Leucogranites from the Eastern Part of the South Mountain Batholith, Nova Scotia

The South Mountain Batholith is a peraluminous granitic complexranging in composition from biotite granodiorite to muscovite-topaz‘leucogranite’. Leucogranitic rocks (with generally<2% biotite) form a minor part ({small tilde}1•5%) ofthe batholith, and are of two types: (1) ‘associated leucogranites’occurring as relatively small zones in fine-grained leucomonzogranites;and (2) ‘independent leucogranites’ forming generallylarger bodies having no particular spatial association withother rock types. Mean chemical compositions of these two typesof leucogranite are as follows (associated, independent): Na₂O(3•46,3•83),K₂O(4•40,4•09),andP₂O₅ (0•26, 0•45)in wt.%;Li(149, 281), F(1199, 2712),Rb (393, 725), U (7•4, 4•4), Nb (12•8, 23•4),Ta (2•9, 7•1), and Zr (52, 31) in ppm. Rare earthelements also differ between the two types (associated, independent):REE (34•1 ppm, 19•9 ppm); and in the degree and variabilityof heavy REE fractionation (Gd_N/Yb_N=4•62•2, 2•00•7).In addition, associated leucogranite has REE compositions similarto those of its host rocks. Mean ¹⁸O values (associated +ll•21•2,independent +ll•40•5; relative to SMOW) are comparablewith the mean for the entire South Mountain Batholith (+l0•80•7).Radiometric dating (⁴⁰Ar/³⁹Ar on muscovite) shows that bothtypes of leucogranite have identical ages of 3723 Ma, equivalentto ages determined by other techniques for granodiorite andmonzogranite samples elsewhere in the batholith. Field relationsand geochemistry suggest that the associated leucogranite resultsfrom an open-system interaction between a fluid and its hostleucomonzogranite, whereas the independent leucogranite bodiesare discrete intrusions of highly fractionated melts that underwentclosed-system, late-magmatic to post-magmatic fluid alteration.Where mineralized, the associated leucogranite characteristicallyhosts greisen-type or disseminated polymetallic mineralization,whereas the independent leucogranite hosts pegmatitic or disseminatedpolymetallic mineralization.     

Ring schlieren: Description and interpretation of field relations in the Halifax Pluton,South Mountain Batholith,Nova Scotia

A ∼35 km coastal transect of the Halifax Pluton in South Mountain Batholith (SMB) reveals 96 m-scale ring schlieren, clustered in four locations. Ring schlieren are alternating melanocratic gradational to leucocratic bands in granites forming open to closed, nested, circular to elliptical, concentric to eccentric structures with centres aligned along the major axis or minor axis of the outer ellipse, with a cylindrical form in three dimensions, and in which cross-cutting relations suggest a younging direction towards the centre. We use detailed geometric measurements of these ring schlieren to interpret the process(es) of their formation, and to indicate the relative timing of emplacement of the SMB. The dimensions and orientations of the rings are highly variable: major-axis lengths (1.39 ± 1.43 m), minor-axis lengths (1.01 ± 0.79 m), ellipticities (1.34 ± 0.25), and major-axis orientations (008°±54°). Ring schlieren appear to be the youngest structures in this part of the batholith. Modal-abundance and grain-size variation in the rings suggests that they result from shear flow. In three dimensions, the rings are nested vertical cylinders, and probably represent vertical fossil pathways, either of descending xenoliths or of ascending supercritical vapour bubbles. Such processes can produce, and preserve, a track in a crystal-melt mush having a degree of crystallinity between 55 and 75%. Two miarolitic cavities within one multi-ring structure suggest that a rising bubble train may have produced the rings.     

Magmatic andalusite from the South Mountain batholith,Nova Scotia

Accessory andalusite has been found in some late-stage granitic differentiates of the South Mountain batholith. The andalusite is petrographically distinct from the andalusite of the thermal aureole, and it occurs in regions of the batholith which show little evidence of contamination by the country rocks. Analyses of biotites from andalusite-bearing and andalusite-free phases suggest that those coexisting with andalusite actually grew in equilibrium with the andalusite. It is concluded that magmatic andalusite must be confined mainly to water-saturated, peraluminous, epizonal granites, and some possible P-T paths for the crystallization of magmatic andalusite are considered.     

