Temporal constraints on the timing of high-grade metamorphism in the northern Gawler Craton: implications for assembly of the Australian Proterozoic

LA-ICPMS U–Pb data from metamorphic monazite in upper amphibolite and granulite-grade metasedimentary rocks indicate that the Nawa Domain of the northern Gawler Craton in southern Australia underwent multiple high-grade metamorphic events in the Late Paleoproterozoic and Early Mesoproterozoic. Five of the six samples investigated here record metamorphic monazite growth during the period 1730–1690 Ma, coincident with the Kimban Orogeny, which shaped the crustal architecture of the southeastern Gawler Craton. Combined with existing detrital zircon U–Pb data, the metamorphic monazite ages constrain deposition of the northern Gawler metasedimentary protoliths to the interval ca 1750–1720 Ma. The new age data highlight the craton-wide nature of the 1730–1690 Ma Kimban Orogeny in the Gawler Craton. In the Mabel Creek Ridge region of the Nawa Domain, rocks metamorphosed during the Kimban Orogeny were reworked during the Kararan Orogeny (1570–1555 Ma). The obtained Kararan Orogeny monazite ages are within uncertainty of ca 1590–1575 Ma zircon U–Pb metamorphic ages from the Mt Woods Domain in the central-eastern Gawler Craton, which indicate that high-grade metamorphism and associated deformation were coeval with the craton-scale Hiltaba magmatic event. The timing of this deformation, and the implied compressional vector, is similar to the latter stages of the Olarian Orogeny in the adjacent Curnamona Province and appears to be part of a westward migration in the timing of deformation and metamorphism in the southern Australian Proterozoic over the interval 1600–1545 Ma. This pattern of westward-shifting tectonism is defined by the Olarian Orogeny (1600–1585 Ma, Curnamona Province), Mt Woods deformation (1590–1575 Ma), Mabel Creek Ridge deformation (1570–1555 Ma, Kararan Orogeny) and Fowler Domain deformation (1555–1545 Ma, Kararan Orogeny). This westward migration of deformation suggests the existence of a large evolving tectonic system that encompassed the emplacement of the voluminous Hiltaba Suite and associated volcanic and mineral systems.     

Behaviour of geochronometers and timing of metamorphic reactions during deformation at lower crustal conditions: phase equilibrium modelling and U–Pb dating of zircon,monazite, rutile and titanite from the Kalak Nappe Complex,northern Norway

This study investigates the behaviour of the geochronometers zircon, monazite, rutile and titanite in polyphase lower crustal rocks of the Kalak Nappe Complex, northern Norway. A pressure–temperature–time–deformation path is constructed by combining microstructural observations with P–T conditions derived from phase equilibrium modelling and U–Pb dating. The following tectonometamorphic evolution is deduced: A subvertical S1 fabric formed at ~730–775 °C and ~6.3–9.8 kbar, above the wet solidus in the sillimanite and kyanite stability fields. The event is dated at 702 ± 5 Ma by high‐U zircon in a leucosome. Monazite grains that grew in the S1 fabric show surprisingly little variation in chemical composition compared to a large spread in (concordant) U–Pb dates from c. 800 to 600 Ma. This age spread could either represent protracted growth of monazite during high‐grade metamorphism, or represent partially reset ages due to high‐T diffusion. Both cases imply that elevated temperatures of >600 °C persisted for over c. 200 Ma, indicating relatively static conditions at lower crustal levels for most of the Neoproterozoic. The S1 fabric was overprinted by a subhorizontal S2 fabric, which formed at ~600–660 °C and ~10–12 kbar. Rutile that originally grew during the S1‐forming event lost its Zr‐in‐rutile and U–Pb signatures during the S2‐forming event. It records Zr‐in‐rutile temperatures of 550–660 °C and Caledonian ages of 440–420 Ma. Titanite grew at the expense of rutile at slightly lower temperatures of ~550 °C during ongoing S2 deformation; U–Pb ages of c. 440–430 Ma date its crystallization, giving a minimum estimate for the age of Caledonian metamorphism and the duration of Caledonian shearing. This study shows that (i) monazite can have a large spread in U–Pb dates despite a homogeneous composition; (ii) rutile may lose its Zr‐in‐rutile and U–Pb signature during an amphibolite facies overprint; and (iii) titanite may record crystallization ages during retrograde shearing. Therefore, in order to correctly interpret U–Pb ages from different geochronometers in a polyphase deformation and reaction history, they are ideally combined with microstructural observations and phase equilibrium modelling to derive a complete P–T–t–d path.     

Ordovician high-grade metamorphism of a newly recognised late Neoproterozoic terrane in the northern Harts Range,central Australia

