Properties and mixing of soil components in Apollo 17 double-drive tube 79001/2

Abstract— Previous studies of Apollo 17 double-drive tube 79001/2 showed that portions of this lunar regolith segment have some unusual properties, such as very high I_s/FeO values (Monis et al., 1989) and N contents (Stone and Clayton, 1989). To understand the geologic significance of these features in this core, we determined the grain-size distribution and modal abundance of the petrographic constituents for samples from 12 different depths of the core. Also, we measured the elemental and isotopic compositions of noble gases in the coarse-grained (150–250 μm) and fine-grained (<20 μm) sample fractions from four depths of this core. The agglutinate abundance and ³⁶Ar contents show depth-related variations similar to those observed for I_s/FeO and N in this core. Samples from the top (～0.5 cm depth) and the bottom (～45 cm depth) of the drive tube are related to Apollo 17 submature soils with about 250–300 Ma galactic cosmic-ray (GCR) exposure age. But the soil at the top of the drive tube received additional surface irradiation for ～2 Ma after deposition at Van Serg. The samples at intermediate depths (i.e., ～7 cm (upper zone) and ～20 cm (lower zone) of the 79001/2 core) show features characteristic of mixtures of Apollo 17 mature soils and finely comminuted regolith breccias having about 600–800 Ma GCR exposure age. The mixing ratios between the coarse and fine fractions of the intermediate-depth samples are similar to each other. Though the mixing ratios for the samples from the top and the bottom of the core are also similar to each other, they differ significantly from the ratios at intermediate depths. The results presented here are consistent with the two-component Van Serg core model proposed by Stone and Clayton (1989) and McKay et al. (1988).     

Aluminum-26, sodium-22 and cobalt-60 in two drill cores and some other samples of the Jilin chondrite

Abstract— Two drill cores have been taken from the main mass of the Jilin chondrite, Jilin I. One was bored perpendicular to the 2π surface of the first exposure stage, the other parallel to this surface, and both intersected at the presumed 4π center of Jilin's second exposure stage. The probed depths were 65 cm and 105 cm, respectively, with a diameter of 26.5 mm. Fifteen drill core samples, 2 documented samples and 14 strewn field samples have been analysed for ²⁶Al, ⁶⁰Co and ²²Na. The reconstruction of the preatmospheric Jilin via ⁶⁰Co resulted in slight deviations for the center position and for the radius (now R = 80⁺¹⁰_?5 cm) compared to an earlier study in 1985. The ⁶⁰Co production rate profile is now almost completely reproduced. A constant production rate of ²²Na and of ²⁶Al during the 4π irradiation is confirmed also for the center region. The good linear correlation of ²⁶Al and ²¹Ne yields slightly revised irradiation ages for both stages of t₁ = 7 ± 1 Ma and t₂ = 0.32^+0.06-_0.03 Ma.     

Light noble gases in Jilin: More of the same and something new

Abstract— Results are reported for documented samples from two drill cores and for specimens from the strewn field of the largest known stone meteorite, the H chondrite Jilin. Core B was found to have been parallel to the surface of Jilin during its first stage of irradiation, in 2π geometry. Core A was normal to the 2π surface; in it the mean attenuation length for the production by galactic cosmic rays of ³⁸Ar from metal and of ²¹Ne from Mg, Al, Si in silicates was found to be the same. A numerical value for the mean attenuation length of (71 ± 4) cm or (246 ± 14) g × cm^?2 follows if corrections for the contribution from the second stage of exposure are based on T₂ = 0.32 Ma; agreement with the lower values of ～180 g × cm^?2 obtained from lunar studies and target data requires T₂ to be about twice as long. Previous results are confirmed that in specimens with high contents of stable spallogenic gases the ratio ²¹Ne_bulk/³⁸Ar_metal is low. The suggestion had been, and is, mat this is a transition effect in near-surface samples where the secondary cascade of nuclear-active particles, and hence the production of ²¹Ne, was not yet fully developed. This suggestion is borne out by the present results on two samples that, based on cosmic-ray tracks and ⁶⁰Co content, are certified near-surface samples (although, strictly speaking, this is true only for the depth of burial during the second stage of irradiation). Cosmic-ray produced ⁶⁰Co is positively correlated with ⁴He content, indicating that significant losses of ⁴He occurred when the Jilin meteoroid had acquired already its final size and shape and that the losses were more severe for near-surface samples than for such from the 4π interior. Presumably, the losses were caused by a thermal spike associated with the excavation of Jilin from its parent body. The same event caused losses of part of the ³He produced during the first irradiation stage. From the systematics of the ³He/²¹Ne vs. ⁴He correlation, we derive for the second 4π irradiation a production ratio ³He/²¹Ne = 3.2 ± 0.4.     

