九龙江口、厦门西海域磷的生物地球化学研究──Ⅲ.生物活动参与下的磷形态转化及磷循环估算

１９８７年３月～１９８８年１２月笔者于九龙江口、厦门西海域的调查研究结果表明，厦门西海域特殊的地理、水文环境、沉积物的高磷量、磷形态的快速转化是西海域初级生产力［５５５ｇ／（ｍ２·ａ）］比九龙江口区［１５９ｇ／（ｍ２·ａ）］高得多的主要原因。颗粒态磷（ＰＰ）、溶解态无机磷（ＤＩＰ）、溶解态有机磷（ＤＯＰ）等以生物为媒介发生了某种程度的形态转化。本文估算了九龙江水总磷（ＴＰ）的入海通量为７８７ｔ／ａ，其中ＤＩＰ为６９．２ｔ／ａ，ＤＯＰ为１７０ｔ／ａ，ＰＰ为５４７ｔ／ａ；九龙江口和厦门西海域沉积物磷的年释放量估计为１６ｔ和１３ｔ．接初级生产力估算全调查海域消耗磷约为９８１ｔ／ａ，而生物活动参与下磷的再生和转化起重要的作用。     

九龙江口海域中磷的化学形态分布

根据１９８７年３月至１９８８年１２月笔者在九龙江口、厦门西海域的调查研究资料，着重讨论颗粒态磷（ＰＰ）、溶解态无机磷（ＤＩＰ）、溶解态有机磷（ＤＯＰ）、总磷（ＴＰ）等各种形态磷的含量分布、季节变化，及其与叶绿素（Ｃｈｌ．ａ）、总悬浮物量（ＴＳＭ）等其他要素的关系。     

九龙江口、厦门西海域磷的生物地球化学研究──Ⅲ.生物活动参与下的磷形态转化及磷循环估算

１９８７年３月～１９８８年１２月笔者于九龙江口、厦门西海域的调查研究结果表明，厦门西海域特殊的地理、水文环境、沉积物的高磷量、磷形态的快速转化是西海域初级生产力［５５５ｇ／（ｍ＾２·ａ）］比九龙江口区［１５９ｇ／（ｍ＾２·ａ）］高得多的主要原因。颗粒态磷（ＰＰ）、溶解态无机磷（ＤＩＰ）、溶解态有机磷（ＤＯＰ）等以生物为媒介发生了某种程度的形态转化，本文估算了九龙江水总磷（ＴＰ）的入海通量为７８７ｔ     

九龙江口磷的界面分配和转移

１９９２年８月航次调查结果表明，九龙江口水体中磷的迁移呈保守行为，ＴＰ和ＰＰ含量随着海水盐度的降低呈增加趋势，ＤＰ含量刚好相反；Ｓ〈１５的低盐区，盐度对磷迁移的影响比较显著。     

台湾海峡中北部上升流区各种形态磷的化学特性

根据１９８８年７月调查资料讨论了台湾海峡中北部海域夏季上升流区各种形态磷的分布特征。结果表明，上升流中心区（即海坛岛东侧一带水域）具有低温、高盐、低溶解氧；ＤＩｐ，ＴＤＰ，ＰＰ，ＴＰ较高；ＤＯＰ较低（０．２７）；及ＤＩＰ／ＤＯＰ比值（约为１）较高的特性。ＤＯＰ是该海域磷的主要形态（占ＴＰ的４９．２％），其含量分布及其形态转化与生物活动直接相关，是该海域生物生产力高的体现。     

九龙江口ATP分布与环境因子的关系

本文根据１９９４年７月至１９９５年４月间４个航次调查资料而得。结果表明，九龙江口ＡＴＰ的含量平均值为２７８．４μｇ／ｍ＾３，变化范围在３２．４￣８５７．６μｇ／ｍ＾３之间。ＡＴＰ与叶绿素ａ和ＰＯＣ之间存在着正相关性。Ｃｈｌ－ａ／ＡＴＰ的高值区出现在盐度为２５￣３０间。ＰＯＣ（Ｂ）／ＰＯＣ的高温区出现在盐度为１５￣２５间。该区域颗粒碳含有最大比例的活体的有机碳约占６０％。     

