青藏高原杂多地区晚二叠世—早三叠世陆相火山岩的地球化学特征

在北羌塘盆地东部杂多县特龙赛等地首次厘定出晚二叠世—早三叠世火山岩。该火山岩形成于陆相环境，由４个爆发－溢流相火山韵律组成一个完整的火山旋回。这些火山岩主要由强蚀变杏仁状橄榄玄武岩、岩屑晶屑凝灰岩、杏仁状安山岩等组成，ＴｉＯ２含量（１．３３％～１．７６％）与峨眉山低Ｔｉ玄武岩相当，ＭｇＯ含量较低（２．２３％～７．５２％，平均为５．０２％），富集轻稀土元素（ＬＲＥＥ／ＨＲＥＥ＝４．１６～１３．４４，平均为６．５），无明显的Ｅｕ异常（δＥｕ＝０．８５～１．０２，平均０．９６），Ｎｂ、Ｔａ轻度负异常，地球化学特征与大陆拉斑玄武岩相似。各种微量元素判别图解显示这些火山岩形成于大陆拉张带或陆内裂谷区。结合区域研究成果，晚古生代时整个羌塘地区很可能处于一种伸展背景。     

青藏高原北羌塘盆地治多地区松赛弄一带火山岩的特征及构造意义

测区松赛弄晚三叠世-带火山岩为-套酸性-中性-基性火山岩组合,由玄武岩、安山岩、英安岩、流纹岩及少量火山碎屑岩等组成.火山岩中SiO2含量为48.89%～88.15%,平均67.44%,TiO2为0.22%～1.85%,平均0.63%,MgO含量0.23%～7.81%,与岛弧钙碱性火山岩相似;高场强元素Nb、Ta、Zr、Hf、Ti等亏损,大离子亲石元素Rb、Sr、Ba等相对富集,(La/Sm)n为1.79～5.19,LREE/HREE值多数在4.08～6.63,属轻稀土元素富集型,δEu多数在0.47～0.99.铕呈负异常;La/Nb多数大于2.00,Nb/Zr>0.04;Th/Ta>4.41,Th×Ta/Hf2>0.042,具有陆缘火山弧的特性.上述特征表明,羌塘盆地治多地区松赛弄一带晚三叠世火山岩产于大陆碰撞与陆缘弧并存的环境.     

云南富宁地区晚二叠世基性火山岩的发现及其构造意义

笔者在云南富宁地区厘定出一套较大面积展布的火山岩,为讨论该火山岩岩石地球化学特征及其构造意义,对该火山岩进行了地质学、岩石学、地球化学分析。结果表明：（1） 该套火山岩是研究区全新发现,结合其地质学特征及邻近地区测年数据,认为其时代可能为晚二叠世;（2）该火山岩主要由灰色致密状玄武岩、灰色（球颗）玄武岩、灰色气孔状玄武岩等基性岩石构成,多具有间粒结构,致密块状构造、气孔状构造,主要由斜长石、辉石组成,局部可见微弱热液蚀变发育;（3）该火山岩属亚碱性系列,SiO2含量处于46.08%~51.80%之间,全碱alk=2.94~5.21,K2O/Na2O=0.03~1.03,钠质多,为基性中-高钾钙碱性玄武岩;（4）该火山岩呈现轻稀土富集、重稀土亏损的弱分异右倾式稀土元素配分特征,δEu=1.02~1.10,呈现Eu正异常,δCe=0.93~0.96,表现Ce负异常。（Rb/Yb）N=1.6~11.4,强不相容元素富集;（Ce/Yb）N=2.03~7.59,（La/Lu）N=2.4~9.93,稀土元素分异明显;微量元素表现为Sr、Ti、Zr、Nb亏损,而P、Th富集特征。Nb/Ta介于11.8~18.5,显示出岩浆源遭受过来自消减板块的影响;（5）火山岩构造判别图显示该火山岩既具有大陆板内环境特征,又具有大洋板内构造背景,是一种叠加的构造环境,这可能是因为该地区大洋演化过程中同时受到了峨眉山玄武岩影响造成的。     

