Insights into Wasatch fault vertical slip rates using the age of sediments in Timpanogos Cave, Utah

Timpanogos Cave, located near the Wasatch fault, is about 357 m above the American Fork River. Fluvial cave sediments and an interbedded carbonate flowstone yield a paleomagnetic and U–Th depositional age of 350 to 780 ka. Fault vertical slip rates, inferred from calculated river downcutting rates, range between 1.02 and 0.46 mm yr^− 1. These slip rates are in the range of the 0–12 Ma Wasatch Range exhumation rate ( 0.5–0.7 mm yr^− 1), suggesting that the long-term vertical slip rate remained stable through mid-Pleistocene time. However, the late Pleistocene (0–250 ka) decelerated slip rate ( 0.2–0.3 mm yr^− 1) and the accelerated Holocene slip rate ( 1.2 mm yr^− 1) are consistent with episodic fault activity. Assuming that the late Pleistocene vertical slip rate represents an episodic slowing of fault movement and the long-term (0–12 Ma) average vertical slip rate, including the late Pleistocene and Holocene, should be  0.6 mm yr^− 1, there is a net late Pleistocene vertical slip deficit of  50–75 m. The Holocene and late Pleistocene slip rates may be typical for episodes of accelerated and slowed fault movement, respectively. The calculated late Pleistocene slip deficit may mean that the current accelerated Wasatch fault slip rate will extend well into the future.     

Treatment of Acid Mine Drainage (AMD) in South Brazil: Comparative active processes and water reuse

This work describes AMD techniques of neutralization, with lime, flocculation of the precipitates and comparative flocs/liquid separation by flotation with microbubbles or by lamellar settling (LS). The AMD treated water was characterized by its quality for recycling in terms of inorganic or organic elements, suspended or dissolved solids, among others. Two types of flocs were formed, “aerated” or not, in a special flocculation reactor, patented by this research group (RGF^®). Aerated flocs formed (within seconds) entered into contact with microbubbles under high shearing and raised-up at rates > 120 mh^− 1 allowing a rapid solid–liquid separation by flotation (HR-high rate), at about 13–15 m³m^− 2 h^− 1 loading capacity. Conversely, the non-aerated flocs settled at about 5–6 m h^− 1 in a lamella settler. Both AMD treatment techniques showed similar efficiencies (removal of ions > 90%) but the separation by lamella settling presented advantages, namely less reagents (no flotation collector required), lower power requirements and easier to operate. The operating costs (approximate values) of the AMD treatment by LS at pH 9 reaches about 0.3 US$ m^− 3 against 0.6 US$ m^− 3 for the HR-flotation process. Results found were proved to be similar to those found in recent ADM treatment installations in South Brazil. The quality of the treated water is fairly good, nearly free of heavy metals ion, low BOD (biological oxygen demand) and TOC (total organic content), low solids content and may be readily reused for irrigation, industrial processes and as wash water (among others, streets, vehicles, dust control). However, there is a need to extend the use of this treated water resource, but this, at least in Brazil, has not been legislated properly. It is concluded that this research will contribute in the discussion of this old and complex problem in acid mining effluents worldwide.     

Mercury mobilization by oxidative dissolution of cinnabar (α-HgS) and metacinnabar (β-HgS)

Cinnabar (α-HgS) and metacinnabar (β-HgS) dissolved at environmentally significant rates in oxygenated slurry experiments simulating a low-flow fluvial system. Based on SO₄²⁻ production, cinnabar dissolution rates were 2.64 to 6.16 μmol (SO₄²⁻) m^− 2 day^− 1, and metacinnabar dissolution rates were 1.20 to 1.90 μmol (SO₄²⁻) m^− 2 day^− 1. Monodentate-bound thiosulfate (S₂O₃²⁻) was identified as an oxidation product on the HgS surface by ATR-IR spectroscopy based on strong infrared absorption bands in the 1140–1145 cm^− 1 and 1006–1014 cm^− 1 regions. The presence of sulfide oxidation intermediates on the HgS surface indicates that SO₄²⁻ concentration underestimates α-HgS and β-HgS dissolution in this setting. Mercury release rates during dissolution were more than two orders of magnitude less than SO₄²⁻ production, but were significant: 0.47 mg (Hg) m^− 2 y^− 1 from cinnabar [6.45 nmol (Hg) m^− 2 day^− 1], and 0.17 mg (Hg) m^− 2 y^− 1 from metacinnabar [2.29 nmol (Hg) m^− 2 day^− 1]. The Hg mobilized during α-HgS and β-HgS dissolution is sufficient to form natural Au–Hg amalgam in downstream placer settings. The proportion of mercury that is not remobilized during α-HgS and β-HgS dissolution likely adsorbs to the dissolving mercuric sulfide. Adsorption of Hg²⁺ to cinnabar was detected in situ by anodic stripping voltammetry using a cinnabar-modified carbon paste electrode following accumulation of Hg²⁺ on the electrode at open circuit potential.     

