Nitrogen and phosphorus concentrations within North Inlet,South Carolina—Speculation as to sources and sinks

The daily concentrations of $\text{NH}{}_4{}^{\mathrm{+}}$, $\text{NO}{}_3{}^{\mathrm{?}}$, and $\text{NO}{}_3{}^{\mathrm{?}}\text{+ NO}{}_2{}^{\mathrm{?}}$ within the North Inlet system are all negatively associated with tidal stage during the late summer, this association breaking down during the winter. The high concentrations of these constituents during low tide coupled with the lack of streamflow during the late summer suggests that there is an internal source for these species. Ammonium and orthophosphate most likely have their source in sediment diffusion from tidal creek sediments and/or seepage from the vegetated marsh surface during tidal exposure. It is hypothesized that high nitrate plus nitrite values at low tide are caused by nitrification within the tidal water or tidal creek sediments. During the summer there is evidence for a source of dissolved organic nitrogen and dissolved organic phosphorus within the North Inlet system, probably via diffusion from creek sediments. In general the main source of dissolved organic nitrogen is via stream-flow from the adjacent watershed. Particulate nitrogen and phosphorus concentrations are a function of: (1) wind and rain events which cause resuspension of particulate material from the tidal creek banks, (2) rain events which scour the marsh surface during tidal exposure, and (3) high tidal velocities which scour the creek bottoms.     

A modeling study of the dynamics of pore water seepage from intertidal marsh sediments

A numerical boundary integral equation model has been used to simulate tidally driven transient variations in pore water seepage from salt marsh sediments into tidal channels and its subsequent recharge by tidal inundation. In general the results show that the maximum seepage discharge occurs at or near the intersection of the creek bank and the channel water surface. Over a tidal cycle typically two-thirds of the total seepage discharge occurs through the creek bank with only about a third discharging from the channel bottom. Of the creek-bank discharge up to a third occurs through the seepage face that develops above the tide line at tidal stages below mean tide. These results indicate that placement of seepage meters only on the channel bottom will not give samples or measures representative of the total seepage. Of the total recharge only about 5% occurs through the upper part of the creek bank with the remainder infiltrating vertically through the marsh platform during early stages of tidal submergence. For the platform recharge about 80% occurs within 3 m of the creek bank. Thus, most of the water that seeps out of marsh sediments is derived from sediments that lie within several meters of the creek bank and accordingly has had a relatively short residence (one to two years) in the marsh. Compared to the distal portion of the marsh this relatively rapid flushing may enhance the productivity of Spartina alterniflora in the creek-bank environment and control the differential generation of radium quartet isotopes.     

Tidal exchange between a freshwater tidal marsh and an impacted estuary: the Scheldt estuary, Belgium

Tidal marsh exchange studies are relatively simple tools to investigate the interaction between tidal marshes and estuaries. They have mostly been confined to only a few elements and to saltwater or brackish systems. This study presents mass-balance results of an integrated one year campaign in a freshwater tidal marsh along the Scheldt estuary (Belgium), covering oxygen, nutrients (N, P and Si), carbon, chlorophyll, suspended matter, chloride and sulfate. The role of seepage from the marsh was also investigated. A ranking between the parameters revealed that oxygenation was the strongest effect of the marsh on the estuarine water. Particulate parameters showed overall import. Export of dissolved silica (DSi) was more important than exchange of any other nutrient form. Export of DSi and import of total dissolved nitrogen (DIN) nevertheless contributed about equally to the increase of the Si:N ratio in the seepage water. The marsh had a counteracting effect on the long term trend of nutrient ratios in the estuary.     

