Distribution and degradation of Alkyl benzene sodium sulfonate, and its harmful effect on carp in Dianchi Lake

Sanitary and industrial sewage is a daily serious detriment to the water quality of Dianchi Lake, Yunnan Province, China. The numerous anionic detergents contained in sanitary sewage and the large number of metallic elements such as Cu, Pb, Cd contained in industrial discharge have made an obvious harmful effect on growth of carp (Cyprinus carpio chilia Wu et al.) in the lake. At the Dianchi Lake sampling and water intake area near Dragon Gate Village, the Linear Alkyl Sulfonate content in the water is over 0.7 (mg/l). This caused the carp's incubation rate and the terateger rate to reach 85% and 28% respectively, and results in a lethality rate of young carp of about 38%. In addition, further study has been stated on the distribution and degradation rates in Dianchi Lake water and in its sediments of two isomeric anionic detergents: ABS (Alkyl Benzene Sulfonate, in short form ABS) and LAS (Linear Alkyl Sulfonate, in short form LAS), and the harmful effect of LAS to its carp. Measures for harnessing and protecting the lake's aquatic environment from pollution, and using the area to develop carp aquaculture are posed. Water quality standards for feeding carp are also covered.     

大地热流对滇池环境的影响与滇池污染治理的新思路

滇池经过长达7年、投资40多亿元的治理,在污染源头控制上已经取得了明显成绩,在一定程度上缓解了生态环境的进一步恶化。滇池水体水质至今没有好转的根本原因在于对滇池蓝藻爆发机理的认识没有考虑其所处的特殊地理环境。滇池水体富营养化之后,是由于较高的大地热流背景和四季如春的气候条件使蓝藻得以不停息地繁殖,致使滇池的水生生态系统完全瘫痪,水体完全失去自净能力。“抑制蓝藻的繁殖”和“清除水体中的营养物质”两大问题形成了滇池治理中一个难解的死结。解开死结的有效措施是从抚仙湖调清水给滇池换水,恢复草海,提高湖水自净能力,发展水生生态系统,抑制藻类繁殖。     

牛栏江流域水污染特征与水资源保护对策研究

牛栏江—滇池补水工程是滇池流域及周边地区的水资源综合利用工程,是增加滇池生态环境水量,改善滇池水资源质量的重要工程,对于保障现代新昆明建设和云南省经济社会可持续发展具有重大战略意义。然而近年的监测结果表明,牛栏江流域水资源质量有下降趋势。在以往的研究中曾提出面源污染是主要污染源。通过研究,发现牛栏江水污染物以总磷(TP)为主,且主要集中在七星桥断面以上;总磷(TP)污染主要来自于工业排放。并据此提出水污染治理的水资源保护对策。水环境治理措施和水质监测结果验证了结果的可靠性。     

天然矿物材料修复富营养化水体的实验研究

采用底泥掩蔽技术，选取天然红土，添加适量的粉煤灰及石灰粉作为掩蔽覆盖物，对滇池富营养化水体进行现场修复实验。结果表明：用天然矿物材料减小底泥内源营养盐负荷的释放修复富营养化水体的效果良好；红土是有效的底泥覆盖材料，添加粉煤灰和石灰粉有助于消减底泥中TP、TN的释放量，还可提高对藻类等浮游植物繁殖的营养基础和对藻、藻细胞及其胚胎上浮生长的控制效率，最终达到除藻的目的，为滇池及类似湖库富营养化水体的修复提供了崭新的思路。     

滇池流域集约化农田区氮素损失研究

集约化农田区氮素流失是构成滇池流域面源污染、水体富营养化的重要因素。基于滇池流域集约化农田区产业结构特征、施肥方式、土壤物化性质分析,利用现场模拟试验,探讨水土生复合系统中氮素输移、分布和损失机制,量化不同情景下氮素损失量。研究表明,集约化农田土壤氮素损失主要途径是通过气态(NH3、N2O、NO/NO2、N2等)、作物吸收、生物作用和淋失。气态氮损失受温度、土壤特性、施肥类型、方式与施肥量、地下水埋藏条件等因素综合制约,NO-3 N是氮淋失的主要形式。根据试验与计算结果,Ⅰ区和Ⅱ区的合理施肥的氮利用率分别为30 8%和20 8%,高于习惯施肥的11 5%和8 5%,气态损失和淋失率均低于习惯施肥。显然,施肥的合理性是控制集约化农业区氮素损失的重要措施。     

Environmental variation and striped bass population dynamics: A size-dependent mortality model

