Research on catastrophic rock avalanche at Guanling, Guizhou, China

On June 28, 2010, a catastrophic rock avalanche occurred after an extreme rainstorm at Guanling with N 25°59′10′′ in latitude and E 105°16′50′′ in longitude, Guizhou, China. This rock avalanche has a long run-out distance of 1.5 km, with 1.75 million cubic meters of debris instantly burying two villages and resulting in 99 deaths. It originated in the coal measure strata, with the upper part of limestone and dolomite, the middle part of the sandstone with gentle inclination, and the lower part of shale and mudstone, together locally with coals. This kind of unique structure, with hard resistant caprock overlying softer ductile rocks, coupled with the central outflow region at the contact zone, has catastrophic potential for rock avalanches and creates challenges for engineering geological/hydrogeological analysis. The topography showed that the hillside slopes were steeper at the upper portion but gentler in the lower portion, looked like the shape of a “boot.” The upper steep landform easily led to slope instability due to its high static shear stresses, and the wide middle and lower parts provided kinematic conditions for long run-out. Transformation of the larger potential energy into kinetic energy contributed to the formation of a rapid long run-out rock avalanche. The rainfall from June 27 to 28 was the apparent trigger of this catastrophic avalanche. The measured rainfall of more than 310 mm within 24 h exceeded the local historical records that were recorded over the last 60 years. The pore pressure on discontinuities of sandstone had an effect on the slope stability. The valley runoff supplied a saturated base for the long run-out debris, inducing an additional increase of the terminus distance and the increased velocity of the avalanche movement.     

Predicting Lahar-Inundation Zones: Case Study in West Mount Pinatubo, Philippines

This paper demonstrates techniques for pre-eruption prediction of lahar-inundation zones in areas where a volcano has not erupted within living memory and/or where baseline geological information about past lahars could be scarce or investigations to delimit past lahars might be incomplete. A lahar source (or proximal lahar-inundation) zone is predicted based on ratio of vertical descent to horizontal run-out of eruptive deposits that spawn lahars. Immediate post-eruption distal lahar-inundation zones are predicted based on “pre-eruption” distal lahar-inundation zones and on spatial factors derived from a digital elevation model. Susceptibility to distal lahar-inundation is estimated by weights-of-evidence, by logistic regression and by evidential belief functions. Predictive techniques are applied using a geographic information system and are tested in western part of Pinatubo volcano (Philippines). Predictive maps are compared with a forecast volcanic-hazard map through validation against a field-based volcanic-hazard map. The predictive model of proximal lahar-inundation zone has “true positive” prediction accuracy, “true negative” prediction accuracy, “false positive” prediction error and “false negative” prediction error that are similar to those of the forecast volcanic-hazard map. The predictive models of distal lahar inundation zones have higher “true positive” prediction accuracy and lower “false negative” prediction error than the forecast volcanic-hazard map, although the latter has higher “true negative” prediction accuracy and lower “false positive” prediction error than the former. The results illustrate utility of proposed predictive techniques in providing geo-information could be used, howbeit with caution, for planning to mitigate potential lahar hazards well ahead of an eruption that could generate substantial source materials for lahar formation.     

Landslide Hazard Zonation using Remote Sensing and GIS: a case study of Dikrong river basin, Arunachal Pradesh, India

Landslides are among the most costly and damaging natural hazards in mountainous regions, triggered mainly under the influence of earthquakes and/or rainfall. In the present study, Landslide Hazard Zonation (LHZ) of Dikrong river basin of Arunachal Pradesh was carried out using Remote Sensing and Geographic Information System (GIS). Various thematic layers namely slope, photo-lineament buffer, thrust buffer, relative relief map, geology and land use / land cover map were generated using remote sensing data and GIS. The weighting-rating system based on the relative importance of various causative factors as derived from remotely sensed data and other thematic maps were used for the LHZ. The different classes of thematic layers were assigned the corresponding rating value as attribute information in the GIS and an “attribute map” was generated for each data layer. Each class within a thematic layer was assigned an ordinal rating from 0 to 9. Summation of these attribute maps were then multiplied by the corresponding weights to yield the Landslide Hazard Index (LHI) for each cell. Using trial and error method the weight-rating values have been re-adjusted. The LHI threshold values used were: 142, 165, 189 and 216. A LHZ map was prepared showing the five zones, namely “very low hazard”, “low hazard”, “moderate hazard”, “high hazard” and “very high hazard” by using the “slicing” operation.     