Geomorphological control of subsurface hydrology in the creekbank zone of tidal marshes

A combination of field and numerical modeling methods was used to assess porewater movement in a narrow (20 m) Spartina marsh which was flooded regularly by tidal waters. Soil composition and soil hydraulic properties did not vary across the marsh or with depth. Hydraulic head was monitored on a transect perpendicular to the creekbank. During exposure of the marsh surface, hydraulic gradients were predominantly horizontal; vertical gradients were small or zero. Subsurface flow was directed from the marsh interior toward the creekbank. Approximately 141 of pore water were discharged laterally to the adjacent tidal creek per meter of creekbank over a complete tidal cycle.A numerical hydrological model was modified to simulate subsurface hydraulics in the creekbank vicinity of regularly flooded tidal marshes. The model was parameterized to represent soil conditions, tidal fluctuations and topography at the field site. Observed changes in hydraulic head over complete tidal cycles were accurately predicted by the model. Model simulations identified the vertical infiltration of creek water into the marsh surface at the onset of tidal flooding as the primary source (66%) for the replacement of water drained at the creekbank. Significant replacement (31%) also occurred as discharge from the interior marsh. Horizontal recharge at the creekbank was minimal (3%).A sensitivity analysis was conducted with the model to assess the relative importance of geomorphological factors and soil properties in controlling pore water export at the creekbank of tidal marsh soils. Each parameter was varied systematically over a realistic range for field conditions. Changes in marsh elevation exerted greater control over creekbank discharge than changes in soil hydraulic properties. More rapid turnover of pore water near creekbanks of higher elevation marshes is hypothesized.     

Nutrient flux in the Rhode River: Tidal exchange of nutrients by brackish marshes

Tidal exchanges of nitrogen, phosphorus, and organic carbon by a high and a low elevation marsh in the Rhode River estuary were measured throughout the year. Both marshes tended to import particulate matter and export dissolved matter, although they differed in the fluxes of certain nutrients. Compared with tidal exchanges, bulk precipitation was a major source of ammonia and nitrate and a minor source of other nutrients. There was a net retention of nutrients by the portion of the Rhode River that included both marshes and a mudflat. However, the marshes accounted for only 10% of the phosphorus retention and 1% of the nitrogen retention while they released organic carbon amounting to 20% of the retention. This suggests that the mudflat acted as a sink for nutrients. The primary role of the marshes seems to be transformation of particulate to dissolved nutrients rather than nutrient retention or release.     

Water and organic carbon fluxes from an irregularly flooded brackish marsh on the upper Texas coast,U.S.A.

Water flows, concentrations of total (TOC), dissolved (DOC), and particulate (POC) organic carbon and seston were monitored for 52 diel periods in the single creek draining a 270-ha Spartina patens-Distichlis spicata marsh on the upper Texas coast. Rainfall, creek water flows, and water levels in the creek and on the marsh were measured by recording instruments.Rainfall accounted for most marsh flooding, and water outflow was significantly correlated with both rainfall and marsh water level. Creek flows were predominantly outward because microtopographic features and dense vegetation restricted overmarsh water flows and thereby reduced tidal flooding while extending the time of precipitation runoff. Concentrations of organic carbon in water leaving the marsh were highest in spring and summer and averaged 25·62, 21·41 and 3·35 mg l^?1 of TOC, DOC and POC, respectively. These were 9·34, 9·93 and 0·04 mg l^?1, respectively, higher than bay water. Most POC was 0·3–28 μm in diameter. Seston > 28μ leaving the marsh was 95% amorphous material; the rest was plankton, grass particles and fecal pellets. Loss of organic carbon was directly correlated with net water flux, and thus rainfall accounted for most carbon loss. Net carbon loss averaged 196 kg TOC, 150 kg DOC and 32 kg POC per day. Net annual loss was 2·4–5·5% of net aerial primary productivity (NAPP), or 21·55-30·09 g TOC m^?2 year^?1.Export from this marsh falls within the range found for other marshes and the data collectively indicate that coastal marshes are not losing as much organic carbon as has been suggested by indirect measurements. The discrepancy between potential and realized export is explained by the fact that export is not a simple removal of excess detritus by tidal action but is a more complicated process mediated by the interaction of additional factors such as rainfall, vegetation structure, microtopographic variation and decomposition, which can serve to reduce the amount and quality of NAPP exported.     