Granulite facies rocks from the northernmost Harts Range Complex (Arunta Inlier, central Australia) have previously been interpreted as recording a single clockwise cycle of presumed Palaeoproterozoic metamorphism (800–875 °C and >9–10 kbar) and subsequent decompression in a kilometre‐scale, E‐W striking zone of noncoaxial, high‐grade (c. 700–735 °C and 5.8–6.4 kbar) deformation. However, new SHRIMP U‐Pb age determinations of zircon, monazite and titanite from partially melted metabasites and metapelites indicate that granulite facies metamorphism occurred not in the Proterozoic, but in the Ordovician (c. 470 Ma). The youngest metamorphic zircon overgrowths from two metabasites (probably meta‐volcaniclastics) yield ²⁰⁶Pb/²³⁸U ages of 478±4 Ma and 471±7 Ma, whereas those from two metapelites yield ages of 463±5 Ma and 461±4 Ma. Monazite from the two metapelites gave ages equal within error to those from metamorphic zircon rims in the same rock (457±5 Ma and 462±5 Ma, respectively). Zircon, and possibly monazite ages are interpreted as dating precipitation of these minerals from crystallizing melt within leucosomes. In contrast, titanite from the two metabasites yield ²⁰⁶Pb/²³⁸U ages that are much younger (411±5 Ma & 417±7 Ma, respectively) than those of coexisting zircon, which might indicate that the terrane cooled slowly following final melt crystallization. One metabasite has a second titanite population with an age of 384±7 Ma, which reflects titanite growth and/or recrystallization during the 400–300 Ma Alice Springs Orogeny. The c. 380 Ma titanite age is indistinguishable from the age of magmatic zircon from a small, late and weakly deformed plug of biotite granite that intruded the granulites at 387±4 Ma. These data suggest that the northern Harts Range has been subject to at least two periods of reworking (475–460 Ma & 400–300 Ma) during the Palaeozoic. Detrital zircon from the metapelites and metabasites, and inherited zircon from the granite, yield similar ranges of Proterozoic ages, with distinct age clusters at c. 1300–1000 and c. 650 Ma. These data imply that the deposition ages of the protoliths to the Harts Range Complex are late Neoproterozoic or early Palaeozoic, not Palaeoproterozoic as previously assumed.     

Timing and style of high-temperature metamorphism across the Western Gawler Craton during the Paleo- to Mesoproterozoic

Abstract

Combined in situ monazite dating, mineral equilibria modelling and zircon U–Pb detrital zircon analysis provide insight into the pressure–temperature–time (P–T–t) evolution of the western Gawler Craton. In the Nawa Domain, pelitic and quartzo-feldspathic gneisses were deposited after ca 1760?Ma and record high-grade metamorphic conditions of ～7.5?kbar and 850?°C at ca 1730?Ma. Post-peak microstructures, including partial plagioclase coronae and late biotite around garnet, and subtle retrograde garnet compositional zoning, suggest that these rocks cooled along a shallow down-pressure trajectory across an elevated dry solidus. In the northwest Fowler Domain (Colona Block), monazite grains from pelitic gneisses record two stages of growth/recrystallisation interpreted to represent discrete parts of the P–T path: (1) ca 1710?Ma monazite growth during prograde to peak conditions, and (2) ca 1690?Ma Y-enriched monazite growth/recrystallisation during partial garnet breakdown and cooling towards the solidus. Relict prograde growth zoning in garnet suggests rocks underwent a steep up-P path to peak conditions of ～8?kbar at 800?°C. The new P–T–t results suggest basement rocks of the southwestern Nawa and northwestern Fowler were buried to depths of 20–25?km during the Kimban Orogeny, ca 10 Myrs after the sedimentary precursors were deposited. The P–T path for the Kimban Orogeny is broadly anti-clockwise, suggesting that at least the early phase of this event was associated with extension. Exhumation of rocks from both the southwestern Nawa and northwestern Fowler domains may have occurred during the waning stages of the Kimban Orogeny (<ca 1690?Ma). The limited low-grade overprint in these rocks may be explained by a mid-to-upper crustal position for these rocks during the subsequent Kararan Orogeny. Aluminous quartz-feldspathic gneiss of the Nundroo Block in the eastern Fowler Domain records peak conditions of ～7?kbar at 800?°C. Monazite grains from the Nundroo Block are dominated by an age peak at ca 1590?Ma, although the presence of some older ages up to ca 1690?Ma, possibly reflect partial resetting of older monazite domains. The P–T–t conditions suggest these rocks were buried to 20–25?km at ca 1590?Ma during the Kararan Orogeny. This high-grade metamorphism in the Nundroo Block is a mid-crustal expression of the same thermal anomaly that caused magmatism in the central-eastern Gawler Craton. Juxtaposition of rocks affected by the Kimban and Kararan orogenic events in the western Gawler Craton was controlled by lithospheric-scale shear zones, some of which have facilitated ～20 kilometres of exhumation.     

U–Pb ages and trace elements in metamorphic zircon and titanite from UHP eclogite in the Dabie orogen: constraints on P–T–t path

