New seismo-stratigraphic and marine magnetic data of the Gulf of Pozzuoli (Naples Bay, Tyrrhenian Sea, Italy): inferences for the tectonic and magmatic events of the Phlegrean Fields volcanic complex (Campania)

A detailed reconstruction of the stratigraphic and tectonic setting of the Gulf of Pozzuoli (Naples Bay) is provided on the basis of newly acquired single channel seismic profiles coupled with already recorded marine magnetics gathering the volcanic nature of some seismic units. Inferences for the tectonic and magmatic setting of the Phlegrean Fields volcanic complex, a volcanic district surrounding the western part of the Gulf of Naples, where volcanism has been active since at least 50 ka, are also discussed. The Gulf of Pozzuoli represents the submerged border of the Phlegrean caldera, resulting from the volcano-tectonic collapse induced from the pyroclastic flow deposits of the Campanian Ignimbrite (35 ka). Several morpho-depositional units have been identified, i.e., the inner continental shelf, the central basin, the submerged volcanic banks and the outer continental shelf. The stratigraphic relationships between the Quaternary volcanic units related to the offshore caldera border and the overlying deposits of the Late Quaternary depositional sequence in the Gulf of Pozzuoli have been highlighted. Fourteen main seismic units, both volcanic and sedimentary, tectonically controlled due to contemporaneous folding and normal faulting have been revealed by geological interpretation. Volcanic dykes, characterized by acoustically transparent sub-vertical bodies, locally bounded by normal faults, testify to the magma uprising in correspondence with extensional structures. A large field of tuff cones interlayered with marine deposits off the island of Nisida, on the western rim of the gulf, is related to the emplacement of the Neapolitan Yellow Tuff deposits. A thick volcanic unit, exposed over a large area off the Capo Miseno volcanic edifice is connected with the Bacoli-Isola Pennata-Capo Miseno yellow tuffs, cropping out in the northern Phlegrean Fields.     

Identification and dispersion of the campanian ash layer (Y-5) in the sediments of the Eastern Mediterranean

Sedimentological, mineralogical, optical, and geochemical analyses were used to identify pyroclastic material contained within gravity and piston cores recovered from the northwestern Aegean and Gulf of Corinth areas of the eastern Mediterranean Sea. The lithological, optical, and elemental signatures of the tephra suggest that the material originated from the Campanian Province of Italy, and is known as the Campanian Ash Layer or Y-5. The identification of the Y-5 layer in these two previously unreported areas extend the distribution of this stratigraphic marker and increases the quantitative estimates of pyroclastic material volume. In addition, our knowledge of sedimentary processes active within these two areas is extended.     

苏门答腊外海13.5万年来的火山灰记录:来自深海沉积物岩心IR-GC1的证据

Three volcanic ash layers were identified in a deep-sea Core IR-GC1 from the north-eastern Indian Ocean, adjacent to western Indonesian arc. They were dominated by glass shards with minor mineral crystals, such as plagioclase, biotite, and hornblende. According to the morphology and major element compositions of the representative glass shards, combined with the δ18O-based age, it is suggested that ash Layer A is correlated to the youngest Toba tuff(YTT), Layer B is supposed to be associated with a new eruption of Toba caldera in an age of 98 to 100 ka. Ash Layer C is different the geochemistry characteristics than those of Layer A and Layer B, suggesting that Layer C was not originated from Toba but registered another volcanic eruption event.     

Analysis of the magnetic anomaly field of the volcanic district of the Bay of Naples, Italy

We here present and discuss the results of the analysis and qualitative interpretation of two magnetic surveys performed in the Bay of Naples in 1998 and 2000. A map of the Bay of Naples based on the data acquired during these surveys has already been published by the Italian CNR-IAMC Research Institute. We re-processed the same data to produce maps of the pole reduced, analytic signal and horizontal derivative data and correlated them with the bathymetry and the gravimetric data of the area. The analysis shows strong anomalies in the NW and NE volcanic areas of the Bay of Naples, while the central area seems magnetically quiet. In the Phlegrean area the maps clearly show the southern rim of the Phlegrean caldera and demonstrate that while the Magnaghi Canyon is correlated to gravimetric highs and magnetic structures, and can therefore be interpreted as an active lineament, most of Dohrn Canyon is not characterized by volcanic activity and does not correlate to any gravimetric or magnetic structures. An important round-shaped magnetic anomaly is for the first time identified in the central slope of the gulf between the two canyons, probably correlated to a large buried volcanic edifice. In the Vesuvian area some intense circular anomalies, aligned in the NNW–SSE direction, are localized in the Torre del Greco and Torre Annunziata offshore, related to the submerged part of Vesuvius and possibly connected to buried vents.     

