插层-磨剥法制备不同径厚比的高岭石

通过对醋酸钾/高岭石插层复合物的机械磨剥制备了不同径厚比的高岭石样品,并利用X射线粉晶衍射(XRD)、激光粒度仪、扫描电子显微镜(SEM)、透射电子显微镜(TEM)和傅里叶变换红外光谱(FTIR)表征了4个样品的粒径、结构以及形貌。实验结果表明:随着插层磨剥次数的增加,高岭石的结晶度指数(HI)由原矿的1.29降至0.69,结晶度降低,晶体结构在一定程度上遭到破坏。同时,4个样品的粒径及厚度逐渐减少,径厚比依次增大至11.7。此外,经过3次插层磨剥洗涤后,部分剥离的片层发生卷曲,但很少完全卷曲成纳米卷。     

机械研磨对平鲁煤系高岭石热行为的影响

对煤系高岭石进行0-2h的研磨之后，再在900℃、1000℃、1400℃的温度条件下分别对其加热1h，然后利用X射线衍射（XRD）、差热分析（DTA）、红外光谱（IR）等手段，研究机械研磨对于煤系高岭石晶体结构的破坏作用以及对其热行为的影响。结果显示，煤系高岭石被研磨1h之后，高岭石的晶体结构几乎全部跨塌。把研磨1h的煤系高岭石加热到1000℃（加热1h），便能形成结晶良好的莫来石。     

砟子煤矿区硬质高岭(土)岩生产高白度煅烧高岭土工艺研究

吉林省地质矿信息中心与白山市八道江区煤管局合作,对山地区石炭、二叠系煤系地层中的硬质高岭（土）岩进行了实验室加工试验,得出了影响砟子煤矿区硬质高岭（土）岩煅烧高岭土白度的六大因素,指出了煅烧工艺对砟子煤矿区硬质高岭（土）岩的关键所在,但各因素之间又是相关连,相互渗透的,对下一步建厂生产指明了方向,清楚地论述了应用砟子煤矿区硬质高岭（土）岩的煅烧加工过程,获得超细双９０型造纸涂料级产品的把握所在,双９０型产品指的是：粒度－２μｍ〉９０％,白度（ＧＥ高度）〉９０度。     

Effect of heavy metal and alkali contamination on the swelling properties of kaolinite

One of the most important factors that determine engineering properties of soils are the type and the amount of clay present in soil. Kaolinite being a very common and non-swelling clay mineral in soil was chosen as the medium, and significance of the change in swelling property of kaolinite due to contaminant-clay interaction was investigated. The amount of change in swelling percentages of the kaolinite due to contamination with 10,000 ppm solutions of Pb(NO₃)₂ and Zn(NO₃)₂ was determined using oedometers. For uncontaminated kaolinite, the amount of swell was determined as 2.2%. For Pb-contaminated and Zn-contaminated kaolinite, these values reached to 5.8 and 5.3%, respectively. Besides heavy metals, kaolinite was also contaminated with 4 N NaOH. The biggest change in the amount of swelling was obtained from NaOH-contaminated kaolinite which is 13.9%. In addition to swelling percentages, swelling pressures were also determined. The swelling pressure of the uncontaminated kaolinite was found as 1.06 N/cm². For Zn and Pb-contaminated kaolinite, this value reached up to 2.0 and 2.6 N/cm². The NaOH-contaminated kaolinite has the greatest swelling pressure which was 230 N/cm².     

Influence of pyrrhotite on the corrosive wear of grinding balls in magnetite ore grinding

The influence of pyrrhotite on the corrosive wear of grinding balls in magnetite ore grinding was studied using three types of balls, namely, mild steel, high carbon low alloy (HCLA) steel and austenitic stainless steel under different aeration conditions. The results obtained through marked ball grinding tests were correlated with electrochemical measurements using magnetite, pyrrhotite and the respective ball material electrodes.In the absence of sulfide-bearing minerals such as pyrrhotite, corrosive wear of the grinding balls in the wet grinding of magnetite ore was relatively small, even in the presence of oxygen. The presence of pyrrhotite significantly increased the corrosive wear of mild steel and HCLA steel balls, especially in the presence of oxygen. No such increase in ball wear with pyrrhotite addition was observed with austenitic stainless steel balls. Electrochemical studies indicate that the corrosion of both mild steel and HCLA steel in mill water is accelerated in the presence of pyrrhotite.     