Laser ablation inductively coupled plasma mass spectrometry analyses of U–Pb isotopes and trace elements in zircon and titanite were carried out on epoxy mounts and thin sections for ultrahigh‐pressure (UHP) eclogite in association with paragneiss in the Dabie orogen. The results provide a direct link between metamorphic ages and temperatures during continental subduction‐zone metamorphism. Zircon U–Pb dating gives two groups of concordant ages at 242 ± 2 to 239 ± 5 Ma and 226 ± 2 to 224 ± 6 Ma, respectively. The Triassic zircon U–Pb ages are characterized by flat heavy rare earth element (HREE) patterns typical of metamorphic growth. Ti‐in‐zircon thermometry for the two generations of metamorphic zircon yields temperatures of 697 ± 27 to 721 ± 8 °C and 742 ± 19 to 778 ± 34 °C, respectively. We interpret that the first episode of zircon growth took place during subduction prior to the onset of UHP metamorphism, whereas the second episode in the stage of exhumation from UHP to HP eclogite facies regime. Thus, the continental subduction‐zone metamorphism of sedimentary protolith is temporally associated with two episodes of fluid activity, respectively, predating and postdating the UHP metamorphic phase. The significantly high Ti‐in‐zircon temperatures for the younger zircon at lower pressures indicate the initial ‘hot’ exhumation after the peak UHP metamorphism. There are two types of titanite. One exhibits light rare earth element (LREE) enrichment, steep MREE–HREE patterns and no Eu anomalies, and yields Zr‐in‐titanite temperatures of 551 to 605 °C at 0.5 GPa, and the other shows LREE depletion and flat MREE–HREE patterns, and gives Zr‐in‐titanite temperatures of 782–788 °C at 2.0 GPa. The former is amenable for U–Pb dating, yielding a discordia lower intercept age of 252 ± 3 Ma. Thus, the first type of titanite is interpreted to have grown in the absence of garnet and plagioclase and thus in the early stage of subduction. In contrast, the second one occurs as rims surrounding rutile cores and thus grew in the presence of garnet during the ‘hot’ exhumation. Therefore, there is multistage growth of zircon and titanite during the continental subduction‐zone metamorphism. The combined studies of chronometry and thermobarometry provide tight constraints on the P–T–t path of eclogites during the continental collision. It appears that the mid‐T/UHP eclogite facies zone would not only form by subduction of the continental crust in a P–T path slightly below the wet granite solidus, but also experience decompression heating during the initial exhumation.     

Age and radiogenic isotopic composition of a late- to post-tectonic anorthosite in the Grenville Province: the Labrieville massif, Quebec

The Labrieville anorthosite massif (LBV) is found in the Central Granulite Terrain of the Grenville Structural Province, but it displays no evidence of post-emplacement deformation or metamorphism, implying intrusion following peak Grenvillian metamorphic conditions. We report U---Pb zircon dates of 1008±3.4 Ma for border leucogabbro and 1010±5.6 Ma for a cogenetic jotunite dike intruding anorthosite. We interpret these dates as igneous crystallization ages, and regard 1010 Ma as a reasonable estimate of the emplacement age for LBV. LBV is thus the youngest massif anorthosite yet recognized in North America, and its age is consistent with late-tectonic emplacement relative to the 1.1-1.0 Ga Grenville Orogeny. We also report a U---Pb date of 1015±1.8 Ma for metamorphic zircon in a country rock amphibolite. This could reflect the age of Grenvillian regional metamorphism, or perhaps a later heating episode resulting from the intrusion of numerous “late” felsic plutons in this area.

Rb---Sr, Sm---Nd and U---Th---Pb isotopic compositions for four rock types (anorthosite, jotunite, leucogabbro and a plagioclase megacryst) span narrow ranges in each case, consistent with comagmatism among these units. I_Sr (T=1010 Ma) range from 0.7032–0.7034 and are among the lowest yet reported for anorthosite in the Grenville Province. Initial ε_Nd-values are positive (+0.8 to +2.5), like other Grenville anorthosites. Pb-isotopic compositions lie near the model mantle evolution curve of Zartman and Doe (1981), implying no involvement of significantly older crust in the petrogenesis of these rocks. Collectively, these data suggest a source for LBV in the mantle or mafic lower crust. LBV is a compositionally extreme anorthosite characterized by alkalic plagioclase (An₃₂Or₁₂) and high levels of Sr (2000 ppm) and Ba (1000 ppm). These properties cannot be attributed to simple crustal contamination of mantle-derived basalt. We suggest, alternatively, that LBV's compositional features may be linked with its late-tectonic character, perhaps reflecting partial melting of mafic lower crust brought about by crustal thickening during the Grenville Orogeny.     

Crustal architecture above the high-pressure belt of the Grenville Province in the Manicouagan area: new structural, petrologic and U–Pb age constraints

Recent U–Pb age determinations and P–T estimates allow us to characterize the different levels of a formerly thickened crust, and provide further constraints on the make up and tectono-thermal evolution of the Grenville Province in the Manicouagan area. An important tectonic element, the Manicouagan Imbricate zone (MIZ), consists of mainly 1.65, 1.48 and 1.17 Ga igneous rocks metamorphosed under 1400–1800 MPa and 800–900 °C at 1.05–1.03 Ga, during the Ottawan episode of the Grenvillian orogenic cycle, coevally with intrusion of gabbro dykes in shear zones. The MIZ has been interpreted as representing thermally weakened deep levels of thickened crust extruded towards the NW over a parautochthonous crustal-scale ramp. Mantle-derived melts are considered as in part responsible for the high metamorphic temperatures that were registered.New data show that mid-crustal levels structurally above the MIZ are represented by the Gabriel Complex of the Berthé terrane, that consists of migmatite with boudins of 1136±15 Ma gabbro and rafts of anatectic metapelite with an inherited monazite age at 1478±30 Ma. These rocks were metamorphosed at about the same time as the MIZ (metamorphic zircon in gabbro: 1046±2 Ma; single grains of monazite in anatectic metapelite: 1053±2 Ma) and under the same T range (800–900 °C) but at lower P conditions (1000–1100 MPa). They are mainly exposed in an antiformal culmination above a high-strain zone, which has tectonic lenses of high P–T rocks from the MIZ and is intruded by synmetamorphic gabbroic rocks. This zone is interpreted as part of the hangingwall of the MIZ during extrusion. A gap of 400 MPa in metamorphic pressures between the tectonic lenses and the country rocks, together with the broad similarity in metamorphic ages, are consistent with rapid tectonic transport of the high P–T rocks over a ramp prior to the incorporation of the mafic lenses in the hangingwall.Between the antiformal culmination of the Gabriel Complex and the MIZ 1.48 Ga old granulites of the Hart Jaune terrane are exposed. They are intruded by unmetamorphosed 1228±3 Ma gabbro sills and 1166±1 Ma anorthosite. Hart Jaune Terrane represents relatively high crustal levels that truncate the MIZ-Gabriel Complex contact and are preserved in a synformal structure.Farther south, the Gabriel Complex is overlain by the Banded Complex, a composite unit including 1403+32/−25 Ma granodiorite and 1238+16/−13−1202+40/−25 Ma granite. This unit has been metamorphosed under relatively low-P (800 MPa) granulite-facies conditions. Metamorphic U–Pb data, limited to zircon lower intercept ages (971±38 Ma and 996±27 Ma) and a titanite (990±5 Ma) age, are interpreted to postdate the metamorphic peak.The general configuration of units along the section is consistent with extrusion of the MIZ during shortening and, finally, normal displacement along discrete shear zones.     

