Tritium in the Caspian Sea

The tritium content of the surface water on the south shore of the Caspian Sea was determined in samples taken in two- to three-month intervals for the period of time from 1960 to 1970. Tritium concentrations following the massive H-bomb testing in 1962 and 1963 were particularly high in this water, much higher than in the surface waters of the open oceans. The data are interesting in connection with the tritium inventories on the continents and with the persistence of inert chemical pollutants in the surface layers of water masses.     

Anthropogenic Radionuclides in the Caspian Sea

Analysis and interpretation of the distribution of anthropogenic radionuclides ⁹⁰Sr, ¹³⁷Cs, and ^239,240Pu in the Caspian Sea water are presented. These radionuclides are shown to be of environmental importance and to be useful for studying water mass dynamics.     

Organochlorinated compounds in Caspian Sea sediments

Several organochlorinated contaminants, including numerous pesticides, were determined in coastal sediments from the Caspian Sea. The most important contaminants were p,p'-DDT (up to 7400 pg g(-1)) and its breakdown products, p,p'-DDD (up to 3400 pg g(-1)) and p,p'-DDE (up to 1300 pg g(-1)). Although the contamination was most severe in Azerbaijan, the sediment concentrations and percentage distribution of the three DDT-related compounds indicated that such contamination constitutes a contemporary and ubiquitous problem in the Caspian Sea. Lindane represented the second most significant contaminant, particularly in the Russian Federation, with concentrations up to 609 pg g(-1). The concentrations of HCB and other chlorinated pesticides (cis- and trans-chlordane, methoxychlor, heptachlor, heptachlor epoxide, aldrin, endrin, and endosulfans) were lower and not generally of concern, but the pesticides did demonstrate markedly different distributions reflecting differing agricultural usage in the region. The concentrations of Sigma PCBs were also quite low and ranged from 0.03 to 6.4 ng g(-1), with the highest amounts in the Russian Federation and Azerbaijan.     

Metals contamination along the watershed and estuarine areas of southern Bohai Sea,China

Distributions and magnitude of metals in water, sediment and soil collected from the watershed and estuarine areas of southern Bohai Sea, were investigated. The largest dissolved concentrations of As, Cu and Zn in water were 347.70, 2755.00, 2076.00 μg/L, respectively, much higher than corresponding drinking water guidelines. The greatest concentrations of Cu, Zn, Cr, Ni, Pb, As and Cd in sediments were 1462.2, 1602.17, 196.43, 67.15, 63.54, 73.86 and 1.41 mg/kg, dw, respectively. The mean concentrations of Cu, Ni, Cd, Zn, Cr, Pb and As in soils were 24.67, 24.73, 0.14, 64.75, 56.52, 25.12 and 9.34 mg/kg, dw, respectively. Land use was confirmed to be an important factor of influence on soil metal concentrations. Metal contents along the watershed of Jie River were significantly greater than in other locations. The detection of metals in relatively high concentrations from different environmental matrices in this region indicates the necessity of further studies.     

Nonlinear dynamics of level variations in the Caspian Sea

Caspian Sea level variations, which have several equilibrium states, are studied by the methods of the theory of nonlinear dynamic systems. Normal monthly values of sea level according to data collected at Makhachkala gauge from 1900 to 2000 are considered. The diagnostic characteristics of dynamic chaos are used to show that sea level variations have some properties of series with chaotic behavior. A model of level variations in the Caspian Sea, comprising a system of water balance equations for the sea basin, the dynamics of river runoff, and water balance of the sea itself, is proposed. Equation of a nonlinear oscillator is derived and shown to have solutions with chaotic regimes at some combinations of parameters.     