九龙江口海域中磷的化学形态分布

根据１９８７年３月至１９８８年１２月笔者在九龙江口，厦门西海域的调查研究资料，着重讨论颗粒态磷，溶解态无机磷，溶解态有机磷，总磷等各种形态磷的含量分布，季节变化，及其与叶绿素，总悬浮物量等其他要素的关系。     

9810号台风过程厦门近岸海域POC的变化特征

本文研究了９８１０号台风影响下九龙江口及厦门西港表层海水颗粒有机碳（ＰＯＣ）的变化特征及其与某些环境因子的关系,除厦门西港低潮水外,台风期间ＰＯＣ含量的迅速增大,此“冲击期”共维持３ｄ后ＰＯＣ值迅速回落,进入“恢复期”。台风期间,九龙江口高低潮,厦门西港高潮表层水ＰＯＣ含量分别为０．７３９、１．３１９和０．８４８ｍｇ／ｄｍ＾３,是非台风状况下的１．１、１．９和１．４倍,陆源有机物的输入和底质再悬浮作用是控制表层水ＰＯＣ含量的主要因素,而厦门西港低潮水ＰＯＣ含量受台风作用影响较小,碎屑ＰＯＣ为厦门近岸海域表层海水ＰＯＣ的主要组成部分。ＰＯＣ与溶解态Ｎ、Ｐ营养盐有一定正相关性,暗示其可能来自颗粒物有机Ｎ、Ｐ的生物降解。     

九龙江口和厦门西港海域若干重金属元素的生物地球化学特性

根据１９８７年３月至１９８８年１２月九龙江口，厦门西港海域的调查资料，初步探讨该海域Ｆｅ，Ｍｎ，Ｃｕ，Ｚｎ，Ｎｉ，Ｃｏ，Ｐｂ，Ｃｄ等重金属元素的生物地球化学特性，及其与磷的生物地球化学的关系。结果表明该海域重金属元素的分布主要受九龙江径流的影响。在河水与海水混合过程中，悬浮颗粒态重金属元素发生明显转移，Ｆｅ，Ｍｎ，Ｃｏ，Ｚｎ等元素自悬浮颗粒物上解吸，Ｃｕ可能被吸附，颗粒态重金属元素与颗粒态磷呈良好     

九龙江口、厦门西海域磷的生物地球化学研究——Ⅱ.表层沉积物中磷形态的分布及在再悬浮过程中的转化

本文根据１９８７年３月至１９８８年１２月九龙江口、厦门西海域调查资料、讨论表层沉积物中各种形态磷的分布特征以及在沉积与再悬浮过程中磷形态的转化。结果表明表层沉积物磷含量最高值处距悬浮颗粒物最大沉降速率处下游约５ｋｍ，磷在悬浮颗粒物上主要以颗粒态有机磷存在，在表层沉积物中主要以无机结合态磷存在，缺氧的沉积环境中可溶性磷自表层沉和只物上释放以及吸附在悬浮颗粒物上的磷的解吸作用，是该水域溶解态无机磷再生     

Transfer and transport of phosphorus and silica in the turbidity maximum zone of the Changjiang estuary