Distribution and Influence of Iron Phases the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-ray Electron Spin Resonance(ESR) spectroscopes.The purity of the samples and the degree of their structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which persist after chemical dissolution of free iron.The Moessbauer spectra of these clays show two doublets with isomer shift and quadrupole splitting typical of octahedrally coordinated Fe^3 ,in addition to third doublet with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H) sample.Six-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octahedral symmetry as well as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activation of the investigated montmorillonite samplas by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,the amount and site occupation of Fe associated with kaolinite samples show an inverse correlation with the parameters used to describe the degree of crystallinity perfection,color,brightness and vitrification range of these kaolinite samples.     

Distribution and Influence of Iron Phases on the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-band Electron Spin Resonance(ESR) spectroscopies.The purity of the samples and the degree of structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which is present after chemical dissolution of free iron.The Moessbauer spectra of these clays sow two doublets with isomer shift and quadrupole splitting typical of octahedral coordinated Fe^3 ,in addition to third doubler with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H)sample.6-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octaedral symmetry and as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activaiton of investigated montmorillonite samples by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,amounts and site occupation of Fe associated with kaolinite samples show a negative correlation with the parameters used to describe the degree of crystalline perfection,color,brightness and vitrification range of these kaolinite samples.     

Influence of physico-chemical components on the consolidation behavior of soft kaolinites

Pore solution salinity has important bearing on engineering behavior of marine sediments as they influence electrochemical stress (A–R) and differential osmotic stress (?π) of the salt-enriched clays. The electrochemical stress (A–R) is contributed by van der Waals (A) attraction and diffuse ion layer repulsion (R), while the differential osmotic stress (?π) is governed by the differences in dissolved salt concentrations in solutions separated by osmotic membrane. The paper examines the relative influence of differential osmotic stress (Δπ) and electrochemical stress (A–R) on the consolidation behavior of slurry consolidated kaolinite specimens, which are known to be encountered in recent alluvial marine sediments. Methods are described to evaluate the magnitudes of these physico-chemical components and their incorporation in true effective stress. Results of the study demonstrate that differential osmotic stress finitely contributes to true effective stress. The contribution from differential osmotic stress enables kaolinite specimens to sustain larger void ratio during consolidation.     

高岭石表面酸碱反应的电位滴定实验研究

采用表面酸碱电位滴定法探讨高岭石表面酸碱性质,基于多位模式(即假定高岭石表面存在3种基团Al2 OH 、AlOH 和SiOH ) ,根据实验所得数据对高岭石表面的质子化和去质子化过程的相关参数进行拟合,讨论各个位点所发生的反应,并探讨了支持电解质浓度、高岭石溶解过程对表面酸碱电位滴定结果的影响。高岭石的表面零净质子电荷点(pHPZNPC,5 .2 )不等同于零电荷点,当pH <5 .2时,高岭石表面荷正电荷,主要由于表面富硅贫铝层的形成和Al位的质子化所致;当pH >5 .2时,高岭石表面荷负电荷,以Si位和Al的去质子化反应为主。     

On the mechanical properties of synthetic kaolinite/quartz fault gouge

The mechanical properties and microstructures of mixed kaolinite/ quartz fault gouge have been studied by means of triaxial tests, wherein a 1 mm thickness of fault gouge was sheared between rigid, sintered alumina sliders. Test conditions ranged up to 200 MPa confining pressure, 175 MPa pore water pressure and temperatures to 600°C. Constant displacement rate tests were carried out at 5×10^-4 mm s^-1, and the stress relaxation technique was used to access a wide range of lower displacement rates down to 10^-10 mm s^-1. The effects of different ratios of clay: quartz were studied, and some experiments were cafried out using crushed Tennessee sandstone gouge and pre-faulted cylinders of Tennessee sandstone. Deformation-induced microstructures were studied by optical, scanning and transmission electron microscopy, and mineral chemistry changes were identified using EDS analysis in the STEM. The most important factor determining the strength of these gouges is effective confining pressure, and the effective stress law was obeyed at all test conditions. Increasing the proportion of quartz in the gouge slightly increases the strength, as does increase of temperature. Under all test conditions the gouges deformed by strain-hardening stable sliding. At 2 mm displacement the friction coefficient is similar to that for rock and rock sliding (μ= 0.85). Over wide ranges of strain-rate and temperature the strength of these gouges is little affected if the effective pressure is high, but strength drops rapidly with decreasing strain-rate if effective pressure is low (or if pore water pressure is high). Reloading of the gouge after stress relaxation at high temperatures demonstrated hardening arising from hydrothermal cementation during stress relaxation, which led to sudden rupture of the cemented gouge. This phenomenon may be responsible for cyclic rupture of natural faults. New mineral phases were produced in these experiments only at 600°C. At 400°C, anticipated production of pyrophyllite from kaolinite plus quartz was not found, but recrystallization of kaolinite is believed to have occurred and evidence of healing of cracks in quartz was seen. Microstructural studies revealed the ubiquitous development of P and R₁ foliations and other features, which are identical to those found in natural clay-bearing fault zones. Microstructural evolution is associated with the strain-hardening, and apparent hardening is strongly associated with the stress path during loading.     