Hydrocarbons in the modern sediments of the Caspian Sea

The presented results have been obtained in a study of the concentrations and composition of aliphatic and polycyclic hydrocarbons in bottom sediments of Volga delta branches and in its shallow zone (2009–2010), as well as the Caspian Sea proper (2010–2013). Oil hydrocarbon pollution has been found to manifest itself mostly in Volga delta branches, which, despite the low concentrations (up to 54.5 μg/g), showed higher hydrocarbons share in C_org (up to 33.8%), while the composition of alkanes suggested their oil genesis. The geochemical barrier the Volga–the Caspian Sea prevents anthropogenic hydrocarbons from entering the open parts of the Caspian. Bottom sediments in the shallow zone of the Northern Caspian, represented by coarse-grained material, are now polluted by oil hydrocarbons to a lesser extent compared with other areas. The highest concentrations of aliphatic hydrocarbons (up to 178 μg/g) were recorded in the deepsea bottom sediments of Derbent Depression and in depressions of the Middle and Southern Caspian. These areas show a higher concentration of C_org (up to 9.884%) and a low concentration of hydrocarbons in C_org (up to 0.16%), while odd high-molecular homologues (n-C₂₅–C₃₁) dominate in the composition of alkanes.     

Aliphatic and aromatic hydrocarbons in coastal Caspian Sea sediments

This investigation represents the first extensive study of the spatial distribution and sources of aliphatic (n-alkanes and unresolved complex mixture of fossil hydrocarbons) and polycyclic aromatic hydrocarbons (PAHs) in coastal sediments from the Caspian Sea. PAH concentrations, n-alkanes and biomarker profiles all suggested that there was limited petrogenic contamination in the shallow North Caspian Sea sediments, which are coarse with a low total organic carbon content. In contrast, moderate to high petrogenic contamination was found in the South Caspian Sea, in particular in the offshore oil fields near Baku, Azerbaijan. Contaminant patterns indicated that the PAHs were mainly from fossil sources, with higher contributions of pyrolytic only near industrialized and urban areas. A high contribution of perylene, a geochemically derived PAH, to the total PAHs was found in the west and south at sites influenced by the Kura, Safid Rud, Terek, Sulak and Samur Rivers.     

U, Th, K and Cs activity concentrations along the southern coast of the Caspian Sea, Iran

The determination of activity concentrations of the radioactive elements ²³⁸U, ²³²Th, ⁴⁰K and ¹³⁷Cs was performed on grab samples taken from a polluted environment. The samples were sliced into strata from 5 cm depth, dried and ground to sieved through a 170 mesh size prior to the analysis. Activity concentration was quantified using gamma spectroscopy. The results showed that the concentrations of activity in the sediment samples are 177 ± 12.4, 117 ± 11.5, 1085 ± 101.6 and 131 ± 4.8 Bq kg⁻¹ for ²³⁸U, ²³²Th, ⁴⁰K and ¹³⁷Cs, respectively. In general, the distribution of activity concentrations along the southern coast of the Caspian Sea area exceeded international limits. The hazard index of the samples was 0.19-0.88, with an average of 0.49. The mean values of radium equivalent activity and dose rate are 176 Bq kg⁻¹ and 63 nGy h⁻¹, respectively.     

A Nonlinear Model of Level Variations in the Caspian Sea

A new thermophysical mechanism of the Caspian Sea level variations is proposed. The mechanism incorporates the effect exerted on the dynamics of the water budget of the Caspian Sea by the nonlinear dependence of the evaporation rate on the moistening of the basin.     

Present-day changes in water consumption in the Caspian Sea basin

Indices characterizing the withdrawal of water resources in the basins of rivers flowing into the Caspian Sea and the use of these resources in different economic sectors in 1970–2003 are analyzed. The dynamics of disposal of wastewaters and collector-drainage waters is discussed. Tendencies in changes in the volumes of consumptive water use in the basins of individual rivers and the Caspian Sea as a whole are identified.     

Variations in the Caspian Sea Level in the Historic Epoch

Reconstruction of variations in the Caspian Sea level is proposed based on the results of investigations of deposits in the Agrakhan sand bar and bays (or former bays) of the eastern sea coast. The history of sedimentation in particular regions is reconstructed by the radiocarbon dating. Generalized data on the age of deposits are used to construct the most likely temporal course of variations in the sea level within the historic epoch.     