Mineralogy and geochemistry of the Holocene lacustrine sediments in Nam Co, Tibet

The carbonates, clays and major chemical compositions of lacustrine sediments in Nam Co (Lake) were examined by X-ray diffraction, scanning electron microscopy and chemical analysis. Carbonates include monohydrocalcite (MHC, first report from China and in a high-altitude lake), low-Mg calcite and traces of dolomite. MHC in Nam Co is developed in water (1.8 g/L) with high Mg/Ca molar ratios (10.03–15.03), high pH (8.04–9.72) and the presence of bacteria, algae, diatom and ostracoda. Illite and Mg-chlorite provide a strong evidence for physical weathering in the Holocene. Most Ca and Sr in sediments originate from carbonates as the molar ratios of Ca and CO₃²⁻ are all less than 1 and the curve of Sr is very similar to that of Ca. However, most of the Mg, Fe and Rb are from clays. The lake water shifted from a fresh water environment to an evaporative, alkaline environment by 2.06 cal. ka BP. There was a depositional event that the depositional rate changed from 0.134 to 1.639 mm/a at about 2 cal. ka BP.     

A 5000 year record of intertidal peat stratigraphy and sea level change from northwest Alaska

Coastal environments of northwest Alaska preserve a detailed record of sea level change during the past 5000 ¹⁴C yr. Rapid burial of intertidal marshes by storm overwash processes, a short open water period, and the arctic maritime climate contribute to the preservation of marine and eolian facies. Eustatic and storm-controlled changes in sea level can be identified from interbedded sequences of marsh peat and coastal flood deposits on barrier islands and estuaries along northwest Seward Peninsula. Mean eustatic sea level has risen about 1.5 m during the last 5000 years, at an average of ca. 0.028 cm yr⁻¹, based on the depth and age relationship of a suite of 23 peat horizons sampled from a 140 km-long reach of coast. Nearshore erosion and sedimentation are controlled by secular variations in wave climate. Peaks in tidal amplitude and storminess correlate with transgressive sedimentary regimes and occurred during the periods 3300–1700, 1200–900, and since about 400 ¹⁴C yr BP. Short-term fluctuations in relative sea level are superimposed on the long-term regional eustatic trend, and record the coastal response to variable rates of sea-level change during the late Holocene.     

Magnetic anisotropy of calcite at room-temperature

The intrinsic room temperature magnetic properties of pure calcite were determined from a series of natural crystals, and they were found to be highly dependent on the chemical composition. In general, dia-, para-, and ferromagnetic components contribute to the magnetic susceptibility and the anisotropy of magnetic susceptibility (AMS). With a combination of magnetic measurements and chemical analysis these three contributions were determined and related to their mineralogical sources. The intrinsic diamagnetic susceptibility of pure calcite is − 4.46 ± 0.16 × 10^− 9 m³/kg (− 12.09 ± 0.5 × 10^− 6 SI) and the susceptibility difference is 4.06 ± 0.03 × 10^− 10 m³/kg (1.10 ± 0.01 × 10^− 6 SI). These diamagnetic properties are easily dominated by other components. The paramagnetic contribution is due to paramagnetic ions in the crystal lattice that substitute for calcium; these are mainly iron and manganese. The measured paramagnetic susceptibility agrees with the values calculated from the known concentration of paramagnetic ions in the crystals according to the Curie law of paramagnetic susceptibility. Substituted iron leads to an increase in the AMS. The paramagnetic susceptibility difference was found to correlate linearly with the iron content for concentrations between 500 and 10,000 ppm. An empirical relation was determined: (k₁ − k₃)^para (kg/m³) = Fe-content (ppm) × (1 ± 0.1) × 10^− 12 (kg/m³/ppm). The maximum susceptibility difference (Δk = k₁ − k₃) was found to be unaffected by iron contents below 100 ppm. Ferromagnetic contributions due to inclusions of ferromagnetic minerals can dominate the susceptibility. They were detected by acquisition of isothermal remanent magnetization (IRM) and their contribution to the AMS was separated by high-field measurements.     

