Zur Geologie und Petrologie der Inseln Nisyros und Jali (Dodekanes)

Nisyros as well as the islet of Yiali are found in the crossing of two fault lines, that of Episcopi — Patmos and the one of southern Aegean (Soussaki-Gulf of Saronic — Milos — Santorini — Dodecanese) it consists almost exclusively of volcanic rocks, that is lavas and tuff and very limited appearence of Holocene formations. The presence of two volcanic effusions is certified, everyone of which began from basic magma, poor in SiO₂ (olivinic pyroxenic andesites), and gave as final products acidic petrological types (liparites and volcanic glasses). The basic magmas of the first volcanic periods are found only in few places and in very limited areas of appearence. After the ascension of volcanic fragmental products the cycle of the first volcanic period closed with the creation of very thick beds of pumice. The second volcanic period gave more petrological types with transitive forms. After the creation of olivinic — pyroxenic andesites followed the exit of trachyandesites, trachytic and dacitic lavas with final creation of rhyolite and of volcanic glasses. The extension of the mentioned rocks is noted in detail on the geological map. The classification of the exact geological age is difficult because there is no place where they come in contact with sediments. In general the researches think that the volcanity in the region of Dodecanese began during the middle or the end of the Miocene with successive explosions up to the young geological ages. Only on the islet Yiali which consists exclusively of acid lavas (pumice stones, rhyolite, perlite) fossiliferous layers of marly limestone, sandstone and konglomerate are found, as much at the sea level as in the top of the layers of pumice stone, of tyrrhenian age. The discovery of tools of obsidian in the layers of pumice stone is perhaps a sign that these explosions continued up to the Holocene period. Among the post volcanic phenomena are classified emanations, sulfur-genetic activity with the creation of sulfur deposits of the island and the presence of the thermal healing springs in many parts. Petrochemically the lavas of the island Nisyros and Yiali belong to calcium alkaline magmas.     

Trace element geochemistry of high alumina basalt - Andesite - Dacite - Rhyodacite lavas of the Main Volcanic Series of Santorini Volcano,Greece

Trace element systematics throughout the cal-calkaline high alumina basalt — basaltic andesite — andesite — dacite — rhyodacite lavas and dyke rocks of the Main Volcanic Series of Santorini volcano, Greece are consistent with the crystal fractionation of observed phenocryst phases from a parental basaltic magma as the dominant mechanism involved in generating the range of magmatic compositions. Marked inflection points in several variation trends correspond to changes in phenocryst mineralogy and divide the Main Series into two distinct crystallisation intervals — an early basalt to andesite stage characterised by calcic plagioclase+augite+olivine separation and a later andesite to rhyodacite stage generated by plagioclase augite+hypersthene+magnetite+apatite crystallisation. Percent solidification values derived from ratios of highly incompatible trace elements agree with previous values derived from major element data using addition-subtraction diagrams and indicate that basaltic andesites represent 47–69%; andesites 70–76%; dacites ca. 80% and rhyodacite ca. 84% crystallisation of the initial basalt magma. Least squares major element mixing calculations also confirm that crystal fractionation of the least fractionated basalts could generate derivative Main Series lavas, though the details of the least squares solutions differ significantly from those derived from highly incompatible element and addition-subtraction techniques. Main Series basalts may result from partial melting of the mantle asthenosphere wedge followed by limited olivine+pyroxene+Cr-spinel crystallisation on ascent through the sub-Aegean mantle and may fractionate to more evolved compositions at pressures close to the base of the Aegean crust. Residual andesitic to rhyodacite magmas may stagnate within the upper regions of the sialic Aegean crust and form relatively high level magma chambers beneath the southern volcanic centres of Santorini. The eruption of large volumes of basic lavas and silicic pyroclastics from Santorini may have a volcanological rather than petrological explanation.     

