古今湿热气候条件下典型碳酸盐岩缝洞系统结构模式及发育特征

碳酸盐岩地层在湿热气候条件下可形成典型的裂缝-溶洞系统。塔里木盆地奥陶系碳酸盐岩存在3大构造隆起,与上覆志留系、石炭系地层存在沉积间断,具备了岩溶缝洞形成的基础条件;在泥盆纪、志留纪时塔里木古陆位于低纬度地区,具有与现代中国南方相似的热带、亚热带湿热海洋性气候条件,岩溶作用强烈,为大型岩溶缝洞储层的形成提供了水热条件。为了更好地揭示塔河油田岩溶缝洞储层的发育和分布规律,文章基于对塔北露头区古岩溶的调查分析,结合地震、岩心、测井等资料,并与我国西南岩溶区现代岩溶研究成果相比较,总结了古今湿热气候条件下典型碳酸盐岩缝洞系统的空间结构和发育特征,将其划分为地下河、岩溶洞穴、溶蚀孔洞、溶蚀缝等4种缝洞类型,地下河又细分为单支管道、多支管道、廊道型管道3个亚类,洞穴细分为厅堂型、溶洞型和竖井型洞穴3个亚类,分别建立了这些缝洞类型的地质结构模式,并对其发育特征和地球物理响应特征进行了归纳,为深入认识岩溶缝洞储层油气富集规律和油田地质建模提供科学依据。      

Mountain glaciers under a changing climate

Mountain glaciers are found around the world in ranges such as the Himalaya, the Andes and the European Alps. The majority of mountain glaciers world‐wide are shrinking. However, the rugged alpine topography through which these glaciers flow governs their dynamics and impacts on the regional climate systems that modify glacier mass balance. As a result, the response of mountain glaciers to climate change is difficult to predict, and highly spatially variable even across one mountain range, particularly where orography controls precipitation distributions. To understand how mountain glaciers behave and change, geologists combine many different techniques based on direct observations and dating of glacial geology, measurements of present‐day glaciers, and predictive numerical (computer) models. Recent advances in these techniques and their applications to glacial environments have demonstrated that the glacial geological record is a rich archive of information about how climate has changed in the past, and gives greater confidence in predictions of glacier change in the future, which is required if populations living in glacerised catchments are able to adapt to the rapid response of glaciers to a changing climate.     

Physical and biological controls on the formation of carbonate and siliciclastic bedforms on the north-east Brazilian shelf

The continental shelf of the State of Rio Grande do Norte, Brazil, is an open shelf area located 5°S and 35°W. It is influenced by strong oceanic and wind-driven currents, fair weather, 1·5-m-high waves and a mesotidal regime. This work focuses on the character and the controls on the development of suites of carbonate and siliciclastic bedforms, based on Landsat TM image analysis and extensive ground-truth (diving) investigations. Large-scale bedforms consist of: (i) bioclastic (mainly coralline algae and Halimeda) sand ribbons (5–10 km long, 50–600 m wide) parallel to the shoreline; and (ii) very large transverse siliciclastic dunes (3·4 km long on average, 840 m spacing and 3–8 m high), with troughs that grade rapidly into carbonate sands and gravels. Wave ripples are superposed on all large-scale bedforms, and indicate an onshore shelf sediment transport normal to the main sediment transport direction. The occurrence of these large-scale bedforms is primarily determined by the north-westerly flowing residual oceanic and tidal currents, resulting mainly in coast-parallel transport. Models of shelf bedform formation predict sand ribbons to occur in higher energy settings rather than in large dunes. However, in the study area, sand ribbons occur in an area of coarse, low-density and easily transportable bioclastic sands and gravels compared with the very large transverse dunes in an offshore area that is composed of denser medium-grained siliciclastic sands. It suggests that the availability of different sediment types is likely to exert an influence on the nature of the bedforms generated. The offshore sand supply is time limited and originates from sea floor erosion of sandstones of former sea-level lowstands. The trough areas of both sand ribbons and very large transverse dunes comprise coarse calcareous algal gravels that support benthic communities of variable maturity. Diverse mature communities result in sediment stabilization through branching algal growth and binding that is thought to modify the morphology of dunes and sand ribbons. The occurrence and the nature of the bedforms is controlled by their hydrodynamic setting, by grain composition that reflects the geological history of the area and by the carbonate-producing benthic marine communities that inhabit the trough areas.     