Contributions of mineral and organic components to tidal freshwater marsh accretion

Vertical accretion in tidal marshes is necessary to prevent submergence due to rising sea levels. Mineral materials may be more important in driving vertical accretion in tidal freshwater marshes, which are found near the heads of estuaries, than has been reported for salt marshes. Accretion rates for tidal freshwater marshes in North America and Europe (n = 76 data points) were compiled from the literature. Simple and multiple linear regression analyses revealed that both organic and mineral accumulations played a role in driving tidal freshwater marsh vertical accretion rates, although a unit mass of organic material contributed ∼4 times more to marsh volume than the same mass input of mineral material. Despite the higher mineral content of tidal freshwater marsh soils, this ability of organic matter to effectively hold water and air in interstitial spaces suggests that organic matter is responsible for 62% of marsh accretion, with the remaining 38% from mineral contributions. The organic material that helps to build marsh elevation is likely a combination of in situ production and organic materials that are deposited in association with mineral sediment particles. Regional differences between tidal freshwater marshes in the importance of organic vs. mineral contributions may reflect differences in sediment availability, climate, tidal range, rates of sea level rise, and local-scale factors such as site elevation and distance to tidal creeks. Differences in the importance of organic and mineral accumulations between tidal freshwater and salt marshes are likely due to a combination of factors, including sediment availability (e.g., proximity to upland sources and estuarine turbidity maxima) and the lability of freshwater vs. salt marsh plant production.     

江苏大丰海岸碱蓬滩潮沟及滩面的沉积动力特征

根据2002年7月在江苏大丰碱蓬滩潮沟观测的水文、悬沙、底质等资料,分析了潮沟的输水、输沙特征及悬沙和底质在粒径组成上的关系,结果表明,潮沟在流速、悬沙浓度、输水、悬沙输运、底质活动性等方面具有明显的涨落潮不对称.滩面归槽水占潮沟落潮输水量的33%,由此造成的悬沙输运量占潮沟落潮悬沙输运量的20%,这是导致潮沟涨落潮输水输沙不对称的主要因素.在一个潮周期中潮沟的净输水、净悬沙输运方向与滩面相反,指向落潮方向.悬沙和底质组成以粉砂和黏土为主,潮沟和滩面的悬沙粒径组成差别很小.悬沙是滩面底质的主要物质来源,两者在粒径组成上存在着必然联系,沉积物粒径与该粒级在底质中的含量与在悬沙中的含量之比具有明显的幂函数关系.     

Tidal sands as biogeochemical reactors

Sandy sediments of continental shelves and most beaches are often thought of as geochemical deserts because they are usually poor in organic matter and other reactive substances. The present study focuses on analyses of dissolved biogenic compounds of surface seawater and pore waters of Aquitanian coastal beach sediments. To quantitatively assess the biogeochemical reactions, we collected pore waters at low tide on tidal cross-shore transects unaffected by freshwater inputs. We recorded temperature, salinity, oxygen saturation state, and nutrient concentrations. These parameters were compared to the values recorded in the seawater entering the interstitial environment during floods. Cross-shore topography and position of piezometric level at low tide were obtained from kinematics GPS records. Residence time of pore waters was estimated by a tracer approach, using dissolved silica concentration and kinetics estimate of quartz dissolution with seawater. Kinetics parameters were based on dissolved silica concentration monitoring during 20-day incubations of sediment with seawater. We found that seawater that entered the sediment during flood tides remained up to seven tidal cycles within the interstitial environment. Oxygen saturation of seawater was close to 100%, whereas it was as low as 80% in pore waters. Concentrations of dissolved nutrients were higher in pore waters than in seawater. These results suggest that aerobic respiration occurred in the sands. We propose that mineralised organic matter originated from planktonic material that infiltrated the sediment with water during flood tides. Therefore, the sandy tidal sediment of the Aquitanian coast is a biogeochemical reactor that promotes or accelerates remineralisation of coastal pelagic primary production. Mass balance calculations suggest that this single process supplies about 37 kmol of nitrate and 1.9 kmol of dissolved inorganic phosphorus (DIP) to the 250-km long Aquitanian coast during each semi-diurnal tidal cycle. It represents about 1.5% of nitrate and 5% of DIP supplied by the nearest estuary.     

