Geomorphology and tectonics of the Dorrigo Plateau,N.S.W.

The Dorrigo Plateau is covered by basalt, which is a remnant of the 18 Ma old Ebor Volcano. The centre of this volcano is an intrusion in the Bellinger Valley. The volcano was erupted on a palaeoplain of moderate relief. Subsequent uplift and tilting led to erosion of the Nambucca Beds, together with much of the volcano, and creation of a major escarpment, part of the Great Escarpment of eastern Australia. In this area the Great Escarpment is younger than 18 Ma.     

A framework for the palaeozoic geology of the southern part of the New England Geosyncline

The southern part of the New England Geosyncline is divided by the Peel Fault into two major zones, termed the Tablelands Complex to the east and the Tamworth Belt to the west. Because of stratigraphical similarities the Hastings Block is correlated with the Tamworth Belt. Seven major lithostratigraphic associations are recognized in the Tablelands Complex. The Woolomin Association is a deepwater marine chert‐jasper‐basic volcanic‐dominated sequence in which sandstones are rare. The Sandon Association is a turbidite sequence in which minor chert, jasper, and basic volcanics are present. The Coffs Harbour Association is a deepwater marine turbidite sequence and is distinguished from the Sandon Association by the absence of chert, jasper, and basic volcanics. The Nambucca Association is also deepwater marine in nature and is dominated by diamictites deposited by mass movements. The Silverwood Association contains components of a volcanic arc, and the Dummy Creek Association consists of terrestrial to shallow‐water marine sediments deposited in rim synclines associated with the granitic intrusions. The above associations contain sandstones which are predominantly quartz‐poor lithic greywackes and these differ from the Beenleigh Association which contains continental shelf to deepwater marine deposits in which the sandstones are quartz‐rich. Recognition of the associations has been hindered by the intrusion of four granitic suites, metamorphism of the sediments under differing conditions of temperature and pressure, and fragmentation by several large‐scale faults into numerous blocks.     

Field and geochemical characteristics of the Coolac Ophiolite suite and its possible origin in a marginal sea

Geological and geochemical data from the Coolac Serpentinite Belt, North Mooney Complex and Honeysuckle Beds in southern New South Wales indicate that the association represents a partially dismembered ophiolite suite. All the ideal ophiolite units are present, although the sheeted dyke unit is apparently of limited extent. Major and trace element (including rare‐earth) results, relationships of mafic volcanics and dolerite to massive and layered gabbroic and ultramafic intrusives, the occurrence of tectonised harzburgite with podiform chromitite, and the nature of pyritic sulphide occurrences, are consistent with a marginal sea or back‐arc environment for the generation of the ophiolite suite.     

Relation between trace and major element composition of the Chitaldrug metabasalts,Mysore, India,and the Archaean mantle

The ferromagnesium trace-element content of the Chitaldrug metabasalts is not compatable with its normative composition. The major elements resemble quartz-normative tholeiites and some trace-elements like Co are even higher or similar to that of olivine-normative tholeiites or the deep-oceanic tholeiites. The relationship between MgO and ferromagnesium traces is sympathetic but of very low order. The high ferromagnesium trace content in this suite and its poor relation with major elements suggest that probably the Archaean/Early Precambrian upper mantle had higher levels of these elements than the present mantle. Lateral compositional inhomogeneities in the Archaean upper mantle are also indicated from the available trace-element data over the Archaean metabasalts from different shields.     