Reservoir operation using system dynamics under climate change impacts: a case study of Yamchi reservoir,Iran

This paper proposes a decision support system for Yamchi reservoir operation in semi-arid region of Iran. The paper consists of the following steps: Firstly, the potential impacts of climate change on the streamflow are predicted. The study then presents the projections of future changes in temperature and precipitation under A2 scenario using the LARS-WG downscaling model and under RCP2.6, RCP4.5, and RCP8.5 using the statistical downscaling model (SDSM) in the northwestern of Iran. To do so, a general circulation model of HadCM3 is downscaled by using the LARS-WG model. As a result, the average temperature, for the horizon 2030 (2011–2030), will increase by 0.77 °C and precipitation will decrease by 11 mm. Secondly, the downscaled variables are used as input to the artificial neural network to investigate the possible impact of climate change on the runoffs. Thirdly, the system dynamics model is employed to model different scenarios for reservoir operation using the Vensim software. System dynamics is an effective approach for understanding the behavior of complex systems. Simulation results demonstrate that the water shortage in different sectors (including agriculture, domestic, industry, and environmental users) will be enormously increased in the case of business-as-usual strategy. In this research, by providing innovative management strategies, including deficit irrigation, the vulnerability of reservoir operation is reduced. The methodology is evaluated by using different modeling tests which then motivates using the methodology for other arid/semi-arid regions.     

Facies, cycles, and controls on the evolution of a keep-up carbonate platform (Kimmeridgian, Swiss Jura)

During the Late Jurassic, accelerated ocean-floor spreading and associated sea-level rise were responsible for a worldwide transgression, which reached its maximum in the Late Kimmeridgian. In many Western European basins, this major sea-level rise led to the formation of marly and condensed sections. In the Swiss Jura, however, a shallow carbonate platform kept growing and only subtle changes in the stratigraphic record suggest an increasingly open-marine influence. Field observations and thin-section analyses reveal that the central Swiss Jura was at that time occupied by tidal flats and by more or less open marine lagoons where shoals and bioherms developed. The evolution through time of sedimentary facies and bed thicknesses permits the definition of small-, medium-, and large-scale depositional sequences. The diagnostic features of these sequences are independent of scale and seem largely controlled by the Kimmeridgian second-order transgression. A high-resolution sequence-stratigraphic correlation with biostratigraphically well-dated hemipelagic and pelagic sections in the Vocontian Basin in France reveals that: (i) The most important increase in accommodation recorded in the Kimmeridgian of the central Swiss Jura occurs in the Eudoxus ammonite zone (Late Kimmeridgian) and corresponds to the second-order maximum flooding recognized in many sedimentary basins. (ii) The small- and medium-scale sequences have time durations corresponding to the first and second orbital eccentricity cycle (i.e. 100 and 400 ka, respectively), suggesting that sedimentation on the platform and in the basin was at least partly controlled by cyclic environmental changes induced by insolation variations in the Milankovitch frequency band. The comparison of the high-resolution temporal framework defined in the Swiss Jura and Vocontian Basin with the sequence-stratigraphic interpretation realized in other Western European basins shows that the large-scale sequence boundaries defined in the Kimmeridgian of the Swiss Jura appear in comparable biostratigraphic positions in most Western European basins. Discrepancies that occur are probably because of local or regional tectonics.     

A comparative study of four vulnerability mapping methods in a detritic aquifer under mediterranean climatic conditions