Regime of water balance components of the Caspian Sea

The results of studying the hydrological regime of the Caspian Sea and its basin climate in observation period 1945–2010 are generalized. The results of analysis of the regime of precipitation, air temperature in the Caspian Sea basin and its level, as well as Volga runoff in periods of Caspian Sea level rise and drop are given. The conformity in variations of the trends in Caspian Sea level its basin climate is demonstrated, and the direction of further studies is substantiated.     

Space and Time Variations of Organic Matter in Caspian Sea Water

Water Resources - The analysis of data on the space and time variations of the concentrations and element composition of organic matter dissolved in Caspian Sea water over 2010–2015 showed...     

Concentrations of trace elements in muscle of sturgeons in the Caspian Sea

Concentrations of 21 trace elements were determined in muscle of beluga (Huso huso), Persian sturgeon (Acipenser persicus), Russian sturgeon (Acipenser gueldenstaedtii), ship sturgeon (Acipenser nudiventris) and stellate sturgeon (Acipenser stellatus) collected from coastal regions of Azerbaijan, Iran, Kazakhstan and Turkmenistan, surrounding the Caspian Sea during 2000-2001. Concentrations of Mn, Co, Cu, Mo, Sn, Hg, Pb and Bi in the muscle were apparently different among the five species of sturgeons. Especially, beluga showed the highest concentrations of Hg, Pb and Mn in all the five species. In addition, more than half of the individuals of beluga exceeded the guideline level (0.3 microg/g wet wt.) of Hg for food in UK. However, V, Cr, Zn, Ga, Rb, Sr and Ba concentrations were similar among five sturgeons. Growth-dependent increase in Hg in beluga, Cu in Persian sturgeon, and Zn in Russian sturgeon were observed, whereas V, Mn, Co, Cu, Ga, Sr, Mo, Sn, Hg and Bi concentrations in Persian sturgeon, Pb in ship sturgeon, and Cr, Mn, and Rb in stellate sturgeon were negatively correlated with body length. All species of sturgeon in Azerbaijan showed the highest concentration of Sr and the lowest concentration of Rb, while the five sturgeons from Iran showed opposite trends. Concentration of V, which is present in oil, in sturgeons in the Caspian Sea was considerably lower than that of fish from Kuwait, but was comparable to that of Cambodia and the Gulf and Gulf of Oman. To our knowledge, this study provides the first extensive data on multielemental accumulation in sturgeons of the Caspian Sea.     

Nutrient Input into the Caspian Sea with River Runoff

Long-term observational data are used to compare and analyze time and space variations in the concentrations of nutrients in the water of major rivers flowing into the Caspian Sea and assess the nutrients runoff into the sea. Annual variations in the normal monthly values of river runoff and nutrient compound concentrations and input into the sea are considered (18 compounds and considered for the Volga, Ural, Terek, Sulak, and Samur, and 7 compounds are considered for the Kura). The Volga contribution to nutrient input into the sea is found to vary from 77 to 94% with the average of 86%.     

An assessment of metal contamination in coastal sediments of the Caspian Sea

An assessment of marine pollution due to metals was made in the Caspian Sea based on coastal sediment collected in Azerbaijan, Iran, Kazakhstan, Russia and Turkmenistan. Despite the high carbonate content, the distribution of most metals was largely controlled by terrigenous inputs. Several metals (As, Cr, Ni) exhibited concentrations that exceed sediment quality guidelines. Such metals have a high natural background but anthropogenic activities, notably mining, may further enhance concentrations. This would explain hot spots for Cu and Zn in Azerbaijan and Iran, and Cr at the mouth of the Ural River in Kazakhstan. Contamination by Hg was observed to the south of Baku Bay, Azerbaijan. Some anomalously high concentrations of Ba in the central Caspian are probably from offshore drilling operations, but the elevated U concentrations (up to 11.1 microg g(-1)) may be natural in origin. Several metals (Ag, Cd, Pb) have relatively low levels that pose no environmental concerns.     

