Trace metals in harbour and slipway sediments from the island of Malta, central Mediterranean

Sediment samples collected from large harbours and public slipways on the island of Malta have been analysed for geochemically important metals (Al, Ca, Fe, Mn) and contaminant metals (As, Cd, Co, Cr, Cu, Ni, Pb, Sn, Zn) following fractionation (<63 μm) and digestion in aqua regia. Absolute and Al-normalised concentrations of contaminant metals exhibited relatively little dispersion both among different samples from the same location and between samples from different locations, notable exceptions including lower concentrations of Cr and Sn on the slipways than in the harbours. Sources of contaminant metals are attributed to diffuse and specific waste inputs from urban surroundings and boating and shipping activities. Overall, concentrations are similar to those reported for other large harbours in urban settings where equivalent sample fractionation-digestion has been performed. Relative to various sediment quality guidelines, Pb is predicted to exert the greatest threat to the marine environment of Malta.     

Multi-source water pollution in a highly anthropized wetland system associated with the estuary of Huelva (SW Spain)

Major ions, nutrients, trace elements and pesticides distribution were studied in a coastal wetland heavily impacted by human development in Spain. Past land use has altered the local hydrodynamics leading to the partitioning of the ecosystem into a tideland subject to marine influence, and an artificial freshwater reservoir created by stream impoundment. The tideland stretch is flooded twice a day with a heavy metal plume that emerges from the mine-polluted estuary of Huelva and propagates landward depicting the same dispersal trend of major seawater ions. Additionally, the tidal channel receives acid discharges from industrial point sources that contribute to metal enhancement. The impounded area and stream tributaries are affected by agrochemicals runoff (nitrate, phosphate, pendimethalin, simazine, diuron and therbuthylazine) from surrounding agricultural lands. The tidal regime plays a crucial role in the transport and dispersion of pollutants, except in the artificial reservoir where freshwater exhibits a seasonal mineralization pattern.     

Mediterranean Talitrus saltator (Crustacea, Amphipoda) as a biomonitor of heavy metals contamination

The use of sandhoppers and beachfleas as biomonitors of heavy metals contamination is relatively recent. Using adult individuals of Talitrus saltator from nine localities on the northern Mediterranean Sea, we studied the concentrations of eight trace elements: Al, Cd, Cr, Fe, Hg, Pb, Cu, Zn, both in the substratum and in the individuals. We also carried out a preliminary investigation of the correspondence between the sandhoppers' genetic variability and heavy metal contamination at the sampling sites. T. saltator accumulated Cd, Cu, Zn and Hg (at higher concentrations than in the sand) and also Al and Fe (at lower concentrations than in the sand). It seems that Mediterranean sandhoppers do not accumulate Pb and Cr. An intraspecific comparison between northern European (Baltic) and Mediterranean populations of T. saltator was made. Finally, we observed a tendency to a positive correlation between the sandhoppers' genetic variability and heavy metals contamination.     

Climate threats,water supply vulnerability and the risk of a water crisis in the Monterrey Metropolitan Area (Northeastern Mexico)

This paper evaluates the risk of a water crisis – a substantial, sudden reduction in water supply – in the Monterrey Metropolitan Area (MMA), posed by climate threats and the vulnerability of its water supply system. Our analysis of long-term precipitation, water supply and water availability data reveals that the MMA is highly vulnerable to recurring periods of exceptionally low precipitation and scarce surface water availability. We identify two episodes in the recent past (1998 and 2013) when the MMA water supply system almost collapsed as reservoirs neared depletion in the face of abnormally dry weather. Furthermore our climate projections point to warmer and drier future conditions for the region and consequently, heightened climate threats. We conclude that the risk of a water crisis in the MMA is substantial and probably will increase due to climate change. This establishes a clear and pressing need for a comprehensive package of adaptation measures to mitigate the consequences of a water crisis should one occur as well as to reduce the likelihood of such an event.     

