Geochemistry of Manasbal lake sediments,Kashmir: Weathering,provenance and tectonic setting

This paper presents a detailed sediment chemistry investigation of the Manasbal lake, Srinagar, Jammu and Kashmir, India, which is one of the high altitude lakes in the Kashmir valley. 22 lake floor sediment samples covering the entire lake were collected and analyzed for textural characteristics, CaCO₃, organic matter, TOC, TN contents, C/N ratio, major and trace element chemistry. These analyses were conducted to trace the provenance of the sediments. Textural parameters reveal that the lake sediments consist predominantly clay and silt fractions. The C/N ratio of the sediments indicates a mixed source of TOC, both autochthonous and allochthonous in origin. The log (Fe₂O₃/K₂O) Vs. log (SiO₂/ Al₂O₃) graph of the sediments discriminates the rock types of the catchment area that are Fe-shale, Fe-sand, wacke, shale and litharenite. The Chemical Index of Alteration (CIA) falls between 59.11 to 90.16% and Chemical Index of Weathering (CIW) between 63.97 to 99.68% and these values are higher than the Post-Archaean Australian Shale (PAAS), indicating moderate to highly chemically weathered lake floor sediments. Plagioclase Index of Alteration (PIA) values (60.74-99.63%) suggests the occurrence of plagioclase feldspars in the lake floor sediments. Geochemical characteristics signify a mixed-nature of provenance of the lake floor sediments due to the tectonic settings of the lake basin in a complex catchment area.     

Geochemical characteristics of modern river sediments in Myanmar and Thailand: Implications for provenance and weathering

The elemental composition of organic matter and the major and trace element compositions of stream sediments from Myanmar (Ayeyarwady and Sittaung rivers) and Thailand (Mekong and Chao Phraya rivers, and their tributaries) were determined to examine their distributions, provenance, and chemical weathering processes. Higher total organic carbon (TOC) and total nitrogen (TN) contents in the finer grained sediments indicate hydrodynamic energy may control their distributions. TOC/TN ratios indicate inputs of both aquatic macrophyte and higher vascular plant material to the river sediments. The major element abundances of the sediments are characterized by predominance of SiO₂ in coarser fractions and a marked negative correlation with Al₂O₃, representing primary grain size primarily control on SiO₂ content. Marked depletion of most labile elements (Na₂O, CaO, K₂O, Ba and Sr) relative to UCC (upper continental crust), indicate destruction of feldspar during chemical weathering in the source area or during transport. However, enrichment of some high field strength elements (Zr, Th, Ce and Y) relative to UCC and higher Zr/Sc ratios indicate moderate concentration of resistant heavy minerals in finer-grained samples. Discriminant diagrams and immobile trace element characteristics indicate that the Mekong, and Chao Phraya river sediments were largely derived from felsic sources with compositions close to typical rhyolite, dacite/granodiorite, UCC, I- and S-type granites. Relative enrichment of ferromagnesian elements (e.g. MgO, Cr, Ni) and high Cr/V and low Y/Ni ratios in Ayeyarwady and Sittaung sediments indicate the presence of a mafic or ultramafic component in their sources. The ICV (Index of Compositional Variability), CIA (Chemical Index of Alteration), PIA (Plagioclase Index of Alteration), α^Al, Rb/Sr and K₂O/Rb ratios indicate that the Ayeyarwady and Sittaung sediments record low to moderate degrees of chemical weathering in their source, compared to moderate to intense chemical weathering in the Mekong and Chao Phraya river basins. These results are compatible with existing major ion data for river waters collected at the same locations.     