This paper presents the results of a comparative study relating to the application of four vulnerability mapping methods, GOD, AVI, DRASTIC and SINTACS, in a pilot detritic aquifer situated in NW Morocco, known as the Martil–Alila aquifer. The principal objective of this work is to determine the most suitable such methods for this aquifer type within a Mediterranean context, and to show the effect of the rainfall variations that are characteristic of the Mediterranean climate on the degree of vulnerability. The methods applied distinguish five classes of vulnerability, these being irregularly divided up in space, with the division varying according to the method in question. The vulnerability maps obtained by the different methods strongly suggest that the eastern half of the aquifer is more vulnerable to contamination than the western half, for all hydrological situations. The effect of climatic conditions on the degree of vulnerability is well represented by the DRASTIC, according to which the aquifer is moderately to strongly vulnerable during humid hydrological years and weakly to moderately vulnerable during dry ones. For the other methods, this climatic effect is limited to the area occupied by the two predominant classes (“High” and “Low” for GOD and “High” and “Moderate” for SINTACS) while it is null for AVI. In conclusion, DRASTIC appears the most suitable for mapping the vulnerability to contamination of Mediterranean coastal detritic aquifers such as the Martil–Alila aquifer.     

Reconstruction of the Holocene climate based on a carbonate sedimentary record from shallow saline Lake Verkhnee Beloe (western Transbaikalia)

We present results of mineralogical and crystallochemical studies of the Holocene carbonate sediments of a small saline lake localized in the Borgoi dry-steppe region, western Transbaikalia. Mg-calcites with a varying Mg content are predominant in the assemblage of endogenic carbonate minerals from bottom sediments. Mathematical modeling of the XRD spectra of carbonates permitted us to identify excess-Ca dolomites, which are an indicator of a shallow (playa) lake. The studies showed that the lacustrine Mg-calcites do not form a continuous series from low- to high-Mg varieties. We discuss the cause of this phenomenon and also consider the existing viewpoints of the structure of low-temperature Mg-calcites and excess-Ca dolomites and their formation conditions in lacustrine sediments. Juxtaposing the carbonate record with the data of lithological analysis, determined stable isotopes (δ¹⁸O and δ¹³C), and distribution of some geochemical indicators of climatic changes, we reconstructed the intricate evolution of Lake Verkhnee Beloe, which was controlled by the regional climate since the postglacial period till the present day.     

Abiotic versus biotic controls on the development of the Fairmont Hot Springs carbonate deposit, British Columbia, Canada

The relict Fairmont Hot Springs deposit, formed largely of carbonates, covers an area of 0·5 km², and is up to 16 m thick. The triangle‐shaped discharge apron, which broadens down‐valley, is divided into a proximal part with beds dipping at <10° and a distal part with beds dipping at 10° to 15°. The deposit is formed of the: (1) Basal Macrophyte; (2) Lower Carbonate; (3) Middle Clastic; (4) Upper Carbonate; and (5) Upper Clastic Sequences. Two charcoal samples embedded in the Lower Carbonate Sequence yielded dates of 8690 ± 90 and 8270 ± 70 cal yr bp , indicating that much of the deposit formed post‐glacially during the Early to Mid‐Holocene. Deposit aggradation ceased in the Mid to Late Holocene when the Fairmont Creek valley was incised. The Lower and Upper Carbonate Sequences, which are the thickest sequences, are composed of nearly equal parts of travertine (abiotic) and tufa (biotic), with feather dendrite travertine, radiating dendrite travertine and stromatolite tufa dominating. Competition between calcite precipitation rates and biotic growth rates controlled the distribution of tufa and travertine across the discharge apron. Calcite and biotic growth rates were controlled largely by flow velocity across the apron which, in turn, was controlled by topography and regular fluctuations in spring water discharge volume. During times of high spring discharge, slow sheet flow over the proximal part of the apron promoted stromatolite growth, whereas fast, turbulent flow on the distal part of the apron induced rapid feather dendrite formation. During times of low spring discharge, quiescent, shallow evaporative pools, conducive to radiating dendrite formation, formed on the proximal part of the apron, whereas slow flow on the distal part promoted stromatolite growth. Facies with high calcite supersaturation experienced rapid abiotic dendrite growth that precluded most biotic growth.     

Chemical dynamics and weathering rates of a carbonate basin Bow River,southern Alberta

Discharge is the dominant control on the TDS load of the Bow River; TDS varies inversely with discharge. Although discharge is the dominant control on concentration, the sources of ions in the river are atmospheric deposition and water/rock interaction. Atmospheric loading can be a significant source of some ions in the pristine headwaters of the river (e.g., 50% of K, 17% of SO₄, 16% of Cl). In terms of water/rock interaction, the input of ions to the river is largely controlled by dissolution of carbonate and evaporite minerals.The chemical denudation rate for the Bow River at Banff is 678 kg/ha/a, or 1.50×10⁸ kg of rock that is removed as dissolved load each year, in the low range for an alpine carbonate basin. An additional 11 kg/ha/a are removed as suspended load. A rock volume of 5.45×10⁴ m³ is carried by the Bow River from Banff National Park each year.     

