La prévision du climat : de l'échelle saisonnière à l'échelle décennale

The atmosphere and the ocean are subject to many dynamical instabilities, which limit the time during which their behaviour can be deterministically forecasted. At longer timescales, the atmosphere can be predicted at best using statistical methods, as a response to external forcing linked to sea- and land-surface anomalies. Climate being defined as the mean of atmospheric states, it appears that it can be predicted up to a few months in advance, which is the characteristic time of the so-called slow components of the climate system. Forecasting can sometimes be extended to longer time ranges, especially when the coupled ocean–atmosphere system exhibits internal variability modes, with characteristic times of a few years. Seasonal climate forecasting is most often based upon Monte-Carlo simulations, where the various realisations correspond to slightly different initial conditions. The present sate-of-the-art in Europe (ECMWF) and/or in the USA (IRI) allows to forecast such major phenomena, as El Niño, up to six months in advance. Finally, some parameters may exhibit predictability at still longer time-ranges (inter-annual to decadal), but only for certain regions. The example of electricity production is used to underline the potentially large economical benefit of seasonal climate forecasting. To cite this article: J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.

Résumé

L'atmosphère et l'océan sont le siège d'instabilités dynamiques, qui limitent la durée pendant laquelle il est possible d'en prévoir l'évolution de façon déterministe. Au-delà, l'atmosphère n'est plus prévisible, au mieux, que de façon statistique, en fonction du forçage externe qu'exerce(nt) sur elle l'océan et/ou la surface des continents. Le climat (au sens d'une moyenne des états atmosphériques) se révèle ainsi prévisible jusqu'à des échéances temporelles de quelques mois, échelle de temps caractéristique des composantes dites « lentes » du système climatique. La prévision peut s'étendre à des échéances parfois plus longues, dans le cas où le système couplé océan–atmosphère posséderait des modes de variabilité temporelle de périodes caractéristiques de quelques années. La prévision climatique saisonnière est très souvent construite à partir de simulations de type Monte-Carlo, avec des ensembles de réalisations utilisant des conditions initiales légèrement différentes. Dans l'état actuel de ces prévisions, qu'elles soient réalisées en Europe (CEPMMT) ou aux États-Unis (IRI), il est possible de prévoir environ six mois à l'avance un certain nombre de phénomènes climatiques, en particulier ceux liés aux épisodes dits « El Niño », pour lesquels l'amplitude des variations est suffisamment importante. Il existe, par ailleurs, une prévisibilité à encore plus longue échéance (inter-annuelle à décennale), mais seulement pour certains paramètres et certaines régions. L'exemple de la production d'électricité montre l'importance économique potentielle très grande de la prévision climatique saisonnière. Pour citer cet article : J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.     

Le gisement AgHg de Zgounder (Jebel Siroua, Anti-Atlas, Maroc) : un épithermal néoprotérozoïque de type Imiter

The Zgounder ore deposit (Anti-Atlas, Morocco), is hosted in a PII–PIII Proterozoic volcanosedimentary series. Disseminated mineralization is dominated by mercuriferous native silver (2 to 30 wt.% Hg), with few silver sulfosalts (acanthite, pearceite), arsenopyrite and base-metal sulfides. Arsenic grade of arsenopyrite and homogenisation temperatures of fluid inclusions indicate initial conditions of high temperature (above 400 °C). Lead isotope compositions comfort a Late-Proterozoic age and a crustal origin for metals. Similarities are obvious with the neighbouring silver ore deposit of Imiter and lead to consider Zgounder as another example of Neoproterozoic epithermal deposit in the Anti-Atlas of Morocco, a region that appears more and more as a silver metallogenic province. To cite this article: É. Marcoux, A. Wadjinny, C. R. Geoscience 337 (2005).     

