Terrigenous zircon of archean greenstone belts as a source of information on the early earth’s crust: Azov and Dnieper domains,Ukrainian shield

Zircons from the metasedimentary rocks of the Mesoarchean greenstone belts of the Azov and Middle Dnieper blocks of the Ukrainian shield were studied and dated by U-Pb method on a NORDSIM secondary-ion mass spectrometer. Detrital zircons from the metasediments of the Belozerskaya Formation of the greenstone belts of the Middle Dnieper block are usually dated within 3000–3100 Ma, while individual grains have an age of 3200–3300 Ma. This indicates that the sediments were derived mainly from proximal volcanic source with minor contribution of the basement material (Aul’skaya Group). The metasediments of the Soroki greenstone structure of the Azov block contain mainly zircons with ages within 3500–3600 Ma, except for scarce grains having the ages older than 3700 Ma. Zircon cores are overgrown by granulitic rims dated at approximately 3300 Ma. A wide scatter in ages and Th/U ratios in the zircons indicate that they were derived from rocks of different composition and age. Obtained data suggest significantly wider distribution of the Paleoarchean crust within the Azov block of the Ukrainian shield than was previously assumed.     

Fold-thrust dislocations in sedimentary cover of the Sea of Azov

As follows from geological and geophysical data, tectonic deformations formed under lateral compression are widespread in the sedimentary cover at the bottom of the Sea of Azov. Fold-thrust dislocations are established in the North Azov Trough on the southern slope of the Ukrainian Shield, in the Azov Swell of the young Scythian Plate, and in the Indol-Kuban Foredeep. The transregional Main Azov Thrust Fault and smaller thrust faults of listric morphology tens of kilometers in extent are known. Asymmetric anticlines are related to their fronts. In plan view, the crests of these anticlines are displaced down the dip of the controlling faults. Folds and thrusts developed in pulsatory manner in the regime of periodically acting tangential compression are recorded in the thickness of the plate complex and stratigraphic and angular unconformities. Some of these dislocations are active and accompanied by anomalously high formation pressure, temperature and hydrochemical anomalies, tectonic brecciation, and mud volcanoes.     

Composition and age of metaorthopyroxenite xenoliths and host enderbite gneisses in the Pobuzhie granulite complex,Ukrainian Shield

The SIMS U-Pb isotopic age of zircons from enderbite gneisses and their metaorthopyroxenite xenoliths in the Pobuzhie granulite complex, Ukrainian Shield (48°13′57.3″ N and 29°59′21.5″ E, WGS84 system), was determined. The chemical compositions of these rocks and composing minerals were studied. Enderbite gneisses contain quartz, antiperthite plagioclase, K-feldspar, clinoenstatite, diopside, amphibole, and a small amount of biotite; accessory minerals are ilmenite and apatite. The age of zircon from enderbite gneiss is estimated at about 3.15 Ga. Metaorthopyroxenites are composed of orthopyroxene, clinopyroxene, phlogopite (up to 6% TiO₂), and plagioclase. The age of magmatic zircons from metaorthopyroxenite determined by the upper intercept of the discordia with the concordia is 3485 ± 33 Ma (MSVD = 1.6), and the age of metamorphic zircons is 2742 ± 22 Ma (MSVD = 0.22). Hence, the enderbite gneisses studied pertain to a young group of enderbites in the Pobuzhie granulite complex, while the age of metaorthopyroxenites from xenoliths in these rocks is similar to that of ancient Pobuzhie enderbites and pyroxenites of the Novopavlovsk complex in the Azov Region.     

Provenances of late Pliocene rare-metal-titanium placers in the Tamansky Peninsula

The comprehensive mineralogical analysis of the Taman nearshore Ti-Zr placers and their provenances in the adjoining late Pliocene sedimentation basin is presented. Taking into account paleogeographic reconstructions and contemporary mineral potential of sediments in the Sea of Azov, a contribution of specific feeding sources of terrigenous minerals to the formation of the late Pliocene placers have been estimated. These sources are crystalline and sedimentary rocks of the Caucasus, the southern Russian Plate, and the southeastern Ukrainian Shield (listed in the order of their contribution). The Miocene placers of the Stavropol Arch and Adygea Prominence, as well as the Cretaceous and younger placers of the Ukrainian Shield and the Voronezh Anteclise are suggested to be transitional reservoirs. Economic deposits are forecasted in the zone of paleostraits.     

