Precambrian mafic magmatism in the Bastar craton,central India

The Bastar craton has experienced many episodes of mafic magmatism during the Precambrian. This is evidenced from a variety of Precambrian mafic rocks exposed in all parts of the Bastar craton in the form of volcanics and dykes. They include (i) three distinct mafic dyke swarms and a variety of mafic volcanic rocks of Precambrian age in the southern Bastar region; two sets of mafic dyke swarms are sub-alkaline tholeiitic in nature, whereas the third dyke swarm is high-Si, low-Ti and high-Mg in nature and documented as boninite-norite mafic rocks, (ii) mafic dykes of varying composition exposed in Bhanupratappur-Keskal area having dominantly high-Mg and high-Fe quartz tholeiitic compositions and rarely olivine and nepheline normative nature, (iii) four suites of Paleoproterozoic mafic dykes are recognized in and around the Chattisgarh basin comprising metadolerite, metagabbro, and metapyroxenite, Neoarchaean amphibolite dykes, Neoproterozoic younger fine-grained dolerite dykes, and Early Precambrian boninite dykes, and (iv) Dongargarh mafic volcanics, which are classified into three groups, viz. early Pitepani mafic volcanic rocks, later Sitagota and Mangikhuta mafic volcanics, and Pitepani siliceous high-magnesium basalts (SHMB). Available petrological and geochemical data on these distinct mafic rocks of the Bastar craton are summarized in this paper. Recently high precision U-Pb dates of 1891.1±0.9 Ma and 1883.0±1.4 Ma for two SE-trending mafic dykes from the BD2 (subalkaline) dyke swarm, from the southern Bastar craton have been reported. But more precise radiometric age determinations for a number of litho-units are required to establish discrete mafic magmatic episodes experienced by the craton. It is also important to note that very close geochemical similarity exist between boninite-norite suite exposed in the Bastar craton and many parts of the world. Spatial and temporal correlation suggests that such magmatism occurred globally during the Neoarchaean-Paleoproterozoic boundary. Many Archaean terrains were united as a supercontinent as Expanded Ur and Arctica at that time, and its rifting gave rise to numerous mafic dyke swarms, including boninitenorite, world-wide.     

Magnetic anomalies across Bastar craton and Pranhita-Godavari basin in south of central India

Aeromagnetic anomalies over Bastar craton and Pranhita-Godavari (P-G) basin in the south of central India could be attributed to NW-SE striking mafic intrusives in both the areas at variable depths. Such intrusions can be explained considering the collision of the Bastar and Dharwar cratons by the end of the Archaean and the development of tensile regimes that followed in the Paleoproterozoic, facilitating intrusions of mafic dykes into the continental crust. The P-G basin area, being a zone of crustal weakness along the contact of the Bastar and Dharwar cratons, also experienced extensional tectonics. The inferred remanent magnetization of these dykes dips upwards and it is such that the dykes are oriented towards the east of the magnetic north at the time of their formation compared to their present NW-SE strike. Assuming that there was no imprint of magnetization of a later date, it is concluded that the Indian plate was located in the southern hemisphere, either independently or as part of a supercontinent, for some span of time during Paleoproterozoic and was involved in complex path of movement and rotation subsequently. The paper presents a case study of the utility of aeromagnetic anomalies in qualitatively deducing the palaeopositions of the landmasses from the interpreted remanent magnetism of buried intrusive bodies.     

Petrochemistry of crater facies Tokapal kimberlite pipe, Bastar craton, central India and its orangeitic affinities

Tokapal kimberlite is the only well preserved crater facies kimberlite intruded within sedimentary sequence of Indravati basin in Bastar craton of central India. We present detailed petrographical and whole rock geochemical studies, carried out on ten samples collected from different locations from Tokapal kimberlite to constrain its genesis and also the mantle processes involved in the origin of this earlier characterized Group I kimberlite. Geochemical studies show that only SiO₂ content and the mobile trace elements Ba, Sr, and K vary in the crater facies while rest others show restricted range and can be successfully used in evaluating the petrogenetic processes. Very low abundances of Rb (<2 ppm), Sr (<28 ppm), Ba (<52 ppm) and Cs (0.02–3 ppm) are observed which show possible effects of late-stage alteration rather than significant crustal contamination. The LREE enriched REE pattern, absence of positive Eu anomalies and HREE depletion also provide further additional evidence against crustal contamination considerably modifying magma composition. We infer the presence of less enriched (metasomatised) mantle source regions and comparatively greater degrees of partial melting responsible for the genesis of Tokapal kimberlite. Present study also suggests that crater facies Tokapal kimberlite intruding the Indravati basin, Bastar craton has a Group II kimberlite (orangeite) affinity. This finding is important in light of recent identification of Mainpur kimberlites of Bastar craton as orangeites.     