Trace elements in the sediments of a large Mediterranean marina (Port Camargue,France): Levels and contamination history

The study of trace elements (Cu, Zn, Pb, As, Hg) and butyltin concentrations in the sediments of Port Camargue enabled assessment of the levels and history of the contamination of the largest European marina linked with the use of antifouling paints. Surface sediments near the boat maintenance area were heavily contaminated with up to 1497 μg g⁻¹ of Cu, 475 μg g⁻¹ of Zn, 0.82 μg g⁻¹ of Hg, 94 μg g⁻¹ of Pb and over 10,000 ngSn g⁻¹ of tributyltin (TBT). High concentrations of Hg and TBT indicate ongoing sources of these elements despite the ban on their use as biocides in paints. Sediment cores provided records of contamination since 1969. The peak concentrations of As, Hg, Pb and TBT in the sediment profile reflect their presence on boat hulls when the marina was built at the end of the 1960s. Degradation of TBT in the sediments near the boat maintenance area is slow compared to other less contaminated area of the marina.     

Evaluating methods to quantify sediment volumes trapped behind check dams,Salda(n)a badlands (Spain)

The determination of sediment yield in catchments based on the sediment trapped by check dams is becoming a subject of interest.In fact,several methods have been developed in recent years to estimate the sediment retained by check dams.The complexity,precision and accuracy of each method vary greatly.In this study,we evaluate the sediment trapped by check dams comparing the Sections method respect to the Prism,Pyramid,DTMs and Trapezoid methods.We analyzed a sample of 25 check dams(α-1=90%;ε=10%) in the Saldana badlands(Spain).The results showed that the Sections method offered a volume of retained sediment between the others,which gave an absolute variation from 22%to40%.The high variability of the check dam and sediment wedge sizes made necessary to compare methods in groups combining both characteristics.No significant differences in sediment volumes could be found between the methods for very small(height(h):1.8-2.3 m;trapped volume(V):6-102 m~3) or large check dams(h 2.3 m;V:165-387 m~3),while significant differences are found for small(h 1.5 m;V:1-229 m~3) or middle-sized check dams(h:2.2-3.2 m;V:65-235 m3).Nevertheless,volume differences between groups ranged up to + 25%.For these reason,the size of the check dam,the shape of the sediment wedge and the accuracy of the measure methods must considered when selecting an appropriate method to obtain the volume of retained sediment by check dams.A correct estimation of the sediment retention is needed to evaluate the role and efficiency of check dams in restoration projects or to estimate sediment yields.     

Short-term effects of changes in water management on the limnological characteristics and zooplankton of a eutrophic Mediterranean coastal lagoon (NE Iberian Peninsula)

The Ter Vell (NE Iberian Peninsula) is a eutrophic coastal lagoon which has been flooded by the excess irrigation water and the agricultural runoff during the last decades. Between 1999 and 2003, restoration measures were applied to improve its water quality. At the same time, but independently, agricultural water management drastically reduced the freshwater inflow. The short-term effects of these management actions on the limnological characteristics of the lagoon were analysed by comparing two hydrological cycles, one before (1999/2000) and the other one after (2002/2003) the actions. The two cycles are illustrative of opposite situations in the hydrological functioning of coastal wetlands. In the first, the lagoon was exorheic, with prolonged flooding periods and a low residence time; in the second, it had a more endorheic character, with scarce water inputs and prolonged periods of confinement. Consequently, nitrogen inputs diminished and organic load and salinity increased as the internal loading and the accumulation effects became more relevant. These effects were actually caused by the drastic reduction in the freshwater inflow which prevented, in turn, the success of the restoration measures. The zooplankton community of the Ter Vell lagoon was not significantly altered by the hydrological change, at least in the short-term, and rotifers and cladocerans, mainly those species indicative of eutrophy, dominated the community.     

Occurrence of priority pollutants in WWTP effluents and Mediterranean coastal waters of Spain

A comprehensive study aimed at evaluating the occurrence, significance of concentrations and spatial distribution of priority pollutants (PPs) along the Comunidad Valenciana coastal waters (Spain) was carried out in order to fulfil the European Water Framework Directive (WFD). Additionally, PP concentrations were also analysed in the effluent of 28 WWTPs distributed along the studied area. In coastal waters 36 organic pollutants of the 71 analysed, including 26 PPs were detected although many of them with low frequency of occurrence. Only 13 compounds, which belong to four different classes (VOCs, organochlorinated pesticides, phthalates and tributyltin compounds (TBT)) showed a frequency of occurrence above 20% in coastal waters. In the results obtained until now, octylphenol, pentachlorobenzene, DEHP and TBT exceeded the annual average concentration (EQS-AAC), and only TBT surpassed the maximum allowable concentration (EQS-MAC). The most frequent contaminants determined in coastal waters were also present in WWTP effluents.     

