Lunar surface agglutinates: Mapping composition anomalies

From the Clementine UVVIS imagery of the lunar surface, the abundance of agglutinates in the lunar regolith and their composition in terms of FeO and Al₂O₃ oxides have been predicted. Data on the spectral, chemical, and mineralogic measurements of about 30 lunar soil samples from the Lunar Samples Characterization Consortium (LSCC) collection were used. The fulfilled prognosis confirms that the mare agglutinates are enriched in Al₂O₃ and depleted of FeO, while the highland agglutinates are depleted of Al₂O₃ and enriched in FeO. This behavior can be caused by the global transport of the lunar surface material induced by cosmogenic factors.     

Lunar meteorite Queen Alexandra Range 93069 and the iron concentration of the lunar highlands surface

Abstract— Lunar meteorite Queen Alexandra Range 93069 is a clast-rich, glassy-matrix regolith breccia of ferroan, highly aluminous bulk composition. It is similar in composition to other feldspathic lunar meteorites but differs in having higher concentrations of siderophile elements and incompatible trace elements. Based on electron microprobe analyses of the fusion crust, glassy matrix, and clasts, and instrumental neutron activation analysis of breccia fragments, QUE 93069 is dominated by nonmare components of ferroan, noriticanorthosite bulk composition. Thin section QUE 93069,31 also contains a large, impact-melted, partially devitrified clast of magnesian, anorthositic-norite composition. The enrichment in Fe, Sc, and Cr and lower Mg/Fe ratio of lunar meteorites Yamato 791197 and Yamato 82192/3 compared to other feldspathic lunar meteorites can be attributed to a small proportion (5–10%) of low-Ti mare basalt. It is likely that the nonmare components of Yamato 82192/3 are similar to and occur in similar abundance to those of Yamato 86032, with which it is paired. There is a significant difference between the average FeO concentration of the lunar highlands surface as inferred from the feldspathic lunar meteorites (mean: ～5.0%; range: 4.3–6.1%) and a recent estimate based on data from the Clementine mission (3.6%).     

Searching for high alumina mare basalts using Clementine UVVIS and Lunar Prospector GRS data: Mare Fecunditatis and Mare Imbrium

In the context of sample evidence alone, the high-alumina (HA) basalts appear to be an unique, and rare variety of mare basalt. In addition to their distinct chemistry, radiometric dating reveals these basalts to be among the oldest sampled mare basalts. Yet, HA basalts were sampled by four missions spanning a lateral range of ∼2400 km, with ages demonstrating that aluminous volcanism lasted at least 1 billion years. This evidence suggests that HA basalts may be a widespread phenomenon on the Moon. Knowing the distribution of HA mare basalts on the lunar surface has significance for models of the origin and the evolution of the Lunar Magma Ocean. Surface exposures of HA basalts can be detected with compositional remote sensing data from Lunar Prospector Gamma Ray Spectrometer and Clementine. We searched the lunar surface for regions of interest (ROIs) that correspond to the intersection of three compositional constraints taken from values of sampled HA basalts: 12-18 wt% FeO, 1.5-5 wt% TiO₂, and 0-4 ppm Th. We then determined the “true” (unobscured by regolith) composition of basalt units by analyzing the rims and proximal ejecta of small impacts (0.4-4 km in diameter) into the mare surface of these ROIs. This paper focuses on two ROIs that are the best candidates for sources of sampled HA basalts: Mare Fecunditatis, the landing site of Luna 16; and northern Mare Imbrium, hypothesized origin of the Apollo 14 HA basalts. We demonstrate our technique's ability for delineating discrete basalt units and determining which is the best compositional match to the HA basalts sampled by each mission. We identified two units in Mare Fecunditatis that spectrally resemble HA basalts, although only one unit (Iltm) is consistent with the compositional and relative age of the Luna 16 HA samples. Northern Mare Imbrium also reveals two units that are within the compositional constraints of HA basalts, with one (Iltm) best matching the composition of the basalts sampled by Apollo 14.     