The concentration of suspended particulate matter (SPM), sedimentation flux, and various forms of phosphorus and silica in turbidity maximum zone (TMZ) in the Changjiang (Yangtze) estuary was studied. Based on the budget of P and Si, their mass balances in the TMZ were calculated. Results show that the variation in concentration of dissolved inorganic silicon (DISi) was mainly controlled by seawater dilution, while that of dissolved inorganic phosphorus (DIP) was considerably affected by the buffering of suspended matter and sediment. Our experiments showed that the sedimentation fluxes of SPM and particulate inorganic phosphorus (PIP), total particulate phosphorus (TPP), particulate inorganic silicon (PISi), and biological silicon (BSi) in the TMZ were 238.4 g m⁻² d⁻¹ and 28.3, 43.1, 79.0, 63.0 mg m⁻² d⁻¹, respectively. In addition, a simple method to estimate the ratio of resuspension of sediment in the TMZ was established, with which the rate in surface and bottom waters of the TMZ accounted for 55.7 and 66.1% of the total SPM, respectively, indicating that the sediment resuspension in the TMZ influenced significantly the mass balances of P and Si. Particulate adsorbed P (60.8%) and 35.5% of total particulate P discharged from the river were filtered and then deposited in the TMZ. The input flux of PIP from the river mouth was 55.9% of that of DIP, being important as biologically available P, while that of PISi was only 3.5% of DISi, showing that particulate adsorbed Si was much less important than particulate adsorbed P.     

九龙江河口区海水水质模糊综合评价

根据九龙江河口区2011—2018年的监测数据,分析了该海域海水中无机氮(inorganic nitrogen, DIN)、活性磷酸盐(active phosphate, DIP)、化学耗氧量(chemical oxygen demand, COD)和石油类含量的年际变化趋势和平面分布特征,并应用模糊综合评价法对九龙江河口区的水质进行了评价。结果表明,2011—2018年,九龙江河口区DIN和DIP年均含量呈现先增加后降低趋势,COD年均含量呈现逐年下降趋势,而石油类年均含量总体呈波动变化趋势;DIN、DIP、COD和石油类均受九龙江径流输入的影响,含量平面分布大部分呈现西南部高于东北部的特征。模糊综合评价显示九龙江河口区水质为Ⅳ类水,主要污染物是DIN和DIP。水质综合评分值逐年变大,表明水质开始出现好转趋势。     

9810号台风期间厦门近岸海域磷的分布特征

于1998年10号台风期间及台风解除后一周内，对九龙江口和西海域表层水中总磷（TP）、溶解态无机磷（DIP）、溶解态有机磷（DOP）、颗粒态磷（PP）、颗粒态无机磷（PIP）和颗粒态有机磷（POP）进行了为期9d（10月26日至11月3日）的现场观测。根据观测结果，讨论了台风对上述各形态磷的分布特征的影响，认为台风伴随的增水、入海径流量的骤增和底质再悬浮的加剧导致表层水体中各形态磷含量的短期增加。     

Phosphorus in Bottom Sediments of Pomeranian Bay (Southern Baltic—Poland)

The paper presents the results of determination of inorganic and organic forms of phosphorus in bottom sediments of Pomeranian Bay. The sediments were collected in March and July of 1996. The following characteristics of the sediments were determined: organic matter content, forms of inorganic phosphorus: loosely adsorbed phosphorus and phosphorus bound to aluminium, calcium and iron, as well as total inorganic phosphorus. Pomeranian Bay is a shallow basin, with depth averaging between 12 and 15 m and sandy sediments prevailing. Smaller silt fractions occur only in the vicinity of the wina River estuary and in deeper northern regions of the Bay. Calcium-bound phosphorus is the dominant form of inorganic phosphorus in the Pomeranian Bay. Iron-bound phosphorus is the second most prevailing form, and aluminium-bound phosphorus the third. Loosely bound phosphorus was present in the lowest amounts. Total inorganic phosphorus in the Bay consisted of the four forms listed above, except in estuarine regions where an additional form of phosphorus occurred, most probably occluded phosphorus. High organic phosphorus concentrations were found at the wina River estuary and in the northern part of the Bay (Saßnitz Deep) corresponding to the higher organic matter content of these sediments. Sediments of Pomeranian Bay contained less phosphorus than those from the Gulf of Gda sk or Puck Bay and other parts of the Baltic Sea, suggesting that the amount of phosphorus in the sediments was determined by a number of inter-related factors, such as sediment type, amount of organic matter, the chemical composition of the sediment and oxygen content of near-bottom water.     