The effect of tidally induced changes in the creekbank water table on pore water chemistry

Water moved into the creekbank sediments in direct response to the changing levels of the water table caused by the tides. The net water loss of the sediments was 3–30% on each low tide and this loss was confined to within 4 m (horizontal) of the creek. The replacement of this water by incoming tidal water could not supply sufficient nutrients for the growth of creekbank Spartina. However, during ebb tide there was a replacement of water in the creekbanks with nutrient-rich water from the marsh interior as demonstrated by the large changes in pore water chemistry over a tidal cycle. The concentration and the range of a chemical parameter depended upon the stage of the tide, the tidal range, the time of year and (for salinity) the rainfall patterns of the month preceding sampling. Over a single tidal cycle the maximum ranges were: salinity ‰, 26–33; alkalinity, 2·5–13·6 med 1^?1, ammonia, 2–400 μm, sulfate, 23·5–29 mmol 1^?1. Measurable concentrations of sulfide were only found in a few samples. This high nutrient water can supply nitrogen and probably other nutrients to Spartina.     

Sampling and computational design of nutrient flux from a southeastern U.S. saltmarsh

A sampling and computational approach for estimating nutrient fluxes from a salt marsh ecosystem is presented. Extensive and intensive sampling of tidal velocities, water depths, and nutrient concentrations was made synoptically across three tidal creeks, connecting a 34 km² South Carolina salt marsh with surrounding coastal waters. An estimate of nutrient exchange over each sampling period is based on measurements over four tidal cycles during a neap and spring tidal regime. The computation of instantaneous fluxes of NO₃^?NO₂^?, NH₄⁺, and o-PO₂^4? was based on the cross-multiplication of concentration, velocity, and integrated over the cross-sectional area of each tidal creek. The net flux of nutrients was estimated using a least-squares regression model which included periodic functions simulating tidal and diurnal cycles. This computational approach allows for a rigorous test of the statistical significance of the measured nutrient fluxes and a basis on which interpretations of the ecological significance of the exchange can be made.Tidal patterns in inorganic nutrient concentrations and the corresponding exchanges are presented for a spring time sampling. Nitrate-nitrite was exported consistently from the marsh to the coastal ocean with a mean value of 8.0 kg per tidal cycle for the neap sampling set and 15.6 kg per tidal cycle for the spring set. This corresponded to high concentrations of nitrate-nitrite (0.6 μM) on the ebb tide with low concentrations (0.1 μM) on the flood tide. Ammonia flux was variable and did not portray a consistent tidal concentration pattern. Concentrations ranged from 1 to 6 μM. Ammonia flux was exported to the coastal ocean only during the spring tidal set with a mean value of 114 kg per tidal cycle. Ortho-phosphate was also exported only on the spring tidal set with a mean flux of 40.0 kg per tidal cycle. A tidal concentration pattern of high concentrations (0.6 μM) on the ebb tide and low concentrations (0.05 μM) on the flood was consistent for ortho-phosphate during both neap and spring tidal sets.     

Transport and retention of a conservative tracer in an isolated creek–marsh system

A study of tracer transport and retention in a small tidal creek and marsh system located in the southeastern US was conducted using a three-dimensional hydrodynamic model and data from a dye tracer release. The model simulated tidally driven flow, including inundation and drying out of the marshes and the dispersal of the dye tracer. Flow measurements in the tidal creek showed that the simulations appeared to generally duplicate the tidally driven flow into and out of the tidal creeks and marshes. The dye tracer experiment was conducted to test the hydrodynamic model's ability to simulate dispersal of a point release of pollutants into the creek during an incoming tide. The simulations reproduced much of the experimental measurements, but bathymetric errors and lack of resolution of the smallest arms of the tidal creeks affected the ability to faithfully reproduce the initial peak in measured dye tracer concentrations at a sampling location far from the boundary. The lack of the smallest tidal creeks led to some trapping of water and dye in the marshes. Two independent estimates of flushing time yielded values between 1.6 and 2.4 days. An uncertainty analysis indicates that model simulations are sensitive to variations in parameters such as water depth and marsh grass density. On the other hand, omission of the smallest tidal creeks in simulations may be partially offset by decreasing marsh grass density. Further improvements must rely on more accurate and detailed bathymetric data that resolves the smaller arms of the tidal creeks and includes quantitative information about the density and distribution of marsh grass.     

