Deeper groundwater chemistry and geochemical modeling of the arsenic affected western Bengal basin,West Bengal,India

A regional scale hydrogeochemical study of a ∼21,000-km² area in the western Bengal basin shows the presence of hydrochemically distinct water bodies in the main semiconfined aquifer and deeper isolated aquifers. Spatial trends of solutes and geochemical modeling indicate that carbonate dissolution, silicate weathering, and cation exchange control the major-ion chemistry of groundwater and river water. The main aquifer water has also evolved by mixing with seawater from the Bay of Bengal and connate water. The isolated aquifers contain diagenetically altered water of probable marine origin. The postoxic main aquifer water exhibits overlapping redox zones (metal-reducing, sulfidic and methanogenic), indicative of partial redox equilibrium, with the possibility of oxidation in micro-scale environments. The redox processes are depth-dependent and hydrostratigraphically variable. Elevated dissolved As in the groundwater is possibly related to Fe(III) reduction, but is strongly influenced by coupled Fe–S–C redox cycles. Arsenic does not show good correlations with most solutes, suggesting involvement of multiple processes in As mobilization. The main river in the area, the Bhagirathi–Hoogly, is chemically distinctive from other streams in the vicinity and probably has little or no influence on deep groundwater chemistry. Arsenic in water of smaller streams (Jalangi and Ichamati) is probably introduced by groundwater discharge during the dry season.     

Hydrogeochemical and isotopic evidences of the groundwater regime in Datong Basin, Northern China

Datong Basin is one of the Cenozoic faulted basins in Northern China’s Shanxi province, where groundwater is the major source of water supply. The results of hydrochemical investigation show that along the groundwater flow path, from the margins to the lower-lying central parts of the basin, groundwater generally shows increases in concentrations of TDS, HCO₃ ^?, SO₄ ^2?, Cl^?, Na⁺ and Mg²⁺ (except for Ca²⁺ content). Along the basin margin, groundwater is dominantly of Ca–HCO₃ type; however, in the central parts of the basin it becomes more saline with Na–HCO₃-dominant or mixed-ion type. The medium-deep groundwater has chemical compositions similar to those of shallow groundwater, except for the local area affected by human activity. From the mountain front to the basin area, shallow groundwater concentrations of major ions increase and are commonly higher than those in medium-deep aquifers, due to intense evapotranspiration and anthropogenic contamination. Hydrolysis of aluminosilicate and silicate minerals, cation exchange and evaporation are prevailing geochemical processes occurring in the aquifers at Datong Basin. The isotopic compositions indicate that meteoric water is the main source of groundwater recharge. Evaporation is the major way of discharge of shallow groundwater. The groundwater in medium-deep aquifers may be related to regional recharges of rainwater by infiltrating along the mountain front faults, and of groundwater permeating laterally from bedrocks of the mountain range. However, in areas of groundwater depression cones, groundwater in the deep confined aquifers may be recharged by groundwater from the upper unconfined aquifer through aquitards.     

Assessing groundwater availability and the response of the groundwater system to intensive exploitation in the North China Plain by analysis of long-term isotopic tracer data

The use of isotope tracers as a tool for assessing aquifer responses to intensive exploitation is demonstrated and used to attain a better understanding of the sustainability of intensively exploited aquifers in the North China Plain. Eleven well sites were selected that have long-term (years 1985–2014) analysis data of isotopic tracers. The stable isotopes δ¹⁸O and δ²H and hydrochemistry were used to understand the hydrodynamic responses of the aquifer system, including unconfined and confined aquifers, to groundwater abstraction. The time series data of ¹⁴C activity were also used to assess groundwater age, thereby contributing to an understanding of groundwater sustainability and aquifer depletion. Enrichment of the heavy oxygen isotope (¹⁸O) and elevated concentrations of chloride, sulfate, and nitrate were found in groundwater abstracted from the unconfined aquifer, which suggests that intensive exploitation might induce the potential for aquifer contamination. The time series data of ¹⁴C activity showed an increase of groundwater age with exploitation of the confined parts of the aquifer system, which indicates that a larger fraction of old water has been exploited over time, and that the groundwater from the deep aquifer has been mined. The current water demand exceeds the sustainable production capabilities of the aquifer system in the North China Plain. Some measures must be taken to ensure major cuts in groundwater withdrawals from the aquifers after a long period of depletion.     