Petrographic and magnetic properties of tephra in a deep-sea core from the northwest Pacific

All the tephra layers sampled from a core in the northwest Pacific have both ortho-and clinopyroxenes as essential minerals, most of them containing hornblende and some of them biotite, zircon, apatite and olivine. Refractive indices of volcanic glass shards range between 1.49 and 1.53. Comparison of the refractive indices with those of artificial glass beads as well as the mineralogical composition of the tephra suggest that its sources are possibly acidic volcanoes in the Japanese island arc. Magnetic and crystallographic features of the ferromagnetic constituents in tephra have also shown that the tephra originated not from oceanic basalt but from acidic volcanoes.     

基于海洋细菌为受试生物的海洋防污剂快速筛选方法

本文研究探索了一种快速简单易行的海洋防污剂室内评价筛选方法。将待测防污剂均匀分散于凝胶溶液中,然后均匀涂布到一定面积的玻璃板上,固化得到含防污剂凝胶测试板,将其置于接种有三种分离自舟山以东海域的优势海洋菌种(编号为Y-16,W-1和F-6)的人工加富海水中,连续培养24h后显微镜下可发现凝胶板表面上细菌菌落,将凝胶板表面细菌淋洗、定容,测定其光密度(optical density,OD)值,计算平均抑菌率,得到吡啶硫酮锌(ZPT)为38.87%,吡啶硫酮铜(CPT)为41.24%,三甲基氧化锡(TBTO)为65.19%,N,N-二甲基-3,4-二氯苄胺(DCDMA)为30.88%,敌草隆(Diuron)仅为15.29%,抑菌性大小为TBTOCPTZPTDCDMADiuron。实验结果表明5种受试防污剂的抑菌性大小为TBTOCPTZPTDCDMADiuron。采用绘制OD-t生长曲线法,分别得到5种防污剂对3种海洋细菌的最小抑制浓度(minimum inhibitory concentration,MIC),TBTO对三种菌的MIC均为0.5×10–3mg/mL;CPT对W-1和F-6的MIC为0.97×10–3mg/mL,对Y-16的MIC为1.93×10–3mg/mL;ZPT对W-1和Y-16的MIC为1.91×10–3mg/mL,对F-6的MIC为0.96×10–3mg/mL;DCDMA对W-1和F-6的MIC为8.46×10–3mg/mL,对Y-16的MIC为×10–342.29mg/mL。其中,Diuron对细菌的生长几乎没有抑制作用。其抑菌性与室内短期挂板结果具有一致性,表明经OD-t生长曲线得到的MIC可作为溶剂可溶型防污剂评价的辅助方法。另外,将本文中室内短期挂板方法应用于不同粒径的氧化亚铜的防污评价,也取得了与文献一致的结果。     

Evidence of relief inversion from the rim-syncline of Bannock Basin

The last steps in the geological exploration of Bannock Basin (cruises BAN-88 and BAN-89 of R.V. Bannock) provided direct evidence of an inversion of relief that was long suspected but hitherto never recorded.

Dolostones and dolomitic mudstones of probable Messinian age subcropping beneath the brine in the northern part of Bannock Basin and Zanclean oozes recorded on the sill separating two narrow and elongate satellite basins along the eastern part of the rim-syncline record a relief inversion during their evolution from cylindric folds to collapse structures.

In particular, the core from the eastern intrabasin sill contains two major unconformities: one separates early Zanclean oozes from late Piacenzian pelagic sediments characterized by winnowed layers, inclined bedding and incipient hardgrounds, and the second separates the latter from Middle Pleistocene pelagic sediments. The deepening is certainly post-late Piacenzian (post-M Pl 6 biozone) because sediments of that age record an actively uplifting structure.