Although density-dependent growth and mortality are understood to play a large role in regulating populations of some young fish, many investigators report associations between striped bass population fluctuations and environmental variation, not density. One explanation is that mortality is primarily determined by size, which responds through growth to environmental conditions. Mathematically relating mortality to inverse size explains several aspects of striped bass biology. Numerical decline of the 1975 Hudson River cohort is well predicted. Simulated year-class strength responds more strongly to changes in growth and length at hatch than to direct mortality of eggs. The effect of changes in length at hatch and growth, rate on subsequent population size decreases as fish grow. Small changes in temperature or food density early in life could cause the reported association of year-class strength and environmental variation. Disappearance of larvae from an early spawning in the Hudson River in 1976 is attributed to decreasing water temperature, which decreased growth rate. Increased mortality of young striped bass may also result from sublethal exposure to toxicants that decrease growth rate and size at hatch. The approach to modeling population dynamics developed here should be valid for other estuarine and marine species.     

滇池湖泊沉积物中游离类脂物的有机地球化学特征

在对滇池湖泊沉积物有机质总体特征分析的基础上,对沉积物中可溶性有机质的组成进行了定量测定,并揭示了其剖面变化特征.研究结果表明:(1)正构烷烃组分具有较强的稳定性,反映出滇池沉积有机质以菌藻类来源为主,沉积柱上、下两段存在陆源高等植物输入相对增加的特征,且从下往上存在草本植物相对贡献增加的特征;(2)脂肪醇组分,以具有强烈偶碳优势的高碳数脂肪醇为主,反映了沉积有机质中陆源输入的部分;(3)脂肪酸组分揭示出可溶有机质中以浮游植物贡献为主,局部层段存在相对较强的细菌改造作用.因此,湖泊沉积物记录了滇池从一个贫营养的湖泊演变成富营养化湖泊的过程,特别是最近几十年,滇池内源有机物和陆源有机物的输入都呈现快速增长的趋势,结合同位素组成特征表明滇池进入了重富营养化阶段.     

应用潜在生态风险指数法评价滇池沉积物中的重金属污染

测定了滇池8个断面表层沉积物中重金属(Cu、Zn、Pb及Cd),结果表明,除Cd外,Cu、Zn及Pb在沉积物中的含量较高,这几种元素的含量顺序为Zn>Cu>Pb>Cd。同时采用Hakanson指数法评价了沉积物中重金属生态风险,结果显示:滇池表层沉积物中重金属元素的潜在生态风险整体表现为轻微。其中海口西和观音山东断面总的重金属潜在生态风险指数最高。对于晖湾、观音山西、白渔口及海口西断面,Cu表现为首要的潜在生态风险因子;对于罗家营、观音山中及滇池南断面,Pb表现为首要的潜在生态风险因子;对于观音山东断面,Cd表现为首要潜在生态风险因子。     

Phosphorus in suspended matter and sediments of a hypertrophic lake. A case study: Lake Dianchi,China

From June 2004 to December 2004, Lake Dianchi, which had large scale of cyanobacterial blooms was investigated in order to study P-fractionation in the suspended matter and the sediment. The investigation improves our understanding of phosphorus in Lake Dianchi and the relationship between phosphorus and cyanobacterial blooms. It contributes to the available literature on the behavior of P in hypertrophic lakes. The distribution of P-fractions in Lake Dianchi was not uniform from northwest to south, but was closely related to the trophic status of the whole lake. The concentrations of total phosphorus, labile P (NH₄Cl-P), Organic P (NaOH-NRP) and loss on ignition in suspended matter were positively correlated with the strength of cyanobacterial blooms. Total phosphorus in suspended matter was relatively stable for almost half an year and closely related to Chl. a concentration. The main content of organic phosphorus is in the cyanobacterial blooms. The concentrations of phosphorus bound to metal oxides and carbonates (NaOH-SRP and HCl-P) in sediment were similar to NaOH-SRP and HCl-P in the corresponding suspended matter. The latter two forms of P in suspended matter were not affected by cyanobacterial blooms, indicating that the inorganic phosphorus is derived from the sediment after resuspension from the sediment due to wind and wave action. The contribution of the different P-fractions to TP in sediment and in suspended matter indicates that NH₄Cl-P in the suspended matter is an important buffer for maintaining dissolved phosphorus in water.     