Exhumation of a Variscan orogenic complex: insights into the composite granulitic–amphibolitic metamorphic basement of south-east Corsica (France)

A structural, petrological and geochronological (U‐Th‐Pb of zircon and monazite) study reveals that the lower crust sequences of the Variscan high‐grade basement cropping out between Solenzara and Porto Vecchio, south‐east Corsica (France) have been tectonically juxtaposed along with middle crustal rocks during the extrusion of the orogenic root of the Variscan chain. We propose that a system of high‐temperature, orogen‐parallel shear zones that developed under a transpressive dextral tectonic regime caused the exhumation of the entire sequence. This tectonic complex is thus made up of rocks having undergone different P–T conditions (eclogite‐?, high‐pressure granulite facies and amphibolite facies) at different times, reflecting the progressive foreland migration of the orogenic front. The Solenzara granulites were derived from burial of continental crust to high‐pressure (1.8–1.4 GPa) and high‐ to ultrahigh‐temperature conditions (900–1000 °C) during the Variscan convergence: U–Pb ELA‐ICPMS zircon dating constrained the timing of this metamorphism at c. 360 Ma. The gneisses cropping out at Porto Vecchio are middle crustal‐level rocks that reached their peak temperature conditions (700–750 °C at <1.0 GPa) at c. 340 Ma. The diachronism of the metamorphic events, the foliation patterns and their geometry suggest that the granulites were exhumed to middle crustal levels through channel flow tectonics under continuous compression. The amphibolite facies gneisses of Porto Vecchio and the granulites of Solenzara were accreted through the development of a major dextral mylonitic zone forming under amphibolite facies conditions: in situ monazite isotope dating (ELA‐ICPMS) revealed that this deformation occurred at c. 320 Ma and was accompanied by the emplacement of syntectonic high‐K melts. A final HTLP static overprint, constrained at 312–308 Ma by monazite U‐Th‐Pb isotope dating, is related to the emplacement of the igneous products of the Sardinia‐Corsica batholith and marks the transition from the Variscan orogenic event to the Permian extension.     

SHRIMP U–Pb detrital zircon ages from Proterozoic and Early Palaeozoic sandstones and their bearing on the early geological evolution of Tasmania

Detrital zircons from 13 Late Mesoproterozoic to Early Neoproterozoic sandstones and two Palaeozoic sandstones from Tasmania were dated in order to improve constraints on depositional ages, to test correlation between Proterozoic inliers, and to characterise source regions. These include successions considered to be the oldest presently exposed in Tasmania. Typical features of the age distributions of the Proterozoic rocks are prominent data concentrations at 1800–1650 Ma and 1450–1400 Ma, and a minor spread of Archaean ages. Statistical testing of the similarity of the age profiles shows that widespread quartzarenaceous samples from the Detention Subgroup, Needles Quartzite and from the Tyennan region are strongly similar, consistent with broad correlation. Relatively large differences are seen between the Detention Subgroup and the conformable, stratigraphically higher Jacob Quartzite, which contains an additional spread of 1300–1000 Ma zircons suggestive of a Grenvillian source. Age profiles of the quartzarenites and quartzwacke turbidites (Oonah Formation and correlatives) cannot be readily differentiated. The Oonah Formation likewise includes samples with and without Grenvillian ages, and there is no 750 Ma zircon population that would be expected if the turbidites were genetically related to the Wickham Orogeny. The simplest interpretation is that the quartzarenites (Rocky Cape Group and correlatives) and the turbidites (Oonah Formation and correlates) are lateral equivalents, although a younger (post-Wickham Orogeny) age for the Oonah Formation cannot be discounted. A maximum age of ca 1000 Ma is inferred for the Oonah Formation, Rocky Cape Group and correlatives. A minimum age of ca 750 Ma is provided by the basal age of the overlying Togari Group and correlatives. In a metasediment from western King Island, the youngest detrital zircons are ca 1350 Ma, allowing a pre-Grenvillian depositional age as suggested by previous dating of metamorphic monazite. However, the age profile of this sample is not dissimilar to the other Tasmanian successions that are inferred to be 1000–750 Ma. The Wings Sandstone, of southern Tasmania, contains an unusual profile dominated by Grenvillian ages, consistent with an allochthonous origin. Basement ages that broadly match the age spectra of the Tasmanian Proterozoic sediments are found in southwestern Laurentia, consistent with mutual proximity in Rodinia reconstructions. The Palaeozoic sandstones, from the turbiditic Mathinna Supergroup of northeastern Tasmania, have zircon age profiles typical of the Lachlan Fold Belt, with a predominant latest Neoproterozoic-Early Cambrian component and a lesser, broad Proterozoic data concentration at ca 1000 Ma. Western Tasmania was not a significant part of the source area for these rocks.     