Simulation of the interaction of galactic cosmic ray protons with meteoroids: On the production of 3H and light noble gas isotopes in isotropically irradiated thick gabbro and iron targets

Abstract— Thick spherical targets, one made of gabbro (R = 25 cm) and one made of iron (R = 10 cm), were irradiated isotropically with 1.6 GeV protons at Laboratoire National Saturne (LNS)/Saclay to simulate the interactions of galactic cosmic ray protons with meteoroids in space. At various depths, both artificial meteoroids contained a large number of high‐purity, single‐element target foils and chemical compounds of up to 28 target elements. In these individual target foils, the elemental production rates of radionuclides and noble gas isotopes were measured. Here, we report the results for the light noble gas isotopes ^3,4He, ^20,21,22Ne, and ^36,38,39Ar for the most cosmochemically relevant target elements as well as for some meteoritic material from Jilin, Farmington, and Cape York. From ³He analyses done several years apart, ³H diffusive losses during sample storage have been obtained, and direct as well as cumulative ³He production rates for O, Mg, Al, Si, Fe, Ni, and the meteoritic material are given. Losses by diffusion of tritium from metallic Mg and Fe are found to occur on time scales of months, while metallic Al, Si, and stone meteorites are much more retentive. The production rate ratios P(³H)/P(³He)_d obtained in the simulation experiments are 0.73, 1.28, and 1.16 for O, Al, and Si, respectively. These rates are based on our best knowledge about the ³H and ³He production rates and should, therefore, replace data published earlier (Leya et al. 2000a). The earlier calculations for ⁴He, ^20,21,22Ne, and ^36,38,39Ar remain valid. The new modeled correlation ³He_cum/²¹Ne versus ²²Ne/²¹Ne for chondrites exposed to cosmic rays with an energy spectrum characterized by a modulation parameter of φ = 650 MeV is in fair agreement with the empirical relationship (“Berne plot”). However, for small meteorites and little shielding in larger ones, there are systematic differences that most likely are due to an underestimation of the spallogenic ²²Ne/²¹Ne ratio by ?2%.     

Noble gases and cosmogenic radionuclides in the Gold Basin L4 chondrite shower: Thermal history,exposure history,and pre‐atmospheric size

Abstract— We measured the concentrations of the cosmogenic radionuclides ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca in the stone and metal fractions of 15 fragments of the Gold Basin L4 chondrite shower, as well as noble gases in 18 Gold Basin fragments. A comparison of ¹⁰Be, ²⁶Al, and ⁴¹Ca concentrations with calculated production rates from two different models indicates that the Gold Basin samples came from depths of about 10 cm to more than 150 cm in an object with a radius of 3–5 m. As was predicted by recent model calculations, the noble gases show a reversal of the ²²Ne/²¹Ne ratio at very high shielding. The ²¹Ne/¹⁰Be and ²¹Ne/²⁶Al ratios in most samples are constant and correspond to a 4π exposure age of 18 ± 2 Myr. However, three Gold Basin samples show a 30–120% excess of ²¹Ne implying that they were previously exposed close to the surface of the parent body, whereas the other samples were buried several meters deeper. Concentrations of neutron‐capture ³⁶Ar in most samples are consistent with measured concentrations of neutron‐capture ³⁶Cl and an exposure age of 18 Myr. Large excesses of neutron‐capture ³⁶Ar were found in those samples with an excess of ²¹Ne, providing additional evidence of a first‐stage exposure on the parent body. The excess of spallation‐produced ²¹Ne and neutron‐capture‐produced ³⁶Ar in these samples indicate a first‐stage exposure of 35–150 Myr on the parent body. The radiogenic ⁴He and ⁴⁰Ar concentrations indicate a major impact on the parent body between 300 and 400 Myr ago, which must have preceded the impacts that brought the Gold Basin meteoroid to the surface of the parent body and then expelled it from the parent body 18 Myr ago.     