琼北火山活动分期与全新世岩浆演化

琼北火山活动始于始新世以来,早第三纪火山岩以夹层隐伏于不同时期的地层中。本文新提供的琼北火山岩K-AT年龄和砂岩捕虏体热释光年龄,从年代学上确定了琼北存在全新世火山喷发活动。琼北地表火山岩从早到晚分为6期：蓬莱期(中新世)、金牛岭期(上新世)、多文岭期(早更新世)、东英期(中更新世)、道堂期(晚更新世)、雷虎岭期(全新世)。雷虎岭期又分为早晚两个亚期：雷虎岭亚期和马鞍岭亚期,它们分别属于橄榄拉斑玄武岩和石英拉斑玄武岩。火山岩稀土元素、微量元素和Sr,Nd,Pb同位素地球化学特征揭示,岩浆来自亏损地幔(DMM)和富集岩石圈或亏损地幔(DMM)与俯冲洋壳两种不同的地球化学组分混合源区。橄榄拉斑玄武岩是相对原始的地幔岩浆。橄榄拉斑玄武岩岩浆经约10％橄榄石分离结晶可以形成石英拉斑玄武岩浆。岩浆上升过程中未受明显的陆壳混染。     

青海南部杂多地区新建扎青组的地层层序及地质意义

在青藏高原北羌塘盆地青海南部,青海省杂多县扎青乡地区的然者涌一带,发现以基性火山熔岩为主夹有中基性火山碎屑岩,具大陆板内裂谷拉斑玄武岩喷发特点的一套火山地层。该地层底部角度不整合接触覆盖在早中二叠世开心岭群诺日巴尕日保组、九十道班组之上,其上被晚三叠世结扎群甲丕拉组角度不整合覆盖。主要岩性为灰绿—灰紫色橄榄玄武岩、粗面玄武岩、玄武粗安岩及流纹岩、中基性火山角砾岩、角砾凝灰岩夹少量流纹岩和紫红色岩屑砂岩及细砾岩,其特征与峨眉山低钛玄武岩相似,具陆相喷发-沉积特征。区域对比在北羌塘地区具有独特地层特征,可与四川峨眉山玄武岩地层进行对比。而区域上该地区晚二叠世主要为一套海陆交互相含煤碎屑岩建造,未发现陆相火山岩出露,本文建立正式地层单位扎青组,以供参考,其时代暂归晚二叠—早三叠世。     

青藏高原北羌塘盆地东部二叠纪高Ti玄武岩的地球化学特征

在北羌塘盆地东部莫云地区早二叠世栖霞期尕笛考组中首次发现高Ti玄武岩。在当郎寨剖面上,火山岩主要产于尕笛考组第2和第4岩性段,第3岩性段中火山岩呈夹层产出,火山岩形成于浅海环境。岩石类型包括杏仁状玄武岩、粗玄岩、块状玄武岩、橄榄玄武岩和安山玄武岩,属碱性玄武岩系列。该火山岩岩石地球化学特征表现为高FeO,极高TiO2,较高FeO/MgO值,而Al2O3、MgO和Mg″值则低,LILE(Rb、Sr、Ba)和HFSE(Nb、Ta、Zr、Hf、Th、P2O5)富集,REE总量高,显示出LREE富集的配分型式,Eu表现为弱的负异常或无异常,具板内碱性玄武岩的地球化学特征。以上特征表明,火山岩形成于陆块边缘拉张带(初始裂谷)环境。     

