蜀南地区茅口组古岩溶地貌与缝洞系统发育关系研究

蜀南地区茅口组古岩溶地貌形态对缝洞系统的发育起着控制作用。在恢复茅口组古地貌的基础上,根据上二叠统在区域上的分布厚度、风化壳表面侵蚀特征和茅口组地层保存程度,将茅口组顶部古岩溶面划分为岩溶台地、岩溶坡地(又分为西部陡坡带和北东部缓坡带)和岩溶盆地3个二级地貌单元;研究了各地貌单元和缝洞系统发育关系。结果表明:岩溶台地岩溶水以垂向渗流为主,风化剥蚀强烈,形成垂向的溶缝、溶洞常被泥质等充填,横向连通性弱;岩溶陡坡、岩溶台地和岩溶陡坡过渡带岩溶作用最强,溶孔、溶洞发育,且充填程度低,缝洞系统最为发育,是有利的勘探区带;岩溶缓坡水流速度慢,岩溶作用周期长,溶蚀空间易受充填,不利于缝洞保存;岩溶盆地岩溶发育最弱,储集性能差,是不利的勘探区带。      

轮南奥陶系潜山表层岩溶储层的分布特征

轮南古潜山位于塔里木盆地塔北隆起轮南低凸起中部地区,主要岩溶层位是奥陶系鹰山组与一间房组,轮南古潜山的形成条件和表生岩溶作用时间与中国南方的桂林岩溶存在极其相似之处。本文通过研究轮南地区古风化壳表层岩溶带发育分布特征及其形成影响因素,认为:表层岩溶带主要分布于距古风化面以下0～40m范围内,此带范围内岩溶缝洞系统相对比较发育,岩溶缝洞系统具有一定连通性,属岩溶储层较为发育的部位,岩溶储层有效储集空间主要是溶蚀孔洞、小规模溶洞和溶蚀裂缝;表层岩溶带发育与古岩溶地貌及古水动力条件具有密切关系,岩溶地貌类型或水动力条件不同,表层岩溶带发育厚度、岩溶形态与岩溶缝洞系统发育规模、岩溶缝洞系统充填特征也不同。      

塔里木盆地轮古东地区前石炭纪古岩溶微地貌及岩溶发育模式

以现代岩溶理论为指导,应用"印模与残厚组合法"恢复岩溶古地貌,在4种二级地貌类型(岩溶高地、岩溶陡坡地、岩溶缓坡地和岩溶盆地)划分的基础上,将塔里木盆地轮古东地区前石炭纪古岩溶地貌进一步划分为峰丛洼地、丘峰谷地、溶丘洼地、峰丛垄脊沟谷、峰丘洼地、丘丛垄脊沟谷、岩溶谷地、溶丘平原等8种三级地貌类型。并在垂向岩溶分带研究的基础上,明确了不同古岩溶地貌条件下的岩溶发育特征及充填机制。研究认为:岩溶高地为区域补给区,发育溶蚀裂缝和溶洞系统;岩溶陡坡地为补给-径流区,以高角度溶蚀裂缝为主;岩溶缓坡地为地下水径流区,发育暗河管道系统;岩溶盆地为排泄区,岩溶缝洞充填程度高。     

塔中西部奥陶系鹰山组古岩溶特征及主控因素

为明确塔中西部奥陶系鹰山组古岩溶储层发育及主控因素,总结鹰山组古岩溶特征及发育条件,划分了岩溶层组类型。在鹰山组古地貌恢复基础上,通过钻井、取心、测井等资料,分析丘状岩溶台地、上丘状岩溶缓坡地和下丘状岩溶缓坡地典型井岩溶缝洞特征。结合大量钻井资料分析了上述3类古地貌单元岩溶缝洞储层发育规律及主控因素。对岩溶缝洞储层发育深度分析表明,岩溶缝洞发育段主要在鹰山组顶面以下0~180 m,受3期海平面控制,发育多层缝洞。表层溶洞主要发育在0~50 m,泥质充填较强,测井GR值较高,溶洞规模多小于2 m。岩溶台地区岩溶缝洞形成受微地貌、水动力条件控制,以小规模溶洞、溶蚀孔洞、溶蚀裂缝为主,缝洞后期易充填。岩溶缓坡地岩溶缝洞形成受岩溶层组、水动力条件控制,以小溶蚀孔洞、溶蚀裂缝为主,后期不易充填。滨岸岩溶带及岩溶岛屿发育海水、混合水岩溶作用,溶蚀作用及冲蚀、侵蚀作用使该区域形成较大洞穴。     

