NASA IRTF using a high-resolution long-slit spectrograph CSHELL at LT = 21:30 and 4:00 on Venus. Variations of the O₂ airglow at 1.27 μm and its rotational temperature are extracted from the observed spectra. The mean O₂ nightglow is 0.57 MR at 21:30 at 35°S-35°N, and the temperature increases from 171 K near the equator to ∼200 K at ±35°. We have found a narrow window that covers the OH (1-0) P1(4.5) and (2-1) Q1(1.5) airglow lines. The detected line intensities are converted into the (1-0) and (2-1) band intensities of 7.2 ± 1.8 kR and <1.4 kR at 21:30 and 15.5 ± 2 kR and 4.7 ± 1 kR at 4:00. The f-component of the (1-0) P1(4.5) line has not been detected in either observation, possibly because of resonance quenching in CO₂. The observed Earth’s OH (1-0) and (2-1) bands were 400 and 90 kR at 19:30 and 250 and 65 kR at 9:40, respectively. A photochemical model for the nighttime atmosphere at 80-130 km has been made. The model involves 61 reactions of 24 species, including odd hydrogen and chlorine chemistries, with fluxes of O, N, and H at 130 km as input parameters. To fit the OH vibrational distribution observed by VEX, quenching of OH (v > 3) in CO₂ only to v ? 2 is assumed. According to the model, the nightside-mean O₂ emission of 0.52 MR from the VEX and our observations requires an O flux of 2.9 × 10¹² cm⁻² s⁻¹ which is 45% of the dayside production above 80 km. This makes questionable the nightside-mean O₂ intensities of ∼1 MR from some observations. Bright nightglow patches are not ruled out; however, the mean nightglow is ∼0.5 MR as observed by VEX and supported by the model. The NO nightglow of 425 R needs an N flux of 1.2 × 10⁹ cm⁻² s⁻¹, which is close to that from VTGCM at solar minimum. However, the dayside supply of N at solar maximum is half that required to explain the NO nightglow in the PV observations. The limited data on the OH nightglow variations from the VEX and our observations are in reasonable agreement with the model. The calculated intensities and peak altitudes of the O₂, NO, and OH nightglow agree with the observations. Relationships for the nightglow intensities as functions of the O, N, and H fluxes are derived.     

Spatially-resolved high-resolution spectroscopy of Venus 2. Variations of HDO, OCS, and SO2 at the cloud tops

While CO, HCl, and HF, that were considered in the first part of this work, have distinct absorption lines in high-resolution spectra and were detected four decades ago, the lines of HDO, OCS, and SO₂ are either very weak or blended by the telluric lines and have not been observed previously by ground-based infrared spectroscopy at the Venus cloud tops. The H₂O abundance above the Venus clouds is typically below the detection limit of ground-based IR spectroscopy. However, the large D/H ratio on Venus facilitates observations of HDO. Converted to H₂O with D/H ≈ 200, our observations at 2722 cm⁻¹ in the Venus afternoon show a H₂O mixing ratio of ∼1.2 ppm at latitudes between ±40° increasing to ±60° by a factor of 2. The observations in the early morning reveal the H₂O mixing ratio that is almost constant at 2.9 ppm within latitudes of ±75°. The measured H₂O mixing ratios refer to 74 km. The observed increase in H₂O is explained by the lack of photochemical production of sulfuric acid in the night time. The recent observations at the P-branch of OCS at 4094 cm⁻¹ confirm our detection of OCS. Four distributions of OCS along the disk of Venus at various latitudes and local times have been retrieved. Both regular and irregular components are present in the variations of OCS. The observed OCS mixing ratio at 65 km varies from ∼0.3 to 9 ppb with the mean value of ∼3 ppb. The OCS scale height is retrieved from the observed limb darkening and varies from 1 to 4 km with a mean value of half the atmospheric scale height. SO₂ at the cloud tops has been detected for the first time by means of ground-based infrared spectroscopy. The SO₂ lines look irregular in the observed spectra at 2476 cm⁻¹. The SO₂ abundances are retrieved by fitting by synthetic spectra, and two methods have been applied to determine uncertainties and detection limits in this fitting. The retrieved mean SO₂ mixing ratio of 350 ± 50 ppb at 72 km favors a significant increase in SO₂ above the clouds since the period of 1980-1995 that was observed by the SOIR occultations at Venus Express. Scale heights of OCS and SO₂ may be similar, and the SO₂/OCS ratio is ∼500 and may be rather stable at 65-70 km under varying conditions on Venus.     