Geochemistry and provenance of the Miocene sandstones of the Surma group from the Sitapahar anticline,Southeastern Bengal Basin,Bangladesh

Geochemical composition (major and trace elements) of Miocene sandstones of the Surma Group exposed in Sitapahar anticline, Southeastern Bengal Basin was determined to reveal their provenance, tectonic setting and source area weathering conditions. The sandstones are sub-arkosic, sub-lithic and greywacke in composition with abundant low-grade metamorphic, sedimentary lithics (mainly chert with some shale fragments), low feldspars and little volcanic detritus. Compared to the average sandstone value, the Surma Group sandstones are depleted in CaO and enriched in Al₂O₃, Fe₂O₃ and Na₂O. The Chemical Index of Alteration (CIA) values for the Miocene Surma Group sandstones vary from 57 to 73 with an average of 65, indicating low to moderate weathering of the source areas. The geochemical characteristics suggest an active continental margin to passive margin setting for the Surma Group sandstones; preserve the signatures of a recycled provenance that is agreement with sandstone petrography and derivation of these sandstones from felsic source rocks.     

Provenance and weathering history of Mesoproterozoic clastic sedimentary rocks from the basal Gulcheru Formation,Cuddapah Basin

Geochemical analysis for the Mesoproterozoic clastic sedimentary rocks of the basal Gulcheru Formation of the Cuddapah Basin in the Gugudu-Dadithota-Parnapalle-Palkonda region (extending atleast 40 km) have been performed to highlight their provenance and weathering history. The low K₂O/Al₂O₃ ratios of the representative samples points to the recycled nature of sediments and illite clay in the sediments indicate an overall cold climate (low chemical weathering degree). All the provenance diagrams indicate a mixed source of the Gulcheru sediments with felsic dominancy and Upper continental crust (UCC) signature.     

Petrography and geochemistry of the Late Cretaceous redbeds in the Gan-Hang Belt,southeast China: implications for provenance,source weathering,and tectonic setting

ABSTRACT

The distinct basin and range tectonics in southeast China were generated in a crustal extension setting during the late Mesozoic. Compared with the adjacent granitoids of the ranges, the redbeds of the basins have not been well characterized. In this article, provenance, source weathering, and tectonic setting of the redbeds are investigated by petrographic and geochemical studies of sandstone samples from the Late Cretaceous Guifeng Group of the Yongchong Basin in the Gan-Hang Belt, southeast China. Detrital grains are commonly subangular to subrounded, poorly sorted, and are rich in lithic fragments. The variable pre-metasomatic Chemical Index of Alternation (CIA* = 62–85), Chemical Index of Weathering (CIW = 70.90–98.76, avg. 85.62), Plagioclase Index of Alteration (PIA = 60.23–98.35, avg. 79.91), and high Index of Compositional Variability (ICV = 0.67–3.08, avg. 1.40) values collectively suggest an overall intermediate degree of chemical weathering and intense physical erosion of the source rocks, but a relatively decreased degree of chemical weathering during the late stage (Lianhe Formation) of the Guifeng Group is observed. Several chemical ratios (e.g. Al₂O₃/TiO₂, La/Th, Cr/Th, Th/Sc, Zr/Sc) also suggest a dominant felsic source nature, significant first-cycle sediment supply, and low sedimentary recycling. Such features are consistent with active extension tectonic setting. Sandstone framework models and geochemical characteristics suggest the provenance is related to passive margin (PM), active continental margin (ACM), and continental island arc (CIA) tectonic settings. Sediment derivation from the Neoproterozoic metamorphic rocks and Silurian–Devonian granites indicates a PM provenance, whereas sediments derived from the Early Cretaceous volcanic-intrusive complexes suggest an ACM and CIA nature. Therefore, the Late Cretaceous redbeds were deposited in a dustpan-like half-graben under the back-arc extension regime when southeast China was possibly influenced by northwestward subduction of the Palaeo-Pacific plate beneath East Asia.     