昆明滇池及盘龙江磷形态分布研究

对昆明地区松华坝水库－盘龙江－滇池水系表层水中的可溶性和不溶性正磷酸盐,聚磷酸盐和有机磷等磷的几种形态进行分析,得出了磷形态分布曲线,从而为滇池水系磷污染的研究和治理提供了一定依据。     

滇池湖泊沉积物中甘油二烷基甘油四醚脂的组成特征

以云贵高原浅水湖泊—滇池作为研究对象,在对湖心一个63 cm沉积物柱样的有机质总体及分子有机地球化学研究的基础上,对沉积物有机质中甘油二烷基甘油四醚脂（GDGTs）组成进行了测定。研究结果表明,滇池湖泊沉积物中具有丰富的GDGTs,且以反映陆相土壤来源的支链类GDGTs为主。该沉积柱样中支链类GDGTs的环化指标（CBT）和甲基化指标（MBT）揭示出:1）整个沉积阶段滇池流域土壤的pH值主要介于7.5~8.2,相对中、下部层段,上部层段pH值呈现略微减小的趋势;2）基于CBT/MBT重建的滇池流域内年平均气温呈现由早期的温暖潮湿气候逐渐向寒冷干燥气候变化,近来又有所回暖的变化过程,这可以很好地解释该沉积柱中、下层段记录的总体有机质主要特征的演化规律。     

The Potential Endangers of the Tectonic Lake Water Leakage from Dianchi and Water Security

Dianchi or Lake Dian is the largest shallow water lake on the Yunnan-Guizhou Plateau, which is not only crucial to maintain the ecological environments of Kunming, the famous city with four springs, but also contains almost 1.5×10⁹ m³ highly polluted water. The management of the lake pollution and eutrophication will be a long-lasting hard work and the sudden diffusion of such highly polluted water can lead to catastrophic eco-environmental problems. Based on the historical documents, underwater topographic features, regional geological tectonics and the chronology of the sediments, it can be concluded that at one time the water leaked out in Dianchi, which is in consistent with the historical record of 1764 AD. This water leak event resulted in two funnels in the center of Dianchi. The sedimentary feature and the deformation properties indicated that the slope of one funnel collapsed, which means it was blocked, but the other one was under development or in dormancy. When the pressure induced from the water level changed or the earthquakes occurred, the underwater channel could be open or connected, a catastrophic water leakage might be induced. The highly polluted lake water would possibly flow to Lake Fuxian and pollute almost 9% national strategic fresh water resource, resulting in an eco-environmental event and endangering the national water security. Therefore, to monitor the water flowing situation, detect the position and direction of the channel, block the channel and prevent possible lake water leakage are the priority and urgent measurements at present.     

论成油和成煤的若干基本条件--以云南三个湖泊为例

本文以云南三个湖泊水生生物的数量和质量、沉积环境与有机质的关系、有机质埋藏初期和成岩早期的演化趋势等方面,着重讨论了成油和成煤的基本条件,并联系我国新生代成油成煤的有关条件,提出六点主要认识:1.成油、成煤必须具有构造条件;2.湖泊所处气候带必须适中;3.湖水须属富营养型;4.成煤与成油要求湖水深度不同;5.湖水的氧化还原状况;6.成煤还需没有陆源碎屑物质的补入。     

Heavy metals pollution on the sediments in lakes Dianchi, Erhai and Poyanghu and historical records

In this paper²¹⁰ Pb and ¹³⁷Cs dating methods were used to determine sedimentation rates of lakes Dianchi, Erhai and Poyanghu, and to establish the time scale of the sediments. Also based on geochemical records in the sediment column, the historical variation in heavy metal content over the past one hundred years was determined. Some element concentration increased rapidly after the 1970s, such as Cu, Zn and Mn in the sediments of northern Lake Dianchi, Cd and Mn in southern Lake Erhai and in the west central parts of Lake Poyanghu, Our investigations indicate that the increase in element concentration is caused by human activities. In order to understand the extent of the effect caused by human activities, we have calculated the flux of Zn, Cd and Mn. Results show that the flux caused by human activities is seven times greater than the natural one and the ratio is about 2 times in Lake Erhai and Lake Poyanghu.     

Using Stable Isotope Mixing in a Great Lakes Coastal Tributary to Determine Food Web Linkages in Young Fishes

We characterized stable isotope mixing along a river-Great Lake transition zone in the St. Louis River, an important fish nursery in western Lake Superior, and used it to identify food web linkages supporting young fish production. We observed a broad, spatial pattern in the carbon stable isotope ratio (δ¹³C); downriver enrichment in particulate organic carbon and aquatic vegetation δ¹³C, as well as pelagic, benthic and littoral invertebrate δ¹³C, reflected isotope mixing along the river-lake transition zone. Fishes with similarly enriched δ¹³C were used to identify benthopelagic and littoral trophic pathways. River and Lake Superior organic matter (OM) sources contributed to both pathways. Differences between the δ¹³C in fishes and invertebrate prey revealed that fish production was supported at multiple spatial scales. The result was that the food web specific to any location along the transition zone incorporated multiple OM sources from across the watershed.     