Studies of the relationship between coal petrology and grinding properties

The maceral and microlithotype composition of selected coals has been investigated with respect to the grinding properties, specifically Hardgrove grindability index (HGI), of the coals. The study expands upon previous investigations of HGI and coal petrology by adding the dimension of the amount and composition of the microlithotypes. Coal samples, both lithotypes and whole channels, were selected from restricted rank ranges based on vitrinite maximum reflectance: 0.75–0.80% R_max, 0.85–0.90% R_max and 0.95–1.00% R_max. In this manner, the influence of petrographic composition can be isolated from the influence of rank. Previous investigations of high volatile bituminous coals demonstrated that, while rank is an important factor in coal grindability, the amount of liptinite and liptinite-rich microlithotypes is a more influential factor. In this study, we provide further quantitative evidence for the influence of microlithotypes on HGI and, ultimately, on pulverizer performance.     

煤系高岭石的原始晶粒尺寸及结晶度对插层作用的影响

采用SEM、XRF、XRD和IR研究了大同、平朔和淮北煤系高岭石的结构、粒度及其特性,探讨了粒度大小对高岭石插层作用的影响及其机理。研究发现:粒度中等且结晶有序的平朔煤系高岭石插层率最高,其次为晶体粗大但结晶有序的大同高岭石,粒度最小且结晶无序的淮北高岭石插层率最低。研究认为高岭石原始晶粒粒度对高岭石插层作用有重要影响,中等粒度最有利于高岭石插层作用的进行,粒度过大或过小均不利于高岭石插层作用的进行,其原因是由于不同粒度的高岭石插层作用过程中导致的差异弹性变形引起的。结晶有序度对高岭石插层作用也有重要影响,结构无序不利于插层作用的进行。     

Influence of the size effect on crystallomorphological properties of kaolinite (Zhuravlinyi Log deposit,Southern Urals): Evidence from electron microscopy and EPR

Doklady Earth Sciences -     

Influence of transducer-ground coupling on vibration measurements

Various methods of transducer mounting provide varying degrees of coupling between the transducer and the measurement surface. The influence of four of these methods on vibration measurements was studied. For this purpose, the first transducer was placed freely on a horizontal surface, the second one was 'sandbagged', the third one was 'spiked' and the fourth one was completely buried in soil. These transducers were mounted side by side and ground vibrations were monitored for 14 blasts at an opencast coal mine.

Ground vibrations in terms of peak particle velocity, peak vector sum and frequency with different mounting methods were analysed. Assuming the data of the buried transducer as the most acceptable one, relative values of other transducers were determined and plotted. For the given tolerance for instrumental and human errors, anomalous readings were found in some cases. The waveforms of the buried transducer were then compared with those of others. Clear distortion in the waveforms or a very low correlation coefficient between two waveforms was suspected poor coupling.

The results indicate that decoupling is most likely with the surface transducer. However, the sandbagged and spiked transducers are also prone to decoupling. Decoupling can result in higher or lower ground vibration. Therefore, burial should be the preferred method for mounting of transducers in soil.     

