Trace elements in ocean ridge basalts

A correlary of sea floor spreading is that the production rate of ocean ridge basalts exceeds that of all other volcanic rocks on the earth combined. Basalts of the ocean ridges bring with them a continuous record in space and time of the chemical characteristics of the underlying mantle. The chemical record is once removed, due to chemical fractionation during partial melting. Chemical fractionations can be evaluated by assuming that peridotite melting has proceeded to an olivine-orthopyroxene stage, in which case the ratios of a number of magmaphile elements in the extracted melt closely match the ratios in the mantle. Comparison of ocean ridge basalts and chondritic meteorites reveals systematic patterns of element fractionation, and what is probably a double depletion in some elements. The first depletion is in volatile elements and is due to high accretion temperatures of a large percentage of the earth from the solar nebula. The second depletion is in the largest, most highly charged lithophile elements (“incompatible elements”), probably because the mantle source of the basalts was melted previously, and the melt, enriched in these elements, was removed. Migration of melt relative to solid under ocean ridges and oceanic plates, element fractionation at subduction zones, and fractional melting of amphibolite in the Precambrian are possible mechanisms for depleting the mantle in incompatible elements. Ratios of transition metals in the mantle source of ocean ridge basalts are close to chondritic, and contrast to the extreme depletion of refractory siderophile elements, the reason for which remains uncertain. Variation of ocean ridge basalt chemistry along the length of the ridge has been correlated with ridge elevation. Thus chemically anomalous ridge segments up to 1000 km long appear to broadly coincide with regions of high magma production (plumes, hot spots). Basalt heterogeneity at a single location indicates mantle heterogeneity on a smaller scale. Variation of ocean ridge basalt chemistry with time has not been established, in fact, criteria for recognizing old oceanic crust in ophiolite terrains are currently under debate. The similarity of rare earth element patterns in basalt from ocean ridges, back-arc basins, some young island arcs, and some continental flood basalts illustrates the dangers of tectonic labeling by rare earth element pattern.     

The sylhet traps,their tectonic history,and their bearing on problems of indian flood basalt provinces

Recent studies of the Sylhet Traps (? Jurassic) and the overlying Cretaceous-Tertiary sedimentary cover in the southern part of the Khasi Hills, Shillong Plateau in Assam have led to a reconstruction of the tectonic history of the area since Jurassic times; a clear picture regarding the nature of volcanism has also emerged. The history begins with effusion of tholeiitic basalts, apparently through E-W fissures developed in the peneplaned crystalline basement. One of these fractures became a fault (the Raibah fault) along which the northern non-volcanic block moved up relative to the southern block experiencing volcanism. The fault was active during and after the volcanism till Upper Cretaceous times. The sequence of eruption was as follows: (1) tholeiitic basalts, (2) minor alkali basalts (nepheline tephrite), (3) tholeiitic basalts, (4) localised explosive effusion of minor rhyolites and acid tuffs, and (5) tholeiitic basalts. Neither feeder dykes nor volcanic vents have been noted in the Sylhet Traps. There are no agglomerates among the basic flows; the fragmental rocks are actually flow breccias. The formation of the various structures such as flow breccias, layering and flow folds in many of the basalt flows are thought to have been controlled by the angle of slope and the rate of flow. Thus, the Sylhet Trap flood basalts are characterised by quiet effusion through linear fissures. The effusion was followed by a dyke phase, intruding also along E-W fractures, expecially in the monoclinally bent southern portion; the subsequent tectonic history of the area is also characterised by relative uplift and downsinking of different basement blocks. It is concluded that in the Shillong Plateau uparching of the basement led to fracturing, effusion of basalts apparently along some zones of fissuring along which differential vertical movement of basement blocks was taking place. In the light of the foregoing conclusions, available data on the tectonics of the Rajmahal and the Deccan Traps are examined; both these flood basalt provinces have suffered broadly similar tectonic histories as the Sylhet Traps. The various features of flood basalts, viz., large extent, huge thickness, subaerial nature, a post-volcanic dyke phase are interpreted as a consequence of fusion of the Upper Mantle, development of tensional fractures eruptions apparently along fractures between adjoining basement blocks undergoing differential uplift.     