古岩溶盆地岩溶作用模式及古地貌精细刻画——以鄂尔多斯盆地东部奥陶系风化壳为例

鄂尔多斯盆地东部奥陶系风化壳天然气勘探的核心问题是寻找储层 ,关键技术是对古沟槽、古台地的识别。该区风化壳储层不发育有两方面的原因 :一是沉积相带不利 ;二是风化壳岩溶部位不利 ,属于岩溶洼地 ,溶蚀作用较弱 ,充填作用较强。鄂尔多斯盆地东部奥陶系风化壳古岩溶地貌为地势平坦、向东开口的半封闭岩溶盆地 ,这就为该区古风化壳岩溶的发育创造了相对于其他全封闭盆地更好的条件。将岩溶盆地划分为谷地、台地、残丘、沟槽、浅洼 5种三级地貌单元类型 ,东部发育 3个水平岩溶带 ,第三水平岩溶带距夷平面 70～ 85m。根据观察结果及地下水的渗流规律 ,提出深潜流溶蚀带—深泉排水模式 ,为岩溶盆地风化壳储集体的发育提供了另一种可能的溶蚀作用方式。岩溶盆地在中深埋藏期压释岩溶作用较强 ,有利于储集体孔渗的改善、上古生界烃类的带入、古台地边缘致密带的产生及圈闭的形成。综合利用地质、钻井、地震及测井手段精细刻画了神木—榆林地区奥陶系风化壳古地貌 ,结果表明该地区古台地规模适中、古沟槽较多 ,认为东部是较有利的勘探区带     

新疆阿克苏地区震旦系风化壳古岩溶特征及其发育模式

阿克苏露头区多条震旦系地质剖面研究揭示震旦系风化壳古岩溶作用识别标志主要有区域性不整合面、大型洞穴垮塌角砾岩、溶洞、溶孔及高角度溶沟、溶缝等。震旦系风化壳古岩溶垂向分带结构以水平潜流带和深部缓流带为主,垂直渗流带发育较弱或不发育。水平潜流带以发育大型洞穴垮塌堆积体及蜂窝状溶洞群为特征,深部缓流带以发育孤立溶洞为特征。区域古岩溶特征及垂向分带结构对比表明,阿克苏露头区震旦系风化壳古岩溶模式为高潜水面缓坡型古岩溶。     

轮古西奥陶系潜山洞穴型岩溶储层发育特征与充填规律

洞穴型岩溶储层是塔里木盆地轮古油田缝洞型碳酸盐岩油藏的主要储集空间类型,多数高效井均钻遇大型洞穴型岩溶储层。依据轮古西奥陶系潜山大量单井资料分析,洞穴型岩溶储层可分为充填洞穴、半充填洞穴和未充填洞穴三种类型。结合古地貌精细刻画与岩溶垂向分带成果,认为古地貌位置由岩溶台地向岩溶缓坡和岩溶盆地逐渐降低,而洞穴发育和充填程度在逐渐增高。未充填与半充填洞穴主要发育在岩溶台地和岩溶缓坡的溶峰边坡、溶丘边坡及沟槽谷洼地边坡等地貌单元。表层岩溶带、径流溶蚀带洞穴型岩溶储层发育频率最高,其次为垂直渗滤带和潜流溶蚀带。未充填与半充填洞穴型岩溶储层主要发育在表层岩溶带。     

轮古西地区前石炭纪古岩溶微地貌特征及刻画

应用印模法,以石炭系区域标志层双峰灰岩底至奥陶系潜山面填平补齐的沉积厚度为标识,恢复了轮古西地区前石炭纪古岩溶地貌。自东向西划分了岩溶台地、岩溶缓坡地和岩溶盆地3类二级地貌单元。应用现代岩溶分类方法,根据微地貌组合形态,对二级地貌作精细刻画,划分了9种三级地貌单元。认为不同的地貌位置,其水动力条件不同,不同类型岩溶地貌的发育特征、古水系排泄和储层充填特征存在着差异性。     

