Liner design for waste disposal sites

 Since the beginning of the 1980s waste disposal has become a particularly sensitive issue. This has led to the development of new legislations in the European Community and internationally which resulted in an array of regulations concerning landfill liner design. This paper comments on different "engineered" containment methods with particular reference to landfill liner design. Suggestions based on the review of the different methodologies are given and a case study is presented. Received: 25 February 1997 · Accepted: 16 December 1997     

Geochemical evaluation of suitability of sites for hazardous waste disposal: a case study of recent and old waste-disposal sites in Calabar Municipality, SE Nigeria

 Two waste-disposal sites (old and new) in Calabar Municipality, SE Nigeria were evaluated to assess their suitability as landfill sites and their impact on the groundwater. The field investigation included surface geological/hydrogeological and geochemical studies. Leachate and groundwater were sampled and analysed for 3 months (April, May and June, 1997) for geochemical characterisation. The results indicate that the two waste-disposal sites in the Calabar Municipality do not meet the requirements as landfill sites. Physico-chemical analyses for temperature, pH, conductivity, dissolved oxygen, biological oxygen demand after 5 days of incubation (BOD₅), sulphate, nitrates, nitrite, trace and major elements in the leachate known to impact human health and the environment, indicate high levels of pollution. The values for groundwater in the vicinity of the disposal sites were found to be within the World Health Organisation (WHO) permissible limit. Received: 29 March 1999 · Accepted: 3 January 2000     

Engineering geological assessment of a proposed waste disposal site in coastal southwestern Ghana

 An engineering geological investigation has been undertaken of a proposed landfill site in coastal southwestern Ghana which is characterized by torrential rains, high relative humidity, shallow groundwater conditions and almost surrounded by a ridge. The study shows that the site has some desirable characteristics such as availability of suitable soils for the construction of the capping and bottom liners of the landfill, a large tract of land for landfilling operation and its location close to a major highway. However, the groundwater table was shallow and there was a high potential for leachate intrusion into and consequent contamination of nearby groundwater abstraction wells and surface potable water sources thereby constituting serious threat to life. Construction costs could be prohibitive as extensive dewatering and backfilling of vast portions of the project site would be required to enable the provision of a separation between the shallow water table and the bottom of the landfill. Received: 20 January 1998 · Accepted: 26 May 1998     

Long-term behaviour and mineralogical reactions in hazardous waste landfills: a comparison of observation and geochemical modelling

 Drill cores from a Bavarian hazardous waste landfill were investigated for their mineralogical composition. Because of the formation of many new minerals, geochemical equilibrium calculations were performed to find the most stable state of the waste body. A comparison of mineralogical observations and geochemical modelling was undertaken. The remaining solubilities of the newly formed secondary mineral assemblages were calculated. Newly formed minerals were shown using electron microscopy. Received: 26 November 1999 · Accepted: 15 May 2000     

Integrated use of hydrochemistry and resistivity methods in groundwater contamination caused by a recently closed solid waste site

 In order to investigate the groundwater contamination by solid waste disposal using both hydrochemical and geophysical methods, the Halkalı (I˙stanbul) solid waste disposal site which was closed in 1994 was investigated. The disposal site lies on a ridge between two valleys filled with alluvium. A total of six boreholes were drilled on two lines across the Menekşe valley adjacent to the Halkalı site. Groundwater samples collected from these boreholes were analyzed for various contaminant parameters. The results indicate that TDS and chloride concentrations decrease horizontally away from the waste site whereas they increase with depth. Electrical soundings carried out at 12 locations yielded high resistivity values at the upstream part of Menekşe valley while lower values were obtained from the locations near the leachate seepage points. Received: 11 November 1997 · Accepted: 23 February 1998     

Atmospheric oxidation of the pyritic waste rock in Maardu, Estonia. 1 field study and modelling

