Seismic intensity zoning and earthquake risk mapping in Iraq

The recently published Iraqi earthquake data file over the period 1905–1984 is used to derive a local I _o -M _s formula. This is then combined with a local intensity attenuation relationship to compile the observed I _o (MM) zoning map for Iraq. Earthquake risk is calculated using the log N (M _s )relation for selected design magnitudes and periods and is mapped as the (%) probability of occurrence using a 0.5 deg latitude/longitude grid system. It is observed that the intensity zones and contour distributions are highly influenced by the presence of large magnitude shocks while risk maps reveal the Tauros seismogenic zone as having a greater risk of occurrence than the Zagros zone. The compiled zoning maps are intended for the use of local practising engineers for earthquake-resistant design procedures that are currently being adopted in the country.     

Distribution of effects in the urban area of Rome During the October 14, 1997 Umbria Marche earthquake

In the last years many studies were carried out in order to assess the correlation between nearsurface geology and seismic response of downtown Rome during local and regional earthquakes. Nevertheless, only historical macroseismic data and theoretical modelling could be used so far to estimate the ground motion in the historical part of the city. The occurrence of the October 14, 1997 Umbria Marche event (M_w = 5.7), located about 115 km far from Rome but largely felt in the city, allowed us to verify our knowledge of the seismic response on the basis of the present urban setting of Rome.A prompt macroseismic survey in the urban area within the ring-road (G.R.A.) was performed. 949 questionnaires were compiled by means of 1842 interviews: such a large amount of macroseismic information, for the first time available in Rome, was related to 669 observation points providing a picture of local intensity variations. The areal distribution of collected intensity points is quite homogeneous.The data analysis points out a preferential distribution of larger effects (65%) in correspondence of Holocene alluvium outcrops. Furthermore, a tight correspondence between remarkable intensities and alluvial sediments is pointed out in suburban areas characterized by the minor hydrographic network of the Tiber River. Macroseismic anomalies were outlined in sectors of the urban area where local hydrogeological conditions can be responsible for a significant deterioration of geomechanical properties.     

The record of historic earthquakes in lake sediments of Central Switzerland

Deformation structures in lake sediments in Central Switzerland can be attributed to strong historic earthquakes. The type and spatial distribution of the deformation structures reflect the historically documented macroseismic intensities thus providing a useful calibration tool for paleoseismic investigations in prehistoric lake sediments.The Swiss historical earthquake catalogue shows four moderate to strong earthquakes with moment magnitudes of M_w=5.7 to M_w=6.9 and epicentral intensities of I₀=VII to I₀=IX that affected the area of Central Switzerland during the last 1000 years. These are the 1964 Alpnach, 1774 Altdorf, 1601 Unterwalden, and 1356 Basel earthquakes. In order to understand the effect of these earthquakes on lacustrine sediments, four lakes in Central Switzerland (Sarner See, Lungerer See, Baldegger See, and Seelisberg Seeli) were investigated using high-resolution seismic data and sediment cores. The sediments consist of organic- and carbonate-rich clayey to sandy silts that display fine bedding on the centimeter to millimeter scale. The sediments are dated by historic climate and environmental records, ¹³⁷Cs activity, and radiocarbon ages. Deformation structures occur within distinct zones and include large-scale slumps and rockfalls, as well as small-scale features like disturbed and contorted lamination and liquefaction structures. These deformations are attributed to three of the abovementioned earthquakes. The spatial distribution of deformation structures in the different lakes clearly reflects the historical macroseismic dataset: Lake sediments are only affected if they are situated within an area that underwent groundshaking not smaller than intensity VI to VII. We estimate earthquake size by relating the epicentral distance of the farthest liquefaction structure to earthquake magnitude. This relationship is in agreement with earthquake size estimations based on the historical dataset.     