Zoobotryon verticillatum Della Chiaje, 1822 (Bryozoa), a new occurrence in the archipelago of the Azores (North-Eastern Atlantic)

The new occurrence of the bryozoan Zoobotryon verticillatum Della Chiaje, 1822 is herein recorded in multiple places throughout Azores archipelago. Where introduced, this species has caused important ecological and economical damage and therefore is regarded as invasive. In the Azores, no detrimental effects have yet been noted. The species is so far restricted to marinas (Horta, Faial Island; Vila Franca do Campo, São Miguel Island) and a natural coastal pool located near a secondary harbour (Lajes do Pico, Pico Island).A total of 29 colonies were counted during a specific survey conducted in August 2008 in the marina of Horta. The distribution of the species throughout the eastern and central island groups denotes a wide dispersion area and offers control or eradication measures a low probability of success together with the lack of harbour management practices that could effectively prevent the arrival, settlement and dispersal of non-native species transported by human-assisted means.     

Hydrological behaviour of a small catchment in the dehesa landuse system (Extremadura, SW Spain)

Investigations of the hydrological processes operating in a small experimental catchment representative of the dehesa ecosystem were carried out. The dehesa constitutes a system of agro-silvo-pastoral landuse, which is characterized by a Mediterranean, semi-arid climate. The study includes an analysis of the relationships between rainfall, soil water content and discharge, as well as the establishment of the annual water budget. The results demonstrate a complex hydrological response. The relationships between the factors involved and the operating processes are difficult to explain because of the decisive role played by the valley bottoms. These areas typically possess a sediment fill, and contrast with the shallow soils developed on the hillslopes. Genesis and quantity of runoff (Hortonian or saturation) measured at the outlet depend on the antecedent moisture conditions of the valley bottoms because of their water-retention capacity. Annual runoff coefficients are similar to those reported from other semi-arid areas. The analysis of the annual water budget shows that rainfall is positively related with both actual evapotranspiration and discharge.     

Heavy metal sedimentary record in a Galician Ria (NW Spain): background values and recent contamination

Two long sediment cores were sampled at the Ferrol Ria (Galicia, NW Spain) and the heavy metal (Co, Cr, Cu, Fe, Ni, Pb and Zn) concentrations measured in order to (i) state accurate background values providing baseline relationships with respect to a reference element and (ii) to investigate the recent metal contamination trends. Background values were found to agree well with the world average values for granite/schists-genisses rocks. However, Cu, Co, Pb and Zn were found to be lower than those previously reported as background values for the Galician Rias. Results emphasize the importance of using baseline relationships with respect to a normalizing element in order to reduce the scattering of data and to allow an accurate statement of background values. The distribution of metals in the cores showed an evident enrichment in the surface layers belonging to the industrial era. Normalized enrichment factors (NEF) for copper and zinc are in the order of 3-5 (certain/severe contamination) in the surface sediments, decreasing with depth. Lead contamination has decreased in the recent years from NEF of 3-7 down to a NEF of 2 (i.e. moderate contamination), probably due to the introduction of unleaded gasolines. Chromium, cobalt and nickel NEFs were always in the <1-2 range indicating null/low contamination by these metals.     

