An integrated approach for modeling solute transport in streams and canals with applications

A new modeling approach for solute transport in streams and canals was developed to simulate solute dissolution, transport, and decay with continuously migrating sources. The new approach can efficiently handle complicated solute source feeding schemes and initial conditions. Incorporating the finite volume method (FVM) and the ULTIMATE QUICKEST numerical scheme, the new approach is capable of predicting fate and transport of solute that is added to small streams or canals, typically in a continuous fashion. The approach was tested successfully using a hypothetical case, and then applied to an actual field experiment, where linear anionic polyacrylamide (LA-PAM) was applied to an earthen canal. The field experiment was simulated first as a fixed boundary problem using measured concentration data as the boundary condition to test model parameters and sensitivities. The approach was then applied to a moving boundary problem, which included subsequent LA-PAM dissolution, settling to the canal bottom and transport with the flowing canal water. Simulation results showed that the modeling approach developed in this study performed satisfactorily and can be used to simulate a variety of transport problems in streams and canals.     

Coupled groundwater flow and transport: 1. Verification of variable density flow and transport models

This work examines variable density flow and corresponding solute transport in groundwater systems. Fluid dynamics of salty solutions with significant density variations are of increasing interest in many problems of subsurface hydrology. The mathematical model comprises a set of non-linear, coupled, partial differential equations to be solved for pressure/hydraulic head and mass fraction/concentration of the solute component. The governing equations and underlying assumptions are developed and discussed. The equation of solute mass conservation is formulated in terms of mass fraction and mass concentration. Different levels of the approximation of density variations in the mass balance equations are used for convection problems (e.g. the Boussinesq approximation and its extension, fully density approximation). The impact of these simplifications is studied by use of numerical modelling.Numerical models for nonlinear problems, such as density-driven convection, must be carefully verified in a particular series of tests. Standard benchmarks for proving variable density flow models are the Henry, Elder, and salt dome (HYDROCOIN level 1 case 5) problems. We studied these benchmarks using two finite element simulators - ROCKFLOW, which was developed at the Institute of Fluid Mechanics and Computer Applications in Civil Engineering and FEFLOW, which was developed at the Institute for Water Resources Planning and Systems Research Ltd. Although both simulators are based on the Galerkin finite element method, they differ in many approximation details such as temporal discretization (Crank-Nicolson vs predictor-corrector schemes), spatial discretization (triangular and quadrilateral elements), finite element basis functions (linear, bilinear, biquadratic), iteration schemes (Newton, Picard) and solvers (direct, iterative). The numerical analysis illustrates discretization effects and defects arising from the different levels of the density of approximation. We contribute new results for the salt dome problem, for which inconsistent findings exist in literature. Applications of the verified numerical models to more complex problems, such as thermohaline and three-dimensional convection systems, will be presented in the second part of this paper.     

Implementation of Solute Transport in the Vadose Zone into the “HYDRUS Package for MODFLOW”

The “HYDRUS package for MODFLOW” is an existing MODFLOW package that allows MODFLOW to simultaneously evaluate transient water flow in both unsaturated and saturated zones. The package is based on incorporating parts of the HYDRUS-1D model (to simulate unsaturated water flow in the vadose zone) into MODFLOW (to simulate saturated groundwater flow). The coupled model is effective in addressing spatially variable saturated-unsaturated hydrological processes at the regional scale. However, one of the major limitations of this coupled model is that it does not have the capability to simulate solute transport along with water flow and therefore, the model cannot be employed for evaluating groundwater contamination. In this work, a modified unsaturated flow and transport package (modified HYDRUS package for MODFLOW and MT3DMS) has been developed and linked to the three-dimensional (3D) groundwater flow model MODFLOW and the 3D groundwater solute transport model MT3DMS. The new package can simulate, in addition to water flow in the vadose zone, also solute transport involving many biogeochemical processes and reactions, including first-order degradation, volatilization, linear or nonlinear sorption, one-site kinetic sorption, two-site sorption, and two-kinetic sites sorption. Due to complex interactions at the groundwater table, certain modifications of the pressure head (compared to the original coupling) and solute concentration profiles were incorporated into the modified HYDRUS package. The performance of the newly developed model is evaluated using HYDRUS (2D/3D), and the results indicate that the new model is effective in simulating the movement of water and contaminants in the saturated-unsaturated flow domains.     