Atmospheric angular momentum variations of Earth, Mars and Venus at seasonal time scales

Atmospheric angular momentum variations of a planet are associated with the global atmospheric mass redistribution and the wind variability. The exchange of angular momentum between the fluid layers and the solid planet is the main cause for the variations of the planetary rotation at seasonal time scales. In the present study, we investigate the angular momentum variations of the Earth, Mars and Venus, using geodetic observations, output of state-of-the-art global circulation models as well as assimilated data. We discuss the similarities and differences in angular momentum variations, planetary rotation and angular momentum exchange for the three terrestrial planets. We show that the atmospheric angular momentum variations for Mars and Earth are mainly annual and semi-annual whereas they are expected to be “diurnal” on Venus. The wind terms have the largest contributions to the LOD changes of the Earth and Venus whereas the matter term is dominant on Mars due to the CO₂ sublimation/condensation. The corresponding LOD variations (ΔLOD) have similar amplitudes on Mars and Earth but are much larger on Venus, though more difficult to observe.     

Spatially-resolved high-resolution spectroscopy of Venus 1. Variations of CO2, CO, HF, and HCl at the cloud tops

Variations of the upper cloud boundary and the CO, HF, and HCl mixing ratios were observed using the CSHELL spectrograph at NASA IRTF. The observations were made in three sessions (October 2007, January 2009, and June 2009) at early morning and late afternoon on Venus in the latitude range of ±60°. CO₂ lines at 2.25 μm reveal variations of the cloud aerosol density (∼25%) and scale height near 65 km. The measured reflectivity of Venus at low latitudes is 0.7 at 2.25 μm and 0.028 at 3.66 μm, and the effective CO₂ column density is smaller at 3.66 μm than those at 2.25 μm by a factor of 4. This agrees with the almost conservative multiple scattering at 2.25 μm and single scattering in the almost black aerosol at 3.66 μm. The expected difference is just a factor of (1 − g)⁻¹ = 4, where g = 0.75 is the scattering asymmetry factor for Venus’ clouds. The observed CO mixing ratio is 52 ± 4 ppm near 08:00 and 40 ± 4 ppm near 16:30 at 68 km, and the higher ratio in the morning may be caused by extension of the CO morningside bulge to the cloud tops. The observed weak limb brightening in CO indicates an increase of the CO mixing ratio with altitude. HF is constant at 3.5 ± 0.2 ppb at 68 km in both morningside and afternoon observations and in the latitude range ±60°. Therefore the observations do not favor a bulge of HF, though HF is lighter than CO. Probably a source in the upper atmosphere facilitates the bulge formation. The recent measurements of HCl near 70 km are controversial (0.1 and 0.74 ppm) and require either a strong sink or a strong source of HCl in the clouds. The HCl lines of the (2-0) band are blended by the solar and telluric lines. Therefore we observed the P8 lines of the (1-0) band at 3.44 μm. These lines are spectrally clean and result in the HCl mixing ratio of 0.40 ± 0.03 ppm at 74 km. HCl does not vary with latitude within ±60°. Our observations support a uniformly mixed HCl throughout the Venus atmosphere.     

