Nutrient exchange across the sediment-water interface in the Potomac River estuary

The flux of ammonia, phosphate, silica and radon-222 from Potomac tidal river and estuary sediments is controlled by processes occurring at the sediment-water interface and within surficial sediment. Calculated diffusive fluxes range between 0·6 and 6·5 mmol m^?2 day^?1 for ammonia, 0·020 and 0·30 mmol m^?2 day^?1 for phosphate, and 1·3 and 3·8 mmol m^?2 day^?1 for silica. Measured in situ fluxes range between 1 and 21 mmol m^?2 day^?1 for ammonia, 0·1 and 2·0 mmol m^?2 day^?1 for phosphate, and 2 and 19 mmol m^?2 day^?1 for silica. The ratio of in situ fluxes to diffusive fluxes (flux enhancement) varied between 1·6 and 5·2 in the tidal river, between 2·0 and 20 in the transition zone, and from 1·3 to 5·1 in the lower estuary. The large flux enhancements from transition zone sediments are attributed to macrofaunal irrigation. Nutrient flux enhancements are correlated with radon flux enhancements, suggesting that fluxes may originate from a common region and that nutrients are regenerated within the upper 10–20 cm of the sediment column.The low fluxes of phosphate from tidal viver sediments reflect the control benthic sediment exerts on phosphorus through sorption by sedimentary iron oxyhydroxides. In the tidal river, benthic fluxes of ammonia and phosphate equal one-half and one-third of the nutrient input of the Blue Plains sewage treatment plant. In the tidal Potomac River, benthic sediment regeneration supplies a significant fraction of the nutrients utilized by primary producers in the water column during the summer months.     

Nutrient flux and budget in the Ebro estuary

The Ebro river flows to the Mediterranean coast of Spain. During its final stretch, the Ebro behaves in a similar way to a highly stratified estuary. This paper describes the transport of nutrients to the Ebro estuary, evaluates the general movement of nutrients in the estuarine region, using a mass balance approach, and estimates the amounts of nutrients discharged to the coastal environment. Given the strong saline stratification, this study only includes the surface layer that contains the continental freshwater. The annual nutrient budget for the Ebro estuary shows a net excess for nitrogen and phosphorus, while silicate almost attains equilibrium between addition and removal. There are several reasons for gains in nitrogen and phosphorous: a contribution of dissolved and particulate compounds in the freshwater (some of which are mineralized); a lower uptake of phytoplankton indicated by chlorophyll reduction in the estuary; an entrainment of the nutrient-rich upper part of the salt wedge; and, to a lesser extent, the impact of wastewater and agricultural water use. The biggest load discharged into the Mediterranean Sea by the Ebro is nitrogen, followed by silicate with over 10 000 tons of each deposited annually. Phosphorus is discharged at relatively low concentrations and with an annual load of about 200 t yr⁻¹.     

Detecting environmental change in estuaries: Nutrient and heavy metal distributions in sediment cores in estuaries from the Gulf of Finland,Baltic Sea

Historical sediment nutrient concentrations and heavy metal distributions were studied in four estuaries in the Gulf of Finland, Baltic Sea to examine the response of these estuaries to temporal changes in human activities. Cores were collected using a 1-m Mackereth corer and dated using ²¹⁰Pb and ¹³⁷Cs. The cores were analyzed for total carbon (TC), total nitrogen (TN), total phosphorus (TP), organic phosphorus (OP), inorganic phosphorus (IP), biogenic silica (BSi), loss-on-ignition (LOI), Cu, Zn, Al, Fe, Mn, K, Ca, Mg and Na. Principal component analysis (PCA) was used to summarize the trends in the chemical variables and to compare the trends at the different sites. Applying the 1986 ¹³⁷Cs date as a reference point, ²¹⁰Pb chronologies were constructed for the sites using either the CRS model or a composite model (using both CIC and CRS). Significant increases were observed in sedimentation rates, TP and TN concentrations in all of the cores. Copper showed clear increases from 1850 towards present at all sites. Furthermore, redundancy analysis (RDA) was used to correlate environmental variables (catchment land use, catchment size, estuary surface area, depth and lake percentage) to sediment geochemistry. Based on redundancy analysis (RDA), the percentage of agriculture in the catchment was the most important factor affecting the sediment accumulation rate. Urban land-use types and industry correlate well with sediment Cu and Ca concentrations. Forest areas were related to high sediment BSi concentrations. Catchment land use was the most significant factor affecting sediment geochemical composition and sediment accumulation rates in these coastal embayments. Our results demonstrate that the coastal estuaries of the Gulf of Finland respond to the increased nutrient loading with the increased sedimentation and nutrient accumulation rates.     

