MORICE--new technology for mechanical oil recovery in ice infested waters

Mechanical oil recovery in ice infested waters (MORICE) was initiated in 1995 to develop technology for the recovery of oil spills in ice. It has been a multinational effort involving Norwegian, Canadian, American and German organizations and researchers. Through a stepwise approach with the development organized in six separate phases, laboratory tests and field experiments have been conducted to study various ideas and concepts, and to refine the ideas that were considered to have the best potential for removing oil in ice. Put together in one unit, these concepts included ice processing equipment and two alternative oil recovery units installed on a work platform. In January 2002, the final oil and ice testing with MORICE concepts was conducted at the Ohmsett test facility in Leonardo, New Jersey. The unit has been referred to as a harbor version to indicate the size and operating conditions, but the concepts could be scaled up to increase the capacity of oil and ice processing. For heavier ice conditions it would also be necessary to increase the overall strength.     

An oil spill-food chain interaction model for coastal waters

An oil spill-food chain interaction model, composed of a multiphase oil spill model (MOSM) and a food chain model, has been developed to assess the probable impacts of oil spills on several key marine organisms (phytoplankton, zooplankton, small fish, large fish and benthic invertebrates). The MOSM predicts oil slick thickness on the water surface; dissolved, emulsified and particulate oil concentrations in the water column; and dissolved and particulate oil concentrations in bed sediments. This model is used to predict the fate of oil spills and transport with respect to specific organic compounds, while the food chain model addresses the uptake of toxicant by marine organisms. The oil spill-food chain interaction model can be used to assess the environmental impacts of oil spills in marine ecosystems. The model is applied to the recent Evoikos-Orapin Global oil spill that occurred in the Singapore Strait.     

河口海域水流挟沙能力分析

水流挟沙力是反映河床处于冲淤平衡状态下水流挟带泥沙能力的综台性指标。作者通过对众多挟沙力公式的分析比较,基于量纲和谐的考虑,建立了新的挟沙力公式形式。本文以长江口的泥沙输运为例,利用长江口泥沙实测资料,研究了新建立的挟沙力公式在长江口的适用性。计算结果表明,本文作者建立的公式在长江口具有一定的适用性,与刘家驹公式相比较,计算精度差不多,计算结果尚令人满意,但还存在一定的误差,说明将本文建立的挟沙力公式进行率定后,可以将其推广到近岸河口海域,为工程实践提供有益的参考价值。     

基于粗糙集的低阻油层灰色评价

在进行低阻油层识别的过程中,影响判别的测井参数众多,存在大量的冗余信息,从而影响判别的精度和速度.而常规的识别方法又不能有效地识别低阻油层,为此,本文提出了将粗糙集(RS)理论与灰色系统理论相结合的方法进行信息优化,并应用于低阻油层的识别.在剖析粗糙集理论和灰色关联方法的基础上,提出了基于粗糙集的低阻油层灰色识别过程.首先选取反映该类油层特征的识别参数,然后采用粗集理论的属性重要性方法,对这些判别参数进行约简,剔除冗余信息,再将约简后的参数作为低阻油层的最终评价标准,输入灰色系统,最后利用灰色关联法对低阻油层进行识别.通过对某油田18口有测试资料的井进行了实证研究.研究结果表明:粗集理论的属性重要性方法可以有效地约简判别参数,将约简后的参数作为灰色系统的初始值对研究区低阻油层进行识别,通过降维大大提高了判别的运算速度,处理了原来被解释为水层和油水层而实际上是低阻油层的井段,与测试结果相比,识别的准确率达到97%.     