Neoproterozoic evolution and Cambrian reworking of ultrahigh temperature granulites in the Eastern Ghats Province,India

The time‐scales and P–T conditions recorded by granulite facies metamorphic rocks permit inferences about the geodynamic regime in which they formed. Two compositionally heterogeneous cordierite–spinel‐bearing granulites from Vizianagaram, Eastern Ghats Province (EGP), India, were investigated to provide P–T–time constraints using petrography, phase equilibrium modelling, U–Pb geochronology, the rare earth element composition of zircon and monazite, and Ti‐in‐zircon thermometry. These ultrahigh temperature (UHT) granulites preserve discrete compositional layering in which different inferred peak assemblages are developed, including layers bearing garnet–sillimanite–spinel, and others bearing orthopyroxene–sillimanite–spinel. These mineral associations cannot be reproduced by phase equilibrium modelling of whole‐rock compositions, indicating that the samples became domainal on a scale less than that of a thin section, even at UHT conditions. Calculation of the P–T stability fields for six compositional domains within which the main rock‐forming minerals are considered to have attained equilibrium suggests peak metamorphic conditions of ~6.8–8.3 kbar at ~1,000°C. In most of these domains, the subsequent evolution resulted in the growth of cordierite and final crystallization of melt at an elevated (residual) H₂O‐undersaturated solidus, consistent with <1 kbar of decompression. Concordant U–Pb ages obtained by SHRIMP from zircon (spread 1,050–800 Ma) and monazite (spread 950–800 Ma) demonstrate that crystallization of these minerals occurred during an interval of c. 250 Ma. By combining LA‐ICP‐MS U–Pb zircon ages with Ti‐in‐zircon temperatures from the same analysis sites, we show that the crust may have remained above 900°C for a minimum of c. 120 Ma between c. 1,000 and c. 880 Ma. Overall, the results suggest that, in the interval 1,050 to 800 Ma, the evolution of the Vizianagaram granulites culminated with UHT conditions from c. 1,000 Ma to c. 880 Ma, associated with minor decompression, before further zircon crystallization at c. 880–800 Ma during cooling to the solidus. However, these rocks are adjacent to the Paderu–Anantagiri–Salur crustal block to the NW that experienced counterclockwise P–T–t paths, and records similar UHT peak metamorphic conditions (7–8 kbar, ~950°C) followed by near‐isobaric cooling, and has a similar chronology during the Neoproterozoic. The limited decompression inferred at Vizianagaram may be explained by partial exhumation due to thrusting of this crustal block over the adjacent Paderu–Anantagiri–Salur crustal block. The residual granulites in both blocks have high concentrations of heat‐producing elements and likely remained hot at mid‐crustal depths throughout a period of relative tectonic quiescence in the interval 800–550 Ma. During the Cambrian Period, the EGP was located in the hinterland of the Denman–Pinjarra–Prydz orogen. A later concordant population of zircon dated at 511 ± 6 Ma records crystallization at temperatures of ~810°C. This age may record a low‐degree of melting due to limited influx of fluid into hot, weak crust in response to convergence of the Crohn craton with a composite orogenic hinterland comprising the Rayner terrane, EGP, and cratonic India.     

Granular titanite from the Roter Kamm crater in Namibia: Product of regional metamorphism,not meteorite impact

Accessory minerals with so-called granular texture have risen in importance as geochronological tools for U-Pb dating of meteorite impact events. Grain-scale recrystallization, typically triggered by a combination of high-strain deformation and post-impact heating, can create a polycrystalline microstructure consisting of neoblasts that expel radiogenic Pb, which are thus ideal for isotopic dating. While granular domains in zircon and monazite from shocked rocks have been demonstrated to preserve impact ages, few U-Pb dating studies have been conducted on granular microstructures in titanite (CaTiSiO₅). Here we report the occurrence of granular-textured titanite from ～2020 Ma granite basement rock exposed in the rim of the 4–5 Ma Roter Kamm impact structure in Namibia. Orientation mapping reveals two microstructurally distinct titanite populations: one consisting of strained/deformed grains, and the other consisting of grains that comprise aggregates of strain-free neoblasts. In situ U-Pb geochronology on 37 grains shows that most grains from both titanite populations yield indistinguishable U-Pb dates of ca. 1025 Ma, consistent with the observed microstructures forming during the Mesoproterozoic Namaqua Orogeny. Only four grains preserved older age domains, recording ca. 1875 Ma Paleoproterozoic metamorphism. Two significant observations emerge: (1) none of the analyzed titanite grains yield the 2020 Ma igneous crystallization age previously established from zircon in the same sample, and (2) no age-resetting was detected that could be attributed to the 4 to 5 Ma Roter Kamm impact event. Despite the similarity of the neoblastic microstructure to minerals from other sites with an established impact provenance, the granular texture and near-complete Pb-loss in titanite from Roter Kamm granite instead records a Paleo- to Mesoproterozoic polymetamorphic history, rather than Miocene age shock-related processes. These results highlight the critical importance of grain-scale context for interpretation of U-Pb data in granular titanite, and the potential for misinterpreting inherited (pre-impact) microstructures as impact-related phenomenon in target rocks with a complex geological history.     

