A Climatology of the Southwest Vortex during 1979–2008

Using a new vortex detection and tracing method, a dataset of the Southwest Vortex（SWV） is established based on Japanese 25-year Reanalysis（JRA-25） reanalysis data during 1979–2008. The spatiotemporal features of the SWV are derived from the dataset. In comparison to other seasons, summer yields the least SWVs, but with the highest probability that they will migrate from their region of origin. SWVs mostly emerge in the southwest of the Sichuan Basin and the southeast of the Tibetan Plateau. Migratory SWVs mainly move along either an eastward or southeastward path. Detailed composite analysis of warm-season SWVs shows that the subtropical high is a key factor in determining the direction of migratory SWVs. Furthermore, the steering wind at 700 hPa dominates the moving direction of migratory SWVs. Potential stability diagnosed by pseudo-equivalent potential temperature ？ se is of certain significance for the evolution and movement of SWVs. On the other hand, migratory SWVs possess relatively greater strength than stationary SWVs, due to a stronger low-level jet with enhanced baroclinicity and moisture transport providing more energy to support the growth of SWVs along their paths of movement.     

Nondimensionalization of the Atmospheric Boundary-Layer System: Obukhov Length and Monin–Obukhov Similarity Theory

Boundary-Layer Meteorology - The Obukhov length, although often adopted as a characteristic scale of the atmospheric boundary layer, has been introduced purely based on a dimensional argument...     

Monin–Obukhov Similarity Functions of the Structure Parameter of Temperature and Turbulent Kinetic Energy Dissipation Rate in the Stable Boundary Layer

The Monin–Obukhov similarity theory (MOST) functions f_ε and f_T, of the dissipation rate of turbulent kinetic energy (TKE). ε, and the structure parameter of temperature, C_T², were determined for the stable atmospheric surface layer using data gathered in the context of CASES-99. These data cover a relatively wide stability range, i.e. ζ=z/L of up to 10, where z is the height and L the Obukhov length. The best fits were given by f_ε = 0.8 + 2.5ζ and f_T= 4.7[ 1+1.6(ζ)^2/3], which differ somewhat from previously published functions. ε was obtained from spectra of the longitudinal wind velocity using a time series model (ARMA) method instead of the traditional Fourier transform. The neutral limit f_ε =0.8 implies that there is an imbalance between TKE production and dissipation in the simplified TKE budget equation. Similarly, we found a production-dissipation imbalance for the temperature fluctuation budget equation. Correcting for the production-dissipation imbalance, the ‘standard’ MOST functions for dimensionless wind speed and temperature gradients (φ_m and φ_m) were determined from f_ε and f_T and compared with the φ_m and φ_h formulations of Businger and others. We found good agreement with the Beljaars and Holtslag [J. Appl. Meteorol. 30, 327–341 (1991)] relations. Lastly, the flux and gradient Richardson numbers are discussed also in terms of f_ε and f_T.     

A Cautionary Note on the Use of Monin–Obukhov Similarity Theory in Very High-Resolution Large-Eddy Simulations

In several recent large-eddy simulation studies, the lowest grid level was located well within the roughness sublayer. Monin–Obukhov similarity-based boundary conditions cannot be used under this scenario, and in this note we elaborate on this fundamental problem and suggest potential solutions.     

Air–Sea Interaction in the Southern Ocean: Exploring the Height of the Wave Boundary Layer at the Air–Sea Interface

We investigate the momentum and energy exchange across the wave boundary layer (WBL). Directly at the air–sea interface, we test three wave-growth parametrizations by comparing estimates of the wave-induced momentum flux derived from wave spectra with direct covariance estimates of the momentum flux. An exponential decay is used to describe the vertical structure of the wave-induced momentum in the atmospheric WBL through use of a decay rate, a function of the dimensionless decay rate and wavenumber (A?=?α k). The decay rate is varied to minimize the difference between the energy extracted from the WBL and the energy flux computed from wave spectra using our preferred wave-growth parametrization. For wave ages (i.e. the peak phase speed to atmospheric friction velocity ratio) in the range \( 15 < c_{p}/u_{*} < 35 \) we are able to balance these two estimates to within 10%. The decay rate is used to approximate the WBL height as the height to which the wave-induced flux is 0.1 of its surface value and the WBL height determined this way is found to be between 1–3 m. Finally, we define an effective phase speed with which to parametrize the energy flux for comparison with earlier work, which we ultimately attempt to parametrize as a function of wind forcing.     