Petrography and geochemistry of Jumara Dome sediments,Kachchh Basin: Implications for provenance,tectonic setting and weathering intensity

In the Kachchh Mainland, the Jumara Dome mixed carbonate-siliciclastic succession is represented by the Jhurio and Patcham formations and siliciclastic-dominating Chari Formation （Bathonian to Oxfordian）. The Ju- mara Dome sediments were deposited during sea-level fluctuating, and were interrupted by storms in the shallow marine environment. The sandstones are generally medium-grained, moderately sorted, subangular to subrounded and of low sphericity. The sandstones are mineralogically mature and mainly composed of quartzarenite and subar- kose. The plots of petrofacies in the Qt-F-L, Qm-F-Lt, Qp-Lv-Ls and Qm-P-K ternary diagrams suggest mainly the basement uplift source （craton interior） in rifted continental margin basin setting. The sandstones were cemented by carbonate, iron oxide and silica overgrowth. The Chemical Index of Alteration values （73% sandstone and 81% shale） indicate high weathering conditions in the source area. Overall study suggests that such strong chemical weathering conditions are of unconformity with worldwide humid and warm climates during the Jurassic period. Positive correlations between A1203 and Fe203, TiO2, Na20, MgO, K20 are evident. A high correlation coefficient between A1203 and K20 in shale samples suggests that clay minerals control the major oxides, The analogous con- tents of Si, A1, Ti, LREE and TTE in the shale to PAAS with slightly depleted values of other elements ascribe a PAAS like source （granitic gneiss and minor mafics） to the present study. The petrographic and geochemical data strongly suggest that the studied sandstones/shales were deposited on a passive margin of the stable intracratonic basin.     

华北北部中元古界洪水庄组页岩地球化学特征： 物源及其风化作用

华北北部洪水庄组黑色页岩是中元古代的富有机质沉积,它可能记录了当时重要的地球化学信息。通过对洪水庄组页岩中的常量和微量元素特征的分析,研究了洪水庄组的物源及其风化作用。高Th/Sc、Al2O3/TiO2、La/Sc、La/Cr、La/Co、Th/Cr和Th/Co值,低Cr/Zr和TiO2/Zr比值,Euan值、Co/Y Ti/Zr关系和La Th Sc组成表明洪水庄组页岩物源主要为上地壳中的长英质花岗闪长岩。洪水庄组页岩的Al、Ca、Na和K组成表明其具有较高的化学蚀变指数（CIA）,同时,元素组成的化学风化作用轨迹反映了洪水庄组页岩受到钾交代作用的影响,可能导致CIA值被低估,其原始CIA值应在90以上。高的原始CIA、化学风化指数（CIW）和斜长石蚀变指数（PIA）表明洪水庄组物源区经历了强烈的化学风化作用。化学风化作用强度以及微量元素组成特征揭示了中元古代洪水庄组沉积时期可能处于温暖潮湿的气候条件,这与中元古代时期大气高CO2浓度以及华北板块古大陆当时位于低纬度地区重建的结果不谋而合。     

Evaluation of environmental status and geochemical assessment of sediments,Manasbal Lake,Kashmir, India

The present study was conducted on the Manasbal Lake (34°14′N: 74°40′E) to assess the geochemical characteristics of the lake bottom sediments, its environmental implications and its response in the local catchment area. This study tracks the spatial distribution of grain size, geochemical analysis, C/N ratio, calcium carbonate (CaCO₃) and organic matter (OM) of the lake bottom sediments. It is observed that the clay fraction (49.79%) is predominant in the lake bottom sediments, followed by silt (35.88%) and sand (14.33%) and its spatial distribution is controlled by water depth. Geochemistry and normalized diagrams for the major oxides and trace elements reveal enrichment of CaO, K₂O, P₂O₅, S, Cl, Ni, Zn and Sr. Chemical index of alteration (CIA) reflects low to moderate weathering intensity and near compositional similarity with the bedrock exposed in the catchment area around the lake. Environmental indices (EF, Igeo) suggest that the sediments are enriched in Cu, Ni, Zn, Cr, Co, Pb followed by Mn content. Pollution load index (PLI) reveal that all the sampling sites reflect low to moderately polluted category except for few stations that are towards the southern and southeastern side of the lake. OM (16.85%), CaCO₃ (14.04%) and C/N ratio (15.5) of the lake bottom sediments is attributed to high organic activity within the lake, shell fragments, contributions from the lake flora and fauna adhering to the clayey silty sediments. The C/N ratio of 15.5 suggests a mixed source of organic matter both terrestrially and in situ formation within the lake. Sulphur and chlorine are high amongst the trace elements suggesting anthropogenic detritus input into the lake and this is due to the chemical fertilizers from the agricultural runoff and organic load into the lake. Thus, the present study suggests that in order to preserve the pristine lake ecology and the environment; continued monitoring and restoration efforts need to be undertaken.     