Sulfur chemistry in the Venus mesosphere from SO2 and SO microwave spectra

First measurements of SO₂ and SO in the Venus mesosphere (70-100 km) are reported. This altitude range is distinctly above the ∼60-70 km range to which nadir-sounding IR and UV investigations are sensitive. Since July 2004, use of ground-based sub-mm spectroscopy has yielded multiple discoveries. Abundance of each molecule varies strongly on many timescales over the entire sub-Earth Venus hemisphere. Diurnal behavior is evident, with more SO₂, and less SO, at night than during the day. Non-diurnal variability is also present, with measured SO₂ and SO abundances each changing by up to 2× or more between observations conducted on different dates, but at fixed phase, hence identical sub-Earth Venus local times. Change as large and rapid as a 5σ doubling of SO on a one-week timescale is seen. The sum of SO₂ and SO abundances varies by an order of magnitude or more, indicating at least one additional sulfur reservoir must be present, and that it must function as both a sink and source for these molecules. The ratio SO₂/SO varies by nearly two orders of magnitude, with both diurnal and non-diurnal components. In contrast to the strong time dependence of molecular abundances, their altitude distributions are temporally invariant, with far more SO₂ and SO at 85-100 km than at 70-85 km. The observed increase of SO₂ mixing ratio with altitude requires that the primary SO₂ source be upper mesospheric photochemistry, contrary to atmospheric models which assert upward transport as the only source of above-cloud SO₂. Abundance of upper mesospheric aerosol, with assumption that it is composed primarily of sulfuric acid, is at least sufficient to provide the maximum gas phase (SO + SO₂) sulfur reported in this study. Sulfate aerosol is thus a plausible source of upper mesospheric SO₂.     

Scattering particles in nightside limb observations of Venus’ upper atmosphere by Venus Express VIRTIS

Nightside infrared limb spectra of the Venus upper atmosphere, obtained by Venus Express VIRTIS, show strong scattering of thermal radiation. This scattering of upward-going radiation into the line-of-sight is dominant below 82.5 km even at a wavelength of 5 μm, which is indicative of relatively large particles. We show that 1 μm-sized sulfuric acid particles (also known as mode 2 particles) provide a good fit to the VIRTIS limb data at high altitudes. We retrieve vertical profiles of the mode 2 number density between 75 and 90 km at two latitude ranges: 20-30°N and 47-50°N. Between 20 and 30°N, scattering by mode 2 particles is the main source of radiance for altitudes between 80 and 85 km. Above altitudes of 85 km smaller particles can also be used to fit the spectra. Between 47 and 50°N mode 2 number densities are generally lower than between 20 and 30°N and the profiles show more variability. This is consistent with the 47-50° latitude region being at the boundary between the low latitudes and high latitudes, with the latter showing lower cloud tops and higher ultraviolet brightness (Titov, D.V., Taylor, F.W., Svedhem, H., Ignatiev, N.I., Markiewicz, W.J., Piccioni, G., Drossart, P. [2008]. Nature 456, 620-623).     

A layer of ozone detected in the nightside upper atmosphere of Venus

To date, ozone has only been identified in the atmospheres of Earth and Mars. This study reports the first detection of ozone in the atmosphere of Venus by the SPICAV ultraviolet instrument onboard the Venus Express spacecraft. Venusian ozone is characterized by a vertically confined and horizontally variable layer residing in the thermosphere at a mean altitude of 100 km, with local concentrations of the order of 10⁷–10⁸ molecules cm⁻³. The observed ozone concentrations are consistent with values expected for a chlorine-catalyzed destruction scheme, indicating that the key chemical reactions operating in Earth’s upper stratosphere may also operate on Venus.     