A geochemical model of mid-ocean ridge magma chambers

A computer model of mid-ocean ridge basalt generation using trace element geochemistry has been developed. The model simulates a periodically replenished, continually cooled and fractionated magma chamber, with periodic lava extrusion. Primitive basalts from the ocean floor are used to generate likely evolution paths for the magma chamber. The steady state variant of this model has led to the isolation of several variables which critically affect the basalt composition. Although the fraction of cumulates is an important parameter, other variables such as the volume of incoming magma batches, their frequency, and the volume of the mixing cell, play a critical part especially on slow-spreading ridges. The growing magma chamber model uses random number generators to simulate the initiation and growth of a chamber. This model predicts a rapid increase in incompatible element concentrations, immediately after chamber initiation on a fast-spreading ridge. This would occur in situations such as propagating rifts and may help in the understanding of ferrobasalt generation.     

Geochemical characteristics of Carboniferous greenstones in the Inner Zone of Southwest Japan

Abstract Greenstones, representing remnants of paleo-oceanic crust, occur in Permian and Jurassic accretionary complexes of the Inner Zone in the Southwestern Japan arc. The formation age of most of the greenstones is early Carboniferous, based on fossil ages for overlying limestones and Sm-Nd isotope ages of the greenstones themselves. The geochemistry of such greenstones is similar to those of present-day oceanic islands. Greenstones of the Permian accretionary complex (Akiyoshi belt) are alkalic and tholeiitic in composition. Some alkali basalts show peculiar features from an EM-1 mantle source, such as the Gough Island and Tristan da Chunha basalts in the South Atlantic. Greenstones of the Jurassic accretionary complex (Tamba belt) are also alkali and tholeiitic basalts with both basalt types in the northern part of the Tamba belt coming from strongly depleted characters similar to a mid-ocean ridge basalt source mantle. The variable geochemistry of the oceanic basalts is explained by hypothesis on existence of a Carboniferous mantle plume below the spreading ridge which divides the Farallon and Izanagi plates. The Akiyoshi belt seamounts and/or oceanic islands of the Farallon plate and Tamba belt seamounts and/or oceanic islands of the Izanagi plate formed simultaneously by the upwelling of the thermal plume. Some part of the Akiyoshi belt basalts originated locally from an EM-1 mantle source, while basalts from the northern parts of the Tamba belt have a normal-type mid-ocean ridge basalt (N-MORB) source component. Existence of an N-MORB signature is consistent with the presence of a spreading center in a Carboniferous 'Pacific Ocean' that caused separation of the Farallon and Izanagi plates. Disparity in accretion ages of the basaltic rocks in the Permian and Jurassic may have been caused by differences in the relative motion of the two plates.     

Basalt geochemistry and tectonic discrimination within continental flood basalt provinces

Continental flood basalts are usually regarded as a single tectonomagmatic entity but frequently quoted examples exhibit a variety of tectonic settings. In one well-studied, classic, flood basalt province, the Mesozoic Karoo province of southern Africa, magmatism occurred in the following tectonic settings: (a) continental rifting leading to ocean-floor spreading in the South Atlantic Ocean (Etendeka suite of Namibia); (b) stretched continental lithosphere and rifting not leading directly to ocean-floor formation (Lebombo suite of southeastern Africa); and (c) an a-tectonic, within-plate, continental setting characterized by an absence of faulting or warping (Lesotho highlands and Karoo dolerites of South Africa). By means of spidergrams of the elements Rb, Ba, Th, Nb, K, La, Ce, Sr, Nd, P, Hf, Zr, Sm, Ti, Tb, Y, V, Ni and Cr, uncontaminated tholeiites from (c) above [i.e. the Lesotho-type continental flood basalts (LTCFB)] are compared with mid-ocean ridge basalts (MORB), ocean-island tholeiites (OIT), and tholeiites and calc-alkali basalts from subduction environments. The comparison reveals the LTCFBs are geochemically distinct. The differences are reflected in relative enrichments or depletions of the more incompatible elements (Rb-Ce) to less incompatible elements (Ce-Y), i.e. the overall slope of the spidergrams, and in anomalous enrichments or depletions of one or more of the elements Th, K, Nb, Sr, Ti, Hf, and Zr. The distinctive geochemical character of the Lesotho LTCFBs is interpreted in terms of a lithospheric mantle source for the basalts. This is supported by isotopic data. There are no major geochemical differences between Lesotho CFBs and basalts of the rift-related Etendeka and Lebombo suites, although the latter are somewhat enriched in Rb, Ba and K. However, unlike the Lesotho basalts, the Lebombo and Etendeka basalts are associated with voluminous silicic volcanics or intrusive centres and late-stage dolerites having MORB/OIT (i.e. asthenospheric) geochemical characteristics. The flood basalt/silicic magmatism/late-stage dyke swarm association is characteristic of several rift or thinned lithosphere environments (e.g., Ethiopia, Skye, eastern Greenland) but in many of these the flood basalts have ocean-island basalt (OIT) geochemical characteristics. The Lesotho-type CFB geochemistry is exhibited by the Grande Ronde Basalt of the Columbia River Group (a possible subduction-related flood basalt province) and the basic rocks associated with Mesozoic rifting in the North and South Atlantic. Basalt geochemistry alone is unhelpful in determining the tectonic setting of CFBs although the rift-related environments may be identified by the petrology and geochemistry of the whole igneous suite. A two-source model is proposed for the mantle-derived basic rocks in rift-related CFB provinces. Early enriched basalts are derived from the lithosphere and, following pronounced lithospheric attenuation or rifting, later MORB-like melts are emplaced from the rising asthenosphere. The presence of both Lesotho- and OIT-type geochemical patterns in rift-related CFBs suggests that the lithosphere exhibits different styles of enrichment.     