Constraints on the location and mechanism of the 1511 Western-Slovenia earthquake from active tectonics and modeling of macroseismic data

The 1511 Western Slovenia earthquake (M = 6.9) is the largest event occurred so far in the region of the Alps–Dinarides junction. Though it strongly influences the regional seismic hazard assessment, the epicenter and mechanism are still under debate. The complexity of the active tectonics of the Alps–Dinarides junction is reflected by the presence of both compressional and transpressional deformations. This complexity is witnessed by the recent occurrence of three main earthquake sequences, the 1976 Friuli thrust faulting events, the 1998 Bovec–Krn Mountain and the 2004 Kobarid strike-slip events. The epicenters of the 1998 and 2004 strike-slip earthquakes (M_s = 5.7 and M_s = 4.9, respectively) lie only 50 km far from the 1976 thrust earthquake (M_s = 6.5).We use the available macroseismic data and recent active tectonics studies, to assess a possible epicenter and mechanism for the 1511 earthquake and causative fault. According with previous works reported in the literature, we analyze both a two-and a single-event case, defining several input fault models. We compute synthetic seismograms up to 1 Hz in an extended-source approximation, testing different rupture propagations and applying a uniform seismic moment distribution on the fault segments. We extract the maximum horizontal velocities from the synthetics and we convert them into intensities by means of an empirical relation. A rounded-to-integer misfit between observed and computed intensities is performed, considering both a minimized and a maximized databases, built to avoid the use of half-degree macroseismic intensity data points. Our results are consistent with a 6.9 magnitude single event rupturing 50 km of the Idrija right-lateral strike-slip fault with bilateral rupture propagation.     

Analysis of macroseismic and instrumental data for the study of the 19 November 1923 earthquake in the Aran Valley (Central Pyrenees)

The 19 November 1923 earthquake in the Aran Valley (Central Pyrenees), with observed maximum intensityI _max = VIII (MSK), has been studied through the compiling and reviewing of macroseismic information and collecting and processing early seismograms. Analysis of macroseismic data gives a focal depth ofh = 5 km and an anelastic attenuation coefficient 10^–3 km^–1. Analysis of early instrumental records allows the computation of estimate of magnitude (M _L = 5.6) and seismic moment (M _o = 1.1 × 10¹⁷ N × m) which are consistent with the values ofI _o andh obtained from macroseismic data.     

The earthquake in the Swabian Jura of 16 November 1911 and present concepts of seismotectonics

Beginning with the Swabian Jura earthquake in 1911 the seismic activity in Central Europe is concentrated to this area. A comparison with other events of the same epicentral region shows that the largest earthquake in Germany has the character of a left-lateral horizontal strike slip striking N — NNE. The focal parameters can be assumed within the following intervalls: Seismic moment M_o = 1…8·10¹⁷ Nm; focal area F_o = 18…53 km²; average dislocation d_o = 20…53 cm and stress drop Δp_o = 13…19 bar.     

Analyses of Seismic Deformation at the Kibyra Roman Stadium,Southwest Turkey

The ancient city of Kibyra in southwest Turkey has the potential to reveal the location and date of historical earthquakes. The most compelling evidence for earthquake faulting is observed in the city's Roman stadium. Damage related to seismic shaking is characterized by systematically collapsed columns, dilated and collapsed walls, and by rotated and displaced blocks in the stadium. Detailed archaeoseismological observations suggest that Kibyra was affected by earthquakes that were also recorded in historical earthquake catalogs. Although there is no historical record of a large earthquake after the 5th century A.D., Optically stimulated luminescence (OSL) dating of deposits under the collapsed blocks suggests a later seismic event. OSL results indicate that another large event occurred in southwest Turkey, probably around the 10–11th century A.D., and caused extensive damage (I_o = VIII‐IX) to the Kibyra stadium.     