Another argument in favour of the relief inversion, and of the youthful age of the deepening, is derived from a core raised from the northern part of the major western basins (large sill separating Maestro from Borea basins) which contains a coarse turbidite of North African origin representing an upflow turbidite similar to others recorded on the outer slopes of the Mediterranean Ridge. This unique finding in the area of Bannock Basin is preserved in the central part of the collapse basin, whereas in other settings an erosional gap is noticed at the equivalent stratigraphic position.     

Buried nodules and associated sediments from the central Indian basin

Buried nodules from siliceous sediments in the central Indian Basin are morphologically variable and mineralogically consist ofd-MnO₂ and incipient todorokite. Compositionally they are weakly diagenetic. The sediment coarse fractions (>63 μm) at different depths show variable abundances of micronodules, volcanic glass shards and biodebris. Dissolution of biodebris increases and abundance of micronodules decreases with increasing depth. Enrichment in Mn, Fe, Cu, Ni, Co, together with a decrease in organic carbon in the sediment column, may result from diagenetic metal remobilization. Diagenetically remobilized trace metals might have been utilized for the growth of micronodules over the buried nodules. The details of the chemical analyses of buried nodules and associated sediments can be obtained from the first author.     

Prolonged Magmatic and Tectonic Development of the Caribbean Igneous Province Revealed by a Diving Submersible Survey

Using the diving submersible survey NAUTICA we investigated the central part of the Caribbean large igneous province (CLIP) to observe and sample internal portions of this proposed oceanic plateau. Most of the samples are gabbroic and doleritic rocks; basalts are scarce. Radiometric dating by ⁴⁰Ar/³⁹Ar incremental heating experiments indicate that the intrusive rocks are Campanian in age (81–75 Ma). In some places these intrusive rocks underlie older Santonian (85–83 Ma) extrusive basaltic rocks, suggesting that the Campanian rocks represent a sill injection and an underplating episode. Results of the diving program supplemented by information from ODP and DSDP drilling sites document a 20 m.y. period (94–75 Ma) of igneous activity in the submerged portion of the Caribbean large igneous province (CLIP). In the northern part of the Beata Ridge late Campanian and/or post Campanian uplift is documented by prominent Maastrichtian (71–65 Ma) erosion and the establishment of a Paleocene-middle Eocene (65–49 Ma) carbonate platform. During and after the uplift an extensional period is indicated by seismic images and the subsidence (3 km depth) of the carbonate platform. Paleocene ages (55–56 Ma) determined on some volcanic samples are attributed to localised decompression mantle melting that accompanied the extension. We document a prolonged period of magmatic and tectonic events that do not fit with the current models of short-lived plateau formation during mantle plume initiation but shares many similarities with the constructional histories of other oceanic large igneous provinces.     

利用H/V方法研究琼北火山区的浅表层地质变化特征

海南琼北活火山作为华南沿海重要的第四纪火山, 一直受到国内外学者的广泛关注, 目前对该火山的形成演化已开展了大量深部地质结构的研究, 但对其表层地质结构特征仍然缺乏详细了解。水平-垂直频谱比法(简称H/V方法)已被广泛应用于浅表层地质结构的研究, 本文基于35个便携式微功耗地震仪组成的流动台阵观测数据, 采用经典全波场H/V_(full)和瑞利波椭圆率H/V_(Ray)分析方法, 获得了琼北火山区H/V曲线峰值频率(F₀)和放大倍数(A₀)的空间变化特征。琼北火山区H/V曲线峰值频率变化强烈, 以长流-仙沟断裂为界, 断裂西南侧很难从H/V曲线中获取清晰的F₀和A₀, 而断裂东北侧则存在明显的F₀和A₀。结合已有地质资料, 本文认为长流-仙沟断裂西南侧处于凹陷区, 其浅表层火山岩未发生明显的风化作用, 而东北侧位于隆起区域, 地表火山岩受到了比较严重的风化作用。这一研究结果表明, H/V方法可反映表层火山岩的风化状态, 火山岩出露场地H/V曲线的峰值频率和放大倍数随风化作用程度的增强而表现得更加明显。本研究为琼北火山区浅表火山岩风化状态和地震危险性评估提供了重要的信息支撑。     