Correlated Nd,Sr and Pb isotope variation in Walvis Ridge basalts and implications for the evolution of their mantle source

Basement intersected in DSDP holes 525A, 528 and 527 on the Walvis Ridge consists of submarine basalt flows and pillows with minor intercalated sediments. These holes are situated on the crest and mid and lower northwest flank of a NNW-SSE-trending ridge block which would have closely paralleled the paleo mid-ocean ridge [13, 14]. The basalts were erupted approximately 70 m.y. ago, an age equivalent to that of immediately adjacent oceanic crust in the Angola Basin and consistent with formation at the paleo mid-ocean ridge [14]. The basalt types vary from aphyric quartz tholeiites on the ridge crest to highly plagioclase phyric olivine tholeiites on the ridge flank. These show systematic differences in incompatible trace element and isotopic composition. Many element and isotope ratio pairs form systematic trends with the ridge crest basalts at one end and the highly phyric ridge flank basalts at the other.The low ¹⁴³Nd/¹⁴⁴Nd (0.51238), ²⁰⁶Pb/²⁰⁴Pb (17.54), ²⁰⁸Pb/²⁰⁴Pb (15.47), ²⁰⁸Pb/²⁰⁴Pb (38.14) and high⁸⁷Sr/⁸⁶Sr (0.70512) ratios of the ridge crest basalts suggest derivation from an old Nd/Sm-, Rb/Sr- and Pb/U-enriched mantle source. This isotopic signature is similar to that of alkaline basalts on Tristan de Cunha but offset to significantly lower Nd and Pb isotopic ratios. The isotopic ratio trends may be extrapolated beyond the ridge flank basalts with higher¹⁴³Nd/¹⁴⁴Nd (0.51270), ²⁰⁶Pb/²⁰⁴Pb (18.32), ²⁰⁷Pb/²⁰⁴Pb (15.52), ²⁰⁸Pb/²⁰⁴Pb (38.77) and lower ⁸⁷Sr/⁸⁶Sr (0.70417) ratios in the direction of increasingly Nd/Sm-, Rb/Sr- and Pb/U-depleted source compositions. These isotopic correlations are equally consistent with mixing od depleted and enriched end member melts or partial melting of an inhomogenous, variably enriched mantle source. However, observe ZrBaNbY interelement relationships are inconsistent with any simple two-component model of magma mixing, as might result from the rise of a lower mantle plume through the upper mantle. Incompatible element and Pb isotopic systematics also preclude extensive involvement of depleted (N-type) MORB material or its mantle sources. In our preferred petrogenetic model the Walvis Ridge basalts were derived by partial melting of mantle similar to an enriched (E-type) MORB source which had become heterogeneous on a small scale due to the introduction of small-volume melts and metasomatic fluids.     