A sheeted dyke complex within the Coolac Ophiolite,southeastern New South Wales

A unit composed of sheeted dykes and an associated unit of sodic felsic rocks have been found within the Coolac Ophiolite, about 5 km east of Coolac township, southeastern N.S.W. The dyke complex consists of small multiple dykes intruding gabbro screens. About half the dykes are basaltic in composition and half are ande‐sitic. Felsic differentiates occur as minor intrusions within the dyke complex, and also constitute the sodic felsic unit. It is suggested that the dyke complex and associated felsic rocks be included in the Honeysuckle Beds, and that the absence of a mappable dyke unit further south within the Honeysuckle Beds is caused by tectonic dismembering of the ophiolite. The dyke complex bears considerable resemblance to the sheeted dyke members of other ophiolite sequences. However, the scale of development is roughly 10 times smaller than at Troodos or Newfoundland, and one‐way chilling is not well developed. The mechanism of intrusion in the Coolac dyke complex therefore is probably not symmetrical spreading about a well defined axis, but a diffuse injection of small multiple dykes within a relatively broad extensional zone. The environment in which such a mechanism might develop, and which is suggested by geochemical evidence, including the high proportion of intermediate and felsic rocks, is that of a small basin adjacent to or within an island‐arc system.     

The origin of decoupled Hf-Nd isotope compositions in Eoarchean rocks from southern West Greenland

Radiogenic isotope compositions of Hf and Nd are typically coupled in Phanerozoic and Proterozoic mafic rocks due to a similar behaviour of Lu-Hf and Sm-Nd during mantle melting. Eoarchean rocks, for instance those from southern West Greenland, exhibit an apparent decoupling of Hf and Nd isotope compositions. This apparent decoupling may either indicate metamorphic disturbance or, alternatively, mirror early differentiation processes in the silicate Earth. To evaluate the issue, we performed combined measurements of Hf-Nd isotope compositions together with major and trace element concentrations for well preserved >3720 to >3800 Ma old tholeiitic metabasalts and gabbros from the ∼3700 Ma and ∼3800 Ma old terranes of the Isua Supracrustal Belt, southern West Greenland. In contrast to younger mafic rocks, calculated initial εHf-εNd values of the Isua tholeiites show similar spreads and are both near chondritic to strongly depleted (−0.7 to +6.3 and −0.8 to +4.4, respectively), also in contrast to previously reported more depleted signatures in nearby boninite-like metabasalts of the Garbenschiefer unit. An evaluation of alteration effects based on preserved major and trace element arrays reveals pristine magmatic trends and therefore the measured isotope compositions indeed in most cases characterize contrasting Eoarchean mantle sources. In accord with this view, compositions of the Isua metabasalts yield Eoarchean regression ages in Sm-Nd and Lu-Hf isochron spaces, overlapping with emplacement ages inferred from crosscutting relationships with tonalites. Lutetium-Hf systematics of the Isua metabasalts studied here, yield clear isochron relationships. For both terranes, there is some scatter in Sm-Nd space, indicating early disturbance of the Sm-Nd system close in time to the extrusion ages, possibly by seafloor alteration. Trace element compositions of the metabasalts indicate an arc setting and a strong source overprint by melt-like subduction components. It is likely, that the source overprint may have caused partial decoupling of the εHf-εNd values, due to selective addition of Nd as observed in modern subduction settings. In this case, the most radiogenic initial εNd and εHf isotope values characterize the most depleted mantle sources, and less radiogenic values would reflect increased contributions of isotopically more enriched subduction components. However, the most depleted samples still exhibit decoupled Hf-Nd compositions, making a case for the presence of even older mantle heterogeneities. A proposed superchondritic composition of the silicate Earth (SCHEM), however, cannot account for the most depleted sample compositions. Conversely, a depleted upper mantle formed by crystallization of perovskite-rich cumulates in the early Hadean may well explain these observed compositions. A literature survey reveals an overlap in initial Hf-Nd compositions between southern West Greenland TTGs and the metabasalts analyzed here. This overlap suggests a genetic relationship between these lithologies, where the TTGs may have inherited their unusual Hf-Nd compositions from mafic precursors isotopically similar in composition to the Isua tholeiites.     