The nonstationary and nonlinear character of Caspian Sea level variations

A stochastic model of level variations in a drainless water body is considered. The model accounts for the nonstationary character of sea level under stationary climate. It is shown that in the case of the Caspian Sea, the range from ?29 to ?26 m BS corresponds to a relative stability of the level because of the greatest gentleness of the shores and shelf slope in combination with the maximal water outflow into Kara-Bogaz-Gol Gulf.     

The Khvalynian transgression of the Caspian Sea and the New-Euxinian basin of the Black Sea

The Late Pleistocene history of the Caspian and Black seas is considered. It is suggested that the New-Euxinian basin was to a great degree due to the penetration of the Caspian water through the Manych depression into the Black Sea during the Caspian-Early Khvalynian transgression.     

Wood export prediction at the watershed scale

Wood export from a watershed is a function of peak annual discharge, but one hydrologic relationship alone does not fully explain observed variability. Consideration of physical processes that influence the amount of wood available for transport is needed. However, wood recruitment, storage, mobilization, breakage, and transport rates and processes remain difficult to quantify. A theoretical wood transport equation focused on variations in discharge was the motivation for investigation into watershed‐specific wood export rates. Herein, multiplicative coefficients categorized by water year type are developed, paired with the equation, and validated to provide a new method for prediction of wood export at the watershed scale. The coefficients are defined as representing a broad suite of watershed processes that encompass spatio‐temporally variable scales. Two complementary datasets from the 1097 km² mountainous North Yuba River, California watershed were used. Wood surveys above New Bullards Bar Reservoir yielded a wood availability estimate of 250 000–300 000 m³ along the channel network. Annual wood export into the reservoir was field‐surveyed in 2010, 2012 and 2013, and estimated in seven years via remotely sensed images over the 30 year study period of water years 1985–2014. Empirical, watershed‐scale wood export rates ranged from 0.3–5.6%. Comparison of predicted quantities using the new DVWP (discharge variations modified by watershed processes) wood export equation to observed wood export quantities resulted in an aggregate error rate of ±10%. When individual wood export quantities were compared, predicted to observed varied by 0.5–3.0 times. Total wood export of 59 000–71 000 m³ was estimated over the 30 year period, yielding a rate of 1.8 to 2.2 m³/year/km². Wood export predictive capabilities at the watershed scale may help water resource and regulatory agencies plan for wood transfers to augment downstream ecosystems. Copyright © 2017 John Wiley & Sons, Ltd.     

A hydrologic contribution to risk assessment for the Caspian Sea

The Caspian Sea (CS), the world's largest inland sea, may also be considered as large-scale limnic system. Due to strong fluctuations of its water level during the 20th century and the flooding of vast areas in a highly vulnerable coastal zone, economic and environmental risk potentials have to be considered. Since the major water input into the CS is attributed to the Volga river, the understanding of its long-term flow process is necessary for an appropriate risk assessment for the CS and its coastal area. Therefore, a top-down approach based on statistical analyses of long-term Volga flow series is pursued. For the series of annual mean flow (MQ) of the Volga river basin during the 20th century, a complex oscillation pattern was identified. Analyses for multiple gauges in the Volga river basin and Eurasian reference basins revealed that this oscillation pattern resulted from the superposition of oscillations with periods of ∼30 years (MQ) in the western part of the Volga river basin, and ∼14 years (flow volume of snowmelt events) and ∼20 years (flow volume of summer and autumn) in the eastern part of the Volga river basin (Kama river basin). Almost synchronous minima or maxima of these oscillations occurred just in the periods of substantial changes of the Caspian Sea level (CSL). It can thus be assumed that the described mechanism is fundamental for an understanding of the CSL development during the 20th century. Regarding the global climate change, it is still difficult to predict reliably the development of the CSL for the 21st century. Consequently, we suggest an ongoing, interdisciplinary research co-operation among climatology, hydrology, hydraulics, ecology and spatial data management.