Impacts of agricultural irrigation recharge on groundwater quality in a basalt aquifer system (Washington, USA): a multi-tracer approach

Irrigation in semi-arid agricultural regions can have profound effects on recharge rates and the quality of shallow groundwater. This study coupled stable isotopes (²??, ¹⁸O), age-tracers (³H, CFCs, ¹⁴C), ⁸⁷Sr/⁸⁶Sr ratios, and elemental chemistry to determine the sources, residence times, and flowpaths of groundwater and agricultural contaminants (e.g. NO ₃ ^?C ) in the Saddle Mountains Basalt Aquifer in central Washington, USA, where over 80% of the population depend on groundwater for domestic use. Results demonstrate the presence of two distinct types of water: contaminated irrigation water and pristine regional groundwater. Contaminated irrigation water has high NO ₃ ^?C concentrations (11?C116? mg/l), ⁸⁷Sr/⁸⁶Sr ratios (0.70659?C0.71078) within range of nitrogen-based fertilizers, detectable tritium (2.8?C13.4 TU), CFC ages 20?C40?years, high ??¹⁸O values (?16.9 to ?13.5??), and ??100 percent modern ¹⁴C. Pristine regional groundwater has low NO ₃ ^?C concentrations (1?C5? mg/l), no detectable tritium (??0.8 TU), low ??¹⁸O values (?18.9 to ?17.3??) and ¹⁴C ages from ??15 to 33?ky BP. Nitrogen and oxygen isotopes of NO ₃ ^?C , combined with high dissolved oxygen values, show that denitrification is not an important process in the organic-poor basalt aquifers resulting in transport of high NO ₃ ^?C irrigation water to depths greater than 40?m in less than 30? years.     

Appraisal of groundwater quality in a crystalline aquifer: a chemometric approach

The purpose of this study is to assess the groundwater quality and identify the processes that control the groundwater chemistry in a crystalline aquifer. A total of 72 groundwater samples were collected during pre- and post-monsoon seasons in the year 2014 in a semi-arid region of Gooty Mandal, Anantapur district, Andhra Pradesh, India. The study utilized chemometric analysis like basic statistics, Pearson’s correlation coefficient (r), principal component analysis (PCA), Gibbs ratio, and index of base exchange to understand the mechanism of controlling the groundwater chemistry in the study area. The results reveal that groundwater in the study area is neutral to slightly alkaline in nature. The order of dominance of cations is Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ while for anions, it is \( {\mathrm{HCO}}_3^{-}>{\mathrm{Cl}}^{-} \)>\( {\mathrm{NO}}_3^{-} \)>\( {\mathrm{SO}}_4^{2-} \)>\( {\mathrm{CO}}_3^{2-}>{\mathrm{F}}^{-} \) in both seasons. Based on the Piper classification, most of the groundwater samples are identified as of sodium bicarbonate (\( {\mathrm{Na}}^{+}-{\mathrm{HCO}}_3^{-}\Big) \) type. According to the results of the principal component analysis (PCA), three factors and two factors were identified pre and post monsoon, respectively. The present study indicates that the groundwater chemistry is mostly controlled by geogenic processes (weathering, dissolution, and ion exchange) and some extent of anthropogenic activities.     

Transboundary aquifer mapping and management in Africa: a harmonised approach

Recent attention to transboundary aquifers (TBAs) in Africa reflects the growing importance of these resources for development in the continent. However, relatively little research on these aquifers and their best management strategies has been published. This report recapitulates progress on mapping and management frameworks for TBAs in Africa. The world map on transboundary aquifers presented at the 6th World Water Forum in 2012 identified 71 TBA systems in Africa. This report presents an updated African TBA map including 80 shared aquifers and aquifer systems superimposed on 63 international river basins. Furthermore, it proposes a new nomenclature for the mapping based on three sub-regions, reflecting the leading regional development communities. The map shows that TBAs represent approximately 42 % of the continental area and 30 % of the population. Finally, a brief review of current international law, specific bi- or multilateral treaties, and TBA management practice in Africa reveals little documented international conflicts over TBAs. The existing or upcoming international river and lake basin organisations offer a harmonised institutional base for TBA management while alternative or supportive models involving the regional development communities are also required. The proposed map and geographical classification scheme for TBAs facilitates identification of options for joint institutional setups.     