Heat flow and lithospheric thermal regime in the Northeast German Basin

New values of surface heat flow are reported for 13 deep borehole locations in the Northeast German Basin (NEGB) ranging from 68 to 91 mW m^− 2 with a mean of 77 ± 3 mW m^− 2. The values are derived from continuous temperature logs, measured thermal conductivity, and log-derived radiogenic heat production. The heat-flow values are supposed free of effects from surface palaeoclimatic temperature variations, from regional as well as local fluid flow and from thermal refraction in the vicinity of salt structures and thus represent unperturbed crustal heat flow. Two-D numerical lithospheric thermal models are developed for a 500 km section along the DEKORP-BASIN 9601 deep seismic line across the basin with a north-eastward extension across the Tornquist Zone. A detailed conceptual model of crustal structure and composition, thermal conductivity, and heat production distribution is developed. Different boundary conditions for the thickness of thermal lithosphere were used to fit surface heat flow. The best fit is achieved with a thickness of thermal lithosphere of about 75 km beneath the NEGB. This estimate is corroborated by seismological studies and somewhat less than typical for stabilized Phanerozoic lithosphere. Modelled Moho temperatures in the basin are about 800 °C; heat flow from the mantle is about 35 to 40 mW m^− 2. In the southernmost part of the section, beneath the Harz Mountains, higher Moho temperatures up to 900 to 1000 °C are shown. While the relatively high level of surface heat flow in the NEGB obviously is of longer wave length and related to lithosphere thickness, changes in crustal structure and composition are responsible for short-wave-length anomalies.     

Glacial–interglacial productivity and environmental changes in Lake Biwa,Japan: A sediment core study of organic carbon,chlorins and biomarkers

Temporal changes in paleoproductivity of Lake Biwa (Japan) over the past 32 kyr have been studied by analyzing bulk organic carbon and photosynthetic pigments (chlorins) in the BIW95-5 core. Primary productivity was estimated on the assumption of C/N_org values of 8 for autochthonous organic matter (OM) and 25 for allochthonous OM and using an equation developed for the marine environment. The estimate indicates that primary productivity ranges from 50 to 90 g C m^?2 yr^?1 in the Holocene, while it is ～60 g C m^?2 yr^?1 on average in the last glacial. Pheophytin a and pheophorbide a are the major chlorins. A downcore profile of chlorin concentration normalized to autochthonous organic carbon (OC) shows a decreasing trend. Chlorin productivity was corrected by removal of the effect of post-burial chlorin degradation. The temporal profile of chlorin productivity thereby obtained resembles that from autochthonous OC.The difference in primary productivity between the Holocene and the glacial for the lake is markedly smaller than that for Lake Baikal situated in the boreal zone. This difference between the two lakes is probably caused by the difference in their climatic conditions, such as temperature and precipitation. Precipitation at Lake Biwa is relatively large during the glacial and the Holocene because of the continuous influence of the East Asian monsoon. Lake Baikal precipitation is generally small as a result of control by the continental (Siberia) climate regime. In addition, a significant difference in productivity between the glacial and the Holocene for Lake Baikal may be essentially controlled by the hydrodynamic systems in the lake.Lake Biwa terrigenous OM input events occurred at least five times over the period 11–32 kyr BP, suggesting enhanced monsoon activity. Molecular examination of the layer with a large input of terrigenous OM during the Younger Dryas indicates that concentrations of terrigenous biomarkers such as n-C₂₇–C₃₁ alkanes, lignin phenols, cutin acids, ω-hydroxy acids and C₂₉ sterols are high, suggesting that soil OM with peat-like material entered the lake as a result of flooding. An enhanced sedimentation rate in the last 3000 years might have been partially caused by agricultural activity around the lake.     

Groundwater recharge history and hydrogeochemical evolution in the Minqin Basin, North West China