Petrogenesis of a late-Variscan rhyodacite at the Ossa Morena-Central Iberian zones boundary,Iberian Massif,Central Portugal: Evidence for the involvement of lithospheric mantle and meta-igneous lower crust

A late-Variscan rhyodacite is exposed at the contact between the Ossa Morena Zone and the Central Iberian Zone of the Iberian Massif, Central Portugal. Dykes of rhyodacite intruded the Série Negra Unit and the Sardoal Complex that are part of the Cadomian basement. The igneous crystallization age of the rhyodacite (308 ± 1 Ma) was obtained on igneous monazite by the ID-TIMS U-Pb method. It is broadly coeval with the emplacement of late-Variscan granitoids during the last deformation phase of the Variscan Orogeny (ca. 304–314 Ma) and with the development of the large late-Variscan strike-slip shear zones (ca. 307 Ma). The rhyodacite samples are calc-alkaline, show identical composition and belong to the same magmatic sequence. The rhyodacite isotopic signatures (Sm-Nd and δ¹⁸O) are consistent with depleted-mantle juvenile sources and the contribution of the meta-igneous lower crust. The input of mantle juvenile sources is related to Variscan reactivation of lithospheric fractures. The inherited Neoproterozoic (ca. 619 Ma) and Mesoproterozoic (ca. 1054 Ma) zircon ages, are similar to those of the Central Iberian Zone. This suggests that lower crust of the Central Iberian Zone was involved in the magma generation of the rhyodacite. Coeval late-Variscan magmatic rocks display a larger contribution from ancient crustal components, which may be attributed to the smaller volume and faster cooling rate of the rhyodacite and consequent lower melting of the crust. Mixing of juvenile mantle-derived melts with melts from the lower continental crust was followed by fractional crystallization of garnet and amphibole that remained in the source. Fractional crystallization of plagioclase, biotite, quartz and zircon occurred in shallower magma chambers. Fractional crystallization of zircon was not significant.     

Early Cretaceous K-rich rhyolites from the Duolong Cu–Au deposit,southern Qiangtang,China: evidence for crustal growth

We report new zircon U–Pb age, Hf isotopic, and major and trace element data for rhyolites from the Duolong Ore Concentration Area of the Southern Qiangtang Terrane. Building on previous studies, we constrain the tectonic setting and propose a model to explain the geodynamics and crustal growth during regional magmatism in the Early Cretaceous. The analysed rhyolites yield laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb ages of 115 and 118 Ma. The rocks are K-rich (K₂O = 6.66–9.93 wt.%; K₂O/Na₂O = 8.2–19.7 wt.%), alkaline and peraluminous (A/CNK = 1.02–1.46), and are characterized by high SiO₂ contents (72.8–78.8 wt.%) similar to highly fractionated I-type granites. Fractionation of Fe–Ti oxides, plagioclase, hornblende, Ti-bearing phases, apatite, monazite, allanite and zircon contributed to the variations in major and trace element chemistry. High K₂O contents are likely due to partial melting of the continental crust. The samples have positive zircon εHf(t) values ranging from +7.1 to +11.2. These features, together with young zircon Hf crustal model ages of 489–721 Ma, indicate that the K-rich rhyolites were derived from juvenile lower crust with an input of a mantle-derived component. We suggest that the Early Cretaceous K-rich rhyolites formed in a continental arc setting during northward subduction of Bangong Co–Nujiang oceanic lithosphere. Basaltic magma underplating was responsible for vertical crustal growth, triggered by slab roll-back in the Duolong Ore Concentration Area in the Early Cretaceous.     

Constraints on the early metamorphic evolution of Broken Hill, Australia, from in situ U-Pb dating and REE geochemistry of monazite

The Broken Hill Pb-Zn deposit, New South Wales Australia, is hosted in granulite facies gneisses of the Southern Curnamona Province (SCP) that have long been known to record a polydeformational and polymetamorphic history. The details of this potentially prolonged tectonothermal history have remained poorly understood because of a historical emphasis on conventional (i.e. grain mount) U-Pb zircon geochronology to reveal details of the sedimentary, magmatic and metamorphic history of the rock that crops out in the vicinity of the city of Broken Hill. An alternative approach to unravelling the metamorphic history of the granulite facies gneisses in and around Broken Hill is to date accessory minerals, such as monazite, that participate in sub-solidus metamorphic reactions. We have taken advantage of the high spatial resolution and high sensitivity afforded by SHRIMP monazite geochronology to reconstruct the early history of the metamorphic rocks at Broken Hill. In contrast to previous studies, in situ analysis of monazite grains preserved in their original textural context in polished thin sections is used. Guided by electron microprobe X-ray maps, SHRIMP U-Pb dates for three distinct monazite compositional domains record pulses of monazite growth at c. 1657 Ma, c. 1630 Ma and c. 1602 Ma. It is demonstrated that these ages correspond to monazite growth during lower amphibolite facies, upper amphibolite facies and granulite facies metamorphism, respectively. It is speculated that this progressive heating of the SCP crust may have been driven by inversion of the upper crust during the Olarian Orogeny that was pre-heated by magmatic underplating at c. 1657 Ma.     