Assessment of groundwater salinity using GIS and multivariate statistics in a coastal Mediterranean aquifer

The integration of the statistical approaches and GIS tools with the hydrogeological and geological contexts allowed the assessment of the processes that cause groundwater quality deterioration in the great important deltaic aquifer in the northeastern Tunisia (Medjerda Lower Valley Aquifer). The spatial variation of the groundwater parameters and the molar ratio (Cl^?/Br^?) were also used to determine the possible impacts from seawater intrusion and from the septic tank leachate. Sixty shallow groundwater samples were collected in 2014 and analyzed for major and trace ions over an area of about 1090 km² to determine the suitability for drinking or agricultural purposes. The total dissolved solids (TDS) content ranges from 1005 to 19,254 mgl^?1 with a mean value of 3477.18 mgl^?1. The chemistry is dominated by the sodium–chloride waters (55%). Mapping of TDS, Cl^?, Na⁺, SO₄^2? and NO₃^? using kriging method shows a clear increase in salinity toward the coastline accompanied by Na⁺ and Cl^? increase which may be related to seawater intrusion and halite dissolution. Locally, higher nitrate concentration is related to the agricultural activities inducing contribution of chemical fertilizers and irrigation with treated wastewater. The saturation indices indicate that all carbonate minerals tend to reach saturation equilibrium confirming water–rock interactions, while evaporitic minerals are still in sub-saturation state and may increase the salinity of the groundwater. The principal component analysis proves the occurrence of groundwater contamination principally by seawater intrusion in the factor I (74.15%) and secondary by an anthropogenic source in the factor II (10.35%).     

Numerical analysis of subsurface deformation induced by groundwater level changes in the Bangkok aquifer system

Acta Geotechnica - Subsurface deformation due to long terms of groundwater drawdown from 1960 to 1997 and groundwater recovery from 1997 to 2016 in the upper part of the Bangkok multi-aquifer...     

Use of chloride mass balance and tritium data for estimation of groundwater recharge and renewal rate in an unconfined aquifer from North Africa: a case study from Tunisia

The scarcity of surface water resources in arid and semi-arid regions from North African countries contributes to the considerable increase of groundwater exploitation, which leads to the development of hydrogeological studies. However, due to the lack of hydrodynamic data in these regions, these studies focus more and more on the geochemical and environmental isotope techniques to insure a better understanding of the hydrodynamic functioning of subsurface systems. In this study, which interests an important unconfined aquifer in central Tunisia, tritium data and chloride mass balance (CMB) method were applied in order to (1) understand the mode of recharge of this aquifer and (2) obtain a reliable estimation of its recharge amount as well as (3) estimate its annual renewal rate. It has been demonstrated that the shallow groundwaters are classified into two groups according to their tritium contents. The first group includes wells located mainly downstream and highlights the significant role of the post-nuclear lineal recharge through Wadis courses. The second group encloses wells located practically overall the rest of the basin and refers to relatively modern waters originated from areal recharge of present-day rainfall. Based on the CMB method, the recharge to this unconfined aquifer is estimated to 31.7 mm year⁻¹, which corresponds to 10.5% of the total rainfall. The annual renewal rate of groundwater, evaluated based on the tritium contents, is up to 16%.     

A multi-tracer approach to delineate groundwater dynamics in the Rio Actopan Basin,Veracruz State,Mexico

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.     

A generalized solution for groundwater head fluctuation in a tidal leaky aquifer system

A new analytical solution is developed for describing groundwater level fluctuations in a coupled leaky confined aquifer system which consists of an unconfined aquifer, confined aquifer, and an aquitard in between. The aquifer system has a tidal boundary at the seashore, a no flow boundary at remote inland side, and a confined aquifer extending under the sea and terminated with an outlet-capping. This new solution has shown to be a generalisation of most existing analytical solutions for a tidal aquifer system which includes single confined and leaky confined aquifers. In addition, the solution is used to explore the influences of the dimensionless leakance of the outlet-capping, the dimensionless hydraulic diffusivities, and the leakages of the inland and offshore aquitards on the head responses in the leaky confined aquifer.     