Morphological methods and dynamic modelling in landslide hazard assessment of the Campania Apennine carbonate slope

Landslide risk of the Campanian carbonate slopes covered by pyroclastic deposits is mainly connected with the occurrence of high-velocity debris avalanches and debris flows. Analyses show that flows initiate as small translational slides in the pyroclastics. The failure process is controlled by the interaction of both natural and human-induced factors. Geomorphological settings play a decisive role in locating the source failures. Therefore, the crucial aspects in landslide hazard and risk assessment are: (a) recognise the geomorphological control factors, (b) determine parameters defining landslide intensity (velocity, volume, depth of deposit) and (c) predict landslide runout distance. An approach combining geomorphology and numerical analysis has been adopted in the work reported here. Potential future landslide intensity scenarios are simulated predicting the runout behaviour of potential instabilities by using a dynamic model previously calibrated by back-analysing observed events of similar scale and type. The selected area is a sector of the Avella Mountains having the same geomorphological environment as the 1998 Sarno landslides (Campania, Southern Italy).     

Pioneering assessment of carbon stocks in polder soils developed in inter-dune landscapes in a semiarid climate,Lake Chad

In semiarid Sahelian region, the dynamics of soil organic carbon (SOC) and water are key to sustainable land management. This work focuses on the behaviour of carbon. A total of 33 soil profiles in four polders, ranging from 10 to 65 years in age, were sampled, analysed (0–1 m), and matched with marsh soil profiles in recent sediments considered as reference (t₀) for carbon stocks determination. SOC and soil inorganic carbon (SIC) stocks show a spatial variability between polders. SOC stocks were t₀ 200 ± 0.8; t₆₀ 183 ± 34; and t₆₅ 189 ± 1.1 MgC·ha^?1, whereas the SIC stocks were negligible. These results show the highest stocks of soil carbon observed for this climatic region. The SOC stocks were also calculated for the equivalent soil mass at a defined depth (0–0.3 m); the corrected calculation of SOC stocks (S_corr) for 2450 Mg·ha^?1 of equivalent soil mass is t₀ 64 ± 1.9, t₆₀ 59 ± 9.8, and t₆₅ 53 ± 2.2 MgC·ha^?1; the stocks decrease by ?7.8% and ?17.2% from t₀ to t₆₀ and t₆₅. Carbon was inherited from the pre-existing·marsh and the polders have conserved high stock values.     

Environmental controls on the Late Holocene carbonate sedimentation of a karstic lake in the Middle‐Atlas Mountains (Lake Afourgagh,Morocco)

The Lake Afourgagh sediment record and facies successions provide an outstanding example of environmentally controlled carbonate sedimentation. Afourgagh is a small, shallow permanent lake located in the Middle‐Atlas Mountains in Morocco in a karstic context. It is fed by ground waters that are relatively enriched in Mg resulting from the leaching of the Jurassic dolomitic bedrock of the catchment. This eutrophic lake is episodically restricted and characterized by alkaline waters with a fluctuating high Mg/Ca ratio. The maximum extension of the Holocene shoreline coincides with evidence of a lake stabilization level corresponding to the outflow of the lake through a wadi. Lakeshore terrace sediments deposited on an alluvial fan siltstone during the past ca 2500 cal yr bp comprise four main facies: a littoral crust, palaeosols, palustrine silts and charophyte tufas, which reflect different environments from the shoreline toward the deeper water. In the more distal parts, the charophyte tufas display a well‐expressed lamination punctuated by the development of microstromatolites on algae thalli. The mineralogical composition of the carbonates is linked to the facies. While the charophyte tufas are characterized by a relatively high content in aragonite, in addition to low‐Mg calcite, the littoral crust is mainly composed of magnesite. This pattern is related to the evolving chemistry of water due to the influence of charophyte proliferation during dry summers. Calcium‐carbonate precipitation on algae thalli (both bioinduced and microbially mediated) progressively induces an increase in the Mg/Ca ratio of the lake water, while the capillary evaporation of shallow ground waters causes precipitation of a magnesite precursor on the shoreline, producing magnesite during early diagenesis. This effect is characteristic of two episodes: part of the Roman Warm Period and the beginning of the Dark Age Cold Period. The carbonate mineralogy of the different depositional sequences at Afourgagh indicates lake‐level and water‐chemistry fluctuations under a climatic influence. Therefore, among other regional records, the Lake Afourgagh sedimentary record provides useful evidence for reconstructing these environmental changes.     