Measuring and adjusting the weathering and hydraulic sorting effects for rigorous provenance analysis of sedimentary rocks: a case study from the Jurassic Ashikita Group,south‐west Japan

The present study examines the provenance of the Jurassic Ashikita Group distributed in south‐west Japan, which is composed of the Idenohana, Kyodomari and Sakamoto Formations. Two geochemical diagrams for provenance analysis were utilized, which incorporate full consideration of compositional modifications resulting from weathering (MFW diagram) and hydraulic sorting processes (SiO₂/Al₂O₃–Na₂O/K₂O diagram). The MFW diagram delineates weathering trends of sedimentary rocks and allows estimation of the original source rock composition by tracing the weathering trends backwards to an unweathered domain. Weathering trends of the Idenohana and Kyodomari Formations extend backward to the domain of intermediate and felsic igneous rocks. In contrast, sediments of the Sakamoto Formation do not fit into a linear weathering trend, indicating that the source rock cannot be approximated to igneous rocks. On the SiO₂/Al₂O₃–Na₂O/K₂O diagram, sediments are organized into compositional trends, in which the range reflects compositional variations induced by the hydraulic sorting effect. On this diagram, sediments derived from the igneous and recycled sedimentary provenances can be distinguished by reading the inclination of the trend. By utilizing this principle, source rocks of the Idenohana and Kyodomari Formations are interpreted as igneous rocks and those of the Sakamoto Formation are interpreted as recycled sedimentary rocks. Therefore, these diagrams concurrently estimate the source rock composition through quantifying and adjusting the weathering and sorting effects, and reveal a systematic transition in the provenance of the Ashikita Group. The Idenohana and Kyodomari Formations were supplied chiefly from an igneous provenance, which shifted from intermediate to felsic compositions in stratigraphic order. Whereas, sediments of the Sakamoto Formation were sourced primarily from a recycled sedimentary provenance.     

Geochemistry of sandstones from the Neoproterozoic Jinshanzhai Formation in northern Anhui Province, China: Provenance, weathering and tectonic setting

Sandstones from the Neoproterozoic Jinshanzhai Formation in northern Anhui Province, China, were analyzed for major oxides and trace elements to infer their provenance, the intensity of paleo-weathering of their source rocks and the depositional tectonic setting. Diagrams of (SiO2/20)-(Na2O+K2O)-(MgO+TiO2+FeO*), TiO2-Ni, Th-Hf-Co, Hf-La/Th and some ratios of elements indicate that felsic rocks constitute the source rocks in the provenance. The values of Chemical Index of Alteration (CIA) are low, which are considered to be affected by K-metasomatism. Whereas the high CIW (Chemical Index of Weathering) values indicate intensive weathering of the source material. Plots of sandstones on bivariate and triangle discriminant diagrams, as well as ICV (Index of Compositional Variation) values revealed that they were deposited on a passive continental margin or in an intra-plate basin. Our recent study, in combination with previous studies and the research progress of the Rodinia super continent, demonstrated that the convergence and extension of the Rodinia super continent were preserved by twice extension as expressed by petrological variation of the southeastern margin of the North China Craton (NCC) during the Neoproterozoic.     

