合肥盆地安参1井同位素年代地层学研究

安参1井是胜利油田取得合肥盆地油气勘探权之后钻探的第一口区域探井,但因化石极少,更没有发现具有划时代意义的化石,因而选择K-Ar法、40^Ar／^39Ar法、砂岩中石英电子自旋共振（ESB）及大理岩的铅一铅等时线法测年等同位素年代学法进行安参1井的地层划分,从而准确地确定了安参1井的地层时代及划分界限,为合肥盆地基础地质的深入研究奠定了坚实的基础。     

大别高压—超高压变质岩剥露历史在合肥盆地的记录

位于大别造山带北部的合肥盆地,其中的沉积是造山带剥露历史的重要记录。自生伊利石K—Ar测年,证实了合肥盆地中部安参1井自上而下钻遇了下白垩统,上、中、下侏罗统,下二叠统和上石炭统地层,下伏为奥陶系。中生界砂岩碎屑组分分析,表明其源区为大别造山带。安参1井内下二叠统砂岩不含造山带来源的碎屑多硅白云母。自下侏罗统至下白垩统,钻遇的砂岩中连续出现了丰富的碎屑多硅白云母(Si>3．3)。这不但指示大别造山带是合肥盆地的主要物源区,也限定了大别高压—超高压变质岩在早侏罗世早期就已经剥露地表．继而连续出露。     

一种自动划分地层的计算方法

介绍一种自动划分地层的计算方法。该方法是运用地球物理测井信息,自动追索地震反射界面,定量地确定它在钻遇地层中的空间位置,建立地层层序,达到正确地划分地层的目的。在东海10多口钻井中,用该方法划分的地层界面与根据化石、岩相等所确定的地质时代分层界面基本一致,吻合率可达90％以上。     

合肥盆地安参1井前侏罗纪基底地层的孢粉组合特征与时代归属

大别山北缘的安参1井是合肥盆地最深的一口参数井,钻遇前侏罗纪基底地层达千米以上,为一套不含煤层(线)或灰岩以泥岩为主的地层,与周缘华北陆块和大别造山带等构造单元的地层对比困难。因缺少宏观化石记录和明确的定年依据,其时代归属一直存在争议,制约了对这一套特殊地层所反映的地质信息的进一步挖掘。为进一步明确该套特殊地层的地质时代,本项研究对安参1井4160~5152m井段大量岩心和岩屑样品进行了微古化石分析,在其中5块样品中发现了保存良好的孢粉化石647粒,共计23属51种及部分未定种。根据对孢粉化石的类型、属种和含量的分析,将其自下而上划分为两个孢粉化石组合:Ⅰ.Densosporites reynoldburgensisLaevigatosporites perminutus;Ⅱ.Triquitrites-Macrotorispora media。孢粉组合Ⅰ中蕨类植物孢子以平均含量87.67%占绝对优势,代表分子有Laevigatosporites perminutus,Lycospora rotunda,Patellisporites meishanesis等,裸子植物花粉均为单囊粉属Florinites;孢粉组合Ⅱ中,蕨类植物孢子平均含量降低至53.78%,其中蕨类孢子Lycospora rotunda消失,Leiotriletes adnatus,Triquitrites,Crassipora等含量下降,并有特征分子大一头沉孢属Macrotorispora出现,裸子植物花粉含量和丰富度明显增加,以柯达粉属Cordaitina为主。经过与华北其他地区孢粉组合特征的对比分析,上述两个孢粉组合分别与华北陆块晚古生代二叠系太原组和上石盒子组具有明确的相似性,与早期和中晚期华夏植物群面貌相一致,反映了裸子植物逐渐繁盛、属种越来越丰富的过程,孢粉组合Ⅰ和Ⅱ的地质时代分别为晚石炭世晚期至早二叠世早期和晚二叠世,为安参1井前侏罗纪基底存在石炭—二叠系提供了直接证据,也为合肥盆地沉积环境和古气候分析提供了新资料。     