Climate and material controls on periglacial soil processes: Toward improving periglacial climate indicators

One of the distinguished efforts of A.L. Washburn was to reconstruct mean annual air temperature using periglacial features as climate indicators. This paper reviews existing periglacial indicators and proposes a strategy to improve their thermal resolution based on recent periglacial process studies, with a focus on solifluction and thermal contraction cracking and associated landforms/structures. Landforms resulting from solifluction reflect both the depth subjected to freeze-thaw and the thickness of frost-susceptible soils. The thickness of a solifluction structure can be used to infer the dominant freeze-thaw regime and minimum seasonal frost depth. Ice-wedge pseudomorphs have limited potential as a climate indicator because (1) they mainly reflect extreme winter temperatures, (2) their thermal thresholds depend on the host material, and (3) they need to be distinguished from frost wedges of other origin produced under different thermal and/or material conditions. Monitoring studies of currently active ice wedges suggest that ice-wedge cracking requires a combination of low temperature and large temperature gradients in the frozen active layer. Further field monitoring of periglacial processes and their controlling factors under various climate conditions and in various materials are needed, however, to improve the resolution of periglacial paleoclimate indicators.     

Benthic dynamics at the carbonate mound regions of the Porcupine Sea Bight continental margin

A brief review is given of some dynamical processes that influence the benthic dynamics within the carbonate mound provinces located at the Porcupine Bank/Sea Bight margin, NE Atlantic. The depth range of the mounds in this region (600–1,000 m) marks the upper boundary of the Mediterranean outflow water above which Eastern North Atlantic Water dominates. Both water masses are carried northwards by the eastern boundary slope current. In the benthic boundary layer both the action of internal waves, and other tidal period baroclinic waves, may enhance the bottom currents and add to both the residual and maximum flow strength. Both residual and maximum bottom currents vary at different mound locations, with stronger currents found at Belgica (SE Porcupine Sea Bight) mound and Pelagia (NW Porcupine Bank) mound regions, whilst weakest currents are found at the Hovland and Magellan Mounds at the northern Sea Bight margin. The differences may be attributed to the presence of internal waves (Pelagia) or bottom intensified diurnal waves (Belgica). These different dynamical regimes are likely to have implications for the distribution patterns of live coral at the different locations.     

Tectonic, eustatic and environmental controls on mid-Cretaceous carbonate platform deposition, south-central Pyrenees, Spain

Cenomanian–Turonian strata of the south‐central Pyrenees in northern Spain contain three prograding carbonate sequences that record interactions among tectonics, sea level, environment and sediment fabric in controlling sequence development. Sequence UK‐1 (Lower to Upper Cenomanian) contains distinct lagoonal, back‐margin, margin, slope and basin facies, and was deposited on a broad, flat shelf adjacent to a deep basin. The lack of reef‐constructing organisms resulted in a gently dipping ramp morphology for the margin and slope. Sequence UK‐2 (Upper Cenomanian) contains similar shallow‐water facies belts, but syndepositional tectonic modification of the margin resulted in a steep slope and deposition of carbonate megabreccias. Sequence UK‐3 (Lower to Middle Turonian) records a shift from benthic to pelagic deposition, as the shallow platform was drowned in response to a eustatic sea‐level rise, coupled with increased organic productivity. Sequences UK‐1 to UK‐3 are subdivided into lowstand, transgressive and highstand systems tracts based on stratal geometries and facies distribution patterns. The same lithologies (e.g. megabreccias) commonly occur in more than one systems tract, indicating that: (1) the depositional system responded to more than just sea‐level fluctuations; and (2) similar processes occurred during different times throughout sequence development. These sequences illustrate the complexity of carbonate platform dynamics that influence sequence architecture. Rift tectonics and flexural subsidence played a major role in controlling the location of the platform margin, maintaining a steep slope gradient through syndepositional faulting, enhancing slope instability and erosion, and influencing depositional processes, stratal relationships and lithofacies distribution on the slope. Sea‐level variations (eustatic and relative) strongly influenced the timing of sequence and parasequence boundary formation, controlled changes in accommodation and promoted platform drowning (in conjunction with other factors). Physico‐chemical and climatic conditions were responsible for reducing carbonate production rates and inducing platform drowning. Finally, a mud‐rich sediment fabric affected platform morphology, growth geometries (aggradation vs. progradation) and facies distribution patterns.     