Geochemistry of Renuka Lake and wetland sediments,Lesser Himalaya (India): implications for source-area weathering,provenance, and tectonic setting

The geochemical investigation of sediments deposited in the Renuka Lake basin and its adjoining wetland has shown variation in the distribution and concentration of major, trace and REEs. The major elements are depleted in the lake in relation to wetland and that of Post Archaean Australian, Shale (PAAS), except for CaO which is strikingly in excess and has a dilution effect on SiO₂ and other oxides and trace elements. The Wetland sediments, on the other hand, are enriched in Al₂O₃, Fe₂O₃, K₂O and TiO₂ and the latter three show a positive correlation with Al₂O₃ in both wetland and lake sediments suggesting their association with phyllosilicates and similar source rocks. The enrichment of Y, Zr, Ni, Th, U and Nb in wetland compared to lake and their similarity with PAAS in the former, suggests more clay fractions in the wetland. A high Zr/Hf ratio in wetland and lake sediments and a positive correlation of Zr with Y and HREE indicate Zr control on HREEs. However, higher Zr/Yb and Zr/Th ratios in wetland compared to lake indicate mineral sorting during the process of lighter particles (clays) being trapped in wetland soil. This is also reflected from negative correlation of Gd_N/Yb_N with Al₂O₃ and a strong positive correlation with SiO₂ in wetland sediments. The wetland in this context has a control on lake sediment chemistry. The chondrite normalized REE patterns are essentially the same for lake as well as wetland sediments but abundance decreases in the former. The similarity of pattern with that of PAAS and negative Eu anomaly indicates a cratonic source of sediments. In a plot of the individual samples, wetland samples cluster while lake samples are separated indicating fractionation of lake sediments. A strong positive correlation of La_N/Yb_N with Al₂O₃ and a positive correlation of Zr-∑LREE and Zr-La_N/Yb_N suggest that LREEs are controlled by both phyllosilicates and zircon. The chemical index of alteration (CIA) indices in lake sediments and in wetland are higher than PAAS indicating moderate chemical weathering in the source area. The petrography, lack of felsic magmatic rock fragments, and negative correlation between Zr-(Gd/Yb)_C indicate sedimentary source rocks for the detritus. This is in conformity with the Lesser Himalayan sedimentary sequence belonging to neo-Proterozoic–Proterozoic age and constituting lake catchment of Renuka. The tectonic delineation and discriminant function plots of lake and wetland sediments indicate their cratonic and/or quartzose sedimentary orogenic terrain source that has been deposited in a passive margin setting.     

Geochemistry of Vellayani lake sediments: Indicators of weathering and provenance

The Vellayani lake, located on the west coast, Kerala, South India, is a natural fresh water lake. In order to understand the source and nature of the sediments; thirteen lake floor sediment samples were collected from the Vellayani lake at different intervals along the S-N transects covering the entire surface area of the lake. Textural studies indicate that lake floor sediments are dominant in sand (55.39%) followed by clay (30.57%) and silt (14.04%) fractions. Coarse components are dominant at the inlet ofthe stream into the lake. The geochemical content of the sediments reveals low SiO₂, MnO, CaO, MgO, Na₂O, K₂O, and P₂O₅ content while TiO₂, Fe₂O₃ and Al₂O₃ are high when compared with Post Archean Australian Shale (PAAS) and Upper Continental Crust (UCC) values. SiO₂ is high in coarse fractions while Al₂O₃ is strongly associated with fine sediments. Major oxide contents supported by Rare Earth Element (REE) data reveal a distinct negative Eu anomaly reflecting a dominant cratonic origin of the sediments. Detailed geochemical data indicate a mixed source, predominantly, the lateritic soils, sedimentary and metamorphic bedrocks exposed around the lake and in the catchment area.     