长江口及毗邻海区沉积物中磷的分布特征

于2006年6月和2007年4月在长江口及毗邻海区采集了表层沉积物样品,利用水淘选法对沉积物进行了粒径分级,并采用改进后的SEDEX方法对沉积物样品及分粒级沉积物样品进行了磷形态分析。结果表明,2006年6月和2007年4月长江口及毗邻海区沉积物总磷变化分别为12.56~19.64μmol/g和8.99~19.91μmol/g,其中碎屑磷是磷的主要存在形态。可交换态磷、铁结合态磷、有机磷、自生磷灰石磷及难分解有机磷在长江口外的平面分布比较一致,均在紧邻长江口门外、杭州湾外的条状带出现了含量的高值,而在口门内及口门外河口靠海一侧碎屑磷含量较高。不同形态磷在不同粒径沉积物中的含量不尽相同:有机磷、自生磷灰石磷以及难分解有机磷是小于8μm粒级沉积物中磷的主要组成部分,而且其在总磷中所占比例随沉积物粒径的增加而下降;碎屑磷则主要集中在粗沉积物中,为32~63μm及大于63μm粒级沉积物中磷的主要贡献者。沉积物的粒度分异以及各形态磷在不同粒径沉积物中含量的差异,共同影响着河口沉积物中磷的分布。     

Seasonal changes in nitrogen and phosphorus transport in the lower Changjiang River before the construction of the Three Gorges Dam

Water and sediment samples were collected at Datong from June 1998 to March 1999 to examine seasonal changes in the transports of nitrogen (N) and phosphorus (P) from the Changjiang River (Yangtze River) to the East China Sea (ECS). Dissolved inorganic nitrogen (DIN; dominated by nitrate) concentration exhibited small seasonality, and DIN flux was largely controlled by water discharge. Dissolved inorganic phosphorus (DIP) concentration was inversely correlated with water discharge, and DIP was evenly delivered throughout a year. The transports of DIN and DIP from the Changjiang River were consistent with seasonal changes in nutrient distributions and P limitation in the Changjiang Estuary and the adjacent ECS. Dissolved organic and particulate N (DON and PN) and P (DOP and PP) varied parallel to water discharge, and were dominantly transported during a summer flood. The fluxes of DOP and particulate bioavailable P (PBAP) were 2.5 and 4 times that of DIP during this period, respectively. PBAP accounted for 12–16% of total particulate P (PP), and was positively correlated with the summation of adsorbed P, Al–P and Fe–P. Ca–P, the major fraction of PP, increased with increasing percent of CaCO₃. The remobilization of riverine DOP and PBAP likely accounted for the summer elevated primary production in DIP-depleted waters in the Changjiang Estuary and the adjacent ECS. The Changjiang River delivered approximately 6% of DIN (1459 × 10⁶ kg), 1% of DIP (12 × 10⁶ kg), and 2% of dissolved organic and particulate N and P to the totals of global rivers. The construction of the Three Gorges Dam might have substantially reduced the particulate nutrient loads, thereby augmenting P limitation in the Changjiang Estuary and ECS.     