Analytical Solutions for Water Flow and Solute Transport in the Unsaturated Zone

Analytical solutions for the water flow and solute transport equations in the unsaturated zone are presented. We use the Broadbridge and White nonlinear model to solve the Richards’ equation for vertical flow under a constant infiltration rate. Then we extend the water flow solution and develop an exact parametric solution for the advection-dispersion equation. The method of characteristics is adopted to determine the location of a solute front in the unsaturated zone. The dispersion component is incorporated into the final solution using a singular perturbation method. The formulation of the analytical solutions is simple, and a complete solution is generated without resorting to computationally demanding numerical schemes. Indeed, the simple analytical solutions can be used as tools to verify the accuracy of numerical models of water flow and solute transport. Comparison with a finite-element numerical solution indicates that a good match for the predicted water content is achieved when the mesh grid is one-fourth the capillary length scale of the porous medium. However, when numerically solving the solute transport equation at this level of discretization, numerical dispersion and spatial oscillations were significant.     

A quasi three-dimensional model for flow and transport in unsaturated and saturated zones: 1. Implementation of the quasi two-dimensional case

A quasi three-dimensional (QUASI 3-D) model is presented for simulating the subsurface water flow and solute transport in the unsaturated and in the saturated zones of soil. The model is based on the assumptions of vertical flow in the unsaturated zone and essentially horizontal groundwater flow. The 1-D Richards equation for the unsaturated zone is coupled at the phreatic surface with the 2-D flow equation for the saturated zone. The latter was obtained by averaging 3-D flow equation in the saturated zone over the aquifer thickness. Unlike the Boussinesq equation for a leaky-phreatic aquifer, the developed model does not contain a storage term with specific yield and a source term for natural replenishment. Instead it includes a water flux term at the phreatic surface through which the Richards equation is linked with the groundwater flow equation. The vertical water flux in the saturated zone is evaluated on the basis of the fluid mass balance equation while the horizontal fluxes, in that equation, are prescribed by Darcy law. A 3-D transport equation is used to simulate the solute migration. A numerical algorithm to solve the problem for the general quasi 3-D case was developed. The developed methodology was exemplified for the quasi 2-D cross-sectional case (QUASI2D). Simulations for three synthetic problems demonstrate good agreement between the results obtained by QUASI2D and two fully 2-D flow and transport codes (SUTRA and 2DSOIL). Yet, simulations with the QUASI2D code were several times faster than those by the SUTRA and the 2DSOIL codes.     

Modeling the Impact of Stream Discharge Events on Riparian Solute Dynamics

The biogeochemical composition of stream water and the surrounding riparian water is mainly defined by the exchange of water and solutes between the stream and the riparian zone. Short-term fluctuations in near stream hydraulic head gradients (e.g., during stream flow events) can significantly influence the extent and rate of exchange processes. In this study, we simulate exchanges between streams and their riparian zone driven by stream stage fluctuations during single stream discharge events of varying peak height and duration. Simulated results show that strong stream flow events can trigger solute mobilization in riparian soils and subsequent export to the stream. The timing and amount of solute export is linked to the shape of the discharge event. Higher peaks and increased durations significantly enhance solute export, however, peak height is found to be the dominant control for overall mass export. Mobilized solutes are transported to the stream in two stages (1) by return flow of stream water that was stored in the riparian zone during the event and (2) by vertical movement to the groundwater under gravity drainage from the unsaturated parts of the riparian zone, which lasts for significantly longer time (> 400 days) resulting in long tailing of bank outflows and solute mass outfluxes. We conclude that strong stream discharge events can mobilize and transport solutes from near stream riparian soils into the stream. The impact of short-term stream discharge variations on solute exchange may last for long times after the flow event.     