Tsunami hazard risk of a future volcanic eruption of Kolumbo submarine volcano,NE of Santorini Caldera,Greece

Kolumbo submarine volcano, located NE of Santorini caldera in the Aegean Sea, has only had one recorded eruption during historic times (1650 AD). Tsunamis from this event severely impacted the east coast of Santorini with extensive flooding and loss of buildings. Recent seismic studies in the area indicate a highly active region beneath Kolumbo suggesting the potential for future eruptive activity. Multibeam mapping and remotely operated vehicle explorations of Kolumbo have led to new insights into the eruptive processes of the 1650 AD eruption and improved assessments of the mechanisms by which tsunamis were generated and how they may be produced in future events. Principal mechanisms for tsunami generation at Kolumbo include shallow submarine explosions, entrance of pyroclastic flows into the sea, collapse of rapidly accumulated pyroclastic material, and intense eruption-related seismicity that may trigger submarine slope collapse. Compared with Santorini, the magnitude of explosive eruptions from Kolumbo is likely to be much smaller but the proximity of the volcano to the eastern coast of Santorini presents significant risks even for lower magnitude events.     

Arc dacite genesis pathways: Evidence from mafic enclaves and their hosts in Aegean lavas

Mafic enclaves are commonly found in intermediate arc magmas, and their occurrence has been linked to eruption triggering by pre-eruptive magma mixing processes. New major, trace, Sr–Nd and U–Th isotope data of rocks from Nisyros in the Aegean volcanic arc are presented here. Pre-caldera samples display major and trace element trends that are consistent with fractionation of magnetite and apatite within intermediate compositions, and zircon within felsic compositions, and preclude extensive hybridization between mafic and felsic magmas. In contrast, post-caldera dacites form a mixing trend towards their mafic enclaves. In terms of U-series isotopes, most samples show small ²³⁸U excesses of up to  10%. Mafic enclaves have significantly higher U/Th ratios than their dacitic host lavas, precluding simple models that relate the mafic and felsic magmas by fractionation or aging alone. A more complicated petrogenetic scenario is required. The post-caldera dacites are interpreted to represent material remobilized from a young igneous protolith following influx of fresh mafic magma, consistent with the U–Th data and with Sr–Nd isotope constraints that point to very limited (< 10%) assimilation of old crust at Nisyros. When these results are compared to data from Santorini in the same arc, there are many geochemical similarities between the two volcanic centers during the petrogenesis of the pre-caldera samples. However, striking differences are apparent for the post-caldera lavas: in Nisyros, dacites show geochemical and textural evidence for magma mixing and remobilization by influx of mafic melts, and they erupt as viscous lava domes; in Santorini, evidence for geochemical hybridization of dacites and mafic enclaves is weak, dacite petrogenesis does not involve protolith remobilization, and lavas erupt as less viscous flows. Despite these differences, it appears that mafic enclaves in intermediate Aegean arc magmas consistently yield timescales of at least 100 kyrs between U enrichment of the mantle wedge and eruption, on the upper end of those estimated for the eruptive products of mafic arc volcanoes. Finally, the data presented here provide constraints on the rates of differentiation from primitive arc basalts to dacites (less than  140 kyrs), and on the crustal residence time of evolved igneous protoliths prior to their remobilization by mafic arc magmas (greater than  350 kyrs).     

Normal faults associated with volcanic activity arc

Volcanic centers (volcanoes, fumaroles or solfatara fields), epicenters of strong shallow earthquakes (with focal depths up to 20 km) and epicenters of intermediate depth strong earthquakes (with focal depths between 120 and 160 km) in the southern Aegean volcanic arc can be grouped into five, well defined, linear clusters trending about N60°E. This lineation of shallow earthquakes and volcanic activity is attributed to five corresponding normal faults which are named after the five corresponding volcanic centers (Sousaki, Methana, Milos, Santorini and Nisyros). This is supported by a similar trend of the geomorphological features (grabens and islands) and of geophysical features (Bouguer anomalies), as well as by other seismological data (fault plane solutions and the origins of tsunamis) and geological information on the Santorini caldera. The greater volcanic activity in the eastern volcanic centers (Santorini and Nysiros) compared to the western volcanic centers (Sousaki, Methana and Milos) is attributed to the higher rate of extensional crustal deformation. In the eastern part of the volcanic arc it is 26 mm/yr: in the west it is 2 mm/yr. The delineation of the epicenters of the intermediate depth earthquakes along the same five lines indicates the existence of five corresponding rupture zones in the lower (leading) part of the descending lithospheric slab (at depths of 120–180 km). These deep zones are probably the sources of hot material which is ascending vertically upwards and intrudes into the crust along its fracture zones. The orientation of these zones explains the focusing of the macro-seismic results of these deep shocks at narrow regions of the sedimentary arc (Peloponnesus, Crete, etc).     