Behaviour of boron,calcium and magnesium in a polluted estuary

Behaviour of industrially added boron in the well mixed Ambika river estuary of South Gujarat, India has been studied along with that of calcium and magnesium. The ratios of Ca : Cl and Mg : Cl at varying chlorinities were always within the normal ranges found in river water at one end and seawater at the other end. B : Cl exceeded the river water end limit at the ebb tide at an upstream station. Percentage addition or removal of boron, calcium and magnesium was calculated using the concept of the theoretical dilution line. The external input raised the boron concentration by 263% in the vicinity of the industrial discharge. A correlation coefficient of ?0·82 between chlorinity and percentage addition or removal of boron supports the theory of boron incorporation in sediments in amounts proportional to salinity. Inverse relationship between percentage addition or removal of boron and suspended solids was observed. Behaviour of calcium and magnesium was in line with the replacement of Ca²⁺ ions occupying the majority of ion-exchange sites in riverine clays by Mg²⁺, Na⁺ and K⁺ during their first encounter with seawater.     

A note on the economics of Swedish Baltic Sea fisheries

The cod stocks in the Baltic Sea are important not only for fisheries but for the entire ecosystem utilized by numerous stakeholders around the coast. All such activities have economic values. In this note the economics of the Swedish Baltic Sea cod fishery is estimated in relation to the sector's interaction with other users of the Baltic Sea ecosystem. The results show a negative resource rent for the fishery, € −5 million without public expenses (subsidies and administrative costs), and € −13 million including public expenses. The interactions between the fisheries and tourism, seal population, carbon dioxide emissions, recreational fishing, and discards are discussed, and when monetary estimates are available these are related to the estimated resource rent.     

Application of a mass-balance model to predict PCDD/F turnover in a Baltic coastal estuary

A dynamical, process-based mass-balance model was applied to quantify the transports of polychlorinated-p-dibenzodioxins and dibenzofurans (PCDD/Fs) to, within and from the Kallrigafjärden Bay, a coastal estuary in the Baltic Sea, and to predict the PCDD/F levels in the water and sediments of the bay. Before the modelling, a one-year sampling programme was implemented in 2007–2008 to measure the flows of PCDD/Fs in tributaries entering the system, the fluxes from the adjacent sea and the levels in water, sediment and fish within the estuary. The collected data set was used as input data to the model and for validation purposes.     

Axial convergence in a well-mixed estuary

Transverse secondary circulations involving surface convergence, observed in a well-mixed estuary in North Wales, are made visible by the collection of surface material along an axial line which extends continuously for many kilometres through the estuary. The circulation and axial convergence, however, are seen only during the flood phase of the tide and no similar behaviour has been observed during the ebb phase.Convergent circulations in the estuary are associated with small but steady transverse density gradients in the cross-section, produced by non-uniform advection of the longitudinal gradient through the channel. A diagnostic model, using measured mean distributions of cross-sectional density, indicates surface transverse velocities (～0.1 ms^?1) similar to those observed in the estuary. The model further predicts appreciable transverse divergent currents at a fractional depth of 0.75: a prediction which has been tested in the estuary using a vertical array of accurately resolving current direction indicators.     

Environmental protection and the freedom of the high seas: The Baltic Sea as a PSSA from a Swedish perspective

In 2005, the Baltic Sea, except for its Russian waters, was designated as a particularly sensitive sea area (PSSA) by the International Maritime Organization (IMO). The previous designation of the Western European waters as a PSSA—intensely debated within the IMO—had repercussions for this process. Reviewing the case exposes the conflict between the fundamental principles, territorial sovereignty, and freedom of the high seas that international law seeks to balance. Likewise, review indicates that the PSSA concept is under almost constant reconceptualization as it is put to test in practice.     

Assessing Trends in Nutrient Concentrations in Coastal Shelf Seas: a Case Study in the Irish Sea

Single point time-series data collected in the Irish Sea since 1954 by Allen et al. (1998) have been re-evaluated using more recent data and areal winter surveys of the Celtic and Irish Seas. Survey data illustrate the heterogeneity of nutrient distributions with N (≈28 μM) and P (2·0 μM) enrichment of the eastern Irish Sea relative to the western Irish Sea (7–8 μM N and 0·7 μM P). Salinity nutrient relationships demonstrate distinct regional differences throughout the two seas. Trends in the Isle of Man time-series are unlikely to have resulted from changes in analytical procedures and personnel. Concerns over data quality cannot be resolved and there are no independent data to validate the time-series. Including more recent data shows P has declined since the late 1980s and N concentrations have remained stable since the mid 1970s. The absence of a Si trend is consistent with limited anthropogenic influence on riverine Si concentrations. Trends in N and P are consistent with changes in riverine concentrations of these two nutrients and the biogeochemical processes controlling their cycling in shelf waters. Denitrification is the most likely reason for offshore Irish Sea concentrations of N being lower than expected.     