Late Archean magmatic complexes of the Azov terrane,Ukrainian Shield: Geological setting,isotopic age,and sources of material

Geochemical, isotopic-geochemical, and geochronological information was obtained on magmatic rocks from the Saltychan anticlinorium in the Azov domain of the Ukrainian Shield. The rocks affiliate with the calc-alkaline series and a high-Mg series. The rocks of these series notably differ in concentrations of trace elements and REE and range from gabbro to granodiorite-quartz diorite in composition. The NORDSIM ionprobe U-Pb zircons ages of rocks belonging to the Obitochnen Complex and having both elevated and normal mg# correspond to 2908–2940 Ma. The Osipenkovskaya intrusion has an age of 2855 ± 19 Ma. The most alkaline North Obitochnen intrusion was emplaced in the Proterozoic, at 2074 ± 11 Ma. The age of the amphibolite metamorphism of the host gneisses is reliably dated at 3120–3000 Ma. The model Sm-Nd ages of the intrusive rocks do not exceed 3150 Ma. According to geochemical evidence, the parental melts of the magmatic rocks were derived from mantle domains variably enriched in lithophile elements. The results obtained by studying the Sm-Nd isotopic system corroborate the conclusion drawn from geochemical evidence that most of the melts were derived from the mildly enriched mantle, practically without involvement of ancient crustal material. The mantle became enriched in LREE at approximately 3000 Ma, which corresponds to the age of metamorphism of the supracrustal rocks. This process was separated from the derivation of the melts by a time span of 70–80 Ma. The relative age of the intrusive rocks and their variable composition can be most adequately explained by a contribution of heat and material from a plume to the derivation of the parental melts of these rocks.     

Zircon geochemistry and U–Pb age at rare metal deposits of syenite in the Ukrainian Shield

The distribution of rare and rare earth elements in zircon at the Yastrebets, Azov (Zr–REE–Y), and Perzhan (Be) rare metal deposits of the Ukrainian Shield was studied. Additional evidence for magmatic genesis of these deposits is obtained: unaltered zircon is characterized by a magmatic REE distribution spectrum with a somewhat higher δ¹⁸O value than that of the mantle (6.6‰ on average). The final formation stage of the deposit was marked by predominance of fluids enriched in Y, REE, Nb, and heavy oxygen, resulting in anomalous geochemical characteristics of zircon rims and alteration zones (up to 81500 Y ppm, over 10300 ppm Nb, and 13.9‰ δ¹⁸O). The age of zircon formed in ore-bearing Yastrebets and Azov nonnepheline syenite deposits was estimated at ~1770 Ma (U–Pb, SHRIMP-II).     

Isotopic-Geochemical Features of Zircon and Its Significance for Reconstructing the Geological History of Paleoarchean Granulites in the Ukrainian Shield

This paper presents the results of a complex study (morphology of grains, internal texture in cathodoluminescence and backscattered electrons, microprobe analysis, Lu–Hf data) of five groups (generations) of zircon crystals differing in age and separated from the same granulite sample pertaining to the Bug River Complex of the Ukrainian Shield. The data show that the oldest zircon crystals of the first group (3.74 Ga in age) are xenogenic and initially crystallized from a granitic melt; zircon of the second group (3.66 Ga) formed from a mafic melt contaminated by felsic country rocks. The third group (3.59 Ga) is represented by zircons that formed about 100 Ma later than the second group under conditions of granulite-facies metamorphism and with the participation of fluid-saturated anatectic melt. Two Paleoproterozoic zircon groups (~2.5 and 2.1 Ga) also formed under granulite-facies conditions; to a certain extent, their structure and composition were controlled by fluid. The geochemistry of all zircon generations provides evidence for their crystallization in the continental crust, but from the sources differing in the contribution of mantle-derived material and in oxygen fugacity.     

Detrital zircon ages from southern Norway – implications for the Proterozoic evolution of the southwestern Baltic Shield

