Selenium content in soils from Murcia Region (SE,Spain)

The objective of this study was to determine the selenium content in soils from the Region of Murcia (SE, Spain) and to study the possible relationship between mineralogical composition, soil properties and selenium content. In addition, generic reference level (GRL) for selenium was determined according to Spanish legislation. For this study, 490 samples were selected in areas subjected to agricultural activity or abandoned agricultural soils with natural vegetation. Five different zones were established in order to study selenium variability. Four different mineralogical groups were established, based on significant relationship with the mineralogical composition, and each sample was included in one mineralogical group. The results showed that the concentration of selenium is correlated with the electrical conductivity, sulphate content and with the mineralogical composition, particularly positively with quartz and in a negative way with calcite percentage. In addition, selenium level was positively correlated with the phyllosilicate content. Established GRL for selenium varies with the mineralogical group, having a great transcendence from the legal and economic points of view.     

Background levels and baseline values of available heavy metals in Mediterranean greenhouse soils (Spain)

This study determines extractable levels of Cd, Cu, Pb, Zn, Ni and Co in western Almería (Spain) greenhouse surface soil horizons using EDTA solution, which is identified as the fraction available for organisms and plants. It also establishes background levels, geochemical baseline concentration and reference values (RV), and investigates the possible relationships between soil properties and elemental concentrations. The results show that the soil concentration of these extractable heavy metals was high as those reported by other authors for Spanish agricultural soils. The available RV concentrations obtained (mg kg⁻¹) were: Cd 0.17, Cu 1.6, Pb 13.8, Zn 5.0 Ni 1.7 and Co 2.9. Using the upper baseline criterion, 95% of greenhouse soils present a relatively higher content of extractable heavy metals given their Cd and Cu concentration. Significant correlations between total and EDTA-extractable metal levels were found for Zn, Pb, Cu, Cd and Ni. Soil properties also related to heavy metals content, suggesting that Cd, Cu, Pb and Zn are of similar origin and relate to anthropic activities, and implies the same interactions and/or relationships among these metals.     

Contamination and potential mobility assessment of heavy metals in urban soils of Hangzhou,China: relationship with different land uses

Concentration and distribution of heavy metals (Cd, Cu, Pb and Zn) in urban soils of Hangzhou, China, were measured based on different land uses. The contamination degree of heavy metals was assessed on the basis of pollution index (PI), integrated pollution index (IPI) and geoaccumulation index (I _geo). The 0.1 mol l⁻¹ HCl extraction procedure and gastric juice simulation test (GJST) were used to evaluate the potential mobility and environmental risk of heavy metals in urban soils. The average concentration of Cd, Cu, Pb and Zn in urban soils was measured at 1.2 (with a range of 0.7–4.6), 52.0 (7.4–177.3), 88.2 (15.0–492.1) and 206.9 (19.3–1,249.2) mg kg⁻¹, respectively. The degree of contamination increased in the order of industrial area (IA) > roadside (RS) > residential and commercial areas (RC) > public park and green areas (PG). The PIs for heavy metals indicated that there is a considerable Cd, Cu, Pb and Zn pollution, which originate from traffic and industrial activities. The IPI of these four metals ranged from 1.6 to 11.8 with a mean of 3.5, with the highest IPI in the industrial area. The assessment results of I _geo also supported that urban soil were moderately contaminated with Cd and to a lesser extent also with Cu, Pb and Zn. The IP and I _geo values reveal the pollution degree of heavy metal was the order of Cd > Pb > Zn ≈ Cu. It was shown that mobility and bioavailability of the heavy metals in urban soils increased in the order of Cd > Cu > Zn ≈ Pb. Owing to high mobility of Cd and Cu in the urban soils, further investigations are needed to understand their effect on the urban environment and human health. It is concluded that industrial activities and emissions from vehicles may be the major source of heavy metals in urban contamination. Results of this study present a rough guide about the distribution and potential environmental and health risk of heavy metals in the urban soils.     