A model for the relation between spreading rate and oblique spreading

Atwater and Macdonald have suggested that oblique spreading occurs at mid-ocean ridges which spread slowly (half rate less than 3 cm/yr), while the spreading is perpendicular at faster-spreading ridges. This paper explores this relation using the ratio of the power dissipated at ridges to that on transform faults to find the angle of oblique spreading (θ). The dependence of the energy dissipation rate on spreading rate is included in simple models of a ridge and transform. These arguments suggest that θ is related to the half spreading rate approximately by sin θ ～ V^?1.     

An “off-axis” alkali volcanic suite associated with the Bay of Islands ophiolites,Newfoundland

The Skinner Cove volcanic rocks, the lowermost of a sequence of thrust slices associated with the Bay of Islands ophiolites of western Newfoundland, make up a continuous alkaline differentiation sequence from pillowed ankaramites to trachytes. They are interpreted as having formed off the axis of the mid-ocean ridge on which the main ophiolitic rocks were formed, in a manner comparable to the Upper Pillow lavas of the Troodos Massif, Cyprus, and the alkaline rocks dredged near the flanks of modern mid-ocean ridges.     

洋中脊构造及地震调查现状

介绍了洋中脊的全球分布和构造特征,对全球主要的、不同扩张速率的洋中脊进行了分类和列表描述;对洋中脊的构造特征,如地形特征、地壳厚度与扩张速率的关系及扩张轴下的岩浆房的特征、洋中脊与地幔柱的相互作用进行了阐述。回顾了海底地震仪在洋中脊构造调查中的应用及取得的主要成果。简要介绍了我国将用海底地震仪开展洋中脊构造调查的技术路线。     

Internal stratigraphic relationships in the Etendeka group in the Huab Basin, NW Namibia: understanding the onset of flood volcanism

The Etendeka Igneous Province in NW Namibia forms the eastern most extent of the Paraná–Etendeka Flood Basalt Province and, despite only covering about 5% of the Paraná–Etendeka, has been the focus of much interest, due to its extremely well exposed nature. The Huab Basin in NW Namibia forms the focus of this study, and formed a connected basin with the Paraná throughout Karoo times (late Palaeozoic) into the Lower Cretaceous. It contains a condensed section of the Karoo deposits, which indicate early periods of extension, and Lower Cretaceous aeolian and volcanic Etendeka deposits, which have their correlatives in the Paraná. In the Huab Basin, the volcanic rocks of the Etendeka Group consists of the Awahab and Tafelberg Formations, which are separated by a disconformity. Detailed examination of the Awahab Formation reveals an additional disconformity, which separates olivine-phyric basalts (Tafelkop-type) from basalt/basaltic andesites (Tafelberg-type) marking out a shield volcanic feature which is concentrated in an area to the SE of the Huab River near to the Doros igneous centre. Early volcanism consisted of pahoehoe style flows of limited lateral extent, which spilled out onto aeolian sands of an active aeolian sand sea 133 million years ago. This sand sea is equivalent to the sands making up the Botucatu Formation in the Paraná basin. The early expression of flood volcanism was that of laterally discontinuous, limited volume, pahoehoe flows of Tafelkop-type geochemistry, which interleaved with the aeolian sands forming the Tafelkop–Interdune Member basalts. These basalts are on-lapped by more voluminous, laterally extensive, basalt/basaltic andesite flows indicating a step-up in the volume and rate of flood volcanism, leading to the preservation of the shield volcanic feature. These geochemically distinct basalts/basaltic andesites form the Tsuhasis Member, which are interbeded with the Goboboseb and Sprinkbok quartz latite flows higher in the section. The Tsuhasis Member basalts, which form the upper parts of the Awahab Formation, are of Tafelberg-type geochemistry, but are stratigraphically distinct from the Tafelberg lavas, which are found in the Tafelberg Formation above. Thus, the internal stratigraphy of the flood basalt province contains palaeo-volcanic features, such as shield volcanoes, and other disconformities and is not that of a simple layer-cake model. This complex internal architecture indicates that flood volcanism started sporadically, with low volume pahoehoe flows of limited lateral extent, before establishing the more common large volume flows typical of the main lava pile.     