Nutrient flux in the Rhode River: Tidal exchange of nutrients by brackish marshes

Tidal exchanges of nitrogen, phosphorus, and organic carbon by a high and a low elevation marsh in the Rhode River estuary were measured throughout the year. Both marshes tended to import particulate matter and export dissolved matter, although they differed in the fluxes of certain nutrients. Compared with tidal exchanges, bulk precipitation was a major source of ammonia and nitrate and a minor source of other nutrients. There was a net retention of nutrients by the portion of the Rhode River that included both marshes and a mudflat. However, the marshes accounted for only 10% of the phosphorus retention and 1% of the nitrogen retention while they released organic carbon amounting to 20% of the retention. This suggests that the mudflat acted as a sink for nutrients. The primary role of the marshes seems to be transformation of particulate to dissolved nutrients rather than nutrient retention or release.     

Estuaries as Repositories of Historical Contamination and their Impact on Shelf Seas

Estuaries are sites of port, industrial, urban and recreational development and also important to many forms of animal life. They often form sinks for sediment and thus for contaminants associated with the sediment which arise from anthropogenic activities in their hinterland and along their shores. These contaminants can adversely affect estuarine ecosystems and are the subject of international agreements on environmental protection. For both of these reasons, it is important to increase our knowledge of the distribution, concentration, controlling influences on, and impacts of, estuarine contamination. Evidence from around the world shows that although estuaries are sinks for contaminants from the terrestrial environment, there is significant transport of marine material up-estuary as bed load sediment whilst fine-grained terrestrial material may be transported seawards in suspension. Major movement of contaminants from estuaries onto the continental shelf probably occurs only during floods and storms and, in general, the impact on shelf seas is relatively minor and confined to the coastal zone. The chief exception to this rule is in the Far East where sediment from major Chinese rivers may be dispersed up to 300 km across the shelf.     

Tidal and subtidal water volume exchange in an estuarine system

Estuarine water movements occur over a broad range of time scales. In this study, moored current meter data were used to investigate water volume exchange in the tidal passes of Lake Pontchartrain, Louisiana on the tidal and subtidal time scales. A calibration technique, employing cross-channel measurements of water velocity, was used to calibrate the moored current meters, thus allowing for calculation of volume flow over a 35-day period. The local diurnal tide accounted for 50% of the total volume exchange, the rest being due to subtidal events (frontal passage). This subtidal exchange occurs primarily as large-scale events characterized by volume fluxes up to six times greater than the normal tidal prism. Neglecting this subtidal component in the determination of the volume fluxes for a system such as Lake Pontchartrain, could result in substantial underestimation (by as much as 50%) of these volume and their corresponding material fluxes.     

Shear stress variations in an estuary

Observations in 1929 of the tidal variation of surface gradients in the Tees estuary were combined with measurements of the velocity and density structure in 1975 to compute the internal and boundary shear stresses. Drag coefficients were generally higher on ebb than on flood tides and this inequality is explained using established boundary layer theory. The results suggest that the wide variation in drag coefficients in estuaries may depend, in addition to roughness changes, on the bed slope and the available kinetic energy of the mean flow.     

Environmental factors influencing macrodetritus flux in North Inlet estuary

Floating macrodetritus transport was determined on 72 tidal cycles over 18 months. Floating macrodetritus was exported from the marsh-estuarine ecosystem to the Atlantic Ocean, but export was low (less than 1% of Spartina net aerial primary production). Season and processes within the system seem to determine ebb flux, while flood flux is best explained by a semi-lunar cycle or high water. The extensive observations reported here indicate macrodetritus probably should not be considered a major source of organic carbon export from marsh-estuarine systems.     

Reynolds stress and TKE production in an estuary with a tidal bore

We report new measurements of the turbulent properties of the flow in a tidally energetic estuarine channel of almost uniform cross-section. A high-frequency (1.2 MHz), bottom-mounted Acoustic Doppler Current Profiler (ADCP) has been used to observe the velocity field at a sampling rate of 10 Hz in parallel with measurements of the surface elevation by tide gauges. Our data have been analysed using the Variance Method to determine turbulent kinetic energy (TKE), shear stress and TKE production over the tidal cycle with a time resolution of 60 s. During the highly energetic but brief flood period, when the surface axial velocity reaches 2 m s⁻¹, we observed large values of stress (>2 Pa) and shear production (5 W m⁻³). TKE is also input through the release of energy in the bore itself which results in a brief but intense injection of energy at the bore front with large transient TKE levels (100 J m⁻³). Subsequent input by shear production maintains TKE levels which are generally lower (20 J m⁻³) than the strong peak associated with the bore for the rest of the flood. On the ebb, the flow is relatively tranquil with maximum speeds 0.5 m s⁻¹ and peak TKE production rates of 0.1 W m⁻³.The flow and elevation data have also been used to estimate the energy fluxes into and out of the estuary. Short (1 h), intense energy inputs (8 MW at springs) on the flood flow are largely balanced by longer, less intense seaward energy flow on the ebb. The net energy input is found to be 0.1 MW at springs which is consistent with estimates of upstream dissipation. Peak dissipation in the bore itself may exceed the mean energy input but it is active only for a small fraction of the tidal cycle and its average contribution does not exceed 12% of total dissipation.