 A field survey and modelling of the oxidation and carbonate buffering reactions inside the alum-shale-containing waste rock dumps located in Maardu, Estonia, was accomplished. In the slope areas, the shale has been altered at high temperatures due to the spontaneous combustion and the pyritic acidity has been eliminated through migration of SO_x gases out from the dump. In the central parts of the waste rock plateaus, low temperature pyrite oxidation fronts develop towards the dump depth and towards the centres of individual shale lumps. The main secondary phases precipitating in the weathering profile are gypsum, ferric oxyhydroxide, K-jarosite and smectite. The respective field data made it possible to calibrate the two-stage oxygen diffusion model and the characteristic pyrite oxidation rate 0.06–0.08 mol of pyrite reacted per kg of available water (pyrox/H₂O value) was estimated to describe the first tens of years of dump performance. The model is capable to compare different shale disposal strategies that are illustrated with two case scenarios. The buffering of sulphuric acid by Mg-calcite appears to be an incongruent reaction with gypsum precipitating that leads to the build-up of the high Mg/Ca ratio in the leachate. Application of the Mg/Ca method estimates the pyrox/H₂O value in the range of 0.05–0.14 mol/kg. Received: 26 January 1999 · Accepted: 23. February 1999     

Hydrogeological studies on the mechanical behavior of landfill gases and leachate of the Nanjido Landfill in Seoul, Korea

 The Nanjido Landfill is the largest uncontrolled landfill in Korea and it causes various kinds of environmental problems. Landfill gases and leachate are recognized as the most serious environmental problems associated with the landfill. This study employs a series of numerical models and uses test data to interpret the distribution and flow of landfill gases and leachate. Leachate seepage appears about 40–60 m higher than the estimated basal groundwater table. Thus, seepage data indicate that perched or floating leachate layers are formed in the unsaturated zone of the landfill. The leachate production rate is estimated using infiltration test data and a model for unsaturated groundwater flow. Geochemical data indicate that the landfill leachate degrades the basal groundwater quality along the downgradient zone. The environmental impact of the leachate on river water is estimated. Received: 17 June 1996 · Accepted: 2 October 1996     

Suitability of Hydrologic Evaluation of Landfill Performance (HELP) model of the US Environmental Protection Agency for the simulation of the water balance of landfill cover systems

 Cover systems are widely used to safeguard landfills and contaminated sites. The evaluation of the water balance is crucial for the design of landfill covers. The Hydrologic Evaluation of Landfill Performance (HELP) model of the US Environmental Protection Agency was developed for this purpose. This paper discusses some limitations of version 2 of this model and some operational difficulties for the use of this model in Germany, which has been developed for the United States. The model results are tested against field data of the water balance, measured on test fields on the Georgswerder landfill in Hamburg. Theoretically, HELP considers gravitational forces as driving forces of water flow only. Therefore capillary barriers cannot be simulated. Furthermore, the formation of and the flow through macropores are not considered, a main critical process that the diminishes the effectiveness of compacted soil liners. In the output comparison, the matching of measured and simulated data is quite good for lateral drainage, but failed for surface runoff and liner leakage through compacted soil liners. A further validation study is planned for HELP version 3 using a broader range of test field data. Received: 10 January 1995 · Accepted: 14 November 1995     

Analysis of flow behavior in a landfill with cover soil of low hydraulic conductivity

 This paper presents the results of field tests of hydrologic parameters in a landfill and the results of numerical simulation to find the efficiency of the pumping method to reduce leachate levels in the landfill. The field hydraulic conductivity and storativity of waste and buried cover soils in the landfill are measured by pumping and slug tests. The hydrologic condition inside the landfill is first calibrated using the drawdown-time curve obtained from the pumping test, and the flow behavior of leachate during pumping in the landfill, when various layers of waste and buried cover soil exist, is analyzed through three-dimensional numerical simulation of flow. The results of the field investigation show that the buried cover soil of low hydraulic conductivity forms an impermeable layer preventing the downward flow of leachate and upward flow of landfill gas. The hydraulic conductivities of the pumping test and slug tests were quite close on the same order of magnitude. It was also possible to match the drawdown-time data of the field tests with those of the model using input data close to the hydrologic property obtained from the field tests. The numerical flow analysis showed that pumping was possible up to 120 tons/day for a single well without a drain, while the pumping rate could be increased to 300 tons/day for the same well with the drain. From the vertical section of the flow vector with a horizontal drain, the barrier role of buried cover soil is identified, which was proposed by examining the water contents of the disposed cover soil and waste in the field. Received: 15 May 1998 · Accepted: 4 January 1999     