冲绳海槽中段末次冰消期以来的元素地层

在对冲绳海槽中段180号岩心进行高分辨率取样的基础上,测定了沉积物中的23个地球化学指标,通过对各元素与Al₂O₃含量的比值在岩心中的垂向变化规律的分析,结合氧同位素、黏土矿物、粒度、AMS14C测年和R型因子分析方法,可将岩心从上至下划分为5层:第1,3,5层具有相似的元素组合特征,第2,4层为明显的异常变化层位,将元素的地球化学行为、元素组合与物质来源联系起来,并与碎屑矿物、古生物资料对比,探讨岩心中元素组合垂向变化的制约因素,据此讨论了冲绳海槽中段末次冰消期以来陆源、火山源及生物源物质的分布规律。结果表明,冲绳海槽中段末次冰消期以来的沉积物来源以陆源物质为主,但在局部层位可因生源组分和火山源组分的强烈影响而发生实质性的变化。     

Experimental Study on Coupled Cross-Flow and in-Line Vortex-Induced Vibration of Flexible Risers

In this work, we study the coupled cross-flow and in-line vortex-induced vibration （VIV） of a fixedly mounted flexible pipe, which is free to move in cross-flow （ Y- ） and in-line （ X- ） direction in a fluid flow where the mass and natural frequencies are precisely the same in both X- and Y-direction. The fluid speed varies from low to high with the corresponding vortex shedding frequency varying from below the first natural frequency to above the second natural frequency of the flexible pipe. Particular emphasis was placed on the investigation of the relationship between in-line and cross-flow vibration. The experimental results analyzed by using these measurements exhibits several valuable features.     

晚中新世南海珍贝-黄岩海山岩浆活动及其演化:岩石地球化学和年代学证据

南海海盆15°N附近呈东西向展布的珍贝-黄岩海山被认为是32~17Ma前南海海盆的残留扩张中心.对采自黄岩海山的两个火山岩样品(9DG,9DG-2)进行了岩石学、地球化学和年代学研究.两个样品的SiO₂含量分别为60.3%和63.6%,Al₂O₃含量分别为17.56%和17.55%,TiO₂含量分别为0.48%和0.31%,碱度率分别为3.88和3.62.根据岩石学和岩石化学分类,样品属碱性系列的粗面岩.对稀土元素和微量元素分析表明岩石具有洋岛玄武岩(OIB)型配分型式,轻重稀土总量比(∑c(LREE)/∑c(HREE))和球粒陨石标准化镧镱比((La/Yb)N)分别高达17.22和27.23,并具有铕负异常和锶、磷、钛亏损的特点.样品9DG的锶-钕-铅同位素分析结果为锶-87的含量与锶-86的含量之比值为0.704183,钕-143的含量与钕-144的含量之比值为0.512827,铅-206的含量与铅-207的含量之比值为18.68668,铅-207的含量与铅-204的含量之值为15.67962,铅-208的含量与铅-204的含量之比值为39.00261,表明初始岩浆来自软流圈地幔,具有与珍贝海山玄武岩相似的同位素组成.经钾-氩法测年,粗面岩的年龄为(7.77±0.49)Ma,略晚于珍贝海山玄武岩的年龄[(9.1±1.29)~10.0±1.80Ma],属于南海扩张期后晚中新世火山活动的产物.对比珍贝海山玄武岩的地球化学和同位素特征,认为两者有相同的岩浆源区,但是它们经历了不同程度的结晶分异过程,在晚中新世期间珍贝-黄岩海山可能有地幔柱活动.     

南海火山玻璃的分布特征、化学成分及源区探讨

研究了南海火山玻璃的分布特征、化学成分及源区,结果表明,表层沉积物中的火山玻璃含量基本呈南北向分布,由北部、西部、南部大陆架分别向中部、东部深海盆逐渐增加;柱样沉积物中的火山玻璃在深海盆出现的层数多、含量大.火山玻璃化学组分之间的相关性不显著,表层沉积物中的火山玻璃属于安山岩,柱样沉积物中的火山玻璃的岩石类型广泛,主要属于安山岩和流纹岩.菲律宾岛弧火山带、南海深海盆火山喷发以及印尼岛弧火山带是南海火山玻璃主要源区,火山玻璃搬运和沉积主要受台风、越赤道气流和环流的影响和控制.     