The petrology,geochemistry, and age of lunar regolith breccias Miller Range 090036 and 090070: Insights into the crustal history of the Moon

Meteorites ejected from the surface of the Moon as a result of impact events are an important source of lunar material in addition to Apollo and Luna samples. Here, we report bulk element composition, mineral chemistry, age, and petrography of Miller Range (MIL) 090036 and 090070 lunar meteorites. MIL 090036 and 090070 are both anorthositic regolith breccias consisting of mineral fragments and lithic clasts in a glassy matrix. They are not paired and represent sampling of two distinct regions of the lunar crust that have protoliths similar to ferroan anorthosites. ⁴⁰Ar‐³⁹Ar chronology performed on two subsplits of MIL 090070,33 (a pale clast impact melt and a dark glassy melt component) shows that the sample underwent two main degassing events, one at ~3.88 Ga and another at ~3.65 Ga. The cosmic ray exposure data obtained from MIL 090070 are consistent with a short (~8–9 Ma) exposure close to the lunar surface. Bulk‐rock FeO, TiO₂, and Th concentrations in both samples were compared with 2‐degree Lunar Prospector Gamma Ray Spectrometer (LP‐GRS) data sets to determine areas of the lunar surface where the regolith matches the abundances observed on the sample. We find that MIL 090036 bulk rock is compositionally most similar to regolith surrounding the Procellarum KREEP Terrane, whereas MIL 090070 best matches regolith in the feldspathic highlands terrane on the lunar farside. Our results suggest that some areas of the lunar farside crust are composed of ferroan anorthosite, and that the samples shed light on the evolution and impact bombardment history of the ancient lunar highlands.     

Lunar Clinopyroxene and Plagioclase: Surface Distribution and Composition

The Clementine UVVIS images and the spectral and chemical (mineral) characteristics of lunar soil samples previously measured by the Lunar Samples Characterization Consortium were used to map the plagioclase and clinopyroxene abundance in the lunar surface material. An excess of plagioclase was found in young highland craters (e.g., in the crater Tycho) and in their ray systems. For clinopyroxenes, analogous behavior was observed in mare craters (e.g., in the crater Aristarchus). The maps for the FeO and Al₂O₃ bulk contents and the contents of these oxides in plagioclase and clinopyroxene were estimated by the same technique. These maps were compared to each other and to the predicted distribution of the lunar regolith maturity. The regolith of highland ray systems (e.g., the Tycho crater system) is characterized not only by low maturity but also by peculiar iron and aluminum contents: the lower the soil maturity degree, the smaller the iron content and the greater the aluminum content. This is confirmed by the data for the lunar soil samples from the Apollo 16 landing site. A cluster analysis of the “clinopyroxene content-maturity” and “plagioclase content-maturity” correlation diagrams allowed the mineral mapping of the lunar surface to be performed.__________Translated from Astronomicheskii Vestnik, Vol. 39, No. 4, 2005, pp. 291–303.Original Russian Text Copyright © 2005 by Shkuratov, Kaydash, Pieters.     

X-ray digital imaging petrography of lunar mare soils: modal analyses of minerals and glasses

It is essential that accurate modal (i.e., volume) percentages of the various mineral and glass phases in lunar soils be used for addressing and resolving the effects of space weathering upon reflectance spectra, as well as for their calibration such data are also required for evaluating the resource potential of lunar minerals for use at a lunar base. However, these data are largely lacking. Particle-counting information for lunar soils, originally obtained to study formational processes, does not provide these necessary data, including the percentages of minerals locked in multi-phase lithic fragments and fused-soil particles, such as agglutinates. We have developed a technique for modal analyses, sensu stricto, of lunar soils, using digital imaging of X-ray maps obtained with an energy-dispersive spectrometer mounted on an electron microprobe. A suite of nine soils (90 to 150 micrometers size fraction) from the Apollo 11, 12, 15, and 17 mare sites was used for this study. This is the first collection of such modal data on soils from all Apollo mare sites. The abundances of free-mineral fragments in the mare soils are greater for immature and submature soils than for mature soils, largely because of the formation of agglutinitic glass as maturity progresses. In considerations of resource utilization at a lunar base, the best lunar soils to use for mineral beneficiation (i.e., most free-mineral fragments) have maturities near the immature/submature boundary (Is/FeO approximately or = 30), not the mature soils with their complications due to extensive agglutination. The particle data obtained from the nine mare soils confirm the generalizations for lunar soils predicted by L.A. Taylor and D.S. McKay (1992, Lunar Planet Sci. Conf. 23rd, pp. 1411-1412 [Abstract]).     

