云南墨江镍金矿床主要控矿因素分析与研究

采用控矿因素分析研究，通过构造岩石地层及构造变形筛分探讨镍金矿床的成矿过程，认为本区金镍矿主要为地层及构造控矿。在矿床内，热（泉）水喷溢构造（成矿构造）有似环状粘土岩化带及热水同生沉积－交代－喷流构造岩石层序，脆－韧性剪切带（储矿构造）由近水平的纵张裂隙构造、左行共轭剪切裂隙及相对封闭的脆韧性剪切带组成。脆性张剪性X形微裂隙系统为富金矿脉的定位提供了构造空间。成矿演化过程为：①晚泥盆世热水同生沉积成岩成矿期形成含金黄铁矿硅质岩；②印支期逆冲推覆型脆韧性剪切构造成岩成矿期形成含金脆韧性剪切带；③燕山－喜马拉雅山期深源热流体叠加成矿期形成富金矿脉。指出3处成矿远景区，认为红土型金矿很可能是本区一种新的金矿类型，值得重视研究。     

陕西凤太拉分盆地构造变形样式与动力学及金-多金属成矿

陆-陆斜向碰撞过程中形成的拉分盆地及构造变形史、变形样式及动力学、流体大规模运移与构造岩相学记录等是值得重视的大陆动力学问题,也有助于对西秦岭卡林型-类卡林型金矿和多金属矿成矿规律的深入研究.西秦岭陕西凤县—太白县晚古生代拉分盆地是热水沉积-改造型多金属矿床和金矿集中区.本文采用构造-岩相学研究方法,对该拉分盆地的构造-热流体变形历史、变形样式及动力学、盆地流体驱动力等进行了研究,认为该拉分盆地构造变形史复杂,构造变形序列为:(1)石炭纪—中三叠世构造反转与热流体叠加改造期(DS1).(2)印支期陆-陆全面斜向碰撞挤压体制下拉分盆地发生挤压收缩变形、断裂-褶皱作用、岩浆侵位形成热叠加改造和脆韧性剪切变形(DS2).(3)燕山期陆内造山期构造断陷、岩浆侵位形成热叠加改造与脆性变形(DS3).石炭纪—中三叠世反转构造样式为泥盆系发生分层剪切流变构造、热流体角砾岩化叠加构造岩相和南部温江寺—留凤关拉分断陷盆地.印支期—燕山期,该盆地内部构造变形样式有复式褶皱与压扭性断裂构造、脆韧性剪切带、逆冲推覆构造、反冲构造与冲起构造.在该盆地南北缘形成了对冲式逆冲推覆构造.盆地流体运移受构造变形驱动,在该盆地东部,印支期西坝复式中-酸性岩浆侵入提供了区域性热流体叠加改造的稳定热源场.研究认为“M-W”型复式背斜和断裂带控制了多金属矿床后期改造富集和矿体定位.反冲构造与冲起构造控制了金矿和多金属成矿分带.“W-M”型复式向斜和脆韧性断裂带控制了卡林型-类卡林型金矿的形成,其中,倒转向斜和脆韧性剪切带对于八卦庙类卡林型金矿多期多阶段富集成矿具有显著控制作用,温江寺卡林型金矿受复式向斜和脆性断裂带控制.     

陕川丁家林-太阳坪金矿带成矿机理

丁家林-太阳坪金矿带与丁家林-太阳坪脆-韧性剪切带同位分布、同能源作用、同步生成，是脆-韧性剪切变形形成的石英脉型金矿，总体走向NE，主要由丁家林和太阳坪2个金矿床组成，分石英单脉、单脉密集带、复脉带3个亚型。丁家林以含Au石英复脉为主，太阳坪以含Au石英单脉为主；成矿物质来源于富含Si质的志留系黄坪组，成矿流体主要是构造水；内生成矿作用分脆．韧性剪切变形-构造分异热液期和韧-脆性剪切变形-构造分异热液期，与2期脆-韧性剪切变形相对应，第2期为主成矿期。其成矿机理是脆-韧性剪切变形动力成岩成矿。     

燕山期构造—热事件演化与小秦岭金矿床的形成

本文以小秦岭金矿床的基本地质特征为基础，分析了燕山期构造－热事件的演化规律及其与花岗岩、韧性剪切带和金矿床的关系。认为花岗岩是构造－热事件高峰期地壳深部物质部分熔融的产物，区域性热异常的出现则导致地壳浅部形成了韧性剪切带。构造－热事件晚期，随着热异常的衰减，剪切带的变形性质发生转化并有序叠加，金矿床便是在这一变形性质转化与叠加过程中，在成矿流体演化的晚期形成的。花岗岩侵位在局部造成横向上显著的物理     

陕西凤县八卦庙金矿床成矿地质特征及外围找矿前景分析

阐述了八卦庙金矿床经历了长期、复杂的非线性成矿过程，着重分析了：含矿建造为与同生伸展断裂伴生的海底喷流热水沉积岩、热水浊积碎屑岩；脆-韧性剪切构造控制着主成矿过程；后期幔源岩浆气液叠加富集使其成为超大型金矿床。指出矿床成因为热水同生沉积细碎屑岩-剪切蚀变岩-幔源岩浆气液叠加富集型。八卦庙金矿床外围仍有巨大的找矿前景。     