Apport de la gravimétrie à l'étude des structures profondes du Sahel de Tunisie (cas de la région de Kairouan–Sousse–Monastir)

The monotony of the surface and of the deep structure of the Sahel domain in eastern Tunisia (low topographic area covered by a Quaternary series) induces the possible existence of an important subsiding collapsed block and associated faulted zones. Gravity data analyses have permitted the reconnaissance of the crustal and gravimetric setting of the northern part of the Sahel domain and the discussion of main outlines of subsurface structures. The deep structure of a particular zone (Kairouan–Sousse–Monastir area) demonstrates the existence of an east-west en-doigt-de-gant crustal thinning confirmed by the gravity data. This deep structuring is perfectly showed by the high-resolution second-order enhanced analytic signal technique developed to image geologic boundaries such as contacts and faults. This technique, correlated with the distribution of all seismic events in the last century, has permitted to define an important east–west Kairouan–Sousse–Monastir tectonic corridor (CKSM). This corridor corresponds to major faults oriented east-west, were some folded structures can be developed. To cite this article: H. Gabtni, C. R. Geoscience 337 (2005).     

Paléoclimat des Petites Antilles depuis 4000 ans BP : l'enregistrement de la lagune de Grand-Case à Saint-Martin

A 2.5-m-thick sequence of lake sediments at the Étang de Grand-Case, Saint Martin (French West Indies) is studied here. Significant hydrological budget fluctuations allows distinction of three main climatic periods: (1) an overall dry period (4200 BP–2300 BP), characterised by carbonated mud, gypsum and storm sand layers; (2) a wet phase (2300 BP–1150 BP) dominated by organic mud; and (3) a more complex phase (1150 BP to present), with detrital inputs due to human activities. Comparison with other regional high-resolution records shows that similar climate modifications typify the whole Mesoamerican and Caribbean area. The climatic phenomena that are implicated in the variations of both precipitation and hurricane frequency over the Lesser Antilles are due to the latitudinal displacement of the inter-tropical convergence zone. These data give new support to the hypothesis of the existence of a correlation between peopling phases and climate variations in the Caribbean as previously proposed by some archaeologists. To cite this article: P. Bertran et al., C. R. Geoscience 336 (2004).     

L'érosion des chaînes de montagnes : influence de la sédimentation de piedmont

The applanation of mountain belts that results in peneplain is generally considered to be caused by the long-term activity of erosion. Peneplanation has been previously defined as the lowering of an elevated topography and the concomitant subduing of its relief. We propose a model following which piedmont sedimentation induces the base level rise, allowing applanation to develop at high elevation and resulting in an elevated ‘peneplain’. This model is illustrated by the morphological evolution of the southern flank of the Pyrenees during the Cainozoic. To cite this article: J. Babault, J. Van Den Driessche, C. R. Geoscience 337 (2005).     

Définition et datation de la Formation de Venaco (Corse) : dépôt d’origine gravitaire d’âge Priabonien

Priabonian age is highlighted for the first time in Corsica in the Venaco Formation using the presence of specific microfauna (in particular some representatives of Turborotalia cerroazulensis lineage). This silicoclastic formation is mainly represented by coarse facies. It is composed of three members from south to north and from oldest towards youngest: member of Uboli, Cardo and Orsu. The sedimentologic analysis reveals a gravity depositional environment, involving different type of currents. Sedimentologic and chronologic characteristics make the Venaco Formation and the Annot Formation (p.p.) equivalent. Dating the Venaco Fm. brings confirmation that the green schist metamorphism of the Variscan batholith and the related deformation are from the pre-Priabonian period.     

Enregistrement de phénomènes de resédimentation au cours du Maastrichtien supérieur et du Paléocène supérieur (J. Serj, Tunisie atlasique) : apport micropaléontologique et signature tectono-eustatique

Sedimentological and biostratigraphic analysis of Campanian–Maastrichtian reduced series of the J. Serj permitted to characterize two episodes of submarine erosion. The first is pre-Upper Maastrichtian (Rosita contusa zone), the second is pre-Upper Palaeocene (Morozovella velascoensis zone). Thus, two type-1 boundary surfaces are distinguished. These surfaces limit three stratigraphic intervals in apparent continuity. Syn-sedimentary tectonic activity is attested by gravity deposits or processes (conglomerates, slumps). To cite this article: A. Amri et al., C. R. Geoscience 337 (2005).     