Enrichment pattern of leachable trace metals in roadside soils of Miri City,Eastern Malaysia

This article presents the results on distribution and enrichment pattern of acid-leachable trace metals (ALTMs) from roadside soil of Miri city, Sarawak, East Malaysia. The city is one of the fastest developing in the Malaysian region with huge petroleum resources. ALTMs Fe, Mn, Cr, Cu, Ni, Co, Pb, Zn and Cd along with organic carbon and carbonates (CaCO₃) were analyzed in 37 soil sediments collected from roadside. The enrichment of ALTMs [especially Cu (0.4–13.1 μg g^?1), Zn (9.3–70.7 μg g^?1), Pb (13.8–99.1 μg g^?1)] in the roadside soils indicate that these metals are mainly derived from sources related to traffic exhausts, forest fires and oil refineries. The comparative study and enrichment pattern of elements indicates that Mn, Cu, Zn and Pb are enriched multi-fold than the unpolluted soil and Ni, Pb, Cd in some samples compared to Sediment Quality Guidelines like Lowest Effect Level (LEL) and Effects Range Low (ERL) in the region which is mainly due to the recent industrial developments in the region.     

Comparison of water-level,extensometric, DInSAR and simulation data for quantification of subsidence in Murcia City (SE Spain)

Subsidence due to groundwater overexploitation has been recognized in the metropolitan area of Murcia (25 km²) in south-eastern Spain since the early 1990s. Previous published works have focused their attention on land subsidence that occurred during the drought period between 1995 and 2008. This work first analyzes the groundwater recovery that has occurred since 2008 and then determines the kind of associated ground deformation detected by the new extensometric data. Subsequently, subsidence time series are computed on 24 geotechnical boreholes scattered throughout the study area by means of a hydro-mechanical finite element code and a linear-elastic constitutive law. A spatio-temporal interpolation of the numerically modeled surface displacements is performed over the whole domain and compared with extensometers and DInSAR-derived displacement maps in two different periods: the drought period from 2004 to 2008, and the recovery period from 2008 to 2012. In spite of the limited information on the geomechanical parameters characterizing the modelled geological formations, the proposed approach is able to discriminate areas where the soils have an elastic behavior (small differences in the comparisons) or an elasto-plastic behavior (large differences in the comparisons). This zonation enhances the understanding of the subsidence phenomenon in Murcia City and could prevent, from a quantitatively point of view, future severe subsidence due to aquifer overexploitation.     

Application of sugar foam to red soils in a semiarid Mediterranean environment

The study described here involved evaluating the effects that the application of one by-product (sugar foam waste) has upon red soils in the region of La Mancha (Central Spain). In view of the fact that this is a location where this type of soil abounds, this technique has been a common practice for many years. The principal goal was to investigate the impact of this approach on some of the soil properties and, secondly, on its level of fertility. As a result, this represents an investigation into the effects that this type of waste has on some soil quality parameters. The results showed that, after the addition of by-products over 25 years, sugar foam waste is of agricultural interest mainly due to the increase in organic matter concentration (about 2%) and, to a lesser extent, by increases in calcium carbonate (more than 30%) and P (four times more). The soil pH was also found to increase slightly (1.4), while the electrical conductivity almost did not change. The properties associated with these pedological qualities therefore had a positive effect by improving nutrient availability. As a result, foams arising from sugar industries have a positive effect on soil quality and the application of such foams to soils is beneficial since the need to dispose this residue is also removed.     

Instrumental monitoring of the subsidence due to groundwater withdrawal in the city of Murcia (Spain)

This paper presents the results of investigations of the generalized subsidence occurring in and around the city of Murcia, Spain. Based on this research, this is the first integrated investigation of its type performed in Spain. The phenomenon of ground consolidation in the city of Murcia leads to the appearance of severe cracking and settlement in buildings. Subsidence is the result of two factors: on the one hand, the nature of the ground in this area, as it is made of recent deposits of clay and soft limes filled in with clay–lime backfills in the top layers. On the other hand, the increase in groundwater withdrawal during the 1992–95 drought led to a decrease in the water level of a magnitude never before recorded in the city. The risk prevention management suggested convenience of the installation of a measurement network to study and follow the phenomena of the subsidence to quantify it and to calibrate this theoretical model. This network is composed of extensometers and piezometers, the best devices to measure moderate ground movements, which is the case of Murcia. The first phase (Phase I) of this study of ground settlement in the metropolitan area of Murcia involved the installation of a network with 22 extensometers and taking the first measurement series. In a second phase (Phase II), during a period of 4 years, measurements with extensometers were performed to make the analysis and calibration of the theoretical model. Experience and data analysis showed the convenience of installation of new control points with an incremental extensometer and a piezometer in close position with the aim of precisely correlating piezometric levels with the observed subsidence. The third phase (Phase III) started in 2007, a new control technique, based on radar interferometry (InSAR), is being employed to provide information about subsidence in areas not previously monitored.     