The relationship between lunar hot spots and the geomorphic index

The previously developed geomorphic index of lunar surfaces is applied to the surface distribution of the lunar hot spots. It was found that the hot spot number density is the highest in areas of intermediate geomorphic index, corresponding to mature maria. Young and old maria and the terrae have fewer hot spots per unit area. An hypothesis is presented relating the probability of formation of a hot spot by impact with the evolutionary stage of the regolith of the target surface. The older is the surface, the deeper is the regolith and also the smaller is the average boulder size. For these reasons hot spots will be less probable. The paucity of hot spots in young maria could also be related with the evolution of the regolith, but fundamental changes in the petro-physics of the mare effusions cannot be ruled out.This paper constitutes contribution no. 04 of the Lunar Science Institute and was performed under NASA Contract No. NSR 09-051-001.     

Constraining the source regions of lunar meteorites using orbital geochemical data

Lunar meteorites provide important new samples of the Moon remote from regions visited by the Apollo and Luna sample return missions. Petrologic and geochemical analysis of these meteorites, combined with orbital remote sensing measurements, have enabled additional discoveries about the composition and age of the lunar surface on a global scale. However, the interpretation of these samples is limited by the fact that we do not know the source region of any individual lunar meteorite. Here, we investigate the link between meteorite and source region on the Moon using the Lunar Prospector gamma ray spectrometer remote sensing data set for the elements Fe, Ti, and Th. The approach has been validated using Apollo and Luna bulk regolith samples, and we have applied it to 48 meteorites excluding paired stones. Our approach is able broadly to differentiate the best compositional matches as potential regions of origin for the various classes of lunar meteorites. Basaltic and intermediate Fe regolith breccia meteorites are found to have the best constrained potential launch sites, with some impact breccias and pristine mare basalts also having reasonably well‐defined potential source regions. Launch areas for highland feldspathic meteorites are much less well constrained and the addition of another element, such as Mg, will probably be required to identify potential source regions for these.     

Data processing and initial results of Chang'e-3 lunar penetrating radar

To improve our understanding of the formation and evolution of the Moon,one of the payloads onboard the Chang'e-3(CE-3) rover is Lunar Penetrating Radar(LPR). This investigation is the first attempt to explore the lunar subsurface structure by using ground penetrating radar with high resolution. We have probed the subsurface to a depth of several hundred meters using LPR. In-orbit testing, data processing and the preliminary results are presented. These observations have revealed the configuration of regolith where the thickness of regolith varies from about 4 m to 6 m.In addition, one layer of lunar rock, which is about 330 m deep and might have been accumulated during the depositional hiatus of mare basalts, was detected.     

Regolith thickness over the lunar nearside: Results from Earth-based 70-cm Arecibo radar observations

The inversion of regolith thickness over the nearside hemisphere of the Moon from newly acquired Earth-based 70-cm Arecibo radar data is investigated using a quantitative radar scattering model. The radar scattering model takes into account scattering from both the lunar surface and buried rocks in the lunar regolith, and three parameters are critically important in predicting the radar backscattering coefficient: the dielectric constant of the lunar regolith, the surface roughness, and the size and abundance of subsurface rocks. The measured dielectric properties of the Apollo regolith samples at 450 MHz are re-analyzed, and an improved relation among the complex dielectric constant, bulk density and regolith composition is obtained. The complex dielectric constant of the lunar regolith is estimated globally from this relation using the regolith composition derived from Lunar Prospector gamma-ray spectrometer data. To constrain the lunar surface roughness and abundance of subsurface rocks from radar data, nine regions are selected as calibration sites where the regolith thickness has been estimated using independent analysis techniques. For these sites, scattering from the lunar surface and buried rocks cannot be perfectly distinguished, and a tradeoff relationship exists between the size and abundance of buried rocks and surface roughness. Using these tradeoff relations as guidelines for globally representative parameters, the regolith thickness of four regions over the lunar nearside is inverted, and the inversion uncertainties caused by calibration errors of the radar data and model input parameters are analyzed. The regolith thickness of the maria is generally smaller than that of highlands, and older surfaces have thicker regolith thicknesses. Our approach cannot be applied to regions where the surface roughness is very high, such as with young rocky craters and regions in the highly rugged highlands.     