On Monin–Obukhov Scaling in and Above the Atmospheric Surface Layer: The Complexities of Elevated Scintillometer Measurements

In scintillometry Monin–Obukhov similarity theory (MOST) is used to calculate the surface sensible heat flux from the structure parameter of temperature (C_T²){(C_{T^2})} . In order to prevent saturation a scintillometer can be installed at an elevated level. However, in that case the observation level might be located outside the atmospheric surface layer (ASL) and thus the validity of MOST questioned. Therefore, we examine two concepts to determine the turbulent surface sensible heat flux from the structure parameter at elevated levels with data obtained at 60-m height on the Cabauw tower (the Netherlands). In the first concept (MOSTs) C_T²{C_{T^2}} is still scaled with the surface flux, whereas in the second (MOSTl) C_T²{C_{T^2}} is scaled with the local sensible heat flux. The C_T²{C_{T^2}} obtained from both concepts is compared with direct observations of C_T²{C_{T^2}} using a sonic anemometer/thermometer. In the afternoon (when the measurement height is located within the ASL) both concepts give results that are comparable to the directly observed values of C_T²{C_{T^2}} . In the morning (data outside the ASL), our data do not unequivocally support either of the two concepts. First, the peak in C_T²{C_{T^2}} that occurs when the measurement height is located in the entrainment zone disqualifies the use of MOST. Second, during the morning transition, local scaling shows the correct pattern (zero flux and a minimum in C_T²{C_{T^2}}) but underestimates C_T²{C_{T^2}} by a factor of ten. Third, from the best linear fit a we found that the slope of MOSTl gave better results, whereas the offset is closer to zero for MOSTs. Further, the correlation between the direct observations and MOST-scaled results is low and similar for the two concepts. In the end, we conclude that MOST is not applicable for the morning hours when the observation level is above the ASL.     

A Lagrangian Model to Predict the Modification of Near-Surface Scalar Mixing Ratios and Air–Water Exchange Fluxes in Offshore Flow

A model was developed to predict the modification with fetch in offshore flow of mixing ratio, air–water exchange flux, and near-surface vertical gradients in mixing ratio of a scalar due to air–water exchange. The model was developed for planning and interpretation of air–water exchange flux measurements in the coastal zone. The Lagrangian model applies a mass balance over the internal boundary layer (IBL) using the integral depth scale approach, previously applied to development of the nocturnal boundary layer overland. Surface fluxes and vertical profiles in the surface layer were calculated using the NOAA COARE bulk algorithm and gas transfer model (e.g., Blomquist et al. 2006, Geophys Res Lett 33:1–4). IBL height was assumed proportional to the square root of fetch, and estimates of the IBL growth rate coefficient, α, were obtained by three methods: (1) calibration of the model to a large dataset of air temperature and humidity modification over Lake Ontario in 1973, (2) atmospheric soundings from the 2004 New England Air Quality Study and (3) solution of a simplified diffusion equation and an estimate of eddy diffusivity from Monin–Obukhov similarity theory (MOST). Reasonable agreement was obtained between the calibrated and MOST values of α for stable, neutral, and unstable conditions, and estimates of α agreed with previously published parametrizations that were valid for the stable IBL only. The parametrization of α provides estimates of IBL height, and the model estimates modification of scalar mixing ratio, fluxes, and near-surface gradients, under conditions of coastal offshore flow (0–50 km) over a wide range in stability.     

A science–policy interface in the global south: the politics of carbon sinks and science in Brazil