Geochemistry of Caledonian metabasalts from some Norwegian ophiolite fragments

Major and trace element analyses of metabasalts from five of the Lower Palaeozoic Caledonian ophiolite fragments along a strike distance of some 800 km of the west Norwegian coast are presented. Characteristically the REE patterns show depletion of both LREE and HREE relative to intermediate REE, giving an upward convex shape, but nearly flat, LREE depleted or enriched patterns occur. The REE patterns of the metabasalts from three of these sequences, i.e. the Lykling, Solund and Stavfjorden ophiolite fragments show little within-sequence but large between-sequence variation. The REE patterns of the metabasalts from the Gullfjellet (Major Bergen Arc) and Skålvær ophiolite fragments, however, show significant within-sequence variations, indicative of local source heterogeneties.When incompatible trace elements such as Ta, Nb, Ce, P, Zr, Hf, Sm, Ti, Y and Yb are normalized against average MORB, the metabasalts can be subdivided into two major groups. One group, geographically comprising the ophiolite fragments north of Bergen (i.e. Solund, Stavfjorden og Skålvær) show trace element ratios similar to average MORB, whereas the other group, defined by the Gullfjellet and Lykling ophiolite fragments (from Bergen southwards) differ significantly with respect to Yb/Y, Ti/Y and Nb/Ce ratios. These features are discussed in terms of trace element patterns in basalts from oceanic islands, island arcs and back-arc basins, and it is tentatively concluded that they reflect partial melts from a mid-oceanic mantle, or probably a back-arc basin mantle, which differed chemically from that of the northwestern Norwegian ophiolite fragments.     

Middle to Late Ordovician age for the Jindalee Group of the Lachlan Fold Belt,New South Wales: Conodont evidence and some tectonic implications

The first definitive evidence for a late Middle to early Late Ordovician age for the Jindalee Group comes from identification of conodonts, including Periodon aculeatus, preserved in chert from an exposure northeast of Cootamundra, New South Wales. In the Grenfell area, the Hoskins Chert, a constituent formation of the Jindalee Group, also yields conodonts of the same general age, although no diagnostic species have been recognised. Conodonts found in the Jindalee Group, along with a distinctive fossil flora of probable cyanobacterial filaments, are similar to those of the Mugincoble Chert in the vicinity of Parkes. Age correlation of the Jindalee Group with the Girilambone Group is confirmed by the newly found conodonts, but at a much more precise level than previously inferred. However, the tectonic settings of the Jindalee and Girilambone Groups might have been quite distinct, with the Jindalee Group forming in an intra‐arc rift and the Girilambone Group depositing in the backarc Wagga Marginal Basin.     

SHRIMP U-Pb Zircon Dating of the Blueschists in the Heilongjiang High-pressure Metamorphic belt, NE China and its Tectonic Implications

The Heilongjiang complex is a sequence of high-pressure (HP) metamorphic rocks, locatated along the suture zone that separates the Jiamusi-Khanka and Shongliao-Zhangguangcai blocks in NE China. The lithologic association and major and trace element composition of the blueschist facies rocks indicate they were metabasalts. The trace element data show they are of OIB and E-MORB affinity, most likely intra-oeeanic basalts that formed at the western margin of the Jiamusi block. The sequences of the Heilongiiang complex mainly consist of the marie-ultramafie rocks, OIB and E-MORB affinity basalts and Radiolarian-bearing quartzite in protolith, most likely the subduction complex.     

Petroi Metabasalt: Alkaline within‐plate mafic rocks from the Nambucca Slate Belt,northeastern New South Wales