Groundwater pollution risk mapping for the Eocene aquifer of the Oum Er-Rabia basin, Morocco

Sustainable development requires the management and preservation of water resources indispensable for all human activities. When groundwater constitutes the main water resource, vulnerability maps therefore are an important tool for identifying zones of high pollution risk and taking preventive measures in potential pollution sites. The vulnerability assessment for the Eocene aquifer in the Moroccan basin of Oum Er-Rabia is based on the DRASTIC method that uses seven parameters summarizing climatic, geological, and hydrogeological conditions controlling the seepage of pollutant substances to groundwater. Vulnerability maps were produced by using GIS techniques and applying the “generic” and “agricultural” models according to the DRASTIC charter. Resulting maps revealed that the aquifer is highly vulnerable in the western part of the basin and areas being under high contamination risk are more extensive when the “agricultural” model was applied.     

Mapping block-and-ash flow hazards based on Titan 2D simulations: a case study from Mt. Taranaki,NZ

Numerical models for simulation of mass flows are typically focussed upon accurately predicting the paths, travel times and inundation from a single flow or collapse event. When considering catchment-based hazards from a volcano, this is complicated by often being faced with several possible scenarios. Over the last 800 years at Mt. Taranaki/Egmont, a number of dome growth and collapse events have resulted in the genesis and emplacement of block-and-ash flows (BAFs). Each BAF was directed northwestward by a breach in the crater rim. The latest dome collapse events in the AD 1880s and AD 1755 inundated the northwestern flank and had run-out lengths 10 km from source. Future activity of this type could have a devastating effect on the Taranaki region’s communities, infrastructure and economy. Hazard planning has involved constructing volcanic hazard maps based upon the areas inundated by past volcanic flows, with little consideration of present-day topography. Here, a numerical geophysical mass flow modelling approach is used to forecast the hazards of future comparable BAF events on NW Mt. Taranaki. The Titan2D programme encompasses a “shallow water”, continuum solution-based, granular flow model. Flow mechanical properties needed for this approach include estimates of internal and basal friction as well as the physical dimensions of the initial collapse. Before this model can be applied to Taranaki BAFs, the input parameters must be calibrated by simulating a range of past collapse events. By using AD 1860 and AD 1755 scenarios, initial collapse volumes can be well constrained and internal and basal friction angles can be evaluated through an iterative approach from previous run-out lengths. A range of possible input parameters was, therefore, determined to produce a suite of potentially inundated areas under present-day terrain. A suite of 10 forecasts from a uniformly distributed range were combined to create a map of relative probabilities of inundation by future BAF events. These results were combined in a GIS package to produce hazard zones related to user-specified hazard thresholds. Using these input parameter constraints, future hazard forecasts for this scale and type of event can also take into account changing summit and topographic configurations following future eruptive or collapse events.     

Synchronism between development of Cenozoic volcanic arcs and back-arc basins: Reasons and consequences

A geographic information system (GIS “Volcanic belts”) was used for analyzing the spatial and temporal relationship between tectono-magmatic cycles in the Cenozoic that took place at the convergent plate boundaries, mostly in volcanic arc-back-arc systems. The onset of back-arc basins and subaerial arc volcanism and their main evolutionary stages are shown to have occurred about the same time. These processes are still ongoing, which is indicated by today’s active volcanoes, high heat flows, and high deep-focus seismicity. The crust underlying both tectonic structures undergoes transformation, which results in a significant thinning of the “granite” layer within the volcanic belts, whereas crust within the back-arc basins changes its properties to the transitional (suboceanic) and oceanic type crusts. All processes that occur at the convergent plate boundaries can be described within the arc-back-arc system, the principal dynamic components of which are the asthenospheric plume upwelling above the continent edge and the oceanward-spreading plume head. This was accompanied by a gradual crustal thinning in the back-arc region and the formation of areas with oceanic crust, as well as by involvement of crustal material, together with rocks of the subducting slab, into subduction processes. As a result, the continental crust is removed from the tectonosphere and stored in the “slab cemetery.” Only a minor portion of the crustal materials is returned to the surface as subduction-related magmatism.     