Oceanic mantle beneath the southern Rio Grande rift

Major element and modal trends in spinel lherzolites from Salt Lake Crater, Hawaii, and Kilbourne Hole, New Mexico, are essentially identical. These trends have developed through 5–30% partial melting of the same pyrolite-like parent composition. The melting events probably took place at mid-ocean ridges.Using Cr/(Cr + Al + Fe³⁺) in spinel as an index of the degree of depletion in fusible components in each of a large number of lherzolite inclusions, we have subdivided both suites into relatively parental, intermediate, and refractory groups, and computed an average bulk composition for each group. Compositions of hypothetical melts generated from these rocks are characterized by high MgO (about 18%), low Ti and K, and CaO/Al₂O₃ around 1.0.The strongly similarity between the two xenolith suites suggests that south central New Mexico is underlain by oceanic mantle. We propose that the Kilbourne Hole lherzolites represent oceanic lithosphere which was buried beneath offshore sediments during a Precambrian ocean basin formation, later to be preserved when subduction further offshore created new additions to the continent above that near-shore oceanic lithosphere. In addition, we propose that the Mg-rich, Ti- and K-poor calculated melts reported here are the primitive precursors to mid-ocean ridge basalts. Early dunite and wehrlite cumulates from some ophiolite sequences may record the fractionation histories these liquids follow prior to eruption at the surface.     

Compositionally diverse magmas erupted close together in space and time within a Karoo flood basalt crater complex

Geochemical data and mapping from a Karoo flood basalt crater complex reveals new information about the ascent and eruption of magma batches during the earliest phases of flood basalt volcanism. Flood basalt eruptions at Sterkspruit, South Africa began with emplacement of thin lava flows before abruptly switching to explosive phreatomagmatic and magmatic activity that formed a nest of craters, spatter and tuff rings and cones that collectively comprise a crater complex >40 km² filled by 9–18 km³ of volcaniclastic debris. Rising magma flux rates combined with reduced access of magma to external water led to effusion of thick Karoo flood basalts, burying the crater-complex beneath the >1.5 km-thick Lesotho lava pile. Geochemical data is consistent with flood basalt effusion from local dikes, and some lava flows likely shared or re-occupied vent sites active during explosive eruptions at Sterkspruit. Flood basalt magmas involved in Sterkspruit eruptions were chemically heterogenous. This study documents the rapid (perhaps simultaneous) eruption of three chemically distinct basaltic magmas which cannot be simply related to one another from one vent site within the Sterkspruit crater complex. Stratigraphic and map relationships indicate that eruption of the same three magma types took place from closely spaced vents over a short time during formation of the bulk of the crater-complex. Two magma types recognized there have not been recognized in the Karoo province before. The variable composition of flood basalts at Sterkspruit argues that magma batches in flood basalt fields may be small (0.5–1 km³) and not simply related to one another. This implies in turn that heterogeneities in the magma source region may be close to each other in time and space, and that eruptions of chemically distinct magmas may take place over short intervals of space and time without significant hybridisation in flood basalt fields.     

Density variation amongst mid-ocean ridge basalts: Implications for magma mixing and the scarcity of primitive lavas

Densities calculated from glass compositions of observed mid-ocean ridge basalts show that the more primitive melts are likely to be buoyant in more evolved melts. Consideration of this and other physical properties indicates that convective mixing between most basaltic magmas occurs under intermittently turbulent to turbulent conditions (transitional Reynolds Numbers) accounting for the widespread occurrence of hybrid lavas. Hypothetical picritic melts inferred to be parental to mid-ocean ridge basalts are by contrast denser than most basalts erupted on the sea floor. The most primitive basalts observed to erupt occupy a density minimum when compared to more primitive and more fractionated melts. The density minimum occurs approximately at those compositions where plagioclase and/or pyroxene join olivine as major fractionating phases. Picritic basalts are rarely erupted, because they stratify at the base of magma reservoirs.     

Ridge collision and in situ greenstones in accretionary complexes: An example from the Late Cretaceous Ryukyu Islands and southwest Japan margin