Chemical composition of landfill leachate in a karst area with a Mediterranean climate (Marbella, southern Spain)

 Between March 1994 and April 1997, the physical and chemical parameters and chemical composition of the urban solid waste leachate of the Marbella landfill (southern Spain) were determined. The data obtained show an ammonium and sodium chloride and bicarbonate type, a pH>7 and high mineralization, effectively described by the following parameters: Na⁺, K⁺, NH₄ ⁺, Cl^– and alkalinity. The chemical composition depends on the rainfall: in dry years, the mineralization and component concentrations have values as much as double those found in normal rainfall years. After storm events, a major and rapid dilution (within several hours) is seen in the leachate. Received: 28 January 1998 · Accepted: 2 June 1998     

Testing the ability of bentonite-amended natural zeolite (clinoptinolite) to remove heavy metals from liquid waste

 The design of environmentally sound liquid waste containment structures has become a crucial task in engineering applications due to ever increasing groundwater contamination from such sites. Construction of such structures usually requires a bottom liner of low hydraulic conductivity as part of the design. In order to reduce the hazards associated with liquid wastes including landfill leachate, bentonite-amended natural zeolite is proposed as an alternative to conventional earthen liners. Among many contaminants associated with liquid wastes, heavy metals are the most dangerous ones. This paper deals with determining the ability of natural zeolite to remove heavy metals from aqueous waste. For this purpose, crushed natural zeolite (clinoptinolite) is amended with commercial powdered bentonite to yield a soil mixture low in permeability and high in ion-exchange capacity. Leachate from a conventional landfill is used as the percolation fluid. Concentrations of certain heavy metals in the effluent fluid percolated through the bentonite-zeolite mixture are compared with that of initial leachate. The conclusion is reached that certain metals are efficiently removed from the influent solution by the soil matrix whereas some ions do not show significant reduction in concentration. This is attributed to high hydraulic conductivity of the bentonite-zeolite mixture.     

Validation of the hydrologic evaluation of landfill performance (HELP) model for simulating the water balance of cover systems

 Simulation models can be efficient tools for several tasks especially in planning. In the USA, the HELP model was developed to simulate the water balance of landfill liner systems, especially of cover systems. HELP version 3 was examined in a German climate in an extensive validation study, and a German adaptation was developed. The validation study consists of three parts: a methodological part (meaning, aims and procedure of validation), a theoretical part (comparison of the modelling approach with the state of science, comparison of documentation, literature and source code), and a practical part (sensitivity analyses and operational validation). In the operational validation, measured and simulated discharges and actual evapotranspiration data of test fields on the landfill Hamburg-Georgswerder from 1988 to 1995 were compared. Limitations, weak points, and errors of the HELP model are shown. The HELP model is a suitable tool for experts in hydrology; but good knowledge of the model and its behaviour and critical review of the simulation results are essential. Received: 14 May 1999 · Accepted: 23 September 1999     

The influence of hazardous liquid waste on the permeability of earthen liners

 Permeability and its susceptibility to changes with time or exposure to chemicals are major factors in selection of earthen liners for use in hazardous liquid-waste containment systems. Earthen liners often consist of mixtures including both granular soil and fine matrix. Six different solid mixtures were tested to investigate the influence of hazardous liquid waste on their permeability. The granular part of the mixtures included sand and crushed natural zeolite, whereas the matrix was composed of bentonite and microcement. Highly acidic solutions, bases, leather industry leachate and municipal waste leachate were used as permeants. Of the mixtures tested, only two mixtures performed well against the attack of chemicals. The testing method was the falling head system with the compaction mold permeameter. The period of experiments varied from two to eight weeks. Received: 24 September 1998 · Accepted: 5 January 1999     