Non-invasive Geophysical Surveys in Search of the Roman Temple of Augustus Under the Cathedral of Tarragona (Catalonia,Spain): A Case Study

An integrated geophysical survey has been conducted at the Tarragona’s Cathedral (Catalonia, NE Spain) with the aim to confirm the potential occurrence of archaeological remains of the Roman Temple dedicated to the Emperor Augustus. Many hypotheses have been proposed about its possible location, the last ones regarding the inner part of the Cathedral, which is one of the most renowned temples of Spain (twelfth century) evolving from Romanesque to Gothic styles. A geophysical project including electrical resistivity tomography (ERT) and ground probing radar (GPR) was planned over 1 year considering the administrative and logistic difficulties of such a project inside a cathedral of religious veneration. Finally, both ERT and GPR have been conducted during a week of intensive overnight surveys that provided detailed information on subsurface existing structures. The ERT method has been applied using different techniques and arrays, ranging from standard Wenner–Schlumberger 2D sections to full 3D electrical imaging with the advanced Maximum Yield Grid array. Electrical resistivity data were recorded extensively, making available many thousands of apparent resistivity data to obtain a complete 3D image after a full inversion. In conclusion, some significant buried structures have been revealed providing conclusive information for archaeologists. GPR results provided additional information about shallowest structures. The geophysical results were clear enough to persuade religious authorities and archaeologists to conduct selected excavations in the most promising areas that confirmed the interpretation of geophysical data. In conclusion, the significant buried structures revealed by geophysical methods under the cathedral were confirmed by archaeological digging as the basement of the impressive Roman Temple that headed the Provincial Forum of Tarraco, seat of the Concilium of Hispania Citerior Province.     

Sediment production in large gullies of the Mediterranean area (NE Spain) from high‐resolution digital elevation models and geographical information systems analysis

Recent studies in the Mediterranean area have shown gully erosion to have a very significant contribution to total soil loss. In the Penedès vineyard region (NE Spain), between 15 and 27% of the land is affected by large gullies and gully‐wall retreat seems to be an ongoing process. Multi‐date digital elevation model (DEM) analysis has allowed computation of sediment production by gully erosion, showing that the sediment production rates are very high by the, up‐to‐date, usual global standards. Here, we present a study carried out using large‐scale multi‐date (1975 and 1995) aerial photographs (1 : 5000 and 1 : 7000) to monitor sediment yield caused by large gullies in the Penedès region (NE Spain). High‐resolution DEMs (1 m grid) were derived and analysed by means of geographical information systems techniques to determine the gully erosion rates. Rainfall characteristics within the same study period were also analysed in order to correlate with the soil loss produced. Mass movement was the main process contributing to total sediment production. This process could have been favoured by rainfalls recorded during the period: 58% of the events were of an erosive character and showed high kinetic energy and erosivity. A sediment production rate of 846 ± 40 Mg ha^?1 year^?1, a sediment deposition rate of 270 ± 18 Mg ha^?1 year^?1 and a sediment delivery ratio of 68·1% were computed for a gully area of 0·10 km². The average net erosion within the study period (1975–95) was 576 ± 58 Mg ha^?1 year^?1. In comparison with other methods, the proposed method also includes sediment produced by processes other than only overland flow, i.e. downcutting, headcutting, and mass movements and bank erosion. Copyright © 2003 John Wiley & Sons, Ltd.     

Occurrence of perfluorinated compounds in water, sediment and mussels from the Cantabrian Sea (North Spain)

Perfluorinated compounds (PFCs) have emerged as significant global environmental pollutants with persistent, bioaccumulative and toxic properties. The aim of this study was to determine the occurrence of PFCs in water (wastewater, submarine emissaries and port-waters), sediment and transplanted mussels in estuarine areas of high urban and industrial impact from Northern Spain. Five PFCs of industrial use were studied: perfluorooctanesulfonate, perfluorohexanesulfonate, perfluorobutanesulfonate, perfluorooctanoate acid and perfluorononanoate acid. After selective extraction, samples were analyzed by Ultra Performance Liquid Chromatography coupled to tandem mass spectrometry. ΣPFCs ranged from 0.06 to 10.9 ng/L in water, with higher levels in wastewater treatment plants effluents and port waters than in submarine emissaries. Little accumulation was observed in sediments and mussels with ΣPFCs ranging from 0.01-0.13 ng/g dw and 0.01-0.06 ng/g ww, respectively. Most ubiquitous compounds were PFOS and PFOA. Mass fluxes of PFCs to the Cantabrian Sea are estimated and the impact to the coastal ecosystem is discussed.     

