海水中悬浮粒子的微电泳研究 Ⅰ针铁矿、δ-Mno_2的电泳淌度与酸度、重金属离子及有机物浓度的关系

本文用微电泳的方法研究了针铁矿及δ-MnO_2悬浮粒子的电泳行为。支持电解质的离子强度影响淌度的大小,但不改变等电点(IEP)。重金属离子在悬浮粒子上的吸附,使pH高于IEP时的表面电荷由负变正,而在pH低于IEP时影响不大。 小分子量的有机物如氨基酸对悬浮粒子的淌度影响不大,而大分子量的有机物如腐殖酸使IEP左移。天然海水,河水等对悬浮粒子表面电荷的影响是其中的有机物使IEP左移的结果,故天然水体中悬浮粒子无例外地均荷负电。     

海水中悬浮粒子的微电泳研究 Ⅰ针铁矿、δ-MnO2的电泳淌度与酸度、重金属离子及有机物浓度的关系

本文用微电泳的方法研究了针铁矿及δ—MnO2悬浮粒子的电泳行为。支持电解质的离子强度影响淌度的大小，但不改变等电点(IEP)。重金属离子在悬浮粒子上的吸附，使pH高于IEP时的表面电荷由负变正，而在pH低于IEP影响不大。小分子量的有机物如氨基酸对悬浮粒子的淌度影响不大，而大分子量的有机物如腐殖酸使IEP左移。天然海水，河水等对悬浮粒子表面电荷的影响是其中的有机物使IEP左移的结果，故天然水体中悬浮粒子无例外地均荷负电。     

黄河口泥沙颗粒表面电荷的微电泳研究

黄河是世界河流中携带泥沙颗粒最多的河流。泥沙的沉积不仅受物理因素，也受化学因素的控制，例如受表面电荷的控制。研究黄河口水中悬浮体颗粒的表面电荷，有助于探求河口区域的悬浮物沉积规律。本文测定了不同盐度下黄河口水体中悬浮粒子的电泳行为，得到如下结果：(1)所有悬浮粒子均带负电荷。(2)粒子Zeta电位的负值随盐度增大而减小。这个结果与文献报道(欧洲一些河流的)情况一致。     

黄河口泥沙颗粒表面电荷的微电泳研究

黄河是世界河流中携带泥沙颗粒最多的河流。泥沙的沉积不仅受物理因素,也受化学因素的控制,例如受表面电荷的控制。研究黄河口水中悬浮体颗粒的表面电荷,有助于探求河口区域的悬浮物沉积规律。 本文测定了不同盐度下黄河口水体中悬浮粒子的电泳行为,得到如下结果:(1)所有悬浮粒子均带负电荷。(2)粒子Zeta电位的负值随盐度增大而减小。这个结果与文献报道(欧洲一些河流的)情况一致。     

河口细颗粒泥沙的絮凝作用

本文对河口细颗粒泥沙絮凝作用的研究工作进行了综合评述．对盐度、有机物、水流切应力及悬浮颗粒的表面电荷等因素对河口细颗粒泥沙絮凝作用的影响规律及絮凝机理进行了总结和探讨．     

河口细颗粒泥沙的絮凝作用

本文对河口细颗粒沙絮凝作用的研究工作进行了综合评述。以盐度，有机物，水流切应力及悬浮颗粒的表面电荷等因素对河口细颗粒泥沙絮凝作用的影响规律及絮凝机理进行了总结和探讨。     

河口悬浮粒子Stern电位的测定方法

首次提出了一种间接测定悬浮粒子Stern电位的方法,即通过测定悬浮粒子在不同浓度NaCl(0.01～0.40mol/L)溶液中的ζ-电位,按照Gouy-Chapman理论一般公式之对数变换式,用作图法计算悬浮粒子的Stern电位.用该方法研究了黄河口悬浮粒子Stern电位的变化规律.结果表明,在淡、咸水混合初期,悬浮粒子的Stern电位迅速减小;当S>3.5时,Stern电位不再随盐度的增大而变化.由此提出,对Ca2+和Ms2+的吸附是影响河口悬浮粒子Stern电位变化的主要因素.     