Provenance, tectonics and source weathering of modern fluvial sediments of the Brahmaputra–Jamuna River, Bangladesh: Inference from geochemistry

This present study describes the elemental geochemistry of fluvial sediments in the Kurigram (upstream) to Sirajganj–Tangail (downstream) section of the Brahmaputra–Jamuna River, Bangladesh, with the aim of evaluating their provenance, weathering and tectonic setting. Petrographically, the sediments are rich in quartz (68%), followed by feldspars (8.5%) and lithic grains (7%). The bulk sediment chemistry is influenced by grain size. Concentrations of TiO₂, Fe₂O₃, MgO, K₂O, P₂O₅, Rb, Nb, Cr, V, Y, and, Ce, Th and Ga slightly decrease with increasing SiO₂/Al₂O₃ and grain size, suggesting clay matrix control. In contrast, concentrations of CaO, Na₂O, Sr and Pb increase with increasing SiO₂/Al₂O₃ and grain size, suggesting residence of these substances in feldspar. Decrease in Zr as grain size increases is likely controlled both by clay matrix and heavy minerals. In addition, heavy minerals' sorting also influences Ce, Th, Y and Cr abundances in some samples. The sediments are predominantly quartzose in composition with abundant low-grade metamorphic and sedimentary lithics, low feldspars and trace volcanic detritus, indicating a quartzose recycled orogen province as a source of the sediments. Discriminant diagrams together with immobile element ratio plots show that, the Brahmaputra–Jamuna River sediments are mostly derived from rocks formed in an active continental margin. Moreover, the rare earth element ratios as well as chondrite-normalized REE patterns with flat HREE, LREE enrichment, and negative Eu anomalies indicate derivation of the sediments of Brahmaputra–Jamuna River from felsic rock sources of upper continental crust (UCC). The chemical indices of alteration suggest that Brahmaputra–Jamuna River sediments are chemically immature and experienced low chemical weathering effects. In the A–CN–K ternary diagram, most of the samples close to the plagioclase–K-feldspar join line and to the UCC plot, and in the field of various lithologies of Higher Himalayan Crystalline Series, suggesting that rocks in these series are likely source rocks. Therefore, the elemental geochemistry of the Brahmaputra–Jamuna River sediments is controlled mostly by mechanical breakdown of lithic fragments and subsequent preferential attrition of muscovite > albite > quartz.     

Provenance and weathering history of the maastrichtian shale member of the Patti Formation,southern Bida Basin,Nigeria

The present study is focused on the geochemical characterization and provenance of the shale member of the Maastrichtian Patti Formation which is well represented at the centre of the southern Bida Basin in Nigeria. The major element composition of the studied shales and clays compare favourably with the reference shales, however, the trace elements vary slightly. Application of binary plot of TiO₂ versus Al₂O₃ and Al₂O₃/TiO₂ ratios of the studied shale samples show mixed mafic to felsic igneous sources. The chemical composition (plot of SiO₂ versus Log (K₂O/Na₂O) indicates active to passive continental margin province, however, a minor derivation from recycled provenance is probable. Intense chemical weathering based on the high values of Chemical Index Alteration (CIA), Chemical Index of Weathering (CIW) and Zr values obtained from the shale and clay samples a warm humid condition is suggested. The high values also probably suggest predominance of clay minerals and low feldspar. This is supported by the XRD (X-Ray Diffractometer) data which indicates predominance of kaolinite in the samples.     

Petrography and geochemistry of Eocene sandstones from eastern Pontides (NE TURKEY): Implications for source area weathering,provenance and tectonic setting

Subaerial weathering level, source area and tectonic environments were interpreted by using petrographic and geochemical characteristics of Eocene age sandstones found in the eastern Pontides. The thickness of Eocene age clastic rocks in the eastern Pontides ranges from 195 to 400 m. Mineralogical components of sandstones were mainly quartz, feldspar, rock fragments, and opaque and accessory minerals. Depending on their matrix and mineralogical content, Eocene age sandstones are identified as arkosic arenite-lithic arenite and feldspathic wacke-lithic wacke. CIA (Chemical Index of Alteration) values observed in the Eocene age sandstones (43–55) suggest that the source terrain of the sandstones was not affected by intense chemical weathering. Low CIW/CIA (Chemical Index of Weathering/Chemical Index of Alteration) values of the sandstones studied here suggest only slightly decomposed material and having undergone little transport until final deposition. Zr/Hf, Th/Sc, La/Sc and CIA ratios are low and demonstrate a mafic source; on the other hand, high LREE/HREE ratios and a slightly negative Eu anomaly indicate a subordinate fclsic source. Modal mineralogical and SiO₂/Al₂O₃ and K₂O/Na₂O and Th, Zr, Co, Sc of Eocene age sandstone contents indicate that they are probably magmatic arc originated and deposited in the back arc basin.     