Sedimentary model and high-frequency cyclicity in a Mediterranean, shallow-shelf, temperate-carbonate environment (uppermost Miocene, Agua Amarga Basin, Southern Spain)

Uppermost Tortonian to lower Messinian temperate carbonates crop out in the Agua Amarga Basin (SE Spain). They consist of four units. The lower three units can be tentatively assigned to the lowstand systems tract of a fourth-order sequence, constituting in turn the lowstand (‘megatrough unit’), transgressive (‘breccia unit’) and highstand (‘bedded unit’) stages of a higher-order cycle. All these materials were deposited in a small pull-apart basin related to the sinistral Carboneras strike-slip fault system. The best represented is the bedded unit (up to 25 m thick), which consists of bioclastic, bryozoan/bivalve-dominated calcarenites/calcirudites with abundant fragments of echinoids, barnacles, benthic foraminifers, coralline algae, brachiopods and solitary corals. Facies trends within this unit are roughly arranged in an E-W direction, with the coastline to the north of the basin. The depositional model is that of a gentle ramp with prograding beaches and shoals in its higher parts. Seaward of the shoals was the ‘factory area’, where most organisms lived and maximum carbonate production took place. From this area some of the skeletons were washed landwards by waves and/or currents during storms and incorporated into the shoals and beaches, and others moved downslope along the ramp as mass-flows, accumulating to form the ‘fan-bedded zone’. The factory-area and fan-bedded sediments intercalate five well-defined, thick beds of calcarenites/fine-grained calcirudites. They show bar morphologies (single or amalgamated), or make up sand-waves with very consistent tabular cross-bedding pointing landwards. These beds formed in a very shallow, wave/current-influenced, coastal environment. The bars and sand waves in the fan-bedded zone developed during lowstands, while those located higher up in the ramp interbedded with the factory facies are related to transgressive stages. Prograding beaches, shoals, factory facies and fan-bedded layers developed during the highstands. Net skeletal production occurred mainly during the highstands. Sediment-accretion values of these sediments are similar to those of present and ancient shallow-marine, temperate carbonates considering that the whole bedded unit was deposited in a 100 000-year interval (equivalent to the short eccentricity cycle). The five cycles inside the bedded unit would therefore correspond to the c. 20 000-year precession cycles of the Milankovitch band.     

Impact of land use types on the concentrations of metals in soils of urban environment in Nigeria

The concentrations of metals (Cd, Pb, Ni, Cr, Cu, Fe, Mn and Zn) were determined in soils under different land use types in an urban environment in order to study the impact of land uses on the concentrations of metals in the soils. The mean concentration range of metals for all land use types were 42.1 to 410, 11.2 to 118.2, 4388.2 to 31891.1, 9.7 to 65.4, 0.1 to 1.8, 4.7 to 35.2, 2.0 to 16.8 and 77.9 to 881.7 mg/kg, for Mn, Pb, Fe, Cu, Cd, Cr, Ni and Zn, respectively. The computed multiple pollution index (MPI) indicated that 67 % of the examined sites had MPI values between 1 and 20 i.e. at the pollution range, while 33 % of sites had MPI values of zero which indicated that these sites were not polluted with the studied metals. Zinc had the highest impact on the multiple pollution index values. Three main principal components were identified from the principal component analysis which include (i) Cu, Zn, Pb, Cr and Ni originating from both industrial and agricultural sources, and as well as automobile exhausts; (ii) Fe and Mn which originated from both natural and anthropogenic sources; (iii) Cd which its anthropogenic origin is different from components I and II. This study provided information on the sources of metals in the urban environment and extent of contamination associated with each land use, which are useful in the ranking of contaminated sites, environmental quality management, environmental forensic studies and guidance for remediation/redevelopment of contaminated land.     