Solar-proton-produced neon in shergottite meteorites and implications for their origin

Abstract— Measured Ne isotopes in samples of shergottite ALHA77005 show variations in ²¹Ne/²²Ne ratios and ²¹Ne abundances that are consistent with the presence of two cosmogenic components: a component produced by nuclear interactions of galactic cosmic rays (GCR) and a component produced at shallow shielding depths (～0–3 cm) by energetic solar flare protons (SCR). We suggest that the ²¹Ne/²²Ne ratio generally can be used to distinguish between SCR and GCR components in many meteorite types. Analysis of cosmogenic Ne produced in chondrite mineral separates, eucrites, and anorthositic lunar rocks, all having diverse major element compositions, indicate that the GCR ²¹Ne/²²Ne ratio increases modestly with relative Mg content. Data for hundreds of chondrite analyses suggest that SCR Ne is present in no more than a very small fraction of chondrites. Examination of literature data for other shergottites, however, indicate that all of these meteorites contain SCR Ne but that it is apparently absent in other SNC meteorites. The ubiquitous presence of SCR Ne in shergottites, in contrast to most other types of meteorites, suggests that the martian origin of shergottites gave them different orbital parameters compared to other meteorites. This in turn may have contributed to slower entry velocities and lesser surface ablation in the atmosphere or even to higher SCR production rates.     

Cosmogenic and trapped noble gases in individual chondrules: Clues to chondrule formation

Abstract— We studied the elemental and isotopic abundances of noble gases (He, Ne, Ar in most cases, and Kr, Xe also in some cases) in individual chondrules separated from six ordinary, two enstatite, and two carbonaceous chondrites. Most chondrules show detectable amounts of trapped ²⁰Ne and ³⁶Ar, and the ratio (³⁶Ar/²⁰Ne)_t (from ordinary and carbonaceous chondrites) suggests that HL and Q are the two major trapped components. A different trend between (³⁶Ar/²⁰Ne)_t and trapped ³⁶Ar is observed for chondrules in enstatite chondrites indicating a different environment and/or mechanism for their formation compared to chondrules in ordinary and carbonaceous chondrites. We found that a chondrule from Dhajala chondrite (DH‐11) shows the presence of solar‐type noble gases, as suggested by the (³⁶Ar/²⁰Ne)_t ratio, Ne‐isotopic composition, and excess of ⁴He. Cosmic‐ray exposure (CRE) ages of most chondrules are similar to their host chondrites. A few chondrules show higher CRE age compared to their host, suggesting that some chondrules and/or precursors of chondrules have received cosmic ray irradiation before accreting to their parent body. Among these chondrules, DH‐11 (with solar trapped gases) and a chondrule from Murray chondrite (MRY‐1) also have lower values of (²¹Ne/²²Ne)_c, indicative of SCR contribution. However, such evidences are sporadic and indicate that chondrule formation event may have erased such excess irradiation records by solar wind and SCR in most chondrules. These results support the nebular environment for chondrule formation.     

Cosmogenic nuclides in core samples of the Chico L6 chondrite: Evidence for irradiation under high shielding

Abstract— Core samples were obtained from various locations of the ～ 105-kg Chico, NM, L6 chondrite in order to study the effects of large shielding on the production rates of cosmic-ray-produced nuclides. Relations between measured abundances of cosmogenic nuclides (¹⁰Be, ²⁶Al, and stable isotopes of He, Ne, and Ar) and the cosmogenic ²²Ne/²¹Ne ratio were determined and compared with recent model predictions of production rates. The measured ²²Ne/²¹Ne ratios (1.06-1.08) and significant variations observed in concentrations of cosmogenic ²¹Ne and ³He suggest an ～40-cm shielding gradient across Chico and irradiation within a large object (> 100-cm radius). Noble gas data indicate that Chico experienced greater shielding than chondrites Knyahinya or Keyes and similar to Jilin. Values of ¹⁰Be (average = 20.7 dpm/kg) and ²⁶Al (average = 71.1 dpm/kg) are nearly constant, however, and show no correlation with either ²²Ne/²¹Ne or ²¹Ne. Activities of ¹⁰Be and ²⁶Al suggest irradiation in a smaller object (～40–80 cm radius). The ²⁶Al activity and the ²⁶Al/¹⁰Be ratio (average value = 3.42) are both significantly larger than values for most other chondrites. These results could indicate a two-stage irradiation with t₁ ～ 104 Ma and t₂ ～ 4 Ma and a second-stage body the size of Knyahinya. The single stage, ¹⁰Be/²¹Ne exposure age for Chico is 65 Ma. The ²²Ne/²¹Ne ratio apparently becomes insensitive to shielding for objects the size of Chico. No substantial evidence exists for chondrites with ²²Ne/²¹Ne ratios significantly less than ～ 1.055.     

