兴化湾表层海水氮磷营养盐含量的时空变化及富营养化状况

根据福建兴化湾海域2006年12月（冬季）和2007年4月（春季）的水质监测资料,分析了表层海水无机氮和活性磷酸盐含量的时空变化特征,并对该海域表层水体的富营养化状况进行了评价.结果表明,冬、春两季,兴化湾表层海水无机氮含量的变化范围分别为0.30~1.30、0.34~1.10mg/dm3,均值分别为0.50、0.54 mg/dm3;无机氮的单项污染指数变化范围分别为1.0~4.2、1.1~3.7,均值分别为1.7和1.8.冬、春两季,其海水活性磷酸盐含量的变化范围分别为0.024~0.085、0.016~0.148 mg/dm3,均值分别为0.040、0.038 mg/dm3;其单项污染指数变化范围分别为0.8~2.8、0.5~4.9,均值则都为1.3.其次,该湾表层海水无机氮和活性磷酸盐含量的空间分布特征为西侧近岸水域的较高,往湾口方向递减.冬、春两季兴化湾表层海水富营养化指数（E值）分别为3.53和4.26,基本呈现富营养状态;富营养化严重的区域主要位于兴化湾西南部,其E值最高达29.9.     

论东营市海洋环境保护的对策

一、东营市毗邻海域海洋环境质量现状 2007年监测数据表明,东营市近岸海域主要以清洁海域和较清洁海域为主.主要污染物为无机氮、活性磷酸盐和石油类.沉积物质量总体良好,综合潜在生态风险较低.     

罗源湾水质评价与富营养化研究

根据2009年7月对罗源湾的调查数据,对罗源湾水质和富营养化进行研究。结果表明:罗源湾海域营养盐含量较高:无机氮均值为0.30 mg/L,活性磷酸盐均值为0.07 mg/L;总体来看,湾北部高于南部,高值多分布于近岸区域。富营养化分级评价表明该海域处于氮限制性富营养化阶段。通过对近30 a的历史文献进行研究,对罗源湾海域富营养化的长期变化趋势进行了探讨。     

苏北灌河口邻近海域氮、磷污染物环境容量研究

本文基于苏北灌河口近岸海域三维水质模型,按照江苏省海洋功能区划的水质要求,采用自净过程积分方法,计算了氮和磷营养盐的环境容量。结果表明,研究海域无机氮和活性磷酸盐年海洋环境容量分别约为6 000和6 00t/a,具有明显季节变化特征,夏季最高,环境容量分别约为2 900和260t,其次是春季,分别约为1 400和140t,冬季和秋季最低,分别平均约为1 000和90t。对比分析现状污染负荷,研究海域无机氮、活性磷酸盐总量削减率分别相当于当前无机氮、活性磷酸盐入海负荷的55%、73%以上,研究结果可为江苏省北部灌河口沿海城市陆源污染物总量控制提供科学依据。     

夏冬季三沙湾海水营养盐含量的时空变化特征及与环境因子的相关性

根据2012年8月和2013年1月对三沙湾海域开展的海域水质现场连续调查数据,阐述了无机氮和活性磷酸盐含量时空变化特征及其与环境因子的相关性.结果表明,三沙湾海域夏冬季无机氮含量范围分别为0.059～1.669、0.569～0.940 mg/dm^3,均值为0.582、0.676 mg/dm^3,活性磷酸盐含量范围分别为0.036～0.071、0.050～0.070 mg/dm^3,均值为0.056、0.060 mg/dm^3.无机氮和活性磷酸盐含量的高值区出现在陆源径流入海区及大量网箱养殖区,总体呈湾顶向湾口递减趋势,氮磷含量表层高于底层,冬季高于夏季,大部分海域都超过第四类海水水质标准.根据CN/CP比值评价结果显示,三沙湾大部分海域浮游植物的生长为氮限制.相关性分析表明,三沙湾海域无机氮与硝酸盐含量相关性极显著（r=0.989）,表明硝酸盐是无机氮的主要存在形态;无机氮还与盐度（r=-0.923）和温度（r=0.939）有极显著的相关性,论证了沿岸径流对三沙湾营养盐的输入有重要影响.活性磷酸盐与铵盐、亚硝酸盐含量存在显著的正相关.本次调研结果为三沙湾海域富营养化研究提供基础数据.     