Influences of Nutrient Outwelling from the Mangrove Swamp on the Distribution of Phytoplankton in the Matang Mangrove Estuary, Malaysia

Distributions of dissolved nutrients and Chl. a were investigated in the Sangga Besar River Estuary in the well-managed Matang Mangrove Forest in West Malaysia. In the estuary, spring tide concentrations of ammonium, silicate and phosphate were higher than those in the neap tide, which suggests that these nutrients are flushed from the mangrove area by the inundation and tidal mixing of the spring tide. Ammonium comprised over 50% of the dissolved inorganic nitrogen in the spring tide, while nitrite tended to dominate in the neap tide, indicating the predominance of nitrification inside the estuary in neap tides. Nutrient concentrations in the creek water were higher than those of estuarine water, indicating the nutrient outwelling from the mangrove swamp and ammonium regeneration from mangrove litter in the creek sediments. The maximum concentration of Chl. a in spring tides reached 80 g/l while it was below 20 g/l in the neap tides. These variations in the phytoplankton biomass and nutrients probably reflect the greater nutrient availability in the spring tide due to outwelling from the mangrove swamp and creek.     

Nutrient flux in the Rhode River: Tidal transport of microorganisms in brackish marshes

Concentrations of bacteria, chlorophyll a, and several dissolved organic compounds were determined during 11 tidal cycles throughout the year in a high and a low elevation marsh of a brackish tidal estuary. Mean bacterial concentrations were slightly higher in flooding (7·1 × 10⁶ cells ml⁻¹) than in ebbing waters (6·5 × 10⁶ cells ml⁻¹), and there were no differences between marshes. Mean chlorophyll a concentrations were 36·7 μg l⁻¹ in the low marsh and 20·4 μg l⁻¹ in the high marsh. Flux calculations, based on tidal records and measured concentrations, suggested a small net import of bacterial and algal biomass into both marshes. Over the course of individual tidal cycles, concentrations of all parameters were variable and not related to tidal stage. Heterotrophic activity measured by the uptake of ³H-thymidine, was found predominantly in the smallest particle size fractions (< 1·0 μm). Thymidine uptake was correlated with temperature (r = 0·48, P < 0·01), and bacterial productivity was estimated to be 7 to 42 μg Cl⁻¹ day⁻¹.     

Seasonal and annual variations in the volumetric sediment balance of a macro-tidal salt marsh