Post-caldera dacites from the Santorini volcanic complex,Aegean Sea,Greece: an example of the eruption of lavas of near-constant composition over a 2,200 year period

The post-caldera Kameni islands of the Santorini volcanic complex, Aegean Sea, Greece are entirely volcanic and were formed by eleven eruptions between 197 B.C. and 1950. Petrographic, mineral chemical and whole-rock major and trace element data are presented for samples of lava collected from the products of seven eruptive cycles which span the entire period of activity. The main phenocryst phases are plagioclase, clinopyroxene, orthopyroxene and titaniferous magnetite, which are weakly zoned (e.g. plagioclase — An₅₅ to An₄₂). The lavas are typical calc-alkaline dacites and show a restricted range of composition (from 64.1 to 68.4 wt. % SiO₂). The phenocrysts were in equilibrium with the melts at temperatures of 960–1012 °C, pressures of 800–1500 bars and oxygen fugacities of 10^–9.6-10^–9.9 bars. The pre-eruptive water content of the magmas was 3–4 wt. % but since the lavas contain only 0.1–0.4 wt. % H₂O, a considerable amount (about 0.01–0.015 km³) of water was lost prior to or during eruption. This indicates that the magmas rose to the surface gradually allowing the (largely) non-explosive loss of volatiles. The lavas were probably extruded initially from more or less cylindrical conduits which developed into fissures as the eruptions proceeded. The post-caldera lavas evolved from more mafic parental magmas (basalt-andesite) via fractional crystallization. The small range of compositional variation shown by these lavas can be explained in terms of near-equilibrium crystallization. Analyses of samples of lavas belonging to single eruption cycles and to individual flows indicate that the underlying magma chamber is compositionally zoned. The average composition of erupted magma has remained approximately constant since 1570 A.D. but that fact that the 197 B.C. magma was sligthly richer in SiO₂ provides additional evidence that the magma chamber is compositionally zoned. Crystal settling has not affected the composition of the magma over a 2,200 year period of time which indicates that the melts do not behave as Newtonian fluids. Zonation was thus probably established prior to the 197 B.C. eruption though it is possible that it is developed and maintained by crystal-liquid differentiation processes other than crystal settling (e.g. boundary layer crystallization). The data indicate that there has been no significant cooling during 2,200 years; the maximum amount of cooling is <50 °C and is probably less than 30 °C. Two hypotheses are considered to explain the thermal and chemical buffering of the post-caldera magma chamber: (i) The magma chamber is large and heat losses due to conduction are largely compensated by latent heat supplied by thick, partially crystalline cumulate sequences. (ii) Periodic influx of hot mafic magma, which does not mix with the dacitic magma, inhibits cooling. The second alternative is favored because the post-caldera lavas differ geochemically from the pre-caldera lavas which signifies that a new batch of magma was formed and/or emplaced after the catastrophic eruption of 1390 B.C., and hence that mafic magmas may still be reaching upper crustal levels.     

Volcanic ash and tsunami record of the Minoan Late Bronze Age Eruption (Santorini) in a distal setting,southwestern Turkey

We present the volcanic ash and tsunami record of the Minoan Late Bronze Age Eruption of Santorini (LBAES) in a distal setting in southwestern Turkey. In one of the drilled cores at the Letoon Hellenic antique site on Eşençay Delta, we encountered a 4 cm thick tephra deposit underlain by 46 cm thick tsunami-deposited sand (tsunamite), and an organic-rich layer that we ¹⁴C dated to 3295 ± 30 bp or 1633 bc. The relationship between Santorini distal volcanic ash and underlying tsunamite is described and interpreted. LBAES occurred in four main phases: (1) plinian; (2) phreatomagmatic; (3) phreatomagmatic with mudflows; and (4) ignimbritic flows and co-ignimbrite tephra falls. In this study, we aim to understand which eruptive phases generate distal ash during the Minoan eruptive sequence by examining the 3D surface morphology of ash formed by different fragmentation processes. To that end, we used numerous statistical multivariates, 3D fractal dimension of roughness, and a new textural parameter of surface area-3D/plotted area-2D to characterise the eruption dynamics. Based on ash surface morphologies and the calculated statistical parameters, we propose that that distal ash is represented by a single layer composed of well-mixed (coarse to fine) magmatic and phreatomagmatic ash.     