Tsumoite (BiTe) and associated Ni-PGE mineralization from Gondpipri mafic-ultramafic complex,Bastar Craton,Central India: mineralogy and genetic significance

This paper reports the occurrence of Tsumoite (a bismuth telluride) in the Heti Cu-Ni-PGM prospect, Gondpipri mafic-ultramafic complex, Central India. The Gondpipri complex consists of several tectonically dismembered gabbronorite-gabbro-anorthositic gabbro — olivine gabbro -websterite disposed in ～10 km long tonalite-trondhjemitegranodiorite (TTG) and charnockite-enderbite suite of rocks. The mineralization occurs in the sulphide zone hosted by gabbro variants. The host rocks have been deformed and metamorphosed to granulite grade and subjected to various degrees of hydrothermal alteration. The mineralization comprises chalcopyrite, pentlandite, pyrrhotite, cubanite, millerite, and pyrite. In addition to these, occur (1) tsumoite (2) PGM in the form of moncheite, merenskyite, Pd-mellonite, and Pt-Pd-Te-Bi-Fe-S alloy. The present study indicates that the mineralization occurs in two stages related to: (i) magmatic and (ii) hydrothermal remobilization and transport of Cu-rich sulphides, tsumoite and PGM, and their re-deposition in hydrosilicate alteration zones. It is possible that the mineralization at Heti formed at different stages of bismuth activity under variable fS₂, T, and fTe₂ conditions due to change in total concentration of Te and S and /or cooling. Since the role of S is limited, Te and cooling are important factor influencing mineralogy and composition of tsumoite and associated mineralization. Mineralization occurs in two different modes of occurrences. The early mineralisation occur as blebs, specks and dissemination of sulphides, viz. pyrrhotite, chalcopyrite, pentlandite and minor pyrite ± PGM, whereas later mineralisation occur as stringers, minor veins of sulphides viz. pyrite, millerite, cubanite, sijenite, tsumoite and ± PGM. Mineral assemblages and textural relationships at Heti has indicated precipitation of tsumoite and associated PGM along fractures and secondary silicates, which confirms their hydrothermal origin.     

Revisiting the stratigraphy of the Mesoproterozoic Chhattisgarh Supergroup,Bastar craton,India based on subsurface lithoinformation

In the last 10 years, several teams of geologists from different institutions in India and abroad have vigorously investigated the Chhattisgarh basin (Bastar craton, India). Based on the new results and the lithologs of more than 350 water wells, resistivity and gamma-ray logs, and extensive geological traverses, we present a revised geological map, relevant cross sections, a new comprehensive stratigraphic column and a discussion of the new findings. Major outcomes of this revision are: (1) confirming the existence of two sub-basins (Hirri and Baradwar) and two depocentres; (2) establishing the age of the basin to be essentially Mesoproterozoic; (3) discarding the ‘unclassified Pandaria Formation’ and classifying the package of Pandaria rock units into Chandi, Tarenga, Hirri and Maniari formations in the Hirri sub-basin; (4) accepting the ‘group’ status of the Singhora Group and the newly proposed Kharsiya Groups in the Baradwar sub-basin; (5) establishing an intrabasinal correlation of formations; (6) reappraising the thicknesses of the different formations; and (7) finding that the geometry of the basin is ‘bowl-shaped’, which is compatible with a sag model for the origin and evolution of the basin.     