Strontium isotope geology of the South Mountain batholith,Nova Scotia

The South Mountain batholith of southwestern Nova Scotia is a large, peraluminous, granodiorite-granite complex which intrudes mainly greenschist facies metasediments of the Cambro-Ordovician Meguma Group. Using Rb-Sr isochrons constructed from whole rocks and mineral separates, the present study shows a variation in age and initial ratios of the intrusive phases of the batholith as follows: biotite granodiorite (371.8 ± 2.2 Ma, (${}^{87}\text{Sr}{}^{86}\text{Sr}\text{)}{}_{\mathrm{i}}$ ranges from 0.7076 ± 0.0003 to 0.7090 ± 0.0003, with the average = 0.7081); adamellite (364.3 ± 1.3 Ma, $\text{(}{}^{87}\text{Sr}{}^{86}\text{Sr}\text{)}{}_{\mathrm{i}}\text{= 0.70942 ± 35}$); porphyry (361.2 ± 1.4 Ma, $\text{(}{}^{87}\text{Sr}{}^{86}\text{Sr}\text{)}{}_{\mathrm{i}}\text{= 0.71021 ± 119}$); using λ⁸⁷Rb = 1.42 × 10^?11yr^?1.A suite of Meguma country rock samples showed a variation of ${}^{87}\text{Sr}{}^{86}\text{Sr}\text{= 0.7113?0.7177}$ at the time of intrusion of the batholith. A number of xenoliths of this material occurring in the marginal granodiorite had partially equilibrated isotopically with the granodiorite at a higher ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratio than elsewhere in the granodiorites. This evidence demonstrates that isotopic (and probably some accompanying bulk chemical) contamination by the Meguma rocks has been an important factor in determining the ultimate chemical composition and mineralogy of the South Mountain batholith.The $\text{(}{}^{87}\text{Sr}{}^{86}\text{Sr}\text{)}{}_{372}\text{= 0.7081}$ of the early granodiorites indicates that the parent magma of the South Mountain batholith was derived from a source unlike the Meguma Group. The precise nature of the source region cannot be determined by Rb-Sr work unless the degree of contamination with Megumalike material is known.     

Lead isotope and trace element composition of K-feldspars from peraluminous granitoids of the Late Devonian South Mountain Batholith (Nova Scotia, Canada): implications for petrogenesis and tectonic reconstruction

The South Mountain Batholith (SMB) of southwestern Nova Scotia (Canada) is a Late Devonian (~375 Ma) composite intrusion, which crops over an area of about 7,300 km². This peraluminous granitoid body consists of rocks ranging from granodiorite through monzogranite and leucomonzogranite to leucogranite that locally host greisen tin-base metal mineralization. K-feldspar displays large compositional variations of trace elements and Pb isotopic ratios, particularly in the highly fractionated rocks. Many variations are consistent with processes of fractional crystallization, but a distinct enrichment of Rb, Li and Cs accompanied by low K/Rb, Ba/Rb, Eu/Eu* and K/Cs ratios point to the role of fluids during the late stages of magmatic evolution. The correlation of Pb isotopic ratios with the enriched elements and their ratios implies that the isotopic variations are an integral part of the evolution of the SMB. Together with well-defined isochronal relationships of Pb systems in the feldspars, the correlation suggests that fractional crystallization accompanied in the late stages by fluid fractionation led to the formation of Li–F-rich leucogranites. Internally derived U-rich fluids fractionated U/Pb ratios, which in turn produced distinct variations of ²⁰⁶Pb/²⁰⁴Pb and ²³⁸U/²⁰⁴Pb ratios in K-feldspars. This implies that the Pb isotopic values of K-feldspar, which have traditionally been used for tectonic reconstructions, might have been modified in many granitic rocks. Thus, only early magmatic K-feldspars, which show no discernible effects of fluid fractionation yield the initial Pb isotopic compositions of the parental granitic magmas and their sources. The data also show that the geochemical characteristics of the leucogranites are the results of magmatic evolution rather than a distinctive source.     