Precursors to the plinian eruptions of thera (late bronze age) and vesuvius (AD 79): Data from archaeological areas

Volcanological studies in the Bronze Age settlement of Akrotiri (Santorini, Greece) and in the Roman towns of Pompeii and Herculaneum (Vesuvius, Italy) provided information about the precursory phenomena preceding the Minoan and AD 79 plinian eruptions. Both the eruptions were characterised by seismic precursors with very different magnitudes and effects. The Minoan eruption was preceded by strong earthquake(s) that destroyed the Akrotiri settlement and forced an early evacuation of the island before the onset of the eruption. Instead, only some low magnitude shakings occurred before the AD 79 eruption of Vesuvius, which caught Roman towns and their inhabitants in the middle of their every-day life. Clear evidences of real volcanic precursors (both magmatic and phreatic) are not recorded in the deposits of the two eruptions. The onset of volcanic activity in both cases was represented by phreatomagmatic pulses of low energy shortly followed by the main eruption.     

Reconstruction of the paleo-coastline of Santorini island (Greece), after the 1613 BC volcanic eruption: A GIS-based quantitative methodology

A catastrophic volcanic explosion took place in Thera/Santorini island around 1613 BC, known as the ‘Minoan’ eruption. Many papers have dealt with the shape of the shoreline of the island before the eruption, but none with the shape of the shoreline exactly after it, assuming that it would be the same with the contemporary one. However, this is not correct due to the wave erosion. In this paper, a new DEM was constructed, covering both land and submarine morphology, then topographic sections were drawn around the island. Using these sections, the ‘missing parts’ (sea-wave erosion) were calculated, the shoreline was reconstructed as it was one day after the eruption and finally the erosion rate was calculated.     

Origin of post‐Minoan caves and volcaniclastic cave fill,Thera (Santorini), Greece

The Aegean island of Thera (Santorini) was covered by tephra from its cataclysmic Late Bronze Age (ca. 3600 yr B.P.) eruption. Vertical exposures of the eruptive sequence show secondary, nonvolcanic, circular (in cross section) features composed of stratified sediment. Many are inaccessible from the floors of modern quarries and appear to be caves filled with younger sediment, but show no connection to the land surface. A filled cave was found in the wall of a modern gully outside the modern quarries, and a filled cave was found in a terrace scarp, well above the modern gully. Natural (and probably rapid) incision by gullies into the thick tephra deposit left many locations with lateral access to tephra. Inhabitants from post‐Minoan to recent times excavated tephra for materials and buildings, and caves were subsequently filled by sporadic (possibly seasonal) flood events that deposited sediment. These gullies may have provided access for modern tephra removal that isolated the filled caves high on the modern quarry walls. © 2003 Wiley Periodicals, Inc.     

Eastern Mediterranean sea during the last glacial maximum; an 18,000-years B.P. reconstruction

An ecological transfer function based on the distribution of planktonic foraminifera in 66 Mediterranean and 8 North Atlantic surface-sediment samples is used to estimate sea-surface temperatures and salinities for the eastern Mediterranean during the last glacial maximum (18,000 yr B.P.). The present-day distribution of planktonic foraminifera can be explained by four faunal assemblages, each of which has diagnostic environmental preferences. Factor 1 is a tropical-subtropical assemblage; factor 2 is a transitional assemblage; factor 3 is a low-salinity assemblage; and factor 4 is a subpolar assemblage. The geographic distribution of these faunal assemblages reflect the variation in overlying hydrographic conditions. The 18,000-yr B.P. samples were selected based on total faunal stratigraphy, oxygen-isotope stratigraphy, and previously determined radiometric dates for eastern Mediterranean volcanic ash layers. Estimated temperature and salinity patterns show that the greatest change between present-day and 18,000-yr B.P. sea-surface conditions existed in the Aegean Sea and immediately south of Crete. The winter temperature anomaly (18,000 yr B.P.-present) within the Aegean Sea is 6°C cooler than present. In contrast to this, the maximum summer temperature anomaly exists to the south of Crete, where sea-surface temperatures were 4°C cooler than present. Estimated sea-surface salinities also show that the greatest change took place within the Aegean Sea, being 5‰ less saline than present. The estimated temperature and salinity patterns seem to reflect changing drainage patterns during glacial times and the diversion of cool, low-salinity water into the Aegean Sea. The source of this glacial runoff appears to be large freshwater lakes that existed during this time over parts of eastern Europe and western Siberia.     