The Petroi Metabasalt comprises approximately 2000 m of massive and pillowed metabasalt flows, breccias, and metadolerite sills that overlie and are intercalated with Early Permian epiclastic rocks of the Nambucca Slate Belt. Both the basaltic rocks and associated sedimentary material were multiply deformed and metamorphosed to pumpellyite‐actinolite facies grade at about 255 Ma. Metamorphism and earlier sea‐floor alteration of these mafic rocks have led to hydration, carbonation and oxidation and considerable redistribution of the major elements and the more labile traces, notably Rb, Ba and Sr. However, abundances of TiO₂, the high field strength trace elements, Ni, Cr and V, the light rare earths and yttrium are interpretable as being the largely unmodified magmatic abundances of mildly alkaline within‐plate basalts. This interpretation is supported by the composition of relic Ca‐rich pyroxenes in the metadolerites which fall in the fields of mildly alkaline basalts. The field relationships, age and composition of these rocks suggest either eruption on oceanic crust covered by a thick sequence of epiclastic rocks and subsequent incorporation into an accretionary subduction complex, or generation during rifting of the eastern part of the New England Fold Belt and accumulation, together with the associated sedimentary rocks, in a graben. The chemical and mineral characteristics of the igneous rocks indicate that the volcanism was not related to magmatic arc activity, and their presence demonstrates the rocks of the Nambucca Slate Belt are neither fore‐arc basin nor slope‐basin deposits.     

Trace fossil evidence from the Adigrat Sandstone for an Ordovician glaciation in Eritrea, NE Africa

Trace fossils are described here from the Adigrat Sandstone formation of hitherto uncertain Palaeozoic-Mesozoic age in south-central Eritrea. The formation is subdivided into a lower unit, the Adi MaEkheno Member, and an upper informal unit, Member 2. The formation was deposited on the locally mudcracked top of the glacigenic Edaga Arbi Beds, suggesting that these two rock units were formed in a very short time interval. The Adi MaEkheno Member and the lower part of Member 2 contain trace fossils Arthrophycus alleghaniensis (Harlan), Arthrophycus ?brongniartii (Harlan), Didymaulichnus lyelli (Rouault), Palaeophycus tubularis Hall, Taenidium isp., thin winding ridges, winding ridges and furrows, simple cylinders, and ‘stellate’ forms. A. alleghaniensis is distinctively of Ordovician–Silurian (?Early Devonian) age. The trace fossil association belongs to the Cruziana ichnofacies that indicates a shallow marine environment between the normal and storm wave bases. The trace fossil data and stratigraphic relationships indicate that the Adigrat Sandstone formation and the Edaga Arbi Beds in Eritrea are Ordovician–Silurian in age. The Edaga Arbi Beds are correlated with other Upper Ordovician (Hirnantian) glacial units in northern Africa and the Arabian Peninsula, lending these beds the status of a marker unit in the Lower Palaeozoic stratigraphy of the Horn of Africa. The Jurassic “Adigrat Sandstone” in central-west and eastern Ethiopia cannot be correlated with the Adigrat Sandstone formation in its type area and in Eritrea.     

Geochemical and stratigraphic evidence against an oceanic crust interpretation for the Tumut ‘greenstone’ occurrence

Evidence is presented to show that the Tumut ‘greenstone’ occurrence is unlikely to be an example of Palaeozoic oceanic crust. First, new rare‐earth element analyses are unlike those obtained from oceanic tholeiites. Second, the published major‐ and trace‐element analyses of the metabasalts are not definitive of an oceanic magma type. Third, the juxtaposition of mafic volcanic rocks and ultramafic intrusives is not considered to be diagnostic of an oceanic crustal section. Fourth, the sulphide mineralization is not similar to that found in typical ophiolites such as those at Troodos in Cyprus.

In the light of the presently available data the basalts could have formed in a variety of environments including island‐arc, continental‐marginal or continental.     

Assessing the origin of old apparent ages derived by Pb stepwise leaching of vein-hosted epidote from Mount Isa,northwest Queensland,Australia