Calcium,Na, K and Mg Concentrations in Seawater by Inductively Coupled Plasma‐Atomic Emission Spectrometry: Applications to IAPSO Seawater Reference Material,Hydrothermal Fluids and Synthetic Seawater Solutions

We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q^® water. We obtained an average reference value r_K (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg^?1)/(g kg^?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to r_Na, r_Ca and r_Mg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.     

Les argiles bleues du Cambrien inférieur de Saint-Pétersbourg et leur fissuration. Implications pour des stockages souterrains

The Lower Cambrian Saint Petersburg blue clays are composed of predominant illite and chlorite, sometimes accompanied by kaolinite. The <0.1 μm fraction has a high content of illite–smectite mixed layers. Particle-size distribution is more than 50% of clay particles and about 30% of silts. These blue clays correspond to plastic (and soft) clays; they may be compared to the Callovian clays of Bure (France), where storage of natural waste is envisaged. To cite this article: M. Arnould et al., C. R. Geoscience 334 (2002) 1135–1140.

Résumé

Les « argiles bleues » du Cambrien Inférieur de Saint-Pétersbourg sont constituées d'illite dominante et de chlorite, avec parfois présence de kaolinite. Des interstratifiés illite/montmorillonite sont très abondants dans la phase <0,1 μm. Du point de vue granulométrique, outre plus de 50% de particules argileuses, il existe une phase silteuse de l'ordre de 30%. Du point de vue pétrophysique, ce sont des argiles plastiques, de consistance molle. Elles sont subhorizontales et ont jusqu'à 116 m d'épaisseur. Outre l'absence de métamorphisme, malgré leur âge, leur caractère le plus remarquable est leur réseau de fracturation, bien observable en carrière. Les joints sont nets, sans remplissage ni cimentation. Les plans verticaux sont particulièrement développés. Le volume unitaire des blocs de matrice ne dépasse guère 1 m³. Des traces d'oxydation témoignent de circulations d'eau. Ces argiles silteuses anciennes peuvent aider à mieux connaı̂tre et comprendre les argilites silteuses épigénétiques calloviennes du site de Bure (Haute-Marne, France), où un stockage souterrain de déchets nucléaires est envisagé. Pour citer cet article : M. Arnould et al., C. R. Geoscience 334 (2002) 1135–1140.     

Stable isotopic evidence for fluid infiltration during contact metamorphism in a multiply-metamorphosed terrane: the Reynolds Range, Arunta Block, central Australia

The Lander Rock Beds form the local basement of the Reynolds Range in the Arunta Inlier of central Australia. These dominantly quartzose and pelitic lithologies underwent low-grade ( c.   400  °C) regional metamorphism prior to contact metamorphism ( c.   2.5  kbar) around S-type megacrystic granitoids at 1820–1800  Ma. The Lander Rock Beds are overlain by metasediments of the Reynolds Range Group, which were subsequently intruded by granitoids at c. 1780  Ma. Regional metamorphism at 1590–1580  Ma produced grades varying from greenschist (400  °C at 4–5  kbar) to granulite (750–800  °C at 4–5  kbar) from north-west to south-east along the length of the Reynolds Range. Oxygen isotope ratios of the Lander Rock Beds were reset from 13.4±0.8 to as low as 6.7 adjacent to the contacts of the larger plutons, and to 10.3±1.1 around the smaller plutons. Biotite in all the major rock types found in the aureoles has δD values between −52 and −69, probably reflecting resetting by a cooling igneous+metamorphic fluid near the plutons. Sapphirine-bearing and other Mg- and Al-rich rock types have low δ¹⁸O values (4.0±0.7). The precursors to these rocks were probably low-temperature ( c. 200  °C) diagenetic–hydrothermal deposits of Mg-rich chlorite, analogous to those in Proterozoic stratiform precious metal and uranium deposits that form by the infiltration of basin brines or seawater. As in the overlying Reynolds Range Group, regional metamorphism involved little fluid–rock interaction and isotopic resetting.     