西湖1井钻前地震压力预测

西湖1井是准噶尔盆地南缘深部地层进一步油气勘探研究提供基础资料而部署的一口风险预探井。该井钻探构造高陡,钻遇断裂多,地层变化大,钻前地层压力预测更为重要。在地震地质解释研究的基础上,综合分析了工区内已钻的异常压力分布情况和形成机理,确定了本区地层压力的经验公式。通过对地震速度研究,建立三维速度场,进行层速度反演,提取井点地震速度。正确地估算了西湖1井的地层压力,为井身结构工程设计提供了依据,确保了钻井的顺利,地层压力预测结果与完钻后地层压力测试一致。     

"川蔺地1井"钻探施工难点与对策

"川蔺地1井"是部署在古蔺县大寨乡的一口页岩气地质调查井.旨在通过钻取地层岩心及测录井等工作,揭示川南古叙地区龙潭组富有机质页岩厚度、岩性、物性、含气性等页岩气基本地质情况.该井钻遇地层情况复杂,上部地层涌水量大、压力高,采用套管封隔引流解决了涌水难题.采用环保型防塌钻井液体系,解决了煤系地层垮塌等难题,满足环保要求和...     

用测井信息综合评价钻遇地层

用测井信息快速综合评价钻遇地层，在钻遇地层中建立测井波阻抗曲线和岩性剖面，追索地震反射界面、划分地层，识别测井相，对钻遇地层中烃源岩有机质丰度和含油气储集层的产能特征进行自动评价。     

合肥盆地钻井地层的同位素测年与地层划分

合肥盆地内部中、新界地层大面积被第四系覆盖，其地层的时代与划分主要依赖已有的6口深井地层资料。由于缺乏可靠的化石记录，这6口深井地层时代与划分一直存在着很大的分歧，制约了对该盆地的油气勘探与远景评价。本文利用这6口深井泥岩类岩屑中自生伊利石，在其结晶度分析基础上，进行了K-Ar同位素测年，成功地获得了不同深度上的地层形成时代。据此地层年龄，文中对这6口深井所钻遇的地层进行了重新的划分。     

九龙山某井气体钻井技术及事故处理实践

九龙山地区上部地层存在井漏、垮塌的可能,中部地层研磨性强、可钻性极差,下部地层存在多产层多压力系统并可能会钻遇异常高压。为了应对异常情况、缩短钻井周期、节约处理成本,龙某井设计从350～2000 m使用气体钻井。空气钻井钻至1170.28 m后地层出气,甲烷浓度超过6%,后改用氮气钻进,钻至1868 m时出现井壁垮塌和钻具阻卡,随后停止气体钻进。记录了钻进过程中返出主要气体的浓度变化情况和异常情况处理措施,实践表明,气体钻井在防止井漏、钻遇地层出气（不含H2S）、异常压力等复杂情况具有常规钻井无法比拟的优势。     

唐山市第一眼蓟县系地热井钻探及成井技术

唐山市丰南区ZK1地热井终孔深度3204.8 m,成井深度较深,揭露地层情况较为复杂,采用“四开”井身结构。施工过程中,根据钻遇地层情况的变化,及时调整钻具组合及钻进、钻井液等参数,降低了由于地层变化较大而产生漏浆、掉块、井壁垮塌等造成埋钻、卡钻的施工风险,保证了孔内钻探施工安全及成井质量,为唐山地区相同或此类地层的地热井勘探施工提供了成功经验。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

海南长塘岭矿区大坡岩体岩石学、地球化学特征及其含矿性初探

海南大坡岩体位于五指山褶皱带内,主要受昌江—琼海构造带、琼西构造带与潭爷断陷构造带控制.岩石地球化学及岩石学研究表明,大坡岩体形成于海西-印支晚期,岩性单一,主要为中细粒似斑状黑云母二长花岗岩.岩体显示为Ⅰ型花岗岩与S型花岗岩的混合,主体以地壳物质部分熔融为主,形成过程有少量地幔物质加入.元素对的比值及稀土元素配分特征说明岩体钨锡等多金属含矿性可能较差.