Epidote metasomatism affected large areas of tholeiitic metabasalts of the ~1,780 Ma Eastern Creek Volcanics in the Western Fold Belt of the Proterozoic Mount Isa inlier. Hydrothermal epidote generally occurs in quartz veins parallel to or boudinaged within the dominant S₂ fabrics which formed during the regional metamorphic peak at ~1,570 Ma associated with the Isan orogeny. Previously published stable isotopic and halogen data suggest that the fluids responsible for epidote formation are metamorphic in origin (with an evaporitic component). Application of the Pb stepwise leaching technique to the epidote does not separate radiogenic Pb⁴⁺ and common Pb²⁺, generating little spread in ²⁰⁶Pb/²⁰⁴Pb (between 16.0 and 30.5). The causes for this relatively low range are twofold: There is little radiogenic Pb in the epidotes (the most radiogenic steps account for <1 % of Pb released) and both Pb²⁺ and uranogenic Pb⁴⁺ substitute into the same site in the epidote crystal lattice. Consequently, age regressions using the Pb stepwise leaching data give ages between 150 and 1,500 myrs older than the host rocks and over 450 myrs older than the thermal metamorphic peak. These old ages are attributed to chemical inheritance from the host metabasalts, via radiogenic Pb release by breakdown of phases such as zircon, monazite, titanomagnetite, and ilmenite during metamorphism. This idea is supported by trace element data and chrondrite-normalized rare earth element patterns that are similar to both the metabasalts and epidotes (except for a variable Eu anomaly in the latter). Relatively high fO₂ during vein formation (Fe³⁺ dominates in the epidote crystal lattice) would allow the incorporation of Th⁴⁺ and exclusion of U⁶⁺ and would explain elevated Th/U ratios (up to 12) in epidote compared with the host metabasalts. Non-incorporation of U would explain the relatively low U/Pb ratios and non-radiogenic character of the epidote. This process may provide a source of metal for the small U deposits around Mount Isa and may also suggest a relationship between U mineralization and regional Cu mobilization during the Isan orogeny. Our work suggests that non-conventional geochronometers should be used only if additional geological information and geochemical data (e.g., mineral chemistry, trace elements) are available to evaluate any resulting age calculations.     

Geochemical discrimination of metabasalt rocks of the Fan–Karategin transitional blueschist/greenschist belt, South Tianshan, Tajikistan: seamount volcanism and accretionary tectonics

The Fan–Karategin metamorphic belt, South Tianshan, Tajikistan, is regarded to be an ancient subduction–accretionary complex and is composed of three tectonostratigraphic units which display lithologies consistent with different tectonic settings. The mafic schists, which make up the major part of the older unit of the belt, contain both alkali and tholeiitic metabasalts. On the basis of rare-earth and other immobile element characteristics, the alkali metabasalts are akin to within-plate ocean island basalts, whereas the tholeiitic metabasalts resemble E-type MORB. The association is interpreted to have been formed on seamount-like structures under a within-plate plume. Bedded cherts and marbles in the unit are regarded as ancient pelagic sediments and carbonate caps developed upon basaltic seamounts, respectively. Dismemberment of the seamount-related basalts and pelagic sediments and the high-P/low-T prograde metamorphism of the unit rocks up to transitional blueschist/greenschist facies was the result of paleoseamount submergence into a subduction zone. This unit is tectonically overlain by arc-derived metavolcanic unit and a disrupted, mainly clastic unit of Upper Ordovician–Lower Silurian age. Metavolcanic and metasedimentary rocks of the two upper units have geochemical characteristics compatible with subduction-related origin. The lithological assemblages of the individual units and their juxtaposition suggest an origin involving collision–accretionary processes. The Fan–Karategin belt is a subduction–accretionary complex which formed during subduction of oceanic crust under a volcanic arc and was subjected to tectonic juxtaposition and imbrication of seamount, deep-sea, trench and volcanic arc sequences.     

Stratigraphic subdivision and correlation of the upper part of the Willyama Complex,New South Wales

Within the complexly deformed and metamorphosed middle Precambrian Willyama Complex in western New South Wales, two distinct sedimentary sequences are recognized at the top of the succession. The fine‐grained carbonaceous Bijerkerno Beds conformably overlie a very thick psammopelitic unit termed the Wookookaroo Beds. These two sequences record different depositional histories, though they probably have similar source areas. The base of the Wookookaroo Beds is terminated against a significant tectono‐stratigraphic boundary, which may represent a major stratigraphic break within the Willyama Complex. Beneath this boundary, felsic and mafic gneisses and high‐grade metasediments are correlated with mine‐sequence rocks such as are developed within the vicinity of the main Broken Hill lode. Correlations between the stratigraphy, as established at Bijerkerno, and other areas from the Willyama Complex, help provide a fuller understanding of this Precambrian terrain.     