Modelling Compositional Change: The Example of Chemical Weathering of Granitoid Rocks

Perturbation on the simplex is an operation which can be used to numerically describe changes in the composition of, for example, soils, sediments, or rocks. The combination of perturbation and power transformation provides a strong tool for analyzing compositional linear processes in the simplex. When the process is constrained in the sense of a well-known starting (or final) composition, noncentred principal component analysis can be used to estimate the leading perturbation vector of the process. Applying these mathematical tools to chemical major element data from a weathering profile developed on granitoid rocks allows us to model the compositional changes associated with the process of chemical weathering. The comparison of these results with the compositional linear trend defined by erosional products of several of the world's major drainage systems yields close similarities. The latter observation allows for a mathematical formulation of a global mean weathering trend within the system Al₂O₃–CaO– Na₂O– K₂O. We further demonstrate the usefulness of the approach for validating processes behind individual trends and for combining the effects of different processes which modify the composition of soils, sediments, and rocks. Alternatives to the Chemical Index of Alteration (CIA) are discussed to obtain a translation-invariant scale for the process of chemical weathering.     

Geochemistry of shales from the Upper Miocene Samh Formation,north Marsa Alam,Red Sea,Egypt: implications for source area weathering,provenance, and tectonic setting

The Upper Miocene shales of the Samh Formation, North Marsa Alam along the Egyptian Red Sea coastal plain were analyzed for major and selected trace elements to infer their provenance, weathering intensity, and tectonic setting. The Samh Formation consists of sandstone underlies by shale and marl intercalations. The Samh shales are texturally classified as mudstones. Mineralogically, these shales consist mainly of smectite and kaolinite, associated with non clay minerals (abundant quartz and trace of plagioclase, microcline, and halite). Compared to post-Archaean Australian shales (PAAS), the Samh shales are highly enriched in SiO₂, Al₂O₃, and Fe₂O₃ and depleted in TiO₂, P₂O₅, Na₂O, MgO, and K₂O contents. The K₂O/Al₂O₃ ratio values indicate predominance of clay minerals over K-bearing minerals. Trace elements like zirconium (Zr), Cr, Pb, Sc, Rb, and Cs are positively correlated with Al₂O₃ indicating that these elements are likely fixed in K-feldspars and clays. The Chemical Index of Alteration (CIA), Plagioclase Index of Alteration (PIA), and Chemical Index of Weathering (CIW) values indicate moderate to intense weathering of the source material in a semiarid climate. The geochemistry results suggest that the Samh shales were deposited in a passive margin of a synrift basin and derived from felsic (granitic) source rocks. The inferred tectonic setting for the Upper Miocene Samh shales in Marsa Alam is in agreement with the tectonic evolutionary history of the Eastern Desert of Egypt during the Upper Miocene.     