Shallow-Water Gasohydrothermal Vents of Ushishir Volcano and the Ecosystem of Kraternaya Bight (The Kurile Islands)

Abstract. A marine ecosystem in the crater of the Ushishir Volcano (Kraternaya Bight, Yankich Island, the Kuriles) showing gasothcrmal activity was studied for hydrographical, hydrochemical, and biological characteristics. Maximal changes in chemical and biological characteristics were observed in the surface water layer of 0–5 m. This layer had higher water temperature, was saturated with volcanogcnic carbon dioxide (up to 2000 10^-6 torr), ovcrsaturatcd with oxygen (up to 200 %), and contained high concentrations of chlorophyll a. Hydrogen sulfide was found in the surface water layer and at a depth of 15 m in the area of maximal effect of volcanic effluents.
The planktonic community is characterized by high rates of production and destruction of organic matter only in the 0–5 m layer. Daily vertical migrations of the ciliatc Mesodinium rubrum were observed, which caused "red tides".
Bacterial, algobacterial, and diatom mats developed on the bottom of the bight in the zone of gasohydrothermal vents and in areas of volcanic water seeping. The rate of organic matter production in algobacterial mats reached 33.4g C-rrr²-d^-l, chcmolithotrophy predominating. Bottom settlements had high population density and great animal biomass, which reached 10 kg m^-2 in gasohydrothermal fields. They obtain sufficient energy from primary production of microphy-tobenthos, algobacterial, and bacterial mats. Bcnthic species dominant in the bight were not found off the Ushishir Islands.
Some species of macrobenthos inhabiting the Kraternaya Bight differ markedly in size and biomass from the same species found beyond the bight.     

Ice-rafted volcanic ash in the South Atlantic sector of the Southern Ocean during the last 100,000 years

Eucampia antarctica (Castr.) Mangin abundance curves for two piston cores from the western Agulhas Basin (southeast Atlantic sector of the Southern Ocean) were used to place volcanic glass shard and ice-rafted debris abundance curves into a stratigraphic framework for the last 100,000 years. A direct correlation is shown between increased abundance of E. antarctica, tephra and ice-rafted debris; low abundances are often characterized by calcareous sediment in the northern core. Peaks in abundance of E. antarctica have been interpreted as an indication of glacial periods and the increased ice-rafted debris and tephra during glacial periods is evidence for an ice-rafted origin for the tephra.Microprobe geochemical analysis of volcanic glass shards provides no single distinct source for the ash. The geochemical data is consistent, but not definitive, with a primary source in the Scotia Arc and a minor source from Bouvet Island. Between core correlations of geochemically “fingerprinted” dispersed tephra zones were not successful due to variability of glass shard geochemistry and limited sample size.     

Source and magmatic evolution of ocean island basalts from the Pohnpei Island,Northwest Pacific Ocean: Insights from olivine geochemistry

The compositional variability of ocean island basalts (OIBs) is thought to reflect partial melting of a lithologically-heterogeneous mantle source dominated by either pyroxenite or peridotite. The Pohnpei Island in Micronesia, which is associated with the Caroline hotspot, is suggested to have been generated from partial melting of a pyroxenite-rich mantle. To examine this hypothesis, we present new major- and trace-element compositions of olivine phenocrysts in basalts from the island. The olivines exhibit large systematic inter- and intra-crystalline compositional variability. In Sample DS1, olivines record compositional zonation, in which cores have relatively high Fo (77–85), Ni (550×10?6–2 392×10?6), and Fe/Mn ratios (66–82), whereas rims have lower Fo (71–78), Ni (526×10?6–1 537×10?6), and Fe/Mn ratios (51–62). By contrast, olivines within other samples preserve no clear compositional zonation, exhibiting similar or slightly lower Fo values (66–78), Ni contents (401×10?6–1 268×10?6), and Fe/Mn ratios (53–69) as the rims of zoned crystals. The distinct chemical contrast between the two different types of olivine suggests they formed in magma chambers at different depths. Analysis using forward petrological modeling and multi-element indicators (Fe/Mn, Zn/Fe, FC3MS (FeOT/CaO?(3×MgO/SiO₂)), Mn/Zn, and Ni/(Mg/Fe)) of whole-rock samples and high-Fo olivines is inconsistent with a pyroxenite-rich mantle source. We suggest these inconsistencies reflect an influence on the partition coefficients of Ni and Mn between olivine and liquid during melting at variable pressures and temperatures. In addition, magma recharge and mixing within the magmatic plumbing system can change the composition of olivine. We suggest that identification of the mantle source of OIBs in volcanic islands such as the Pohnpei Island using olivine geochemistry should be treated with caution.     