On the Bur Gheluai H5 chondrite and other meteorites with complex exposure histories

Abstract— We present the ¹⁴C, ²⁶Al, ¹⁰Be, ³He, ⁴He, ²⁰Ne, ²¹Ne, ²²Ne, ³⁶Ar, ³⁸Ar, and ⁴⁰Ar concentrations and the track densities measured in up to 13 samples of the Bur Gheluai (H5) meteorite fall. Only a multi-stage exposure history can explain the data in a self-consistent way. Parameters for a model two-stage history obtained by simultaneous, least-squares fitting of the concentrations of ¹⁴C, ²⁶Al, ¹⁰Be, and ²¹Ne were: first stage duration ～10 Ma and radius >2 m; second stage duration ～0.6 Ma and radius 40–100 cm. Nominal one-stage ²¹Ne production rates (P₂₁) inferred from ²⁶Al in Bur Gheluai samples exceed those inferred from ¹⁰Be as expected for a meteorite with a complex history. Nonetheless, data for other meteorites indicate that multi-stage irradiations alone do not account for all the high reported values of P₂₁ based on ²⁶A***l: The equations describing the production of cosmogenic nuclides show that uncorrected shielding effects may also play a role. A compilation of ordinary, solar-gas-poor chondrites for which two-stage histories have been proposed includes many with short second stages but none with unambiguously long first stages (>0.2 Ga).     

Exposure history of the St‐Robert (H5) fall

Abstract— The compositionally typical H5 chondrite St‐Robert has an exposure age, 7.8 Ma, indistinguishable from that of the main cluster of H chondrites. Small values of the cosmogenic ²²Ne/²¹Ne ratio in interior samples imply a pre‐atmospheric radius on the order of 40 cm. Sample depths based on tracks and the production rates of Bhattacharya et al. (1973) range from 6 to ～40 cm and are generally larger than depths estimated from published ⁶⁰Co activities, perhaps because the track production rates adopted are too high. Depth profiles of the production rates of ¹⁴C, ³⁶Cl, ²⁶Al, ¹⁰Be, and ²¹Ne in stony material show increases with depth and reach levels 5% to 15% higher than expected from modeling calculations. The maximum concentrations in St‐Robert are, however, generally comparable to those measured for the L5 chondrite, Knyahinya, whose pre‐atmospheric radius of ～45 cm is thought to lead to the maximum possible production rates in chondrites. We infer that the pre‐atmospheric radius of St‐Robert was within 5 cm of the value that supports maximum production rates (i.e., 45 ± 5 cm). This radius corresponds to a pre‐atmospheric mass of (1.3 ± 0.4) × 10³ kg. The agreement of exposure ages for St‐Robert obtained in several different ways and the similarity of the depth profiles for ¹⁴C, ²⁶Al, ¹⁰Be, and ²¹Ne argue against a lengthy pre‐exposure of St‐Robert on the parent body and against a two‐stage exposure after launch from the parent body. Following Morbidelli and Gladman (1998), we suggest that St‐Robert was chipped from deep in its parent body, spent the next 7–8 Ma without undergoing a major collision, was nudged gradually into an orbital resonance with Jupiter, and then traveled quickly to Earth.     