This paper examines the spatial and temporal variability in the volumetric sediment balance of Allen Creek marsh, a macro-tidal salt marsh in the Bay of Fundy. The volumetric balance was determined as the balance of inputs of sediments and organic matter via accretion on the marsh surface and outputs of sedimentary material primarily due to erosion of the marsh margin. Changes in marsh surface elevation were measured at 20 buried plates and 3 modified sediment elevation tables from 1996–2002, and detailed margin surveys were conducted in 1997, 1999 and 2001 using a differential global positioning system. Changes in surface area were calculated using GIS overlay analysis and used in conjunction with accretion and erosion data to derive volumetric estimates of gains and losses of sedimentary material in the marsh system.Currently the volumetric sediment balance at Allen Creek marsh is positive. However the processes of erosion and accretion demonstrate seasonal, annual and spatial variability. Inputs to the system include deposition on the marsh surface from sediment laden waters and from ice rafting of sediments. Sediment is deposited onto the marsh surface year round, even during the winter when vegetation cover is sparse, and the amount of deposition in general is not significantly correlated with the frequency of tidal inundations. Based on the data from 1996 to 2002, the mid and high marsh zones experience mean accretion rates of approximately 1.4 cm year^− 1 whereas accretion rates in the low marsh region are statistically significantly lower (0.8 cm year^− 1). The absolute amount of accretion varies between seasons and from year to year. The main loss to the marsh is through erosion of the marsh margin cliffs which can remove a comparatively large volume of sedimentary material in one mass wasting event and which also decreases the vegetated surface area available for deposition from sediment laden waters. The volume of material removed from the marsh margin almost tripled between 1997 (169 m³) and 2001 (502 m³) following breaching of the side of a tidal creek channel, altering the patterns of margin erosion and deposition in the marsh system. During this time, however, other sheltered areas of the marsh system, such as along the tidal creek banks, showed evidence of new vegetation growth, increasing the amount of vegetated surface area available for deposition.The processes of erosion and deposition on the marsh surface exhibit considerable spatial variability, with different regions of the marsh being more or less sensitive to seasonal variability in the dominant controls influencing sediment deposition and erosion in this system, namely wave activity, vegetation, ice and water depths. A key factor in predicting how a marsh will evolve and respond to a number of different controls, e.g. sea-level rise or reduced sediment supply, is to quantify both accretion of the marsh surface and erosion of the marsh margin, evaluating the marsh system as a volumetric whole. This study demonstrates that a marsh system should be assessed in three dimensions rather than simply as a surface of accumulation. This is particularly important for open coastal marshes exposed to the erosive action of waves.     

海南新村潟湖潮汐、潮流特征及其对营养盐的影响

基于海南新村潟湖2020年12月水文和水质多要素实测数据,研究了该海域的潮汐、潮流变化特征,并探讨了潮位变化对潟湖营养盐的影响。结果表明,新村潟湖的潮汐为不规则全日潮,潟湖口门处的潮流为往复流,涨潮历时15 h,落潮历时10 h。大、小潮期间3个观测站点溶解性无机氮(DIN)浓度变化范围为0.91~20.87 μmol/L,磷酸盐(PO3-4)浓度变化范围为0.11~5.92 μmol/L,硅酸盐(SiO2-3)浓度变化范围为2.36~134.75 μmol/L。大、小潮期间,潟湖内3个观测站点DIN、PO3-4、SiO2-3浓度随着涨、落潮过程发生变化。潟湖口门处流速对观测站点潮位变化有着重要的影响,潮通量基本决定了潮位的变化。潟湖口门处和渔排密集区域的营养盐浓度与潮位呈现显著的负相关关系,潮流流速对口门处和渔排密集区域的营养盐变化有着重要影响。该研究结果将为新村潟湖的污染治理及生态修复提供科学依据。     

Variability of the partial pressure of CO2 on a daily-to-seasonal time scale in a shallow coastal system affected by intensive aquaculture activities (Bay of Cadiz, SW Iberian Peninsula)

The present study describes the temporal variability of the water fCO₂ as well as the different driving forces controlling this variability, on time scales from daily to seasonal, in the Rio San Pedro, a tidal creek located in a salt marsh area in the Bay of Cadiz (SW Iberian Peninsula). This shallow tidal creek system is affected by effluents of organic matter and nutrients from the surrounding marine fish farms. Continuous pCO₂, salinity and temperature were recorded for four periods of approximately one month, between February and September in 2004.Major processes controlling the CO₂ variability are related to three different time scales. Daily variations in fCO₂ are controlled by tidal advection and mixing of the water from within the creek and the seawater that enters from the Bay of Cadiz. Significant cyclical variations of the fCO₂ have been observed with the maximum values occurring at low tide. On a fortnightly time scale, the amplitude of the daily variability of fCO₂ is modulated by the variations in the residence time of the water within the creek, which are related to the spring–neap tide sequence.On a third time scale, high seasonal variability is observed for the temperature, salinity and fCO₂. Maximum and minimum values for fCO₂ were 380 µatm and 3760 µatm for February and July respectively. Data suggest that seasonal variability is related to the seasonal variability in discharges from the fish farm and to the increase with temperature of organic matter respiratory processes in the tidal creek. The fCO₂ values observed are in the same range as several highly polluted European estuaries or waters surrounding mangrove forests. From the air–water CO₂ flux computed, it can be concluded that the Rio San Pedro acts as a source of CO₂ to the atmosphere throughout the year, with the summer accounting for the higher average monthly flux.     