An ion-microprobe (SIMS) U-Pb zircon dating study on four samples of Precambrian metasediments from the high-grade Bamble Sector, southern Norway, gives the first information on the timing of discrete crust-forming events in the SW part of the Baltic Shield. Recent Nd and Pb studies have indicated that the sources of the clastic metasediments in this area have crustal histories extending back to 1.7 to 2.1 Ga, although there is no record of rocks older than 1.6 Ga in southern Norway. The analysed metasediments are from a sequence of intercalated, centimetre to 10-metre wide units of quartzites, semi-metapelites, metapelites and mafic granulites. The zircons can be grouped in two morphological populations: (1) long prismatic; (2) rounded, often flattened. The BSE images reveal that both populations consist of oscillatory zoned, rounded and corroded cores (detrital grains of magmatic origin), surrounded by homogeneous rims (metamorphic overgrowths). The detrital zircons have ²⁰⁷Pb/²⁰⁶Pb ages between 1367 and 1939 Ma, with frequency maxima in the range 1.85 to 1.70 Ga and 1.60 to 1.50 Ga. There is no correlation between crystal habit and age of the zircon. One resorbed, inner zircon core in a detrital grain is strongly discordant and gives a composite inner core-magmatic outer core ²⁰⁷Pb/²⁰⁶Pb age of 2383 Ma. Two discrete, unzoned zircons have ²⁰⁷Pb/²⁰⁶Pb ages of 1122 and 1133 Ma, representing zircon growth during the Sveconorwegian high-grade metamorphism. Also the μm wide overgrowths, embayments in the detrital cores and apparent “inner cores” which represent secondary metamorphic zircon growth in deep embayments in detrital grains, are of Sveconorwegian age. The composite-detrital-metamorphic zircon analyses give generally discordant ²⁰⁶Pb/²³⁸U versus ²⁰⁷Pb/²³⁵U ratios and maximum ²⁰⁷Pb/²⁰⁶Pb ages of 1438 Ma. These data demonstrate the existence of a protocrust of 1.7 to 2.0 Ga in the southwestern part of the Baltic Shield, implying a break in the overall westward younging trend of the Precambrian crust, inferred from the southeastern part of the Baltic Shield. Received: 8 April 1997 / Accepted: 14 July 1997     

Metasedimentary Rocks of the Lapland–Kolvitsa Granulite Belt of the Baltic Shield: Primary Mineral Composition and Petrogeochemistry

The normative mineral composition is reported on source rocks of metasediments from the granulite belt of the Baltic Shield. The primary composition, CIA index, and position of data points of studied rocks in discriminant diagrams indicate that a significant part of the studied rocks formed from immature sediments (graywackes and subgraywackes). The material supplied to sedimentation paleobasins was obtained from different (ultrabasic, basic, intermediate, and acid) rocks. The paleobasin was characterized by organic activity and reducing environment in the bottom layer. Correlation found between some elements, e.g., (Rb, Ba, Pb)–K; Sr–(Na, Ca), and so on, is also typical of Phanerozoic deposits. The possible contents of OM (C_org) and U were reconstructed in source rocks of metasediments of the Lapland–Kolvitsa granulite belt of the Baltic Shield.     

Age range of formation of sedimentary-volcanogenic complex of the Vetreny Belt (the southeast of the Baltic Shield)

As a result of studying the Vetreny Belt greenstone structure (the southeast of the Baltic Shield), zircons from terrigenous deposits of the Toksha Formation, underlying the section of the sedimentary-volcanogenic complex, and zircons of the Vetreny Belt Formation, deposits of which crown the section, were dated. The results of analysis of age data of detrital zircons from quartzites of the Toksha Formation indicate that Mesoarchean greenstone complexes and paleo-Archean granitogneisses of the Vodlozero Block (Karelia) were the provenance area from which these zircons were derived. The occurrence of the youngest zircons with age of 2654.3 ± 38.5 Ma is evidence that the formation of the Vetreny Belt, including the Toksha Formation, began no earlier than this time. Zircons from volcanic rocks of the Vetreny Belt yielded the age of 2405 ± 5 Ma. Thus, the age interval of the formation of the sedimentary-volcanogenic complex of the Vetreny Belt ranges from 2654.3 ± 38.5 to 2405 ± 5 Ma.     

Hydrocarbons and other volatile components in alkaline rocks from the Ukrainian shield and Kola Peninsula

Gas chromatography and other analytical techniques (EMR, PMR, and IR spectroscopy) were used to examine volatile components (CH₄, C₂-C₃, CO₂, CO, H₂, H₂O, and others) in alkaline rocks and minerals from the Ukrainian Shield (eight massifs and dikes of grorudites) and from the Khibina and Lovozero massifs in the Baltic Shield. The alkaline rocks from the Ukrainian Shield are mostly of Proterozoic (1.7–2.1 Ga) age. The alkaline rocks from the Kola Peninsula were confirmed to be rich in methane (21 ± 14 μl/g on average) and other hydrocarbons, whereas the analogous rocks from the Ukrainian Shield are poor in methane (2.1 ± 1.6 μl/g on average at a maximum of 14 μl/g). The latter rocks are richer in CO₂, which is one of the major volatile components of alkaline rocks, including agpaitic nepheline syenites from the Kola Peninsula. The rocks from the Ukrainian Shield often have elevated contents of nitrogen (up to 20 μl/g). The reasons for the differences in the composition of volatile components of rocks from the Kola Peninsula and Ukrainian Shield are as follows: the agpaitic crystallization trends of large massifs in the Kola Peninsula and much less clearly pronounced agpaitic trends in the small massifs in the Ukrainian Shield, the affiliation of these rocks with different complexes, the deeper erosion levels of the Ukrainian alkaline massifs, different ages of these rocks, etc.     