Hydrothermal sedimentation in the caldera of Santorini, Hellenic Volcanic Arc

Sediments in the caldera of Santorini are receiving a hydrothermal input of iron and manganese from presently active hydrothermal vents off the Kameni Islands, and are enriched in these elements in their surface layer. However, greater Fe-Mn enrichments occur in discrete layers at depth in the cores separated from the surface by Fe-Mn poor sediments, suggesting that a past hydrothermal event may have been more intense than the present one. The buried Fe-Mn enriched layers occur above a turbidite thought to have resulted from sediment slumping due to a major volcanic eruption and earthquake in 1650, and are thought to have formed consequent on the activation of faults related to the magma chamber by the eruption facilitating seawater-rock interaction processes and the formation of metal-rich hydrothermal solutions.     

The petrologic evolution and pre-eruptive conditions of the rhyolitic Kos Plateau Tuff (Aegean arc)

The Kos Plateau Tuff is a large (>60 km³) and young (160 k.y.) calc-alkaline, high-SiO₂ rhyolitic ignimbrite from the active Kos-Nisyros volcanic center in the Aegean arc (Greece). Combined textural, petrological and geochemical information suggest that (1) the system evolved dominantly by crystal fractionation from (mostly unerupted) more mafic parents, (2) the magma chamber grew over ≥ 250 000 years at shallow depth (～1.5-2.5 kb) and was stored as a H₂O-rich crystalline mush close to its solidus (～670-750°C), (3) the eruption occurred after a reheating event triggered by the intrusion of hydrous mafic magma at the base of the rhyolitic mush. Rare banded pumices indicate that the mafic magma only mingled with a trivial portion of resident crystal-rich rhyolite; most of the mush was remobilized following partial melting of quartz and feldspars induced by advection of heat and volatiles from the underplated, hotter mafic influx.     

Climatic significance of D/H and13C/12C ratios in Irish oak cellulose

δD and δ¹³C analyses of cellulose nitrate from two modern Irish oak trees that form part of the 7400 year long chronology were carried out, covering a period of 123 years (1861–1983 A.D.) with a 5 year resolution so as to assess the potential of this long chronology for retrieval of palaeoenvironmental data. One of the trees (Q5293) showed significant correlations of δD, δ¹³ C and ring width with mean annual temperatures as recorded at the Armagh weather station nearby and the mean fall temperatures of Central England. The other tree (Q5296) did not exhibit any significant climatic correlations either because it grew utilizing a nearby permanent source of ground water or because the intra-ring isotopic variations in Irish oak are significant enough to mask the climatic signal. Whilst our results have given a positive indication of the usefulness of these trees for palaeoenvironmental information, more trees need to be analysed to confirm our findings. Even though one of the trees did not exhibit climatic correlations, both trees show a significant positive correlation of δ¹³C and a negative correlation of δD with ring width variations. Furthermore, two tree samples that grew during the 1620s B.C., when a volcano is thought to have erupted on the Aegean island of Santorini, show increased δD and decreased δ¹³C for one to two decades following the eruption, though the magnitudes of change seem to vary with site and trees. We have proposed a possible mechanism based on tree phenology to explain both the above effects.     