Response of some soil attributes to different land use types in calcareous soils with Mediterranean type climate in north-west of Iran

Monitoring general variability of soil attributes is a fundamental requirement from the point of view of understanding and predicting how ecosystems yield. In order to monitor impact of different land use types on the combination of morphological, clay mineralogical and physicochemical characterizes, 42 soil samples (0–30 cm) were described and analyzed. Soil samples belonging to Cambisols and Vertisols reference soil groups collected from three neighboring land use types included cropland (under long-term continuous cultivation), grassland, and forestland. The soils were characterized by high pH (mean of 7.1–7.5) and calcium carbonate equivalent (CCE) (mean of 35–97 g kg^?1) in the three land use types. The weakening in soil structure, hardening of consistency, and lighting of soil color occurred for the cropland under comparable condition with grassland and forest. Changes in land use types produced a remarkable change in the XRD patterns of clay minerals containing illite and smectite due the dynamic and removal of potassium. Continuous cultivation resulted in an increase in sand content up to 35 % while silt and clay content decreased up to 22 and 18 %, respectively, as compared to the adjoining grassland and forest mainly as a result of the difference of dynamic alterational and erosional process in the different land use. Long-term cultivation caused a negative and degradative aspects on soil heath as is manifested by the increasing in soil pH (a rise of 0.3–0.46 unit), electrical conductivity (EC) (a rise of 1.78–5.5 times), sodium absorption ration (SAR) (a rise of 10–51 %), exchangeable sodium percentage (ESP) (a rise of 3–46 %), and the decrease in soil organic C (a drop of 12–41 %), along with soil fertility attributes. Overall, the general distribution of soil organic C, total N, available P and K, cation exchange capacity (CEC), and exchangeable cations (Ca, Mg, and K) followed the order: forestland > grassland > cropland. The general distribution of EC, SAR, ESP, and exchangeable Na, however, followed the order: cropland > grassland > forestland. Soil quality index (SQI), calculated based on some physicochemical properties, specified that cultivation led to a negative effect in SQI for both Cambisols (a drop of 10–17 %) and Vertisols (a drop of 17 %) as compared to those of under grassland and forestland.     

Chemical composition of landfill leachate in a karst area with a Mediterranean climate (Marbella, southern Spain)

 Between March 1994 and April 1997, the physical and chemical parameters and chemical composition of the urban solid waste leachate of the Marbella landfill (southern Spain) were determined. The data obtained show an ammonium and sodium chloride and bicarbonate type, a pH>7 and high mineralization, effectively described by the following parameters: Na⁺, K⁺, NH₄ ⁺, Cl^– and alkalinity. The chemical composition depends on the rainfall: in dry years, the mineralization and component concentrations have values as much as double those found in normal rainfall years. After storm events, a major and rapid dilution (within several hours) is seen in the leachate. Received: 28 January 1998 · Accepted: 2 June 1998     

Groundwater problems resulting from CO2 pollution and overexploitation in Alto Guadalentín aquifer (Murcia,Spain)

 The Alto Guadalentín detrital aquifer is both overexploited and polluted. Water conductivity ranges between 1200 and 4900 μS cm^–1, HCO₃ ^– between 1000 and 1990 mg l^–1, and PCO₂ between 0.041 and 1.497 bars. The temperature and chemical composition of the water show a positive thermal anomaly directly attributable to the neotectonic activity in the area. The high CO₂ content has caused the abandonment of numerous wells due to water corrosiveness which attacks pumping equipment. Received: 10 October 1995 · Accepted: 14 November 1995     

Pedo-geochemical baseline content levels and soil quality reference values of trace elements in soils from the Mediterranean (Castilla La Mancha, Spain)