Global survey of lunar regolith depths from LROC images

We performed the first global survey of lunar regolith depths using Lunar Reconnaissance Orbiter Camera (LROC) data and the crater morphology method for determining regolith depth. We find that on both the lunar farside and in the nearside, non-mare regions, the regolith depth is twice as deep as it is within the lunar maria. Our data compare favorably with previous studies where such data exist. We also find that regolith depth correlates well with density of large craters (>20 km diameter). This result is consistent with the gradual formation of regolith by rock fracture during impact events.     

The spatial and temporal distribution of lunar mare basalts as deduced from analysis of data for lunar meteorites

In this work we analyze data for lunar meteorites with emphasis on the spatial and temporal distribution of lunar mare basalts. The data are mostly from the Lunar Meteorite Compendium (http://www-curator.jsc.nasa.gov/antmet/lmc/contents.cfm cited hereafter as Compendium) compiled by Kevin Righter, NASA Johnson Space Center, and from the associated literature. Analysis of the data showed that (i) a significant part of the lunar meteorite source craters are not larger than hundreds of meters in diameter; (ii) cryptomaria seem to be rather abundant in lunar highlands; (iii) the ratios of lunar meteorites belonging to three broad petrologic groups (mare basalt/gabbro, feldspatic highland breccias, and mingled breccias which are a mixture of mare and highland components) seem to be roughly proportional to the areal distribution of these rocks on the lunar surface; and (iv) the meteorite mare basalt ages show a range from ～2.5 to 4.3 Ga and fill the gaps in the Apollo/Luna basalt age distribution. The ages of mare basalt clasts from mingled breccias seem to be systematically higher than those of “normal” mare basalts, which supports the suggestion that mingled breccias originated mostly from cryptomaria.     

Lunar meteorite Queen Alexandra Range 93069: A lunar highland regolith breccia with very low abundances of mafic components

Abstract— Lunar meteorite QUE 93069 found in Antarctica is a mature, anorthitic regolith breccia with highland affinities that was ejected from the Moon <0.3 Ma ago. The frequency distribution of mineral and lithic clasts gives information about the nature of the regolith and subregolith basement near the ejection site as well as about the abundances of rock types shocked to different degrees prior to the breccia formation. Thin section QUE 93069,37 consists of 67.5 vol% fine-grained (<～130 μm) constituents and 32.5 vol% mineral and lithic clasts and an impact melt vein. The most abundant types of these clasts are intragranularly recrystallized anorthosites and plagioclases (together 26.3 vol%) and feldspathic fine-grained to microporphyritic crystalline melt breccias (21.9 vol%). Mafic crystalline melt breccias are extremely rare (1.3 vol%). Granulitic lithologies are 10.4 vol%, recrystallized feldspathic melt breccias are 15.0 vol%, and glasses are 3.5 vol%. The impact melt vein cutting across the entire thin section was probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Lunar meteorite QUE 93069 has a higher abundance of clear glass, occurring within melt spherules, glassy fragments, and an impact melt vein than lunar meteorites ALHA81005, Y-791197, Y-82192/3, Y-86032, or MAC 88104/5. The high abundance of melt spherules indicates that this lunar meteorite contains the highest content of typical regolith components. Mafic crystalline melt breccias are much rarer in QUE 93069 than in all other lunar highland regolith breccias. The extremely low abundance of mafic components may constrain possible areas of the Moon, from which the breccia was derived. The source area of QUE 93069 must be a highland terrain lacking significant mafic impact melts or mare components.     