Volcaniclastic resedimentation in distal fluvial basins induced by large-volume explosive volcanism: the Ebisutoge–Fukuda tephra, Plio-Pleistocene boundary, central Japan

The Ebisutoge–Fukuda tephra (Plio‐Pleistocene boundary, central Japan) has a well‐recorded eruptive style, history, magnitude and resedimentation styles, despite the absence of a correlative volcanic edifice. This tephra was ejected by an extremely large‐magnitude and complex volcanic eruption producing more than 400 km³ total volume of volcanic materials (volcanic explosivity index=7), which extended more than 300 km away from the probable eruption centre. Remobilization of these ejecta occurred progressively after the completion of a series of eruptions, resulting in thick resedimented volcaniclastic deposits in spatially separated fluvial basins, more than 100 km from the source. Facies analysis of resedimented volcaniclastic deposits was carried out in distal fluvial basins. The distal tephra (≈100–300 km from the source) comprises two different lithofacies, primary pyroclastic‐fall deposits and reworked volcaniclastic deposits. The resedimented volcaniclastic succession shows five distinct sedimentary facies, interpreted as debris‐flow deposits (facies A), hyperconcentrated flow deposits (facies B), channel‐fill deposits (facies C), floodplain deposits with abundant flood‐flow deposits (facies D) and floodplain deposits with rare flood deposits (facies E). Resedimented volcaniclastic materials at distal locations originated from unconsolidated deposits of a climactic, large ignimbrite‐forming eruption. Factors controlling inter‐ and intrabasinal facies changes are (1) temporal change of introduced volcaniclastic materials into the basin; (2) proximal–distal relationship; and (3) distribution pattern of pyroclastic‐flow deposits relative to drainage basins. Thus, studies of the Ebisutoge–Fukuda tephra have led to a depositional model of volcaniclastic resedimentation in distal areas after extremely large‐magnitude eruptions, an aspect of volcaniclastic deposits that has often been ignored or poorly understood.     

内蒙古达里诺尔晚新生代火山群喷发特征研究

达里诺尔火山群有近百座晚新生代单成因火山,其地质地貌形态各异,喷发形式多样。这些火山既有爆破式喷发,如:夏威夷式喷发,斯通博利式喷发,强斯通博利式喷发和射汽岩浆喷发;也有溢流式喷发,如盾状火山;还有岩浆缓慢侵出,如大黑山。火山群内典型火山机构表明,不同的喷发方式穿插于火山喷发过程:早期火山活动多以侵出和溢流为主,逐渐转变为岩浆爆破式喷发(强斯通博利式,斯通博利式),晚期又过渡为溢流式喷发,喷发过程大体经历一个爆破强度弱-强-弱的转变。射汽岩浆型的火山则是以剧烈的射汽岩浆爆炸开始,后期逐渐转弱为岩浆爆破喷发和溢流喷发。火山喷发过程中火山产物出现牛顿流体,宾汉流体,层流,颗粒流,涌流,空降等不同类型的运动形式,自火口向远源运动,形成差异化的火山产物。岩浆的输送速率、上升速度,以及围岩的类型,可能是造成达里诺尔火山群多样化喷发的主要因素。     

The influence of volcanism on paleoclimate in the northeast of China： Insights from Jinchuan peat, Jilin Province, China

Just like contemporary sediments, peat itself is a good repository of information about climate change, the effects of volcanic activity on climate change have been truly recorded in peat, since it is a major archive of volcanic eruption incidents. A section of sand was identified as tephra from the Jinchuan peat, Jilin Province, China, for the grains look like slag with surface bubbles and pits, characterized by high porosity, and loose structure with irregular edges and corners. According to the peat characteristics of uniform deposition, the tephra was dated at 2002–1976 a B.P. by way of linear interpolation, so the time of volcanic eruption was 15 B.C.–26 A.D. (the calibrated age). While the geochemical characteristics of tephra in this study are quite the same as those of tephra from the Jinlongdingzi volcano at Longgang and from alkaline basaltic magma, with the contents of SiO₂<55%, and the similar contents to Al₂O₃ and Fe, but the contents of Na₂O>K₂O. We speculated that the tephra in this study came from the Longgang volcano group. Compared with 11 recorded volcanic eruption events as shown on the carbon and oxygen isotope curves of the Jinchuan peat cellulose, it is obviously seen that adjacent or large-scale volcanic eruptions are precisely corresponding to the minimum temperature and humidity. It seems that these volcanic eruptions indeed affected the local climate, leading to the drop of regional temperature and humidity. As a result, there was prevailing a cold and dry climate there, and all these changes can be well recorded in peat. So the comparison of volcanic eruption events with information about climate change developed from peat, can provide strong evidence for the impact of volcanism on climate change.     