To evaluate trace element soil contamination, geochemical baseline contents and reference values need to be established. Pedo-geochemical baseline levels of trace elements in 72 soil samples of 24 soil profiles from the Mediterranean, Castilla La Mancha, are assessed and soil quality reference values are calculated. Reference value contents (in mg kg^?1) were: Sc 50.8; V 123.2; Cr 113.4; Co 20.8; Ni 42.6; Cu 27.0; Zn 86.5; Ga 26.7; Ge 1.3; As 16.7; Se 1.4; Br 20.1; Rb 234.7; Sr 1868.4; Y 38.3; Zr 413.1; Nb 18.7; Mo 2.0; Ag 7.8; Cd 4.4; Sn 8.7; Sb 5.7; I 25.4; Cs 14.2; Ba 1049.3; La 348.4; Ce 97.9; Nd 40.1; Sm 10.7; Yb 4.2; Hf 10.0; Ta 4.0; W 5.5; Tl 2.3; Pb 44.2; Bi 2.2; Th 21.6; U 10.3. The contents obtained for some elements are below or close to the detection limit: Co, Ge, Se, Mo, Ag, Cd, Sb, Yb, Hf, Ta, W, Tl and Bi. The element content ranges (the maximum value minus the minimum value) are: Sc 55.0, V 196.0, Cr 346.0, Co 64.4, Ni 188.7, Cu 49.5, Zn 102.3, Ga 28.7, Ge 1.5, As 26.4, Se 0.9, Br 33.0 Rb 432.7, Sr 3372.6, Y 39.8, Zr 523.2, Nb 59.7, Mo 3.9, Ag 10.1, Cd 1.8, Sn 75.2, Sb 9.9, I 68.0, Cs 17.6, Ba 1394.9, La 51.3, Ce 93.5, Nd 52.5, Sm 11.2, Yb 4.2, Hf 11.3, Ta 6.3, W 5.2, Tl 2.1, Pb 96.4, Bi 3.0, Th 24.4, U 16.4 (in mg kg^?1). The spatial distribution of the elements was affected mainly by the nature of the bedrock and by pedological processes. The upper limit of expected background variation for each trace element in the soil is documented, as is its range as a criterion for evaluating which sites may require decontamination.     

Application of the FAO quantitative and SINDI methods to assess the quality of different soils in Castilla-La Mancha (Spain)

In the region of Castilla-La Mancha (Spain), over half of the soils are under cropping. This vast agricultural activity, combined with other anthropological uses, has led to a deterioration of the soil quality and virtual degradation. Therefore, it was deemed to assess the quality of these soils, which was achieved by applying two different methods. Three soils, representative of typical conditions in this community, were sampled and diverse properties were analysed in order to apply two different approaches. The first soil evaluation was carried out by a traditional method developed by FAO using a productivity index, whereas the second method consisted of the application of a new method called SINDI, developed in New Zealand. Both approaches make an evaluation based on a number of indicators that differs in each case. These differences explain why each method ranked the soils studied in different order reaching diverse conclusions on their quality.     

Nitrous oxide emissions from different land use patterns in a typical karst region, Southwest China

Fluxes of nitrous oxide (N2O) from different land use patterns (matured forest, secondary forest, grassland and cropland) in a subtropical karst region of Guizhou Province, Southwest China, were measured for one year with a closed static chamber technique and by gas chromatography. The results showed that soil under different land uses was a source of atmospheric N2O. The cropland was a source with relatively high N2O as compared to forest and grassland, but no significant differences were observed. N2O emissions from soils varied with land use change and fertilizer application. There were two peaks of N2O flux occurred following the combination of two obvious precipitation and fertilizer events in the cultivated land. Converting from the matured forest to secondary forest tended to increase annual emissions of N2O (from 1.40 to 1.65 kg N ha -1 a -1 ), while changing land use from secondary forest to scattered grassland tended to decrease annual emissions of N2O slightly (from 1.65 to 1.45 kg N ha -1 a -1 ). Our range of cumulative annual N2O emission across different land uses (1.40-1.91 kg N ha -1 a -1 ) in a karst region is in general agreement with previously published data in a non-karst region. However, in the maize field, N2O emission factor (EF) was 0.34% for fertilizer application, which is about 71.2% lower than the IPCC default value. It is suggested that current IPCC (Intergovernmental Panel on Climate Change) EF methodology could overestimate N2O emission from the karstic cropland. Anyway, the N2O emission from cropland in the karst region would contribute significantly to the global N2O budget, so reducing fertilization frequency during the crop growing season could lead to a decrease in N2O emission in the whole year.     