The IPCC and other global environmental assessment processes stress the need for national scientific participation to ensure decision makers’ trust in the associated scientific conclusions and political agendas. The underpinning assumption is that the relationship between scientists and decision makers at the national level is characterized by trust and interpretive synergy. Drawing on ethnographic research in Brazil, this article challenges that assumption through a case study of the policy uptake of divergent scientific interpretations as to whether or not the Amazon is a net carbon sink. It shows that the carbon sink issue became a site for struggles between important Brazilian scientists and decision-makers with central authority over the definition of the country’s official position in international climate negotiations. In a geopolitically charged scientific controversy involving scientific evidence bearing on the Kyoto Protocol, Brazilian decision makers studied revealed critical distance from national scientists advancing evidence that the Amazon is a net carbon sink. As such, the decision-makers’ interpretations were at odds also with dominant framings in the Brazilian media and closer to those of American scientists involved in carbon cycle research in the Amazon. Seeking to explain this disconnect, the paper discusses the divergent policy preferences of key scientists and decision-makers involved, and the correlations of these preferences with interpretations of the available scientific evidence. It identifies the continued impact of a national political tradition of limited participation in decision making and suggests that this tradition—while increasingly challenged by countervailing democratizing trends—is reinforced by key Brazilian decision makers’ constructions of science as a medium through which rich countries maintain political advantage. Reflecting this, key Brazilian decision-makers justified rejecting national scientists’ interpretations of the Amazon as a significant overall carbon sink by suggesting that the scientists’ scientific training and associated foreign interactions bias them in favor of foreign interests, compromising their ability to accurately identify national interests. The paper situates its analysis in terms of theories of the science–policy interface and argues for greater attention to the role of culturally and politically laden understandings of science and the role of science in policy and geopolitics.     

A decade of cloud‐to‐ground lightning in Canada: 1999–2008. Part 1: Flash density and occurrence

Abstract

Flash density and occurrence features for more than 23.5 million cloud‐to‐ground (CG) lightning flashes detected by the Canadian Lightning Detection Network (CLDN) from 1999 to 2008 are analyzed on 20 × 20 km equal area squares over Canada. This study was done to update an analysis performed in 2002 with just three years of data. Flashes were detected throughout the year, and distinct geographic differences in flash density and lightning occurrence were observed. The shape and locations of large scale patterns of lightning occurrence remained almost the same, although some details were different. Flash density maxima occurred at the same locations as found previously: the Swan Hills and Foothills of Alberta, southeastern Saskatchewan, southwestern Manitoba and southwestern Ontario. A region of greater lightning occurrence but relatively low flash density south of Nova Scotia occurred at the same location as reported previously. New areas of higher flash density occurred along the US border with northwestern Ontario and southern Quebec. These appear to be northward extensions of higher flash density seen in the previous study. The greatest average CG flash density was 2.8 flash km^?2 y^?1 in southwestern Ontario, where the greatest single‐year flash density (10.3 flash km^?2 y^?1) also occurred. Prominent flash density minima occurred east of the Continental Divide in Alberta and over the Niagara Escarpment in southern Ontario.

Lightning activity is seen to be highly influenced by the length of the season, proximity to cold water bodies and elevation. The diurnal heating and cooling cycle exerted the main control over lightning occurrence over most land areas; however, storm translation and transient dynamic features complicated the time pattern of lightning production. A large portion of the southern Prairie Provinces experienced more than 50% of flashes between 22:30 and 10:30 local solar time. The duration of lightning over a 20 × 20 km square at most locations in Canada is 5–10 h y^?1, although the duration exceeded 15 h y^?1 over extreme southwestern Ontario. Lightning occurred on 15–30 days each year, on average, over most of the interior of the country. The greatest number of days with lightning in a single year was 47 in the Alberta foothills and 50 in southwestern Ontario. Beginning and ending dates of the lightning season show that the season length decreases from north to south; however, there are considerable east‐west differences between regions. The season is nearly year‐round in the Pacific coastal region, southern Nova Scotia, southern Newfoundland and offshore.     

Impacts of warm and cold situations in the Mediterranean basins on the West African monsoon: observed connection patterns (1979–2006) and climate simulations

Using both empirical and numerical ensemble approaches this study focuses on the Mediterranean/West African relationship in northern summer. Statistical analyses utilize skin temperature, sea surface temperature, in situ and satellite rainfall, outgoing longwave radiation (OLR) observations and reanalyzed data winds and specific humidity on isobaric surfaces. Numerical investigations are based on a large set of sensitivity experiments performed on four atmospheric general circulation models (AGCM): ARPEGE-Climat3, ECHAM4, LMDZ4 and UCLA7.3. Model outputs are compared to observations, discussed model by model and with an ensemble (multi-model) approach. As in previous studies the anomalous Mediterranean warm events are associated with specific impacts over the African monsoon region, i.e., a more intense monsoon, enhanced flux convergence and ascendances around the ITCZ, a strengthening of low level moisture advection and a more northward location of ascending motion in West Africa. The results show also new features (1) thermal variability observed in the two Mediterranean basins has unalike impacts, i.e. the western Mediterranean covaries with convection in Gulf of Guinea, while the eastern Mediterranean can be interpreted as Sahelian thermal-forcing; (2) although observations show symmetry between warming and cooling, modelling evidences only support the eastern warming influence; (3) anomalous East warm situations are associated with a more northward migration of the monsoon system accompanied by enhanced southwertely flow and weakened northeasterly climatological wind; (4) the multi-model response shows that anomalous East warm surface temperatures generate an enhancement of the overturning circulation in low and high levels, an increase in TEJ (Tropical Eeasterly Jet) and a decrease in AEJ (African Eeasterly Jet).     