Gold metallogeny associated with craton destruction: A geophysical perspective from the North China Craton

Currently ranking as the largest producer of gold in the world, China's gold reserves are spread over 200 major gold deposits and several minor deposits. A large part of these belong to the late Mesozoic gold deposits in the North China Craton (NCC) that occur along craton margins, as well as within the cratonic interior in reactivated paleo sutures, and show a close spatio-temporal relationship with zones of lithospheric thinning and craton destruction. Here we integrate and evaluate geophysical information from the NCC through an analysis of receiver function and tomography that suggest mantle upwelling accompanied by lower crustal or lithospheric delamination. Our results identify that the major gold belts in the NCC are largely located above zones of mantle upwelling and craton destruction. The faults and paleo sutures provided the pathways for migration of ore-bearing fluids, with the granitoids offering favorable conditions for gold deposition.     

The Central Bundelkhand Archaean greenstone complex,Bundelkhand craton,central India: geology,composition, and geochronology of supracrustal rocks

Analysis of 3.3 Ga tonalite–trondhjemite–granodiorite (TTG) series granitoids and greenstone belt assemblages from the Bundelkhand craton in central India reveal that it is a typical Archaean craton. At least two greenstone complexes can be recognized in the Bundelkhand craton, namely the (i) Central Bundelkhand (Babina, Mauranipur belts) and (ii) Southern Bundelkhand (Girar, Madaura belts). The Central Bundelkhand greenstone complex contains three tectonostratigraphic assemblages: (1) metamorphosed basic or metabasic, high-Mg rocks; (2) banded iron formations (BIFs); and (3) felsic volcanics. The first two assemblages are regarded as representing an earlier sequence, which is in tectonic contact with the felsic volcanics. However, the contact between the BIFs and mafic volcanics is also evidently tectonic. Metabasic high-Mg rocks are represented by amphibolites and tremolite-actinolite schists in the Babina greenstone belt and are comparable in composition to tholeiitic basalts-basaltic andesites and komatiites. They are very similar to the metabasic high-Mg rocks of the Mauranipur greenstone belt. Felsic volcanics occur as fine-grained schists with phenocrysts of quartz, albite, and microcline. Felsic volcanics are classified as calc-alkaline dacites, less commonly rhyolites. The chondrite-normalized rare earth element distribution pattern is poorly fractionated (La_N/Lu_N = 11–16) with a small negative Eu anomaly (Eu/Eu* = 0.68–0.85), being characteristic of volcanics formed in a subduction setting. On Rb – Y + Nb, Nb – Y, Rb – Ta + Yb and Ta – Yb discrimination diagrams, the compositions of the volcanics are also consistent with those of felsic rocks formed in subduction settings. SHRIMP-dating of zircon from the felsic volcanics of the Babina belt of the Central Bundelkhand greenstone complex, performed for the first time, has shown that they were erupted in Neoarchaean time (2542 ± 17 Ma). The early sequence of the Babina belt is correlatable with the rocks of the Mauranipur belt, whose age is tentatively estimated as Mesoarchaean. The Central Bundelkhand greenstone complex consists of two (Meso- and Neoarchaean) sequences, which were formed in subduction settings.     

Mafic and ultramafic magmatism and associated mineralization in the Dharwar craton,southern India