Spectral analysis of climate cycles to predict rainfall induced landslides in the western Mediterranean (Majorca,Spain)

In the present work, spectral analysis has been applied to determine the presence and statistical significance of climate cycles in long-term data series from different rainfall and gauging stations located in the Tramuntana Range, in the north-western sector of the island of Majorca. Climate signals recorded previously in the Mediterranean region have been identified: the ENSO, NAO, HALE, QBO and Sun Spot cycles as well as others related to solar activity; the most powerful signals correspond to the annual cycle, followed by the 6-month and NAO cycles. The incorporation of data derived from gauging stations contributes to better climate signal detection as local and exceptional influences are eliminated. Simulations have been performed for each rainfall/gauging station, using the most significant climate cycles obtained by means of the power spectrum. A good correlation between rainfall/flow values and simulated cycles has been obtained. The NAO and ENSO cycles are the most influential in the rainy periods, and specifically the NAO cycle, where a good correlation between episodes of high rainfall/flow and high values of ANAOI can be observed. At a second stage, landslides dated and recorded in the Tramuntana Range since 1954 (174 events) have been correlated with the simulated cycles obtaining good results, as the landslide events match rainfall peaks well. The correlation for the past decade (since 2005), when a detailed landslide inventory is available, also reveals a coincidence between landslide events and climate cycles, and specifically NAO and ENSO cycles. That is the case of the period 2008–2010, when numerous mass movements took place, and when the largest movement of the inventory was recorded. Results show a potential rainy period in the Tramuntana Range for the coming years (with maximum values around year 2021), when conditions similar to those related to the 2008–2010 event could take place again. The methodology presented in this work can contribute to the prediction of temporal, extreme hydrological events in order to design short-/medium-term mitigation strategies on a regional scale.     

Molecular evidence for recent land use change from a swampy environment to a pond (Lorraine,France)

Evidence of a changing environment in the catchment area of a small pond (Lansquenet, Lorraine, France) during the last millennium was provided by coupling palynology data and organic ratios [terrestrial to aquatic ratio: TAR_(HC); the C₂₉ vs. C₂₇ sterols, C₂₉/C_27(ST); average chain length, ACL and aquatic/macrophytes ratio, P_aq]. The depositional and alteration conditions of organic matter (OM) were provided by the 5α(H)-stanols/Δ⁵-sterols ratio. This study shows that quite simple organic ratios clearly allow identification of the different evolution steps of a watershed, from a swamp to the progressive settlement of a pond. During the swampy period, the C/N_(at) (ca. 11.1), TAR_(HC) (ca. 36.8)_, C₂₉/C_27(ST) (ca. 8.7) and P_aq (<0.3) show a high contribution of allochthonous OM associated with the presence of particular aquatic and mesohygrophilous species. A woody level dated to the XIIIth century reflects the period of the settlement of the pond in a more oxic environment [5α(H)-stanol/Δ⁵sterol ratio <0.2]. Then, the progressive increase in aquatic input and the development of submerged and floating macrophytes are evidenced by low C/N_(at) (<7.6), TAR_(HC) (ca. 2.7), C₂₉/C_27(ST) (ca. 2) and high P_aq (ca. 0.5), suggesting an increase in the water level and eutrophication of the pond. A second oxic event [5α(H)-stanols/Δ⁵sterols ratio averaging 0.16], associated with extensive OM degradation, corresponds to the most recent dredging in 2002 and reflects an important disturbance of sediments due to pond management.     

Risk of metal mobility in soils from a Pb/Zn depleted mine (Lugo,Spain)

The risk of Pb, Zn and Cd mobility is evaluated in soils from a depleted mine at Rubiais (Lugo, Spain). This area is under special protection because of its outstanding natural value. Soils from nine different areas were selected: at the mining zone (R1, R2, R3), at minespoils (R4, R5, R6) and soils developed on the settling pond (R7, R8, R9). A control soil (RC) was sampled outside the mine. The objectives are (i) to study the characteristics of soils with high influence on metal retention, (ii) to determine the content of Pb, Zn and Cd comparing it with the generic reference levels, and (iii) to evaluate the distribution and the interactions between the metals and the soil geochemical phases by means of sequential chemical extraction, X-ray diffraction, field emission scanning electron microscopy/energy-dispersive X-ray spectroscopy (FE-SEM/EDS) and time of flight secondary ion mass spectrometry (TOF–SIMS). The concentration of Pb, Zn and Cd ranges 850–6,761, 1,754–32,287 and 1.8–43.7 mg kg^?1, respectively, and the highest proportion is in the residual fraction. The Mn oxides highly influence the retention of Cd while Pb retention is mainly influenced by Fe oxides. Zn is uniformly distributed amongst the residual fraction and the Fe and Mn oxides. TOF–SIMS and SEM/EDS techniques confirm the fractionation results, showing how Pb and Zn are as sulphide and associated with Fe and Mn oxides. Nevertheless, care should be taken since oxides and sulphides could suffer sulphide oxidation processes or alteration of the oxides causing leaching and the contamination of the protected ecosystem.     