Relating zircon and monazite domains to garnet growth zones: age and duration of granulite facies metamorphism in the Val Malenco lower crust

Zircon from a lower crustal metapelitic granulite (Val Malenco, N‐Italy) display inherited cores, and three metamorphic overgrowths with ages of 281 ± 2, 269 ± 3 and 258 ± 4 Ma. Using mineral inclusions in zircon and garnet and their rare earth element characteristics it is possible to relate the ages to distinct stages of granulite facies metamorphism. The first zircon overgrowth formed during prograde fluid‐absent partial melting of muscovite and biotite apparently caused by the intrusion of a Permian gabbro complex. The second metamorphic zircon grew after formation of peak garnet, during cooling from 850 °C to c. 700 °C. It crystallized from partial melts that were depleted in heavy rare earth elements because of previous, extensive garnet crystallization. A second stage of partial melting is documented in new growth of garnet and produced the third metamorphic zircon. The ages obtained indicate that the granulite facies metamorphism lasted for about 20 Myr and was related to two phases of partial melting producing strongly restitic metapelites. Monazite records three metamorphic stages at 279 ± 5, 270 ± 5 and 257 ± 4 Ma, indicating that formation ages can be obtained in monazite that underwent even granulite facies conditions. However, monazite displays less clear relationships between growth zones and mineral inclusions than zircon, hampering the correlation of age to metamorphism. To overcome this problem garnet–monazite trace element partitioning was determined for the first time, which can be used in future studies to relate monazite formation to garnet growth.     

High-grade Paleoproterozoic reworking in the southeastern Gawler Craton,South Australia ∗

SHRIMP U–Pb geochronology and monazite EPMA chemical dating from the southeast Gawler Craton has constrained the timing of high-grade reworking of the Early Paleoproterozoic (ca 2450 Ma) Sleaford Complex during the Paleoproterozoic Kimban Orogeny. SHRIMP monazite geochronology from mylonitic and migmatitic high-strain zones that deform the ca 2450 Ma peraluminous granites indicates that they formed at 1725 ± 2 and 1721 ± 3 Ma. These are within error of EPMA monazite chemical ages of the same high-strain zones which range between 1736 and 1691 Ma. SHRIMP dating of titanite from peak metamorphic (1000 MPa at 730°C) mafic assemblages gives ages of 1712 ± 8 and 1708 ± 12 Ma. The post-peak evolution is constrained by partial to complete replacement of garnet–clinopyroxene-bearing mafic assemblages by hornblende–plagioclase symplectites, which record conditions of ～600 MPa at 700°C, implying a steeply decompressional exhumation path. The timing of Paleoproterozoic reworking corresponds to widespread deformation along the eastern margin of the Gawler Craton and the development of the Kalinjala Shear Zone.     

Differential response of U-Pb systems in coexisting accessory minerals,Winnipeg River Subprovince,Canadian Shield: implications for Archean crustal growth and stabilization

The U-Pb isotopic systems of zircon, monazite, titanite and some apatite and the Pb isotopic composition of K-feldspar have been investigated in three areas of the Winnipeg River Subprovince (WRS) of the Superior Province, Canada, in order to define the timing of magmatic and metamorphic processes in this Archean gneissic-granitoid terrain.The new data together with published results define the following stages in the evolution of the WRS: (1) an extended period of early crustal growth punctuated by the episodic generation of tonalite. New ages include 3170+20/s-5 Ma, 2875+20/s-5 Ma and 2840+20/s-5 Ma for tonalitic gneisses at Cedar Lake, Kenora and Daniels Lake, respectively. (2) This early evolution was concluded by about 2760 Ma after emplacement of tonalite-granodiorite at Cliff Lake and was followed by a period of magmatic quiescence between about 2760 and 2710 Ma that contrasts with the intensive igneous activity characterizing the evolution of neighbouring greenstone belts. (3) A major episode of magmatism, deformation and metamorphism affected the Kenora and Daniels Lake areas between about 2710 and 2700 Ma. (4) A younger event caused deformation, metasomatism and amphibolite to granulite grade metamorphism at Cedar Lake and Daniels Lake at about 2680 Ma. (5) A subsequent, protracted period of low grade activity reset or (re-)crystallized titanite and apatite defining ages that scatter between about 2640 and 2520 Ma at Cedar and Daniels Lake but not in Kenora where titanite closed by about 2690 Ma. The 2680 Ma metamorphism may have been triggered in part by crustal thickening due to nappe thrusting but the subsequent period of lower grade activity requires the protracted addition of heat and/or fluids probably derived from magmatic and metamorphic processes continuing deep in the crust.The isotopic compositions of K-feldspars are relatively homogeneous and indicate mixing of Pb evolved in different reservoirs. The general enrichment in ²⁰⁷Pb with respect to normal terrestrial Pb reflects the protracted Archean evolution of the terrain.Now-coexisting minerals were formed and closed isotopically at different stages of the complex evolution and were selectively involved or excluded from isotopic equilibration with each other or with external systems such as hydrothermal fluids. This cautions against the indiscriminate interpretation of isotopic values obtained from whole rock systems in such complex terrains.     