春、夏季惠州市海水环境质量及其有机污染评价

为加强惠州市海洋生态环境保护工作,并为其提供科学依据,文章利用2016年春季和夏季惠州市海洋环境综合调查数据,选取溶解氧、化学需氧量、无机氮和活性磷酸盐4个环境因子,分析其近岸海域和海洋基本功能区的海水环境质量,并评价海水有机污染状况。研究结果表明:春季近岸海域海水环境质量优于夏季,无机氮和活性磷酸盐为主要超标因子;港口航运区海水环境质量良好,其他功能区均有环境因子超标现象;近岸海域受到有机污染,旅游休闲娱乐区在2个季节均受到有机污染;海水环境尚未对海洋生物产生影响。     

综合空间相关性和区域分异性方法的上海海洋环境监测站位优化

综合无机氮和活性磷酸盐的海水水质类别现状进行空间分区,拟合无机氮和活性磷酸盐全局半变异函数和局部半变异函数。通过留一交叉检验方法确定统计推断方法,无机氮采用分层克里金插值方法,使得平均绝对误差和误差方差最小;活性磷酸盐采用普通克里金插值方法,使得平均绝对误差和误差方差最小。原则上调整现有站位数的10%,综合考虑对无机氮和活性磷酸盐插值标准差的变化影响,以及对不同水质类别面积的影响,确定去掉冗余的7个历史站位。7个站位均分布在劣四类水区域的长江口南支、北支、和杭州湾北部近岸区域,这些区域站点密集,水体中各要素含量变化不大,水团混合较均匀。优化删减掉的7个站位调整到三类和四类水质分区中,或者无限制区域的优化调整,发现调整优化的站位主要分布在水质类别变化过渡的区域,因此,不同水质类别的分界带以及海域边界处是站位调整优化的关键区域。     

中国近海的环境质量评价

中国近岸海域水质中溶解氧、化学需氧量、活性磷酸盐、无机氮、汞、铅、镉、石油类等8项评价因子均有超过一类海水水质标准的测值,其中活性磷酸盐、无机氮、铅的超标率分别为66％,62％,57％。主要污染指标是无机氮、活性磷酸盐、铅、汞,污染指数分别为3．12,2．46,2．18,2.10。     

辽宁近岸海域水质演化及对近海陆域生态水文格局的响应

根据1991-2000年对辽宁省近岸海域水质的连续监测资料,采用秩相关系数法对辽宁近岸海域水质做了定量评估,结果表明,辽宁省近岸海域海水水质较差,主要污染物为无机氮、活性磷酸盐、石油类和Pb,2000年全省近海海域各类功能区水质总达标率仅为48．1％。秩相关系数趋势预测表明：除COD有下降趋势外,其他主要污染物均有逐年上升趋势,且无机氮的上升趋势最为显著。辽宁省在沿海改革开放的初期,沿海海域的水环境做出了相当大的牺牲：20世纪90年代的中后期水质有了明显的改善,陆域非点源污染对近岸海域水质污染的贡献较大;各主要污染物在各海域的变化不同。生物学指标整体上显示,大连海域和营口海域水质在枯水期要好于丰水期,表现出明显的季节变化。无机氮与石油类和COD呈现出正相关关系,COD与石汕类、活悱磷酸盐和Pb呈现出弱正相关关系,水质PCA结果进一步表明辽宁近海海域水质污染除工业污染外,近海陆域非点源污染对水质污染的贡献最大。生态水文参数的主成分分析(PCA)及与主要污染物的回归分析结果表明,近海海域水质演化受到近海陆域生态水文过程的影响较大,无机氮受到近海陆地水开发影响最大;活性磷酸盐、石油类受到水文过程因子的影响最大;COD和Pb受到农业开发活动的影响最大。建议在辽宁省海水质综合整治的过程中,要加强对近海陆域生态水文过程的调节,实施海陆一体化的综合治理模式。     

厦门海域水体无机氮和活性磷酸盐含量的变化趋势

根据2003～2008年每年丰水期、枯水期和平水期于厦门海域开展的海洋环境调查的资料,研究了该海域水体无机氮和活性磷酸盐含量区域分布和时间变化趋势.结果表明,调查期间该海域水体无机氮和活性磷酸盐平均含量都较高,分别为0.50、0.031 mg/dm^3.其营养盐含量的区域分布相差较大,其中九龙江口水体无机氮含量最高,年均含量为0.52～1.37 mg/dm^3;厦门西港水体活性磷酸盐含量最高,年均含量为0.039～0.061 mg/dm^3;而大嶝海域水体无机氮和活性磷酸盐含量最低,年均含量分别为0.06～0.22、0.007～0.016 mg/dm^3.调查期间全海域水体无机氮含量呈逐年增加趋势,活性磷酸盐含量在2003～2005年间呈上升趋势,而2005～2008年则有小幅度的下降.厦门海域水体N/P原子比较高,调查期间全海域年均值为27.4～47.5,且呈逐年增加趋势.无机氮含量的明显增加趋势及越来越严重的N/P比失衡,势必对该海域海洋生态系统尤其是浮游植物群落演替产生不良影响.此外,研究还发现厦门海域水体无机氮含量与盐度呈高度负相关（r=-0.96,n=30）.这有力地证明了九龙江径流输入是厦门海域无机氮的最主要来源.     