Earthquakes in Switzerland and surrounding regions during 2006

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2006. During this period, 572 earthquakes and 91 quarry blasts were detected and located in the region under consideration. Of these earthquakes, two occurred in conjunction with the construction of the new Gotthard railway tunnel and 165 were induced artificially by the stimulation of a proposed geothermal reservoir beneath the city of Basel. With 20 events with M _L ≥ 2.5, five of which were artificially induced, the seismic activity in the year 2006 was far below the average over the previous 31 years. Nevertheless, six events were felt by the public, most prominently the strongest of the induced Basel events (M _L 3.4), which caused some non-structural building damage. Noteworthy are also the two earthquakes near Cortaillod (M _L 3.2), on the shore of Lake Neuchatel, and in Val Mora (M _L 3.5), between the Engadin and Val Müstair, as well as the 42 aftershocks of the M _L 4.9 Vallorcine earthquake, between Martigny and Chamonix, of September 2005. Editorial handling: Stefan Bucher     

Probabilistic macroseismic hazard assessment for Nicaragua (preliminary results)

A probabilistic macroseismic hazard assessment has been done for Nicaragua. For this, the most complete catalogue for Central America, compiled by NORSAR in Norway has been used. In this catalogue, empirical intensity attenuation relations were found. Using these empirical relations, magnitudes were changed to epicentral intensities expected in sites where no intensities had been reported. The calculated intensities from a polygon surrounding Nicaragua were used to assess the macroseismic hazard in the region. For the whole polygon, the cumulative intensity frequency was calculated resulting in a b-value of 0.60 for an intensity interval of V–IX. The time completeness was also studied indicating that, for strong events causing higher intensities (I ₀ VII), the catalogue is complete for events that have been recorded since 1840. The whole polygon was cut into independent seismotectonic regions where the statistical procedure (intensity frequency and time completeness) was done.     

Attenuation studies based on local earthquake Coda waves in the southern Indian peninsular shield

The Dharwar craton, Cuddapah basin and the Godavari graben characterise three diverse geological and tectonic settings in the peninsular shield of India. Owing to their contiguous proximity, they offer a unique opportunity to document differences, if any, in their seismic wave attenuation characteristics that might have a bearing on the seismogenic nature of the crust in a craton, basin and a rift-like graben structure. An attempt is made here to bring out these differences using constraints from coda-Q. We considered local earthquakes with epicentral distances ranging from␣14 to 150 km recorded at the digital broadband stations at Dharwar (DHD), Cuddapah (CUD) and Kothagudem (KGD) regions to derive the frequency-dependent coda-Q relations. Using the single scattering method, we obtained the frequency-dependent Q _C relationship (Q _C = Q ₀ f ⁿ )for each of the three geological units separately: DHD: Q _C = (730.62 ± 0.09)f ^{(0.54 ± 0.01)}; CUD: Q _C = (535.06 ± 0.13)f ^{(0.59 ± 0.01)} and KGD: Q _C = (150.56 ± 0.08)f ^{(0.91 ± 0.01)}. The Q _C values obtained for all the three sub-regions show moderate to strong frequency dependence and essentially reflect the level of crustal heterogeneities to varying degrees.     

Source parameters of intermediate-depth Vrancea (Romania) earthquakes from empirical Green's functions modeling

Several source parameters (source dimensions, slip, particle velocity, static and dynamic stress drop) are determined for the moderate-size October 27th, 2004 (M_W = 5.8), and the large August 30th, 1986 (M_W = 7.1) and March 4th, 1977 (M_W = 7.4) Vrancea (Romania) intermediate-depth earthquakes. For this purpose, the empirical Green's functions method of Irikura [e.g. Irikura, K. (1983). Semi-Empirical Estimation of Strong Ground Motions during Large Earthquakes. Bull. Dis. Prev. Res. Inst., Kyoto Univ., 33, Part 2, No. 298, 63–104., Irikura, K. (1986). Prediction of strong acceleration motions using empirical Green's function, in Proceedings of the 7th Japan earthquake engineering symposium, 151–156., Irikura, K. (1999). Techniques for the simulation of strong ground motion and deterministic seismic hazard analysis, in Proceedings of the advanced study course seismotectonic and microzonation techniques in earthquake engineering: integrated training in earthquake risk reduction practices, Kefallinia, 453–554.] is used to generate synthetic time series from recordings of smaller events (with 4 ≤ M_W ≤ 5) in order to estimate several parameters characterizing the so-called strong motion generation area, which is defined as an extended area with homogeneous slip and rise time and, for crustal earthquakes, corresponds to an asperity of about 100 bar stress release [Miyake, H., T. Iwata and K. Irikura (2003). Source characterization for broadband ground-motion simulation: Kinematic heterogeneous source model and strong motion generation area. Bull. Seism. Soc. Am., 93, 2531–2545.] The parameters are obtained by acceleration envelope and displacement waveform inversion for the 2004 and 1986 events and MSK intensity pattern inversion for the 1977 event using a genetic algorithm. The strong motion recordings of the analyzed Vrancea earthquakes as well as the MSK intensity pattern of the 1977 earthquake can be well reproduced using relatively small strong motion generation areas, which corresponds to small asperities with high stress drops (300–1200 bar) and high particle velocities (3–5 m/s). These results imply a very efficient high-frequency radiation, which has to be taken into account for strong ground motion prediction, and indicate that the intermediate-depth Vrancea earthquakes are inherently different from crustal events.     