Structure and tectonic history of the Brisbane metamorphics in the Brisbane area

The Palaeozoic basement rocks of the Brisbane area have undergone three major deformations and a minor kinking episode. The central zone of Bunya Phyllite is dominated by a second‐generation transposition layering whereas the flanking Neranleigh‐Fernvale Beds are dominated by first‐generation transposition structures.

The major structure previously described in the area, the Indooroopilly Anticline, is an apparent antiform formed in part by the intersection of dominant first‐ and second‐generation structures and in part by a major third‐generation flxeure. The complete geometry of the first‐generation layering across the structure is suggested using vergence relationships but the stratigraphic relations and the structure of the stratigraphic boundaries are virtually impossible to deduce. Two possibilities are suggested and a major conclusion is that the Bunya Phyllite may be merely a unit within the Neranleigh‐Fernvale Beds.

The first‐generation deformation is a regional event whose effects can be traced north for some 500 km whereas the second‐ and third‐generation structures are more restricted. There is evidence to suggest that all three generations may be related to the same tectonic event, possibly Carboniferous in age.     

Palaeosols in the Reading Beds (Paleocene) of Alum Bay, Isle of Wight, U.K.

Fossil soils occur in the Reading Beds of Alum Bay. All soils have hydromorphic characteristics, caused by either groundwater or stagnating pluvial water; some have illuviation of clay. The combination of bioturbation (striated burrows) and iron segregation may indicate that the Reading Beds in Alum Bay are of fluviomarine origin. The soils were formed in a warm climate with a marked dry season. They indicate a landscape with minor variations in surface level. The Reading Beds have clay mineral assemblages that are partly inherited and partly changed by soil formation. Some soil horizons might be used for stratigraphic correlation.     

变质玄武岩体系相平衡及矿物 熔体微量元素分配：限定TTG/埃达克岩形成条件和大陆壳生长模型

埃达克质岩石是高Na、Al和Sr、低Y和HREE以及Nb、Ta亏损的钠质花岗质岩石,奥长花岗岩-英云闪长岩-花岗闪长岩(TTG)是早期(太古宙)大陆壳主要组分,成分与埃达克质岩石相似,这些成分独特的岩石总体上认为是俯冲洋壳、下地壳和拆沉的下地壳中变质玄武岩部分熔融的产物。文中综述我们近年来在变质玄武岩体系相平衡和矿物-熔体微量元素分配实验研究成果:相平衡实验和熔体微量元素特征研究表明,变质玄武岩部分熔融过程中金红石是导致TTG/埃达克岩浆Nb、Ta亏损的必要残留矿物,从而否定了前人“TTG由无金红石的角闪岩熔融产生”的观点;证实金红石仅仅在压力1.5GPa以上才能稳定存在,从而限定TTG/埃达克岩熔体必定产生在大约50km以上,表明TTG/埃达克岩是在相对较深的含金红石榴辉岩相条件下熔融产生的。矿物(石榴子石、角闪石,单斜辉石和金红石)-熔体微量元素分配系数测定和部分熔融模拟结果进一步限定俯冲洋壳和下地壳起源的TTG/埃达克岩浆由含金红石角闪榴辉岩熔融产生,而拆沉下地壳起源的埃达克岩浆的产生要求软流圈地幔高温,由无水或含有少量含水矿物的榴辉岩熔融产生。     

Neoproterozoic contaminated MORB of Wadi Ghadir ophiolite,NE Africa: Geochemical and Nd and Sr isotopic constraints