Environmental isotopic study on the recharge and residence time of groundwater in the Heihe River Basin, northwestern China

The recharge and origin of groundwater and its residence time were studied using environmental isotopic measurements in samples from the Heihe River Basin, China. δ¹⁸O and δD values of both river water and groundwater were within the same ranges as those found in the alluvial fan zone, and lay slightly above the local meteoric water line (δD=6.87δ¹⁸O+3.54). This finding indicated that mountain rivers substantially and rapidly contribute to the water resources in the southern and northern sub-basins. δ¹⁸O and δD values of groundwater in the unconfined aquifers of these sub-basins were close to each other. There was evidence of enrichment of heavy isotopes in groundwater due to evaporation. The most pronounced increase in the δ¹⁸O value occurred in agricultural areas, reflecting the admixture of irrigation return flow. Tritium results in groundwater samples from the unconfined aquifers gave evidence for ongoing recharge, with mean residence times of: less than 36 years in the alluvial fan zone; about 12–16 years in agricultural areas; and about 26 years in the Ejina oasis. In contrast, groundwater in the confined aquifers had ¹⁴C ages between 0 and 10 ka BP.     

Hydrogeochemical characteristics of groundwater from the two main aquifers in the Red River Delta,Vietnam

In the Red River Delta, situated in the northern part of Vietnam, nearly its entire population depends solely on groundwater for daily water consumptions. For this reason, groundwater quality assessments must be carefully carried out using hydrogeochemical properties, to ensure effective groundwater resource planning for the Delta’s present and future groundwater use. In this study, the spatial and seasonal changes in the hydrogeochemical characteristics of groundwater in the two main aquifers of the RRD were investigated by analyzing the physicochemical data obtained in 2011 from 31 conjunctive wells in the Delta’s Holocene unconfined aquifer (HUA) and Pleistocene confined aquifer (PCA) using the Piper diagram and the Gibbs diagram. Results of the data analysis show that the groundwater in both aquifers in the upstream area of the delta is dominated by the [Ca²⁺–HCO₃⁻] water-type, while the [Na⁺–Cl⁻] dominates along the middle-stream and downstream areas. Seasonal changes in the hydrogeochemical facies in both aquifers, comparing the results for the dry and the rainy seasons, were detected in about one third of the sampling wells, which were mainly located at the upstream portion of the Delta. The hydrogeochemical facies of HUA were different from that of PCA by about 45% of the sampling wells in both the dry and the rainy seasons, which were found mostly in the upstream and middle-stream areas.     

Simulated impacts of artificial groundwater recharge and discharge on the source area and source volume of an Atlantic Coastal Plain stream, Delaware, USA

A numerical groundwater-flow model was used to characterize the source area and volume of Phillips Branch, a baseflow-dominated stream incising a highly permeable unconfined aquifer on the low relief Delmarva Peninsula, USA. Particle-tracking analyses indicate that the source area (5.51 km²) is ～20% smaller than the topographically defined watershed (6.85 km²), and recharge entering ～37% of the surface watershed does not discharge to Phillips Branch. Groundwater residence time within the source volume ranges from a few days to almost 100 years, with 95% of the volume “flushing” within 50 years. Artificial discharge from groundwater pumping alters the shape of the source area and reduces baseflow due to the interception of stream flow paths, but has limited impacts on the residence time of groundwater discharged as baseflow. In contrast, artificial recharge from land-based wastewater disposal substantially reduces the source area, lowers the range in residence time due to the elimination of older flow paths to the stream, and leads to increased discharge to adjacent surface-water bodies. This research suggests that, in this and similar hydrogeologic settings, the “watershed” approach to water-resource management may be limited, particularly where anthropogenic stresses alter the transport of soluble contaminants through highly permeable unconfined aquifers.     

A spatio-temporal three-dimensional conceptualization and simulation of Dera Ismail Khan alluvial aquifer in visual MODFLOW: a case study from Pakistan

Dera Ismail Khan (DIK) is situated in the Lower Indus Basin of Pakistan. The land use has been changed in the canal command area due to irrigation activities near the Indus River. To check the current status and predict the groundwater levels in the area, the unconfined aquifer has been simulated in Visual MODFLOW for a period of 35 years, i.e., from 1985 to 2020. The 2900-km² area has been modeled with a grid of 500 by 500 m and the depth set to 100 m. The aquifer in the study area has been divided vertically and laterally into three and ten zones, respectively, for the characterization. Water wells and streams were used as the sinks and hydrologic boundaries, respectively. The model was successfully calibrated in steady and the non-steady state. The simulation revealed that the whole simulation can be divided into two phases, i.e., before and after the construction of the Chashma Right Bank Canal (CRBC), whereas the results were summarized in the form of water table depth maps and groundwater budget calculations. To determine the groundwater sustainability, a conjunctive use scenario has been employed to simulate the aquifer dynamics till 2020. The simulation revealed incremental drawdowns till the end.     