Evidence of mafic and ultramafic magmatism exists in many parts of the Dharwar craton which is divided into two blocks, the West Dharwar Craton (WDC) and the East Dharwar Craton (EDC). The mafic-ultramafic rocks occur in supracrustal/greenstone belts and in numerous enclaves and slivers in the WDC. The oldest recorded maficultramafic rocks, which are mainly komatiitic in nature, are preserved in the Sargur Group which is more than 3.3–3.4 Ga old, the youngest being manifested by 63–76 Ma old mafic dyke magmatism, possibly related to Deccan volcanism. In the Sargur Group, ultramafics rocks greatly dominate over mafic lithological units. Both extrusive and intrusive varieties, the latter in the form of differentiated layered complexes, occur. Mafic volcanics exists in all the greenstone belts of the eastern block and in the Bababudan and Western Ghats belts of the western block. In addition to the Sargur Group where stratigraphic sequences are unclear, mafic magmatism is recorded in three different formations of the Bababudan Group and two sub-divisions of the Shimoga and Chitradurga Groups where basaltic flows are conspicuous. In the well studied greenstone belts of Kolar and Hutti in the EDC, three to four different Formations of mafic volcanic rocks have been mapped. Isotopic dating has indicated that while mafic magmatism in the greenstone belts of the EDC covers only a short time span of between 2.65 to 2.75 Ga, those in the Dharwar Supergroup of the WDC cover a much longer time span from 3.35 to 2.5 Ga. Mafic dyke magmatism has taken place repeatedly from 2.45 Ga to about 1.0 Ga, but, the peak of emplacement was between 1.8 and 1.4 Ga when the densely developed swarms on the western and south western portions of the Cuddapah Basin and in the central part of Karnataka, were intruded. Emplacement of potassic ultramafic magma in the form of kimberlite-lamproite which is confined to the EDC, is a later magmatic event that took place between 1.4 Ga and 0.8 Ga. From a mineralization perspective, mafic magmatism of the supracrustal groups of the WDC and the greenstone belts of the EDC are the most important. V-Ti-magnetite bands constitute the most common deposit type recorded in the mafic-ultramafic complexes of the Sargur Group with commercially exploitable chromite deposits occurring in a number of belts. PGE mineralization of possible commercial value has so far been recorded in a single mafic-ultramafic complex, while copper-nickel mineralization occurs at certain localities in the Sargur and Chitradurga Groups. Gold mineralization hosted by mafic (occasionally ultramafic) rocks has been noted in many of the old workings located in supracrustal groups of rocks in the WDC and in the greenstone belts of EDC. Economically exploitable mineralization, however, occurs mainly in the greenstone belts of the Kolar, Ramagiri-Penkacherla and Hutti-Maski and along the eastern margin of the Chitradurga belt, where it is associated with a major N-S striking thrust zone separating the WDC from the EDC. Gold deposits of the eastern greenstone belts are comparable to those of the younger greenstone belts of Canada, Zimbabwe and Australia where the mineralization is associated with quartz carbonate veins often in iron-rich metabasic rocks. The gold was emplaced as hydrothermal fluids, derived from early komatiitic and tholeiitic magmas, and injected into suitable dilatent structures. The other common type of mineralization associated with the ultramafic rocks of the Sargur Group and supracrustal belts, particularly of the WDC, are asbestos and soapstone, related to autometamorphism/metasomatism. Ruby/sapphire deposits occur in places at the contacts of ultramafic rocks with the Peninsular Gneiss, and are related to contact metamorphism and metasomatism. Mineable magnesite deposits related to low-temperature hydrothermal/lateritic alteration exist in the zone of weathering, particularly in the more olivine-rich rocks. Recent spurt in diamond exploration is offering promise of discovering economically workable diamondiferous kimberlite/lamproite intrusions in the EDC.     

Biogeochemical studies of areas of sulphide mineralization in Northern Greece

Biogeochemical and geobotanical studies have been carried out in several areas of sulphide mineralization in northern Greece. In porphyry copper areas, mineralized zones can be delineated by mapping the distribution of Minuartia verna, or by measuring the copper content of Rumex acetosella and Thymus sibthorpii. Elevated levels of molybdenum in the soil are indicated by higher concentrations of this element in T. sibthorpii. In an area of barite mineralization, biogeochemical methods were not useful in showing the barium distribution, but did provide an indication of the associated lead mineralization. The appearance of the nickel accumulator Alyssum murale near a zone of antimonite mineralization seems to be related to sporadic occurrences of ultrabasic rocks nearby.     

Tectonostratigraphy and base-metal mineralization controls, Aravalli province (western India): New interpretations from geophysical data analysis

Analysis and synthesis of multi-disciplinary geoscience information from geological literature/maps and from digitally-processed aeromagnetic and gravity data pertinent to the Aravalli province were carried out to address some hitherto unresolved questions about the tectonostratigraphy of this Archaean–Proterozoic metallogenic province. Based on the magnetic anomalies, several tectonic domains were identified. These domains, bounded by regional-scale geophysical lineaments, have distinct crustal, lithological, metamorphic, and metallogenic characteristics and correlate broadly with lithostratigraphic belts identified by several earlier workers. New interpretations on the tectonostratigraphy and the base-metal mineralization controls in the Aravalli province are as follows. The Hindoli sequences, in the eastern parts of the province, constitute an independent Palaeo–Proterozoic tectonic domain and do not form part of the Archaean basement complex. The base-metal-bearing metasedimentary enclaves in the central parts of the province also constitute an independent Palaeo–Proterozoic tectonic domain, which is quite distinct from the surrounding (basement complex?) rocks. The base-metal-bearing metavolcano-sedimentary sequences in the western parts of the province constitute an independent Neo–Proterozoic tectonic domain. The base-metal deposits in the province are spatially associated with the regional-scale lineaments and with the mafic metavolcanic rocks deduced from the aeromagnetic data. The regional-scale lineaments, which possibly represent Proterozoic crustal-scale faults, are plausible structural controls on the base-metal mineralization in the province. The mafic metavolcanic rocks are plausible heat-source controls on the SEDEX- and/or VMS-type base-metal mineralizations and are possible metal-source controls on the VMS-type base-metal mineralization in the province.     