Low pressure cordierite-bearing migmatites from Kelly's Mountain,Nova Scotia

The Kelly's Mountain gneiss complex of Cape Breton Island, Nova Scotia, is a migmatitic paragneiss dominated by biotite- and cordierite-bearing assemblages. Metamorphic grade throughout the complex is in the upper amphibolite facies, with garnet absent and only retrograde muscovite present. In the high grade core of the complex the reaction biotite+andalusite+quartz=cordierite+K-feldspar+sillimanite+ilmenite+H₂O is preserved. The pelitic migmatites contain cordierite- and K-feldspar-rich leucosomes and biotite-rich melanosomes. Minor clinopyroxene-bearing amphibolite in the complex does not show migmatitic textures. The migmatites are interpreted as in situ peraluminous partial melts on the basis of phase relations and textural criteria. Retrograde metamorphism under conditions of high fluid pressure locally produced muscovite after K-feldspar and muscovite+green biotite+chlorite after cordierite in paragneiss, and sphene after ilmenite in amphibolite. Peak metamorphic conditions of 1–3.5 kb and 580–700° C are estimated. The high geothermal gradient inferred from these conditions was probably caused by the intrusion of diorites associated with the gneiss complex. The Kelly's Mountain complex represents a rare example of migmatites formed in the low-pressure facies series, and illustrates some of the reactions involving melting in high grade pelitic rocks.     

铀的地球化学性质与成矿——以华南铀成矿省为例

铀是强不相容元素,随着岩浆演化而不断富集,在岩浆演化末期受结构氧增加影响进入独居石、磷钇矿等副矿物中。岩浆演化通常无法直接形成达到工业品位的铀矿床。铀是对氧逸度敏感的变价元素。在表生风化过程中岩体(层)中的铀被氧化为UO_2~(2+)而极易溶解进入水体中,并可在还原环境沉淀而富集成矿,氧化还原界面是找矿的理想选区。大气水可通过断裂构造系统进入一定深度,并受热源作用形成高氧逸度的热液而萃取出岩体(层)中的铀在还原位置沉淀富集形成矿床。新元古代氧化事件以及Marinoan冰期结束使得表生风化过程中更多的U进入水体;而寒武纪生命大爆发,易在沉积盆地底部形成还原环境,有利于U的沉淀富集。受上述三方面因素控制,在华南形成了广泛分布的富铀黑色页岩层,并被之后的沉积物覆盖,成为华南各型铀矿床的铀源层。印支期构造运动使部分富铀黑色页岩层发生部分熔融形成了富铀的S型花岗岩,该类岩石亦是之后铀成矿作用的铀源岩。燕山运动后期华南发生伸展构造背景下的岩浆热事件为以大气水为主的高氧逸度热液的形成并作用于铀源岩(层)提供了有利条件,促使华南各类型铀矿床开始在白垩纪集中形成。     

Rounded cobbles that have not travelled far: incorporation of corestones from saprolites in the South Mountain area of southern Nova Scotia, Canada

Saprolitic palaeosurfaces occur at several localities on the granitoid rocks of the South Mountain Batholith of Nova Scotia. There are three ages of saprolites within the study area: pre-Pleistocene, pre-Triassic and pre-Carboniferous. Within these ‘in-place’ weathered horizons, there are remnant ellipsoidal blocks of unweathered granitoid referred to as corestones. These corestones are isolated rounded pods of relatively unweathered material surrounded by rotted granitoid saprolitic material. The weathered material which surrounds these corestones is poorly consolidated and easily eroded. The erosion of these horizons produces a lag deposit that contains many rounded corestones which can be incorporated into subsequent sedimentary units. The rounded boulders, cobbles and pebbles of granite within many of the Pleistocene glacial deposits in southern Nova Scotia are probably related to the incorporation of these saprolite related structures, given the locally derived (within 400 m of the source) nature of the tills. The presence of saprolites at unconformities of various ages on the South Mountain granitoid rocks suggests that incorporation of saprolitic material probably occurred along a number of palaeosurfaces in the past. The recognition of this process has implications for the interpretation of rounded granite-clast conglomerates and quartz-rich sandstones of various ages within the stratigraphic record of eastern Canada. Similar palaeosurfaces elsewhere in the world also have related saprolite derived sedimentary rocks associated with them. In summary, well-rounded spherical pebbles, cobbles and boulders of granitoid material incorporated in sedimentary strata need not have travelled far from source nor are they necessarily recycled from older conglomerates.     