Oceanographic controls on shallow‐water temperate carbonate sedimentation: Spencer Gulf,South Australia

Spencer Gulf is a large (ca 22 000 km²), shallow (<60 m water depth) embayment with active heterozoan carbonate sedimentation. Gulf waters are metahaline (salinities 39 to 47‰) and warm‐temperate (ca 12 to ?28°C) with inverse estuarine circulation. The integrated approach of facies analysis paired with high‐resolution, monthly oceanographic data sets is used to pinpoint controls on sedimentation patterns with more confidence than heretofore possible for temperate systems. Biofragments – mainly bivalves, benthic foraminifera, bryozoans, coralline algae and echinoids – accumulate in five benthic environments: luxuriant seagrass meadows, patchy seagrass sand flats, rhodolith pavements, open gravel/sand plains and muddy seafloors. The biotic diversity of Spencer Gulf is remarkably high, considering the elevated seawater salinities. Echinoids and coralline algae (traditionally considered stenohaline organisms) are ubiquitous. Euphotic zone depth is interpreted as the primary control on environmental distribution, whereas seawater salinity, temperature, hydrodynamics and nutrient availability are viewed as secondary controls. Luxuriant seagrass meadows with carbonate muddy sands dominate brightly lit seafloors where waters have relatively low nutrient concentrations (ca 0 to 1 mg Chl‐a m^?3). Low‐diversity bivalve‐dominated deposits occur in meadows with highest seawater salinities and temperatures (43 to 47‰, up to 28°C). Patchy seagrass sand flats cover less‐illuminated seafloors. Open gravel/sand plains contain coarse bivalve–bryozoan sediments, interpreted as subphotic deposits, in waters with near normal marine salinities and moderate trophic resources (0·5 to 1·6 mg Chl‐a m^?3) to support diverse suspension feeders. Rhodolith pavements (coralline algal gravels) form where seagrass growth is arrested, either because of decreased water clarity due to elevated nutrients and associated phytoplankton growth (0·6 to 2 mg Chl‐a m^?3), or bottom waters that are too energetic for seagrasses (currents up to 2 m sec^?1). Muddy seafloors occur in low‐energy areas below the euphotic zone. The relationships between oceanographic influences and depositional patterns outlined in Spencer Gulf are valuable for environmental interpretations of other recent and ancient (particularly Neogene) high‐salinity and temperate carbonate systems worldwide.     

The partitioning of Fe and Mg between olivine and carbonate and the stability of carbonate under mantle conditions