Comparative study of ion cyclotron waves at Mars, Venus and Earth

Ion cyclotron waves are generated in the solar wind when it picks up freshly ionized planetary exospheric ions. These waves grow from the free energy of the highly anisotropic distribution of fresh pickup ions, and are observed in the spacecraft frame with left-handed polarization and a wave frequency near the ion’s gyrofrequency. At Mars and Venus and in the Earth’s polar cusp, the solar wind directly interacts with the planetary exospheres. Ion cyclotron waves with many similar properties are observed in these diverse plasma environments. The ion cyclotron waves at Mars indicate its hydrogen exosphere to be extensive and asymmetric in the direction of the interplanetary electric field. The production of fast neutrals plays an important role in forming an extended exosphere in the shape and size observed. At Venus, the region of exospheric proton cyclotron wave production may be restricted to the magnetosheath. The waves observed in the solar wind at Venus appear to be largely produced by the solar-wind-Venus interaction, with some waves at higher frequencies formed near the Sun and carried outward by the solar wind to Venus. These waves have some similarity to the expected properties of exospherically produced proton pickup waves but are characterized by magnetic connection to the bow shock or by a lack of correlation with local solar wind properties respectively. Any confusion of solar derived waves with exospherically derived ion pickup waves is not an issue at Mars because the solar-produced waves are generally at much higher frequencies than the local pickup waves and the solar waves should be mostly absorbed when convected to Mars distance as the proton cyclotron frequency in the plasma frame approaches the frequency of the solar-produced waves. In the Earth’s polar cusp, the wave properties of ion cyclotron waves are quite variable. Spatial gradients in the magnetic field may cause this variation as the background field changes between the regions in which the fast neutrals are produced and where they are re-ionized and picked up. While these waves were discovered early in the magnetospheric exploration, their generation was not understood until after we had observed similar waves in the exospheres of Mars and Venus.     

Vertical profile of H2SO4 vapor at 70-110 km on Venus and some related problems

The vertical profile of H₂SO₄ vapor is calculated using current atmospheric and thermodynamic data. The atmospheric data include the H₂O profiles observed at 70-112 km by the SOIR solar occultations, the SPICAV-UV profiles of the haze extinction at 220 nm, the VeRa temperature profiles, and a typical profile of eddy diffusion. The thermodynamic data are the saturated vapor pressures of H₂O and H₂SO₄ and chemical potentials of these species in sulfuric acid solutions. The calculated concentration of sulfuric acid in the cloud droplets varies from 85% at 70 km to a minimum of 70% at 90 km and then gradually increasing to 90-100% at 110 km. The H₂SO₄ vapor mixing ratio is ∼10⁻¹² at 70 and 110 km with a deep minimum of 3 × 10⁻¹⁸ at 88 km. The H₂O-H₂SO₄ system matches the local thermodynamic equilibrium conditions up to 87 km. The column photolysis rate of H₂SO₄ is 1.6 × 10⁵ cm⁻² s⁻¹ at 70 km and 23 cm⁻² s⁻¹ at 90 km. The calculated abundance of H₂SO₄ vapor at 90-110 km and its photolysis rate are smaller than those presented in the recent model by Zhang et al. (Zhang, X., Liang, M.C., Montmessin, F., Bertaux, J.L., Parkinson, C., Yung, Y.L. [2010]. Nat. Geosci. 3, 834-837) by factors of 10⁶ and 10⁹, respectively. Assumptions of 100% sulfuric acid, local thermodynamic equilibrium, too warm atmosphere, supersaturation of H₂SO₄ (impossible for a source of SO_X), and cross sections for H₂SO₄·H₂O (impossible above the pure H₂SO₄) are the main reasons of this huge difference. Significant differences and contradictions between the SPICAV-UV, SOIR, and ground-based submillimeter observations of SO_X at 70-110 km are briefly discussed and some weaknesses are outlined. The possible source of high altitude SO_X on Venus remains unclear and probably does not exist.     