Abstract Mélange units containing greenstones are common throughout the Cretaceous-Miocene Shimanto Supergroup in the Ryukyu Is and southwest Japan. Most greenstones in the accretionary complex originated in oceanic spreading ridges and seamounts, and they formed far from the convergent margin. Some mélange-like units in the supergroup, however, contain greenstones that were extruded upon and intruded into unconsolidated fine-grained terrigenous clastic sediments. It is inferred that eruption of the in situ greenstones resulted from igneous activity in the trench area. Geochemical signatures indicate that the greenstone protoliths were similar to mafic lavas generated at spreading ridges. Fossil ages of the strata containing in situ greenstones become younger over a distance of 1300 km eastward from Amami-Oshima (Cenomanian-Turonian) in the Ryukyu Is to central Japan (Late Maestrichtian-earliest Paleocene), implying that a site of igneous activity in the trench area migrated eastward along the Ryukyu Is and southwest Japan margin. Plate reconstructions of the northwest Pacific Ocean suggest the presence of the Kula-Pacific ridge near Late Cretaceous to early Paleogene Japan. In this context, it is suggested that the greenstones formed in response to Kula-Pacific ridge-forearc collision.
Ancient ridge-forearc collisions are best recognized by the presence of mid-ocean ridge basalt (MORB) extruded on sediments inferred to have accumulated in the trench area. Diachronous occurrences of the strata associated with these MORB in an orogenic belt are useful for documenting the ridge collision through time.     

A hafnium isotope and trace element perspective on melting of the depleted mantle

New Hf isotope and trace element data on mid-ocean ridge basalts (MORB) from the Pacific Ocean basin are remarkably uniform (¹⁷⁶Hf/¹⁷⁷Hf≈0.28313–0.28326) and comparable to previously published data [Salters, Earth Planet. Sci. Lett. 141 (1996) 109–123; Patchett, Lithos 16 (1983) 47–51]. Atlantic MORB have ¹⁷⁶Hf/¹⁷⁷Hf ranging from 0.28302 to 0.28335 confirming the wide range originally identified by Patchett and Tatsumoto [Geophys. Res. Lett. 7 (1980) 1077–1080]. Indian MORB define an even wider range, from 0.28277 to 0.28337, but three exotic samples have very unradiogenic Hf isotope compositions. Their very low ¹⁷⁶Hf/¹⁷⁷Hf ratios, together with their trace element characteristics, require the presence of unusual plume-type material beneath the Indian ridge. All other Indian MORB have uniform Hf isotope compositions at about 0.2832, and define a small field displaced to the right of other MORB in Hf–Nd isotope space. The distinct nature of Indian MORB is best explained by the presence in Indian depleted mantle of old recycled oceanic crust and pelagic sediments. Sm/Hf ratios calculated from new high-precision rare earth element and Hf trace element data do not vary in MORB in the same way as in ocean island basalts (OIB): ratios are constant in OIB, but decrease with increasing Sm contents in MORB. The constancy of Sm/Hf in OIB is probably due to an overwhelming influence of residual garnet during melting. By contrast, the decrease of Sm/Hf in MORB is due to the effect of clinopyroxene in the residue of melting beneath ridges, an interpretation confirmed by quantitative modeling of melting. The relationship between Sm/Nd and Lu/Hf ratios in MORB does not require the presence of garnet in the residual mineralogy. The decoupling of Lu/Hf ratios and Hf isotope compositions – the so-called Hf paradox [Salters and Hart, EOS Trans. Am. Geophys. Union 70 (1989) 510] – can be explained by melting dominantly in the spinel field at shallow depths beneath mid-ocean ridges.     

Oxygen isotope variations in marginal basin and ocean-ridge basalts

Oxygen isotope analyses have been made on 27 tholeiitic basalts from the Lau and Mariana marginal ocean basins and from mid-ocean ridges. The ¹⁸O values are related to the extent of hydration by submarine weathering as indicated by H₂O^? and total water content. Extrapolation to zero H₂O^? content gives a δ¹⁸O value of 5.5‰ on the SMOW scale for unaltered marginal basin basalts, in exact agreement with the oxygen isotope “signature” of ocean-ridge tholeiites. Three alkali basalts from seamount provinces also fit the tholeiite relationship. A Lau Basin gabbro has the tholeiitic ¹⁸O content, but an Indian Ocean gabbro is unusually light (δ¹⁸O = 4.0 for whole rock, plagioclase, and amphibole), and resembles the low -¹⁸O Iceland basalts. The basalt data confirm petrologic and chemical evidence for origin of marginal basins by extensional processes with production of basalts from depleted mantle material isotopically identical to the source of ocean-ridge tholeiites.     