崇明岛东滩潮沟体系及其沉积动力学

崇明岛东滩潮沟系在盐沼带内特别发育,其形成与潮滩围垦工程和盐沼带的宽度密切相关。泥滩上潮沟的发育和演化与盐沼带潮盆大小、潮时(大小潮)和降雨量等相关,潮沟体系规模小,涨潮流不受其控制,退潮时潮沟成为主要泄水通道,未沉降的细悬浮颗粒和浮泥层在重力作用下向潮沟汇集,使潮沟内沉积物比滩面细。崇明岛东滩潮沟体系形成、演化及沉积物分布,完全不同于目前研究非常详细的欧美河口湾/港湾型潮道-潮沟体系,后者潮道以涨潮流占优势,沉积物明显比滩面粗。崇明岛东滩潮沟体系是发育在快速淤长的三角洲类型海岸上,通过与其他类型的对比研究,可以更全面地认识潮道-潮沟体系对泥滩和盐沼发育、演化所起的作用。     

Tracing origins of sewage and organic matter using dissolved sterols in Masan and Haengam Bay,Korea

Masan and Haengam Bays in Korea are highly polluted and semi-enclosed. Domestic and industrial effluents are directly or indirectly discharged into the bays through sewage treatment plants (STP) and creeks. In this study, 15 dissolved sterol compounds were determined in order to understand their sources and relative contribution. Freshwater samples were taken from 13 creeks and at two STP sites on a monthly basis. Total dissolved sterol concentrations ranged from 993 to 4158 ng/L. The concentrations of sterols in winter were higher than in summer. Among the sterols analyzed, cholesterol, β-sitosterol, coprostanol and cholestanone were major compounds in creek water. Seawater samples were concurrently collected at 21 stations in Masan Bay. Total sterol concentrations ranged 118–6,956 ng/L. Inner bay showed high concentrations of sterols in summer, while outer bay showed high sterol concentrations in winter. Among the sterols, cholesterol, β-sitosterol and brassicasterol were major compounds in seawater. In order to examine the contribution of urban sewage, the concentration of coprostanol and fecal sterol ratios were calculated. Most of the creek water, inner bay and near STP outlet samples were affected by sewage. Terrestrial organic matters accounted for a high proportion of dissolved organic matter origin. Fecal origins were relatively high in the inner bay areas and in the STP outlet, while sterols of marine origin were high in the outer bay areas.     

Coastal environmental assessment and management by ecological simulation in Yeoja Bay, Korea

An eco-hydrodynamic model was used to estimate the carrying capacity of pollutant loads and response of water quality to environmental change in Yeoja Bay, Korea. An energy-system model also was used to simulate the fluctuation in nutrients and organic matter in the bordering wetland. Most water quality factors showed a pulsed pattern, and the concentrations of nutrients and organic matter of seawater increased when input loads of nutrients increased due to freshwater discharge. The well-developed tidal zones and wetlands in the northern area of the bay were highly sensitive to input loads. Residence times of water, chemical oxygen demand (COD), and dissolved inorganic nitrogen (DIN) within the bay were estimated to be about 16 days, 43.2 days, and 50.2 days, respectively. Water quality reacted more sensitively to the effects of nitrogen and phosphorus input than to COD. A plan to reduce the present levels of COD and dissolved inorganic phosphorus (DIP) by 20–30% and DIN by at least 50% in pollutant loads is needed for satisfying the target water quality criteria. The natural removal rate of nutrients in wetlands by reeds was assessed to be approximately 10%.