The regolith portion of the lunar meteorite Sayh al Uhaymir 169

Abstract— –Sayh al Uhaymir (SaU) 169 is a composite lunar meteorite from Oman that consists of polymict regolith breccia (8.44 ppm Th), adhering to impact‐melt breccia (IMB; 32.7 ppm Th). In this contribution we consider the regolith breccia portion of SaU 169, and demonstrate that it is composed of two generations representing two formation stages, labeled II and III. The regolith breccia also contains the following clasts: Ti‐poor to Ti‐rich basalts, gabbros to granulites, and incorporated regolith breccias. The average SaU 169 regolith breccia bulk composition lies within the range of Apollo 12 and 14 soil and regolith breccias, with the closest correspondence being with that of Apollo 14, but Sc contents indicate a higher portion of mare basalts. This is supported by relations between Sm‐Al₂O₃, FeO‐Cr₂O₃‐TiO₂, Sm/Eu and Th‐K₂O. The composition can best be modeled as a mixture of high‐K KREEP, mare basalt and norite/troctolite, consistent with the rareness of anorthositic rocks. The largest KREEP breccia clast in the regolith is identical in its chemical composition and total REE content to the incompatible trace‐element (ITE)‐ rich high‐K KREEP rocks of the Apollo 14 landing site, pointing to a similar source. In contrast to Apollo 14 soil, SaU 169 IMB and SaU 169 KREEP breccia clast, the SaU 169 regolith is not depleted in K/Th, indicating a low contribution of high‐Th IMB such as the SaU 169 main lithology in the regolith. The data presented here indicate the SaU 169 regolith breccia is from the lunar front side, and has a strong Procellarum KREEP Terrane signature.     

Statistical Analysis of the Links among Lunar Mare Soil Mineralogy, Chemistry, and Reflectance Spectra

A principal goal of the Lunar Soil Characterization Consortium (LSCC) is to evaluate tools that might be successfully used in remote compositional analysis of the lunar surface. Mathematical methods are extremely valuable to assess whether variations exist in a statistically significant manner, independent of their interpretation. The bounds of widely used correlation of visible to near-infrared spectral parameters with composition are first defined and evaluated. We then evaluate direct (or indirect) links between the combined spectral properties of lunar mare soils and their compositional properties (elemental abundance and mineralogy) through a statistical analysis of the variance across each measurement using principal component analysis (PCA). We first separately analyze LSCC elemental abundance, mineralogy, and spectroscopy data (0.35 to 2.5 μm) using PCA to capture the variance of each system with a relatively small number of independent variables. With this compact set of independent variables for each type of data, we derive functions to link composition and spectroscopy. For these mare soils, one of the best empirical predictive capability is that for FeO. This is not surprising since the effect of ferrous iron on optical properties is well documented. Although Al₂O₃ has no direct effect on optical properties, its strong anticorrelation with FeO also produces a relatively high predictive capability from spectra. Similarly, a high accuracy in predicting the abundance of pyroxene is observed and should be expected since iron-bearing pyroxene is one of the most optically active components of lunar soil. The accuracy for predicting either TiO₂ or ilmenite, on the other hand, is disappointing. High- and low-Ti soils are readily distinguished, but these statistics suggest that making subclass distinctions based on spectral predictions of TiO₂ would be risky.     

Photometric properties of lunar terrains derived from Hapke's equation

The photometric parameters of B. W. Hapke's (1986, Icarus 67, 264–280) equation are fit to the lunar disk-integrated visual lightcurve and to disk-resolved data of R. W. Shorthill, J. M. Saari, F. E. Baird, and J. R. LeCompte (1969, Photometric Properties of Selected Lunar Features, NASA Contractor Report CR-1429) for dark, average, and bright lunar terrains. The lunar nearside geometric albedo and phase integral computed from the disk-integrated results are consistent with those of earlier investigators. The single scattering albedos of disk-resolved average and bright lunar terrains are systematically larger than that of lunar mare. Average particles in dark terrain regoliths are more backscattering than those in average and bright lunar terrains. The angular width of the opposition surge is greatest in dark terrains and is found to be best explained by modest differences in regolith particle-size distributions which might accompany the normal regolith maturation process. The total amplitude of the opposition surge for dark terrains is larger than for average and bright terrains. This result appears to be a consequence of the fact that in opaque particles, a larger fraction of singly scattered light at zero phase comes from first-surface reflection. The average subcentimeter macroscopic roughness of dark terrains is significantly lower than that of average and bright terrains. The relative magnitude of this difference is consistent with that obtained from radar measurements at decimeter scales.     