Evolution and provenance of Neoproterozoic basement and Lower Paleozoic siliciclastic cover of the Menderes Massif (western Taurides): Coupled U–Pb–Hf zircon isotope geochemistry

In the Menderes Massif (western Taurides) a Neoproterozoic basement comprising metasediments and intrusive granites is imbricated between Paleozoic platform sediments. U–Pb–Hf zircon analyses of Menderes rock units were performed by us using LA-ICP-MS. The U–Pb detrital zircon signal of the Neoproterozoic metasediments is largely consistent with a NE African (Gondwana) provenance. The oldest unit, a paragneiss, contains significant amounts (~ 30%) of Archean-aged zircons and εHf (t) values of about a half of its Neoproterozoic zircons are negative suggesting contribution from Pan-African terranes dominated by reworking of an old crust. In the overlying, mineralogically-immature Core schist (which is still Neoproterozoic), the majority of the detrital zircons are Neoproterozoic, portraying positive εHf (t) values indicating derivation from a proximal juvenile source, resembling the Arabian–Nubian Shield.The period of sedimentation of the analyzed metasediments, is constrained between 570 and 550 Ma (Late Ediacaran). The Core schist sediments, ~ 9 km thick, accumulated in less than 20 My implying a tectonic-controlled sedimentary basin evolved adjacent to the eroded juvenile terrane. Granites, now orthogneisses, intruded the basin fill at 550 Ma, they exhibit ± 0 εHf (t = 550 Ma) and T_DM ages of 1.4 Ga consistent with anatexis of various admixtures of juvenile Neoproterozoic and Late Archean detrital components. Granites in the northern Arabian–Nubian Shield are no younger than 580 Ma and their εHf (t) are usually more positive. This implies that the Menderes does not represent a straightforward continuation of the Arabian–Nubian Shield.The lower part of the pre-Carboniferous silisiclastic cover of the Menderes basement, comprises a yellowish quartzite whose U–Pb–Hf detrital zircon signal resembles that of far-traveled Ordovician sandstones in Jordan (including 0.9–1.1 Ga detrital zircons), supporting pre-Triassic paleorestorations placing the Tauride with Afro-Arabia. The detrital signal of the overlying carbonate-bearing quartzitic sequence indicates contribution from a different source: the majority of its detrital zircons yielded 550 Ma and ± 0 εHf (t = 550 Ma) values identical to that of the underlying granitic gneiss implying exposure of Menderes-like granites in the provenance.260–250 Ma lead-loss and partial resetting of the U–Pb system of certain zircons in both basement and cover units was detected. It is interpreted as a consequence of a Permian–Early Triassic thermal event preceding known Triassic granitoid intrusions.     

U–Pb SHRIMP II age and origin of zircon from lhertzolite of the bug Paleoarchean complex,Ukrainian Shield

Complex study of the U–Pb and Lu–Hf systems of zircon from a lhertzolite lens of Archean gneiss enderbites of the Bug complex, Ukrainian Shield, showed that ultramafic magma was contaminated by the material of the country gneiss enderbites. The age of the zircons of 2.81 ± 0.05 Ga corresponds to the period of ultramafic magmatism within the Bug complex. Previously, this peak of endogenic activity was considered the stage of manifestation of metamorphism and magmatism of mafic composition.     