Activity coefficients of MgCOo3 and CaSOo4 ion pairs as a function of ionic strength

Based on potentiometric data and gypsum solubility in mixed salt solutions, respectively, the activity coefficients of MgCO^o₃ and CaSO^o₄ ion pairs decrease with ionic strength (I) at 25°C. Computed γ's for the ion pairs fit the empirical equation log γ_i = ? BI. B coefficients of 0.63 ±0.10 for MgCO^o₃ and 0.45 ± 0.15 for CaSO^o₄ are obtained from linear regression of log γ_i values vs I between 0.04 and 0.6 molal. Assumptions that the activity coefficients of these neutral ion pairs equal unity or are approximated by the Setchenow expression (log γ_i = kI) are therefore invalid at moderate ionic strengths. Log γ_i = ? BI is the same general form as the equation of Kirkwood (Chem. Rev.24, 233–251, 1939) for neutral dipoles.     

Tsunami hazard in the Eastern Mediterranean: strong earthquakes and tsunamis in Cyprus and the Levantine Sea

A modern tsunami catalogue has been compiled for the region of Cyprus-Levantine Sea in which 24 certain or possible local tsunamis are listed from antiquity up to the present time, while six regional tsunamis, generated in the Hellenic arc, are documented which affected the region. Another set of 13 doubtful events not included in the catalogue are discussed. Tsunami intensities k and K were re-evaluated using the classic 6-grade and the new 12-grade intensity scales, respectively. The strongest tsunamis reported in the region of interest are those of 551 AD, 749, 1068, 1201, 1222, 1546 and 1759, all occurring along the Levantine coast from Gaza northward, with the exception of the 1222 wave which occurred in the Cyprean arc. The causative earthquakes, however, occur on land and are associated with the left-lateral strike-slip Levantine rift and, as such, remain unexplained. In this paper we speculate on the mechanism of these events. A second tsunami zone follows the Cyprean arc, where the situation of subaqueous seismogenic sources favours the generation of tsunamis by co-seismic fault displacements. Submarine or coastal earth slumping, however, may be an additional tsunamigenic component. Based on historical data, the average tsunami recurrence in the Cyprus-Levantine Sea region is roughly estimated to be around 30 years, 120 years and 375 years for moderate (k/K ≥ 2/3), strong (k/K ≥ 3/5) and very strong (k/K ≥ 5/8) events, respectively. The rate of tsunami occurrence equals 0.033, 8.3 × 10⁻³ and 2.7 × 10⁻³ events/year for intensity k/K ≥ 2/3, 3/5 and 5/8, respectively. For a Poissonian (random) process the probabilities of observing at least one moderate, strong or very strong tsunami are 0.28, 0.01 and 3 × 10⁻³ within 1 year, 0.81, 0.34 and 0.13 within 50 years and 0.96, 0.56 and 0.24 within 100 years, respectively. The tsunami potential in the Cyprus-Levantine Sea area is low relative to other Mediterranean tsunamigenic regions. However, the destructiveness of some historical events indicates the need to evaluate tsunami hazard by all available means. In addition, remote tsunamigenic sources, such as those of 1303 and 1481 in the eastern Hellenic arc, are able to threaten the coasts of the Cyprus-Levantine region and, therefore, such regional tsunamis should be taken into account in the evaluation of the tsunami risk of the region.     