凸起地形对铁路环境振动的影响分析

建立了列车作用下路基-凸起地形的二维有限元计算模型,研究了凸起地形宽度、形状、高宽比以及地基土性质对铁路环境振动的影响规律。结果表明,凸起地形减弱了铁路环境振动的地面加速度,明显放大了水平振动位移,对竖向振动位移的影响不明显;随凸起地形宽度、高宽比的增大,水平振动位移的放大效应更为显著;高宽比越大,竖向、水平两个方向地面加速度减小越明显;半圆形、梯形凸起地形对铁路环境振动的影响较为一致,但三角形凸起地形的水平地面加速度在凸起地形顶部出现明显的局部放大,水平振动位移的放大效应较半圆形、梯形地形要明显;地基愈软弱,凸起地形的影响效应越显著。     

Sorption of lanthanides on smectite and kaolinite

Experiments were carried out to investigate the sorption of the complete lanthanide series (Ln or rare earth elements, REE) on a kaolinite and an a Na-montmorillonite at 22°C over a wide range of pH (3-9). Experiments were conducted at two ionic strengths, 0.025 and 0.5 M, using two different background electrolytes (NaNO₃ or NaClO₄) under atmospheric conditions or N₂ flow (glove box). The REE sorption does not depend on the background electrolyte or the presence of dissolved CO₂, but is controlled by the nature of the clay minerals, the pH and the ionic strength. At 0.5 M, both clay minerals exhibit the same pH dependence for the Ln sorption edge, with a large increase in the sorption coefficient (K_D) above pH 5.5. At 0.025 M, the measured K_D is influenced by the Cation Exchange Capacity (CEC) of the minerals. Two different behaviours are observed for smectite: between pH 3 and 6, the K_D is weakly pH-dependent, while above pH 6, there is a slight decrease in log K_D. This can be explained by a particular arrangement of the particles. For kaolinite, the sorption coefficient exhibits a linear increase with increasing pH over the studied pH range. A fractionation is observed that due to the selective sorption between the HREEs and the LREEs at high ionic strength, the heavy REE is being more sorbed than the light REE. These results can be interpreted in terms of the surface chemistry of clay minerals, where two types of surface charge are able to coexist: the permanent structural charge and the variable pH-dependent charge. The fractionation due to sorption observed at high ionic strength can be interpreted either because of a competition with sodium or because of the formation of inner-sphere complexes. Both processes could favour the sorption of HREEs according to the lanthanide contraction.     

淮北闸河矿区高岭岩特征及其利用途径

用差热、X射线衍射及红外光谱等方法,对淮北闸河矿区下石盒子组底部5^#、6^#煤层间一层高岭岩矿层进行了研究。结果表明:矿层平均厚3.8m,矿石几乎全部是由高岭石组成的单矿物岩,有益组分Al₂O₃含量一般在36%~39%;主要有害组分Fe₂O₃含量变化在0.78%~1.71%之间;TiO₂含量多在0.4 9%~0.97%。为矿物组成纯净,有益组分含量高但有害组分亦较高的高岭岩。这种岩石是生产化工产品,以及煅烧高岭土的良好原料。     

铅在高岭石表面的吸附模式

采用表面络合模式,研究了高岭石表面的酸碱性质以及高岭石表面对铅的吸附行为。结果表明,高岭石表面在不同ｐＨ条件下对质子和铅离子的吸附反应可以用单一表面基团、无静电表面络合模式来描述。高岭石表面酸度常数拟合值分别为ｐＫａ１＝２．７５和ｐＫａ２＝５．５２,电荷零点ｐＨｚｐｃ＝４．１铅在高岭石表面的吸附量随ｐＨ值的升高而增加,吸附铅的两种表面化合态〉ＳＯＰｂ＾＋和〉ＳＯＰｂＯＨ的浓度也随ｐＨ值的变化而变化     

滇东北早石炭世无烟煤理化特性及应用方向

经过10余年的资源勘查和多学科的综合研究,已基本查明滇东北(昭通市)早石炭世无烟煤的分布、煤质特征及主要利用方向。与国内外其他地区、其他时代的无烟煤比较,本区无烟煤内在矿物质含量极低、有机组分中主要成分为无结构镜质体,有机质中C、H元素高达97%,H/C原子比为0.5。结合X衍射分析(XRD)和高分辨透射电镜(HRTEM)研究结果,该区无烟煤有机质的化学组成与分子构型与沥青中间相炭微球(MCMB)类似。一系列实验表明,经选别制备的超低灰无烟煤是多种中、高端新型炭材料和炭素的优质原料。有序而保护性地开发利用该区资源,对我国经济建设和社会发展具有重要意义。