Evolution of high-Mg–Al granulites from Sunkarametta, Eastern Ghats, India: evidence for a lower crustal heating–cooling trajectory

A suite of high-Mg–Al granulites from Sunkarametta, Eastern Ghats Belt, India, shows contrasting prograde assemblages of extremely aluminous orthopyroxene+cordierite+sapphirine and similarly aluminous orthopyroxene+Ti-rich spinel in closely associated domains. Textural and compositional characteristics indicate that both were derived from prograde dehydration–melting of biotite–plagioclase–quartz-bearing protoliths. The former assemblage was stabilized at relatively more magnesian bulk composition. Geothermobarometric data and petrogenetic grid considerations place 'peak' metamorphic conditions at c. 950 °C and 9 kbar. Subsequent to peak metamorphism, the rocks cooled to c . 700–750 °C, with slight lowering of pressure, and the retrograde reactions also involved melt–solid interaction. The inferred P – T  trajectory is one of heating–cooling at lower crustal (25–30 km) depths.     

Hot contacts of garnet peridotites in middle/upper crustal levels: new constraints on the nature of the late Variscan high-T/low-P event in the Moldanubian (Central Vosges/NE France)

P–T  paths based on parageneses in the immediate vicinity of former high-temperature contact zones between mantle peridotites and granulitic country rocks of the Central Vosges (NE France) were derived by applying several conventional thermometers and thermobarometric calculations with an internally consistent dataset. The results indicate that former garnet peridotites and garnet–spinel peridotites were welded together with crustal rocks at depths corresponding to 1–1.2 GPa. The temperature of the crustal rocks was about 650–700 °C at this stage, whereas values of 1100 °C (garnet peridotites) and 800–900 °C (garnet–spinel peridotites) were calculated for the ultramafic rocks. After emplacement of the mantle rocks, exhumation of the lower crust took place to a depth corresponding to 0.2–0.3 GPa. The temperatures of the incorporated peridotite slices were still high (900–1000 °C) at this stage. This is indicated by the presence of high- T  /low- P parageneses ( c . 800 °C, 0.2–0.3 GPa) in a small (1–10 m) contact aureole around a former garnet peridotite. Crustal rocks distant to the peridotites equilibrated in the same pressure range at lower temperature (650–700 °C). High cooling rates (10²–10³ °C Ma⁻¹) were calculated for a garnet–biotite rock inclusion in the peridotites and for the crustal rocks at the contact by applying garnet–biotite diffusion modelling. Minimum rates of 0.75–7.5 cm a⁻¹ are required for vertical ascent of rock units (30 km vertical distance) derived from the crust–mantle boundary, resulting in a late Variscan (340 Ma) high- T  /low- P event.     

Influence of deformation partitioning and metamorphic re-equilibration on P–T path reconstruction in the pre-Alpine basement of central Southern Alps (Northern Italy)

The dominant foliation (S2) in the metapelites of the Southalpine basement, near the western side of the Tertiary Adamello intrusive stock, is a Variscan greenschist facies planar fabric, slightly reworked during thick-skin Alpine tectonics. S2 is defined by muscovite and chlorite and was formed by decrenulation of pre-existing foliations, which are confined to metre-size, less-deformed domains and defined by biotite and white mica. The pre-S2 fabric is composite (D1a & D1b) and defined by contrasting amphibolite facies metamorphic assemblages in different residual sites. Cld+Bt_I+Grt+Ms_I+Pl+Qtz and St+Bt_II+Grt+Ms_II+Pl+Qtz assemblages mark D1a and D1b fabrics respectively; these developed during successive steps of a single, temperature-prograde polyphase event, rather than during separate tectonometamorphic imprints affecting different tectonic units, later coupled during a D2 greenschist facies stage. Thermobarometric estimates of assemblages formed during D1a, D1b and D2 show a transition from T  =480–540  °C (during D1a) to T  =570–660  °C (during D1b), corresponding to a slight pressure-increase from 0.75–0.95  GPa to 0.85–1.15  GPa. D2 greenschist retrogression corresponds to a pressure and temperature decrease ( T  <400–550  °C and P <0.3–0.4  GPa). This P–T– deformation–time path is inferred to be the result of uplift from a depth of c. 35  km, after Palaeozoic subduction and continental collision; it is consistent with models postulated for other metamorphic units of the Variscan Belt in Europe. This is the first documented example in the Southern Alps of temperature-prograde metamorphism before Palaeozoic collision.     