The 1780 seismic sequence in NE Sicily (Italy): shifting an underestimated and mislocated earthquake to a seismically low rate zone

The southernmost sector of the Italian peninsula is crossed by an almost continuous seismogenic belt capable of producing M ∼ 7 earthquakes and extending from the Calabrian Arc, through the Messina Straits, as far as Southeastern Sicily. Though large earthquakes occurring in this region during the last millennium are fairly well known from the historical point of view and seismic catalogues may be considered complete for destructive and badly damaging events (IX ≤ I _o ≤ XI MCS), the knowledge and seismic completeness of moderate earthquakes can be improved by investigating other kinds of documentary sources not explored by the classical seismological tradition. In this paper, we present a case study explanatory of the problem, regarding the Ionian coast between the Messina Straits and Mount Etna volcano, an area of North-eastern Sicily lacking evidence of relevant seismic activity in historical times. Now, after a systematic analysis of the 18th century journalistic sources (gazettes), this gap can be partly filled by the rediscovery of a seismic sequence that took place in 1780. According to the available catalogues, the only event on record for this year is a minor shock (I _o = VI MCS, M _w = 4.8) recorded in Messina on March 28, 1780. The newly discovered data allow to reinstate it as the mainshock (I _o = VII–VIII MCS, M _w = 5.6) of a significant seismic period, which went on from March to June 1780, causing severe damage along the Ionian coast of North-eastern Sicily. The source responsible for this event appears located offshore, 40-km south of the previous determination, and is consistent with the Taormina Fault suggested by the geological literature, developing in the low seismic rate zone at the southernmost termination of the 1908 Messina earthquake fault.     

Vulnerability of buildings to debris flow impact

Quantitative risk assessments (QRAs) for landslide hazards are increasingly being executed to determine an unmitigated level of risk and compare it with risk tolerance criteria set by the local or federal jurisdiction. This approach allows urban planning with a scientific underpinning and provides the tools for emergency preparedness. Debris-flow QRAs require estimates of the hazard probability, spatial and temporal probability of impact (hazard assessment) and vulnerability of the elements at risk. The vulnerability term is perhaps the most difficult to estimate confidently because (a) human death in debris flows is most commonly associated with building damage or collapse and is thus an indirect consequence and (b) the type and scale of building damage is very difficult to predict. To determine building damage, an intensity index (I _DF) was created as the product of maximum expected flow depth d and the square of the maximum flow velocity v (I _DF = dv ²). The I _DF surrogates impact force and thus correlates with building damage. Four classes of building damage were considered ranging from nuisance flood/sedimentation damage to complete destruction. Sixty-six well-documented case studies in which damage, flow depth and flow velocity were recorded or could be estimated were selected through a search of the global literature, and I _DF was plotted on a log scale against the associated damage. As expected, the individual damage classes overlap but are distinctly different in their respective distributions and group centroids. To apply this vulnerability model, flow velocity and flow depth need to be estimated for a given building location and I _DF calculated. Using the existing database, a damage probability (P _DF) can then be computed. P _DF can be applied directly to estimate the likely insurance loss or associated loss of life. The model presented here should be updated with more case studies and is therefore made openly available to international researchers who can access it at .     