Mineralogy and geochemistry of sediments from Simbock Lake,Yaoundé area (southern Cameroon): provenance and environmental implications

Two cores of sediments, named NR and EB, were collected in the Simbock Lake (Mefou watershed, Yaoundé) to assess their provenance and the degree of heavy metal pollution based on mineralogical and geochemical data. The sediments are sandy, sand-clayey to clayey, and yellowish brown to greenish brown, and with high amounts of organic matter (average value of TOC is 1.95%). The sediments are mainly composed of quartz, kaolinite, accessory goethite, smectite, rutile, feldspars, illite, gibbsite, and interstratified illite-vermiculite. Fourier transform infrared (FT-IR) spectroscopy shows that kaolinite is less crystallized in the NR core than in the EB core. The Index of Compositional Variability (ICV), Chemical Index of Alteration (CIA), Plagioclase Index of Alteration (PIA), and the Rb/Sr and K₂O/Rb ratios indicate a high weathering intensity in the source area. These sediments have low contents in Al₂O₃, Fe₂O₃, Na₂O, K₂O, MgO, and CaO as well as high values in SiO₂, P₂O₅, TiO₂, and MnO relative to the upper continental crust. The concentrations of Cr, V, Ba, and Zr are higher in the NR core than those in EB. The total rare earth element (REE) content varies between 78 and 405 ppm. The light REE are abundant (LREE/HREE ~?18–59; avg.?=?25.61). The chondrite-normalized REE patterns exhibit (i) negative Eu anomaly (Eu/Eu^* ~?0.38–0.62; avg.?=?0.5), (ii) slight positive Ce anomaly (Ce/Ce^* ~?1.11–1.34; avg.?=?1.11), and (iii) high REE fractionation ((La/Yb)_N ~?12.3–51.75; avg.?=?25.61). The enrichment factor (EF) shows that the Mefou watershed through the Simbock Lake sediments is slightly polluted by the agricultural and urban activities.     

Origin, weathering, and geochemical composition of loess in southwestern Hungary

Loess geochemistry generally reflects paleo-weathering conditions and it can be used to determine the average composition of the upper continental crust (UCC). In this study, major and trace element concentrations were analyzed on loess samples from southwestern Hungary to determine the factors influencing their chemical compositions and to propose new average loess compositions. All studied loess samples had nearly uniform chemical composition, suggesting similar alteration history of these deposits. Chemical Index of Alteration values (58–69) suggested a weak to moderate degree of weathering in a felsic source area. Typical non-steady state weathering conditions were shown on the Al₂O₃–CaO + Na₂O–K₂O patterns, indicating active tectonism of the Alpine–Carpathian system during the Pleistocene. Whole-rock element budgets were controlled by heavy minerals derived from a felsic magmatic or reworked sedimentary provenance. Geochemical parameters indicated that dust particles must have been recycled and well homogenized during fluvial and eolian transport processes.     

Climate implications of major geochemical elements in the Holocene sediments of the North and East China monsoonal regions

Two Holocene sediment cores were retrieved respectively from the enclosed Lake Daihai in the monsoon/arid transition zone of North China and the Taihu Lake coast in the monsoonal area of the Yangtze delta, Eastern China. Distribution of major geochemical elements and their ratios were employed to reveal the characteristics of Holocene climate and associated environmental implications in the two regions. It is suggested that the temporal distribution of major elements serve as a useful indicator to denote the variations of monsoon effective precipitation for the enclosed lake area. High values of resistant elements such as Al₂O₃, SiO₂, TiO₂, (FeO + Fe₂O₃), MnO in the lake sediments correspond to the depressed chemical weathering and weakened mon-soon effective precipitation, while the highs of mobile and easy soluble elements such as MgO, CaO, Na₂O reflect the enhanced chemical weathering and increased monsoon effective precipitation in the lake basin. In comparison, the behaviors of the major elements in sediments of the Taihu Lake coast were largely controlled by the changes both in sea transgression in the different Holocene time periods and the monsoon precipitation. The relatively highs of Al₂O₃, TiO₂, (FeO + Fe₂O₃), in marine-influenced sediments suggest relatively strong coastal hydrodynamics and chemical weathering, and vice versa. Meanwhile, the lows of SiO₂, Na₂O and CaO in the non-marine-influenced sediments also denote relatively strong hydrodynamics and chemical weathering due to enhanced monsoon precipitation, and vice versa. Sedimentary environment should be taken into account when achieving a full understanding of their climate implications.