Environmental status of several Shubenacadie River headwater lakes,Nova Scotia,Canada

The Shubenacadie River basin is the largest watershed in Nova Scotia, Canada, encompassing an area of approximately 2,800 km² and supporting one of the most rapidly expanding populations in Atlantic Canada. A comprehensive study was carried out to assess the effect of recent development in the basin on the headwater lakes. Information on the environmental status of the lakes can be further used in the development of a management framework for the basin with respect to water quality and quantity objectives.Water and sediment quality were investigated in four of the Shubenacadie River headwater lakes. In addition, trophic status of the lakes was assessed by using dissolved phosphorus and oxygen concentrations. The surface area and mean depth of the lakes ranged from 0.83 to 1.13 km² and 4.3 to 6.6 m, respectively. Three of the studied lakes were thermally stratified during the summer. The concentration of dissolved oxygen decreased significantly in the hypolimnion during the stratification period, although the lakes were generally classified as oligotrophic. The water quality is typical for lakes of the area. The pH of the water ranged between 6.1 and 7.3 during the study period. Major ions were chloride, sodium, and sulphate. A significant increase of As, Hg, Zn, Pb, Cu, Ni and Co was found in surface sediments in all four lakes. However, the concentration of these elements in lake water was lower than recommended guidelines for aquatic life and human consumption.     

安徽庐枞盆地砖桥深部钻孔内电气石对铀钍成矿流体在高温阶段的指示意义

安徽庐枞盆地砖桥深部钻孔深部(1 500~1 900 m)岩体内存在大量铀钍矿化,局部达到工业品位,为区域铀钍矿床(点)在盆地深部、高温热液阶段的产物。钻孔内存在大量电气石族矿物,电气石经历了生长-溶蚀、交代、再沉积-再生长的过程,可至少划分为3个期次,具有以下特点:①晶体因化学成分不同而呈现不同的颜色、结构;②存在于高温阶段;③由于氧化还原状态、流体成分的改变,化学成分发生Fe-Al、Fe-Mg等置换;④从早到晚的3个期次电气石中Mg含量均较高且相对稳定,Fe3+含量逐渐升高,反映氧逸度逐渐升高。电气石族矿物常在高中温热液矿床内出现,因具有多期次且颜色可随成分不同而异,常认为在找矿和勘察中具有重大意义。深钻内多期次的电气石化揭示了流体早期相对富镁,而后镁、铝含量有所降低,铁的含量相对升高。电气石反映出流体氧逸度逐渐升高和富F、B、H2O等挥发分的特征,这些为U6+的形成和运移提供了环境,反映了铀钍成矿流体在盆地深部高温阶段的演化特征。     

Deglaciation environments and evidence for glaciers of Younger Dryas age in Nova Scotia, Canada

The start of deglaciation is recorded in the Minas Basin region of Nova Scotia by the deltaic, glaciofluvial and glaciomarine sediments of the Five Islands Formation. Shell dates on bottomset beds of a delta at Spencers Island range from 14,300 to 12,600^{, 14}C yearsB.P. The time of complete deglaciation of Nova Scotia is still unknown; the uncertainty is at least partially due to evidence for a climatic oscillation at the end of the Late Wisconsinan. Peat beds were deposited during the interval between 12,700 and 10,500 B.P. They overlie previous glacial and fluvial deposits and are overlain by deposits of various origins. Pollen in these peat beds records the migration of spruce into the region indicating climatic warming, and a subsequent deterioration of climate is recorded by the return of tundra-like flora. The peat beds are truncated by a variety of deposits, including fluvial gravel and sand, lacustrine sand, silt and clay, and diamictons. Periglacial landforms and structures have been observed in some of these deposits. At Collins Pond, on the shore of Chedabucto Bay, a diamicton overlying a peat bed is characterized by strong fabrics parallel to the trend of other ice-flow landforms in the region. The evidence suggests that at least some of these deposits are glacigenic, indicating that glaciers were active in Nova Scotia until about 10,000 B.P.     