The Minqin Basin is a type area for examining stress on groundwater resources in the Gobi Desert, and has been investigated here using a combination of isotopic, noble gas and chemical indicators. The basin is composed of clastic sediments of widely differing grain size and during the past half century over 10 000 boreholes have been drilled with a groundwater decline of around 1 m a⁻¹. Modern diffuse recharge is unlikely to exceed 3 mm a⁻¹, as determined using unsaturated zone profiles and Cl⁻ mass balance. A small component of modern (<50 a) groundwater is identified in parts of the basin from ³H–³He data, probably from irrigation returns. A clear distinction is found between modern waters with median δ¹⁸O values of 6.5 ± 0.5‰ and most groundwaters in the basin with more depleted isotopic signatures. Radiocarbon values as pmc range from 0.6% to 85% modern, but it is difficult to assign absolute ages to these, although a value of 20% modern C probably represents the late Pleistocene to Holocene transition. The δ¹³C compositions remain near-constant throughout the basin (median value of −8.1‰ δ¹³C) and indicate that carbonate reactions are unimportant and also that little reaction takes place. There is a smooth decrease in ¹⁴C activity accompanied by a parallel increase in ⁴He accumulations from S–N across the basin, which define the occurrence of a regional flow system. Noble gas temperatures indicate recharge temperatures of about 5.6 °C for late Pleistocene samples, which is some 2–3 °C cooler than the modern mean annual air temperature and the recharge temperature obtained from several Holocene samples. Groundwaters in the Minqin Basin have salinities generally below 1 g/L and are aerobic, containing low Fe but elevated concentrations of U, Cr and Se (mean values of 27.5, 5.8 and 5.3 μg L⁻¹, respectively). Nitrate is present at baseline concentrations of around 2 mg L⁻¹ but there is little evidence of impact of high NO₃ from irrigation returns. Strontium isotope and major ion ratios suggest that silicate reactions predominate in the aquifer. The results have important implications for groundwater management in the Minqin and other water-stressed basins in NW China – a region so far destined for rapid development. The large proportion of the water being used at present is in effect being mined and significant changes are urgently needed in water use strategy.     

The methane hydrate formation and the resource estimate resulting from free gas migration in seeping seafloor hydrate stability zone

It is a typical multiphase flow process for hydrate formation in seeping seafloor sediments. Free gas can not only be present but also take part in formation of hydrate. The volume fraction of free gas in local pore of hydrate stable zone (HSZ) influences the formation of hydrate in seeping seafloor area, and methane flux determines the abundance and resource of hydrate-bearing reservoirs. In this paper, a multiphase flow model including water (dissolved methane and salt)-free gas hydrate has been established to describe this kind of flow-transfer-reaction process where there exists a large scale of free gas migration and transform in seafloor pore. In the order of three different scenarios, the conversions among permeability, capillary pressure, phase saturations and salinity along with the formation of hydrate have been deducted. Furthermore, the influence of four sorts of free gas saturations and three classes of methane fluxes on hydrate formation and the resource has also been analyzed and compared. Based on the rules drawn from the simulation, and combined information gotten from drills in field, the methane hydrate(MH) formation in Shenhu area of South China Sea has been forecasted. It has been speculated that there may breed a moderate methane flux below this seafloor HSZ. If the flux is about 0.5 kg m⁻² a⁻¹, then it will go on to evolve about 2700 ka until the hydrate saturation in pore will arrive its peak (about 75%). Approximately 1.47 × 10⁹ m³ MH has been reckoned in this marine basin finally, is about 13 times over preliminary estimate.     

Carbonate precipitation in artificial soils as a sink for atmospheric carbon dioxide

Turnover of C in soils is the dominant flux in the global C cycle and is responsible for transporting 20 times the quantity of anthropogenic emissions each year. This paper investigates the potential for soils to be modified with Ca-rich materials (e.g. demolition waste or basic slag) to capture some of the transferred C as geologically stable CaCO₃. To test this principal, artificial soil known to contain Ca-rich minerals (Ca silicates and portlandite) was analysed from two sites across NE England, UK. The results demonstrate an average C content of 30 ± 15.3 Kg C m⁻² stored as CaCO₃, which is three times the expected organic C content and that it has accumulated at a rate of 25 ± 12.8 t C ha⁻¹ a⁻¹ since 1996. Isotopic analysis of the carbonates gave values between −6.4‰ and −27.5‰ for δ¹³C and −3.92‰ and −20.89‰ for δ¹⁸O, respectively (against V-PDB), which suggests that a combination of carbonate formation mechanisms are operating including the hydroxylation of gaseous CO₂ in solution, and the sequestration of degraded organic C with minor remobilisation/precipitation of lithogenic carbonates. This study implies that construction/development sites may be designed with a C capture function to sequester atmospheric C into the soil matrix with a maximum global potential of 290 Mt C a⁻¹.     

Late Quaternary deposition and facies model for karstic Lake Estanya (North-eastern Spain)