Coastal Mediterranean plankton stimulation dynamics through a dust storm event: An experimental simulation

An enhancement of aeolian inputs to the ocean due to a future increase in aridity in certain parts of the world is predicted from global change. We conducted an experimental simulation to assess the biological response of NW Mediterranean coastal surface waters to an episodic dust addition. On the assumption that planktonic growth was limited by phosphorus, dust effects were compared to those induced by equivalent enrichments of phosphate. The experiment analyzed the dynamics of several parameters during one week: inorganic nutrients, total and fractioned chlorophyll a, bacterial abundance, phytoplankton species composition, abundance of autotrophic and heterotrophic flagellates, particulate organic carbon and particulate organic nitrogen. The maximum addition of dust (0.5 g dust L⁻¹) initiated an increase in bacterial abundance. After 48 h, bacterial numbers decreased due to a peak in heterotrophic flagellates and a significant growth of autotrophic organisms, mainly nanoflagellates but also diatoms, was observed. Conversely, lower inputs of dust (0.05 g dust L⁻¹) and phosphate enrichments (0.5 μmol PO₄³⁻ L⁻¹) only produced increases in phototrophic nanoflagellates. In our experiment, dust triggered bacterial growth, changed phytoplankton dynamics and affected the ratio of autotrophic to heterotrophic biomass, adding to the variability in the sources that affect system dynamics, energy and carbon budgets and ultimately higher trophic levels of the coastal marine food web.     

珠江口海域春季富营养化现状与影响分析

随着珠江三角洲经济圈的迅速发展,珠江口海域环境污染日趋严重,于2014年春季对珠江口邻近海域进行环境现状调查,并通过因子分析法和聚类分析法就珠江口调查海域管辖城市和邻近区域的环境现状对珠江口海域环境污染的贡献率进行排序和分类.结果表明:珠江口调查海域营养盐污染较为严重,无机氮含量范围为0.213~1.963 mg/dm~3,平均值为0.888 mg/dm~3;活性磷酸盐含量范围为0.009~0.063 mg/dm~3,平均值为0.033 mg/dm~3.无机氮和活性磷酸盐在珠江口上游和中游均超过海水水质第四类标准,珠江口下游无机氮含量符合海水水质第四类标准,活性磷酸盐含量符合海水水质第二类标准.无机氮以硝氮为主,氨氮次之,亚硝氮含量最低.珠江口调查海域DIN/P变化范围为8.5~168.0,平均值为31.8;富营养化指数E变化范围为0.3~45.1,平均值为8.2,富营养化较为严重.来自广州、东莞、佛山、中山的四大口门排入的污染物对珠江口海域环境影响最大,其次是深圳西部海域沿岸和前海湾、深圳湾排入的污染物,最后是珠海、澳门和香港带入的污染物.从珠江口邻近海域环境现状对珠江口海域环境影响进行较为深入地分析和探讨,为珠江口海域环境的治理和修复提供一些意见和建议.     

Photochemical production of ammonium and transformation of dissolved organic matter in the Baltic Sea

The release of ammonium from the photochemical degradation of dissolved organic matter (DOM) has been proposed by earlier studies as a potentially important remineralisation pathway for refractory organic nitrogen. In this study the photochemical production of ammonium from Baltic Sea DOM was assessed in the laboratory. Filtered samples from the Bothnian Bay, the Gulf of Finland and the Arkona Sea were exposed to UVA light at environmentally relevant levels, and the developments in ammonium concentrations, light absorption, fluorescence and molecular size distribution were followed. The exposures resulted in a decrease in DOM absorption and loss of the larger sized fraction of DOM. Analysis of the fluorescence properties of DOM using parallel factor analysis (PARAFAC) identified 6 independent components. Five components decreased in intensity as a result of the UVA exposures. One component was produced as a result of the exposures and represents labile photoproducts derived from terrestrial DOM. The characteristics of DOM in samples from the Bothnian Bay and Gulf of Finland were similar and dominated by terrestrially derived material. The DOM from the Arkona Sea was more autochthonous in character. Photoammonification differed depending on the composition of DOM. Calculated photoammonification rates in surface waters varied between 121 and 382 μmol NH₄⁺ L^− 1 d^− 1. Estimated areal daily production rates ranged between 37 and 237 μmol NH₄⁺ m^− 2 d^− 1, which are comparable to atmospheric deposition rates and suggest that photochemical remineralisation of organic nitrogen may be a significant source of bioavailable nitrogen to surface waters during summer months with high irradiance and low inorganic nitrogen concentrations.     