Comparison Between Large-Eddy Simulation and Reynolds-Averaged Navier–Stokes Computations for the MUST Field Experiment. Part II: Effects of Incident Wind Angle Deviation on the Mean Flow and Plume Dispersion

Large-eddy simulations (LES) and Reynolds-averaged Navier–Stokes (RANS) computations of pollutant dispersion are reported for the Mock Urban Setting Test (MUST) field experiment flow. In particular we address the effects of incident wind angle deviation on the mean velocity and on the mean concentration fields. Both computational fluid dynamical methods are assessed by comparing the simulation results with experimental field data. The comparative analysis proposes to relate the plume deflection with the flow channelling effects. The results show that the plume deflection angle varies with the altitude. As the ground is approached the plume is shown to be almost aligned with the street canyon direction and independent of the incident wind directions considered. At higher altitudes well above the obstacles, the plume direction is aligned with the mean wind direction as in dispersion over flat terrain. The near-ground plume deflection is the consequence of a strong channelling effect in the region near the ground. The mean concentration profiles predicted by LES and RANS are both in good qualitative agreement with experimental data but exhibit discrepancies that can be partly explained by the influence of small incident wind angle deviation effects. Compared to RANS, LES predicts a higher channelling and thus a higher deflection of the plume. Results on the fluctuating intensity of the concentration obtained from LES show a satisfactory agreement with experiments. This information is not available from RANS for which only the mean concentration modelling is considered.     

Comparison Between Large-Eddy Simulation and Reynolds-Averaged Navier–Stokes Computations for the MUST Field Experiment. Part I: Study of the Flow for an Incident Wind Directed Perpendicularly to the Front Array of Containers

The large-eddy simulation (LES) and Reynolds-averaged Navier–Stokes (RANS) methodologies are used to simulate the air flow inside the container’s array geometry of the Mock Urban Setting Test (MUST) field experiment. Both tools are assessed and compared in a configuration for which the incident wind direction is perpendicular to the front array. The assessment is carried out against available wind-tunnel data. Effects of including small geometrical irregularities present in the experiments are analysed by considering LES and RANS calculations on two geometries: an idealized one with a perfect alignment and an identical shape of the containers, and a second one including the small irregularities considered in the experiment. These effects are assessed in terms of the local time-mean average and as well in terms of spatial average properties (relevant in atmospheric modelling) given for the velocity and turbulent fields. The structural flow properties obtained using LES and RANS are also compared. The inclusion of geometrical irregularities is found significant on the local time-mean flow properties, in particular the repeated flow patterns encountered in a perfect regular geometry is broken. LES and RANS provide close results for the local mean streamwise velocity profiles and shear-stress profiles, however the LES predictions are closer to the experimental values for the local vertical mean velocity. When considering the spatial average flow properties, the effects of geometrical irregularities are found insignificant and LES and RANS provide similar results.     

Bifurcation of nonlinear Kelvin wave-CISK with conditional heating in a truncated spectral model: A possible mechanism of 30–60-day oscillation at the equator

In this paper, the nonlinear Kelvin wave equations with “positive-only” nonlinear (conditional) heating at the equator are reduced to a sixth-order nonlinear ordinary differential equation by using the Galerkin spectral truncated method. The stability analysis indicates that when the heating parameter increases, the supercritical pitchfork and Hopf bifurcations can occur for the prescribed three heating profiles. Numerical calculations are made with the help of the fourth-order Rung-Kutta method. It is found that the convec-tion heating-related Hopf bifurcation can lead to limit cycle and chaotic solutions. In a wide range of heat-ing parameter, the solutions possess 30-60-day periods, and are dominated by wavenumbers one and two, especially by wavenurnber-one. In addition, the zonal winds of the low-frequency solutions have a phase reversal between the upper and lower tropospheres. Thus, it appears that the convection heating-related Hopf bifurcation might be a possible mechanism of 30-60-day oscillation in the tropical atmosphere.     