Hydrochemical characterization of groundwater using multivariate statistical analysis: the Maritime Djeffara shallow aquifer (Southeastern Tunisia)

Worldwide, groundwater resources have been considered as the main sources of drinking, domestic uses, industrial and agriculture water demands, especially in arid and semiarid regions. Accordingly, the monitoring of the groundwater quality based on different tools and methods becomes a necessity. The aim of this study was to apply several approaches to assess the water quality and to define the main hydrochemical process which affect groundwater of the Maritime Djeffara shallow aquifer. In addition to the hydrochemical approach, two multivariate statistical analyses, hierarchical clusters analysis (HCA) and principal component analysis (PCA), were carried out to identify the natural and the anthropogenic processes affecting groundwater chemistry. Hydrochemical approach, based on 47 analyzed groundwater samples, shows that most of samples present a sulfate to mixed chloride, with sodi-potassic tendency facies. According to their chemically composition, the HCA revealed three different groups (C1, C2 and C3) according to their electrical conductivity (EC) values: C1 (average EC = 4500 µS/cm), C2 (average EC = 7040 µS/cm) and C3 (average EC = 9767 µS/cm). Furthermore, PCA results show two principal factors account 84.05% of the total variance: (1) F1 represents the natural component, and (2) F2 symbolizes the anthropic component. Moreover, the groundwater quality map of the Maritime Djeffara shows three categories: suitable, doubtful and unsuitable water for irrigation. These different results should be taken to protect water resources in arid and semiarid regions, especially at the alluvial coastal regions. Also, they help to make a suitable planning to manage and protect the groundwater resources.     

Sustainability analysis of groundwater resources in a coastal aquifer, Alabama

Fort Morgan Peninsula is an attached portion of a dynamic barrier complex in the northern Gulf of Mexico and is a large tourist area that brings in a significant amount of revenue for Alabama. Many of the hotels and tourist attractions depend on the groundwater as their water supply. The over-withdrawal of groundwater and saltwater intrustion will have a negative impact on the ecology, tourism and economy if groundwater resources are not properly monitored and managed. In this study a calibrated groundwater flow model was used to analyze the sustainability of groundwater resources at Fort Morgan Peninsula. Detailed flow budgets were prepared to check the various components of inflow and outflow under different water use and climatic conditions. The results indicated the locations where groundwater was over-pumped and subjected to saltwater intrusion, or will be subjected to saltwater intrusion under a range of projected water use and climatic conditions.     

Compositional multivariate statistical analysis of thermal groundwater provenance: A hydrogeochemical case study from Ireland

Thermal groundwater is currently being exploited for district-scale heating in many locations world-wide. The chemical compositions of these thermal waters reflect the provenance and circulation patterns of the groundwater, which are controlled by recharge, rock type and geological structure. Exploring the provenance of these waters using multivariate statistical analysis (MSA) techniques increases our understanding of the hydrothermal circulation systems, and provides a reliable tool for assessing these resources.Hydrochemical data from thermal springs situated in the Carboniferous Dublin Basin in east-central Ireland were explored using MSA, including hierarchical cluster analysis (HCA) and principal component analysis (PCA), to investigate the source aquifers of the thermal groundwaters. To take into account the compositional nature of the hydrochemical data, compositional data analysis (CoDa) techniques were used to process the data prior to the MSA.The results of the MSA were examined alongside detailed time-lapse temperature measurements from several of the springs, and indicate the influence of three important hydrogeological processes on the hydrochemistry of the thermal waters: 1) salinity and increased water-rock interaction; 2) dissolution of carbonates; and 3) dissolution of sulfides, sulfates and oxides associated with mineral deposits. The use of MSA within the CoDa framework identified subtle temporal variations in the hydrochemistry of the thermal springs, which could not be identified with more traditional graphing methods, or with a standard statistical approach. The MSA was successful in distinguishing different geological settings and different annual behaviours within the group of springs. This study demonstrates the usefulness of the application of MSA within the CoDa framework in order to better understand the underlying controlling processes governing the hydrochemistry of a group of thermal springs in a low-enthalpy setting.     