Nutrient fluxes from deep sediment support nutrient budget in the oligotrophic waters of the Gulf of Aqaba

The role of deep sediment in supporting nutrient budget in the Gulf of Aqaba has been investigated by estimating the flux of inorganic nitrogen, phosphate and silicate. Fluxes were calculated directly by pore water profiles and indirectly by chamber incubations carried out onboard the RV Meteor cruise. The results showed that maximum potential fluxes calculated by chamber incubations were higher than those calculated by porewater profiles for all nutrients (6.4–28.5 fold). This has been attributed to the additional flux due to bioturbation and flux from advective porewater exchange in the case of chamber incubation, while porewater fluxes represent diffusive ones. Using a rough estimation considering flux results in addition to the sediment area and water mass of the Gulf of Aqaba, we estimate that 3.3 × 10⁵, 6.4 × 10⁴ and 6.5 × 10⁶ kg year⁻¹ of inorganic nitrogen, phosphate and silicate respectively are effused from deep sediments to the water column. This quanitity would certainly support the primary productivity in the oligotrophic water in the Gulf of Aqaba.     

Excretion and respiration rates of the scyphomedusa <Emphasis Type="Italic">Aurelia aurita</Emphasis> from the Inland Sea of Japan

We measured the ammonium excretion, phosphate excretion and respiration rates of the scyphomedusa Aurelia aurita from Ondo Strait, in the central part of the Inland Sea of Japan, at 28 and 20°C. The rates measured at 28°C were converted to those at 20°C using the Q₁₀ values, i.e. 1.56, 1.57 and 2.80, for ammonium excretion, phosphate excretion and respiration rates, respectively. The composite relationships between metabolic rates and wet weight of a medusa (WW, g, range 11–1330 g) at 20°C were expressed by the following allometric equations. For ammonium excretion rate (N, μmoles N medusa⁻¹d⁻¹): N = 0.497WW ^1.09, phosphate excretion rate (P, μmoles P medusa⁻¹d⁻¹): P = 0.453WW ^0.84, and respiration rate (R, μmoles O₂ medusa⁻¹d⁻¹): R = 96.9WW ^1.06. Mean O:N ratios (i.e. atomic ratios of 16.9 and 11.0 at 28 and 20°C, respectively) indicated that the metabolism of A. aurita medusae was protein-dominated. These metabolic parameters enabled us to estimate the nitrogen and phosphorus regeneration rates of an A. aurita medusa population typical of early summer in the Ondo Strait (means of water temperature, medusa individual weight and population biomass: 20°C, 200 g WW and 50.8 g WW m⁻³, respectively). Regenerated nitrogen and phosphorus were equivalent to 10.0 and 21.6% of phytoplankton uptake rates, respectively, nearly twice that estimated for mesozooplankton, demonstrating that A. aurita medusae are key components of the plankton community, influencing the trophic and nutrient dynamics in the Ondo Strait during early summer.     

Benthic nutrient fluxes along the Laurentian Channel: Impacts on the N budget of the St. Lawrence marine system

Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L⁻¹), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L⁻¹, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m⁻² d⁻¹ in the hypoxic western LSLE to 100 μmol m⁻² d⁻¹ in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m⁻² d⁻¹, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 10⁶ t N, yielding an almost balanced N budget for the SL marine system.     