胶州湾海水中悬浮颗粒对溶解态微量元素的影响

运用离子色谱离线螯合结合ICP-MS的方法,对胶州湾海水中的微量元素(V,Co,Ni,Cu,Mo,Cd,Pb,U,REEs)进行了精确的定量分析。在测试前对在同一站位不同层位采集的平行海水样品进行了两种不同的酸化处理:一份采取先过滤后酸化的方式,以获得海水中溶解态微量元素的含量;另一份采取直接酸化后分析的方式,以评估悬浮颗粒中的可交换态微量元素对溶解态微量元素测定结果可能造成的影响。通过对比研究发现,不同处理方法得到的V、Ni、Cu、Co、Pb以及稀土元素(REEs)的质量浓度存在很大差异,说明悬浮颗粒物质可能对海水中相应元素的测定产生较大的影响。各种微量元素之间的差异和相应离子或离子团的电荷性质、在海水中的配位作用以及悬浮颗粒物质的表面电荷性质有关。初步研究结果表明,在类似于胶州湾这样的近海海域,悬浮颗粒物质是控制微量元素分布特征的一个重要因素。     

河口悬浮粒子Stern电位的测定方法

首次提出了一种间接测定悬浮粒于Ｓｔｅｒｎ电位的方法,即通过测定悬浮粒子在不同浓度ＮａＣｌ（０．０１～０．４０ｍｏｌ／Ｌ）溶液中的ζ－电位,按照Ｇｏｕｙ－Ｃｈａｐｍａｎ理论一般公式之对数变换式,用作图法计算悬浮粒子的Ｓｔｅｒｎ电位。用该方法研究了黄河口悬浮粒子Ｓｔｅｒｎ电位的变化规律。结果表明,在淡、咸水混合初期,悬浮粒子的Ｓｔｅｒｎ电位迅速减小;当ｓ〉３．５时,Ｓｔｅｒｎ电位不再随盐度的增大而变化     

降低干扰和噪声对水中声反向散射信号影响的若干对策

声遥测水中悬浮粒子（如泥沙）的反向散射强度,可反演获得粒子浓度。可是,遥测系统对采样体积采集的声反向散射,除了粒子的散射信号外,还包含附加的干扰和噪声。本文探讨采集悬浮粒子声反向散射信号时,如何降低干扰源和噪声源对其影响的若干对策。     

Surface properties of beached plastic pellets

The presence of pollutants on plastic debris is an emerging environmental hot topic. Understanding the surface alteration of plastics while in the marine environment increases our understanding of the pollutant–plastic debris interaction. Plastic pellets are widely distributed throughout the world oceans. Eroded and virgin polyethylene (PE) and polypropylene (PP) pellets were studied for their surface properties to better understand the interaction between plastic and compounds in marine environment. Surface properties such as point of zero charge, surface area and pore volume, surface topography, functional groups and acid–base behavior are important factors which affect sorption. Virgin plastic pellets had homogeneous smooth surfaces that do not have any acid–base behavior. Eroded PE demonstrates an altered surface that at seawater pH acquires a negative charge due to ketone groups. The uneven surface and possible functional groups could have been formed from the erosion processes while floating at the sea surface and might explain the interaction of eroded plastics with microbes and metals.     

Surface sediment gases as indicators of subsurface hydrocarbons – examining the record in laboratory and field studies

Near-surface sediment gases are commonly examined in surface geochemistry surveys to evaluate subsurface hydrocarbon generation and entrapment. Sediment gases reside in interstitial spaces, bound to mineral or organic surfaces, and/or entrapped in carbonate inclusions. Characterizing migrated sediment gases with minimal compositional and isotopic fractionation is challenging, and different methods are currently in use to extract and analyze surface sediment gases. These methods have not been compared in controlled laboratory experiments. The key to calibration experiments is to know the charge gas composition and thus have a basis to evaluate the sediment gas extraction procedure.     

南黄海盆地北部坳陷北凹油气成藏特征的再认识

南黄海盆地北部坳陷北凹是一个大中型的中、新生代沉积凹陷,经过四十余年的油气勘探,至今仍无商业油气发现,仅发现诸城1-2一个含油气构造.北凹的油气勘探存在诸多问题,其中是否发育优质烃源岩、烃源岩能否生烃、油气是否运移至储层是关系到北凹油气勘探的基础地质问题.在对北凹主要烃源岩分析评价的基础上,采用流体包裹体系统分析技术,对北凹油气成藏特征展开研究.研究认为,北凹存在白垩系泰二段主力烃源岩,为中深湖相,生烃指标较好,分布面积较大,且现今已经成熟并排烃,生烃中心位于ZC-A井区.油气通过断裂发生垂向运移,已充注至始新统戴南组储层.流体包裹体荧光观察结果及显微测温结果均表明戴南组至少存在两期油充注,第一期发生在35 Ma左右,第二期为现今.     