Tectonostratigraphy and base-metal mineralization controls,Aravalli province (western India): New interpretations from geophysical data analysis

Analysis and synthesis of multi-disciplinary geoscience information from geological literature/maps and from digitally-processed aeromagnetic and gravity data pertinent to the Aravalli province were carried out to address some hitherto unresolved questions about the tectonostratigraphy of this Archaean–Proterozoic metallogenic province. Based on the magnetic anomalies, several tectonic domains were identified. These domains, bounded by regional-scale geophysical lineaments, have distinct crustal, lithological, metamorphic, and metallogenic characteristics and correlate broadly with lithostratigraphic belts identified by several earlier workers. New interpretations on the tectonostratigraphy and the base-metal mineralization controls in the Aravalli province are as follows. The Hindoli sequences, in the eastern parts of the province, constitute an independent Palaeo–Proterozoic tectonic domain and do not form part of the Archaean basement complex. The base-metal-bearing metasedimentary enclaves in the central parts of the province also constitute an independent Palaeo–Proterozoic tectonic domain, which is quite distinct from the surrounding (basement complex?) rocks. The base-metal-bearing metavolcano-sedimentary sequences in the western parts of the province constitute an independent Neo–Proterozoic tectonic domain. The base-metal deposits in the province are spatially associated with the regional-scale lineaments and with the mafic metavolcanic rocks deduced from the aeromagnetic data. The regional-scale lineaments, which possibly represent Proterozoic crustal-scale faults, are plausible structural controls on the base-metal mineralization in the province. The mafic metavolcanic rocks are plausible heat-source controls on the SEDEX- and/or VMS-type base-metal mineralizations and are possible metal-source controls on the VMS-type base-metal mineralization in the province.     

Integrated geophysical studies to elicit the subsurface structures associated with Uranium mineralization around South Purulia Shear Zone,India: A review

South Purulia Shear Zone in India is an important zone that hosts uranium mineralization. Since detailed geophysical studies have not been carried out in this region, an integrated geophysical study using self-potential, resistivity, very low frequency electromagnetic and radiometric methods was performed to identify the subsurface structures that could host the hydrothermally altered uranium deposits in the area. The study reveals the wide and large magnitude of negative self-potential anomaly across the South Purulia Shear Zone. The peak negative self-potential anomalies are correlated with the low gravity and low resistivity anomalies measured along various profiles. The low self-potential, gravity and low resistivity anomaly zones are also correlated with conducting zones inferred from very low frequency electromagnetic measurements. Interpretation of self-potential data reveals multiple thick sheet-type vertical and/or inclined structures which might be associated with uranium mineralization. Schlumberger resistivity sounding data reveals an increasing trend of apparent resistivity with current electrode separations/depth. Apparent conductance measured simultaneously with resistivity measurement reveals an increase in current flow of current as depth increases. This exhibits the presence of thin conducting layers at these depths, which is not reflected in resistivity sounding data due to suppression problem. Also this conducting layer is consistent in various soundings and is connected from Raghunathpur to the South Purulia Shear Zone. Correlation of very low frequency and self-potential data shows that the structures are comparable and a radiometric profile also advocate that the conducting structure is associated with radioactive minerals. These structures are likely to be mineralized zones as hydro-uranium anomaly has also been reported from various locations in the area. Moreover, drilling results at a specific mine near the study area also confirms the presence of uranium mineralization. The hydrothermal activity associated with uranium mineralization seems to be still active in the area. Such combined geophysical studies are essential to understand this highly complex shear zone for the economic exploitation of its natural resources.     