Deoxygenation and remineralization above the sediment-water interface; an in situ experimental study

An in situ chamber of volume 3881 and bottom area 0·64 m² was used to determine the flux of oxygen and inorganic nutrients across an estuarine sediment-water interface over a 65-day period. Over the first 7 days, oxygen uptake was 378 mg m^?2 day^?1 and the rates of ammonium and phosphate release were 2·22 and 0·34 mg at. m^?2 day^?1, respectively. The water became anoxic in 14 days.The rates of flux in a similar chamber containing only detritus recently settled from the water column were 371 mg m^?2 day^?1 (oxygen), 1·66 mg at. m^?2 day^?1 (ammonium) and 0 12 mg at. m^?2 day^?1 (phosphate), demonstrating that detritus contributes substantially to exchange across the sediment-water interface.The evolution of the two chambers was similar over the latter part of the experimental period. A third chamber containing only water exhibited very minor changes.The role of detritus in nutrient recycling at the sediment-water interface is discussed in relation to the productivity of shallow water bodies such as the estuary in which the experiment was conducted, which itself undergoes periodic deoxygenation during prolonged stratification. The measured flux of nitrogen across the interface was found to represent approximately 31% of the mean daily phytoplankton requirement.     

Water quality in a polluted lowland stream with chronically depressed dissolved oxygen: Causes and effects

Abstract

The Whangamaire Stream (North Island, New Zealand) has high concentrations of nitrate nitrogen (NO^? ₃‐N), biochemical oxygen demand (BOD₅), and Kjeldahl nitrogen (TKN) as a result of catchment land use practices. The lower reaches of the stream drain intensively farmed land and have dissolved oxygen (DO) levels of 10–50% saturation. The dominant riparian vegetation, Apium nodiflorum, provides a large organic loading by intercepting nutrients in run‐off and then decaying in the stream channel. Water quality and reaeration aspects of the stream were studied in order to explain the observed low DO levels. Measurements of the reaeration coefficient at 20°C, K₂ ²⁰, using methyl chloride (CH₃Cl) as a gas tracer, yielded values of 1.1–3.0 d^?1 for the upper part of the study reach and 15.5–16.2 d^?1 for the lower reach (overall average 12.5 ± 2.5 d^?1). These were in agreement with values inferred from single‐station diurnal curve analysis, which also showed that respiration was dominant in the lower reach where photo‐synthetic activity was inhibited by shade. The relatively large reaeration coefficients ensure that parts of the stream do not become anoxic at night time. Better riparian management and reduced nutrient inputs are likely to improve stream water quality.     

秦皇岛近岸海域夏季小型水母分布特征

本研究基于2014—2018年每年8月份,于秦皇岛海域使用浅水Ⅰ型浮游生物网采集的浮游动物样品数据,分析了小型水母群落的组成种类和丰度分布特征及环境因子与水母群落特征之间的关系。结果如下:2014—2018年调查海域共出现小型水母13种,其中2014、2015和2017年夏季水母种类数均为7种, 2016年夏季水母种类数为6种, 2018年夏季水母种类数最少,仅为2种。秦皇岛近岸水域水母的优势种包括薮枝螅水母、球型侧腕水母和锡兰和平水母。2016年夏季秦皇岛水域水母丰度的平均值最高,达到了95.0 ind./m3。2014、2015和2018年分别为66.9 ind./m³、69.1 ind./m³和35.4 ind./m³。2017年最低,为14.9 ind./m³。通过小型水母丰度与环境因子之间的相关性分析,结果显示:温度、盐度、pH、磷酸盐、溶解氧、无机氮、悬浮物等环境因子会对秦皇岛夏季水域水母群落结构的年际间变化产生显著影响。     

Study on the total water pollutant load allocation in the Changjiang (Yangtze River) Estuary and adjacent seawater area

With the rapid economic development, the water quality is worsening and red tide takes place frequently in the Changjiang Estuary and adjacent seawaters. To improve the marine water quality, the total inland pollutant load should be controlled effectively. With efficiency and fairness in consideration, the total maximum allowable loads of COD_Mn, NH₃–N, inorganic nitrogen and active phosphate to the seawaters were calculated and allocated by the linear programming method based on the water quality response fields of the pollution sources. The maximum allowable loads are 2008 × 10³ tons, 169 × 10³ tons, 226 × 10³ tons and 18 × 10³ tons for COD_Mn, NH₃–N, inorganic nitrogen and active phosphate when the water quality targets are requested to be achieved in the whole studied region, and 346 × 10³ tons and 32 × 10³ tons for inorganic nitrogen and active phosphate when the water quality targets to be achieved only in the red tide sensitive area. The cut task of COD_Mn and NH₃–N is relatively easy and can be finished by the watershed environmental plan; while the cut task of inorganic nitrogen and active phosphate is tremendous. The coastal provinces should install more denitrification and dephosphorization facilities in the existing waste water treatment plants or build new ones to control the red tides in the concerned seawaters.