Using ALSM to map sinkholes in the urbanized covered karst of Pinellas County,Florida—2. Accuracy statistics

We apply the logic of clinical epidemiological studies to quantify the accuracy of mapping sinkholes by ALSM in the 750 km² Pinellas County. By such studies, a new diagnostic procedure is tested by comparing the diagnoses in a clinical trial to diagnoses on the same patients from a more reliable, but more elaborate and expensive procedure (“gold standard” in epidemiological context). A relatively undeveloped, 65 km² focus area where we have aerial photographs that are effectively contemporaneous with the ALSM flights serves as the “clinical trial”. The xy-locations in the focus area are the “patients” in the trial. The “diagnostic test” for having “sinkhole disease” is inclusion in a database of sinkhole polygons delimited by ALSM contours (“ALSM-alone”), as detailed in Part 1. The standard of comparison (“gold standard” would be an overstatement in the absence of geophysical testing) is inclusion in a database of sinkhole outlines derived by best judgment of conjunctive interpretation of ALSM and aerial photography. GIS intersections that indicate the sensitivity and specificity of the test (ALSM-alone) are 43 and 98.3%, respectively, and, in the focus area where the prevalence of “sinkhole disease” is 4.7%, the positive and negative predictive values are 55.5 and 97.2%, respectively. Over much of the rest of the county, where only the test can be applied, the prevalence of sinkholes is sufficiently small that it cannot be determined to be any different from zero given the paucity of interpreted sinkholes (positive diagnoses) and the low specificity of the test method. The conclusion, therefore, is that contemporaneous aerial photography is essential to compile an ALSM-derived database that aims to state that the given xy-points lay inside or outside of topographic depressions in the covered karst of west-central Florida.     

Soil liquefaction susceptibility and hazard mapping in the residential area of Kütahya (Turkey)

This study presents the results of both field and laboratory tests that have been undertaken to assess liquefaction susceptibilities of the soils in Kütahya city, located in the well-known seismically active fault zone. Liquefaction potentials of the sub-surface materials at Kütahya city were estimated by using the geological aspect and geotechnical methods such as SPT method of field testing. And, the data obtained have been mapped according to susceptibility and hazard. The susceptibility map indicated “liquefable” and “marginally liquefable” areas in alluvium, and “non-liquefable” areas in Neogene unit for the magnitude of earthquake of M=6.5; whereas, liquefaction hazard map produced by using of liquefaction potential index showed the severity categories from “very low” to “high.” However, a large area in the study area is prone to liquefy according to liquefaction susceptibility map; the large parts of the liquefable horizon are mapped as “low” class of severity by the use of the liquefaction potential index. It can be said that hazard mapping of liquefaction for a given site is crucial than producing liquefaction susceptibility map for estimating the severity. Both the susceptibility and hazard maps should be produced and correlated with each other for planning in an engineering point of view.     

Assessment of aquifer vulnerability to contamination in Khanyounis Governorate, Gaza Strip—Palestine, using the DRASTIC model within GIS environment