Lake Estanya is a small (19 ha), freshwater to brackish, monomictic lake formed by the coalescence of two karstic sinkholes with maximum water depths of 12 and 20 m, located in the Pre‐Pyrenean Ranges (North‐eastern Spain). The lake is hydrologically closed and the water balance is controlled mostly by groundwater input and evaporation. Three main modern depositional sub‐environments can be recognized as: (i) a carbonate‐producing ‘littoral platform’; (ii) a steep ‘talus’ dominated by reworking of littoral sediments and mass‐wasting processes; and (iii) an ‘offshore, distal area’, seasonally affected by anoxia with fine‐grained, clastic sediment deposition. A seismic survey identified up to 15 m thick sedimentary infill comprising: (i) a ‘basal unit’, seismically transparent and restricted to the depocentres of both sub‐basins; (ii) an ‘intermediate unit’ characterized by continuous high‐amplitude reflections; and (iii) an ‘upper unit’ with strong parallel reflectors. Several mass‐wasting deposits occur in both sub‐basins. Five sediment cores were analysed using sedimentological, microscopic, geochemical and physical techniques. The chronological model for the sediment sequence is based on 17 accelerator mass spectrometry ¹⁴C dates. Five depositional environments were characterized by their respective sedimentary facies associations. The depositional history of Lake Estanya during the last ca 21 kyr comprises five stages: (i) a brackish, shallow, calcite‐producing lake during full glacial times (21 to 17·3 kyr bp ); (ii) a saline, permanent, relatively deep lake during the late glacial (17·3 to 11·6 kyr bp ); (iii) an ephemeral, saline lake and saline mudflat complex during the transition to the Holocene (11·6 to 9·4 kyr bp ); (iv) a saline lake with gypsum‐rich, laminated facies and abundant microbial mats punctuated by periods of more frequent flooding episodes and clastic‐dominated deposition during the Holocene (9·4 to 0·8 kyr bp ); and (v) a deep, freshwater to brackish lake with high clastic input during the last 800 years. Climate‐driven hydrological fluctuations are the main internal control in the evolution of the lake during the last 21 kyr, affecting water salinity, lake‐level changes and water stratification. However, external factors, such as karstic processes, clastic input and the occurrence of mass‐flows, are also significant. The facies model defined for Lake Estanya is an essential tool for deciphering the main factors influencing lake deposition and to evaluate the most suitable proxies for lake level, climate and environmental reconstructions, and it is applicable to modern karstic lakes and to ancient lacustrine formations.     

Topographic and climatic influences on accelerated loess accumulation since the last glacial maximum in the Palouse, Pacific Northwest, USA

Topographic and climatic influences have controlled thick loess accumulation at the southern margin of the Palouse loess in northern Oregon. Juniper and Cold Springs Canyons, located on the upwind flank of the Horse Heaven Hills, are oriented perpendicular to prevailing southwesterly winds. These canyons are topographic traps that separate eolian sand on the upwind side from thick accumulations (nearly 8 m) of latest Pleistocene to Holocene L1 loess on the downwind side. Silt- and sand-rich glacial outburst flood sediment in the Umatilla Basin is the source of eolian sand and loess for the region. Sediment from this basin also contributes to loess accumulations across much of the Columbia Plateau to the northeast. Downwind of Cold Springs Canyon, Mt. St. Helens set S and Glacier Peak tephras bracket 4 m of loess, demonstrating that approximately 2500 g m⁻² yr⁻¹ of loess accumulated between about 15,400–13,100 cal yr B.P. Mass accumulation rates decreased to approximately 250 g m⁻² yr⁻¹ from 13,100 cal yr B.P. to the present. Tephrochronology suggests that the bulk of near-source Palouse loess accumulated in one punctuated interval in the latest Pleistocene characterized by a dry and windy climate.     

Production of dissolved organic carbon in forest soils along the north–south European transect

The aim of this study is to estimate the C loss from forest soils due to the production of dissolved organic C (DOC) along a north–south European transect. Dissolved organic matter (DOM) was extracted from the forest soils incubated at a controlled temperature and water content. Soils were sampled from forest plots from Sweden to Italy. The plots represent monocultures of spruce, pine and beech and three selected chronosequences of spruce and beech spanning a range of mean annual temperature from 2 to 14 °C. The DOM was characterized by its DOC/DON ratio and the C isotope composition δ¹³C. The DOC/DON ratio of DOM varied from 25 to 15 after 16 days of incubation and it decreased to between 16 and 10 after 126 days. At the beginning of incubation the δ¹³C values of DOC were 1‰ or 2‰ less negative than incubated soils. At the end of the experiment δ¹³C of DOC were the same as soil values. In addition to DOC production heterotrophic respiration and N mineralization were measured on the incubated soils. The DON production rates decreased from 30 to 5 μgN gC⁻¹ d⁻¹ after 16 days of incubation to constant values from 5 to 2 μgN gC⁻¹ d⁻¹ after 126 days at the end of experiment. The DIN production rates were nearly constant during the experiments with values ranging from 20 to 4 μgN gC⁻¹ d⁻¹. DOC production followed first-order reaction kinetics and heterotrophic respiration followed zero-order reaction kinetics. Kinetic analysis of the experimental data yielded mean annual DOC and respiration productions with respect to sites. Mean annual estimates of DOC flux varied from 3 to 29 g of C m⁻² (1–19 mg C g⁻¹ of available C), corresponding to mean DOC concentrations from 2 to 85 mg C L⁻¹.     