Field characterization and data integration to define the hydraulic heterogeneity of a shallow granular aquifer at a sub-watershed scale

Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km². The workflow involves characterization and data integration steps that were applied on a 12-km² study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.     

Groundwater flow through Pleistocene glacial deposits in the rapidly urbanizing Rouge River–Highland Creek watershed,City of Scarborough,southern Ontario,Canada

The city of Scarborough lies on the eastern margin of the Greater Toronto Area of southern Ontario, Canada, along the northern coastline of Lake Ontario. The City has a population of 500,000 and is presently one of the fastest growing communities in Canada. The City is expanding northwards onto rural land on the south slope of the large Pleistocene glacial Oak Ridges Moraine system. The moraine system is underlain by a thick (150 m) succession of tills, sands and gravels and is a regionally-significant recharge area for three principle aquifer systems that discharge to numerous watercourses that flow to Lake Ontario. Protection of deeper aquifers from surface-generated urban contaminants is a particular concern. A groundwater flow model using Visual MODFLOW was developed for the 350-km² Rouge River–Highland Creek (RRHC) drainage basin using an extensive GIS-based collection of subsurface geological, geophysical and hydrogeological data, maps of land use and surficial geology. The RRHC model was calibrated against point water level data, known potentiometric surfaces of the principal aquifers and baseflow measurements from streamflow gauging stations and determined to be within acceptable limits. Water balance calculations indicate that 70% of the basin recharge (106,000 m³/day) enters the Upper Aquifer along the crest and immediate flanks of the Oak Ridges Moraine. To the south, Upper Aquifer water moving through fractured till aquitards accounts for more than 75% of recharge to deeper aquifers. Water quality data confirm previous observations that urban- and rural-sourced contaminants (chlorides and nitrates) present in Upper Aquifer waters are moving rapidly into deeper aquifers. Some 83% of total RRHC recharge water is ultimately discharged as baseflow to creeks draining to Lake Ontario; the remainder discharges to springs and along eroding lakeshore bluffs. Model results demonstrate that deeper aquifers are poorly protected from urban contaminants and that long-term protection of ground and surface water quality has to be a priority of municipal planners if the resource is not to be severely degraded. Electronic Publication     

Hydrochemical evidence of the depth of penetration of anthropogenic recharge in sandstone aquifers underlying two mature cities in the UK

Pollution of urban groundwater is routinely reported but the profile of contamination with depth in urban aquifers is rarely resolved. This limits understanding of the depth of penetration of urban recharge and contaminants, and use of urban groundwater. Penetration of anthropogenic solutes (major ions, trace metals) in Permo-Triassic sandstone aquifers underlying two mature conurbations in the UK was investigated through depth-specific, groundwater sampling of dedicated multilevel piezometers. Identification of solute origin and biogeochemical processes (e.g. denitrification, mineral dissolution) was aided by use of stable isotope ratios (³⁴S/³²S, ¹⁸O/¹⁶O, ¹⁵N/¹⁴N, ¹³C/¹²C) and chemical speciation modelling (PHREEQC). Depth profiles of aquifer hydrochemistry reveal penetration of anthropogenic solutes to depths of between 30 and 47 m below ground in the unconfined sandstone and confirm the contributions of faecal and industrial effluents to urban recharge. They also highlight the complexity of solute loading and difficulty resolving solute origin from the range of potential sources in urban groundwater. Faecally-derived NO₃ is the most pervasive contaminant exceeding drinking-water quality guidelines and is associated with elevated concentrations of B and SO₄. Elevated concentrations of Li, B, Cr and Co are observed at depth in groundwater contaminated by long-term industrial land use (metalworking). Observed penetration of anthropogenic solutes in the unconfined sandstone is consistent with post-development recharge of urban groundwater (residence times <230 a) indicated by flow modelling, and suggests tentatively that urban abstraction to depths of up to 50 m below ground in the unconfined Permo-Triassic sandstone is required to scavenge contaminated groundwater.     