Groundwater is a very important natural resource in Khanyounis Governorate (the study area) for water supply and development. Historically, the exploitation of aquifers in Khanyounis Governorate has been undertaken without proper concern for environmental impact. In view of the importance of quality groundwater, it might be expected that aquifer protection to prevent groundwater quality deterioration would have received due attention. In the long term, however, protection of groundwater resources is of direct practical importance because, once pollution of groundwater has been allowed to occur, the scale and persistence of such pollution makes restoration technically difficult and costly. In order to maintain basin aquifer as a source of water for the area, it is necessary to find out, whether certain locations in this groundwater basin are susceptible to receive and transmit contamination. This study aims to: (1) assess the vulnerability of the aquifer to contamination in Khanyounis governorate, (2) find out the groundwater vulnerable zones to contamination in the aquifer of the study area, and (3) provide a spatial analysis of the parameters and conditions under which groundwater may become contaminate. To achieve that, DRASTIC model within geographic information system (GIS) environment was applied. The model uses seven environmental parameters: depth of water table, net recharge, aquifer media, soil media, topography, impact of vadose zone, and hydraulic conductivity to evaluate aquifer vulnerability. Based on this model and by using ArcGIS 9.3 software, an attempt was made to create vulnerability maps for the study area. According to the DRASTIC model index, the study has shown that in the western part of the study area the vulnerability to contamination ranges between high and very high due to the relatively shallow water table with moderate to high recharge potential, and permeable soils. To the east of the previous part and in the south-eastern part, vulnerability to contamination is moderate. In the central and the eastern part, vulnerability to contamination is low due to depth of water table. Vulnerability analysis of the DRASTIC Model indicates that the highest risk of contamination of groundwater in the study area originates from the soil media. The impact of vadose zone, depth to water level, and hydraulic conductivity imply moderate risks of contamination, while net recharge, aquifer media, and topography impose a low risk of aquifer contamination. The coefficient of variation indicates that a high contribution to the variation of vulnerability index is made by the topography. Moderate contribution is made by the depth to water level, and net recharge, while impact of vadose zone, hydraulic conductivity, soil media, and Aquifer media are the least variable parameters. The low variability of the parameters implies a smaller contribution to the variation of the vulnerability index across the study area. Moreover, the “effective” weights of the DRASTIC parameters obtained in this study exhibited some deviation from that of the “theoretical” weights. Soil media and the impact of vadose zone were the most effective parameters in the vulnerability assessment because their mean “effective” weights were higher than their respective “theoretical” weights. The depth of water table showed that both “effective” and “theoretical” weights were equal. The rest of the parameters exhibit lower “effective” weights compared with the “theoretical” weights. This explains the importance of soil media and vadose layers in the DRASTIC model. Therefore, it is important to get the accurate and detailed information of these two specific parameters. The GIS technique has provided an efficient environment for analysis and high capabilities of handling large spatial data. Considering these results, DRASTIC model highlights as a useful tool that can be used by national authorities and decision makers especially in the agricultural areas applying chemicals and pesticides which are most likely to contaminate groundwater resources.     

Global landslide and avalanche hotspots

Allocating resources for natural hazard risk management has high priority in development banks and international agencies working in developing countries. Global hazard and risk maps for landslides and avalanches were developed to identify the most exposed countries. Based on the global datasets of climate, lithology, earthquake activity, and topography, areas with the highest hazard, or “hotspots”, were identified. The applied model was based on classed values of all input data. The model output is a landslide and avalanche hazard index, which is globally scaled into nine levels. The model results were calibrated and validated in selected areas where good data on slide events exist. The results from the landslide and avalanche hazard model together with global population data were then used as input for the risk assessment. Regions with the highest risk can be found in Colombia, Tajikistan, India, and Nepal where the estimated number of people killed per year per 100 km² was found to be greater than one. The model made a reasonable prediction of the landslide hazard in 240 of 249 countries. More and better input data could improve the model further. Future work will focus on selected areas to study the applicability of the model on national and regional scales.     

Dodging alligators,rattlesnakes, and backyard docks: a political ecology of sweetgrass basket-making and conservation in the South Carolina Lowcountry,USA

There is growing recognition among political ecologists of the need to examine shifting natural resource regimes and their effects on livelihoods in “First World” places. This emerging literature has variously examined the “Third World within,” the persistence of “subsistence activities” in the “First World,” and the “reterritorialization” of land tenure and access. However, much of this work has tended to focus on traditional extractive industries in the American West, indigenous claims to lands and resources in the U.S. and Canada, and non-timber resources on public lands. In contrast, we use a case study of African-American sweetgrass basket-makers, associated with the Gullah culture, in South Carolina’s lowcountry to examine the ways in which ongoing amenity-driven residential development is fundamentally reshaping resource access on private lands. Historically, basket-makers harvested the materials (primarily sweetgrass or Mulenbergia filipes) needed for their culturally important art form from accessible, rural, and privately held tracts of land in close proximity to their communities, but development pressures and changes in resident interpretation of property rights has decreased access to basket-making resources. The case is particularly illuminating, as it examines the emergence of ‘conservation subdivisions’ in the region and raises important questions about what “rural uses” and users are being conserved through responses to exurban, suburban, and urban development in formerly rural areas.     