Outburst floods from glacial Lake Missoula

The Pleistocene outburst floods from glacial Lake Missoula, known as the “Spokane Floods”, released as much as 2184 km³ of water and produced the greatest known floods of the geologic past. A computer simulation model for these floods that is based on physical equations governing the enlargement by water flow of the tunnel penetrating the ice dam is described. The predicted maximum flood discharge lies in the range 2.74 × 10⁶−13.7 × 10⁶ m³ sec⁻¹, lending independent glaciological support to paleohydrologic estimates of maximum discharge.     

Climatic and eustatic signals in a global compilation of shallow marine carbonate accumulation rates

Two of the most important factors that control the accumulation rate of material in carbonate platform environments on geological time scales are climate and eustasy. Accurately assessing the importance of these inter‐related factors through the study of both modern and ancient carbonate facies, however, is problematic. These difficulties arise from both the complexities inherent in carbonate depositional systems and the demonstrable incompleteness of the stratigraphic record. Here, a new compilation of more than 19 000 global Phanerozoic shallow marine carbonate accumulation rates derived from nearly 300 individual stratigraphic sections is presented. These data provide the first global holistic view of changes in shallow marine carbonate production in response to climate and eustasy on geological time scales. Notably, a clear latitudinal dependence on carbonate accumulation rates is recognized in the data. Moreover, it can also be demonstrated that rates calculated across the last glacial maximum and Holocene track changes in sea‐level. In detail, the data show that globally averaged changes in carbonate accumulation rates lagged changes in sea‐level by ca 3 kyr, reflecting the commonly observed delay in the response of individual carbonate successions to sea‐level rise. Differences between the rates of carbonate accumulation and sea‐level change over the past 25 kyr ostensibly reflect changing accumulation mode, with platform drowning (give‐up mode) pervasive during peak Early Holocene sea‐level rise, followed by a switch to catch‐up mode accumulation from ca 9 ka to the present. Carbonate accumulation rates older than the Quaternary are typically calculated over time spans much greater than 100 kyr, and at these time spans, rates primarily reflect long‐term tectonically mediated accommodation space changes rather than shorter term changes in climate/eustasy. This finding, coupled with issues of stratigraphic incompleteness and data abundance, tempers the utility of this and other compilations for assessing accurately the role of climate and eustasy in mediating carbonate accumulation rates through geological time.     

High-resolution isotope records of early Holocene rapid climate change from two coeval stalagmites of Katerloch Cave,Austria

Two coeval stalagmites from Katerloch Cave show pronounced intervals of low δ¹⁸O values around 8.2, 9.1, and 10.0 kyr (all ages are reported before the year 2000 AD) and represent an inorganic U–Th dated climate archive from the southeast of the European Alps, a region where only very few well-dated climate records exist. The O isotope curves, providing near-annual resolution, allow a direct comparison to the Greenland ice core records, as temperature was the primary factor controlling the O isotopic composition of Katerloch speleothems.The 8.2 kyr climate anomaly lasted about one century, from 8196 to 8100 yr, with a maximum amplitude of 1.1‰ at 8175 yr. The event is characterized by a rapid onset and a more gradual demise and U–Th data as well as annual lamina counting support a rapid climate change towards cooler conditions within 10–20 yr. There is no strong evidence that the 8.2 kyr anomaly was superimposed on a pronounced longer-term cooling episode, nor do the new data support two separate cooling events within the 8.2 kyr event as reported by other studies. Our record also shows a distinct climate anomaly around 9.1 kyr, which lasted 70–110 yr and showed a maximum amplitude of 1.0‰, i.e. it had a similar duration and amplitude as the (central) 8.2 kyr event. Compared to the 8.2 kyr event, the 9.1 kyr anomaly shows a more symmetrical structure, but onset and demise still occurred within a few decades only. The different progression of the 8.2 (asymmetrical) and 9.1 kyr anomaly (symmetrical) suggests a fundamental difference in the trigger and/or the response of the climate system. Moreover, both stalagmites show evidence of a climate anomaly around 10.0 kyr, which was of comparable magnitude to the two subsequent events.Using a well constrained modern calibration between air temperature and δ¹⁸O of precipitation for the study area and cave monitoring data (confirming speleothem deposition in Katerloch reflecting cave air temperature), a maximum cooling by ca 3 °C can be inferred at 8.2 and 9.1 kyr, which is similar to other estimates, e.g., from Lake Ammersee north of the Alps. The O isotopic composition of meteoric precipitation, however, is a complex tracer of the hydrological cycle and these temperature estimates do not take into account additional effects such as changes in the source area or synoptic shifts. Apart from that, the relative thickness of the seasonally controlled lamina types in the Katerloch stalagmites remains rather constant across the intervals comprising the isotopic anomalies, i.e. the stalagmite petrography argues against major shifts in seasonality during the early Holocene climate excursions.     