博格达造山带东段芨芨台子地区早二叠世双峰式火山岩地球化学特征及其地质意义

博格达造山带东段芨芨台子地区早二叠世玄武岩和中酸性火山岩在时空上构成双峰式火山岩组合,其岩石类型主要为亚碱性玄武岩和流纹岩,主体属钙碱性系列。玄武岩SiO2含量为47.70%~51.71%,TiO2含量(1.26%~1.52%)略高于N型大洋中脊玄武岩,高Al(Al2O3=14.06%~20.93%),富Na贫K(Na2O/K2O=2.34~28.36),低Mg(MgO=2.99%~8.62%,Mg#为27~52),表明其玄武岩浆发生过明显的橄榄石和辉石的分离结晶作用;玄武岩轻稀土元素略微富集,Eu异常不明显(δEu=0.85~1.02),相对富集Rb、Ba、P等大离子亲石元素,亏损Nb、Ta、Sr、Ti等不相容元素。火山岩地球化学特征表明,研究区玄武质岩浆来自于亏损岩石圈地幔的部分熔融,且受到一定程度的地壳物质混染,显示了板内玄武岩的地球化学特征形成于陆内伸展环境。流纹岩具有较高的SiO2(73.58%~75.45%)和全碱(Na2O+K2O=8.56%~8.79%)含量,以及较低的TiO2(0.12%~0.18%)、Al2O3(12.77%~13.24%)和MgO(平均为0.21%)含量;显示右倾负斜率稀土配分模式,Eu负异常明显(δEu为0.52~0.70),显著富集Rb、Ba、Th等大离子亲石元素,强烈亏损Nb、Ta、Sr、P、Ti等高场强元素,具有A型花岗岩的地球化学特征,为后碰撞伸展环境下底侵玄武岩浆结晶分异的产物。博格达造山带东部芨芨台子地区双峰式火山岩的地球化学特征表明,该套火山岩应形成于碰撞后伸展环境,同时获得流纹岩锆石U-Pb年龄为(294.2±1.3)Ma,表明该套火山岩形成于早二叠世早期。这一发现进一步证实了研究区在历经石炭纪汇聚碰撞事件后进入二叠纪后碰撞伸展的演化时期,为进一步理解博格达地区晚古生代构造格局及板块构造体制提供了重要的地质依据。     

青藏高原北羌塘盆地东部二叠纪高Ti玄武岩的地球化学特征

在北羌塘盆地东部莫云地区早二叠世栖霞期尕笛考组中首次发现高Ti玄武岩.在当郎寨剖面上,火山岩主要产于尕笛考组第2和第4岩性段,第3岩性段中火山岩呈夹层产出,火山岩形成于浅海环境.岩石类型包括杏仁状玄武岩、粗玄岩、块状玄武岩、橄榄玄武岩和安山玄武岩,属碱性玄武岩系列.该火山岩岩石地球化学特征表现为高FeO*,极高TiO2,较高FeO*/MgO值,而Al2O3、MgO和Mg“值则低,LIL(Rb、Sr、Ba)和HFSE(Nb、Ta、Zr、Hf、Th、P2O5)富集,REE总量高,显示出LREE富集的配分型式,Eu表现为弱的负异常或无异常,具板内碱性玄武岩的地球化学特征.以上特征表明,火山岩形成于陆块边缘拉张带(初始裂谷)环境.     

青藏高原北羌塘盆地东部二叠纪高Ti玄武岩的地球化学特征

在北羌塘盆地东部莫云地区早二叠世栖霞期尕笛考组中首次发现高Ti玄武岩.在当郎寨剖面上,火山岩主要产于尕笛考组第2和第4岩性段,第3岩性段中火山岩呈夹层产出,火山岩形成于浅海环境.岩石类型包括杏仁状玄武岩、粗玄岩、块状玄武岩、橄榄玄武岩和安山玄武岩,属碱性玄武岩系列.该火山岩岩石地球化学特征表现为高FeO*,极高TiO2,较高FeO*/MgO值,而Al2O3、MgO和Mg"值则低,LIL(Rb、Sr、Ba)和HFSE(Nb、Ta、Zr、Hf、Th、P2O5)富集,REE总量高,显示出LREE富集的配分型式,Eu表现为弱的负异常或无异常,具板内碱性玄武岩的地球化学特征.以上特征表明,火山岩形成于陆块边缘拉张带(初始裂谷)环境.     

云南鲁春晚三叠世硅质岩的地球化学特征及成因

云南鲁春晚三叠世火山沉积盆地是在江达-维西火山弧的基础之上,通过拉张作用形成的碰撞后拉张盆地,盆地内广泛发育一套由玄武岩和流纹岩组成的“双峰式”火山岩及与其相伴的硅质岩。硅质岩可分为凝灰质硅质岩和纹层状硅质岩两类。通过对两类硅质岩所进行的地球化学研究和分析,表明云南鲁春晚三叠世火山沉积盆地中的凝灰质硅质岩属火山沉积成因,而纹层状硅质岩为海底喷流热液/热泉(热水)沉积成因的热水硅质岩。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案（1999/30/EC）,对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10 μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提出了具体测定要求。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.