Effects of Release Conditions Uncertainty on Avalanche Hazard Mapping

Dynamical models for calculating snow avalanche motion have gained growingimportance in recent years for avalanche hazard assessment. Nevertheless, inherentuncertainties in their input-data specification, although well acknowledged, areusually not explicitly incorporated into the analysis and considered in the mappingresults. In particular, the estimate of avalanche release conditions is affected bystrong uncertainties when associated to a return period. These sources of error arenormally addressed through sensitivity analysis or conservative parameters estimate.However, each of these approaches has limitations in assessing the statistical implications of uncertainties.In the present paper the problem of release scenarios randomness is looked at following a Monte Carlo procedure. This statistical sampling-analysis method allows the evaluation of the probability distributions of relevant variables for avalanche hazard assessment – such as runout distance and impact pressure – once the release variables – essentially releasedepth and release length – are expressed in terms of probability distributions, accounting explicitly for inherent uncertainties in their definition. Both the theoretical framework of this procedure and its application to a real study case are presented. As initial step of this research in the present work the attention is mainly focused on flowing avalanches descending on open slopes. Therefore, the one-dimensional version of VARA dynamic models is usedfor avalanche simulations.     

Rockfall hazard and risk analysis for Monte da Lua,Sintra, Portugal

The prediction of rockfall trajectories below a rock cliff is essential in susceptibility, hazard and risk maps, particularity close to populated areas. The Monte da Lua hill area in Portugal, a tourist destination close to the historic city of Sintra (UNESCO World Heritage), is a typical granite boulder chaos landscape where from time to time rockfalls occur, the last such event having occurred on 29 January 2002. This area is therefore suitable to develop a rockfall study in order to provide hazard and risk maps a basis for mitigation measures. A preliminary investigation of the area leads to the identification of 188 potentially dangerous boulders. Detailed locations and geotechnical characteristics in terms of geometry, strength and context were sampled for each boulder. Digital elevations at 1 × 1 m resolution, known rockfall trajectory and building locations are provided in a GIS project for the study together with the spatial database of boulder characteristics. The modelling approach was conducted in two steps: (1) discrimination of the boulders in terms of static and dynamic mobility behaviour with multivariate analysis; (2) stochastic simulation of rockfall trajectories. The rockfall trajectory algorithm proposed is straightforward and is only dependent on elevation data, initial location of boulders and a friction angle. Due to the slope of the area, it assumes that rockfall is always of the rolling or sliding type. The friction angle was calibrated on the basis of the rockfall travel distance recorded on 29 January 2002 and generates simulated “realistic” trajectories. A smaller friction angle increases all simulated trajectories, leading to more “pessimistic” scenarios. The combined analysis of trajectories and potential damage to buildings and discrimination in terms of static and dynamic behaviour provides a final table in which all 188 sampled boulders are classified in one of the five risk grades.     

Redox environment effect on redox sensitive elements in surface sediments of the Changjiang Estuary hypoxia zone

The grain size and element (including redox sensitive elements and terrigenous elements) concentration of surface sediments from the Changjiang Estuary hypoxia zone and its adjacent sea area were measured in this research. Based on the obtained data, the hypoxic environment’s influence on the distribution of elements in surface sediments was further studied. We believe that the “redox environment effect” greatly influences the distribution of the RSE, which reveals the “patchy enrichment pattern” offshore in the hypoxia zone, while the distribution of the terrigenous elements which shows the “stripped enrichment pattern” near shore is mainly affected by “granularity effects”. Due to the existence of the hypoxia zone of the Changjiang Estuary, the distribution of the RSE such as Mo, Cd and V in the study area exhibits the characteristics of “redox environment effects”. __________ Translated from Marine Geology & Quaternary Geology, 2007, 27(3):1–8 [译自: 海洋地质与第四纪地质]     

A step ahead of time: design, allocation and preservation of private open space in the 1920s––the case of a garden suburb in Israel

In the course of the last 50 years, the landscape in Israel has undergone major changes, due to accelerated urbanization following population growth. These processes had increased the pressure on the open land, especially in areas of urban expansion. Recognizing that Governments and local Municipalities had failed to stop the consequent loss of public open spaces, not only in Israel but worldwide, had lead recently many communities to adopt new solutions in the form of private open spaces. In this article we present a “step ahead of time”: a case of privately owned land, set aside as public green area during the 1920s in a neighborhood called “Ahuza Herbert Samuel” (Herbert Samuel, the first High Commissioner of Palestine under the British Mandate), located in the City of Haifa, in Northern Israel. The roots of this unique phenomenon during the 1920s could be linked to several sources of influence: Colonial town planning concepts, the emergence of garden cities and garden suburbs and most importantly to concepts brought in by the leaders of the immigrant community coming from Rumania. Photogrammetric and GIS analysis of this phenomenon had revealed that it had prevailed throughout 75 years of constant and massive increase in the demand for built-up areas in Israel in general and in Ahuza neighborhood in particular. The success in preserving these open areas gains current relevance in view of recent trends in the Western world of allocating privately owned green areas for public use.     