塔河油田下奥陶统碳酸盐岩储层对比及储层剖面模型

塔河油田奥陶系储层为岩溶缝洞型的碳酸盐岩储层，缝洞储层的形成与古岩溶作用密切相关，风化壳期岩溶作用对储集空间的发育程度有明显的控制作用。不同的储集空间类型受控于不同的岩溶古地貌单元。裂缝性储层主要分布于风化壳型岩溶不发育地区，或褶皱和断裂构造较发育的变化强烈部位；裂缝-孔洞型储层的分布与古岩溶发育带和岩溶斜坡地区密切相关；裂缝-溶洞型储层其分布与裂缝及古岩溶发育带密切相关，常常是在古岩溶高地边缘或部分岩溶斜坡区，多位于多组构造线的交汇处及褶皱的轴部等。为进一步探讨研究区缝洞型碳酸盐岩储层的空间展布规律，根据暴露区淡水岩溶作用发育特点，依据碳酸盐岩储层的波阻抗响应特征、测井曲线、测试成果及开发动态资料，在恢复古岩溶地貌的基础上，对塔河油田（6区）的岩溶值得层进行了划分与对比。研究结果显示高产井多位于古岩溶地貌相对较高部位，而产量较少或没有出油气的井，则位于岩溶地貌相对较低部位。表明早期的古地貌形态对奥陶系碳酸盐岩溶蚀孔洞的发育具有明显的控制作用。岩溶储层的垂向发育和分布主要受碳酸盐岩古岩溶风化壳垂向分带性的影响，纵向上由风化壳顶面向下储层发育逐渐变差。以奥陶系古风化壳顶面为界，向下每60m为单位，对深度0-60m、60-120m、120-180m、180-240m岩溶储层的纵横向分布特征进行了分析，并建立了相应的储层剖面结构模型。     

鄂尔多斯盆地塔巴庙地区奥陶系古岩溶研究

鄂尔多斯盆地是我国重要的油气勘探基地之一,该盆地中一系列奥陶系大气田的发现,进一步揭示了下古生界碳酸盐岩,尤其是以古岩溶地层为主的层位赋存有丰富的油气资源。从塔巴庙地区岩心和薄片资料出发,对奥陶系古岩溶的发育期次及垂向分带和岩溶地貌单元进行了划分。古岩溶在垂向上发育了三期岩溶,每期岩溶又划分为四个岩溶带;平面上划分出了六个岩溶高地、四个岩溶低地以及三个岩溶缓坡(斜坡)。结合物性和气井资料,认为垂向上各期垂直渗流岩溶带储集物性较好;平面上岩溶高地Ⅰ1~Ⅰ4是有利的储层发育区;靠近高地Ⅰ1、Ⅰ2、Ⅰ4的岩溶缓坡及它们之间的区块也是值得重视的区域。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Analysis of F, Al, Mn, Zn, Fe, Cu, Ca and Mg concentrations in brick teas from main producing areas in China

Brick-tea-type fluorosis is a peculiar endemic disease in China, which had been discovered in minority areas of western China since 1980, and distributed mainly in Tibet, Inner Mongolia, Gansu, Xinjiang, Qinghai and parts of Sichuan Province. The prevalence rate of fluorosis in Tibetan and Mongolian nationality people was higher. Epidemiological investigation showed that fluorosis morbidity and degrees were different in different brick-tea drinking areas, and it was probably caused by drinking various kinds of brick tea from different regions. Therefore, we collected 33 samples of brick tea from six provinces where minority nationalities were accustomed to drinking a large quantity of brick tea. F concentrations were determined by the combustion hydrolysis-ion selective electrode method. The results showed that among the brick teas, the F concentrations ranged from the minimum 74.1 mg/kg in Yunnan Province to the maximum 991.2 mg/kg in Sichuan Province. Besides, there was a great difference among the various kinds of brick tea, and F concentrations decreased in the order of Kang brick tea, Green brick tea, Black brick tea, Mi brick tea, Fu brick tea, Chitsu ping tea, Puerh tea, and Tuo tea. The average F concentration in brick teas was 431.92 mg/kg.     