CSEES: An expert system for analysis and design of cut slopes and embankments

 An expert system is developed for evaluating failure potential of cut slopes and embankments. The fuzzy sets theory is used with the modified Monte Carlo simulation technique to obtain the Slope Failure Potential Index (SFPI) incorporating factors affecting slope stability, such as geology, topography, geomorphology, precipitation, vegetation and drainage conditions. The developed Cut Slopes and Embankments Expert System (CSEES) includes a classification system for evaluating failure potential of cut slopes and embankments, and a data bank on landslides in Jordan. The proposed classification system and slope failure-potential method proved to be successful for the areas that experienced landslides in the past. The expert system can be used directly for areas with the same geological formations as those areas in which landslides occurred in the past and can be used for areas with other geological formations by modifying the rock type or foundation-material type factor incorporated in the expert system. Received: 18 February 1998 · Accepted: 19 October 1998     

Distribution and environmental impact of coal-mining wastes in Upper Silesia, Poland

 About 50 million tonnes/year of waste rock from coal-mining is generated in the limited area of the thickly populated Upper Silesian Coal Basin (USCB) in Poland. There are 380 coal-mining waste dumps, including 76 active dump sites covering over 2,000 ha. About 15-16 million tonnes/year of waste rock is being reused for civil engineering purposes in the same area. This brings about a problem of ground water deterioration by constituents leached from waste rock exposed to atmospheric conditions. The major factors determining the ground water contamination potential from waste rock are chloride salinity, sulfur content and acid generation potential. The concept behind the presented studies was to provide data for correct evaluation and prediction of contaminant release from the waste rock, based on the characterization of coal-mining waste properties, as well as on long-term laboratory, lysimetric and field studies. The results show that coal-mining waste dumps can be a long-term source of ground water contamination, lasting for decades and increasing with time. Ground water down-gradient from the disused 15–30-years-old part of the studied dump displays high and increasing acidification, high TDS, SO₄, and the highest, still increasing concentrations of Mn, Fe and Zn. Cost-effective and efficient pollution control measures, similar to the presented design and construction elements of the dump site, can mitigate the negative environmental impacts. Received: 3 July 1997 · Accepted: 9 September 1998     

Scale aspects of groundwater flow and transport systems

Flow-system analysis is based on the concept of hierarchical groundwater flow systems. The topography of the water table, which is strongly related to the topography of the land surface, is a major factor in the hierarchical nesting of gravity-driven groundwater flow, resulting in flow systems of different orders of magnitude in lateral extent and depth of penetration. The concept of flow systems is extremely useful in the analysis of spatial and temporal scales and their mutual relationships. Basic equations on the laboratory scale are extended to larger, regional scales. Making use of Fourier analysis further develops Tóth's original idea of topography-driven flow systems. In this way, the different spatial scales of the water table are separated in a natural way, leading to a simple expression for the penetration depth of a flow system. This decomposition leads also to the relationship between spatial and temporal scales. Analogous to flow systems, water bodies with different water quality may be called 'transport systems.' Field studies, numerical micro-scale modeling over macro-scale domains, and stochastic dispersion theory indicate that between systems with steady transport, the interfaces are relatively thin. The interfaces are much thinner than the relatively large mixing zones predicted by the conventional engineering approach to macrodispersion, in which relatively large, time-independent macrodispersion lengths are applied. A relatively simple alternative engineering approach is presented. For macrodispersion of propagating solute plumes, the alternative dispersion term gives the same results as the conventional engineering approach and gives correct results for steady-state transport.     