Formation waters discharge to rivers near oil sands projects

Groundwater discharges in the western Canadian oil sands region impact river water quality. Mapping groundwater discharges to rivers in the oil sands region is important to target water quality monitoring efforts and to ensure injected wastewater and steam remain sequestered rather than eventually resurfacing. Saline springs composed of Pleistocene‐aged glacial meltwater exist in the region, but their spatial distribution has not been mapped comprehensively. Here we show that formation waters discharge into 3 major rivers as they flow through the Athabasca Oil Sands Region adjacent to many active oil sands projects. These discharges increase river chloride concentrations from river headwaters to downstream reaches by factors of ~23 in the Christina River, ~4 in the Clearwater River, and ~5 in the Athabasca River. Our survey provides further evidence for the substantial impact of formation water discharges on river water quality, even though they comprise less than ~2% of total streamflow. Geochemical evidence supporting formation water discharges as the leading control on river salinity include increases in river chloride concentrations, Na/(Na + Ca) ratios, Cl/(Cl + SO₄) ratios and decreases in ⁸⁷Sr/⁸⁶Sr ratios; each mixing trend is consistent with saline groundwater discharges sourced from Cretaceous or Devonian aquifers. These regional subsurface‐to‐surface connections signify that injected wastewater or steam may potentially resurface in the future, emphasizing the critical importance of mapping groundwater flow paths to understand present‐day streamflow quality and to predict the potential for injected fluids to resurface.     

油田企业贮油(液)罐抗震能力评价方法

油田设施抗震能力评价方法和实践是目前各多地震国家地震工程学术界和工程界广泛关注的课题。本文以贮油(液)罐为研究对象,以其抗震设计方法为依据,开发出其抗震能力评价方法,并用胜利油田立式贮油(液)罐为例,实践了这一方法。     

Potential for photoenhanced toxicity of spilled oil in Prince William Sound and Gulf of Alaska waters

Photoenhanced toxicity is the increase in the toxicity of a chemical in the presence of ultraviolet light (UV) compared to a standard laboratory test conducted with fluorescent lighting (minimal UV). Oil products, weathered oil, and specific polycyclic aromatic compounds present in oil are 2 to greater than 1000 times more toxic in the presence of UV. The photoenhanced toxicity of oil to fish and aquatic invertebrates appears to occur through a process of photosensitization, rather than photomodification of the aqueous phase oil. In photosensitization, the bioaccumulated chemical transfers light energy to other molecules causing toxicity through tissue damage rather than a narcosis mechanism. The available evidence indicates that phototoxic components of oil are specific 3-5 ring polycyclic aromatic hydrocarbons (PAHs) and heterocycles. Determinants of photoenhanced toxicity include the extent of oil bioaccumulation in aquatic organisms and the spectra and intensity of UV exposure. No studies have specifically investigated the photoenhanced toxicity of spilled oil in Alaska waters. Although there are substantial uncertainties, the results of this evaluation indicate there is potential for photoenhanced toxicity of spilled oil in Prince William Sound and the Gulf of Alaska. The potential hazard of photoenhanced toxicity may be greatest for embryo and larval stages of aquatic organisms that are relatively translucent to UV and inhabit the photic zone of the water column and intertidal areas. Photoenhanced toxicity should be considered in oil spill response because the spatial and temporal extent of injury to aquatic organisms may be underestimated if based on standard laboratory bioassays and existing toxicity databases. Additionally, the choice of counter measures and oil removal operations may influence the degree of photoenhanced toxicity.     

Modeling oil spill trajectory in coastal waters based on fractional Brownian motion

This paper proposes a numerical method to simulate oil spill trajectories, which are affected by the combination of advection, turbulent diffusion and mechanical spreading process, based on a particle tracking algorithm. Recent studies have shown that the trajectories of drifters on the ocean surface have a fractal structure that is far from being described using ordinary Brownian motion. Thus, in modeling the diffusion process, a discrete method has been employed for the generation of fractional Brownian motion (fBm) to illustrate superdiffusive transport. The algorithm is implemented to predict oil slick trajectories following the “Arteaga” oil spill accident that occurred near the Dalian coastal region in 2005. When compared with the observed data and the results of traditional diffusion modeling, the numerical results based on the fBm model are encouraging.     