Oil well produced water discharges to the North Sea. Part I: comparison of deployed mussels (Mytilus edulis), semi-permeable membrane devices, and the DREAM model predictions to estimate the dispersion of polycyclic aromatic hydrocarbons

The oil companies operating in the Norwegian sector of the North Sea have conducted field studies since the mid-1990s to monitor produced water discharges to the ocean. These studies have been used to refine monitoring methods, and to develop and validate a dispersion and impact assessment model. This paper summarizes monitoring data from surveys conducted in two major oil and gas production areas, and compares the results to concentrations of polycyclic aromatic hydrocarbons (PAH) in surface waters predicted by the dose-related risk and effect assessment model (DREAM). Blue mussels and semi-permeable membrane devices (SPMDs) were deployed in the Ekofisk and Tampen Regions and analyzed for more than 50 PAH. PAH concentrations in ambient seawater were estimated based on the mussels and SPMD concentrations, and compared to model predictions. Surface water total PAH concentrations ranged from 25 to 350 ng/L within 1 km of the platform discharges and reached background levels of 4-8 ng/L within 5-10 km of the discharge; a 100,000-fold dilution of the PAH in the discharge water. The PAH concentrations in surface water, predicted by three methods, compared well for the Ekofisk Region. The model predicted higher concentrations than the field-based methods for parts of the Tampen Region; particularly the most tidally influenced areas. Tidally-mediated fluctuations in PAH concentrations in surface water must be considered because they affect the estimation of PAH concentrations from mussel and SPMD residue data, and the predictions by the DREAM model. Predictions using mussels, SPMDs, and modeling support and complement each other; all are valuable tools for estimating the fate and impact of chemical contaminants in produced water that are discharged to the ocean.     

不同植物光合膜中镁离子诱导荧光同膜表面电荷变化相关性的比较研究

用水培的大麦苗及１９９２年，秋在青岛汇泉湾采集的大叶藻和刺松藻制备叶绿体膜，观测了Ｍｇ＾２＋诱导它们的ＰＳ－１１ Ｃｈ１α荧光和膜表面电荷变化之间的相互关系，发现在大麦和大叶藻中，Ｍｇ＾２＋诱导荧光的增高与其诱导膜表面电荷密度的降低平行相关；而在刺松藻中，则无类似的相关性变化，这不仅证明在大麦和大叶藻的叶绿体膜中阳离子对激发能分配的调节作用受膜表面静电性质的控制，而在刺松藻的叶绿体膜中则与膜表面静     

Reversible Electrode Effect and Dowsing

Izvestiya, Atmospheric and Oceanic Physics - The volumetric charge of the surface air above the objects of study of dowsers is characterized by a reversible electrode effect—an excess of...     

X80钢在含有SRB的海水溶液中阴极保护准则适用性

通过表面观察及电化学方法研究X80钢在含有SRB的海水溶液中阴极保护准则的适用性,测试结果表明:腐蚀控制因素为阳极控制,对金属施加阴极极化第5天降低金属腐蚀速度主要通过增大金属表面SRB的附着电阻和电荷转移电阻实现;而施加阴极极化第10天,阴极保护主要通过改变金属表面电荷转移电阻控制腐蚀速度,且阴极极化电位越大控制效果越好。无阴级保护的金属试样腐蚀产物较多且附着力差,施加阴极保护的金属试样腐蚀产物较少且附着力较强。阴极保护的确能对存在SRB的海水溶液环境中X80钢起到阴极极化作用,但极化5 d时传统的阴极保护准则中-850 mV_CSE(即-770 mV_SCE)电位未达到85%的保护要求,-950 mV_CSE(即-870 mV_SCE)电位刚刚能满足保护要求;而极化10 d时2种极化电位下保护度都有所下降且都不能满足保护要求,因此还需要进一步实验确定其合适的阴极保护电位。