DC-resistivity mapping of internal landfill structures: two pre-excavation surveys

 Geophysical investigations using 2-D DC resistivity were carried out on old parts of two similar landfills, with waste of different ages. The data sets, which included high data density in both vertical and horizontal directions, were interpreted with 2-D smoothness constrained inversion. The landfills were excavated after the surveying. The objective was to test the capability of the resistivity method as a pre-characterization technique. The objectives were only partially fulfilled. First, the moisture content was the parameter that appeared to exert the dominant control over the resistivity distribution of the landfill. The most important potential information that can be recovered is, therefore, an indication of the waste piles hydraulics. Second, it was neither possible to estimate the amount of recoverable soils, nor to correlate the type of waste with the resistivity models. However, discrete anomalies were identified, and if specific materials are searched for, the resistivity models indicate possible places to search. Received: 23 July 1998 · Accepted: 20 October 1998     

Assessment of mercury contamination and human exposure associated with coastal disposal of waste from a cinnabar mining operation, Palawan, Philippines

 An integrated geochemical and toxicological assessment of environmental mercury contamination and attendant human exposure in Honda Bay, Palawan was undertaken in 1995 following a nationally reported pollution scare centered on a coastal jetty, Sitio Honda Bay, constructed using approximately 1 million tons of tailings and beneficiation waste from a cinnabar mine. Mercury (Hg) data for marine and fluvial sediments, fish tissues and human hair indicate that the toxicological hazard is considerably lower than initially reported by state environment and health officials. Typical Hg concentrations in surficial Honda Bay sediments were found to lie within the global background range (<60 μg/kg). Downcore profiles provide no evidence of enhanced Hg fluxes coincident with the onset of mining and/or coastal tailings disposal. The mean and median Hg concentrations recorded in tissues of six species of Honda Bay fish are compliant with thresholds established by the US Environmental Protection Agency (US-EPA) for marketable stocks. Earlier reports of 'Minamata range' Hg concentrations in fish and shellfish from Honda Bay remain unsubstantiated. Geochemical analyses of samples of the Sitio Honda Bay substrate have confirmed the prevalence of solid-phase Hg concentrations to ca. 340 mg/kg. The speciation of Hg is, however, dominated by secondary oxides of low bioavailability. The mean Hg concentration in hair from Sitio Honda Bay residents (4.41 mg/kg) was found to be statistically analogous to that for a neighbouring coastal community unimpacted by the coastal disposal of mine waste. A negligible residential exposure factor is thus inferred for the former. Relatively high hair Hg burdens prevail throughout the coastal Honda Bay population, consistent with significant methyl Hg ingestion through daily fish consumption. The data presented provide no environmental or toxicological justification for immediate remedial action. Received: 14 May 1998/Accepted: 1 September 1998     

Water vulnerability assessment in karst environments: a new method of defining protection areas using a multi-attribute approach and GIS tools (EPIK method)

 Groundwater resources from karst aquifers play a major role in the water supply in karst areas in the world, such as in Switzerland. Defining groundwater protection zones in karst environment is frequently not founded on a solid hydrogeological basis. Protection zones are often inadequate and as a result they may be ineffective. In order to improve this situation, the Federal Office for Environment, Forests and Landscape with the Swiss National Hydrological and Geological Survey contracted the Centre of Hydrogeology of the Neuchatel University to develop a new groundwater protection-zones strategy in karst environment. This approach is based on the vulnerability mapping of the catchment areas of water supplies provided by springs or boreholes. Vulnerability is here defined as the intrinsic geological and hydrogeological characteristics which determine the sensitivity of groundwater to contamination by human activities. The EPIK method is a multi-attribute method for vulnerability mapping which takes into consideration the specific hydrogeological behaviour of karst aquifers. EPIK is based on a conceptual model of karst hydrological systems, which suggests considering four karst aquifer attributes: (1) Epikarst, (2) Protective cover, (3) Infiltration conditions and (4) Karst network development. Each of these four attributes is subdivided into classes which are mapped over the whole water catchment. The attributes and their classes are then weighted. Attribute maps are overlain in order to obtain a final vulnerability map. From the vulnerability map, the groundwater protection zones are defined precisely. This method was applied at several sites in Switzerland where agriculture contamination problems have frequently occurred. These applications resulted in recommend new boundaries for the karst water supplies protection-zones. Received: 27 October 1997 · Accepted: 4 July 1998