韧性剪切带及其控矿作用——以新疆康古尔金矿为例

康古尔金矿具有独特的成矿地质特征,矿床位于石炭系火山岩区大型韧性剪切带的次级构造中.控矿构造表现为脆韧性剪切活动的特点,该脆韧性剪切带在成矿期的活动具有中低温、高应变速率、高差异应力的动力学特征.金矿床的分布受脆韧性剪切带控制,矿体由蚀变千糜岩和糜棱岩化火山岩中矿化富集地段组成,矿体产状平行于糜棱岩面理.矿化产于脆韧性变形强烈部位,脆性变形叠加有利于形成富金矿.     

燕山期构造－热事件演化与小秦岭金矿床的形成

本文以小秦岭金矿床的基本地质特征为基础，分析了燕山期构造－热事件的演化规律及其与花岗岩、韧性剪切带和金矿床的关系．认为花岗岩是构造－热事件高峰期地壳深部物质部分熔融的产物，区域性热异常的出现则导致地壳浅部形成了韧性剪切带．构造－热事件晚期，随着热异常的衰减，剪切带的变形性质发生转化并有序叠加，金矿床便是在这一变形性质转化与叠加过程中，在成矿流体演化的晚期形成的．花岗岩侵位在局部造成横向上显著的物理化学梯度，是大量金矿床在其周围呈规律性展市的主要原因．     

内蒙古哈达门沟金矿构造演化及成矿控矿构造特征

哈达门沟金矿是内蒙古迄今最大的金矿床,具有超大型金矿床规模。金的成矿作用对岩性没有明确的选择性,而主要是受褶皱断裂构造的控制。成矿流体主要来自深源,在有利的构造扩容带中聚积成矿。研究表明,该区的构造变形从早到晚,力学性质往往从塑性到脆性,构造规模从小到大,构造类型则是褶皱与剪切带同时形成,或相间发育。该区主要经历了4个期次的强烈褶皱剪切作用,并形成了主要的成矿控矿构造。第一期构造变形时岩石的流变性较强,褶皱幅度较小,一般多表现为小规模的塑性流变褶皱,并产生了小规模韧性剪切带;第二期(主期)褶皱以乌拉山主峰为主的东西向区域规模的复式背、向斜(形),并在主期褶皱的倒转翼发育了一系列与褶皱同向延伸的脆韧性剪切带,它们构成了区域性构造薄弱带;第三期为横跨叠加褶皱,使近东西向褶皱发生了南北向蛇形弯曲,伴随该期褶皱作用形成了低绿片岩相韧脆性剪切带,为深源成矿流体的贯入与集聚成矿提供了很好的赋存空间,是主要的成矿控矿构造;第四期构造变形则以区域性隆升作用为主,使早期褶皱发生横弯褶皱的同时,还将深部形成的金矿体抬升至浅部。文中在成矿控矿构造研究的基础上,探讨了矿床成矿规律,提出了找矿远景。     

韧性剪切带及其控矿作用：以新疆康古尔金矿为例

康古尔金矿上有独特的成矿地质特征,矿床位于石炭系火山岩区大型韧性剪切带的次级构造中,控矿构造表现为脆韧性剪切活动的特点,该脆韧性剪切带在成矿期的活动具有中低温,高应变速率,高差异应力的动力学特征,金矿床的分布受脆韧性剪切带控制,矿体由蚀变千糜岩和糜棱岩化火山岩中矿化富集地段组成,矿体产状平行于糜棱岩面理。矿化产于脆韧性变形强烈部位,脆性变形叠加有利于形成富金矿。     

云南墨江含金脆—韧剪切构造带中显微构造的矿物地球化学研究

墨江－元江镍金矿床是哀牢山构造－成矿带上一个十分典型和重要的矿床，在野外实测构造岩石地层层序、矿物学详细填图的基础上，采用X射线粉晶衍射分析、扫描电镜、电子探针微区分析及矿物－构造－地球化学等方法，对墨江镍金矿床中含金脆－韧性剪切构造带的物质组成进行详细研究。显微构造的矿物地球化学研究是一种构造筛分新方法。脆性构造主要表现为含镍金石英脉－硅质岩－黄铁矿硅质岩中普遍发育碎裂岩化及裂隙，碎裂岩化－裂隙构造是深源热流体叠加成矿的储矿构造和运移上升通道，脆性剪切变形过程中伴有粘土化蚀变，粘土矿物主要有铬水云母、铬高岭石、多水铬高岭石、绿铬高岭石、铬蒙脱石、铬迪开石、铬埃洛石和绿鳞石等。在含金脆－韧剪切构造带中，铬绢云母－铬水云母－铬伊利石系列和铬绿泥石的矿物具（脆）韧剪切变形特征，在韧剪切变形过程中伴有强烈的热流体以及H2O为主要组分的矿化剂作用。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.