Shock-induced amorphous textures in plagioclase,Manicouagan, Quebec,Canada

The textural relationships and structural states of optically isotropic labradorite from the Manicouagan, Quebec, impact structure have been examined by light (optical) and transmission electron (TEM) microscopy. Two distinct diaplectic glasses have been recognized based on their contrasting morphology, timing and the inferred modes of formation. The earliest isotropic bands and grain-scale isotropism (maskelynite) optically exhibit a gradational,in situ transformation from crystalline plagioclase with preservation of relict textures (twins, grain boundaries). The same transformation from crystalline to amorphous structure is observed in TEM to occur heterogeneously at scales on the order of the unit cell. The progressive transformation of optical properties reflects an increase in the volume fraction and eventual coalescence of these amorphous units. This maskelynite-type diaplectic glass is interpreted to form in the solid-state directly from crystalline material during the compressional phase of the shock wave. The other isotropic material occurs in spatially discrete tensiongashes and planar deformation features (PDFs) that overprint the maskelynite-type glass. This second type of diaplectic glass (PDF-type) is developed homogeneously within a given glass band and exhibits sharp crystal-glass boundaries, in contrast to the gradational boundaries of the maskelynite-type glass. PDF-type glass is interpreted to form by melting in tensional release zones during passage of the rarefaction wave. These observations emphasize the ability of naturally shocked rocks to preserve subtle evidence of variations in the shock process from highly transient events.     

A catastrophic rockslide-debris flow in Wulong, Chongqing, China in 2009: background, characterization, and causes

On June 5, 2009, a catastrophic rockslide-debris flow occurred at the crest of the Jiweishan Mountain in Wulong, Chongqing, China. Approximately five million cubic meters of limestone blocks slid along a weak interlayer of bituminous and carbonaceous shale. The source mass descended from the upper part of the slope rapidly, crossing a 200-m wide and 50-m deep creek in front of it. Blocked by the opposite steep creek wall, the sliding mass changed its direction and traveled a further 2.2 km along the creek in debris-flow mode, finally forming a large accumulation zone with an average depth of 30 m. This is one of the most catastrophic rockslide events in recent years in China. It buried 12 houses and the entrance of an iron mining tunnel where some 27 miners were working inside. Ten people died, 64 missing, and eight wounded. Immediately after this disaster happened, the government organized an expert team to assist the rescue work. As one of the geological experts, the author did a lot of field investigations and collected first-hand information. Multi-methods including the remote sensing, 3D laser scanning, geophysical exploration, and numerical modeling were used for analyzing the characteristics and the triggering mechanism of the Wulong rockslide. The preliminary investigation results reveal that this rockslide with poor geological conditions was mainly induced by the gravitation and the karst effect and also affected by the previous mining activities. The research in this paper is meaningful and useful for further research on such kind of rockslides that are geologically similar to the Wulong rockslide.     

丘北普者黑岩溶地貌景观特征

通过介绍普者黑地区的岩溶地貌特征,借鉴石林和桂林的研究模式,对普者黑的岩溶地貌形成机理进行了深入研究,并针对普者黑独特的亚热带高原岩溶地貌的特征,阐述了其研究的科学价值。     

夏季长江河口潮间带反硝化作用和N2O的排放与吸收

采用培养箱乙炔抑制和现场静态箱法,于夏季(7月)在长江河口潮滩潮间带进行了采样,研究表明,长江河口潮滩水体自身N2O产生速率很低,在潮汐淹没期沉积物是上覆水体N2O的来源,其来自沉积物中反硝化、硝化等氮素循环的多个反应过程,沉积物中N2O自然产生速率在0.10～8.50μmol/(m2·h)之间,反硝化速率在21.91～35.87μmol/(m2·h)之间。退潮出露期中潮滩是大气N2O的排放源犤交换速率在-11.03～13.17μmol/(m2·h)之间犦,5～10cm地温是影响N2O排放速率的显著性因素;低潮滩-大气界面N2O排放、吸收速率在-5.75～0.49μmol/(m2·h)之间。总体上看,中潮滩是大气N2O的排放源;而低潮滩对大气N2O有明显的吸收作用。潮滩植被(海三棱草和底栖藻类)的光合作用明显抑制了N2O的排放并可能导致吸收,而其呼吸作用则增加了N2O的排放,潮间带-大气界面N2O的排放和吸收与CO2的排放、吸收有显著的正相关关系。     