Groundwater recharge and evolution in the Dunhuang Basin,northwestern China

Groundwater recharge and evolution in the Quaternary aquifer beneath the Dunhuang Basin was investigated using chemical indicators, stable isotopes, and radiocarbon data to provide guidance for regional water management. The quality of groundwater and surface water is generally good with low salinity and it is unpolluted. The dissolution of halite and sylvite from fine-grained sediments controls concentrations of Na⁺ and K⁺ in the groundwater, but Na⁺/Cl⁻ molar ratios >1 in all samples are also indicative of weathering of feldspar contributing to excess Na⁺. The dissolution of carbonate minerals yields Ca²⁺ to the groundwater, thereby exerting a strong influence on groundwater salinity. The δ¹⁸O and δ²H values in unconfined groundwater are enriched along the groundwater flow path from SW to NE. In contrast, confined groundwater was depleted in heavy isotopes, with mean values of −10.4‰ δ¹⁸O and −74.4‰ δ²H. Compared with the precipitation values, all of the groundwater samples were strongly depleted in heavy isotopes, indicating that modern direct recharge to the groundwater aquifers in the plains area is quite limited. The unconfined water is generally young with radiocarbon values of 64.9–79.6 pmc. In the northern basin, radiocarbon content in the confined groundwater is less than 15 pmc and an uncorrected age of ∼15 ka, indicates that this groundwater was recharged during a humid climatic phases of the late Pleistocence or early Holocene. The results have important implications for inter-basin water allocation programmes and groundwater management in the Dunhuang Basin.     

Stable chlorine isotopic signatures and fractionation mechanism of groundwater in Anyang,China

The present work provides an online Bench II-IRMS technique for the measurement of stable chlorine isotope ratio, which is used to measure the δ³⁷Cl of 38 groundwater samples from the Karst and Quaternary aquifers in Anyang area. The regional distribution and signature of δ³⁷Cl value are characterized on the base of isotopic data. The results suggest that the δ³⁷Cl value of Quaternary groundwater decreases with increasing Cl^? concentration, and has no correlation with δ¹⁸O and δD values, but closely correlates with the depth to water table. The fractionation mechanism of the chlorine isotope is expounded according to the type of groundwater. The δ³⁷Cl value of karst water is generally positive, which is relevant to the dissolution of evaporite (gypsum mine), and may be caused by the mixing of groundwater and precipitation. The groundwater of Quaternary unconfined aquifer is mainly recharged by precipitation, and the δ³⁷Cl value of groundwater is generally negative. The δ³⁷Cl value of groundwater in Quaternary confined aquifer is more negative with increasing the depth to water level and elevated Cl^? concentration, which is possible to result from the isotope fractionation of ion filtration. The groundwater with inorganic pollutants in Quaternary unconfined aquifer has generally a positive δ³⁷Cl value.     

Identifying the recharge sources and age of groundwater in the Songnen Plain (Northeast China) using environmental isotopes

The recharge sources and groundwater age in the Songnen Plain, Northeast China, were confirmed using environmental isotopes. The isotopic signatures of the unconfined aquifers in the southeast elevated plain and the north and west piedmont, cluster along local meteoric water lines (LMWLs) with a slope of about 5. The signature of source water was obtained by the intersection of these LMWLs with the regional meteoric water line (RMWL). This finding provides evidence that the recharge water for these areas originate from the Changbai Mountains and the Low and High Hingan Mountains, respectively. Groundwater in the unconfined aquifer in the low plain yields a LMWL with a slope of 4.4; its nitrate concentration indicates the admixture of irrigation return flow. The δ-values of the unconfined aquifer in the east elevated plain plot along the RMWL, reflecting recharge by local precipitation. The mean residence time of groundwater in these aquifers is less than 50?years. However, the ¹⁴C age of the groundwater in the confined Quaternary aquifer ranges from modern to 19,500?years, and in the Tertiary confined aquifer from 3,100 to 24,900?years. Modern groundwater is mainly recharged to the Quaternary confined aquifer on the piedmont by local precipitation and lateral subsurface flow.     

The integrated impacts of natural processes and human activities on groundwater salinization in the coastal aquifers of Beihai,southern China

Salinization in coastal aquifers is usually related to both seawater intrusion and water–rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl^?, Na⁺, Ca²⁺, Mg²⁺ and SO ₄ ^2– ), as well as the isotopic content and ratios (²H, ¹⁸O, ⁸⁷Sr/⁸⁶Sr and ¹³C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.     