Late Quaternary Upper Mississippi River alluvial episodes and their significance to the Lower Mississippi River system

The period in the Upper Mississippi Valley (UMV) from about 25 000 years B.P. until the time of strong human influence on the landscape beginning about 150–200 years ago can be characterized by three distinctly different alluvial episodes. The first episode is dominated by the direct and indirect effects of Late Wisconsin glacial ice in the basin headwaters. This period, which lasted until about 14 000 years B.P., was generally a time of progressive valley aggradation by a braided river system transporting large quantities of bedload sediment. An island braided system evolved during the second episode, which extended from about 14 000 to 9000 years B.P. The second episode is associated with major environmental changes of deglaciation when occurrences of major floods and sustained flows of low sediment concentration from drainage of proglacial lakes produced major downcutting. By the time of the beginning of the third episode about 9000 years B.P., most vegetation communities had established their approximate average Holocene locations. The change of climate and establishment of good vegetation cover caused upland landscapes of the UMV to become relatively stable during the Holocene in comparison to their relative instability during the Late Wisconsin. However, Holocene remobilization of Late Wisconsin age sediment stored in tributary valleys resulted in a return to long-term upper Mississippi River aggradation. The dominance of Holocene deposition over transportation reflects the abundance of sandy bedload sediment introduced from tributaries and the situation that energy conditions for floods and the hydraulic gradient of the upper Mississippi River are much less for the Holocene than they were for the Late Wisconsin and deglaciation periods.Outburst floods from glacial lakes appear to have been common in the UMV during the Late Wisconsin and especially during deglaciation. Magnitudes for the Late Wisconsin floods are generally poorly understood, but an estimate of 10 000–15 000 m³ s⁻¹ was determined for one of the largest events in the northern UMV based on heights of paleo-foreset beds in a flood unit deposited in the Savanna Terrace. For comparison, the great flood of 1993 on the upper Mississippi River was about 12 000 m³ s⁻¹ at Keokuk, Iowa, near the Des Moines River confluence where it represented the 500-year event in relation to modem flood series. Exceptionally large outburst floods derived from the rapid drainage of pro-glacial Lake Michigan and adjacent smaller proglacial lakes between about 16 000 and 15 500 years B.P. are a likely cause of the final diversion of the Mississippi River through the Bell City-Oran Gap at the upstream end of the Lower Mississippi Valley (LMV). The largest outburst flood from northern extremities of the UMV appears to have occurred between about 11700 and 10 800 years B.P. when the southern outlet of Lake Agassiz was incised. Based on the probable maximum capacity of the Agassiz flood channel 600 km downstream near the junction of the Wisconsin and Mississippi Rivers, the Agassiz flood discharge apparently did not exceed 30 000 m³ s⁻¹. However, if the Agassiz flood channel here is expanded to include an incised component, then the flood discharge maximum could have been as large as 100,000 to 125 000 m³ s⁻¹. The larger flood is presently viewed as unlikely, however, because field evidence suggests that the incised component of the cross-section probably developed after the main Agassiz flood event. Nevertheless, the large Agassiz flood between about 11 700 and 10 800 years B.P. produced major erosional downcutting and removal of Late Wisconsin sediment in the UMV. This flood also appears to be mainly responsible for the final diversion of the Mississippi River through Thebes Gap in extreme southwestern Illinois and the formation of the Charleston alluvial fan at the head of the LMV.After about 9000 years B.P. prairie-forest ecotones with associated steep seasonal climatic boundaries were established across the northern and southern regions of the UMV. The general presence of these steep climatically sensitive boundaries throughout the Holocene, in concert with the natural tendency for grasslands to be especially sensitive to climatic change, may partially explain why widespread synchroneity of Holocene alluvial episodes is recognized across the upper Mississippi River and Missouri River drainage systems. Comparison of estimated beginning ages of Holocene flood episodes and alluvial chronologies for upper Mississippi River and Missouri River systems with beginning ages for LMV meander belts and delta lobes shows a relatively strong correlation. At present, dating controls are not sufficiently adequate and confidence intervals associated with the identified ages representing system changes are too large to establish firm causal connections. Although the limitations of the existing data are numerous, the implicit causal connections suggested from existing information suggest that further exploration would be beneficial to improving the understanding of how upper valley hydrological and geomorphic events are influencing hydrological and geomorphic activity in the LMV. Since nearly 80% of the Mississippi River drainage system lies upstream of the confluence of the Mississippi and Ohio Rivers, there is a strong basis for supporting the idea that UMV fluvial activity should be having a strong influence on LMV fluvial activity. If this assertion is correct, then the traditional assignment of strong to dominant control by eustatic sea level variations for explaining channel avulsions, delta lobes, and meander belts in the LMV needs re-examination. A stronger role for upper valley fluvial activity as a factor influencing lower valley fluvial activity does not disregard the role of eustatic sea level, tectonic processes or other factors. Rather, upper valley fluvial episodes or specific events such as extreme floods may commonly serve as a “triggering mechanism” that causes a threshold of instability to be exceeded in a system that was poised for change due to sea level rise, tectonic uplift, or other environmental factors. In other situations, the upper valley fluvial activity may exert a more dominant control over many LMV fluvial processes and landforms as frequently was the case during times of glacial climatic conditions.     