Importance of unsaturated zone flow for simulating recharge in a humid climate

Transient recharge to the water table is often not well understood or quantified. Two approaches for simulating transient recharge in a ground water flow model were investigated using the Trout Lake watershed in north-central Wisconsin: (1) a traditional approach of adding recharge directly to the water table and (2) routing the same volume of water through an unsaturated zone column to the water table. Areas with thin (less than 1 m) unsaturated zones showed little difference in timing of recharge between the two approaches; when water was routed through the unsaturated zone, however, less recharge was delivered to the water table and more discharge occurred to the surface because recharge direction and magnitude changed when the water table rose to the land surface. Areas with a thick (15 to 26 m) unsaturated zone were characterized by multimonth lags between infiltration and recharge, and, in some cases, wetting fronts from precipitation events during the fall overtook and mixed with infiltration from the previous spring snowmelt. Thus, in thicker unsaturated zones, the volume of water infiltrated was properly simulated using the traditional approach, but the timing was different from simulations that included unsaturated zone flow. Routing of rejected recharge and ground water discharge at land surface to surface water features also provided a better simulation of the observed flow regime in a stream at the basin outlet. These results demonstrate that consideration of flow through the unsaturated zone may be important when simulating transient ground water flow in humid climates with shallow water tables.     

Impact of Local Groundwater Flow Model Errors on Transport and a Practical Solution for the Issue

A groundwater flow model is typically used to provide the flow field for conducting groundwater solute transport simulations. The advection term of the mass conserved formulation for groundwater transport assumes that the flow field is perfectly balanced and that all water flowing into a numerical grid cell is exactly balanced by outflows after accounting for sources/sinks or internal storage. However, in many complicated regional or site‐scale models, there may be localized flow balance errors that may be difficult to eliminate through tighter flow convergence tolerances due to simulation time constraints or numerical limits on convergence tolerances. Thus, if water is erroneously gained or lost within a grid cell during the flow computation, the solutes within it will also be numerically affected in the associated transport simulation. Transport solutions neglect this error in groundwater flow as the transport equations that are solved assume no error in flow. This flow imbalance error can however have consequences on the transport solution ranging from unnoticeable errors in the resulting concentrations to spurious oscillations that can grow in time and hinder further solution. An approach has been suggested here, to explicitly handle these flow imbalances during mass conserved advective transport computations and report them in the corresponding transport mass balance output, as corrections that are needed to handle errors originating in the flow solution. Example problems are provided to explain the concepts and demonstrate the impacts.     

MODFLOW/MT3DMS-based simulation of variable-density ground water flow and transport

This paper presents an approach for coupling MODFLOW and MT3DMS for the simulation of variable-density ground water flow. MODFLOW routines were modified to solve a variable-density form of the ground water flow equation in which the density terms are calculated using an equation of state and the simulated MT3DMS solute concentrations. Changes to the MODFLOW and MT3DMS input files were kept to a minimum, and thus existing data files and data files created with most pre- and postprocessors can be used directly with the SEAWAT code. The approach was tested by simulating the Henry problem and two of the saltpool laboratory experiments (low- and high-density cases). For the Henry problem, the simulated results compared well with the steady-state semianalytic solution and also the transient isochlor movement as simulated by a finite-element model. For the saltpool problem, the simulated breakthrough curves compared better with the laboratory measurements for the low-density case than for the high-density case but showed good agreement with the measured salinity isosurfaces for both cases. Results from the test cases presented here indicate that the MODFLOW/MT3DMS approach provides accurate solutions for problems involving variable-density ground water flow and solute transport.     

环太湖各水资源分区入出湖河流总磷浓度与负荷变化分析

入出湖总磷负荷变化是影响太湖湖体磷收支平衡的关键因素.基于2012-2018年水质水量监测资料,计算全湖及各水资源分区河流入出湖总磷负荷,并以水量加权计算其总磷年平均浓度,探明其时空变化规律;运用双累积曲线法分析不同分区水污关系的变化规律;以月为时间尺度,利用Pearson相关系数,揭示入湖总磷负荷分别与入湖水量、入湖...     

On using simple time-of-travel capture zone delineation methods

As part of its Wellhead Protection Program, the U.S. EPA mandates the delineation of "time-of-travel capture zones" as the basis for the definition of wellhead protection zones surrounding drinking water production wells. Depending on circumstances the capture zones may be determined using methods that range from simply drawing a circle around the well to sophisticated ground water flow and transport modeling. The simpler methods are attractive when faced with the delineation of hundreds or thousands of capture zones for small public drinking water supply wells. On the other hand, a circular capture zone may not be adequate in the presence of an ambient ground water flow regime. A dimensionless time-of-travel parameter T is used to determine when calculated fixed-radius capture zones can be used for drinking water production wells. The parameter incorporates aquifer properties, the magnitude of the ambient ground water flow field, and the travel time criterion for the time-of-travel capture zone. In the absence of interfering flow features, three different simple capture zones can be used depending on the value of T . A modified calculated fixed-radius capture zone proves protective when T < 0.1, while a more elongated capture zone must be used when T > 1. For values of T between 0.1 and 1, a circular capture zone can be used that is eccentric with respect to the well. Finally, calculating T allows for a quick assessment of the validity of circular capture zones without redoing the delineation with a computer model.     