The production of cosmogenic nuclides by galactic cosmic‐ray particles for 2π exposure geometries

Abstract— We present a purely physical model for the calculation of depth‐dependent production rates in 2π exposure geometries by galactic cosmic rays (GCR). Besides the spectra of primary and secondary particles and the excitation functions of the underlying nuclear reactions, the model is based on the integral number of GCR particles in the lunar orbit. We derived this value from adjusting modeled depth profiles for ¹⁰Be, ²⁶Al, and ⁵³Mn to measured data from the Apollo 15 drill core. The J_0,GCR value of 4.54 cm^?2 s^?1 and the solar modulation parameter of M = 490 MeV determined this way for 1 AU is in reasonable agreement with the J_0,GCR value derived recently for the meteoroid orbits (Leya et al., 2000b). We also show that the mean GCR proton spectrum in the lunar orbit has not changed substantially over about the last 10 Ma. For the major target elements we present depth‐dependent production rates for ¹⁰Be, ¹⁴C, ²⁶Al, ³⁶Cl and ⁵³Mn, as well as for the rare gas isotopes ^20,21,22Ne. In addition we present production rates for ^36,38Ar from Fe and Ni. The new results are consistent with the data for stony meteoroids presented recently by our group (Leya et al., 2000b), but for the rare gas isotopes the new production rates sometimes differ significantly from earlier estimates. The applicability of the ²²Ne/²¹Ne ratio as a shielding parameter is also discussed.     

Cosmogenic nuclides in the solar gas‐rich H3–6 chondrite breccia Frontier Mountain 90174

Abstract— We re‐evaluated the cosmic‐ray exposure history of the H3‐6 chondrite shower Frontier Mountain (FRO) 90174, which previously was reported to have a simple exposure history, an irradiation time of about 7 Ma, and a pre‐atmospheric radius of 80–100 cm (Welten et al. 2001). Here we measured the concentrations and isotopic compositions of He, Ne, and Ar in 8 aliquots of 6 additional fragments of this shower, and ¹⁰Be and ²⁶Al in the stone fractions of seven fragments. The radionuclide concentrations in the stone fractions, combined with those in the metal fractions, confirm that all samples are fragments of the FRO 90174 shower. Four of the fragments contain solarwind‐implanted noble gases with a solar ²⁰Ne/²²Ne ratio of ?12.0, indicating that FRO 90174 is a regolith breccia. The concentrations of solar gases and cosmogenic ²¹Ne in the samples analyzed by us and by Welten et al. (2001) overlap with those of the FRO H‐chondrites from the 1984 season, suggesting that many of these samples are also part of the large FRO 90174 chondrite shower. The cosmogenic ²¹Ne concentrations in FRO 90174 show no simple correlation with ¹⁰Be and ²⁶Al activities. We found ²¹Ne excesses between 0.3‐1.1 × 10^?8cm³STP/g in 6 of the 17 samples. Since excess ²¹Ne and trapped solar gases are not homogeneously distributed, i.e., we found in one fragment aliquots with and without excess ²¹Ne and solar ²⁰Ne, we conclude that excess ²¹Ne is due to GCR irradiation of the regolith before compaction of the FRO 90174 object. Therefore, the chondrite shower FRO 90174 did not simply experience an exposure history, but some material was already irradiated at the surface of an asteroid leading to excess ²¹Ne. This excess ²¹Ne is correlated to implanted solar gases, clearly indicating that both processes occurred on the regolith.     

The production of cosmogenic nuclides in stony meteoroids by galactic cosmic‐ray particles

Abstract— We present a purely physical model for the calculation of depth‐ and size‐dependent production rates of cosmogenic nuclides by galactic cosmic‐ray (GCR) particles. besides the spectra of primary and secondary particles and the excitation functions of the underlying nuclear reactions, the model is based on only one free parameter—the integral number of gcr particles in the meteoroid orbits. We derived this value from analysis of radionuclide data in Knyahinya. We also show that the mean GCR proton spectrum in the meteoroid orbits has been constant over about the last 10 Ma. For the major target elements in stony meteoroids, we present depth‐ and size‐dependent production rates for ¹⁰Be, ¹⁴C, ²⁶Al, ³⁶Cl, and ⁵³Mn as well as for the rare gas isotopes ³He, ²⁰Ne, ²¹Ne, ²²Ne, ³⁶Ar, and ³⁸Ar. The new data differ from semi‐empirical estimates by up to a factor of 4 but agree within ～20% with results obtained by earlier parametric or physical approaches. The depth and size dependence of the shielding parameter ²²Ne/²¹Ne and the correlations ²⁶Al vs. ¹⁰Be, ²⁶Al vs. ⁵³Mn, ¹⁰Be/²¹Ne vs. ²²Ne/²¹Ne, and ³⁶Ar vs. ³⁶Cl for deciphering preatmospheric sizes, shielding depths, terrestrial residence times, and exposure histories are also discussed.     