SAR observation and model tracking of an oil spill event in coastal waters

Oil spills are a major contributor to marine pollution. The objective of this work is to simulate the oil spill trajectory of oil released from a pipeline leaking in the Gulf of Mexico with the GNOME (General NOAA Operational Modeling Environment) model. The model was developed by NOAA (National Oceanic and Atmospheric Administration) to investigate the effects of different pollutants and environmental conditions on trajectory results. Also, a Texture-Classifying Neural Network Algorithm (TCNNA) was used to delineate ocean oil slicks from synthetic aperture radar (SAR) observations. During the simulation, ocean currents from NCOM (Navy Coastal Ocean Model) outputs and surface wind data measured by an NDBC (National Data Buoy Center) buoy are used to drive the GNOME model. The results show good agreement between the simulated trajectory of the oil spill and synchronous observations from the European ENVISAT ASAR (Advanced Synthetic Aperture Radar) and the Japanese ALOS (Advanced Land Observing Satellite) PALSAR (Phased Array L-band Synthetic Aperture Radar) images. Based on experience with past marine oil spills, about 63.0% of the oil will float and 18.5% of the oil will evaporate and disperse. In addition, the effects from uncertainty of ocean currents and the diffusion coefficient on the trajectory results are also studied.     

Visualization of spatial patterns and temporal trends for aerial surveillance of illegal oil discharges in western Canadian marine waters

This paper examines the use of exploratory spatial analysis for identifying hotspots of shipping-based oil pollution in the Pacific Region of Canada’s Exclusive Economic Zone. It makes use of data collected from fiscal years 1997/1998 to 2005/2006 by the National Aerial Surveillance Program, the primary tool for monitoring and enforcing the provisions imposed by MARPOL 73/78. First, we present oil spill data as points in a “dot map” relative to coastlines, harbors and the aerial surveillance distribution. Then, we explore the intensity of oil spill events using the Quadrat Count method, and the Kernel Density Estimation methods with both fixed and adaptive bandwidths. We found that oil spill hotspots where more clearly defined using Kernel Density Estimation with an adaptive bandwidth, probably because of the “clustered” distribution of oil spill occurrences. Finally, we discuss the importance of standardizing oil spill data by controlling for surveillance effort to provide a better understanding of the distribution of illegal oil spills, and how these results can ultimately benefit a monitoring program.     

Hebei Spirit oil spill monitored on site by fluorometric detection of residual oil in coastal waters off Taean, Korea

The spatiotemporal distributions of dissolved and/or dispersed oil in seawater and pore water were monitored on site by fluorometric detection method after the Hebei Spirit oil spill. The oil concentrations in intertidal seawater, 15 days after the spill, were as high as 16,600 μg/L and appeared to decrease below the Korean marine water quality standard of 10 μg/L at most sites 10 months after the spill. Fluorometric detection of oil in pore water was introduced to eliminate the effects of grain size for the quantification of oil in sediments and to better explain spatial and temporal distribution of oil pollution at sandy beaches. The fluorescence detection method was compared with the conventional laboratory technique of total petroleum hydrocarbon analysis using gas chromatography. The method of fluorescence detection of oil was capable of generating results much faster and more cost-effectively than the traditional GC technique.     

Effect of depression storage capacity on overland‐flow generation for rough horizontal surfaces: water transfer distance and scaling

Overland‐flow triggering on rough surfaces was investigated using an understanding‐oriented model. The model was based on conditioned‐walker technique and developed to simulate and analyse the evolution of puddle connection on numerically generated rough surfaces. The percolation theory gave a theoretical framework to formalize model outputs and to study overland‐flow scaling. Overland‐flow triggering appeared consistent with a percolation process. A scale‐change exponent was suggested. New insights based on the concept of transfer distance of water were emphasized. Transfer distance enabled us to analyse the water redistribution inside a field and helped to define rainfall efficiency when infiltration occurred. Copyright © 2002 John Wiley & Sons, Ltd.     