Carlin-type gold deposits in Qinling and some related problems

The sediment-hosted disseminated gold deposits in the Oinling region are of sedimentation-slight-metamorphic origin superimposed by hydrothermal reworking at moderate-low temperatures and are well comparable with the typical Carlin gold deposits in the United States.In view of the confusing concept concerning the “sediment-hosted”and “Carlin-type” gold deposits,the authors propose that the term“sediment-hosted gold deposit”should be used in a broad sense which encompasses at least the four subtypes,i.e.,the Carlin type,the metamorphic fine clastic type,the hydrothermal sedimentary type and the vein type.In oter words,the “Carlin-type”should not be used as a synonym for “sediment-hosted”but is recommended as a subtype under the general category of “sediment-hosted gold deposits”     

Chemodynamics of trace metal fractions in surface sediments of the Pandoh Lake,Lesser Himalaya,India

The seasonal variation in the trace metals’ concentrations (Cd, Co, Cu, Fe, Mn, Ni, Pb, and Zn) were investigated in surface sediments of the Pandoh Lake. The horizontal distribution of TC, TN, and TP reflects spatial and temporal differences in sedimentary organic production. The chemical sequential extraction of heavy metals was carried out by seven-step fractionation scheme (Leleyter and Probst in Int J Environ Chem 73:109–128, 1999). The significant concentrations of Ni and Cd were associated with “water soluble (Eua)” fraction in the monsoon and winter, respectively, while “exchangeable (Exch)” and “carbonate-bound (Carb)” fractions for Ni and Cd were abundant in winter and summer. The Cd, Cu, and Pb associated with “Exch” fraction in the summer season support their availability on exchange sites due to oxidized nature of surface sediments. Enrichment of Co, Fe, Mn, and Zn in “AFeO” fraction showed poor bioavailability, while Cd, Cu, and Mn in the monsoon, Co in the winter and summer, and Zn in the winter season showed significant “organically bound (Org)” fraction. The ANOVA was significant for chemical fractions of trace elements except “Carb” fraction of Pb and Zn and “CFeO” fraction of Pb. Factor analysis revealed that the “Eua”, “Exch”, and “Carb” fractions together control the metal enrichment of “MnO”, “AFeO”, and “CFeO” fractions in the summer season.     

Geoelectrical investigations by means of resistivity methods in karst areas in Romania

The applicability of resistivity methods to ground water investigations is well recognized. As water-saturated rock formations have a lower electrical resistivity than dry ones, an electrical resistivity survey should result in low resistivity anomalies. Normally, such anomalies are interpreted to indicate areas of potentially significant ground water flows. In karst areas, however, interpretation may not be as straightforward: for example, large electrically conductive domains can represent water bearing zones, whose fluid-permeability may be poor; alternatively, fast flow conduits, which may be unsaturated, occur as slender objects, and not as clear anomalous features. In order to deal with such extreme heterogeneities, resistivity investigations require some specific adjustments. One example is the so-called “mise à la masse” method. In Romania, it was used to trace the cold karst water inflows that detrimentally affected the commercial exploitation of a thermal spring, Hercules at Baile Herculane. Conventional geoelectrical approaches––such as using resistivity highs to detect air-filled cave passages, are proved to be less efficient in the considered karst investigations.     

Solar flare-related eruptions followed by long-lasting occultation of the emission in the He II 304 ? line and in microwaves

Plasma with a temperature close to the chromospheric one is ejected in solar eruptions. Such plasma can occult some part of emission of compact sources in active regions as well as quiet solar areas. Absorption phenomena can be observed in the microwave range as the so-called “negative bursts” and also in the He II 304 ? line. The paper considers three eruptive events associated with rather powerful flares. Parameters of absorbing material of an eruption are estimated from multi-frequency records of a “negative burst” in one event. “Destruction” of an eruptive filament and its dispersion like a cloud over a huge area observed as a giant depression of the 304 ? line emission has been revealed in a few events. One of the three currently known events is considered in this paper. One more of the events considered here is a possible candidate for such events.     