Calibration of cosmogenic noble gas production in ordinary chondrites based on 36Cl‐36Ar ages. Part 1: Refined produced rates for cosmogenic 21Ne and 38Ar

We measured the concentrations and isotopic compositions of He, Ne, and Ar in bulk samples and metal separates of 14 ordinary chondrite falls with long exposure ages and high metamorphic grades. In addition, we measured concentrations of the cosmogenic radionuclides ¹⁰Be, ²⁶Al, and ³⁶Cl in metal separates and in the nonmagnetic fractions of the selected meteorites. Using cosmogenic ³⁶Cl and ³⁶Ar measured in the metal separates, we determined ³⁶Cl‐³⁶Ar cosmic‐ray exposure (CRE) ages, which are shielding‐independent and therefore particularly reliable. Using the cosmogenic noble gases and radionuclides, we are able to decipher the CRE history for the studied objects. Based on the correlation ³He/²¹Ne versus ²²Ne/²¹Ne, we demonstrate that, among the meteorites studied, only one suffered significant diffusive losses (about 35%). The data confirm that the linear correlation ³He/²¹Ne versus ²²Ne/²¹Ne breaks down at high shielding. Using ³⁶Cl‐³⁶Ar exposure ages and measured noble gas concentrations, we determine ²¹Ne and ³⁸Ar production rates as a function of ²²Ne/²¹Ne. The new data agree with recent model calculations for the relationship between ²¹Ne and ³⁸Ar production rates and the ²²Ne/²¹Ne ratio, which does not always provide unique shielding information. Based on the model calculations, we determine a new correlation line for ²¹Ne and ³⁸Ar production rates as a function of the shielding indicator ²²Ne/²¹Ne for H, L, and LL chondrites with preatmospheric radii less than about 65 cm. We also calculated the ¹⁰Be/²¹Ne and ²⁶Al/²¹Ne production rate ratios for the investigated samples, which show good agreement with recent model calculations.     

Meteorite Ablation Evaluated from Data on the Distribution of Cosmogenic Neon Isotopes

The type of the functional dependence of the ratio of the production rates of the cosmogenic isotopes ²²Ne/²¹Ne_c on their location depth d (cm) in ordinary chondrites with a radius R 60 cm was determined on the basis of experimental data on the elemental production rates of cosmogenic Ne isotopes in chondrites (Leya et al., 2000a). The dependence found is of the type ²²Ne/²¹Ne_c = Aexp(–Bd) + C, where the parameters A, B, and C are determined from the relationships: B = 0.560exp(–0.0105R) – 0.187, C = 0.170exp(–0.092R) + 1.083, and 0.170exp(–0.092R) + 1.144. These relationships were used to calculate the average weighted values of the ²²Ne/²¹Ne_c ratio for the volume of the fallen meteorite depending on its given preatmospheric radius. The data obtained served as a basis for plotting a nomogram that makes it possible to estimate the mass lost during passage through the Earth's atmosphere (ablation quantity) from the mass of the fallen meteorite and the average value of the ²²Ne/²¹Ne_c ratio measured in it. The average (median) value of ablation found for 262 chondrites was 91.5^+2.1 _–2.6%. In addition to the earlier-established (Alexeev, 2001a; Alexeev, 2001b) peculiarities of H5-chondrites that distinguish them from H-chondrites of other petrologic types, H5-chondrites appeared to exhibit a higher degree of ablation. The observed effect and other distinctive features of H5-chondrites may be due to the specific evolution of the parent body of H-chondrites in the process of its disintegration, reaccumulation, and subsequent reworking of the surface layers.     

Primordial noble gases in “phase Q” in carbonaceous and ordinary chondrites studied by closed‐system stepped etching