Petrology and microthermometry of aluminous rocks in the Botswanan Limpopo Central Zone: evidence for isothermal decompression and isobaric cooling

Phase analysis in the model K₂O-poor aluminous rock system (FMASH) illustrates the following sequence of reactions during retrograde metamorphism in the Botswanan Limpopo Central Zone:
Opx+Sil+Qtz=Crd ,
Opx+Sil=Spr+Crd ,
Grt+Qtz=Opx+Crd ;
Opx+Crd+W=Ged+Qtz ,
Grt+Opx+Crd+W=Ged ;
and
Grt+Qtz+W=Ged+Crd .
A quantitative petrogenetic grid with phase relations shows that sapphirine results from nearly isothermal decompression in the quartz-undersaturated portions of the grid, and that gedrite formation by reactions (4)–(6) records isobaric cooling from high temperature ( c . 800°  C) after the decompression. Conditions for hydration in the western part of the area were 700–800°  C and c . 6  kbar, based on microthermometric data and the available garnet–cordierite geothermometer. On the basis of these conditions and predicted thermodynamic properties of gedrite, phase relations in T–X _Mg space were constructed to investigate the isobaric cooling event. The results are in good agreement with the hydration P–T  path. Further, the T–X _Mg topologies show that hydration of orthopyroxene in the central part of the area (reaction 4) occurred at about 800°  C and c . 5  kbar. Therefore, we conclude that the Botswanan Limpopo Central Zone has suffered isothermal decompression, similar to the Central Zone in South Africa and Zimbabwe, followed by isobaric cooling. The isobaric cooling event in the western (at c . 6  kbar) and central (at c . 5  kbar) parts of the area commenced at nearly the same temperature ( c . 800°  C), and appear to be consistent with a tectonic model that involved westward movement (thrusting) of the Central Zone.     

Experimental dehydration kinetics of serpentinite using pore volumometry

A series of dehydration experiments was carried out on both intact rock and cold-pressed powdered samples of serpentinite at temperatures in the range 535–610 °C, 100–170 °C above the onset of the breakdown temperature of 435 °C. Pore water pressures near 120 MPa were servo-controlled using a pore volumometer that also allowed dehydration reaction progress to be monitored through measurement of the amount of evolved water. Effective hydrostatic confining pressures were varied between 0 and 113 MPa. The reaction rate of intact specimens of initially near-zero porosity was constant up to 50–80% reaction progress at any given temperature, but decreased progressively as transformation approached completion. Water expulsion rates were not substantially affected by elevation of effective pressures that remained insufficient to cause major pore collapse. An Arrhenius relation links reaction rate to temperature with an activation enthalpy of 429 ± 201 and 521 ± 52 kJ mol⁻¹ for powdered and intact specimens, respectively. Microstructural study of intact specimens showed extensive nucleation beginning at pre-existing cracks, veins and grain boundaries, and progressing into the interior of the lizardite grains. Extrapolation of these data towards equilibrium temperature provides an upper bound on the kinetics of this reaction in nature.     