The ophiolitic metabasalts (pillowed and sheeted dikes) of Wadi Ghadir area, Eastern Desert, Egypt, were analyzed for their major, trace and rare earth elements, Nd and Sr isotopes and the chemistry of their plagioclase, amphibole and chlorite was also reported. Geochemically these rocks range from tholeiitic basalt to basaltic andesite. The generally low MgO, Cr and Ni and high Zr contents are consistent with derivation of these rocks from an evolved magma. The high TiO₂ contents (mostly between 1.76% and 2.23%) classify Wadi Ghadir ophiolitic metabasalts as MORB ophiolite. The chondrite-normalized REE patterns of most samples display small LREE-enrichment with (La/Yb)_n ranging from 1.44 to 2.56. The MORB-normalized spider diagram shows variable LILE abundances, which are either similar to or enriched relative to MORB, and most samples display small Nb depletion. The abundances of some LILE (Ba, Rb and K) as well as Na and Si were modified by post-magmatic seafloor hydrothermal alteration. Enrichment of the least mobile LILE (Th & U) indicates that Wadi Ghadir ophiolitic metabasalts are akin to C (contaminated)-MORB. These geochemical characteristics are similar to BABB modified by contamination.Wadi Ghadir metabasalts have low initial Sr ratios (0.7010–0.7034) which are similar to those of MORB, while their ε_Nd(t) values (+7.7–+4.5) are either more or less positive than the value of depleted mantle (DM). The more positive ε_Nd(t) values indicate DM source for these basalts, while the less positive ε_Nd(t) values reflect the involvement of slightly older component in Wadi Ghadir ophiolite. We suggest that the parent magma of metabasalts was contaminated by slightly older material, most probably oceanic-arc crustal rocks, which caused enrichment in LREE, and by analogy LILE, but did not significantly affect Nd isotopic systematics or modify Sr isotopes.Such contaminated MORB character also revealed by other ophiolitic metavolcanics in the Central Eastern Desert, contrasting the N-MORB character of the Gerf ophiolite in the South Eastern Desert. Moreover, the present work suggests the increase of the degree of contamination of the ophiolitic metabasalts from south to north in the Central Eastern Desert.     

Early Silurian tholeiitic-boninitic Mailisu ophiolite,South Tianshan,Kyrgyzstan: a geochemical record of subduction initiation

ABSTRACT

Ophiolite assemblages of the South Tianshan fold-and-thrust-belt (STS) track the sea floor dynamics of the late Cambrian to Carboniferous Turkestan Ocean in the western Central Asian Orogenic Belt. We interpret new geochronological and geochemical data for the Mailisu ophiolite from western Kyrgyzstan as evidence for an early Silurian incipient subduction zone outboard the South Chatkal Arc of the Middle Tianshan. Igneous zircons from a leucogabbro yielded a U-Pb age of 440 ± 6 Ma indicating one of the oldest sea floor fragments in the STS. Metabasalt samples have N- to E-MORB trace element patterns and initial ε_Nd values of ~5 to 9 support melting of depleted asthenosphere comprising a minor OIB component. Cross-cutting diabase dykes show geochemical characteristics of high-Ca basaltic boninites. Their low REE abundances and highly fractionated middle-heavy REE patterns indicate sources that were more melt-depleted than those of the metabasalts. Concave upwards LREE patterns are compatible with a residual peridotite source, fertilised by small-degree OIB-like melts with ε_Nd of ~5 to 6. Positive Ba, Sr, and Pb anomalies support the involvement of slab-derived hydrous fluids that probably facilitated the melting of the residual mantle. The association of MORB-like metabasalts with younger dykes of boninite affinity suggests subduction initiation for the origin of the Mailisu ophiolite. Our data elucidate one of the major yet little understood episodes in the Paleozoic history of the Turkestan Ocean. Future identification of similar rock assemblages will be helpful to understand the insufficiently constrained history of ocean floor subduction in the Paleozoic Oceans of the western CAOB.