Stratigraphic development during the Late Pleistocene and Holocene offshore of the Yellow River delta, Bohai Sea

A 61-m-long sediment core (HB-1) and 690 km of high-resolution seismic profiles from offshore of the Yellow River delta, Bohai Sea, were analyzed to document the stratigraphy and sea-level changes during the Late Pleistocene and Holocene. Accelerator mass spectrometry ¹⁴C dating and analyses of benthic foraminifera, ostracods, the mineral composition, and sedimentary characteristics were performed for core HB-1, and seven depositional units (DU 1–DU 7 in descending order) were identified. The seismic reflection data were interpreted in light of the sedimentological data of the core and correlated with other well-studied cores obtained previously in the Bohai Sea area. Seven seismic units (SU 1 to SU 7 in descending order) were distinguished and interpreted as follows: SU 7 corresponds to marine facies in Marine Isotopic Stage (MIS) 5; SU 6, to terrestrial facies in MIS 4; SU 5 and SU 4, to alternating terrestrial and marine facies (DU 7–DU 5) in MIS 3; SU 3, to terrestrial facies (DU 4) in MIS 2; SU 2, to Holocene marine facies (DU 3 and DU 2); and SU 1, to modern Yellow River delta sediments deposited since 1855 (DU 1).The sedimentary facies from DU 7 to DU 5 reflect sea-level fluctuations during MIS 3, and the boundary between DU 5 and DU 6, which coincides with that between SU 4 and SU 5, is a distinctive, laterally continuous, undulating erosion surface, with up to 20 m of relief. This surface reflects subaerial exposure between transgressions during MIS 3. Estimated sea levels during MIS 3 ranged from −35 ± 5 to −60 ± 5 m or lower, with short-term fluctuations of 20 m. Sedimentary environments in the Bohai Sea area were governed mainly by eustatic sea-level changes and the Bohai Strait topography, which controls the entry of sea water into the Bohai Sea area.The mineral composition of the sediment core suggests that the Yellow River did not discharge into the Bohai Sea, or at least did not influence the study area significantly, during parts of MIS 3 and MIS 2 to the early Holocene (11–8.5 cal kyr BP).     

Water fluxes and their control on the terrestrial carbon balance: Results from a stable isotope study on the Clyde Watershed (Scotland)

The gradients between precipitation and runoff quantities as well as their water isotopes were used to establish a water balance in the Clyde River Basin (Scotland). This study serves as an example for a European extreme with poorly vegetated land cover and high annual rainfall and presents novel water stable isotope techniques to separate evaporation, interception and transpiration with annual averages of 0.029 km³ a⁻¹, 0.220 km³ a⁻¹ and 0.489 km³ a⁻¹, respectively. Transpiration was further used to determine CO₂ uptake of the entire basin and yielded an annual net primary production (NPP) of 352 × 10⁹ g C (Giga gram) or 185.2 g C m⁻². Compared to other temperate areas in the world, the Clyde Basin has only half the expected NPP. This lower value likely results from the type of vegetation cover, which consists mostly of grasslands. Subtracting the annual heterotrophic soil respiration flux (R_h) of 392 Gg (206.1 g C m⁻² a⁻¹) from the NPP yielded an annual Net Ecosystem Productivity (NEP) of −40 Gg C, thus showing the Clyde Watershed as a source of CO₂ to the atmosphere. Despite the unusual character of the Clyde Watershed, the study shows that areas with predominant grass and scrub vegetation still have transpirational water losses that by far exceed those of pure evaporation and interception. This infers that vegetation can influence the continental water balances on time scales of years to decades.