Groundwater origins and mixing pattern in the multilayer aquifer system of the Gafsa-south mining district: a chemical and isotopic approach

Major ion geochemistry and environmental isotopes were used to identify the origins and the mineralisation processes of groundwater flowing within the three aquifer levels of the multilayer system of the Gafsa-south mining district (Southwestern Tunisia). It has been demonstrated that groundwaters are characterised by a Ca–Mg–SO₄ water type. Geochemical pattern is mainly controlled by the dissolution of halite, gypsum and/or anhydrite as well as by the incongruent dissolution of dolomite. δ¹⁸O and δ²H values are much lower than the isotopic signature of regional precipitation and fall close to the meteoric water lines, indicating that groundwaters have not been significantly affected by evaporation or mineral–water reactions. The distribution of stable and radiogenic isotopes (δ¹⁸O, δ²H, δ¹³C and ¹⁴C) within the aquifer levels suggests that the deep confined aquifer receives a significant modern recharge at higher altitudes, while, the shallow unconfined aquifer has been mainly recharged under cooler paleoclimatic condition, likely during Late Pleistocene and Early Holocene humid periods. However, waters from the intermediate confined/unconfined aquifer have composite isotopic signatures, highlighting that they are derived from a mixture of the two first end-members.     

Contribution of multivariate statistical techniques in the hydrochemical evaluation of groundwater from the Ouargla phreatic aquifer in Algeria

A hydrochemical evaluation of the hydrogeological surface aquifer of Ouargla was conducted using 17 samples of water. The analysis of the samples focused on the determination of calcium, magnesium, sodium, potassium, chloride, sulfate, bicarbonate, and nitrate, while electrical conductivity, temperature, and pH were measured on the ground. The obtained data are processed by multivariate techniques with a varimax rotation approach after standardization. The chemical data follow four factorial axes that provide a cumulative total variance explained by 67 %. Considering the EC as an additional variable, the matrix components after varimax rotation have identified a first axis related to NaCl, a second axis associated with CaSO₄, a third axis of HCO₃ and a fourth axis of NO₃. These variables control a significant part of the chemistry of the groundwater in the region of Ouargla.     

基桩对含水层渗流阻挡作用效应研究

超高层建筑的桩基础通常会打入到深度较大的承压含水砂土层中;在承压含水层的上方通常会进行超深基坑的开挖构建超高层建筑的地下室。为了保持超深基坑的基底稳定,需要在承压含水层中进行降水施工。由于深基坑存在大量的桩基础,基桩的存在会影响降水时地下水的渗流路径,继而影响土体的渗透性状。应用室内试验研究基桩对含水层渗流阻挡作用的机制。试验采用PVC管模拟基桩,将颗粒较均匀的砂土作为试验土体,通过室内渗流试验来研究基桩对地下水渗流的影响。试验结果表明,基桩对于地下水渗流有明显的阻挡效应：基桩的数量以及布置形式会对渗透效应产生较大的影响。考虑砂土体积置换率的有效介质理论可以用来分析矩形布置的基桩对渗透系数的影响,但对梅花形布置的基桩应用有效介质理论计算所得的渗透系数会有将近20%的偏差;其原因是梅花形布置的基桩,会使渗流路径增加。基于对渗流路径的分析,提出了考虑有梅花形布置的基桩存在时等效渗透系数计算的修正方法。     

Geochemistry of groundwater from a rhyolite aquifer,Northwest Iran

Chemical data on groundwater composition in rhyolitic hard rock aquifers with limited global occurrence are rarely found. In this research geochemistry of Mahabad Rhyolite Aquifer, NW Iran, was studied considering major ions, silica and trace elements measured in wet and dry seasons. Based on the results, the mean silica content was 18 mg l^?1, less than the average of the rhyolitic waters. However, the relatively higher electrical conductivity (EC) of 418 µS cm^?1 was measured. Based on a PHREEQCI model, the weathering of the silicate minerals and dissolution of carbonated intercalations turns groundwater dominantly into Ca–HCO₃ type, enhancing EC, pH and silica concentration along the flow path. Trace elements of Sr, Ba and Pb were measured at highest concentrations, the later with an average value of 83 ppb exceeds the drinking guidelines. Cluster analysis confirms biotite weathering and barite dissolution as the main sources of the trace elements in the groundwater. The results signify geochemical features of rhyolitic groundwater which can be a useful tracer of mixing in flow systems containing variety of aquifers including rhyolites.     