江苏省灌河流域污染特征及污染控制对策

基于2008年江苏省沿海地区灌河流域各城市污染源统计及调查数据,分析灌河流域主要污染物来源构成和污染特征,对污染物入河量进行计算及修正.结果表明:灌河的CODMn入河总量为36944.2 t/a,氨氮入河总量为4366.5 t/a,总氮和总磷入河总量分别为6507.4 t/a、444.6 t/a,各污染源均主要来源于农业污染.同时,针对灌河流域的污染特征,明确各类污染源的治理重点,提出了污染控制对策,为有效保护灌河水环境质量,支撑灌河口和灌河沿线的开发提供依据.     

Comparison of SMOS,modelled and in situ long-term soil moisture series in the northwest of Spain

ABSTRACT

This work aimed to evaluate the capability of modelled vs in situ soil moisture observations in the northwest of Spain for a period of four years (2010–2013) in order to validate the SMOS L2 product. Comparisons were performed for a set of representative stations of the Soil Moisture Measurement Stations network of the University of Salamanca (REMEDHUS) at both point and area scales. The SMOS series showed good correlation with the modelled series, better than that obtained with the in situ observations (0.77 vs 0.68 average correlation coefficients). However, some underestimation or overestimation of the SMOS series, related to the soil characteristics, was observed with respect to both the in situ and the modelled series. The SMOS data normalization produced a notable improvement in the results, highlighting the capability of the modelled data to validate the SMOS soil moisture series. This research provides a solid foundation for the future validation of SMOS at large scales, overcoming the spatial representativeness issues arising from the use of in situ point measurements.

Editor M.C. Acreman; Associate editor N. Verhoest     

Changes in benthic fish assemblages as a consequence of coastal works in a coastal lagoon: The Mar Menor (Spain, Western Mediterranean)

The benthic fish assemblage of the Mar Menor consisted of 37 species. Dominant species are: Gobius cobitis, Lipophrys pavo and Tripterygion tripteronotus on infralittoral rocks; Pomatoschistus marmoratus, Callionymus pussillus, Callionymus risso and Solea vulgaris on sandy bottoms and Gobius niger, Syngnathus abaster, Hippocampus ramulosus and Symphodus cinereus on Cymodocea nodosa-Caulerpa prolifera mixed beds. From 1985 to 1989 tourist development has led to the creation of new beaches and the installation of artificial rocky structures for retaining sediments. Dredging for the extraction of sand and subsequent pumping altered sediment characteristics causing a real stress leading to the substitution of typical sandy bottoms communities with Cymodocea nodosa by Caulerpa prolifera communities on mud. Soft bottom fish assemblages responded to changes in vegetation cover and substratum characteristics mainly changing the species composition, while artificial hard substrata contain a similar fish community than natural ones, harbouring even richer and more diverse assemblages. This positive effect of breakwaters should not obscure their likely negative effects on hydrodynamics and the subsequent changes of sediment quality and vegetation cover on the breakwaters' area of influence.     

Sources and sinks of nutrients in a New Zealand hill pasture catchment I. Stormflow generation

The processes of stormflow generation were studied in a hill pasture catchment near Hamilton, New Zealand. Although rainfall was relatively evenly distributed throughout the year, stormflow was highly seasonal and over 65 per cent occurred during the winter. Three main processes contributing to stormflow were identified which could be related to soil type and physiographic position. On gleyed soils derived from rhyolitic colluvium, saturation overland flow was the dominant process. Hydrographs from ‘Whipkey’ throughflow troughs also indicated that there was a subsurface response (saturated wedge) from this soil type. On steeper convex slopes, more permeable soils were derived from weathered greywacke. The presence of ephemeral springs on the hillslopes and direct observation during storm events indicated that storm runoff was generated as return flow from this soil. It was noted that nitrate concentrations from subsurface sources were 5–10 times higher than surface runoff. This difference in concentration was utilized in a chemical mixing equation which partitioned stormflow sources. This was compared with the stormflow predicted from rain falling on to saturated areas. There was good agreement between the two models for winter-spring events with respect to the volumes of surface runoff predicted, however the saturated areas model underestimated total stormflow. The results of the study are briefly discussed in terms of the potential for water quality management.