P-T path determinations in the Tormes Gneissic Dome, NW Iberian Massif, Spain

The Tormes Gneissic Dome (TGD, NW sector of the Iberian Massif, Spain) is a high-grade metamorphic complex affected by a major episode of extensional deformation (D2). The syn-D2 P–T  path of the Lower Unit of the TGD was deduced from the analysis of reaction textures related to superimposed fabrics developed during exhumation, analysis of mineral zoning and thermobarometric calculations. It comprises an initial phase of decompression, determined using the tweequ thermobarometric technique, from 6.4–8.1 kbar at 735–750 °C (upper structural levels) and 7.2 kbar at 770 °C (lower structural levels) to 3.3–3.9 kbar and 645–680 °C. This evolution is consistent with the observed sequence of melting reactions and the generation of garnet- and cordierite-bearing anatectic granitoids. The later part of the syn-D2 P–T  path consisted of almost isobaric cooling associated with the thermal re-equilibration of the unit in the new structural position. This segment of the P–T  path is recorded by assemblages with And +Bt+Ms and Ms+ Chl +Ab related to the later mylonitic S2 fabrics, which indicate retrogression to low-amphibolite and greenschist facies conditions.     

The assemblage diaspore+quartz in metamorphic rocks: a petrological, experimental and thermodynamic study

The upper pressure limit of pyrophyllite is given by the equilibria (i) pyrophyllite=diaspore+quartz and (ii) pyrophyllite=diaspore+coesite. High- P experimental investigations carried out to locate equilibrium (i) yield brackets between 497 °C/24.8  kbar and 535 °C/25.1  kbar, and between 500 °C/23  kbar and 540 °C/23  kbar. Equilibrium (ii) was bracketed at 550 °C between 26.0 and 28.3  kbar. In the experimental P–T  range, equilibria (i) and (ii) are metastable with respect to kyanite. A stable P–T  grid is calculated using thermodynamic data derived under consideration of the present experimental results. According to these data, the lower pressure limit of the assemblage diaspore+quartz according to equilibrium (i) range from about 12  kbar/300 °C to 20  kbar/430 °C (in the presence of pure water). The upper stability of diaspore+quartz is limited by the reaction diaspore+quartz=kyanite+H₂O at about 450 °C (nearly independent of pressure) and, to higher pressure, by the quartz=coesite transition. Equilibrium (ii) is metastable over the whole P–T  range.
Natural occurrences600.S of the diaspore–quartz assemblage in metamorphic rocks in Sulawesi, New Caledonia, Amorgos and the Vanoise are characterized by minerals indicative of high- P such as ferro-magnesiocarpholite, glaucophane, sodic pyroxene and lawsonite. The metamorphic P–T  conditions of these rocks are estimated to be in the range 300–400 °C, >8  kbar. These data are compatible with the derived P–T  stability field of the diaspore+quartz assemblage. We conclude that, in metamorphic rocks, diaspore+quartz is, as ferrocarpholite, an indicator for unusual low- T  /very high- P settings.     

Reconstructing P–T paths during continental collision using multi-stage garnet (Gran Paradiso nappe, Western Alps)

Garnet–chloritoid-bearing micaschists from the Gran Paradiso massif (Western Alps) contain evidence of a polymetamorphic evolution. Detailed textural observations reveal that two stages of garnet growth are present in the micaschists, interpreted as: (i) relics of an early metamorphism of pre-Alpine age and (ii) newly grown Alpine garnet, respectively. Both generations of garnet preserve growth zoning. From thermocalc -based numerical modelling of mineral assemblages in pressure–temperature ( P – T ) pseudosections, we infer that garnet 1 grew at increasing temperature and slightly increasing pressure, whereas garnet 2 grew at decreasing pressure and slightly increasing temperature. Estimated P – T conditions are ∼620 °C, 6 kbar for the peak of the pre-Alpine event, and of 490 °C, 18–20 kbar for the pressure peak of the Alpine event. Modelling of the modal proportion and chemical composition of garnet (i) shows that the subsequent decompression (to 14–15 kbar at 550 °C) must have been accompanied by moderate heating and (ii) does not support a stage of final temperature increase following decompressional cooling. This argues against a late thermal pulse associated with mantle delamination. Preservation of growth zoning in both generations of garnet and the limited amount of diffusive re-equilibration at the boundary between the two garnets suggests that the rocks were subjected to fast burial and exhumation rates, consistent with data obtained from other internal Alpine units.     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.