Arsenic release from biotite into a Holocene groundwater aquifer in Bangladesh

Continuous core sediments (to a depth of 90.1 m) taken at a transitional area of Holocene and Pleistocene deposits in Sonargaon, Bangladesh were characterized for their mineralogy and chemistry. Among the sediments of the lower part of the Holocene aquifer (depth: 18–29 m), where most domestic wells are installed, As is mostly fixed in biotite and organic phases. A positive correlation of As concentration with those of Al and Fe but not that of total organic C clearly suggests that biotite is a primary source of As. Although microbial reduction–dissolution of As-containing Fe oxyhydroxides is thought to cause As-enriched groundwater in the Ganges–Brahmaputra–Meghna delta plain, the authors conclude that chemical weathering of biotite is the primary formation mechanism and prevailing reducing conditions contribute to the expansion of As-enriched groundwater in the study area.     

An integrated approach for aquifer vulnerability mapping using GIS and rough sets: study from an alluvial aquifer in North India

A modified DRASTIC model in a geographic information system (GIS) environment coupled with an information-analytic technique called ‘rough sets’ is used to understand the aquifer vulnerability characteristics of a segment of the lower Kali watershed in western Uttar Pradesh, India. Since the region is a flat plain, topography (T) is removed as a potential control. Other parameters are the same as in DRASTIC, hence the new model is termed as DRASIC. The rough set technique is employed to provide insight into the relative vulnerabilities of different administrative units (blocks) within the study area. Using rough sets, three important factors are computed: strength, certainty and coverage. Strength indicates how the vulnerability characteristics vary in the entire area, certainty gives the relative fractions of low, medium and high vulnerability regions within a particular block, and coverage computes the percentage of a particular vulnerability state in each block. The purpose of the work is to demonstrate the utility of this integrated approach in classifying different administrative blocks in the study area according to their aquifer vulnerability characteristics. This approach is particularly useful for block-level planning and decision making for sustainable management of groundwater resources.     

Role of groundwater protection planning in groundwater governance: A case study from North India

In the present case study, impact of urbanization and industrial development on the shallow groundwater regime of Saharanpur town of Uttar Pradesh in India is examined with the aim of planning groundwater protection for better governance. The hazardous physicochemical and bacteriological parameters and heavy metals detected in the shallow aquifer include harmful pathogens like fecal coliforms, heavy metals like cadmium, chromium, nitrates and sulphates. An assessment of ground water vulnerability using the well known DRASTIC method has confirmed that the shallow groundwater in some central and southern localities of Saharanpur town fall in the medium risk zones. Further, using field data of 32 electrical resistivity soundings, the protective capacity of the unconfined aquifer is assessed in terms of a ‘total longitudinal conductance’ of the semi-pervious to impervious sediments overlying the unconfined aquifer. However, some areas aligned along a northwest-southeast and in the western parts of the town seem to have relatively higher protective capacity against infiltrating waste pollutants. A ground water protection planning map prepared by combining the DRASTIC map and the ‘potentially hazardous pollutants’ map has brought out the need to install eleven new groundwater quality monitoring wells in the town at locations near the line sources and point sources of pollution. This approach can be readily employed by the decision makers in framing sound guidelines for groundwater protection and governance.     

The impact of intensive groundwater abstraction on recharge to a shallow regional aquifer system: evidence from Bangladesh

Quantitative evaluations of the impact of groundwater abstraction on recharge are rare. Over a period (1975??007) during which groundwater abstraction increased dramatically in the Bengal Basin, changes in net groundwater recharge in Bangladesh are assessed using the water-table fluctuation method. Mean annual groundwater recharge is shown to be higher (300??00?mm) in northwestern and southwestern areas of Bangladesh than in southeastern and northeastern regions (<100?mm) where rainfall and potential recharge are greater. Net recharge in many parts of Bangladesh has increased substantially (5??5?mm/year between 1985 and 2007) in response to increased groundwater abstraction for irrigation and urban water supplies. In contrast, net recharge has slightly decreased (??.5 to ???mm/year) in areas where groundwater-fed irrigation is low (<30% of total irrigation) and where abstraction has either decreased or remained unchanged over the period of 1985??007. The spatio-temporal dynamics of recharge in Bangladesh illustrate the fundamental flaw in definitions of “safe yield??based on recharge estimated under static (non-pumping) conditions and reveal the areas where (1) further groundwater abstraction may increase actual recharge to the shallow aquifer, and (2) current groundwater abstraction for irrigation and urban water supplies is unsustainable.