日本北海道音调津的球状石墨

本文利用光学显微镜、X射线衍射仪、透射电镜等手段对日本北海道音调津球状石墨的成因、结构等进行研究,认为日本北海道音调津球状石墨中除了石墨外,还存在镍黄铁矿﹑黄铜矿﹑磁黄铁矿等金属硫化物矿物。通过透射电子显微镜观察发现音调津石墨中大部分是椭圆状石墨颗粒,高分辨晶格条纹主要是非晶态结构,但是同时也发现了结晶良好的石墨。高结晶度石墨的存在可能是在硫化物Fe-Ni-Cu的触媒作用下形成的。天然球状石墨的微结构和性状研究对天然石墨的形成和开发应用有重要意义,对新型碳材料的制备技术有重要科学意义。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

冀北张家口地区汉诺坝玄武岩中麻粒岩捕虏体的硫化物相

捕虏体麻粒岩是了解下地壳形成和演化的重要样品。汉诺坝新生代玄武岩中的二辉麻粒岩捕虏体样品中富含各种硫化物相,主要类型有:①孤立产出的球状出溶硫化物;②矿物颗粒之间或颗粒内的粗晶硫化物;③次生硫化物包裹体群;④裂隙充填硫化物。电子探针分析表明,硫化物的矿物成分均为贫镍磁黄铁矿,(Ni+Co+Cu)/Fe(原子比)远小于0.2;(Fe+Cu+Co+Ni)/S(原子比)比地幔岩的磁黄铁矿小,多小于0.875,反映了一种S过饱和环境。各种产状的磁黄铁矿中Au、Ag都有一定的含量,其平均值分别为0.19%～0.22%(Au)、0.01%～0.02%(Ag),反映下地壳的麻粒岩化与金矿化的成因联系。磁黄铁矿的Ni、Co、Cu含量与S正相关,说明微量重金属元素与S具有同源的关系,由于地幔去气伴随S而进入下地壳。     

Compositional evolution in Ca-amphibole in the Karmutsen metabasites, Vancouver Island, British Columbia, Canada

Abstract The 6-km-thick Karmutsen metabasites, exposed over much of Vancouver Island, were thermally metamorphosed by intrusions of Jurassic granodiorite and granite. Observations of about 800 thin sections from the Campbell River and Buttle Lake area show that the metabasites provide a complete succession of mineral assemblages ranging from the zeolite to pyroxene hornfels facies around the intrusion. The most important observations are as follows. (1) The compositional change of Ca-amphiboles with increasing metamorphic grade is not straightforward. The tremolite component decreases from the prehnite–actinolite facies to the greenschist facies with a compensating tschermak component increase, but the tendency is not clear thereafter. Instead, the edenite component increases from the amphibolite facies to the pyroxene hornfels facies. (2) The most pargasitic Ca-amphibole occurs in high-Fe²⁺/Mg metabasite from the greenschist/amphibolite transition zone. (3) The reasons for such irregular compositional trends, even in the rather uniform MORB-like composition of the Karmutsen metabasites, are non-ideal solid solutions of Ca-amphibole at low temperature and the effective control by bulk rock composition in the amphibolite facies. (4) The data from this study support, but do not prove, a transition loop for the actinolite–hornblende compositional gap rather than a solvus. If the gap is a solvus, its shape is asymmetric, and is highly dependent on the other compositional parameters such as Fe³⁺/Al and Fe²⁺/Mg. (5) The X_NaA/X_A±X_Ab) ratios between Ca-amphibole and plagioclase are most useful as an indicator of metamorphic grade even within the amphibolite facies, and these change systematically from 0.2 to 0.5 from the greenschist to pyroxene hornfels facies. (6) The compositional trend of Ca-amphibole from the Karmutsen metabasites indicates a typical low-P/T metamorphic facies series on a Rbk–Gln–Tr–Ts diagram.