“A sky of brass and burning winds”: documentary evidence of rainfall variability in the Kingdom of Lesotho, Southern Africa, 1824–1900

Forecasting austral summer rainfall in southern Africa is hampered by a lack of long-term instrumental data. This paper extends the historical record for the subcontinent by presenting the first extensive 19th century climate history for Lesotho derived from documentary evidence. The data sources included unpublished English-, French- and Sesotho-language materials archived in Lesotho, South Africa and the UK. These included letters, journals and reports written by missionaries and colonial authorities, which were supplemented by newspapers, diaries, travelogues and other historical sources. Each source was read in chronological order, with any climate information recorded verbatim. Observations were classified into five categories (Very Wet, Relatively Wet, ‘Normal’, Relatively Dry, and Very Dry) based upon the predominant documented climate during each ‘rain-year’ (July to June). The latter portion of the chronology was then compared for accuracy against available instrumental precipitation records from Maseru (1886–1900). The results yield a semi-continuous record of climate information from 1824 to 1900. Data are restricted to lowland areas, but reveal drought episodes in 1833–34, 1841–42, 1845–47, 1848–51, 1858–63, 1865–69, 1876–80, 1882–85 and 1895–99 (the most severe drought years being 1850–51 and 1862–63) and wet periods or floods in 1835–36, 1838–41, 1847–48, 1854–56, 1863–65, 1873–75, 1880–81, 1885–86 and 1890–94. The rainfall chronology is compared with similar records for South Africa, Botswana and Zimbabwe. Linkages to possible forcing mechanisms, including ENSO teleconnections and historical coral-derived southwest Indian Ocean sea surface temperature variations are also explored.     

Virtual water ‘flows’ of the Nile Basin, 1998–2004: A first approximation and implications for water security

This paper interprets an initial approximation of the ‘trade’ in virtual water of Nile Basin states in terms of national water security. The virtual water content (on the basis of weight) of select recorded crop and livestock trade between 1998 and 2004 is provided, and analysed for each state separately, for the Southern Nile and Eastern Nile states as groups, and for the basin states as a whole. To the extent that the datasets allow, the distinction between rainfed and irrigated production is maintained. During the period under study, Nile Basin states ‘exported’ about 14,000 Mm³ of primarily rainfed-derived virtual water outside of the basin annually and ‘imported’ roughly 41,000 Mm³/y. The ‘imports’ are considered to have played a key role in filling the freshwater deficits of Egypt and Sudan, and represent a third of the flow of the Nile River itself. Analysis of food trade within the basin shows that the equivalent of small rivers of water used to raise coffee and tea ‘flow’ from the highlands around Lake Victoria to Egypt and Sudan. Because the bulk of these ‘flows’ derive from rainfed agriculture, the virtual water ‘traded’ annually between the Nile Basin states is not considered to represent a significant demand on the water resources of the basin, nor to significantly remedy the freshwater deficits of the arid basin states. The importance of soil water and rainfed farming is in improving water security is highlighted. The limitations and merits of the inter-state basin-wide approach are also discussed. By highlighting the magnitude of water leaving and entering states in its virtual form, the approach obliges policy-makers to think beyond the basin and reconsider the concept of water security within broader political, environmental, social and economic forces.     

An Observing System Simulation Experiment to Assess the Potential Impact of a Virtual Mobile Communication Tower–based Observation Network on Weather Forecasting Accuracy in China. Part 1: Weather Stations with a Typical Mobile Tower Height of 40 m

The importance of a national or regional network of meteorological stations for improving weather predictions has been recognized for many years. Ground-based automatic weather stations typically observe weather at a height of 2-10 m above ground level(AGL); however, these observations may have two major shortcomings. Large portions of data cannot be used if the station height is significantly lower than the model surface level; and such observations may contain large representativity errors as near-surface observations are often affected by the local environment, such as nearby buildings and tall trees. With the recent introduction of a significant number of mobile communication towers that are typically over40 m AGL in China, a campaign has been proposed to use such towers to build a future observing system with an observing height of 40 m. A series of observing system simulation experiments has been conducted to assess the potential utility of such a future observing system as part of a feasibility study. The experiments were conducted using the Weather Research and Forecasting model and its Rapid Update Cycle data assimilation system. The results revealed the possibility of improving weather forecasting by raising present weather stations to a height of 40 m; this would not only enable more observations to pass the terrain check, but should also reduce interpolation errors. Additionally, improvements for temperature, humidity and wind forecasting could be achieved as the accuracy of the initial conditions increases.     