On the depth of the lunar regolith

The aim of this paper is to point out that if the sinuous rilles on the Moon represent trenches in the mare ground in which they meander, the existence of a great number of individual boulders on their slopes - as discovered on the high-resolution photographs taken by US Lunar Orbiters 4 and 5 in 1967 - suggests that the solid substrate of the lunar globe is covered by broken-up debris produced by cosmic abrasion - and hereafter referred to as lunar regolith - of thickness comparable with the depth of the respective rilles - at least of those lacking flat floors; which is generally in the order of 200–300 m. This depth is much greater than that indicated previously by other methods possessing more limited depth in range; and need not apply uniformly all over the Moon. In point of fact, marial regions abounding in sinuous rilles may represent loci where the lunar regolith has developed its maximum depth.     

The thermal and radiation exposure history of lunar meteorites

Abstract— We have measured the natural and induced thermoluminescence (TL) of seven lunar meteorites in order to examine their crystallization, irradiation, and recent thermal histories. Lunar meteorites have induced TL properties similar to Apollo samples of the same provenance (highland or mare), indicating similar crystallization and metamorphic histories. MacAlpine Hills 88104/5 has experienced the greatest degree of impact/regolith processing among the highland-dominated meteorites. The basaltic breccia QUE 94281 is dominated by mare component but may also contain a significant highland component. For the mare-dominated meteorites, EET 87521 may have a significant highland impact-melt component, while Asuka 881757 and Y-793169 have been heavily shocked. The thermal history of Y-793169 included slow cooling, either during impact processing or during its initial crystallization. Our natural TL data indicate that most lunar meteorites have apparently been irradiated in space a few thousand years, with most <15,000 a. Elephant Moraine 87521 has the lowest irradiation exposure time, being <1,000 a. Either the natural TL of ALHA81005, Asuka 881757 and Y-82192 was only partially reset by lunar ejection or these meteorites were in small perihelia orbits (≤0.7 AU).     

The early geological history of the Moon inferred from ancient lunar meteorite Miller Range 13317

Miller Range (MIL) 13317 is a heterogeneous basalt‐bearing lunar regolith breccia that provides insights into the early magmatic history of the Moon. MIL 13317 is formed from a mixture of material with clasts having an affinity to Apollo ferroan anorthosites and basaltic volcanic rocks. Noble gas data indicate that MIL 13317 was consolidated into a breccia between 2610 ± 780 Ma and 1570 ± 470 Ma where it experienced a complex near‐surface irradiation history for ~835 ± 84 Myr, at an average depth of ~30 cm. The fusion crust has an intermediate composition (Al₂O₃ 15.9 wt%; FeO 12.3 wt%) with an added incompatible trace element (Th 5.4 ppm) chemical component. Taking the fusion crust to be indicative of the bulk sample composition, this implies that MIL 13317 originated from a regolith that is associated with a mare‐highland boundary that is KREEP‐rich (i.e., K, rare earth elements, and P). A comparison of bulk chemical data from MIL 13317 with remote sensing data from the Lunar Prospector orbiter suggests that MIL 13317 likely originated from the northwest region of Oceanus Procellarum, east of Mare Nubium, or at the eastern edge of Mare Frigoris. All these potential source areas are on the near side of the Moon, indicating a close association with the Procellarum KREEP Terrane. Basalt clasts in MIL 13317 are from a very low‐Ti to low‐Ti (between 0.14 and 0.32 wt%) source region. The similar mineral fractionation trends of the different basalt clasts in the sample suggest they are comagmatic in origin. Zircon‐bearing phases and Ca‐phosphate grains in basalt clasts and matrix grains yield ²⁰⁷Pb/²⁰⁶Pb ages between 4344 ± 4 and 4333 ± 5 Ma. These ancient ²⁰⁷Pb/²⁰⁶Pb ages indicate that the meteorite has sampled a range of Pre‐Nectarian volcanic rocks that are poorly represented in the Apollo, Luna, and lunar meteorite collections. As such, MIL 13317 adds to the growing evidence that basaltic volcanic activity on the Moon started as early as ~4340 Ma, before the main period of lunar mare basalt volcanism at ~3850 Ma.     

Lunar Penetrating Radar onboard the Chang'e-3 mission

Lunar Penetrating Radar(LPR) is one of the important scientific instruments onboard the Chang'e-3 spacecraft. Its scientific goals are the mapping of lunar regolith and detection of subsurface geologic structures. This paper describes the goals of the mission, as well as the basic principles, design, composition and achievements of the LPR. Finally, experiments on a glacier and the lunar surface are analyzed.