Identifying granite sources by SHRIMP U-Pb zircon geochronology: an application to the Lachlan foldbelt

The potential genetic link between granites and their host sediments can be assessed using zircon age inheritance patterns. In the Lachlan fold belt, southeastern Australia, granites and associated high-grade metasedimentary rocks intrude low-grade Ordovician country rock. This relationship is well-exposed in the Tallangatta region, northeast Victoria (part of the Wagga-Omeo Metamorphic Complex). In this region granites (two I-types and two S-types) have intruded during the mid-late Silurian between approximately 410–430 Ma based on the ages of magmatic zircons. The age spectra for inherited zircons from the granites have been compared with those of detrital zircons from the enclosing low- and high-grade metasediments. In broad terms, both for detrital zircons in all four sediments and for inherited zircons in three of the four granites, the dominant ages are early Paleozoic and Late Precambrian, with sporadic older Precambrian ages extending up to 3.5 Ga. The ages of the youngest detrital zircons from the low-grade Lockhart and Talgarno terranes limit the time of sedimentation to ca. 466 Ma or younger. The youngest detrital zircons from two samples of the high-grade Gundowring terrane are 473 Ma, making these sediments Ordovician or younger, not Cambrian as originally suggested. However, the individual age spectra for the four selected metasediments are not well matched when closely examined. The age spectra of the inherited zircons in the granites also do not adequately match those in any of the metasediments. Thus, the metasediments might not be representative of the actual source rocks of the granites. While the exact source of the granites cannot be identified from the analysed samples, the existence of a large population of ca. 495 Ma inherited zircon grains in the S-type granites requires that the granite source contains a significant proportion of Cambrian or younger material. This does not preclude the existence of a Precambrian basement to the Lachlan fold belt but indicates that at the level of S-type magma generation, a Cambrian and/or younger protolith is required. Received: 28 August 1998 / Accepted: 7 July 1999     

Results of U–Pb LA–ICP–MS dating of detrital zircons from Ediacaran–Early Cambrian deposits of the eastern part of the Baltic monoclise

Here we present the results of U–Pb LA–ICP–MS dating of detrital zircons from the Ediacaran–Early Cambrian deposits of the eastern part of the Baltic monoclise (Leningrad Region). The obtained age spectra of the detrital zircons suggest that, in the Ediacaran–Early Cambrian, the main clastic material source to the northwest of the Russian Platform was the Baltic Shield. Then in the Early Cambrian along with the Baltic Shield provenance, a clastic source from the Timanian margin of Baltica (northeast in modern coordinates) contributed to the deposits. The obtained data either somewhat set limits of the Timanian orogen formation as older than the previously suggested Middle Cambrian (about 510 Ma), based on the “absence of a Proto–Uralian–Timanian provenance signal” in the Sablino Formation rocks in the south Ladoga, or suggest another rearrangement of detritus transportation paths at the end of Stage 3 (Atdabanian).     

Results of Radiocarbon Dating of Holocene Deposits from the Sea of Azov

New data on the absolute age of Quaternary bottom deposits from the Sea of Azov based on the results of radiocarbon analysis (¹⁴C) are presented. Overall, 67 radiocarbon dating of bottom deposits of New and Ancient Azov Ages were obtained. The thickness of sediments of the New Azov Age and their distribution over different areas of the Sea of Azov was determined during the study; the results obtained were compared with the reference data available. An integrated approach to the study of deposits, based on the combination of the biostratigraphy methods and the results of absolute age dating, was applied.     

Geochemistry of alkali and nepheline syenites of the Ukrainian Shield: ICP-MS data

We present new geochemical data on alkali and nepheline syenites from various complexes of different age within the Ukrainian Shield. The results reveal a correlation between the content of trace elements in the syenites, their assignment to a particular rock complex, the chemistry of primary melts, and the degree of their differentiation. The data also suggest regional geochemical heterogeneity in the ultramafic-alkaline complexes of the Ukrainian Shield. The alkali and nepheline syenites in the ultramafic-alkaline massifs from the eastern and western parts of the region exhibit similar REE contents and Eu/Eu* ratios but are markedly different in Nb, Ta, Zr, and Hf content and are of the miaskitic type. These rocks have lower REE, Nb, and Zr and higher Sr and Ba compared with early foidolites. The rocks of the gabbro-syenite complexes define a distinct Fe-enrichment fractionation trend from early syenitic intrusions to more differentiated varieties; they are also characterized by lower Sr, Ba, and Eu/Eu* and significantly lower contents of some major elements, e.g., Ti, Mg, and P. The agpaitic index and concentrations of Zr, Nb, Y, and REE increase in the same direction. A similar geochemical feature is observed in the alkali syenites genetically associated with anorthositerapakivi-granite plutons, which show incompatible-element enrichment and strong depletion in Sr and Ba. The distinctive evolutionary trends of alkali and nepheline syenites from different rock complexes of the Ukrainian Shield can be explained by different mechanisms of their formation. The main petrogenetic mechanism controlling the distribution of trace elements in the rocks of ultramafic-alkaline complexes was the separation of parent melts of melanephelinite and melilitite types into immiscible phonolite and carbonatite liquids. The gabbro-syenite complexes and alkali syenites from anorthosite-rapakivi granite plutons evolved via crystallization differentiation, which involved extensive feldspar fractionation.     