Climate change in news media across the globe: An automated analysis of issue attention and themes in climate change coverage in 10 countries (2006–2018)

Climate change poses a challenge to countries across the world, with news media being an important source of information on the issue. To understand how and how much news media cover climate change, this study compares coverage in ten countries from the Global North and the Global South between 2006 and 2018 (N = 71,674). Based on a panel analysis, we illustrate that news media attention varies across countries and is often associated with political, scientific, and (partly) societal focusing events. Based on an automated content analysis, we also find that news media do not only cover ecological changes or climate science, but that they focus predominantly on the societal dimension of climate change: They emphasize how humans are aware of, affected by, battle, or cause climate change. Overall, the study illustrates important differences between the Global North and the Global South. While countries from the Global North cover climate change more frequently, countries from the Global South focus more on its challenges and implications for society at large, i.e., the societal dimension of climate change.     

Reply to comment by Ben-Zvi,A., D. Rosenfeld and A. Givati on the paper: Levin,Z., N. Halfon and P. Alpert, “Reassessment of rain experiments and operations in Israel including synoptic considerations,” Atmos. Res. 97, 513–525. DOI: 10.1016/j.atmosres.2010.06.011

Levin et al. (2010; hereafter LHA) (Levin, Z., Halfon, N., Alpert, P., 2010. Reassessment of rain experiments and operations in Israel including synoptic considerations. Atmos. Res. 97, 513–525. DOI:10.1016/j.atmosres.2010.06.011.), reanalyzed the results of the operational seeding in northern Israel between 1975 and 2007 and the preceding Israel 2 cloud seeding experiment (1969–1975) and concluded that there is no net increase in precipitation over the target areas. Our analysis revealed that a synoptic bias during Israel 2 is one of the reasons for the apparent positive effect of seeding in the northern target area and the negative effect in the southern area both of which disappeared in the following experiment in the south (Israel 3; 1975–1995) and the operational seeding in the north.Ben-Zvi et al. (2010;hereafter BRG) criticized our paper primarily on the ground that we did not consider the positive results of Israel 1 experiment (1960–1967). It should be noted that in Israel 1 different seeding lines were used from those in both Israel 2 and the operational period. In addition, its raw data is not accessible anymore for reanalysis. Furthermore, Israel 2 had been designed as a confirmatory cross-over experiment to Israel 1 and failed to reproduce its promising results with double ratio (DR) of ~ 1.00, namely, zero rainfall enhancements. The same DR values were also found in Israel 3 and in the operational seeding. Therefore, because of the differences in the two experiments, the lack of access to the raw data and the disappointing results of the confirmatory experiment, we decided to concentrate our analysis on the more recent seeding activities.The attempt by BRG to explain the reduction of the DR to ~ 1.00 in the operational seeding period by the suppression due to pollution have been disproved by Alpert et al., 2008, Alpert et al., 2009 and also fail to explain the sharp decline of the target/control ratio right at the beginning of the operational seeding period when the lucky draw in this area came to its end (see LHA).     

Comment on “Kinetics of the reactions of Cl atoms with 2-buten-1-ol, 2-methyl-2-propen-1-ol, and 3-methyl-2-buten-1-ol as a function of temperature” by Rodriguez et al. (J. Atmos. Chem. (2008) 59:187–197)

The Arrhenius expressions and the data plotted in Figure 2 of Rodriguez et al. 2008 give rate coefficients of approximately 2?×?10^-8 cm³ molecule^-1 s^-1 at 255 K. Such values are approximately two orders of magnitude larger than expected from simple collision theory (Finlayson-Pitts and Pitts 1986). The rate coefficients reported at sub-ambient temperatures are substantially greater than the gas kinetic limit and are not physically plausible. The rate coefficients reported by Rodriguez et al. imply a long range attraction between the reactants which is not reasonable for reaction of neutral species such as chlorine atoms and unsaturated alcohols. We also note that the pre-exponential A factors (10^-23-10^-20) and activation energies (?15 kcal mol^-1) are not physically plausible. We conclude that there are large systematic errors in the study by Rodriguez et al. (Atmos Chem 59:187–197, 2008).