Sedimentology, mineralogy and isotopic analysis of Pellet Lake, Coorong region, South Australia

ABSTRACT Gravity cores of Holocene sediments from a shallow ephemeral lake in the Coorong region (Pellet Lake, southeastern coastal Australia) show a mineral assemblage and sequence particular to its hydrology. The mineralogical sequence above an initial dolomitic siliciclastic sand reflects conditions of increasing salinity in the lower portions of the core (i.e. organic-rich aragonite to magnesite + hydromagnesite + aragonite) followed by a relative decrease in salinity (i.e. magnesite + aragonite + hydromagnesite to aragonite + hydromagnesite) in the upper portions of the core. This sequence is capped by ? 0.4 m of micritic dolomite and minor amounts of hydromagnesite, with the relative abundance of dolomite increasing upwards. Three stratigraphically and spatially distinct dolomite units (upper, lower and margin) are recognized using stable carbon and oxygen isotope data, unit cell calculations and MgCO₃ mole per cent data of the dolomite. Detailed X-ray diffraction (XRD) analyses of samples with more than 80% dolomite shows that the dolomite is ordered. Average unit cell parameters, calculated from the XRD patterns, indicate that the upper dolomite unit has crystal lattices expanded in the c_o direction (c_o= 16.09 Å) relative to ideal dolomite (c_o= 16.02 Å) and contracted in the a_o direction (a_o= 4.796 Å) relative to ideal dolomite (a_o= 4.812 Å). The mol fraction of MgCO₃ in the upper dolomite shows up to 4.0 ±M 2.0 mole per cent excess Mg in the dolomite crystal lattice (calculated from XRD). This unusual dolomite crystal chemistry is probably generated by rapid precipitation from solutions which have greatly elevated Mg/Ca ratios. Transmission electron microscopy reveals that the upper dolomite has a heterogeneous microstructure which also suggests rapid precipitation from solution. The modulated microstructure found in calcium-rich dolomite is completely lacking. Dolomite ordering reflections are present in electron diffraction patterns, but are weak. Stable oxygen and carbon isotope values of the upper dolomite are tightly grouped (ave. δ¹⁸O ～+ 7.55%_o, δ¹³C ～+ 4.10%_o), yet show three upward-lightening oxygen cycles. The oxygen cycles correlate with three upward decreases in the calculated Mg content of the dolomite zone. These cycles may indicate the increased importance of rain-water dilution of the brine at times when the water in the lake was at its shallowest levels. Analyses of the lower dolomite and the margin dolomite suggest that these units precipitated more slowly from less evaporitic brines than the upper dolomite unit. The lower dolomite is close to stoichiometric, has less evaporitic stable isotope values than the upper dolomite, and has only a slightly expanded c_o-axis. The margin dolomite is Ca-rich, has a more homogeneous microstructure, and has expanded a_o and c_o axes. The abundance of relatively soluble Mg-bearing phases, such as hydromagnesite and magnesite, may supply additional magnesium for the dolomitization of aragonite and calcite during subsequent diagenesis and burial of the sediment. This process may leave a finely laminated dolomicrite deposit which retains little, if any, evidence of evaporite minerals.     

The crystal structure of an intermediate scapolite-wernerite

Summary The crystal structure of a scapolite (52% Me) with strong superlattice (h+k+l=odd) reflections has been determined in the space groupP 4₂/n. The three-dimensional intensity data were collected with a normal beam single-crystal diffractometer using Zr-filtered Mo radiation.The result of the present structural investigation, together with two reported previously (Lin andBurley, 1973 a, b) confirms the theoretical conclusions (Lin andBurley, 1973 c). Two quantitative relationships in scapolite have also been established, (1) the exponential relationship between the intensity ratio (r) I _h+k+l=odd/I _h+k+l=even and the atomic displacement of atoms from the mirror plane consistent with the space groupI 4/m; (2) the linear relationship betweenr and the difference in the Al occupancy between T (2) and T (3) sites.The horizontal disposition of the positionally disordered CO₃ groups in this scapolite is the same as in other scapolites, but the vertical disposition is different; the planar CO₃ groups are tilted from the horizontal (001) plane.