Magmatic and metamorphic history of the Deh-Salm metamorphic Complex, Eastern Lut block, (Eastern Iran), from U–Pb geochronology

The Deh-Salm metamorphic Complex (DMC) of the Lut block in East Iran consists of metapelites, amphibolites, marbles, and metasandstones intruded by granite and pegmatites. U–Pb dating of zircon, monazite, xenotime, and titanite by ID-TIMS show that the granitic rocks were emplaced at 166–163 Ma, confirming that the high temperature metamorphism was synchronous with the intrusive activity, and that the region cooled rapidly thereafter. Late- to post-magmatic hydrothermal activity was probably responsible for the late crystallization, at 159.5 Ma, of zircon and titanite in an amphibolite and of monazite in granite. Xenocrystic zircons yield indications for a Carboniferous component in the source, together with a variety of Precambrian ages, which indicate a provenance of the sedimentary protolith from mature continental crust. The timing and rapidity of the events are consistent with evolution of the DMC in a back-arc environment during the Jurassic subduction of the Neotethys Ocean.     

U–Pb evidence for a polyorogenic evolution of the HP–HT units of the NW Iberian Massif

. A isotope dilution thermal ionisation mass spectrometry U-Pb geochronological study was carried out on the high-pressure and high-temperature units (HP-HT units) overlying the oceanic suture in the Allochthonous Complexes of the NW Iberian Variscan Belt. The rocks investigated are seven granulite- to eclogite-facies paragneisses and one leucosome within mafic high-pressure granulites in the Ordenes and Cabo Ortegal Complexes of NW Spain. U-Pb dating of zircon, monazite, titanite and rutile reveal the presence of a pervasive Early Ordovician metamorphic event at ca. 500-480 Ma and a later Early Devonian event at ca. 400-380 Ma. The U-Pb ages, in conjunction with petrological and structural data, indicate that the high-pressure event recorded by these rocks is Early Ordovician in age. Monazite ages in the paragneisses suggest that peak metamorphic conditions were reached at ca. 500-485 Ma. Subsequently, the rock ensemble underwent exhumation accompanied by partial melting and zircon growth at ca. 485-470 Ma. Melting of mafic granulites was coeval with this latter episode as indicated by zircon crystallisation age in the leucosomes dated at ca. 486 Ma. Based on these data and on the general features of magmatism and metamorphic evolution, it is proposed that this process took place at a convergent plate boundary within a peri-Gondwanan oceanic domain. Monazite, titanite and rutile data in some of the samples studied show evidence of a second metamorphic episode that took place between ca. 400 and 380 Ma (with a peak at ca. 390-385 Ma). This Early Devonian event, at variance with the previous one, was not pervasive, but, rather, was localised in areas of intense Variscan tectonothermal reworking. It is claimed that this later metamorphic event was recorded by the U-Pb system in areas where monazite and titanite growth was enhanced by fluid circulation in highly strained rocks (Variscan shear zones). According to previous structural studies and Ar-Ar dating of fabrics, this Early Devonian episode took place as the HP-HT units were deformed and thrusted upon the ophiolitic units in the early stages of the Variscan collision.     

Clasts of Variscan high-grade rocks within Upper Viséan conglomerates – constraints on exhumation history from petrology and U-Pb chronology

In this paper, U‐Pb zircon, monazite and rutile data for crystalline rocks deposited as clasts in the Upper Viséan conglomerates at the eastern margin of the Bohemian Massif are reported. U‐Pb data of spherical zircon from three different granulite clasts yielded a mean age of 339.0 ± 0.7 Ma (±2σ), while oval and spherical grains of another granulite pebble define a slightly younger date of 337.1 ± 1.1 Ma. These ages are interpreted as dating granulite facies metamorphism. Thermochronology and the derived pressure–temperature (P–T) path of the granulite pebbles reflect two‐stage exhumation of the granulites. Near‐to‐isothermal decompression from at least 44 km to mid‐crustal depths of around 22 km was followed by a near‐isobaric cooling stage based on reaction textures and geothermobarometry. Minimum average exhumation rate corresponds to 2.8–4.3 mm year^?1. The extensive medium‐pressure/high‐temperature overprint on granulite assemblages is dated by U‐Pb in monazite at c. 333 Ma. This thermal event probably has a close link to generation and emplacement of voluminous Moldanubian granites, including the cordierite granite present in clasts. This granite was emplaced at mid‐crustal levels at 331 ± 3 Ma (U‐Pb monazite), whereas the U‐Pb zircon ages record only a previous magmatic event at c. 378 Ma. Eclogites and garnet peridotites normally associated with high‐pressure granulites are absent in the clasts but exotic subvolcanic and volcanic members of the ultrapotassic igneous rock series (durbachites) of the Bohemian Massif have been found in the clasts. It is therefore assumed that the clasts deposited in the Upper Viséan conglomerates sampled a structurally higher tectonic unit than the one that corresponds to the present denudation level of the Moldanubicum of the Bohemian Massif. The strong medium‐temperature overprint on granulites dated at c. 333 Ma is attributed to the relatively small size of the entirely eroded bodies compared with the presently exposed granulites.