One million years of cultural evolution in a stable environment at Atapuerca (Burgos,Spain)

The present paper analyses the evidence provided by three sites (Sima del Elefante, Gran Dolina, and Galería) located in the Trinchera del Ferrocarril of the Sierra de Atapuerca. These three sites are cave infillings that contain sediments deposited from approximately 1.2 Ma to 200 kyr. Pollen, herpetofauna, and small and large mammal remains are used as proxies to obtain a general picture of the environmental changes that occurred at the Sierra de Atapuerca throughout the one million-year period represented at these sites. Similarly, cultural changes are tracked analyzing the evidence of human behavior obtained from the study of several bone and lithic assemblages from these three sites. At least three periods with different cultural features, involving technology, subsistence and behavior, are determined from the available evidence. The first two periods correspond to the Mode 1 technology and Homo antecessor: the first is dated around 1.2 to 1.0 Ma and reflects opportunistic behavior both in technology and subsistence. The second period is around 800 kyr BP. Mode 1 technology is still maintained, but subsistence strategies include systematic hunting and the use of base camps. The third period is dated between 500 ka and 200 ka and corresponds to the Mode 2 technology and the acquisition of directional hunting and other organizational strategies by Homo heidelbergensis. A transition from Mode 2 to Mode 3 seems to appear at the end of this time-range, and may reflect the early phases of a fourth cultural change. With regard to the environment, our main conclusion is that there was an absence of extremely harsh conditions at Atapuerca throughout this time period. The presence of Mediterranean taxa was constant and the dominant landscape was a savannah-like open environment, probably with small forest patches. An alternation of Mediterranean and mesic species as the dominant component of the tree storey was induced by the climatic cycles, and steppes spread across the landscape during the drier periods. In any case, it is not possible to establish clear cut-off points separating entirely different environmental episodes. Our results show no evidence of any relationship between environmental change and cultural change at the Sierra de Atapuerca.     

Wetland soil organic matter composition in a Mediterranean semiarid wetland (Las Tablas de Daimiel, Central Spain): Insight into different carbon sequestration pathways

Wetland soils from a Mediterranean semiarid wetland (Las Tablas de Daimiel, Central Spain) were studied to characterize the organic matter (OM) and determine its origin and transformation. Cross polarization magic angle spinning (CPMAS) ¹³C nuclear magnetic resonance (NMR) spectroscopy and mathematical molecular mixing allowed analysis of the organic fraction in terms of six generic components (carbohydrate, protein, lignin, lipid, char and “carbonyl”). Las Tablas is an active carbon sink, with total organic carbon (TOC) content independent of soil OM quality; the TOC content of the upper sediment is 10.0 ± 7.8%. The inorganic carbon content is also high (5.4 ± 3.3%) and is associated mainly with OM of aliphatic character. The OM composition is variable; samples predominantly aliphatic (carbohydrate, lipid and protein) are characteristic of the northern sector, whereas predominantly aromatic samples are typical of the southern Tablas. A strong negative relationship between protein content and lignin content was found, interpreted as a consequence of different proportions of vascular vs. non-vascular (mostly charophyte) litter input. The effect of perturbation is apparent in the extended presence of char, particularly abundant in fire-prone areas. OM quantity and quality do not seem to depend on hydrology (although seasonal flooding is associated with lower TOC wetland soils) or soil characteristics. Dominant vegetation and fire are the main drivers of OM content and composition. Structural carbohydrate, protein and lipid (>60% of total organic fraction) dominate. Widespread anaerobic conditions and the recent character of the sediments could explain the preservation of different fractions of the original detritus composition (due to different vegetation and presence of microbes).