Abstract— The HF/HCI‐resistant residues of the chondrites CM2 Cold Bokkeveld, CV3 (ox.) Grosnaja, CO3.4 Lancé, CO3.7 Isna, LL3.4 Chainpur, and H3.7 Dimmitt have been measured by closed‐system stepped etching (CSSE) in order to better characterise the noble gases in “phase Q”, a major carrier of primordial noble gases. All isotopic ratios in phase Q of the different meteorites are quite uniform, except for (²⁰Ne/²²Ne)_Q. As already suggested by precise earlier measurements (Schelhaas et al., 1990; Wieler et al., 1991, 1992), (²⁰Ne/²²Ne)_Q is the least uniform isotopic ratio of the Q noble gases. The data cluster ～10.1 for Cold Bokkeveld and Lancé and 10.7 for Chainpur, Grosnaja, and Dimmitt, respectively. No correlation of (²⁰Ne/²²Ne)_Q with the classification or the alteration history of the meteorites has been found. The Ar, Kr, and Xe isotopic ratios for all six samples are identical within their uncertainties and similar to earlier Q determinations as well as to Ar‐Xe in ureilites. Thus, an unknown process probably accounts for the alteration of the originally incorporated Ne‐Q. The noble gas elemental compositions provide evidence that Q consists of at least two carbonaceous carrier phases “Q1” and “Q2” with slightly distinct chemical properties. Ratios (Ar/Xe)_Q and (Kr/Xe)_Q reflect both thermal metamorphism and aqueous alteration. These parent‐body processes have led to larger depletions of Ar and Kr relative to Xe. In contrast, meteorites that suffered severe aqueous alteration, such as the CM chondrites, do not show depletions of He and Ne relative to Ar but rather the highest (He/Ar)_Q and (Ne/Ar)_Q ratios. This suggests that Q1 is less susceptible to aqueous alteration than Q₂. Both subphases may well have incorporated noble gases from the same reservoir, as indicated by the nearly constant, though very large, depletion of the lighter noble gases relative to solar abundances. However, the elemental ratios show that Q₁ and Q₂ must have acquired (or lost) noble gases in slightly different element proportions. Cold Bokkeveld suggests that Q₁ may be related to presolar graphite. Phases Q₁ and Q₂ might be related to the subphases that have been suggested by Gros and Anders (1977). The distribution of the ²⁰Ne/²²Ne ratios cannot be attributed to the carriers Q₁ and Q₂. The residues of Chainpur and Cold Bokkeveld contain significant amounts of Ne‐E(L), and the data confirm the suggestion of Huss (1997) that the ²²Ne‐E(L) content, and thus the presolar graphite abundances, are correlated with the metamorphic history of the meteorites.     

The L3–6 chondritic regolith breccia Northwest Africa (NWA) 869: (II) Noble gases and cosmogenic radionuclides

Abstract– We measured cosmogenic radionuclides and noble gases in the L3–6 chondrite breccia Northwest Africa (NWA) 869, one of the largest meteorite finds from the Sahara. Concentrations of ¹⁰Be, ²⁶Al, and ³⁶Cl in stone and metal fractions of six fragments of NWA 869 indicate a preatmospheric radius of 2.0–2.5 m. The ¹⁴C and ¹⁰Be concentrations in three fragments yield a terrestrial age of 4.4 ± 0.7 kyr, whereas two fragments show evidence for a recent change in shielding, most likely due to a recent impact on the NWA meteoroid, approximately 10⁵ yr ago, that excavated material up to approximately 80 cm deep and exposed previously shielded material to higher cosmic‐ray fluxes. This scenario is supported by the low cosmogenic ³He/²¹Ne ratios in these two samples, indicating recent loss of cosmogenic ³He. Most NWA samples, except for clasts of petrologic type 4–6, contain significant amounts of solar Ne and Ar, but are virtually free of solar helium, judging from the trapped ⁴He/²⁰Ne ratio of approximately 7. Trapped planetary‐type Kr and Xe are most clearly present in the bulk and matrix samples, where abundances of ¹²⁹Xe from decay of now extinct ¹²⁹I are highest. Cosmogenic ²¹Ne varies between 0.55 and 1.92 × 10^?8 cm³ STP g^?1, with no apparent relationship between cosmogenic and solar Ne contents. Low cosmogenic (²²Ne/²¹Ne)_c ratios in solar gas free specimens are consistent with irradiation in a large body. Combined ¹⁰Be and ²¹Ne concentrations indicate that NWA 869 had a 4π cosmic‐ray exposure (CRE) age of 5 ± 1 Myr, whereas elevated ²¹Ne concentrations in several clasts and bulk samples indicate a previous CRE of 10–30 Myr on the parent body, most probably as individual components in a regolith. Unlike many other large chondrites, NWA 869 does not show clear evidence of CRE as a large boulder near the surface of its parent body. Radiogenic ⁴He concentrations in most NWA 869 samples indicate a major outgassing event approximately 2.8 Gyr ago that may have also resulted in loss of solar helium.     