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Die Kristallstruktur eines intermediären Skapolithes-Wernerit

Zusammenfassung Die Kristallstruktur eines Skapolithes (52% Me) mit starken Überstrukturreflexen (h+k+l=ungerade) wurde in der RaumgruppeP 4₂/m bestimmt. Dreidimensionale Intensitätsdaten wurden auf einem Normalstrahl-Einkristall-Diffraktometer mit Zr-gefilteter Mo-Strahlung gesammelt.Das Ergebnis der vorliegenden Strukturuntersuchung bestätigt zusammen mit früheren Ergebnissen (Lin undBurley, 1973a, b) die theoretischen Schlüsse vonLin undBurley (1973c). Zwei quantitative Beziehungen bei Skapolith wurden aufgezeigt: 1. Die Exponentialbeziehung zwischen dem Intensitätsverhältnis (r) I _{h+k+l=ungerade}/I _h+k+l=gerade und der atomaren Verschiebung der Atome von der mit der RaumgruppeI 4/m konsistenten Spiegelebene, und 2 die lineare Beziehung zwischenr und dem Unterschied in der Al-Besetzung der Positionen T 6; 7 und T (2).

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With 5 Figures     

A comparison of seismic and structural measurements of scaling exponents during tensile subcritical crack growth

The observed fractal nature of both fault length distributions and earthquake magnitude-frequency distributions suggests that there may be a relationship between the structure of active fault systems and the resulting seismicity. In previous theoretical work, a positive correlation between the exponent D from the fracture length distribution, and the seismic or acoustic emission (AE) b-value has been inferred from a simple dislocation model of the seismic source. Here, we present the first experimental evidence for a correlation between D and b from a series of tensile fracture mechanics tests on crystalline rock, carried out in different environmental conditions, both air-dry and water-saturated, and at ambient temperature and pressure. The microseismic acoustic emissions were monitored during subcritical crack growth under controlled conditions of constant stress intensity, K_I, and quantitative analyses of the resulting fracture patterns were carried out on the same specimens. It is found that AE b-values, ranging from 1.0 to 2.3, correlate negatively with the normalized stress intensity K_I/KIC, where K_IC is the fracture toughness of the specimen. The microcrack length distribution exponent D, ranges from 1.0 to 1.7. Fluid presence has a first-order influence on both the AE and structure produced in these experiments. For experiments at low stress intensity or high fluid content, the activation of the stress corrosion mechanism for K_I < K_IC leads to a greater relative proportion both of small cracks and of low amplitude acoustic emissions, reflected in higher values of D and b. The exponent D is found to correlate positively with the AE b-value.     

Hydration properties of bentonites from Cabo de Gata (SE, Spain). Isotopic study (O/O; H/H) of the hydration water

The aim of this study is to determine the isotopic composition (δ¹⁸O and δ²H) of interstitial water in bentonites. The study had been carried out from adsorbed vapour in homoionic bentonites. We have worked with the fraction <20 μm of a bentonite from Serrata de Níjar (Almería, Spain). Homoionic sodium and calcium bentonites were prepared as well as variable quantities of exchangeable Na/Ca (75Ca/25Na; 50Ca/50Na; 25Ca/75Na), by mixing pure sodium and calcium suspensions in the appropriate quantities. To carry out the hydration of the samples, every one of them was previously dried at 300 °C overnight, they were subjected to controlled saturation conditions in an atmosphere of different relative humidity and at a constant temperature of 20 °C, until equilibrium was achieved. The different vapour pressures were: P/P_o = 0.05; P/P_o = 0.078; P/P_o = 0.15; P/P_o = 0.32; P/P_o = 0.45; P/P_o = 0.63; P/P_o = 0.8; P/P_o = 1, obtained from the saturated solutions of different salts or sulphuric acid.The saturation water was extracted for isotopic analysis from an aliquot of a saturated sample. The technique used was vacuum extraction based on a modification of the one described by Araguás-Araguás et al. (1995).The differentiation between the isotopes of ¹⁸O and ²H from interstitial water in the bentonite samples, depending on the different relative humidity, may affect the ions diffusion in the interstitial solutions, since in those from low relative humidities, there could be a higher diffusion velocity as they are formed by molecules of light isotopes, versus interstitial solutions from higher relative humidities or those near saturation. This fact should be taken into account in studies on cation and solute transport from these solutions inside bentonite, even though it is important to continue studying and corroborating it with a larger number of solutions isotopically marked.