Trends in chronic marine oil pollution in Danish waters assessed using 22 years of beached bird surveys

Beached bird surveys provide an important tool for monitoring the level of oil pollution at sea, which is the most significant observable cause of death for a large number of waterbird species and pose a serious threat to wintering seabird populations. Linear regression analyses of oil rates from the Danish 22 year dataset show a decline in the oil pollution level in offshore areas of the eastern North Sea and Skagerrak and in near-shore parts of the Kattegat; but a worsening in the offshore areas of the Kattegat. These results raise concern for species such as common scoter, velvet scoter, eider and razorbill, for which the Kattegat serves as a globally important wintering area. It is recommended that surveillance for oil spills is intensified in inner Danish waters, and that action is taken to make responses towards offenders faster, and penalties for oil seepage higher.     

Sampling for isotopic responses in surface waters

This paper considers situations in which stable isotopes may be used as natural tracers of precipitation through to surface waters. Two aspects affecting the applicability of the technique are highlighted: first, the variance through time of isotope concentrations in precipitation, i.e. the isotope input signal, and second, the attenuation or damping of this signal during the transmission of water downwards through the hydrological system. Both factors affect the likelihood of obtaining an isotope response, i.e. a variation of isotope concentrations in a surface water which may be related to variations in the precipitation input. Analysis of precipitation over the Malham area, U.K., reveals large isotopic variations through time. These variations, however, are only poorly correlated with meteorological variables (temperature, precipitation amount, and air mass type). Snowmelt and occluded frontal rainfall are suggested as providing the most reliable ‘spikes’ for an isotopic response at the output in tracing studies. In most hydrological systems, a high degree of signal attenuation is noted. In the Malham area of karst, 57 per cent of the total range of input variation was lost in surface waters, whilst 74 per cent was lost in mobile soil moisture. An isotopic response can only reasonably be expected in a system with rapid throughput, where there is little opportunity for mixing and storage of waters.     

Fluid flow through rough fractures in rocks. II: A new matching model for rough rock fractures

An understanding of fluid flow through natural fractures in rocks is important in many areas, such as in the hydrocarbon and water industries, and in the safe design of disposal sites for domestic, industrial and nuclear waste. It is often impractical to obtain this information by field or laboratory scale measurements, so numerical modelling of fluid flow must be carried out using synthetic fractures with rough fracture surfaces that are representative of the natural rock fractures. Clearly there are two practical requirements; (i) the development of a method for analysing natural rock fractures to obtain their characteristic parameters, and (ii) the development of techniques for creating high quality synthetic fractures using these parameters. We have implemented these practical requirements in two new software packages. The first, ParaFrac allows the analysis and parameterisation of fracture surfaces and apertures. The second, SynFrac, enables the numerical synthesis of fracture surfaces and apertures with basic prescribed parameters. Synthetic fractures are created using, (i) a new model, which takes full account of the complex matching properties of fracture surfaces using two new parameters, a minimum matching fraction and a transition length and (ii) an improved method of partially correlated random number generation. This model more closely captures the often complex matching properties of real rock fractures than previous more simplified models.     

Detection of aliphatic hydrocarbons derived by recent “bio-conversion” from fossil fuel oil in North Sea waters

The higher boiling point range of saturated aliphatic hydrocarbon fractions extracted from North Sea water have been re-investigated in detail with improved high resolution glass capillary columns suitable for high temperature gas-chromatography. The resulting chromatograms reveal hydrocarbon patterns, most of which have the same common feature: a smooth distribution of the long-chain n-alkanes combined with a lack of the branched alkanes normally expected for fossil fuel oil. Instead, two homologous series of iso- and anteiso-alkanes could be detected. Since this finding is always associated with traces of present or past fossil fuel oil contamination of the upper water column, these environmental n-, iso and anteisoalkanes are considered to be recently ‘bio-converted’ from fossil fuel oil hydrocarbons. They form a third group beside recent biogenic and fossil petrogenic hydrocarbons in the marine environment. Oil pollution records of the marine environment will have to take into account this group of microbial hydrocarbons.