We have investigated the effect of Fe on the stabilities of carbonate (carb) in lherzolite assemblages by determining the partitioning of Fe and Mg between silicate (olivine; ol) and carbonates (magnesite, dolomite, magnesian calcite) at high pressures and temperatures. Fe enters olivine preferentially relative to magnesite and ordered dolomite, but Fe and Mg partition almost equally between disordered calcic carbonate and olivine. Measurement of K _d (X _Fe ^carb X _Mg ^ol /X _Fe ^ol X _Mg ^carb ) as a function of Fe/ Mg ratio indicates that Fe–Mg carbonates deviate only slightly from ideality. Using the regular solution parameter for olivine W _FeMg ^ol of 3.7±0.8 kJ/mol (Wiser and Wood 1991) we obtain for (FeMg)CO₃ a W _FeMg ^carb of 3.05±1.50 kJ/mol. The effect of Ca–Mg–Fe disordering is to raise K _d substantially enabling us to calculate W _CaMg ^carb -W _CaFe ^carb of 5.3±2.2 kJ/mol. The activity-composition relationships and partitioning data have been used to calculate the effect of Fe/Mg ratio on mantle decarbonation and exchange reactions. We find that carbonate (dolomite and magnesian calcite) is stable to slightly lower pressures (by 1 kbar) in mantle lherzolitic assemblages than in the CaO–MgO–SiO₂(CMS)–CO₂ system. The high pressure breakdown of dolomite + orthopyroxene to magnesite + clinopyroxene is displaced to higher pressures (by 2 kbar) in natural compositions relative to CMS. CO₂. We also find a stability field of magnesian calcite in lherzolite at 15–25 kbar and 750–1000°C.     

多组分有机质作用下碳酸钙的矿化现象

采用SEM、XRD、FT-IR等手段对氨基酸、多糖以及有机酸混合体系中形成的碳酸钙晶体进行了表征,进而比较了多组分有机质作用下碳酸钙的矿化现象。结果表明,氨基酸-单糖体系(A-M)促进了碳酸钙的沉积,其钙化速率相较于对照组提高了36%;有机酸则抑制了碳酸钙的沉积,单糖-有机酸体系(M-O)、氨基酸-有机酸体系(A-O)和氨基酸-有机酸-单糖体系(A-O-M)的钙化速率分别下降了33%、29%、17%。其次,A-M体系合成的晶体以方解石为主,包含少量的球霰石,M-O、A-O和A-O-M体系则在柠檬酸的调控下合成了方解石。最后,A-M体系合成了块状晶体(粒径为10μm)及中空的环状晶体(粒径为5μm),而A-O和M-O体系合成了棒状晶体(长轴径5～15μm,短轴径3～5μm)。A-O-M体系存在含量最高的有机质,导致成核速率高于生长速率,因此合成的晶体呈粒状(粒径1～3μm)且发育不完整。研究揭示了多组分共存体系中的生物矿化现象,阐明了柠檬酸在多组分体系中对晶体成核及生长的主导调控作用,对研究黄龙高寒环境下的生物矿化机制具有重要意义。     

Environmental controls on the development of Mississippian microbial carbonate mounds and platform limestones in southern Montagne Noire (France)

Late Mississippian carbonates in southern Montagne Noire are dominantly domical to laterally‐accreted microbial mounds in some formations, as well as stratiform microbial limestones occurring in hundreds of olistoliths within a flysch basin, constituting pieces of a giant puzzle that are used to help reconstruct a platform in a region that is no longer preserved. Petrographic data of limestone samples from 14 continuous long sections of olistoliths have been analyzed statistically, using multivariate clustering (Q‐mode) of the components/matrix/cement and canonical correspondence analysis that allow the reconstruction of the environmental parameters of carbonate microbial communities in space and time. Clustering analysis separated microbial and non‐microbial facies. The calculation of indices along the various axes from canonical correspondence analysis allows recognition of the controlling factors of the mounds and microbial growth as being turbidity, light penetration, bathymetry and storms. Turbidity and light penetration are the primary factors controlling the morphology of the microbial limestones. Representation of the light penetration and bathymetry indices on the stratigraphical sections defines two vertical environmental gradients. Light penetration can be subdivided into euphotic, euphotic–dysphotic and dysphotic‐aphotic conditions. The representation of the bathymetry allows the subdivision of samples into a deeper outer ramp, external mid‐ramp and internal mid‐ramp. The curve distance from the section base = f (index) suggests a cyclicity for the platform that cannot be compared with the onlap curve defined from other cratonic areas (Moscow Basin), and thus the cyclic succession of the Montagne Noire is interpreted to have been mostly tectonically‐controlled. Integration of the data allowed the reconstruction of the original Mississippian carbonate platform, where, up to the Mikhailovian, it appears to correspond to a platform morphology, with narrow shallow water facies and wide turbiditic systems, whereas the width of shallow‐water settings expanded during the Venevian to the Protvian, forming a ramp or distally‐steepened ramp with widespread microbial limestones.