Hydrogeology of a montane headwater groundwater system downgradient of a coal-mine waste rock dump: Elk Valley,British Columbia,Canada

Steelmaking-coal waste rock placed in mountain catchments in the Elk Valley, British Columbia, Canada, drain constituents of interest (CIs) to surface water downgradient of the waste rock dumps. The role of groundwater in transporting CIs in the headwaters of mountain catchments is not well understood. This study characterizes the physical hydrogeology of a portion of a 10-km² headwater catchment (West Line Creek) downgradient of a 2.7-km² waste rock dump placed over a natural headwater valley-bottom groundwater system. The study site was instrumented with 13 monitoring wells. Drill core samples were collected to determine subsurface lithology and geotechnical properties. The groundwater system was characterized using field testing and water-level monitoring. The valley-bottom sediments were composed of unconsolidated glacial and meltwater successions (<64 m thick) deposited as a series of cut and fill structures overlying shale bedrock. An unconfined basal alluvial aquifer located above fractured bedrock was identified as the primary conduit for groundwater flow toward Line Creek (650 m from the toe of the dump). Discharge through the basal alluvial aquifer was estimated using the geometric mean hydraulic conductivity (±1 standard deviation). These calculations suggest groundwater discharge could account for approximately 15% (ranging from 2 to 60%) of the total water discharged from the watershed. The residence time from the base of the waste rock dump to Line Creek was estimated at <3 years. The groundwater system was defined as a snowmelt (i.e., nival) regime dominated by direct recharge (percolation of precipitation) across the catchment.     

Characterization of hydrogeologic properties of the Tabriz plain multilayer aquifer system,NW Iran

A detailed hydrogeological investigation was carried out in the Tabriz plain in Iran using conventional hydrogeological field investigations and hydrochemistry. The study was carried out because the aquifers are of particular importance as they are more or less the only source of water supply available to the rural population and for agricultural and industrial activities. Analytical and numerical methods were applied to the constant rate pumping test data from the Tabriz airport and the Tabriz Power Station well fields. Two types of aquifers of different water quality were identified in the study area: an unconfined aquifer that extends over the plain and confined aquifers that are found in the deeper layers of the multilayered sediment terraces of the Aji-Chay River course. Therefore, the central part of the Tabriz plain contains both unconfined and confined aquifers, while close to the highlands, there is only an unconfined aquifer. There was evidence of minor leakage in the confined aquifers when the numerical method was used for analysis. The groundwater in the area can be identified by three main geochemical facies: Na-Cl, Ca-HCO₃, and mixed Ca-Mg-Cl-SO₄. The processes responsible for the hydrochemical evolution in the area fall into five categories: dissolution of evaporate minerals, precipitation of carbonate minerals, evaporation, ion exchange, and anthropogenic activity.     

Hydrogeochemical and isotopic evidence of groundwater evolution and recharge in aquifers in Beijing Plain, China

An investigation was conducted in Beijing to identify the groundwater evolution and recharge in the quaternary aquifers. Water samples were collected from precipitation, rivers, wells, and springs for hydrochemical and isotopic measurements. The recharge and the origin of groundwater and its residence time were further studied. The groundwater in the upper aquifer is characterized by Ca-Mg-HCO₃ type in the upstream area and Na-HCO₃ type in the downstream area of the groundwater flow field. The groundwater in the lower aquifer is mainly characterized by Ca-Mg-HCO₃ type in the upstream area and Ca-Na-Mg-HCO₃ and Na-Ca-Mg-HCO₃ type in the downstream area. The δD and δ¹⁸O in precipitation are linearly correlated, which is similar to WMWL. The δD and δ¹⁸O values of river, well and spring water are within the same ranges as those found in the alluvial fan zone, and lay slightly above or below LMWL. The δD and δ¹⁸O values have a decreasing trend generally following the precipitation → surface water → shallow groundwater → spring water → deep groundwater direction. There is evidence of enrichment of heavy isotopes in groundwater due to evaporation. Tritium values of unconfined groundwater give evidence for ongoing recharge in modern times with mean residence times <50 a. It shows a clear renewal evolution along the groundwater flow paths and represents modern recharge locally from precipitation and surface water to the shallow aquifers (<150 m). In contrast, according to ¹⁴C ages in the confined aquifers and residence time of groundwater flow lines, the deep groundwater is approximately or older than 10 ka, and was recharged during a period when the climate was wetter and colder mainly from the piedmont surrounding the plain. The groundwater exploitation is considered to be “mined unsustainably” because more water is withdrawn than it is replenished.     