桑沟湾磷循环

The phosphorus cycle is studied during 2013–2014 in the Sanggou Bay(SGB), which is a typical aquaculture area in northern China. The forms of measured phosphorus include dissolved inorganic phosphorus(DIP), dissolved organic phosphorus(DOP), particulate inorganic phosphorus(PIP), and particulate organic phosphorus(POP).DIP and PIP are the major forms of total dissolved phosphorus(TDP) and total particulate phosphorus(TPP),representing 51%–75% and 53%–80%, respectively. The concentrations and distributions of phosphorus forms vary among seasons relative to aquaculture cycles, fluvial input, and hydrodynamic conditions. In autumn the concentration of DIP is significantly higher than in other seasons(P0.01), and higher concentrations are found in the west of the bay. In winter and spring the phosphorus concentrations are higher in the east of the bay than in the west. In summer, the distributions of phosphorus forms are uniform. A preliminary phosphorus budget is developed, and shows that SGB is a net sink of phosphorus. A total of 1.80×10~7 mol/a phosphorus is transported into the bay. The Yellow Sea is the major source of net input of phosphorus(61%), followed by submarine groundwater discharge(SGD)(27%), river input(11%), and atmospheric deposition(1%). The main phosphorus sink is the harvest of seaweeds(Saccharina japonica and Gracilaria lemaneiformis), bivalves(Chlamys farreri),and oysters(Crassostrea gigas), accounting for a total of 1.12×10~7 mol/a. Burial of phosphorus in sediment is another important sink, accounting for 7.00×10~6 mol/a. Biodeposition by bivalves is the major source of phosphorus in sediment, accounting for 54% of the total.     

黄河下游调水调沙与暴雨事件对营养盐输出通量的影响

2012年2月至2014年3月在黄河下游采集水样,分析黄河下游营养盐浓度与通量的月际、季节性以及在调水调沙期和暴雨期的变化情况,并估算了调水调沙期和洪水期输水量和营养盐入海通量对黄河年入海通量的贡献。结果表明NO₃- 是TDN的主要存在形式,各形态氮营养盐枯水期高于丰水期;DIP是TDP的主要存在形式,PIP是TPP的主要存在形态,颗粒态磷和DSi丰水期高于枯水期。黄河水体中具有高DIN/DIP和DSi/DIP,低DSi/DIN,严重偏离Redfield比值。营养盐输送通量具有很强的月际变化,在径流量及输沙量最大月份也存在营养盐入海通量峰值。2002-2012年10年间调水调沙和暴雨在营养盐输送通量上占黄河下游营养盐输送通量的23%~68%和5%~59%,对营养盐年入海通量的平均贡献分别为 38%和24%,二者均在短期内导致水、沙和营养盐的大量输送,将对黄河口及其邻近海域的生态环境产生重要的影响。     

长江口及邻近水域氮、磷的形态特征及分布研究

根据近几年大面调查的监测资料,对长江口及邻近水域氮、磷营养盐的形态组成、时空分布及氮磷比的变动规律及其影响因素进行了分析研究。结果表明,长江口及邻近水域中硝酸盐是水体无机氮存在的主要形态,其约占总无机氮的90%,无机氮含量河口高,向东南方向愈来愈低;从该水域总磷的形态组成来看,磷营养盐主要以溶解态和颗粒态共存的形式存在,TDP略高于TPP,无机磷的平面分布与无机氮十分相似,春季无机磷含量高于夏季;N/P值变动范围大和平均值较高是该水域的主要特征,N/P值与长江径流量的大小有关系,夏季N/P值比春季高,综合分析来看,磷营养盐和光照都有可能成为该水域浮游植物生长的重要限制因子。     

镭、氡同位素示踪调水调沙对黄河口水体运移及营养盐分布特征的影响

为研究调水调沙影响下的镭、氡同位素和营养盐在黄河口的分布特征,于2013年7月调水调沙期间在黄河口及其邻近海域进行了多点的连续观测。研究发现:(1)黄河口海域镭、氡同位素分布呈现明显的“分区”现象,南北两区分别为“调水调沙影响非显著区域”和“调水调沙影响显著区域”,北部海域镭、氡同位素浓度高值主要来源于陆源输入(包括河流输入和海底地下水排放);(2)调查期间,北部海域水体年龄为(2.9±1.6)d,南部海域水体年龄为(5.0±2.1)d;水龄随潮汐变化表现出涨潮时水龄增大、落潮时水龄减小的波动趋势;(3)北部海域溶解无机氮(DIN)和溶解硅(DSi)含量明显高于南部海域,而溶解无机磷(DIP)在两个区域的含量相差不大。