Magnetic states of the ionosphere of Venus observed by Venus Express

Strong ultraviolet radiation from the Sun ionizes the upper atmosphere of Venus, creating a dense ionosphere on the dayside of the planet. In contrast to Earth, the ionosphere of Venus is not protected against the solar wind by a magnetic field. However, the interaction between charged ionospheric particles and the solar wind dynamic and magnetic pressure creates a pseudo-magnetosphere which deflects the solar wind flow around the planet (Schunk and Nagy, 1980). The combination of changing solar radiation and solar wind intensities leads to a highly variable structure and plasma composition of the ionosphere. The instrumentation of the Venus Express spacecraft allows to measure the magnetic field (MAG experiment) as well as the electron energy spectrum and the ion composition (ASPERA-4 experiment) of the upper ionosphere and ionopause. In contrast to the earlier Pioneer Venus Orbiter (PVO) measurements which were conducted during solar maximum, the solar activity was very low in the period 2006-2009. A comparison with PVO allows for an investigation of ionospheric properties under different solar wind and EUV radiation conditions. Observations of MAG and ASPERA have been analyzed to determine the positions of the photoelectron boundary (PEB) and the “magnetopause” and their dependence on the solar zenith angle (SZA). The PEB was determined using the ELS observations of ionospheric photoelectrons, which can be identified by their specific energy range. It is of particular interest to explore the different magnetic states of the ionosphere, since these influence the local plasma conductivity, currents and probably the escape of electrons and ions. The penetration of magnetic fields into the ionosphere depends on the external conditions as well as on the ionospheric properties. By analyzing a large number of orbits, using a combination of two different methods, we define criteria to distinguish between the so-called magnetized and unmagnetized ionospheric states. Furthermore, we confirm that the average magnetic field inside the ionosphere shows a linear dependence on the magnetic field in the region directly above the PEB.     

Venus Express observations of ULF and ELF waves in the Venus ionosphere: Wave properties and sources

Electrical activity in a planetary atmosphere enables chemical reactions that are not possible under conditions of local thermodynamic equilibrium. In both the Venus and terrestrial atmospheres, lightning forms nitric oxide. Despite the existence of an inventory of NO at Venus like the Earth’s, and despite observations of the signals expected from lightning at optical, VLF, and ELF frequencies, the existence of Venus lightning still is met with some skepticism. The Venus Express mission was equipped with a fluxgate magnetometer gradiometer system sampling at rates as high as 128 Hz, and making measurements as low as 200 km altitude above the north polar regions of Venus. However, significant noise levels are present on the Venus Express spacecraft. Cleaning techniques have been developed to remove spacecraft interference at DC, ULF, and ELF frequencies, revealing two types of electromagnetic waves, a transverse right-handed guided mode, and a linearly polarized compressional mode. The propagation of both types of signals is sensitive to the magnetic field in ways consistent with propagation from a distant source to the spacecraft. The linearly polarized compressional waves generally are at lower frequencies than the right-handed transverse waves. They appear to be crossing the usually horizontal magnetic field. At higher frequencies above the lower hybrid frequency, waves cannot enter the ionosphere from below when the field is horizontal. The arrival of signals at the spacecraft is controlled by the orientation of the magnetic field. When the field dips into the atmosphere, the higher frequency guided mode above the lower hybrid frequency can enter the ionosphere by propagating along the magnetic field in the whistler mode. These properties are illustrated with examples from five orbits during Venus Express’ first year in orbit. These properties observed are consistent with the linearly polarized compressional waves being produced at the solar wind interface and the transverse guided waves being produced in the atmosphere.     

Near infrared imaging spectroscopy of Venus with the Anglo-Australian Telescope

We have obtained full-disk spatially resolved spectra of the Venus nightside at near-infrared wavelengths during July 2007 using the Anglo-Australian Telescope and Infrared Imager and Spectrograph 2 (IRIS2). The data have been used to map the intensity and rotational temperature of the O₂(a¹Δ_g) airglow band at . The temperatures agree with those obtained in earlier IRIS2 observations and are significantly higher than expected from the Venus International Reference Atmosphere (VIRA) profile. We also report the detection of the corresponding ν=0-1O₂ airglow band at with a similar spatial distribution to the ν=0-0 band. Observations in the thermal window have been used to image surface topography using two different methods of cloud correction. We have also obtained images that can be used to study cloud motion.