Regional groundwater flow and geochemical evolution in the Amacuzac River Basin,Mexico

An approach is presented to investigate the regional evolution of groundwater in the basin of the Amacuzac River in Central Mexico. The approach is based on groundwater flow cross-sectional modeling in combination with major ion chemistry and geochemical modeling, complemented with principal component and cluster analyses. The hydrogeologic units composing the basin, which combine aquifers and aquitards both in granular, fractured and karstic rocks, were represented in sections parallel to the regional groundwater flow. Steady-state cross-section numerical simulations aided in the conceptualization of the groundwater flow system through the basin and permitted estimation of bulk hydraulic conductivity values, recharge rates and residence times. Forty-five water locations (springs, groundwater wells and rivers) were sampled throughout the basin for chemical analysis of major ions. The modeled gravity-driven groundwater flow system satisfactorily reproduced field observations, whereas the main geochemical processes of groundwater in the basin are associated to the order and reactions in which the igneous and sedimentary rocks are encountered along the groundwater flow. Recharge water in the volcanic and volcano-sedimentary aquifers increases the concentration of HCO₃ ^–, Mg²⁺ and Ca²⁺ from dissolution of plagioclase and olivine. Deeper groundwater flow encounters carbonate rocks, under closed CO₂ conditions, and dissolves calcite and dolomite. When groundwater encounters gypsum lenses in the shallow Balsas Group or the deeper Huitzuco anhydrite, gypsum dissolution produces proportional increased concentration of Ca²⁺ and SO₄ ^2–; two samples reflected the influence of hydrothermal fluids and probably halite dissolution. These geochemical trends are consistent with the principal component and cluster analyses.     

Geochemical and isotopic characterization of groundwater from shallow and deep limestone aquifers system of Aleppo basin (north Syria)

Stable isotopes (δ¹⁸O, δ²H and ¹³C) and radioactivity (³H, ¹⁴C) have been used in conjunction with chemical data to evaluate the processes generating the chemical composition, reconstruct the origin of the water and groundwater residence time. The Aleppo basin is comprised of two main limestone aquifers: the first one is unconfined of Paleogene age and the second is confined of Upper Cretaceous age. The chemical data indicate that the dissolution of minerals and evaporation are the main processes controlling groundwater mineralization. The groundwater from the two aquifers is characterized by distinctive stable isotope signatures. This difference in water isotopes is interpreted in terms of difference origin and recharge period. Fresh and brackish shallow groundwater were mostly recharged during the Holocene period. The presence of ³H in several groundwater samples of this aquifer gives evidence that groundwater recharge is going on. Brackish water of the deep confined aquifer has depleted stable isotope composition and very low ¹⁴C activity that indicates recharge during the late Pleistocene cold period.     

Recharge of the plio-quaternary water table aquifer in Tunisian chotts region estimated from stable isotopes

The hydrodynamic groundwater data and stable isotopes of water have been used jointly for better understanding of upward leakage and mixing processes in the Djerid aquifer system (southwestern Tunisia). The aquifer system is composed of the upper unconfined Plio-Quaternary (PQ) aquifer, the intermediate (semi-)confined Complex Terminal (CT) aquifer and the deeper confined Continental Intercalaire (CI) aquifer. A total of 41 groundwater samples from the CT and PQ aquifers were collected during June 2001. The stable isotope composition of waters establishes that the CT deep groundwater (depleted as compared to present Nefta local rainfall) is ancient water recharged during late Quaternary time. The relatively recent water in the shallow PQ aquifer is composed of mixed water resulting from upward leakage and sporadic meteoric recharge. In order to characterize the meteoric input signal for PQ in the study area, rainfall water samples were collected during 4 years (2000–2003) at the Nefta meteorological station. Weighted mean values of isotopic contents with respect to rainfall amounts have been computed. Despite the short collection period in the study area, results agree with those found in Beni Abbes (southwestern Algerian Sahara) by Fontes on 9 years of rainfall surveillance. Stable isotopic relationships provide clear evidence of shallow PQ aquifer replenishment by deep CT groundwater. The ¹⁸O/upward leakage rate allowed the identification of distinctive PQ waters related to CT aquifer configuration (confined in the western part of the study area, semi-permeable in the eastern part). These trends were confirmed by the relation ¹⁸O/TDS. The isotope balance model indicated a contribution of up to 75% of the deep CT groundwater to the upper PQ aquifer in the western study area, between Nefta and Hazoua.