Neutron activation analysis of Mediterranean volcanic rocks – An analytical database for archaeological stratigraphy

Pumice has been used as a serviceable abrasive or religious artifact since antiquity and has therefore been an object of trade. By analyzing pumice samples from archaeological excavations and comparing the results to an analytical database, it is possible to establish the origin of the sample and thereby get information on the maximum age and the transport route of the pumice sample. In addition, the deposition of primary tephra deposits can be used as time markers, and place constraints on the ages of archaeological materials.Neutron activation analysis (NAA) was applied to determine the concentrations of 25 elements (As, Ba, Ce, Co, Cr, Cs, Eu, Fe, Hf, K, La, Lu, Na, Nd, Rb, Sb, Sc, Sm, Ta, Tb, Th, U, Yb, Zn and Zr) in pumice samples from the Mediterranean region: Milos, Santorini, Kos, Giali and Nisyros (Greece), Lipari (Italy) and Cappadokia (Turkey). It was found that eruption products like pumice or volcanic ash can be correlated in many cases to their volcanic sources by comparison of the typical main- and trace-elemental concentration patterns (“chemical fingerprint”). Such a distinction is possible if the volcanic rocks are homogenous enough with respect to the concentrations of geochemically relevant elements. Using only the pure glass fraction of tephra, a sample size of 5 mg is sufficient for identification by NAA.     

火山玻璃风化层的透射电镜研究

利用透射电镜(TEM)和X射线能谱(EDX)研究了长白山天池火山1000年和4000年前两次大喷发产生的火山玻璃风化层特征.TEM分析显示,4000年前大喷发浮岩中的火山玻璃风化层平均厚度3.7 mm,1000年前大喷发浮岩中的火山玻璃风化层平均厚度为1.0 mm.EDX分析显示,两次大喷发浮岩中的火山玻璃风化层化学组成与火山玻璃相比富Al、Fe,而si减少.火山玻璃风化层富Al发生在Al的浓度较高的中到弱酸溶液中(pH=5～6),火山玻璃表面形成含有少量的非晶质的Al、Si、Fe物质,这些非品质的次生物质是火山玻璃风化早期阶段形成的.天池火山喷发物中火山玻璃的微观特征的差异可能与火山喷发年代和喷发后的环境有关,研究天池火山不同期次喷发物中火山玻璃的微观特征具有一定的理论和实际应用价值.     

First evidence of a distal early Holocene ash layer in Eastern Mediterranean deep-sea sediments derived from the Anatolian volcanic province

A hitherto unknown distal volcanic ash layer has been detected in a sediment core recovered from the southeastern Levantine Sea (Eastern Mediterranean Sea). Radiometric, stratigraphic and sedimentological data show that the tephra, here termed as S1 tephra, was deposited between 8970 and 8690 cal yr BP. The high-silica rhyolitic composition excludes an origin from any known eruptions of the Italian, Aegean or Arabian volcanic provinces but suggests a prevailing Central Anatolian provenance. We compare the S1 tephra with proximal to medial-distal tephra deposits from well-known Mediterranean ash layers and ash fall deposits from the Central Anatolian volcanic field using electron probe microanalyses on volcanic glass shards and morphological analyses on ash particles. We postulate a correlation with the Early Holocene ‘Dikkart?n’ dome eruption of Erciyes Da? volcano (Cappadocia, Turkey). So far, no tephra of the Central Anatolian volcanic province has been detected in marine sediment archives in the Eastern Mediterranean region. The occurrence of the S1 tephra in the south-eastern part of the Levantine Sea indicates a wide dispersal of pyroclastic material from Erciyes Da? more than 600 km to the south and is therefore an important tephrostratigraphical marker in sediments of the easternmost Mediterranean Sea and the adjacent hinterland.