Multiproxy evidence of an early Holocene (8.2 kyr) climate oscillation in central Nova Scotia,Canada

An early Holocene lake sediment record from central Nova Scotia contains a minerogenic oscillation that is closely correlative with the 8.2 kyr event (ca. 8200 cal. yr BP), an event that has not been reported elsewhere in Atlantic Canada. A variety of biological and sedimentological indicators have been examined to characterise autochthonous and allochthonous changes that occurred during this time. The minerogenic upper oscillation (UO, ca. 8400 cal. yr BP) is marked by an increase in the chrysophyte:diatom ratio. Following the oscillation, the diatom community reflects a shift to more productive, less acidic conditions. The pollen record shows no major response to this short‐lived event. Lithostratigraphic analyses indicates that the UO is characterised by an increase in clastic content, magnetic susceptibility and mean sediment grain size, all indicators of changing environmental conditions, most likely the result of regional cooling. The Taylor Lake record adds to a growing body of evidence for a widespread, hemispheric climate oscillation at 8.2 kyr. Copyright © 2002 John Wiley & Sons, Ltd.     

Colloidal arsenic composition from abandoned gold mine tailing leachates in Nova Scotia,Canada

Asymmetric-Flow Field-Flow Fractionation (AsFlFFF) coupled to an inductively coupled plasma-mass spectrometer (ICP-MS) was used to determine whether colloidal As exists in mine tailings from abandoned Au mine sites in Nova Scotia. Using this technique, the chemical composition and the size of the colloidal material was determined. Tailings samples were collected from the sites and leachates were analyzed. The resulting fractograms showed the presence of colloidal As. Arsenic co-elutes with Fe and Al suggesting that the As is associated with colloids containing these elements. The colloidal material present in the samples has a calculated median size of 7 nm. The leachates were also analyzed for totalAs, Fe and Al using ICP-MS. The colloidal fraction was determined to account for approximately 20% of the total dissolved As present in these samples. Dissolved As concentrations at the selected mine sites are very high and the arbitrary cutoff for dissolved still incorporates colloidal material. Therefore. it is important to distinguish between truly dissolved and colloidal As as the speciation will affect the toxicity and mobility of As at these locations.     

The tin zone: sediment-hosted hydrothermal tin mineralization at Rooiberg,South Africa

The Rooiberg tin field, also known as the Rooiberg Fragment, is located within the western lobe of the Bushveld Complex. The fragment is triangular-shaped, consists of early Proterozoic Transvaal Sequence volcano-sedimentary rocks, and is surrounded by granitoid intrusives of the Lebowa Granite Suite. Practically all the significant tin deposits are hosted by arkoses, located towards the transition with shaly arkoses at the stratigraphic top of the Boschoffsberg Quartzite Member. This stratabound distribution of individual deposits gave rise to the concept of a regionally developed continuous stanniferous zone. On regional scale, the individual deposits are broadly similar and are collectively classified as replacement and open space-filling type. Particular styles of mineralization such as tourmaline pockets/orbicules, disseminated cassiterite, steep and flat dipping sulphidic fractures and hydrothermal carbonate breccias appear to dominate each mine. Petrological and geochemical investigations of four mineralized centres, indicated the presence of a 500–600 m thick stratified zone of pervasively altered clastic sedimentary rocks of possible arkosic precursor composition. Alteration displays a distinct zonal distribution consisting of a grey-green sodic (albitized) foot wall, an approximately 80 m transitional sericitized-tourmalinized sulphidic tin zone and red hematitic potassic hanging wall. The observed zonal pattern and localization of economically significant cassiterite, is explained by the evolutionary path of magmatic stanniferous hydrothermal fluids genetically related to the surrounding acid phase of the Bushveld Complex. Areas of high fracture density, the tectonic focal points, acted as conduits for the ascending reactive fluids. Factors such as fluid-lithostatic pressure equilibration, limited fracture evolution and/or impermeable shaly arkose retarded this ascent. As a result accumulation, lateral spreading of fluid and pervasive alteration occurred over a broad stratified front. Lateral overlapping of these fronts creates the impression of a continuous tin zone. Abundance of geochemical common denominators between the various focal points (mines) supports a shared composition and source for these contemporaneous fluids.     