Late Precambrian subduction and collision in the Al Amar—Idsas region, Arabian Shield, Kingdom of Saudi Arabia

Recent work on outer arcs and collision belts provides for the first time a possible model for evolution of part of the Arabian Shield. The thick volcanic, volcaniclastic and sedimentary succession of the Proterozoic Halaban Group in the east of the Shield is intruded by synto late tectonic plutons and resembles Cenozoic subduction-related magmatic areas. West of the Halaban Group, and separated from it by a major east-dipping thrust with associated ultrabasic rocks and carbonates, are folded chlorite—sericite metasediments of the Abt Schists, comparable to Cenozoic outer arc successions. West of and beneath the Abt Schists calcareous and arenaceous metasediments of the Ar-Ridaniyah Formation are analogous to Mesozoic—Cenozoic continental margin shelf facies of the subducting plate. Eastward subduction with magmatism (Halaban Group) and tectonic emplacement of ocean-floor sediments (Abt Schists) was followed by continental collision and eastward underthrusting by the Ar-Ridaniyah Group and cratonized central part of the Shield. Collision-related post-tectonic granites were emplaced during and following the collision.     

Isotopic geochronology of the archean posttectonic association of sanukitoids, syenites, and granitoids in central Karelia

The U-Pb geochronological study (by the classic technique and on an ion microprobe) of syenites from central Karelia has established their Archean age. The age values obtained for individual massifs are 2735 ± 15 Ma for syenites from the Sjargozero Massif and 2745 ± 10 Ma for syenite from the Khizhjarvi Massif. The syenites are demonstrated to have been emplaced nearly synchronously with sanukitoid massifs in central Karelia, whose average age is 2743 ± 3 Ma (Bibikova et al., 2005). The syenites of the Sjargozero Massif and granodiorites of the Ust-Volomsky Massif were determined to have practically identical ages of 2735 and 2738 Ma, respectively, a fact also corroborating the coeval character of the syenites and granodiorites. Some zircon grains from the Sjargozero syenites contain cores with an age of about 2755 Ma, which suggests that the syenites could have been contaminated with the material of the host volcanic rocks of basaltic and andesitic composition that were metamorphosed at 2750–2760 Ma. The results of the isotopic geochronologic research indicate that the different rock groups composing the Archean postorogenic association of sanukitoids, syenites, and granitoids in central Karelia have been generated in a single stage at approximately 2740 Ma, i.e., 60–70 m.y. after the origin of the syntectonic tonalites. The zircons have elevated Th/U ratios, which is consistent with the mantle genesis of the rocks. Significant crustal contamination was identified in the most acid members of the sanukitoid series: syenites and granitoids. Our data obtained for zircons from the sanukitoids and syenites of the Karelian craton in the Baltic Shield are in good agreement with the results obtained on the sanukitoids of the Canadian Shield.     

First results of U/Pb dating of detrital zircons from Early Paleozoic and Devonian sandstones of the Baltic-Ladoga region (south Ladoga Area)

The first results of U/Pb isotopic dating (LA ICP MS) of detrital zircons from sands from the Middle Cambrian Sablinka Formation, Upper Cambrian Ladoga Formation, Low Ordovician Tosna Formation, and calcareous sands from Syas’ Formation (Sargaevskii horizon of the Upper Frasnian) from Baltica-Ladoga Glint (BLG) of the Southern Ladoga area are presented. The obtained ages of detrital zircons span the intervals 492.7 ± 5.1-3196.4 ± 5.1 Ma (Sablino Formation); 577.9 ± 7–2972.6 ± 13.4 Ma (Ladoga Formation); 509.4 ± 8.5–3247.6 ± 10.1 Ma (Tosna Formation); 451.1 ± 14.7–2442.2 ± 6.9 Ma (Syas’ Formation). A comparison of the obtained isotopic ages of detrital zircons to ages of crystalline complexes composing the Kola-Karelian, Svecofennian, and Sveconorwegian domains of Baltic Shield and Pre-Uralian-Timanian structures of Subpolar and Polar Urals and basement of Pechora Basin was carried out. It is proposed that the Middle Paleozoic sedimentary basin accumulated Upper Frasnian rocks of Syas’ Formation. The basin ranged northward from the present-day BLG and occupied the eastern part of the Baltic Shield.