Along-strike magma mixing beneath mid-ocean ridges: effects on isotopic ratios

The effects of mixing processes on the isotopic variability of mid-ocean ridge basalts are studied. The processes considered are porous flow dispersion and convective mixing in magma chambers. Porous flow dispersion is capable of mixing magmas over distances of only a few tens of meters. Convective mixing, on the other hand, is found to produce mixing over scales of kilometers to hundreds of kilometers. Calculations of convective mixing are carried out for continuous magma chambers, where mixing is limited by convective processes, and for discontinuous chambers, where mixing is limited by chamber size. Preliminary comparison of our calculations with observations along the mid-ocean ridges shows that the calculations are consistent with the existence of a correlation between bathymetry and isotopic ratio at long, but not at short, wavelengths. They are also capable of explaining a decrease in isotopic variability with increasing spreading rate.     

Element transport by dehydration of subducted sediments: Implication for arc and ocean island magmatism

High-pressure experiments on a natural pelite have been conducted at 2–11-GPa pressures in order to evaluate contributions of subducted sediments to arc and ocean island magmatism. Obtained phase relations suggest that, at least in modern subduction zones, subsolidus dehydration of chlorite and phengitic muscovite in the subducted sediments, rather than partial melting, is a predominant process in overprinting sediment components onto the magma source region. Trace element compositions of sediment-derived fluids are estimated based on dehydration experiments at 5.5 GPa and 900/1300°C. Pb is effectively transported by fluids relative to other elements. This results in the Pb enrichment for arc basalts by fluids, generated by the dehydration of subducted sediments, together with altered mid-ocean ridge basalt (MORB), and complementary depletion of Pb in subducted sediments. Inferred arc magma compositions obtained by model calculations based on the present experimental results agree well with a natural primitive arc basalt composition. A large increase in the U/Pb ratio in the subducted sediments at deeper levels than major dehydration depths results in a high Pb isotopic ratio through radioactive decay after long periods of isolation. Combined with other isotopic ratios such as Sr and Nd, it is possible to produce the EM II source, one of the enriched geochemical reservoirs for ocean island basalt magmas, by mixing of a small amount of subducted sediments with depleted or primitive mantle.     

Electrical Structure in Marine Tectonic Settings

This review paper presents recent research on electrical conductivity structure in various marine tectonic settings. In at least three areas, marine electromagnetic studies for structural exploration have increasingly progressed: (1) data accumulations, (2) technical advances both for hardware and software, and (3) interpretations based on multidisciplinary approaches. The mid-ocean ridge system is the best-studied tectonic setting. Recent works have revealed evidence of conductive zones of hydrothermal circulation and axial magma chambers in the crust and partial melt zones of the mid-ocean ridge basalt source in the mantle. The role of water or dissolved hydrogen and its redistribution at mid-ocean ridges is emphasized for the conductivity pattern of the oceanic lithosphere and asthenosphere. Regions of mantle upwelling (hotspot or plume) and downwelling (subducting slab) are attracting attention. Evidence of heterogeneity exists not only in the crust and the upper mantle, but also in the mantle transition zone. Electrical conductive zones frequently overlap seismic low-velocity zones, but discrepancies are also apparent. Some studies have compared conductivity models with the results of seismic and other studies to investigate the physical properties or processes. A new laboratory-based conductivity model for matured oceanic lithosphere and asthenosphere is proposed. It takes account of both the water distribution in the mantle as well as the thermal structure. It explains observed conductivity patterns in the depth range of 60–200 km.     

PGE geochemistry of Jiding ophiolite in Tibet and its constraint on mantle processes

The total PGE amount (σPGE) of mantle peridotite in the Jiding ophiolite is slightly higher than that of the primitive mantle, but the PGE contents of basalt are higher than those of the mid-ocean ridge basalt (MORB), with obviously lower Pd/Ir ratios. The accumulates, dyke swarm and basalts show remarkable negative Pt and positive Rh anomalies, resulting in the special N-type PGE patterns. Mantle peridotite and crustal rocks have similar distribution patterns. It is proposed that the PGE distribution patterns in the Jiding ophiolite are closely related with a higher degree of partial melting of the mantle in this region. Magmatic crystallization-differentiation led to PGE fractionation, thus making the contents of PGE in the accumulates decrease in the ascending direction. The higher content of Au in the Jiding ophiolite is the result of metasomatic alteration at later stages. Pt-Pd fractionation indicates that both the PGEs are controlled by their alloy and sulfide phases. Positive Rh anomalies seem to be related with higher oxygen fugacity in the melts.