Geological reconstruction of Fangataufa atoll, South Pacific

Several boreholes drilled by the Commissariat à l'Energie Atomique have reached and passed through the volcanic bedrock of Fangataufa atoll. The sampled volcanic rocks under the coral ring were produced during both aerial and submarine activity, whereas rocks drilled under the lagoon were erupted during submarine volcanism only. The bathymetric data show that the atoll has a “starfish” shape. The rift zones are elongated in N-S, N70–80 and N120 directions; these three main directions are also the directions of structural discontinuities in the lithosphere. Reconstruction of the atoll's topography before erosion using a slope angle of about 16° shows that the maximum height reached by the volcano was about 1300 m above sea level. For comparison, the maximum height of Méhetia island (southeast of Tahiti) is approximately 435 m. The successive construction stages are: (1) initiation of volcanism along the rift zones and construction of a central volcano; (2) production of brecciated lavas; (3) emergent volcanism; and (4) central and aerial activity. The present day position of the aerial volcanic rocks under the coral reef and the submarine products under the lagoon is discussed with reference to two hypotheses. The first is based on sea level changes and the second on a tectonic origin (collapse of the atoll's flanks). Using recent geochronological data, the submarine construction of the atoll related to the hot-spot activity lasted about 1.1 Ma. The accumulation rate was approximately 0.7 cm/yr (1.5 × 10⁻³ km³/yr) and the aerial volcanic activity lasted about 2 Ma (1.5 × 10⁻⁵ km³/yr).     

西沙群岛基底火山碎屑岩中单斜辉石的矿物化学特征及其地质意义

本文利用电子探针对南海西沙群岛琛航岛珊瑚礁底部火山碎屑岩中的单斜辉石矿物的化学特征进行了研究。结果表明,该单斜辉石属于富钙透辉石,部分有正环带结构,从核部到边部Ca、Fe、Ti的含量逐渐增加,是岩浆正常结晶顺序的反映,说明该区域的岩浆演化是向着富Ca、Fe、Ti方向发展的。主量元素数据显示,单斜辉石具有低Si高Al的特征(SiO₂=41.40%～48.44%,Al₂O₃=5.54%～10.20%),且AlⅣ含量较高,说明母岩浆为不饱和碱性岩浆系列;此外,单斜辉石Ca含量偏高,Ca/(Ca+Mg+Fe)值在46.1%～51.4%之间,推测是母岩浆的高Ca含量导致了大量高钙辉石的产出。结合西沙海域的地震和构造资料,推测琛航岛珊瑚礁的基底是玄武质火山碎屑岩组成的平顶状海山,系岩浆穿过断裂发育的岩石圈层在西沙群岛的海底喷发,随后火山碎屑物质经过堆积、固结作用而形成;该火山碎屑岩的原岩为板内碱性玄武岩。     

Initial stage of the hydrothermal ore accumulation within the field at 9°50′ N on the East Pacific Rise

In 2003, several hydrothermal mounds located at 9°50′ N on the East Pacific Rise were described and sampled during the expedition of R/V Akademik Mstislav Keldysh during dives of Mir deep-sea manned submersibles. These hydrothermal mounds were formed during a few recent years after the volcanic activity in this region that occurred in 1991. The studies of the chemical and mineralogical compositions of the hydrothermal deposits of these mounds and of the chemical composition of the principal sulfide minerals helped to describe the initial stage of the formation of the hydrothermal circulation system and the initiation of the hydrothermal ore formation.