Synthetic “Cooperite”, “Braggite”, and “Vysotskite” in the system PtS-PdS-NiS at 1100°C, 1000°C, and 900°C

Summary ?Results of experimental investigations in the dry system PtS-PdS-NiS at 1100°C, 1000°C, and 900°C are presented. The phases observed at 1100°C are “cooperite” and a melt, at 1000°C “cooperite”, “braggite”, and a melt and at 900°C “cooperite”, “braggite”, “vysotskite”, Ni_1−xS, and a melt. At 1100°C the maximum solubility of Ni in ideal, Pd-free “cooperite” is 2.7 atomic per cent and the Pd-content limit in Ni-free “cooperite” is 12.8 atomic per cent. At 1000°C the maximum solubility of Ni in ideal, Pd-free “cooperite” is 3.3 atomic per cent and the Pd-content in Ni-free “cooperite” is 13.7 atomic per cent. The “braggite” composition ranges from Pt_0.56Pd_0.38Ni_0.06S and Pt_0.59Pd_0.41S in a Ni-saturated and Ni-free environment respectively to Pt_0.18Pd_0.80Ni_0.02S and Pt_0.14Pd_0.86S respectively. At 900°C the maximum Ni-content in ideal Pd-free “cooperite” is 3.1 atomic per cent and the Pd-limit in Ni-free “cooperite” is 12.5 atomic per cent. The “braggite” composition ranges from Pt_0.59Pd_0.29Ni_0.12S and Pt_0.60Pd_0.40S for a Ni-saturated and Ni-free environment respectively, to Pd_0.91Ni_0.09S and PdS respectively. The Ni-content in “braggite” and “vysotskite” increases slightly with increasing Pt/Pd ratios and is higher at 900°C than at 1000°C. Comparison of experimental trends with cooperite, braggite, and vysotskite analyses from the literature implies high temperatures of formation for Pt-Pd-Ni sulphides in placers if Ni-saturation is assumed.

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Zusammenfassung ?Synthetischer ,,Cooperit”, ,,Braggit” und “Vysotskit” im System PtS-PdS-NiS bei 1100°C, 1000°C und 900°C Ergebnisse experimenteller Untersuchungen im trockenen System PtS-PdS-NiS bei 1100°C, 1000°C und 900°C werden dargestellt. Bei 1100°C sind die Phasen “Cooperit” und Schmelze, bei 1000°C “Cooperit”, “Braggit” und Schmelze und bei 900°C “Cooperit”, “Braggit”, “Vysotskit”, Ni_1−xS und Schmelze stabil. Bei 1100°C ist die maximale L?slichkeit von Ni in idealem, Pd-freiem “Cooperit” 2.7 Atomprozent und der Pd-Gehalt in Ni-freien “Cooperit” liegt bei maximal 12.8 Atomprozent. Bei 1000°C ist die maximale L?slichkeit von Ni in idealem, Pd-freien “Cooperit” 3.3 Atomprozent und der Pd-Gehalt in Ni-freien “Cooperit” liegt bei maximal 13.7 Atomprozent. Die Zusammensetzung des “Braggits” variiert zwischen Pt_0.56Pd_0.38Ni_0.06S und Pt_0.18Pd_0.80Ni_0.02S in einem Ni-ges?ttigtem und zwischen Pt_0.59Pd_0.41S und Pt_0.14Pd_0.86S in einem Ni-freien Umfeld. Bei 900°C liegt die maximale L?slichkeit von Ni in idealem Pd-freien “Cooperit” bei 3.1 Atomprozent und der Pd-Gehalt in Ni-freien “Cooperit” liegt bei maximal 12.5 Atomprozent. Die Zusammensetzung des “Braggits” variiert zwischen Pt_0.59Pd_0.29Ni_0.12S und Pd_0.89Ni_0.08S in einem Ni-ges?ttigten und zwischen Pt_0.59Pd_0.40S und PdS in einem Ni-freien Umfeld. Der Nickelgehalt in “Braggit” und “Vysotskit” nimmt mit zunehmendem Pt/Pd Verh?ltnis zu und ist bei 900°C h?her als bei 1000°C. Ein Vergleich der experimentellen Trends mit Cooperit, Braggit und Vysotskit Analysen aus der Literatur weist auf eine Hochtemperaturbildung der Pt-Pd-Ni Sulfide in Seifenlagerst?tten hin, wenn man von Nickels?ttigung ausgeht.

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Received October 1, 1998;/revised version accepted September 7, 1999