Mineralogy,geochemistry, and genesis of co-genetic granite-pegmatite-hosted rare metal and rare earth deposits of the Kawadgaon area,Bastar craton,Central India

Co-genetic pegmatites associated with the granite of the Kawadgaon area in the Bastar craton, Central India, contain a wide range of ore minerals of Nb, Ta, Be, Sn, Zr, Ti, and REE, including columbite-tantalite, ixiolite, pseudo-ixiolite, wodginite, tapiolite, microlite, fersmite, euxenite, aeschynite, beryl, cassiterite, monazite, xenotime, zircon, ilmenite, triplite, and magnetite. There is a distinct vertical zonation between the rare metal and tin pegmatites in apical parts of the host granite. Geochemically, these are LCT-S type, beryl-columbite-phosphate pegmatites that have notably high contents of SiO₂ (av. 73.80%), Rb (av. 381 ppm), and Nb (av. 132 ppm). The investigated granites probably were derived from the melting of older crustal rocks, as indicated by a high initial ⁸⁷Sr/⁸⁶Sr isotopic ratio, and the major-element geochemistry of the granites and pegmatites. Plots of mol. CaO/(MgO+FeO^t) vs. mol. Al₂O₃/(MgO+FeO^t) suggest that the source rock was pelitic metasediments. Based on the available data, it is postulated that the derivation of pegmatites from the parent granite occurred shortly after granite emplacement in the late Archaean-early Proterozoic (~2500 Ma). The K/Rb, Ba/Rb, and Rb/Sr ratios of the felsic bodies reveal that a substantial part of the granite formed from evolved melts, and further fractionation produced the co-genetic pegmatites and associated rare metal and rare earth deposits.     

AMS studies on a 450 km long 2216 Ma dyke from Dharwar craton,India:Implications to magma flow

Anisotropy of magnetic susceptibility(AMS)studies were carried out on a precisely dated(2216.0±0.9 Ma),450 km long N-S striking dyke in the Dharwar Craton,to determine the magma flow direction along the dyke length.In order to use the imbrication of the magnetic foliation,forty eight samples were collected from 13 locations along the length of the dyke.Magnetogranulometry studies show that AMS fabric is dominated by medium grained interstitial Ti-poor multidomain magnetite.The corrected anisotropy degree(P_j)of the samples was found to be low to moderate,between 1.007 and 1.072,which indicates primary magnetic fabric.The magnetic ellipsoid is either triaxial,prolate or oblate and clearly defines normal,intermediate and inverse magnetic fabrics related to magma flow during the dyke emplacement.The maximum susceptibility axes(K_(max))of the AMS tensor of the dyke is predominantly inclined at low angles(30°),with no systematic variation in depth along the N-S profile,indicating sub-horizontal flow even at mid crustal levels which could probably be governed by location of the focal region of the magma source(mantle plume?),flow dynamics together with the compressive stresses exerted by the overlying crust.     

Possible Carlin-type disseminated gold mineralization in the Mahakoshal fold belt, central India

The paper records the first occurrence of dolomite-hosted, disseminated gold mineralization at Barhi and Jhal, in a Late Archean-Early Proterozoic metavolcano-sedimentary belt (Mahakoshal fold belt) in central India. Gold mineralization is hosted by dolomite that occurs as discontinuous bands interbedded with phyllite. Hydrothermal alteration styles of the host rock include decalcification, silicification, and argillization. Pyrite is the most common sulfide, whereas stibnite and realgar are rare. Mineralization is characterized by persistent gold from 0.20 to 0.62 ppm and a consistent association of anomalous arsenic, antimony, and mercury with gold.     

Indicator minerals as guides to base metal sulphide mineralisation in Betul Belt, central India