Regional recharge estimation using multiple methods: an application in the Annapolis Valley, Nova Scotia (Canada)

Recharge is a key parameter in groundwater resources management, and a reliable estimate of recharge is required for their sustainable development. Several methods are available to evaluate recharge; however, selecting the appropriate one is made difficult because each method has its advantages and drawbacks, and results can vary greatly from one method to another. Recharge methods can actually refer to different processes. This paper compares and discusses the results obtained from five regional-scale recharge assessment approaches applied to a fractured rock aquifer in a region with a temperate and humid climate (Annapolis Valley, Nova Scotia, Canada). These methods are distinguished between those providing estimates of the net infiltration (I) into the subsurface (river hydrograph separation and soil moisture balance) from those considering the net recharge (W) to the regional bedrock aquifer (river 7-day low-flows, the corrected soil moisture balance, a numerical groundwater flow model developed with FEFLOW and an infiltration model developed with HELP). The estimated net infiltration ranges from 160 to 250 mm/year, whereas the net recharge estimates range from 80 to 175 mm/year for the entire study area. Although different assessment methods were used, the estimated recharge range is still quite large, demonstrating the importance of using several methods. This case study should provide guidance on choices to be made in the development of a strategy for assessing representative values of aquifer recharge at the regional scale under similar geological and climatic conditions. The use of multiple complementary approaches should lead to a better understanding of the system dynamics and to better defined a representative range of recharge estimates.     

Fluid-driven low-grade metamorphism in polydeformed rocks of Avalonia (Arisaig Group, Nova Scotia, Canada)

The Lower Silurian??Lower Devonian Arisaig Group (Antigonish Highlands) in the Canadian Appalachians is a sequence of shallow marine strata deposited after the accretion of Avalonia to Baltica during the closure of the Iapetus Ocean. Deformation of the strata is widely attributed to the Devonian Acadian orogeny and produced shallowly plunging regional folds and a cleavage of varying penetrativity. Phyllosilicate minerals from the finest-grained rocks exhibit very low-grade (diagenetic-anchizone) metamorphic conditions. X-ray diffraction study reveals that the sampled rocks contain quartz, K-white mica, chlorite, and feldspars; illite?Csmectite and chlorite?Csmectite mixed-layers are common but Na?CK mica and kaolinite occur only in some samples. The identification of illite?Csmectite mixed-layers in diagenetic samples, with Kübler Index >0.50 ??°2?? and the highly heterogeneous b-cell dimension of the K-white micas are in agreement with the variable chemical composition of dioctahedral micas, which present low illitic substitution and variable phengitic content. The spatial variation in the above crystal-chemical parameters was plotted along a NW?CSE composite cross section across the regional folds. No correlation was found between the metamorphic conditions and either the stratigraphic depth or the strain values measured by phyllosilicates orientation analyses, as a function of the penetrativity of the cleavage. However, the metamorphic grade generally increases towards the Hollow Fault, and is highest in samples located within a 1?km corridor from the fault surface. Incipient cleavage is observed in the anchizonal samples located in the vicinity of the Hollow Fault and in some of the diagenetic samples, indicating cleavage development under low temperatures (<200?oC). These relationships, together with regional syntheses, suggest low-grade metamorphism post-dated regional folding and was coeval with Late Carboniferous dextral movement along the Hollow Fault. Fluid circulation associated with movement along this major fault may be the driving mechanism for the increasing metamorphism towards it.     