Higher and lowest order mixed finite element approximation of subsurface flow problems with solutions of low regularity

In this work we study mixed finite element approximations of Richards’ equation for simulating variably saturated subsurface flow and simultaneous reactive solute transport. Whereas higher order schemes have proved their ability to approximate reliably reactive solute transport (cf., e.g. [Bause M, Knabner P. Numerical simulation of contaminant biodegradation by higher order methods and adaptive time stepping. Comput Visual Sci 7;2004:61–78]), the Raviart–Thomas mixed finite element method (RT₀) with a first order accurate flux approximation is popular for computing the underlying water flow field (cf. [Bause M, Knabner P. Computation of variably saturated subsurface flow by adaptive mixed hybrid finite element methods. Adv Water Resour 27;2004:565–581, Farthing MW, Kees CE, Miller CT. Mixed finite element methods and higher order temporal approximations for variably saturated groundwater flow. Adv Water Resour 26;2003:373–394, Starke G. Least-squares mixed finite element solution of variably saturated subsurface flow problems. SIAM J Sci Comput 21;2000:1869–1885, Younes A, Mosé R, Ackerer P, Chavent G. A new formulation of the mixed finite element method for solving elliptic and parabolic PDE with triangular elements. J Comp Phys 149;1999:148–167, Woodward CS, Dawson CN. Analysis of expanded mixed finite element methods for a nonlinear parabolic equation modeling flow into variably saturated porous media. SIAM J Numer Anal 37;2000:701–724]). This combination might be non-optimal. Higher order techniques could increase the accuracy of the flow field calculation and thereby improve the prediction of the solute transport. Here, we analyse the application of the Brezzi-Douglas-Marini element (BDM₁) with a second order accurate flux approximation to elliptic, parabolic and degenerate problems whose solutions lack the regularity that is assumed in optimal order error analyses. For the flow field calculation a superiority of the BDM₁ approach to the RT₀ one is observed, which however is less significant for the accompanying solute transport.     

Necessary conditions for inverse modeling of flow through variably saturated porous media

Non-unique solutions of inverse problems arise from a lack of information that satisfies necessary conditions for the problem to be well defined. This paper investigates these conditions for inverse modeling of water flow through multi-dimensional variably saturated porous media. It shows that in order to obtain a unique estimate of hydraulic parameters, along each streamline of the flow field (1) spatial and temporal head observations must be given; (2) the number of spatial and temporal head observations required should be greater or equal to the number of unknown parameters; (3) the flux boundary condition or the pumping rate of a well must be specified for the homogeneous case and both boundary flux and pumping rate are a must for the heterogeneous case; (4) head observations must encompass both saturated and unsaturated conditions, and the functional relationships for unsaturated hydraulic conductivity/pressure head and for the moisture retention should be given, and (5) the residual water content value also need to be specified a priori or water content measurements are needed for the estimation of the saturated water content.For field problems, these necessary conditions can be collected or estimated but likely involve uncertainty. While the problems become well defined and have unique solutions, the solutions likely will be uncertain. Because of this uncertainty, stochastic approaches are deemed to be appropriate for inverse problems as they are for forward problems to address uncertainty. Nevertheless, knowledge of these necessary conditions is critical to reduce uncertainty in both characterization of the vadose zone and the aquifer, and prediction of water flow and solute migration in the subsurface.     

Environmental tracer transport (H and SF6) in the saturated and unsaturated zones and its use in nitrate pollution management

An important quantity in groundwater protection is the residence time of water in an aquifer. It relates to both the travel time of a pollutant to arrive at a well and the time span required for self-purification of a polluted aquifer after removal of pollutant inputs. Time scales for aquifers can be gained from artificial tracer experiments or from environmental tracer data, the latter offering the only realistic alternative if time scales of years or decades have to be taken into account.