Cosmic‐ray exposure ages of pallasites

We analyzed cosmogenic nuclides in metal and/or silicate (primarily olivine) separated from the main‐group pallasites Admire, Ahumada, Albin, Brahin, Brenham, Esquel, Finmarken, Glorieta Mountain, Huckitta, Imilac, Krasnojarsk, Marjalahti, Molong, Seymchan, South Bend, Springwater, and Thiel Mountains and from Eagle Station. The metal separates contained an olivine fraction which although small, <1 wt% in most cases, nonetheless contributes significantly to the budgets of some nuclides (e.g., up to 35% for ²¹Ne and ²⁶Al). A correction for olivine is therefore essential and was made using model calculations and/or empirical relations for the production rates of cosmogenic nuclides in iron meteoroids and/or measured elemental concentrations. Cosmic‐ray exposure (CRE) ages for the metal phases of the main‐group pallasites range from 7 to 180 Ma, but many of the ages cluster around a central peak near 100 Ma. These CRE ages suggest that the parent body of the main‐group pallasites underwent a major break‐up that produced most of the meteorites analyzed. The CRE age distribution for the pallasites overlaps only a small fraction of the distribution for the IIIAB iron meteorites. Most pallasites and IIIAB irons originated in different collisions, probably on different parent bodies; a few IIIABs and pallasites may have come out of the same collision but a firm conclusion requires further study. CRE ages calculated from noble gas and radionuclide data of the metal fraction are higher on average than the ²¹Ne exposure ages obtained for the olivine samples. As the metal and olivine fractions were taken in most cases from different specimens, the depth‐dependency of the production rate ratio ¹⁰Be/²¹Ne in metal, not accounted for in our calculations, may explain the difference.     

26AI LOSSES FROM WEATHERED CHONDRITES

He, Ne and Ar have been measured in 8 samples of Dalgety Downs (DD) and 5 samples of Ness County, 1894 (NC). ²⁶Al, K, Th and U have been measured in 4 samples of DD and the chondrites Etter, Bledsoe, Seminole #2 and Zerga. Weathering probably explains the correlation between ²⁶Al and ²¹Ne in DD, the independence of ³He/²¹Ne and ²²Ne/²¹Ne in DD and NC and the > 2σ reduction of all ²⁶Al contents from calculated saturation values.     

Devgaon (H3) chondrite: Classification and complex cosmic ray exposure history

Abstract— The Devgaon meteorite fell in India on February 12, 2001 and was immediately collected. It is an ordinary chondrite having a number of SiO₂‐rich objects and some Ca, Al‐rich inclusions. Olivines (Fa_17–19) are fairly equilibrated, while pyroxenes (Fs_4–20) are unequilibrated. Occasionally, shock veins are visible, but the bulk rock sample is very weakly shocked (S2). Chondrules and chondrule fragments are abundant. Based on chemical and petrological features, Devgaon is classified as an H3.8 group chondrite. Several cosmogenic radionuclides ranging in half‐lives from 5.6 d (⁵²Mn) to 7.3 times 10⁵ yr (²⁶Al), noble gases (He, Ne, Ar, Kr, and Xe), and particle track density have been measured. The track density in olivines from five spot samples varies between (4.6 to 9) × 10⁶ cm^?2 showing a small gradient within the meteorite. The light noble gases are dominated by cosmogenic and radiogenic components. Large amounts of trapped gases (Ar, Kr, and Xe) are present. In addition, (n, γ) products from Br and I are found in Kr and Xe, respectively. The average cosmic ray exposure age of 101 ± 8 Ma is derived based on cosmogenic ³⁸Ar, ⁸³Kr, and ¹²⁶Xe. The track production rates correspond to shielding depths of about 4.9 to 7.8 cm, indicating that the stone suffered type IV ablation. Low ⁶⁰Co, high (²²Ne/²¹Ne)_c, and large neutron produced excesses at ⁸⁰Kr, ⁸²Kr, and ¹²⁸Xe indicate a complex exposure history of the meteoroid. In the first stage, a meter‐sized body was exposed for nearly 10⁸ yr in the interplanetary space that broke up in ?50 cm‐sized fragments about a million years ago (stage 2), before it was captured by the Earth.