锡的地球化学性质与华南晚白垩世锡矿成因

锡在地质过程中表现出亲氧、亲硫和亲铁三重特性。在地幔岩浆过程中,锡是一种中等不相容的金属元素。锡成矿主要与酸性岩浆活动有关,其地球化学性质决定了其成矿主要受源区性质、氧逸度以及挥发分含量、岩浆结晶分异等因素控制。高度结晶分异可使锡在岩浆中进一步富集,是锡成矿相关花岗岩的普遍特征;锡为变价元素,岩浆体系氧逸度影响源区中锡的迁移能力和分离结晶过程中锡的元素行为,还原性岩浆体系有利于锡富集成矿。富含F、Cl和B等挥发组分对锡元素的迁移和富集起积极的作用。全球锡矿床分布与俯冲带关系密切,特提斯和环太平洋构造域是主要蕴藏区。重要的锡成矿事件表现出区域性和阶段性的特征。结合锡的地球化学特性以及锡矿分布特征,我们认为最有利锡成矿的动力学机制是俯冲板片后撤机制。俯冲板片后撤引发深部软流圈地幔上涌,导致强烈的壳幔相互作用,形成低氧逸度、富F、Cl和B等花岗岩,有利于锡成矿。对于华南晚白垩世锡成矿事件,新特提斯洋俯冲板片发生后撤是其成矿地球动力学背景。     

The biogeochemical expression of deeply buried uranium mineralization in Saskatchewan, Canada

Ten kilometres from the eastern edge of the Athabasca Sandstone, near McClean Lake, uranium mineralization (locally up to 27% U₃O₈) lies 150 m beneath the surface at the unconformity between the Athabasca and crystalline basement.A biogeochemical survey of the area sampled A_H and B_F soil horizons, peat moss, and plant organs from the dominant species, viz. black spruce (Picea mariana), jack pine (Pinus banksiana), labrador tea (Ledum groenlandicum), and leather leaf (Chamaedaphne calyculata). Uranium concentrations in the ash of various media are surprisingly high: spruce twigs up to 154 ppm U; labrador tea and leather leaf stems around 100 ppm U. Conversely, labrador tea roots yield < 5 ppm U and spruce trunk wood usually < 1 ppm U. Soils give values of 1–3 ppm U. Contoured U values reveal that highest concentrations occur in plants growing above, but laterally displaced from the mineralization. Track-Etch data show a similar pattern. Upward migration of ions along steeply inclined fractures is invoked to explain the phenomenon. Other elements are present in varying concentrations, depending upon the plant species and the plant organ. High concentrations of several elements are recorded, most notably Cd and Ag in the conifers.     

The Scots Bay formation, Nova Scotia, Canada, a Jurassic carbonate lake with Silica-rich hydrothermal springs

During Early Jurassic time, the Scots Bay Formation accumulated in an aerobic lake on the floor of the subtropical Fundy rift valley. A diverse biota flourished in the lake as evidenced by algal stromatolites, oncolites, charophytes, ostracods, gastropods, conchostracans, fish bones, calcispheres and logs. Carbonate wackestone and packstone were deposited in the littoral zone and lime mudstone accumulated offshore on a proximal slope. Silica-rich hydrothermal springs and seeps around and on the floor of the lake precipitated siliceous tufa and silicified adjacent carbonate strata. The tufa is characterized by the progressive sequence: (1) open-framework, porous substrate of goethite spheres, (2) encrusting chalcedony spherulites where goethite inclusions decrease in size and number outwards towards the surfaces of the spherulites, (3) a fringe of quartz on the chalcedony spherulites and (4) coarsening inwards mosaics of quartz that filled the remaining voids. Carbonate diagenesis included conversion of low-Mg calcite ooze to micrite and microspar-pseudospar, and local dissolution and reprecipitation of calcite cement. At times the lake shrank in size, concentrating silica in increasingly alkaline lake water which then silicified some of the carbonate strata and logs. The latest cements were calcite, zeolites and celadonite.