Different tracers show different time scales due to their different transport mechanisms especially in the unsaturated zone. While solute tracers are moved advectively with the seepage water, gas tracers pass the unsaturated zone diffusively through the air phase. Depending on the properties of the unsaturated zone (hydraulic properties, thickness) this difference in behavior can be used to separate the subsurface transport process into the unsaturated and the saturated parts.

In a field study in Germany, SF₆ and ³H were used as environmental tracers. Both have a relatively well-known input function. Interpretation of data from observation wells by a box model approach led to spatially and temporally varying residence times. This was an indication that the influence of the unsaturated zone could not be neglected. While the gas tracer SF₆ shows only residence times in the saturated zone, the tracer ³H reflects the whole travel time of water including both the unsaturated and saturated zones. Using a one-dimensional plug-flow model for the unsaturated zone combined with a detailed two-dimensional flow and transport model for the saturated zone leads to a holistic and consistent interpretation of the measured tracer concentrations. The observed pattern of old water under thick loess cover and younger water under areas where the fractured basalt aquifer crops out is reproduced after adjusting only two parameters: the effective porosity of the saturated aquifer and the product of field capacity and thickness of the unsaturated zone. While the effective porosity of the saturated zone is adjusted by means of the SF₆ data, the field capacity of the loess layer is adjusted by means of the ³H observations. The thickness of the unsaturated zone is deduced from geological and pedological maps. All flow data are obtained from a calibrated flow model, which is based on geological data, observed heads and pumping tests only.

The transport model for the saturated zone was calibrated by fitting the porosity by means of gaseous tracer concentrations (SF₆). The combined saturated–unsaturated zone model was then calibrated by fitting the field capacity of the unsaturated zone by means of ³H concentrations. With this model it was possible to verify the observed NO₃ concentrations at the drinking water wells and to develop predictions for their future development under various scenarios of fertilizer input reduction in specific areas.     

Kinematic wave solutions for pollutant transport over an infiltrating plane with finite‐period mixing and mixing zone

Kinematic wave solutions are derived for transport of a conservative non‐point‐source pollutant during a rainfall‐runoff event over an infiltrating plane for two cases: (i) finite‐period mixing and (ii) soil‐mixing zone. Rainfall is assumed to be steady, uniform and finite in duration, and it is assumed to have zero concentration of pollutants. Infiltration is assumed constant in time and space. Prior to the start of rainfall, the pollutant is distributed uniformly over the plane. In the first case, when rainfall occurs, the mixing of pollutant in the runoff water occurs in a finite period of time. In the second case, the chemical concentration is assumed to be a linearly decreasing function of rainfall intensity and overland flow. The solute concentration and discharge are found to depend on the flow characteristics as well as the solute concentration parameters. The characteristics of solute concentration and discharge graphs seem to be similar to those reported in the literature and observed in laboratory experiments. Copyright © 2002 John Wiley & Sons, Ltd.     

An Investigation of the Pressure Pulsing Reagent Delivery Approach

Pressure pulsing technology is an innovative method that has been developed with the aim of overcoming preferred flow paths associated with remediation techniques that rely on the injection of reagents. Numerical and field experiments were conducted to assess how pressure pulsing affects groundwater flow and solute transport during reagent injection. A series of field experiments were performed at two field sites where a monitoring network designed to capture the breakthrough of solutes delivered from an injection well was installed. Pressure pulsing and conventional injection methods were used at each site. One site was comprised of fine sand with low heterogeneity, while the other was moderately heterogeneous with discrete layers varying from fine sand to silt. The data suggest that breakthrough was more uniform for the pressure pulsing injections; however, this difference was minor and complicated by sorption of some of the tracers employed. The groundwater flow and solute transport modeling exercise simulated the rapid boundary pressure modulation that occurs in association with pressure pulsing. Two‐dimensional (2D) simulations revealed that repeated sudden onset of injection cessation produces brief periods of gradient reversal and the development of a mixing zone near the injection well. The spatial extents of this mixing zone were found to be highly dependent upon the hydraulic diffusivity of the medium, with medium heterogeneity and pulsing frequency playing secondary roles. Three‐dimensional (3D) numerical simulations were used to benchmark the observations from one of the field sites. The results from the modeling effort showed that solute breakthrough from a pressure pulsing injection is more dispersed relative to a conventional injection as a result of the mixing zone phenomenon; however, we were unable to directly observe this mixing zone using the instrumentation deployed at the two field sites.     