Zn-bearing minerals that act as indicator minerals for base metal sulphide mineralization from the Proterozoic Betul Belt, central India with special emphasis on their genetic significance have been discussed. Sulphide mineralisation is hosted by the felsic volcanic rocks and has similarities with volcanic-hosted massive sulphide deposits in other parts of the world. Synvolcanic hydrothermal alteration is crudely zoned with an inner high Mg-Ca core and an outer wider envelop of Al-Fe rich mineral assemblage. Most of the prospects have strata bound, moderately to steeply dipping, multiple, sub-parallel sheet like ore bodies composed of disseminated and semi-massive to massive ores. Zn-bearing spinel, staurolite, biotite and ilmenite typically occur within the foot-wall alteration zones in close proximity to the sulphide mineralization. Zincian spinel is ubiquitous irrespective of the nature of alteration zone. Zincian staurolite is nearly absent in Mg-Ca alteration zones but commonly present in Al-Fe alteration zone along with zincian ilmenite. Zn-bearing biotite in intimate association with zincian spinel is generally found in Mg-Ca alteration zone and in the transition to Al-Fe alteration zone. Most of these indicator minerals can be considered as products of desulphidation of sphalerite during metamorphism. Mechanisms other than desulphidation like formation of gahnite by overstepping of the zinc saturation limit of biotite during retrogression to chlorite and formation of zincian staurolite at the expense of gahnite is also recorded. Field presence of these minerals has immense significance in exploration in Betul Belt as they occur in close spatial relationship with the sulphide rich zones and therefore act as direct vectors to ore.     

Regolith mass balance inferred from combined mineralogical, geochemical and geophysical studies: Mule Hole gneissic watershed, South India

The aim of this study is to propose a method to assess the long-term chemical weathering mass balance for a regolith developed on a heterogeneous silicate substratum at the small experimental watershed scale by adopting a combined approach of geophysics, geochemistry and mineralogy. We initiated in 2003 a study of the steep climatic gradient and associated geomorphologic features of the edge of the rifted continental passive margin of the Karnataka Plateau, Peninsular India. In the transition sub-humid zone of this climatic gradient we have studied the pristine forested small watershed of Mule Hole (4.3 km²) mainly developed on gneissic substratum. Mineralogical, geochemical and geophysical investigations were carried out (i) in characteristic red soil profiles and (ii) in boreholes up to 60 m deep in order to take into account the effect of the weathering mantle roots. In addition, 12 Electrical Resistivity Tomography profiles (ERT), with an investigation depth of 30 m, were generated at the watershed scale to spatially characterize the information gathered in boreholes and soil profiles. The location of the ERT profiles is based on a previous electromagnetic survey, with an investigation depth of about 6 m. The soil cover thickness was inferred from the electromagnetic survey combined with a geological/pedological survey.Taking into account the parent rock heterogeneity, the degree of weathering of each of the regolith samples has been defined using both the mineralogical composition and the geochemical indices (Loss on Ignition, Weathering Index of Parker, Chemical Index of Alteration). Comparing these indices with electrical resistivity logs, it has been found that a value of 400 Ohm m delineates clearly the parent rocks and the weathered materials. Then the 12 inverted ERT profiles were constrained with this value after verifying the uncertainty due to the inversion procedure. Synthetic models based on the field data were used for this purpose. The estimated average regolith thickness at the watershed scale is 17.2 m, including 15.2 m of saprolite and 2 m of soil cover.Finally, using these estimations of the thicknesses, the long-term mass balance is calculated for the average gneiss-derived saprolite and red soil. In the saprolite, the open-system mass-transport function τ indicates that all the major elements except Ca are depleted. The chlorite and biotite crystals, the chief sources for Mg (95%), Fe (84%), Mn (86%) and K (57%, biotite only), are the first to undergo weathering and the oligoclase crystals are relatively intact within the saprolite with a loss of only 18%. The Ca accumulation can be attributed to the precipitation of CaCO₃ from the percolating solution due to the current and/or the paleoclimatic conditions. Overall, the most important losses occur for Si, Mg and Na with −286 × 10⁶ mol/ha (62% of the total mass loss), −67 × 10⁶ mol/ha (15% of the total mass loss) and −39 × 10⁶ mol/ha (9% of the total mass loss), respectively. Al, Fe and K account for 7%, 4% and 3% of the total mass loss, respectively. In the red soil profiles, the open-system mass-transport functions point out that all major elements except Mn are depleted. Most of the oligoclase crystals have broken down with a loss of 90%. The most important losses occur for Si, Na and Mg with −55 × 10⁶ mol/ha (47% of the total mass loss), −22 × 10⁶ mol/ha (19% of the total mass loss) and −16 × 10⁶ mol/ha (14% of the total mass loss), respectively. Ca, Al, K and Fe account for 8%, 6%, 4% and 2% of the total mass loss, respectively.Overall these findings confirm the immaturity of the saprolite at the watershed scale. The soil profiles are more evolved than saprolite but still contain primary minerals that can further undergo weathering and hence consume atmospheric CO₂.