滇池湖滨带叶绿素a与营养盐空间分布特征

为探讨滇池湖滨带叶绿素a与营养盐空间分布特征及其对滇池水体富营养化的影响,在滇池湖滨带设置21个采样点进行水质调查,采集滇池水样,分析测定总氮(TN)、总磷(TP)、化学需氧量(CODCr)、叶绿素a(Chla)和悬浮固体(SS)。结果表明:滇池湖滨带水体TN、TP、CODCr、Chla、SS浓度均值的空间分布存在差异,叶绿素a空间分布呈现北高南低,西高东低的趋势。滇池湖滨带的北部和东部水体Chla与TN极显著相关,TN具有强变异性。南部和西部TN与CODCr、TP显著相关,南部Chla与营养盐空间变异性较小,污染风险相对较小。按照"一区一策"的原则,滇池北部和东部湖滨带富营养化以控制TN的水平为主,南部、西部的富营养化防控则需要控制整体营养盐元素浓度。     

Impact of Spawning Substrate Complexity on Egg Survival of Atlantic Herring (<Emphasis Type="Italic">Clupea harengus</Emphasis>, L.) in the Baltic Sea

Shallow shore zones are generally considered to provide juvenile habitats for many invertebrate and fish species and additionally serve as spawning grounds for important components of oceanic food webs and fishery resources such as herring (Clupea spp.). Herring attach their demersal eggs to benthic substrates, rendering reproduction success vulnerable to environmental changes and local habitat alterations. However, little information is available on the effects of different substrates on the survival of demersal eggs. Hypothesizing that the structural complexity of spawning substrates generally affects herring egg survival and that the effect magnitude depends on the suitability of ambient environment, field experiments were conducted on a major spawning ground of C. harengus in the Southwestern Baltic Sea. Herring eggs were artificially spawned on substrates of different structural complexities and incubated in situ under differing temperature regimes, at the beginning and the end of the natural herring spawning season, to include the full suite of stressors occurring on littoral spawning beds. Results of this study indicate a positive relation between high structural complexity of spawning substrates and herring egg survival. Mean egg mortality was three times higher on substrates of lowest complexity than on highly complex substrates. These differences became even more prominent under unfavorable conditions that appeared with rising water temperatures later in the spawning season. Although the mechanisms are still unclear, we conclude that structural complexity, particularly formed by submerged aquatic vegetation, provides a crucial prerequisite for the successful reproduction of substrate spawning marine fishes such as herring in the Baltic Sea.     

白洋淀和密云水库野生鲤鱼耳石热释光特征研究

鱼耳石的主体由生命矿物文石组成，其研究在过去二三十年中已取得了不少成果，但是将热释光技术用于鱼耳石的研究未见报道。本文对生长在河北白洋淀和北京密云水库的野生鲤鱼耳石的热释光曲线特征进行了研究，分析了两水域野生鲤鱼耳石中陷阱深度（E）值的差别。热释光测试结果显示，白洋淀10颗鲤鱼耳石样品热释光曲线的峰点温度（T）、发光强度（J）、积分强度（S）和半高宽（w）的均值大于密云水库，而且前者热释光曲线各参数值和E值的稳定程度均不如后者。分析还表明白洋淀鱼耳石在不同温度下的电子和空穴的逃逸几率（α）均大于密云水库。据调查，白洋淀各水体较密云水库水体的环境复杂，污染程度高。研究结果表明，鱼耳石的热释光曲线特征对鱼所生长的水体水质和水环境相当敏感，通过更深入研究，可能成为水质和水环境的重要标型。     

武汉市湖泊汞污染现状研究

对武汉市远郊区、城乡结合部和市区三种环境中6个湖泊沉积物和鲢鱼肌肉中的汞污染特征进行了调查采样,采用原子荧光光谱仪进行了汞含量的测定.结果表明:与环境背景值相比,各湖泊沉积物均不同程度地遭受了汞污染,且汞污染表现出由市区向远郊呈减弱的趋势;在沉积柱垂直方向上,市区湖泊表层汞污染严重,向深层汞含量迅速降低,郊区湖泊沉积柱的汞含量基本上变化不大;沉积物中汞的赋存形态研究表明,汞在各湖泊中主要以惰性残渣态形式出现,反映了以飘尘和悬浮物颗粒形式输入为主的特点;湖泊鲢鱼肌肉中汞含量与沉积物中汞含量的变化规律一致,城区湖泊鲢鱼肌肉中的汞含量大大高于郊区湖泊,但鲢鱼肌肉中的汞含量尚未超出国家标准,属安全范围.     

滇池水中铝的形态分布初探

采用铬天青S光度法对滇池水中的总铝和各主要形态铝进行分析，并利用简单易行的紫外吸收表征水中有机物污染程度和颗粒物含量，初步探讨了各因素的变化对铝形态分布的影响。