Characterising deep vadose zone water movement and solute transport under typical irrigated cropland in the North China Plain

Understanding the dynamics and mechanisms of soil water movement and solute transport is essential for accurately estimating recharge rates and evaluating the impacts of agricultural activities on groundwater resources. In a thick vadose zone (0–15 m) under irrigated cropland in the piedmont region of the North China Plain, soil water content, matric potential, and solute concentrations were measured. Based on these data, the dynamics of soil water and solutes were analysed to investigate the mechanisms of soil water and solute transport. The study showed that the 0–15‐m vadose zone can be divided into three layers: an infiltration and evaporation layer (0–2 m), an unsteady infiltration layer (2–6 m), and a quasi‐steady infiltration layer (6–15 m). The chloride, nitrate, and sulphate concentrations all showed greater variations in the upper soil layer (0–1 m) compared to values in the deep vadose zone (below 2 m). The average concentrations of these three anions in the deep vadose zone varied insignificantly with depth and approached values of 125, 242, and 116 mg/L. The accumulated chloride, sulphate, and nitrate were 2,179 ± 113, 1,760 ± 383, and 4,074 ± 421 kg/ha, respectively. The soil water potential and solute concentrations indicated that uniform flow and preferential flow both occurred in the deep vadose zone, and uniform flow was the dominant mechanism of soil water movement in this study. The piston‐like flow velocity of solute transport was 1.14 m per year, and the average value of calculated leached nitrate nitrogen was 107 kg/ha?year below the root zone. The results can be used to better understand recharge processes and improve groundwater resources management.     

Density effects on solute release from streambeds

Contaminants that entered the streambed during previous surface water pollution events can be released to the stream, causing secondary pollution of the stream and impacting its eco-environmental condition. By means of laboratory experiments and numerical simulations, we investigated density effects on the release of solute from periodic bedforms. The results show that solute release from the upper streambed is driven by bedform-induced convection, and that density effects generally inhibit the solute release from the lower streambed. Density gradients modify the pore water flow patterns and form circulating flows in the area of lower streambed. The formation of circulating flows is affected by density gradients associated with the solute concentration and horizontal pressure gradients induced by stream slope. The circulating flows near the bottom of the streambed enhance mixing of the hyporheic zone and the ambient flow zone.     

Analytical Solutions for Determination of Non-Steady- State and Steady-State Capture Zones

This paper presents analytical solutions for determining non-steady-state capture zones produced by a single recovery well and steady-state capture zones produced by multiple recovery wells. Analysis of non-steady-slate capture zones is based on the lime-dependent location of caplure zone stagnation points and the geometric similarity between steady-slate and non-steady-state capture zones. The analytical solution of steady-state capture zones is obtained from spatial variations of discharge potential across the capture zone boundary. Both capture zone analyses are based on the assumptions of uniform flow field with a constant hydraulic conductivity, the Dupuit assumption of insignificant vertical flow, a negligible delayed yield, and a fully penetrating well with a constant pumping rate. For a ground water pump-and-trcat remediation program, the pumping rate and well location design variables can be adjusted to ensure containment of the ground water contaminant plume.     

Exposure concentration statistics in the subsurface transport

The concentration fluctuations resulting from hazardous releases in the subsurface are modeled through the concentration moments. The local solute exposure concentration, resulting from the heterogeneous velocity field and pore scale dispersion in the subsurface, is a random function characterized by its statistical moments. The approximate solution to the exact equation that describes the evolution of concentration standard moments in the aquifer transport is proposed in a recursive form. The expressions for concentration second, third and fourth central moments are derived and evaluated for various flow and transport conditions. The solutions are sought by starting from the exact upper bound solution with the zero pore scale dispersion and introducing the physically based approximation that allows the inclusion of the pore scale dispersion resulting in simple closed-form expressions for the concentration statistical moments. The concentration moments are also analyzed in the relative and absolute frame of reference indicating their combined importance in the practical cases of the subsurface contaminant plume migration. The influence of pore scale dispersion with different source sizes and orientations are analyzed and discussed with respect to common cases in the environmental risk assessment problems. The results are also compared with the concentration measurements of the conservative tracer collected in the field experiments at Cape Cod and Borden Site.